ES2138678T3 - Procedimiento para la extraccion del agua de una masa fundida de plasticos que contiene agua en una extrusora de dos helices. - Google Patents
Procedimiento para la extraccion del agua de una masa fundida de plasticos que contiene agua en una extrusora de dos helices.Info
- Publication number
- ES2138678T3 ES2138678T3 ES95107103T ES95107103T ES2138678T3 ES 2138678 T3 ES2138678 T3 ES 2138678T3 ES 95107103 T ES95107103 T ES 95107103T ES 95107103 T ES95107103 T ES 95107103T ES 2138678 T3 ES2138678 T3 ES 2138678T3
- Authority
- ES
- Spain
- Prior art keywords
- water
- cake
- colada
- extraction
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract 7
- 238000000605 extraction Methods 0.000 title 1
- 238000002844 melting Methods 0.000 title 1
- 230000008018 melting Effects 0.000 title 1
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 229920001169 thermoplastic Polymers 0.000 abstract 2
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 abstract 1
- 230000005484 gravity Effects 0.000 abstract 1
- 239000004816 latex Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
- C08F6/22—Coagulation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
- B29B7/48—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7461—Combinations of dissimilar mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/84—Venting or degassing ; Removing liquids, e.g. by evaporating components
- B29B7/842—Removing liquids in liquid form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/84—Venting or degassing ; Removing liquids, e.g. by evaporating components
- B29B7/845—Venting, degassing or removing evaporated components in devices with rotary stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/375—Plasticisers, homogenisers or feeders comprising two or more stages
- B29C48/385—Plasticisers, homogenisers or feeders comprising two or more stages using two or more serially arranged screws in separate barrels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
- B29C48/41—Intermeshing counter-rotating screws
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/76—Venting, drying means; Degassing means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7476—Systems, i.e. flow charts or diagrams; Plants
- B29B7/7495—Systems, i.e. flow charts or diagrams; Plants for mixing rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2021/00—Use of unspecified rubbers as moulding material
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
UNA MEZCLA LIQUIDA DE DOS FASES COMPUESTA DE UNA COLADA DE PLASTICO TERMOPLASTICA Y UNA FASE DE AGUA, EN PARTICULAR UN COAGULADO LATEX, SE ELIMINA DE AGUA EN UN EXTRUSIONADOR (1) DE DOBLE TORNILLO SINFIN GIRANDO EN CONTRASENTIDO BAJO UNA PRESION, QUE ES MAYOR QUE LA PRESION DE VAPOR DEL AGUA CORRESPONDIENTE A LA TEMPERATURA DE LA COLADA DEL MATERIAL (7) SINTETICO TERMOPLASTICO DE UNA MANERA, QUE LA COLADA EN LA ZONA DE ELIMINACION DE AGUA SE TRANSPORTA EN LA VIA DE LOS TORNILLOS SINFIN PARCIALMENTE RELLENOS. EN AL MENOS UNA DE ESTAS VIAS DE TORNILLO SINFIN, EN EL ESPACIO DE ADMISION DEL TORNILLO (1) SINFIN DOBLE SE MANTIENE EN SITUACION DE REMANSO BAJO FORMACION DE UN GRADIENTE DE PRESION EMPINADO, LIMITADO DE FORMA ESTRECHA LOCALMENTE CON RESPECTO A UNA TORTA (7) DE COLADA SUSPENDIDA DE FORMA CONJUNTA Y DE MODO QUE EL AGUA ANTES DEL LIMITE DE LA TORTA DE COLADA SE DEJA EVACUAR BAJO EL EFECTO DE LA FUERZA DE GRAVEDAD EN FORMA LIQUIDA HACIA ABAJO A TRAVES AL MENOS DE UNA ABERTURA (8) DE EVACUACION, DE TAL MODO QUE LA TORTA (7) DE COLADA NO SE ENCUENTRA EN CONTACTO CON UNA FASE DE AGUA DE SUSPENSION CONJUNTA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4417559A DE4417559A1 (de) | 1994-05-19 | 1994-05-19 | Verfahren zum Entwässern einer wasserhaltigen Kunststoffschmelze in einem Doppelschneckenextruder |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2138678T3 true ES2138678T3 (es) | 2000-01-16 |
Family
ID=6518496
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES95107103T Expired - Lifetime ES2138678T3 (es) | 1994-05-19 | 1995-05-11 | Procedimiento para la extraccion del agua de una masa fundida de plasticos que contiene agua en una extrusora de dos helices. |
Country Status (8)
Country | Link |
---|---|
US (1) | US5650107A (es) |
EP (1) | EP0683028B1 (es) |
JP (1) | JP3863581B2 (es) |
KR (1) | KR100352350B1 (es) |
AT (1) | ATE184833T1 (es) |
DE (2) | DE4417559A1 (es) |
DK (1) | DK0683028T3 (es) |
ES (1) | ES2138678T3 (es) |
Families Citing this family (65)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19544563A1 (de) | 1995-11-30 | 1997-06-05 | Roehm Gmbh | Farb- und witterungsstabile Schlagzäh-Formmassen auf Basis Polymethylmethacrylat und Verfahren zu ihrer Herstellung |
ATE202125T1 (de) * | 1996-09-26 | 2001-06-15 | Basf Ag | Verfahren zur herstellung von thermoplasten |
DE19718597C1 (de) * | 1997-05-02 | 1999-01-07 | Roehm Gmbh | Zweistufiges Verfahren zur Entwässerung von Kunststoffdispersionen |
EP1094926B1 (en) | 1998-07-06 | 2002-04-10 | ExxonMobil Chemical Patents Inc. | Apparatus and method for dewatering an elastomeric polymer |
US6280667B1 (en) | 1999-04-19 | 2001-08-28 | Andersen Corporation | Process for making thermoplastic-biofiber composite materials and articles including a poly(vinylchloride) component |
US6273599B1 (en) * | 1999-09-17 | 2001-08-14 | Flint Ink Corporation | Process for preparing pigment flush |
DE10012421A1 (de) * | 2000-03-15 | 2001-09-20 | Roehm Gmbh | Kunststoffverbunde und Verfahren zu ihrer Herstellung |
DE10042120A1 (de) * | 2000-08-28 | 2002-03-14 | Roehm Gmbh | Verfahren zur Reduzierung des Polymergehalts bei der Entwässerung von Kunststoff/Wasser-Gemischen |
DE10129702A1 (de) | 2001-06-22 | 2003-01-02 | Roehm Gmbh | Extrusionswerkzeug zur Herstellung von Hohlkammerprofilplatten aus thermoplastischem Kunststoff mit innen liegender coextrudierter Schicht |
DE10243062A1 (de) | 2002-09-16 | 2004-03-25 | Röhm GmbH & Co. KG | Heißwasserwechseltestbeständiges Sanitärmaterial aus PMMA-Formmasse oder schlagzäher PMMA-Formmasse |
EP1400337B1 (de) * | 2002-09-20 | 2007-08-22 | Basf Aktiengesellschaft | Vorrichtung und Verfahren zum Extrudieren von Thermoplasten und Verwendung davon. |
DE10320318A1 (de) | 2003-05-06 | 2004-12-02 | Röhm GmbH & Co. KG | Verfahren zur Herstellung von lichtstreuenden Formteilen mit hervorragenden optischen Eigenschaften |
DE10336129A1 (de) | 2003-08-04 | 2005-02-24 | Röhm GmbH & Co. KG | Kratzunempfindlicher Rückprojektionsschirm und Verfahren zu dessen Herstellung |
DE10349142A1 (de) | 2003-10-17 | 2005-05-12 | Roehm Gmbh | Polymermischung sowie deren Verwendung für Spritzgußteile |
CA2566457C (en) | 2004-05-13 | 2010-03-23 | Caldera Engineering, Llc | Controlled dispersion multi-phase nozzle and method of making the same |
KR101082638B1 (ko) | 2006-10-19 | 2011-11-10 | 주식회사 엘지화학 | 열가소성수지 슬러리의 탈수방법 |
DE102007005432A1 (de) | 2007-01-30 | 2008-07-31 | Evonik Röhm Gmbh | Formmassen für mattierte Polyacrylat-Formkörper |
DE102007006825A1 (de) | 2007-02-07 | 2008-08-14 | Evonik Röhm Gmbh | Kunststoffformkörper mir anisotroper Lichtstreuung |
DE102007029263A1 (de) | 2007-06-22 | 2008-12-24 | Evonik Röhm Gmbh | PMMA/PVDF-Folie mit besonders hoher Witterungsbeständigkeit und hoher UV-Schutzwirkung |
DE102008009735A1 (de) * | 2008-02-19 | 2009-08-20 | Basf Se | Vorrichtung zum Extrudieren von Formmassen |
DE102008001431A1 (de) | 2008-04-28 | 2009-10-29 | Evonik Röhm Gmbh | Schneller lichthärtbarer Polymerisationsklebstoff auf MMA Basis mit verbesserten Materialeigenschaften |
DE102008001596A1 (de) | 2008-05-06 | 2009-11-12 | Evonik Röhm Gmbh | Kunststoffmischungen umfassend ein thermoplastisches Polyurethan (TPU) und ein schlagzähes Poly(meth)acrylat |
DE102008041338A1 (de) | 2008-08-19 | 2010-02-25 | Evonik Röhm Gmbh | Einfärbeprozess für Poly(meth)acrylate mit Flüssigfarben auf Wasserbasis und Flüssigfarben auf Wasserbasis |
DE102009000813A1 (de) | 2009-02-12 | 2010-08-19 | Evonik Degussa Gmbh | Fluoreszenzkonversionssolarzelle I Herstellung im Plattengußverfahren |
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DE102009027431A1 (de) | 2009-07-02 | 2011-01-05 | Evonik Degussa Gmbh | Fluoreszenzkonversionssolarzelle - Herstellung im Extrusionsverfahren oder im Coextrusionsverfahren |
DE102009045122A1 (de) | 2009-09-29 | 2011-03-31 | Evonik Röhm Gmbh | Verfahren und Anlage zur Einfärbung von Kunststoffformmassen |
EP2311886A1 (de) | 2009-10-16 | 2011-04-20 | Nanoresins AG | Verfahren zur Herstellung von Hybrid-Partikeln |
EP2311909A1 (de) | 2009-10-16 | 2011-04-20 | Nanoresins AG | Hybrid-Partikel von Polymeren und Nanopartikeln |
DE102009046197A1 (de) | 2009-10-30 | 2011-05-05 | Evonik Röhm Gmbh | Homopolymere und Copolymere der Hydroxyisobuttersäure(ester)(meth)acrylate |
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DE102010038685A1 (de) | 2010-07-30 | 2012-02-02 | Evonik Röhm Gmbh | Fluoreszenzkonversionssolarzelle Herstellung im Plattengußverfahren |
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WO2023208919A1 (en) | 2022-04-28 | 2023-11-02 | Röhm Gmbh | Poly(meth)acrylat impact modifier with reduced metal ion content and method for its production |
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Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1186770A (en) * | 1967-11-14 | 1970-04-02 | French Oil Mill Machinery | Process and System for Treating Rubber |
US4110843A (en) * | 1973-02-23 | 1978-08-29 | Welding Engineers, Inc. | Pressure restricting means for a liquid outlet of an extruder |
US4446094A (en) * | 1982-09-23 | 1984-05-01 | Welding Engineers, Inc. | Apparatus and method for extracting fluid from an extruded material |
FR2601380B1 (fr) * | 1986-07-08 | 1989-08-18 | Clextral | Procede et dispositif pour la fabrication en continu de combustibles mixtes a base de matieres organiques et de matieres hydrocarbonees |
US5232649A (en) * | 1990-10-31 | 1993-08-03 | Werner & Pfleiderer | Method of removing liquids from solids |
JPH04311703A (ja) * | 1991-04-10 | 1992-11-04 | Asahi Chem Ind Co Ltd | 脱水押出機 |
-
1994
- 1994-05-19 DE DE4417559A patent/DE4417559A1/de not_active Withdrawn
-
1995
- 1995-05-11 DE DE59506869T patent/DE59506869D1/de not_active Expired - Lifetime
- 1995-05-11 DK DK95107103T patent/DK0683028T3/da active
- 1995-05-11 EP EP95107103A patent/EP0683028B1/de not_active Expired - Lifetime
- 1995-05-11 AT AT95107103T patent/ATE184833T1/de not_active IP Right Cessation
- 1995-05-11 JP JP11343995A patent/JP3863581B2/ja not_active Expired - Lifetime
- 1995-05-11 ES ES95107103T patent/ES2138678T3/es not_active Expired - Lifetime
- 1995-05-12 US US08/439,847 patent/US5650107A/en not_active Expired - Lifetime
- 1995-05-18 KR KR1019950012356A patent/KR100352350B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0683028A1 (de) | 1995-11-22 |
DE4417559A1 (de) | 1995-11-23 |
JPH0839558A (ja) | 1996-02-13 |
US5650107A (en) | 1997-07-22 |
KR100352350B1 (ko) | 2002-10-31 |
EP0683028B1 (de) | 1999-09-22 |
ATE184833T1 (de) | 1999-10-15 |
JP3863581B2 (ja) | 2006-12-27 |
KR950031427A (ko) | 1995-12-18 |
DE59506869D1 (de) | 1999-10-28 |
DK0683028T3 (da) | 2000-01-24 |
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