ES2722250T3 - Sustancias químicas de curado por adición de Michael para composiciones de polímero que contienen azufre - Google Patents

Sustancias químicas de curado por adición de Michael para composiciones de polímero que contienen azufre Download PDF

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Publication number
ES2722250T3
ES2722250T3 ES13732070T ES13732070T ES2722250T3 ES 2722250 T3 ES2722250 T3 ES 2722250T3 ES 13732070 T ES13732070 T ES 13732070T ES 13732070 T ES13732070 T ES 13732070T ES 2722250 T3 ES2722250 T3 ES 2722250T3
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integer
independently selected
chr3
michael
sulfur
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Lawrence G Anderson
Juexiao Cai
Marfi Ito
Raquel Keledjian
Renhe Lin
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PRC Desoto International Inc
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PRC Desoto International Inc
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02Polythioethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02Polythioethers
    • C08G75/04Polythioethers from mercapto compounds or metallic derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02Polythioethers
    • C08G75/04Polythioethers from mercapto compounds or metallic derivatives thereof
    • C08G75/045Polythioethers from mercapto compounds or metallic derivatives thereof from mercapto compounds and unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/12Polythioether-ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/14Polysulfides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/02Polythioethers; Polythioether-ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/04Polysulfides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D181/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Coating compositions based on polysulfones; Coating compositions based on derivatives of such polymers
    • C09D181/04Polysulfides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J181/00Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Adhesives based on polysulfones; Adhesives based on derivatives of such polymers
    • C09J181/02Polythioethers; Polythioether-ethers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J181/00Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Adhesives based on polysulfones; Adhesives based on derivatives of such polymers
    • C09J181/04Polysulfides

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Sealing Material Composition (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyethers (AREA)

Abstract

Un aducto de politioeter que comprende al menos dos grupos aceptores de Michael terminales, en donde el aducto de politioeter se selecciona de un aducto de politioeter de Formula (3), un aducto de politioeter de Formula (3a) y una combinacion de los mismos: R6-S-R1-[-S-(CH2)p-O-(R2-O)m-(CH2)2-S-R1-]n-S-R6 (3) {R6-S-R1-[-S-(CH2)p-O-(R2-O)m-(CH2)2-S-R1-]n-S-V'-}zB (3a) en las que: cada R1 se selecciona, de manera independiente, de alcanodiilo C2-10, cicloalcanodiilo C6-8, alcanocicloalcanodiilo C6-10, heterocicloalcanodiilo C5-8 y -[(-CHR3-)s-X-]q-(-CHR3-)r-, en las que: s es un numero entero de 2 a 6; q es un numero entero de 1 a 5; r es un numero entero de 2 a 10; cada R3 se selecciona, de manera independiente, de hidrogeno y metilo; y cada X se selecciona, de manera independiente, de -O-, -S- y -NHR-, en donde R se selecciona de hidrogeno y metilo; cada R2 se selecciona, de manera independiente, de alcanodiilo C1-10, cicloalcanodiilo C6-8, alcanocicloalcanodiilo C6-14 y -[(-CHR3-)s-X-]q-(-CHR3-)r-, en donde s, q, r, R3 y X son tal como se definen para R1; m es un numero entero de 0 a 50; n es un numero entero de 1 a 60; p es un numero entero de 2 a 6; B representa un nucleo de un agente de polifuncionalizacion terminado en vinilo z-valente B(-V)z en el que: z es un numero entero de 3 a 6; y cada V es un grupo que comprende un grupo vinilo terminal; y cada -V'- se deriva de la reaccion de -V con un tiol; y cada R6 se selecciona, de manera independiente, de una vinil cetona, una vinil sulfona, una quinona, una enamina, una cetimina, una aldimina y una oxazolidina.
ES13732070T 2012-06-21 2013-06-21 Sustancias químicas de curado por adición de Michael para composiciones de polímero que contienen azufre Active ES2722250T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/529,237 US8871896B2 (en) 2012-06-21 2012-06-21 Michael addition curing chemistries for sulfur-containing polymer compositions
US13/659,152 US9018322B2 (en) 2012-06-21 2012-10-24 Controlled release amine-catalyzed, Michael addition-curable sulfur-containing polymer compositions
PCT/US2013/046948 WO2013192480A2 (en) 2012-06-21 2013-06-21 Michael addition curing chemistries for sulfur-containing polymer compositions

Publications (1)

Publication Number Publication Date
ES2722250T3 true ES2722250T3 (es) 2019-08-08

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US (2) US9018322B2 (es)
EP (2) EP3495435A1 (es)
JP (1) JP6054524B2 (es)
KR (1) KR101674838B1 (es)
CN (1) CN104487488B (es)
AU (1) AU2013277027B2 (es)
BR (1) BR112014031820B1 (es)
CA (1) CA2876944C (es)
ES (1) ES2722250T3 (es)
HK (1) HK1204634A1 (es)
IN (1) IN2014DN10829A (es)
MX (1) MX2014015630A (es)
RU (1) RU2608739C2 (es)
WO (1) WO2013192480A2 (es)

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JP6054524B2 (ja) 2016-12-27
CN104487488A (zh) 2015-04-01
EP2864395B1 (en) 2019-03-13
CN104487488B (zh) 2016-08-03
RU2608739C2 (ru) 2017-01-23
WO2013192480A2 (en) 2013-12-27
AU2013277027B2 (en) 2015-08-27
CA2876944C (en) 2016-12-13
KR101674838B1 (ko) 2016-11-09
WO2013192480A3 (en) 2014-02-13
US20130345389A1 (en) 2013-12-26
MX2014015630A (es) 2015-07-06
RU2015101718A (ru) 2016-08-10
KR20150023044A (ko) 2015-03-04
BR112014031820B1 (pt) 2021-03-09
JP2015520293A (ja) 2015-07-16
AU2013277027A1 (en) 2015-01-22
US9499668B2 (en) 2016-11-22
IN2014DN10829A (es) 2015-09-04
US20150099858A1 (en) 2015-04-09
BR112014031820A2 (pt) 2017-06-27
HK1204634A1 (en) 2015-11-27
EP3495435A1 (en) 2019-06-12
EP2864395A2 (en) 2015-04-29
US9018322B2 (en) 2015-04-28
CA2876944A1 (en) 2013-12-27

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