ES2200624B1 - Sintesis en medio alcalino de la zeolita itq.-16. - Google Patents

Sintesis en medio alcalino de la zeolita itq.-16.

Info

Publication number
ES2200624B1
ES2200624B1 ES200100385A ES200100385A ES2200624B1 ES 2200624 B1 ES2200624 B1 ES 2200624B1 ES 200100385 A ES200100385 A ES 200100385A ES 200100385 A ES200100385 A ES 200100385A ES 2200624 B1 ES2200624 B1 ES 2200624B1
Authority
ES
Spain
Prior art keywords
itq
zeolite
synthesis
zeolita
different
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES200100385A
Other languages
English (en)
Other versions
ES2200624A1 (es
Inventor
Avelino Corma Canos
M. Teresa Navarro Villalba
Fernando Rey Garcia
Susana Valencia Valencia
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to ES200100385A priority Critical patent/ES2200624B1/es
Priority to PCT/ES2002/000057 priority patent/WO2002064503A1/es
Priority to CA002437132A priority patent/CA2437132A1/en
Priority to EP02710892A priority patent/EP1364913A1/en
Priority to JP2002564441A priority patent/JP2004523457A/ja
Priority to US10/632,535 priority patent/US7056489B2/en
Publication of ES2200624A1 publication Critical patent/ES2200624A1/es
Application granted granted Critical
Publication of ES2200624B1 publication Critical patent/ES2200624B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/023—Preparation of physical mixtures or intergrowth products of zeolites chosen from group C01B39/04 or two or more of groups C01B39/14 - C01B39/48
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/27—Beta, e.g. NU-2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

Síntesis en medio alcalino de la zeolita ITQ-16. La presente invención se refiere a un procedimiento de síntesis en medio OH- y en ausencia de fluoruros de una familia de materiales zeolíticos que se engloban dentro de la denominación ITQ-16, y a sus aplicaciones catalíticas. Esta familia de materiales, zeolita ITQ-16, se caracteriza por tener relaciones diferentes de los distintos polimorfos A, B y C descritos como posibles intercrecimientos en la zeolita Beta, y que por consiguiente presenta patrones de difracción de rayos X diferentes al descrito para la zeolita Beta. La zeolita ITQ-16 en su forma calcinada tiene la siguiente fórmula empírica: x (MX02) : tT02: gGeO2 : (1- g)Si02 donde T es uno o varios elementos con estado de oxidación +4 distintos de Ge y Si; X es uno o varios elementos con estado de oxidación +3 y M puede ser H+ o uno o varios cationes inorgánicos de carga +n.
ES200100385A 2001-02-09 2001-02-09 Sintesis en medio alcalino de la zeolita itq.-16. Expired - Fee Related ES2200624B1 (es)

Priority Applications (6)

Application Number Priority Date Filing Date Title
ES200100385A ES2200624B1 (es) 2001-02-09 2001-02-09 Sintesis en medio alcalino de la zeolita itq.-16.
PCT/ES2002/000057 WO2002064503A1 (es) 2001-02-09 2002-02-08 Sintesis en medio alcalino de la zeolita itq-16
CA002437132A CA2437132A1 (en) 2001-02-09 2002-02-08 Synthesis of zeolite itq-16 in an alkaline medium
EP02710892A EP1364913A1 (en) 2001-02-09 2002-02-08 Synthesis of zeolite itq-16 in an alkaline medium
JP2002564441A JP2004523457A (ja) 2001-02-09 2002-02-08 アルカリ性媒体中でのゼオライトｉｔｑ−１６の合成
US10/632,535 US7056489B2 (en) 2001-02-09 2003-08-01 Synthesis of zeolite ITQ-16 in an alkaline medium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES200100385A ES2200624B1 (es) 2001-02-09 2001-02-09 Sintesis en medio alcalino de la zeolita itq.-16.

Publications (2)

Publication Number Publication Date
ES2200624A1 ES2200624A1 (es) 2004-03-01
ES2200624B1 true ES2200624B1 (es) 2005-05-01

Family

ID=8496800

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200100385A Expired - Fee Related ES2200624B1 (es) 2001-02-09 2001-02-09 Sintesis en medio alcalino de la zeolita itq.-16.

Country Status (6)

Country Link
US (1) US7056489B2 (es)
EP (1) EP1364913A1 (es)
JP (1) JP2004523457A (es)
CA (1) CA2437132A1 (es)
ES (1) ES2200624B1 (es)
WO (1) WO2002064503A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2196963B1 (es) * 2001-07-03 2005-02-16 Universidad Politecnica De Valencia Sintesis de itq-17 en ausencia de iones fluoruro.
JP2004010537A (ja) * 2002-06-06 2004-01-15 Mitsubishi Chemicals Corp 水熱合成用テンプレート、ケイ素含有層状化合物の製造方法及びケイ素含有層状化合物
FR2860224B1 (fr) * 2003-09-26 2006-06-02 Inst Francais Du Petrole Solide cristallise im-12 et son procede de preparation
CA2631560C (en) * 2005-12-20 2014-08-12 Exxonmobil Research And Engineering Company Itq-26, new crystalline microporous material
CA2584876A1 (en) * 2007-02-02 2008-08-02 Albemarle Netherlands Bv A crystalline microporous material of zeolitic nature
WO2009134534A2 (en) * 2008-05-02 2009-11-05 Exxonmobil Chemical Patents Inc. Treatment of small pore molecular sieves and their use in the conversion of oxygenates to olefins
US8865121B2 (en) * 2009-06-18 2014-10-21 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material
ES2462872B1 (es) 2012-10-25 2015-03-10 Consejo Superior Investigacion Catalizador y proceso catalítico para la eterificación/reducción de furfuril derivados a tetrahidro-furfuril éteres
CN104692407B (zh) * 2015-02-28 2016-08-31 中国石油天然气股份有限公司 一种ith结构稀土硅铝分子筛及其合成方法
CN105905921A (zh) * 2016-06-29 2016-08-31 北京化工大学 一种itq-16分子筛的合成方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE28341E (en) 1964-05-01 1975-02-18 Marshall dann
EP0746529B1 (en) * 1994-02-18 2000-01-05 Chevron Chemical Company LLC Zeolite ssz-42
ES2128961B1 (es) * 1996-12-18 2000-03-01 Univ Valencia Politecnica Zeolita itq - 4.
BR9714196A (pt) * 1996-12-31 2000-03-28 Chevron Usa Inc Zeólito,e,processos para preparação de um material cristalino, para a conversão de hidricarbonetos, para a conversão de álcoois inferiores e outros hidrocarbonetos oxigenados,e para a redução de óxidos de nitrogênio contidos numa corrente gasosa na presença de oxigênio.
ES2152143B1 (es) * 1998-02-06 2001-08-16 Univ Valencia Politecnica Sintesis de zeolitas y zeotipos de poro grande.
US6787124B2 (en) * 2002-03-15 2004-09-07 Exxonmobil Research And Engineering Company Synthetic porous crystalline material, EMM-1, its synthesis and use
US6733742B1 (en) * 2002-12-26 2004-05-11 Chevron U.S.A. Inc. Molecular sieve SSZ-63 composition of matter and synthesis thereof

Also Published As

Publication number Publication date
US20040089587A1 (en) 2004-05-13
CA2437132A1 (en) 2002-08-22
ES2200624A1 (es) 2004-03-01
US7056489B2 (en) 2006-06-06
EP1364913A1 (en) 2003-11-26
WO2002064503A1 (es) 2002-08-22
JP2004523457A (ja) 2004-08-05

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