ES2656898T3 - Telas no tejidas de fibras de estopa individualizadas - Google Patents
Telas no tejidas de fibras de estopa individualizadas Download PDFInfo
- Publication number
- ES2656898T3 ES2656898T3 ES13835305.7T ES13835305T ES2656898T3 ES 2656898 T3 ES2656898 T3 ES 2656898T3 ES 13835305 T ES13835305 T ES 13835305T ES 2656898 T3 ES2656898 T3 ES 2656898T3
- Authority
- ES
- Spain
- Prior art keywords
- weight
- percent
- emollient
- woven fabrics
- bast fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000000835 fiber Substances 0.000 title abstract description 5
- 239000004745 nonwoven fabric Substances 0.000 title abstract description 3
- 239000001814 pectin Substances 0.000 abstract description 3
- 235000010987 pectin Nutrition 0.000 abstract description 3
- 229920001277 pectin Polymers 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 description 21
- 239000003974 emollient agent Substances 0.000 description 20
- 239000003906 humectant Substances 0.000 description 14
- -1 petrolatum) Chemical class 0.000 description 10
- 229920001296 polysiloxane Polymers 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- 244000025254 Cannabis sativa Species 0.000 description 5
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 5
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 5
- 235000009120 camo Nutrition 0.000 description 5
- 235000005607 chanvre indien Nutrition 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000011487 hemp Substances 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 235000019388 lanolin Nutrition 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000003607 modifier Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 230000035807 sensation Effects 0.000 description 5
- 239000004166 Lanolin Substances 0.000 description 4
- 229940039717 lanolin Drugs 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 239000004264 Petrolatum Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229940066842 petrolatum Drugs 0.000 description 3
- 235000019271 petrolatum Nutrition 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000002860 competitive effect Effects 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000010705 motor oil Substances 0.000 description 2
- 150000003904 phospholipids Chemical class 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- GTABBGRXERZUAH-UHFFFAOYSA-N hexadecan-1-ol;2-methyloxirane;oxirane Chemical group C1CO1.CC1CO1.CCCCCCCCCCCCCCCCO GTABBGRXERZUAH-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 229940086539 peg-7 glyceryl cocoate Drugs 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 229940068977 polysorbate 20 Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
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- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
- A61F13/538—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium characterised by specific fibre orientation or weave
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- B01D39/083—Filter cloth, i.e. woven, knitted or interlaced material of organic material
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- B01D39/18—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being cellulose or derivatives thereof
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- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01G—PRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
Una tela no tejida que comprende una mayoría de fibras individualizadas que son sustancialmente rectas, basadas en plantas, lisas y alargadas, y sustancialmente exentas de pectina y tienen una longitud media superior a 6 milímetros (mm), y aproximadamente o inferior a 20-25 mm.
Description
emoliente plástico o fluido tal como uno o más hidrocarburos líquidos (por ejemplo, petrolato), aceite mineral y similares, grasas vegetales y animales (por ejemplo, lanolina, fosfolípidos y sus derivados) y/o materiales de silicona tales como uno o más polímeros de polisiloxano sustituidos con alquilo, que incluyen los emolientes de polisiloxano descritos en la patente de los Estados Unidos nº 5.891.126, que se incorpora aquí en su totalidad como referencia.
5 Opcionalmente, un tensioactivo hidrófilo se puede combinar con un emoliente plástico para mejorar la humectabilidad de la superficie recubierta. En algunas realizaciones de la presente invención, se contempla que los emolientes de hidrocarburos líquidos y/o los polímeros de polisiloxano sustituidos con alquilo pueden mezclarse o combinarse con uno o más emolientes de ésteres de ácidos grasos derivados de ácidos grasos o alcoholes grasos.
En una realización de la presente invención, el material emoliente está en forma de una mezcla emoliente. Por ejemplo, la mezcla emoliente puede comprender una combinación de uno o más hidrocarburos líquidos (por ejemplo, petrolato), aceite mineral y similares, grasas vegetales y animales (por ejemplo, lanolina, fosfolípidos y sus derivados), con un material de silicona tal como uno o más polímeros de polisiloxano sustituidos con alquilo. En otro aspecto, la mezcla emoliente comprende una combinación de hidrocarburos líquidos (por ejemplo, petrolato) con
15 dimeticona o con dimeticona y otros polímeros de polisiloxano sustituidos con alquilo. En algunas realizaciones de la presente invención, se contempla que las mezclas de emolientes de hidrocarburo líquidos y/o polímeros de polisiloxano sustituidos con alquilo puedan mezclarse con uno o más emolientes de éster de ácido graso derivados de ácidos grasos o alcoholes grasos. También se puede considerar el cocoato de glicerilo PEG-7, disponible como Standamul HE (Henkel Corp., Hoboken, NJ).
Los aceites emolientes autoemulsionantes solubles en agua, que son útiles en las presentes composiciones humectantes, incluyen las lanolinas polioxialcoxiladas y los alcoholes grasos polioxialcoxilados, como se describe en la patente de los Estados Unidos nº 4.690.821, que se incorpora aquí en su totalidad como referencia. Las cadenas polioxialcoxi comprenden unidades mixtas de propilenoxi y etilenoxi. Los derivados de lanolina comprenden
25 típicamente aproximadamente 20-70 unidades de alcoxi inferior, mientras que los alcoholes grasos C12-C20 se derivatizarán con aproximadamente 8-15 unidades de alquilo inferior. Uno de tales derivados de lanolina útiles es Lanexol AWS (PPG-12-PEG-50, Croda, Inc., Nueva York, NY). Un poli(15-20)alcoxilato C2-C3 útil es PPG-5-Ceteth20, conocido como Procetyl AWS (Croda, Inc.).
Típicamente, la composición humectante contiene menos de aproximadamente 25 por ciento en peso de emolientes basados en el peso total de la composición humectante. En otro aspecto, la composición humectante puede comprender menos de aproximadamente 5 por ciento en peso de emoliente, y, en otro aspecto más, menos de aproximadamente 2% de emoliente. Todavía, en otro aspecto, la composición humectante puede contener de aproximadamente 0,01 por ciento en peso a aproximadamente 8 por ciento en peso de emolientes. Aún así, en otro
35 aspecto, la composición humectante puede contener de aproximadamente 0,2 por ciento en peso a aproximadamente 2 por ciento en peso de emolientes.
En una realización, la composición humectante y/o las toallitas prehumedecidas de la presente invención comprenden una emulsión de aceite en agua que comprende una fase oleosa que contiene al menos un aceite emoliente y al menos un estabilizante de cera emoliente dispersado en una fase acuosa que comprende al menos un emoliente de alcohol polihídrico y al menos un detergente orgánico soluble en agua, como se describe en la patente de los Estados Unidos nº 4.559.157, la totalidad de la cual se incorpora aquí como referencia.
Se pueden emplear modificadores de sensación superficial con la tela no tejida de la presente invención para
45 mejorar la sensación táctil (por ejemplo, lubricidad) de la piel durante el uso del producto. Modificadores de sensación de superficie adecuados incluyen, pero sin limitarse a estos, despolimerizadores comerciales; y suavizantes, tales como los suavizantes usados en la técnica de fabricación de tejidos que incluyen compuestos de amonio cuaternario con grupos laterales de ácidos grasos, siliconas, ceras y similares. Ejemplos de compuestos de amonio cuaternario con utilidad como suavizantes se describen en la patente de los Estados Unidos nº 3.554.862; la patente de los Estados Unidos nº 4.144.122; la patente de los Estados Unidos nº 5.573.637; y la patente de los Estados Unidos nº 4.476.323, la totalidad de todos los cuales se incorpora aquí como referencia. Típicamente, la composición humectante contiene menos de aproximadamente 2 por ciento en peso de modificadores de sensación superficial basados en el peso total de la composición humectante. En otro aspecto, la composición humectante contiene de aproximadamente 0,01 por ciento en peso a aproximadamente 1 por ciento en peso de modificadores de
55 sensación superficial. Todavía, en otro aspecto, la composición humectante contiene de aproximadamente 0,01 por ciento en peso a aproximadamente 0,05 por ciento en peso de modificadores de sensación superficial.
Se puede usar una variedad de fragancias en la composición humectante de la presente invención. Típicamente, la composición humectante contiene menos de aproximadamente 2 por ciento en peso de fragancias en base al peso total de la composición humectante. En otro aspecto, la composición humectante contiene de aproximadamente 0,01 por ciento en peso a aproximadamente 1 por ciento en peso de fragancias. Sin embargo, en otro aspecto, la composición humectante contiene de aproximadamente 0,01 por ciento en peso a aproximadamente 0,05 por ciento en peso de fragancias.
65 Además, se puede usar una variedad de solubilizadores de fragancia en la composición humectante de la presente invención. Los solubilizadores de fragancia adecuados incluyen, pero no se limitan a, polisorbato 20, propilenglicol,
14
- Capacidad de absorción (g/g)
- 6,8 5,6 6,2 7,4 7,1 9,7 10,7
- Brillo (%)
- 84,52 72,12 87,72 77,65 74,01 75,87 71,73
Tabla 3. Propiedades físicas del sustrato de la invención para toallita de cáñamo y de lino en comparación con sustratos para toallita convencionales.
- Sustratos para toallita Heavy Duty Shop
- Sustratos para toalla de servicio de alimentos
- Explicación de la propiedad
- Propiedad Paño de la invención Paños competitivos Paño de la invención Paños competitivos
- Celda 4 patrón de espiga de cáñamo al 100%
- Celda 10 patrón de espiga de lino al 100% Algodón tejido/trapo de PET KC Wypall X-80 HEF / Pulp / PP Celda 8 lino al 100% aperturado Chix® 8250
- Peso base
- Peso base (gsm) 114 116 197 113 76 65,7
- Grosor
- Caliper (mils / 8ply) 213 286 346 183 227 164
- Resistencia
- Tracción en seco MD (g/1 pulgada) 5744 7221 8287 5740 4681 4214
- Resistencia
- Tracción en húmedo (g/1 pulgada) 6021 7421 8294 4434 4842 4181
- Resistencia
- Tracción en húmedo CD (g/1 pulgada) 2333 3347 8871 2971 2115 3769
- Resistencia
- Media cuadrática de la tracción en húmedo MD-CD (g/1 pulgada) 3748 4984 8578 3630 3200 3970
- Resistencia
- Media cuadrática de TEA MD-CD TEA (g/mm) 20 42,9 TBD 36 21,8 38,9
- Gramos de agua absorbidos por gramo de toallita
- Capacidad de absorción de agua (g/g) 7,0 5,8 2,8 6,2 7,8 9,2
- Gramos de aceite absorbido por gramo de barrido
- Capacidad de retención de aceite del motor (g/g) 5,6 5,9 5,7 4,9 7,4 8,3
- Gramos de aceite absorbido por m2 de toallita
- Capacidad de retención de aceite del motor (g/m2) 638,4 685 1123 554 561 545
- Resistencia a la abrasión / durabilidad cuando está mojado
- Abrasión Stoll en húmedo (# golpes) 50 59 TBD 84 35 37
16
- Pérdida de pelusa cuando se frota contra el paño
- Pelusa seca (mg/m^2) 64 49,3 TBD 44 78,9 19,7
- Pérdida de pelusa en agua
- Pelusa extraída en húmedo (%) 0,27 0,12 TBD 0,07 0,04 0,05
Tabla 4. Propiedades físicas y contenido de pectina relativo de tejidos de la invención
- Ensayo
- Lote 1 Patrón de espiga (fibra de estopa de cáñamo al 100%) Lote 2 Patrón de espiga (fibra de estopa de cáñamo al 100%) Lote 3 Patrón de espiga (fibra de estopa de cáñamo al 100%)
- Contenido de azúcar reducido a partir de la extracción de pectina (%)
- 0,1 0,3 0,6
- Peso base (gsm)
- 138,1 114,5 110,2
- Resistencia a la tracción en seco MD (g/pulgada)
- 9570 2490 1480
- Resistencia a la tracción en seco CD (g/pulgada)
- 1790 370 220
- Relación en seco MD/CD
- 5,3 6,7 6,7
- Resistencia a la tracción en húmedo MD (g/pulgada)
- 8720 1370 1440
- Resistencia a la tracción en húmedo CD (g/pulgada)
- 2210 230 200
- Relación en húmedo MD/CD
- 3,9 6,0 7,2
17
Claims (1)
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imagen1 imagen2
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US20170136715A1 (en) * | 2014-06-11 | 2017-05-18 | Invista North America S.A R.L. | Aqueous polyurethaneurea compositions including dispersions and films |
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KR20150054889A (ko) | 2015-05-20 |
CA2882586C (en) | 2021-02-09 |
CA2882586A1 (en) | 2014-03-13 |
CN104704155B (zh) | 2020-03-10 |
ZA201500825B (en) | 2016-02-24 |
EP2893068A4 (en) | 2016-04-20 |
EP2893068A1 (en) | 2015-07-15 |
IN2015DN02260A (es) | 2015-08-21 |
WO2014039361A1 (en) | 2014-03-13 |
IL237546B (en) | 2019-01-31 |
CN104704155A (zh) | 2015-06-10 |
US9926654B2 (en) | 2018-03-27 |
EP2893068B1 (en) | 2017-12-13 |
JP6418609B2 (ja) | 2018-11-07 |
JP2015530494A (ja) | 2015-10-15 |
AU2013313126B2 (en) | 2017-09-14 |
US20140066872A1 (en) | 2014-03-06 |
KR102083199B1 (ko) | 2020-03-02 |
IL237546A0 (en) | 2015-04-30 |
AU2013313126A1 (en) | 2015-02-19 |
BR112015003942A2 (pt) | 2017-07-04 |
MX355903B (es) | 2018-05-03 |
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