ES2431491B1 - Reactor de oxidación preferencial de monóxido de carbono - Google Patents

Reactor de oxidación preferencial de monóxido de carbono Download PDF

Info

Publication number
ES2431491B1
ES2431491B1 ES201331241A ES201331241A ES2431491B1 ES 2431491 B1 ES2431491 B1 ES 2431491B1 ES 201331241 A ES201331241 A ES 201331241A ES 201331241 A ES201331241 A ES 201331241A ES 2431491 B1 ES2431491 B1 ES 2431491B1
Authority
ES
Spain
Prior art keywords
preferential oxidation
carbon monoxide
preferential
naval
oxidation reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES201331241A
Other languages
English (en)
Other versions
ES2431491A1 (es
Inventor
Anton Scholten
Gerard WESTERNDORP
José Javier Brey Sánchez
Belén SARMIENTO MARRÓN
Victoria GALLARDO GARCÍA-ORTA
Mariana MARTÍN BETANCOURT
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Abengoa Hidrogeno SA
Original Assignee
Abengoa Hidrogeno SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Abengoa Hidrogeno SA filed Critical Abengoa Hidrogeno SA
Priority to ES201331241A priority Critical patent/ES2431491B1/es
Publication of ES2431491A1 publication Critical patent/ES2431491A1/es
Priority to KR1020167005866A priority patent/KR20160045078A/ko
Priority to EP14771940.5A priority patent/EP3031776B1/en
Priority to PT14771940T priority patent/PT3031776T/pt
Priority to PCT/ES2014/070637 priority patent/WO2015018961A1/es
Application granted granted Critical
Publication of ES2431491B1 publication Critical patent/ES2431491B1/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
    • B01J8/0407—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds
    • B01J8/0419—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds the beds being placed in separate reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/864—Removing carbon monoxide or hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
    • B01J8/0423—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds
    • B01J8/0442—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds the beds being placed in separate reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0496—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
    • C01B3/583—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction the reaction being the selective oxidation of carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00823—Mixing elements
    • B01J2208/00831—Stationary elements
    • B01J2208/00849—Stationary elements outside the bed, e.g. baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00938—Flow distribution elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435—Catalytic purification
    • C01B2203/044—Selective oxidation of carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/047—Composition of the impurity the impurity being carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217—Alcohols
    • C01B2203/1229—Ethanol

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Fluid Mechanics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Fuel Cell (AREA)

Abstract

Reactor de oxidación preferencial de monoxido de carbono.#La presente invención se puede incluir en el campo técnico de los reactores de oxidación preferencial de CO y más concretamente en los reactores de oxidación preferencial que forman parte de un sistema de procesado de etanol para la posterior alimentación de una pila de combustible utilizada en aplicaciones navales o marinas, que comprende al menos un primer intercambiador de calor para enfriar una corriente de gases con una concentración alta de H{sub,2} mediante una corriente de agua y al menos un módulo reactor de oxidación preferencial con lecho catalítico, comprendiendo además al menos dos sensores de nivel, un sensor de nivel superior y un sensor de nivel inferior que aseguran que el nivel de agua se mantiene en la posición necesaria para el correcto funcionamiento del equipo en las distintas condiciones de operación y en los distintos grados de inclinación requeridos por el tipo de aplicación naval o marina.

Description

imagen1
imagen2
imagen3
imagen4
imagen5
imagen6
imagen7
imagen8
imagen9
imagen10
imagen11
imagen12
imagen13
imagen14

Claims (1)

  1. imagen1
    imagen2
    imagen3
    imagen4
ES201331241A 2013-08-07 2013-08-07 Reactor de oxidación preferencial de monóxido de carbono Active ES2431491B1 (es)

Priority Applications (5)

Application Number Priority Date Filing Date Title
ES201331241A ES2431491B1 (es) 2013-08-07 2013-08-07 Reactor de oxidación preferencial de monóxido de carbono
KR1020167005866A KR20160045078A (ko) 2013-08-07 2014-08-04 일산화탄소의 선택적 산화 반응기
EP14771940.5A EP3031776B1 (en) 2013-08-07 2014-08-04 Carbon dioxide preferential oxidation reactor
PT14771940T PT3031776T (pt) 2013-08-07 2014-08-04 Reator de oxidação preferencial de dióxido de carbono
PCT/ES2014/070637 WO2015018961A1 (es) 2013-08-07 2014-08-04 Reactor de oxidación preferencial de monóxido de carbono

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES201331241A ES2431491B1 (es) 2013-08-07 2013-08-07 Reactor de oxidación preferencial de monóxido de carbono

Publications (2)

Publication Number Publication Date
ES2431491A1 ES2431491A1 (es) 2013-11-26
ES2431491B1 true ES2431491B1 (es) 2014-09-29

Family

ID=49551927

Family Applications (1)

Application Number Title Priority Date Filing Date
ES201331241A Active ES2431491B1 (es) 2013-08-07 2013-08-07 Reactor de oxidación preferencial de monóxido de carbono

Country Status (5)

Country Link
EP (1) EP3031776B1 (es)
KR (1) KR20160045078A (es)
ES (1) ES2431491B1 (es)
PT (1) PT3031776T (es)
WO (1) WO2015018961A1 (es)

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9826222D0 (en) * 1998-12-01 1999-01-20 Johnson Matthey Plc Improved reactor
US6284206B1 (en) * 1999-03-22 2001-09-04 International Fuel Cells, Llc Compact selective oxidizer assemblage for a fuel cell power plant
JP2000302407A (ja) * 1999-04-14 2000-10-31 Toyota Motor Corp 一酸化炭素選択酸化装置
CA2372547A1 (en) * 1999-05-03 2000-11-09 Nuvera Fuel Cells Autothermal reforming system with integrated shift beds, preferential oxidation reactor, auxiliary reactor, and system controls
CA2354343A1 (en) * 2000-07-31 2002-01-31 H. Power Corp. Integrated selective oxidation reactor apparatus and process
US20020090329A1 (en) * 2000-08-11 2002-07-11 Marten Ternan Apparatus for a fuel processing system
WO2003106946A2 (en) * 2002-06-13 2003-12-24 Nuvera Fuel Cells Inc. Preferential oxidation reactor temperature regulation
JP4886417B2 (ja) 2006-08-04 2012-02-29 株式会社東芝 一酸化炭素低減装置、一酸化炭素低減方法、水素製造装置および燃料電池発電システム
CN101462694B (zh) 2007-12-19 2011-04-20 中国科学院大连化学物理研究所 一种微型化的甲醇自热重整制氢集成装置和制氢方法
EP2455334A1 (en) * 2010-11-18 2012-05-23 Tecnicas Reunidas, S.A. Ethanol processing system

Also Published As

Publication number Publication date
ES2431491A1 (es) 2013-11-26
KR20160045078A (ko) 2016-04-26
WO2015018961A1 (es) 2015-02-12
PT3031776T (pt) 2019-05-06
EP3031776B1 (en) 2019-01-09
EP3031776A1 (en) 2016-06-15

Similar Documents

Publication Publication Date Title
ES2527899B2 (es) Aprovechamiento de la redundancia inherente en un IED multifunción
BR112015004035A2 (pt) sistema de computação, meio de armazenagem não transitório lido por máquina armazenando instruções e método
BR112014011279A2 (pt) suprimento de oxigênio para sistema de perfusão de orgãos
BR112014007942A2 (pt) método, dispositivo, sistema e programa para comparação de informações de posicionamento
UA105729C2 (uk) Аміновмісний абсорбент, спосіб і пристрій для абсорбції кислих газів із газових сумішей
CL2017003232A1 (es) Quemador de reducción que permite la ocurrencia separada de reacción de oxidación y reacción de reducción y sistema de reciclaje de gas de síntesis que utiliza el mismo.
ES2431491B1 (es) Reactor de oxidación preferencial de monóxido de carbono
BR112015018768A2 (pt) aparelho e método de detecção de voltagem, e, bateria
CO6940407A2 (es) Sistema interconectado y el método de purificación y recuperación de potasa
AR095796A1 (es) Proceso y equipo para rompimiento, reagrupación molecular, optimización y aumento de volumen de combustible mediante cavitación hidrodinámica y alta presión con la adición de agua y otros aditivos
ATE454310T1 (de) Motorrad
BR102012033267A2 (pt) Dispositivo sensor
BR112019001925A2 (pt) método para o desligamento de uma unidade de gerador, unidade de gerador, veículo dotado de tal unidade de gerador e uso de tal unidade de gerador
CY1117514T1 (el) Αποθειωση καυσαεριων με δυνατοτητα παραγωγης νερου
ES2635281A1 (es) Equipo para el transporte e instalación de aerogeneradores sobre el fondo marino
AR093808A1 (es) Linea de bombeo vertical para conexion de estabilizador en un reactor del tipo de agua presurizada
ES2438090B2 (es) Sistema de inyección de CO2 para estudios ecotoxicológicos
ES2540918B1 (es) Configuración de receptores solares de torre y torre con dicha configuración
ES2523756B1 (es) Sistema y método de inspección de varilla de combustible
ES2514090A1 (es) Sistema combinado de calefacción y enriquecimiento carbónico a partir de biomasa
BR112013029441A2 (pt) método e sistema para detectar parafinização de combustível diesel em um tanque de combustível em um veículo motorizado
CL2015003691A1 (es) Un sistema para la detección temprana de cortocircuitos y contactos eléctricos débiles
ES1174759U (es) Dispositivo de iluminación
ES2548916A2 (es) Contacto de alta velocidad capaz de detectar, indicar y evitar maniobras incorrectas debido a un fallo interno
CN102490494B (zh) 激光打标设备防反装置

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 2431491

Country of ref document: ES

Kind code of ref document: B1

Effective date: 20140929