ES2166272A1 - Metodo para la obtencion de polidiclorofosfazeno lineal de alto peso molecular. - Google Patents

Metodo para la obtencion de polidiclorofosfazeno lineal de alto peso molecular.

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Publication number
ES2166272A1
ES2166272A1 ES009901772A ES9901772A ES2166272A1 ES 2166272 A1 ES2166272 A1 ES 2166272A1 ES 009901772 A ES009901772 A ES 009901772A ES 9901772 A ES9901772 A ES 9901772A ES 2166272 A1 ES2166272 A1 ES 2166272A1
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ES
Spain
Prior art keywords
promoters
reaction
production
molecular weight
high molecular
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009901772A
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English (en)
Other versions
ES2166272B1 (es
Inventor
Ule Gabino A Carriedo
Alonso Francisco J Garcia
Elipe Paloma Gomez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universidad de Oviedo
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Universidad de Oviedo
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Application filed by Universidad de Oviedo filed Critical Universidad de Oviedo
Priority to ES009901772A priority Critical patent/ES2166272B1/es
Publication of ES2166272A1 publication Critical patent/ES2166272A1/es
Application granted granted Critical
Publication of ES2166272B1 publication Critical patent/ES2166272B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

Método para la obtención de polidiclorofosfazeno [NPC12]n lineal (I) con peso molecular del orden de 2 106 a partir directamente de NH4Cl y PC15 en presencia de CaS04.H20 y HS03(NH2) como promotores. El método produce el polímero con un rendimiento entre el 30 y el 40 % basado en el PC15, con un coste muy reducido respecto de los métodos anteriores. El [NPC12]n se ha caracterizado a través de sus derivados [NP(02C12E8)]n y [NP(OCH2CF3)2]n.
ES009901772A 1999-07-29 1999-07-29 Metodo para la obtencion de polidiclorofosfazeno lineal de alto peso molecular. Expired - Fee Related ES2166272B1 (es)

Priority Applications (1)

Application Number Priority Date Filing Date Title
ES009901772A ES2166272B1 (es) 1999-07-29 1999-07-29 Metodo para la obtencion de polidiclorofosfazeno lineal de alto peso molecular.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES009901772A ES2166272B1 (es) 1999-07-29 1999-07-29 Metodo para la obtencion de polidiclorofosfazeno lineal de alto peso molecular.

Publications (2)

Publication Number Publication Date
ES2166272A1 true ES2166272A1 (es) 2002-04-01
ES2166272B1 ES2166272B1 (es) 2003-10-16

Family

ID=8309507

Family Applications (1)

Application Number Title Priority Date Filing Date
ES009901772A Expired - Fee Related ES2166272B1 (es) 1999-07-29 1999-07-29 Metodo para la obtencion de polidiclorofosfazeno lineal de alto peso molecular.

Country Status (1)

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ES (1) ES2166272B1 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108217613B (zh) * 2018-02-11 2019-08-13 北京化工大学 一种催化合成制备线性聚二氯磷腈的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3869540A (en) * 1973-05-25 1975-03-04 Fmc Corp Montmorillonite clay catalysts for the production of phosphonitrilic chloride
EP0316810A2 (en) * 1987-11-16 1989-05-24 The Firestone Tire & Rubber Company Process for the production of linear polyphosphazenes

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3869540A (en) * 1973-05-25 1975-03-04 Fmc Corp Montmorillonite clay catalysts for the production of phosphonitrilic chloride
EP0316810A2 (en) * 1987-11-16 1989-05-24 The Firestone Tire & Rubber Company Process for the production of linear polyphosphazenes

Also Published As

Publication number Publication date
ES2166272B1 (es) 2003-10-16

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