ES2171640T3 - Procedimiento para la polimerizacion de etileno en fase gaseosa. - Google Patents
Procedimiento para la polimerizacion de etileno en fase gaseosa.Info
- Publication number
- ES2171640T3 ES2171640T3 ES96430008T ES96430008T ES2171640T3 ES 2171640 T3 ES2171640 T3 ES 2171640T3 ES 96430008 T ES96430008 T ES 96430008T ES 96430008 T ES96430008 T ES 96430008T ES 2171640 T3 ES2171640 T3 ES 2171640T3
- Authority
- ES
- Spain
- Prior art keywords
- procedure
- polymerization
- gaseous phase
- ethylene
- prepolimerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
UN PROCEDIMIENTO PARA LA POLIMERIZACION DE OLEFINAS EN FASE GASEOSA QUE SE LLEVA A CABO EN PRESENCIA DE UN CATALIZADOR SOBRE UN SOPORTE DE GEOMETRIA RESTRINGIDA. EL PROCEDIMIENTO IMPLICA UNA ETAPA DE PREPOLIMERIZACION QUE PUEDE LLEVARSE A CABO IN SITU. EL CATALIZADOR PUEDE INCLUIR POR EJEMPLO UN COMPLEJO DE METALOCENO DE GEOMETRIA RESTRINGIDA SOPORTADO SOBRE SILICA Y UTILIZADO EN PRESENCIA DE UN ACTIVADOR. LA ETAPA DE PREPOLIMERIZACION PERMITE MEJORAR LA ACTIVIDAD DEL CATALIZADOR.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96430008A EP0816394B1 (en) | 1996-06-26 | 1996-06-26 | Process for polymerising ethylene in the gas phase |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2171640T3 true ES2171640T3 (es) | 2002-09-16 |
Family
ID=8225394
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES96430008T Expired - Lifetime ES2171640T3 (es) | 1996-06-26 | 1996-06-26 | Procedimiento para la polimerizacion de etileno en fase gaseosa. |
Country Status (8)
Country | Link |
---|---|
US (1) | US6437060B1 (es) |
AR (1) | AR007621A1 (es) |
AT (1) | ATE212647T1 (es) |
DE (1) | DE69618936T2 (es) |
ES (1) | ES2171640T3 (es) |
ID (1) | ID17305A (es) |
PT (1) | PT816394E (es) |
TW (1) | TW452580B (es) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1693388A1 (en) * | 2005-02-21 | 2006-08-23 | Innovene Europe Limited | Polymerisation catalysts |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3782243T2 (de) | 1986-08-26 | 1993-03-04 | Mitsui Petrochemical Ind | Katalysator zur polymerisierung von alpha-olefin und verfahren. |
FR2659336B1 (fr) | 1990-03-12 | 1993-05-07 | Bp Chemicals Snc | Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
MY107639A (en) | 1990-04-18 | 1996-05-30 | Mitsui Chemicals Incorporated | Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation |
JP3202349B2 (ja) | 1992-09-22 | 2001-08-27 | 三菱化学株式会社 | 触媒組成物およびそれを用いるオレフィンの重合法 |
CA2146344A1 (en) | 1992-10-05 | 1994-04-14 | Gregory George Hlatky | Catalyst system of enhanced productivity and its use in polymerization process |
FR2717816B1 (fr) | 1994-03-23 | 1996-04-26 | Atochem Elf Sa | Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique. |
EP0763546B1 (de) | 1995-09-13 | 1997-05-28 | Witco GmbH | Verfahren zur Herstellung von Metallocen-Katalysatorsystemen auf inerten Trägermaterialien unter Verwendung von Gasphasenreaktoren |
EP0816394B1 (en) | 1996-06-26 | 2002-01-30 | BP Chemicals S.N.C. | Process for polymerising ethylene in the gas phase |
-
1996
- 1996-06-26 PT PT96430008T patent/PT816394E/pt unknown
- 1996-06-26 DE DE69618936T patent/DE69618936T2/de not_active Expired - Fee Related
- 1996-06-26 ES ES96430008T patent/ES2171640T3/es not_active Expired - Lifetime
- 1996-06-26 AT AT96430008T patent/ATE212647T1/de not_active IP Right Cessation
-
1997
- 1997-06-26 ID IDP972212A patent/ID17305A/id unknown
- 1997-06-26 AR ARP970102816A patent/AR007621A1/es not_active Application Discontinuation
- 1997-06-26 TW TW086108954A patent/TW452580B/zh not_active IP Right Cessation
-
1999
- 1999-12-23 US US09/471,259 patent/US6437060B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
TW452580B (en) | 2001-09-01 |
AR007621A1 (es) | 1999-11-10 |
ID17305A (id) | 1997-12-17 |
ATE212647T1 (de) | 2002-02-15 |
US6437060B1 (en) | 2002-08-20 |
DE69618936D1 (de) | 2002-03-14 |
DE69618936T2 (de) | 2002-08-29 |
PT816394E (pt) | 2002-07-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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