ES2139951T3 - Procedimiento de preparacion de 2,6-difluorobenzonitrilo en ausencia de disolvente. - Google Patents
Procedimiento de preparacion de 2,6-difluorobenzonitrilo en ausencia de disolvente.Info
- Publication number
- ES2139951T3 ES2139951T3 ES95940030T ES95940030T ES2139951T3 ES 2139951 T3 ES2139951 T3 ES 2139951T3 ES 95940030 T ES95940030 T ES 95940030T ES 95940030 T ES95940030 T ES 95940030T ES 2139951 T3 ES2139951 T3 ES 2139951T3
- Authority
- ES
- Spain
- Prior art keywords
- difluorobenzonitrile
- absence
- solvent
- procedure
- tetrasustituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Saccharide Compounds (AREA)
- Catalysts (AREA)
Abstract
UN PROCEDIMIENTO DE OBTENCION DE 2,6 - DIFLUOROBENZONITRILO QUE CONSISTE EN HACER REACCIONAR 2,6 - DICLOROBENZONITRILO CON UN FLUORURO DE METAL BASICAMENTE ANHIDRO A UNA TEMPERATURA ENTRE APROX. 160 (GRADOS) C Y APROX. 300 (GRADOS) C Y EN PRESENCIA DE UN CATALIZADOR DE TRANSFERENCIA DE FASE, QUE ES TIPICAMENTE UN POLIETER, UNA SAL DE FOSFONIO TETRASUSTITUIDA, UNA SAL DE AMONIO TETRASUSTITUIDA Y UN CRIPTANDO, PERO EN AUSENCIA DE DISOLVENTE. TRAS RETIRAR EL PRODUCTO, LA MEZCLA RESULTANTE PUEDE SER RECICLADA EN EL REACTOR PARA EL SIGUIENTE CICLO DE REACCION. LA INVENCION COMPRENDE ASIMISMO, PARA EL CASO DE APARICION DE ALQUITRANES DURANTE EL PROCESO DE REACCION, LA SEPARACION DEL CATALIZADOR DE DICHOS ALQUITRANES Y EL RECICLAJE DEL MISMO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/365,726 US5502235A (en) | 1994-12-28 | 1994-12-28 | Solventless process for making 2,6 difluorobenzonitrile |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2139951T3 true ES2139951T3 (es) | 2000-02-16 |
Family
ID=23440092
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES95940030T Expired - Lifetime ES2139951T3 (es) | 1994-12-28 | 1995-11-17 | Procedimiento de preparacion de 2,6-difluorobenzonitrilo en ausencia de disolvente. |
Country Status (18)
Country | Link |
---|---|
US (1) | US5502235A (es) |
EP (1) | EP0800506B1 (es) |
JP (1) | JPH10511941A (es) |
CN (1) | CN1174546A (es) |
AR (1) | AR000556A1 (es) |
AT (1) | ATE187959T1 (es) |
AU (1) | AU702641B2 (es) |
BR (1) | BR9510428A (es) |
CA (1) | CA2209141A1 (es) |
DE (1) | DE69514122T2 (es) |
DK (1) | DK0800506T3 (es) |
ES (1) | ES2139951T3 (es) |
FI (1) | FI972742A (es) |
HU (1) | HU215936B (es) |
IL (1) | IL116634A (es) |
TW (1) | TW307748B (es) |
WO (1) | WO1996020168A1 (es) |
ZA (1) | ZA9510902B (es) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69614863T2 (de) * | 1995-06-20 | 2002-01-03 | Nippon Soda Co. Ltd., Tokio/Tokyo | 2,3-dihalogen-6-trifluormethylbenzol-derivate und verfahren zu ihrer herstellung |
DE19702282C2 (de) * | 1997-01-23 | 1998-11-19 | Hoechst Ag | Katalysator für Halex-Reaktionen |
US7393980B2 (en) * | 2001-05-17 | 2008-07-01 | Rhodia Chimie | Use of a composition of an ionic nature as a substrate reagent, a composition constituting a fluorination reagent and a method using same |
DE10227223A1 (de) * | 2002-06-18 | 2004-01-08 | Kühlein, Klaus, Prof.Dr. | Verfahren zur Herstellung substituierter organischer Verbindungen und Verwendung von Katalysatoren für Substitutionsreaktionen |
CN103044388B (zh) * | 2011-10-17 | 2015-04-15 | 张家港市国泰华荣化工新材料有限公司 | 一种3,4—二氟环丁砜的制备方法 |
CN104387289B (zh) * | 2014-10-30 | 2017-09-01 | 天津河清化学工业有限公司 | 二氟苯腈生产中降低催化剂用量的方法 |
CN112939782B (zh) * | 2019-12-11 | 2022-09-30 | 兰州康鹏威耳化工有限公司 | 一种含氟芳基化合物的制备方法 |
CN113024414A (zh) * | 2021-03-23 | 2021-06-25 | 江苏合泰新材料科技有限公司 | 一种高效合成含氟化合物的方法 |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB995927A (en) * | 1962-10-23 | 1965-06-23 | Imp Smelting Corp Ltd | Fluorination of perhalo compounds |
NL302228A (es) * | 1962-12-20 | |||
NL129620C (es) * | 1963-04-01 | |||
US4051168A (en) * | 1976-05-12 | 1977-09-27 | E. I. Du Pont De Nemours And Company | Fluorination process |
US4229365A (en) * | 1977-05-28 | 1980-10-21 | Basf Aktiengesellschaft | Manufacture of substituted fluorobenzenes |
DE2803259A1 (de) * | 1978-01-26 | 1979-08-02 | Basf Ag | Verfahren zur herstellung von fluorbenzolen |
DE2902877C2 (de) * | 1978-01-28 | 1983-05-05 | I.S.C. Chemicals Ltd., London | Verfahren zur Herstellung eines Fluorbenzomononitrils |
DE2938939A1 (de) * | 1978-10-05 | 1980-04-17 | Boots Co Ltd | Verfahren zur herstellung von fluornitrobenzolen |
US4174349A (en) * | 1978-10-30 | 1979-11-13 | Allied Chemical Corporation | Preparation of fluoroorganic compounds with calcium fluoride |
FR2490634A1 (fr) * | 1980-09-25 | 1982-03-26 | Rhone Poulenc Ind | Procede de preparation de fluorobenzonitriles |
JPS57197226A (en) * | 1981-05-30 | 1982-12-03 | Dainippon Ink & Chem Inc | Preparation of aromatic fluorine compound |
DE3260500D1 (en) * | 1981-08-31 | 1984-09-06 | Ishihara Sangyo Kaisha | Process for producing 2,6-difluorobenzonitrile |
DE3478681D1 (en) * | 1983-02-18 | 1989-07-20 | Nippon Catalytic Chem Ind | Organic fluorine compounds |
JPS604159A (ja) * | 1983-06-23 | 1985-01-10 | Ishihara Sangyo Kaisha Ltd | フルオロベンゾニトリル系化合物の製造方法 |
US4704483A (en) * | 1984-04-27 | 1987-11-03 | Occidental Chemical Corporation | 3,4-difluoro-5-nitrobenzotrifluoride and preparation of fluoro-nitro-benzotrifluorides |
US4952719A (en) * | 1984-10-15 | 1990-08-28 | Occidental Chemical Corporation | Process for the preparation of halo aromatic compounds |
GB8500180D0 (en) * | 1985-01-04 | 1985-02-13 | Ici Plc | Chemical process |
US4680406A (en) * | 1985-10-15 | 1987-07-14 | The Dow Chemical Company | Process for fluorinating halogenated organo-compounds |
JPS62114939A (ja) * | 1985-11-14 | 1987-05-26 | Sumitomo Chem Co Ltd | フルオロベンゼン誘導体の製造法 |
EP0253837B1 (en) * | 1986-01-06 | 1991-10-09 | Mallinckrodt Specialty Chemicals Company | Catalytic method for producing fluoroaromatic compounds using branched alkyl pyridinium salts |
US4849552A (en) * | 1986-01-06 | 1989-07-18 | Mallinckrodt, Inc. | Preparation of fluoroaromatic compounds in dispersion of potassium fluoride |
EP0253838B1 (en) * | 1986-01-06 | 1991-08-21 | Mallinckrodt Specialty Chemicals Company | Catalytic method for producing fluoroaromatic compounds using n-sec-alkyl pyridinium salts |
US4642398A (en) * | 1986-01-06 | 1987-02-10 | Mallinckrodt, Inc. | Preparation of fluoronitrobenzene compounds in dispersion of potassium fluoride |
DE3642326A1 (de) * | 1986-12-11 | 1988-06-23 | Bayer Ag | Verfahren zur gewinnung von substituierten fluorbenzolen |
US4973772A (en) * | 1987-02-07 | 1990-11-27 | Mallinckrodt, Inc. | Catalytic method for producing fluoroarmatic compounds using substituted pyridinium salts |
JP2577567B2 (ja) * | 1987-07-07 | 1997-02-05 | イハラケミカル工業株式会社 | 芳香族フッ素化合物の製造方法 |
DE3827436A1 (de) * | 1988-08-12 | 1990-02-15 | Bayer Ag | Verfahren zum einfuehren von fluoratomen an aromatische kerne durch nucleophilen austausch |
ES2079666T3 (es) * | 1990-06-25 | 1996-01-16 | Hoechst Ag | Procedimiento para la preparacion de clorofluoro-nitrobencenos y difluoro-nitrobencenos. |
DE59407426D1 (de) * | 1993-07-21 | 1999-01-21 | Clariant Gmbh | Verfahren zur Herstellung von Fluorbenzonitrilen |
-
1994
- 1994-12-28 US US08/365,726 patent/US5502235A/en not_active Expired - Fee Related
-
1995
- 1995-11-17 DK DK95940030T patent/DK0800506T3/da active
- 1995-11-17 ES ES95940030T patent/ES2139951T3/es not_active Expired - Lifetime
- 1995-11-17 BR BR9510428A patent/BR9510428A/pt not_active Application Discontinuation
- 1995-11-17 CA CA002209141A patent/CA2209141A1/en not_active Abandoned
- 1995-11-17 AU AU41645/96A patent/AU702641B2/en not_active Ceased
- 1995-11-17 DE DE69514122T patent/DE69514122T2/de not_active Expired - Fee Related
- 1995-11-17 HU HU9701844A patent/HU215936B/hu not_active IP Right Cessation
- 1995-11-17 WO PCT/US1995/014971 patent/WO1996020168A1/en active IP Right Grant
- 1995-11-17 CN CN95197478A patent/CN1174546A/zh active Pending
- 1995-11-17 EP EP95940030A patent/EP0800506B1/en not_active Expired - Lifetime
- 1995-11-17 AT AT95940030T patent/ATE187959T1/de not_active IP Right Cessation
- 1995-11-17 JP JP8520445A patent/JPH10511941A/ja not_active Ceased
- 1995-11-28 TW TW084112671A patent/TW307748B/zh active
- 1995-12-21 ZA ZA9510902A patent/ZA9510902B/xx unknown
- 1995-12-27 AR ARP950100773A patent/AR000556A1/es unknown
- 1995-12-31 IL IL11663495A patent/IL116634A/xx not_active IP Right Cessation
-
1997
- 1997-06-25 FI FI972742A patent/FI972742A/fi unknown
Also Published As
Publication number | Publication date |
---|---|
ATE187959T1 (de) | 2000-01-15 |
HU215936B (hu) | 1999-03-29 |
IL116634A (en) | 2003-04-10 |
AR000556A1 (es) | 1997-07-10 |
ZA9510902B (en) | 1997-06-23 |
WO1996020168A1 (en) | 1996-07-04 |
CN1174546A (zh) | 1998-02-25 |
IL116634A0 (en) | 1996-03-31 |
FI972742A (fi) | 1997-08-27 |
BR9510428A (pt) | 1998-07-07 |
TW307748B (es) | 1997-06-11 |
DK0800506T3 (da) | 2000-05-15 |
EP0800506B1 (en) | 1999-12-22 |
DE69514122T2 (de) | 2000-04-20 |
EP0800506A1 (en) | 1997-10-15 |
AU4164596A (en) | 1996-07-19 |
CA2209141A1 (en) | 1996-07-04 |
FI972742A0 (fi) | 1997-06-25 |
DE69514122D1 (de) | 2000-01-27 |
AU702641B2 (en) | 1999-02-25 |
US5502235A (en) | 1996-03-26 |
HUT77239A (hu) | 1998-03-02 |
JPH10511941A (ja) | 1998-11-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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