ES2133828T3 - Dispersion de copolimeros con contenido elevado en solidos a partir de un latex y su utilizacion en los materiales de estanqueidad. - Google Patents
Dispersion de copolimeros con contenido elevado en solidos a partir de un latex y su utilizacion en los materiales de estanqueidad.Info
- Publication number
- ES2133828T3 ES2133828T3 ES95938150T ES95938150T ES2133828T3 ES 2133828 T3 ES2133828 T3 ES 2133828T3 ES 95938150 T ES95938150 T ES 95938150T ES 95938150 T ES95938150 T ES 95938150T ES 2133828 T3 ES2133828 T3 ES 2133828T3
- Authority
- ES
- Spain
- Prior art keywords
- dispersion
- solids
- latex
- water
- high solids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Polymerisation Methods In General (AREA)
- Sealing Material Composition (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Paper (AREA)
- Medicinal Preparation (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
UN METODO PARA POLIMERIZAR PREDOMINANTEMENTE UNO O MAS MONOMEROS DE ACRILATO Y/O VINILACETATO EN PRESENCIA DE UN LATEX DA COMO RESULTADO DISPERSIONES ALTAS DE SOLIDOS DE PARTICULAS DE POLIMERO CON VISCOSIDADES INFERIORES A LAS TRADICIONALMENTE OBSERVADAS. UN PORCENTAJE DE PESO IMPORTANTE DE MONOMEROS AÑADIDOS PUEDE ESTAR PRESENTE EN GRANDES PARTICULAS, TENIENDO FORMAS NO ESFERICAS. PARTE DE LAS PARTICULAS DE LATEX ORIGINALES SON RETENIDAS DURANTE LA POLIMERIZACION Y ESTAS AUMENTAN EL CONTENIDO DE SOLIDOS Y REDUCEN LA VISCOSIDAD MEDIANTE EL EMPAQUETAMIENTO DE LOS INTERSTICIOS ENTRE PARTICULAS GRANDES. EL CONTENIDO TOTAL SOLIDO DEL POLIMERO PUEDE SER FACILMENTE VARIADO DEL 70% AL 92% O MAS DE PESO LO CUAL ES SUPERIOR A LO LOGRADO EN CUALQUIERA DE LAS POLIMERIZACIONES ACUOSAS PREVIAMENTE INFORMADAS. LAS VISCOSIDADES EN CONTENIDO SOLIDOS MUY ALTOS LLEGAN A SER TIPO PASTA AUNQUE LOS MATERIALES SON TODAVIA ESTABLES AL ALMACENAMIENTO Y LA MANIPULACION POSTERIOR SIN ROTURA DE LA DISPERSION EN UNA PORCION DE POLIMERO AGLOMERADO Y AGUA LIBERADA. LAS DISPERSIONES SON UTILES PARA FORMAR SELLANTES, MEMBRANAS, ETC., CON O SIN OTROS ADITIVOS. UN USO PREFERIDO ES COMO UN COMPUESTO DE CALAFATEO BASADO EN AGUA DE ACRILATO DONDE LOS SOLIDOS ALTOS Y TIXOTROPIA DE LA DISPERSION PERMITE LA FORMACION DE UN CALAFATE BASADO EN AGUA CON ENCOGIMIENTO BAJO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/321,288 US5541253A (en) | 1994-10-11 | 1994-10-11 | High solids copolymer dispersion from a latex and its use in sealants |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2133828T3 true ES2133828T3 (es) | 1999-09-16 |
Family
ID=23249977
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES95938150T Expired - Lifetime ES2133828T3 (es) | 1994-10-11 | 1995-10-04 | Dispersion de copolimeros con contenido elevado en solidos a partir de un latex y su utilizacion en los materiales de estanqueidad. |
Country Status (30)
Country | Link |
---|---|
US (2) | US5541253A (es) |
EP (1) | EP0785970B1 (es) |
JP (1) | JPH10507221A (es) |
KR (1) | KR970707234A (es) |
CN (1) | CN1085701C (es) |
AT (1) | ATE179444T1 (es) |
AU (1) | AU703054B2 (es) |
BR (1) | BR9509330A (es) |
CA (1) | CA2202378C (es) |
CZ (1) | CZ112497A3 (es) |
DE (1) | DE69509404T2 (es) |
DK (1) | DK0785970T3 (es) |
EE (1) | EE03572B1 (es) |
ES (1) | ES2133828T3 (es) |
GR (1) | GR3030075T3 (es) |
HU (1) | HU219677B (es) |
IL (1) | IL115535A (es) |
LT (1) | LT4278B (es) |
LV (1) | LV11903B (es) |
MA (1) | MA23688A1 (es) |
MX (1) | MX9702678A (es) |
MY (1) | MY112737A (es) |
NO (1) | NO311365B1 (es) |
NZ (1) | NZ295529A (es) |
PL (1) | PL181430B1 (es) |
RO (1) | RO116479B1 (es) |
RU (1) | RU2177013C2 (es) |
SK (1) | SK282482B6 (es) |
TW (1) | TW406092B (es) |
WO (1) | WO1996011234A1 (es) |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5541253A (en) * | 1994-10-11 | 1996-07-30 | The B. F. Goodrich Company | High solids copolymer dispersion from a latex and its use in sealants |
US6040380A (en) * | 1994-10-11 | 2000-03-21 | Tremco Incorporated | High solids copolymer dispersion from a latex and its use in caulks, sealants and adhesives |
AU735778B2 (en) * | 1996-02-26 | 2001-07-12 | Rohm And Haas Company | Latex compositions having improved drying speed |
DE19624280A1 (de) * | 1996-06-18 | 1998-01-02 | Basf Ag | Verfahren zur Herstellung niedrigviskoser, wässriger Polymerisatdispersionen mit Polymervolumenkonzentrationen von wenigstens 50 Vol.-% |
DE19704553A1 (de) * | 1997-02-06 | 1998-08-13 | Wacker Chemie Gmbh | Fugendichtungsmassen mit verbessertem Rückstellvermögen |
US20020197443A1 (en) * | 1997-03-17 | 2002-12-26 | Schrock Alan K. | Process for preparing carpets having polyurethane backings obtained from polyurethane latex formulations |
DE19742678A1 (de) | 1997-09-26 | 1999-04-01 | Wacker Chemie Gmbh | Verfahren zur Herstellung von wäßrigen, Schutzkolloidstabilisierten Vinylester-Homo- und -Co-Polymerdispersionen |
US6001907A (en) * | 1997-12-15 | 1999-12-14 | Witco Corporation | Latex sealants containing epoxysilanes |
US6214450B1 (en) * | 1998-02-25 | 2001-04-10 | Tremco Incorporated | High solids water-borne surface coating containing hollow particulates |
US6147149A (en) * | 1999-03-03 | 2000-11-14 | Glouster Co., Inc. | Adhesive caulking material which can mimic the appearance of a multicolored stone surface |
US6576336B1 (en) | 1998-09-11 | 2003-06-10 | Unitech Corporation, Llc | Electrically conductive and electromagnetic radiation absorptive coating compositions and the like |
US7282260B2 (en) * | 1998-09-11 | 2007-10-16 | Unitech, Llc | Electrically conductive and electromagnetic radiation absorptive coating compositions and the like |
DE19912191C2 (de) | 1999-03-18 | 2001-07-26 | Wacker Chemie Gmbh | Verfahren zur Herstellung von wäßrigen Polymerdispersionen mit hohem Festgehalt |
ATE289334T1 (de) * | 1999-12-30 | 2005-03-15 | Henkel Kgaa | Polymerdispersion mit vernetzerharz, deren herstellung und verwendung |
DE20023340U1 (de) * | 2000-01-12 | 2003-11-06 | Silu Verwaltung Ag | Einkomponentige Dichtmasse auf Basis einer Dispersion von Vinylpolymeren |
WO2001060893A1 (en) * | 2000-02-16 | 2001-08-23 | Sanyo Chemical Industries, Ltd. | Resin dispersions having uniform particle diameters, resin particles and processes for producing both |
AU2001263242A1 (en) * | 2000-05-19 | 2001-12-03 | Ppg Industries Ohio, Inc. | Coating compositions having a geometrically ordered array of polymeric particlesand substrates coated therewith |
DE10035589A1 (de) | 2000-07-21 | 2002-02-07 | Wacker Polymer Systems Gmbh | Verfahren zur Herstellun von Polymerdispersionen mi t hohem Feststoffgehalt |
US6737473B2 (en) * | 2001-07-13 | 2004-05-18 | Dow Corning Corporation | High solids emulsions of elastomeric polymers |
US6720373B2 (en) * | 2001-07-13 | 2004-04-13 | Dow Corning Corporation | High solids emulsions of curable elastomeric polymers |
US6713558B2 (en) * | 2001-07-13 | 2004-03-30 | Dow Corning Corporation | High solids emulsions of silylated elastomeric polymers |
DE60228035D1 (de) | 2001-10-01 | 2008-09-18 | Rohm & Haas | Beschichtungszusammensetzung auf Basis eines bimodalen Emulsionscopolymeren, Verfahren zur Fleckenbeseitigung, Deckkraftverbesserung, Blockneigungsreduzierung und Verbesserung der Scherstabilität |
CN100427543C (zh) * | 2003-01-21 | 2008-10-22 | 株式会社可乐丽 | 丙烯酸类聚合物粉末、丙烯酸溶胶以及成形物 |
US20050129911A1 (en) * | 2003-12-12 | 2005-06-16 | Schlegel Corporation | Surface treated particulated polymeric matrix for forming an exposed surface of a weatherseal |
US20060025534A1 (en) * | 2004-07-30 | 2006-02-02 | Johnson Jeffery W | High solids coating composition based on thermal initiated free-radical polymerization |
US7435777B2 (en) * | 2005-12-30 | 2008-10-14 | Columbia Insurance Company | Low-VOC compositions containing a polymeric latex, coatings made therefrom, substrates containing same, and methods for making same |
PT1990376E (pt) * | 2007-05-11 | 2011-07-27 | Omya Development Ag | Processo de moagem em meio aquoso de matérias minerais e de ligantes aplicando uma emulsão inversa de um polímero de acrilamida com um monómero acrílico |
DE102007055692A1 (de) * | 2007-12-03 | 2009-06-04 | Wacker Chemie Ag | Radikalisch vernetzbare Polymerisat-Zusammensetzungen enthaltend Epoxy-funktionelle Copolymere |
US9015093B1 (en) | 2010-10-26 | 2015-04-21 | Michael Lamport Commons | Intelligent control with hierarchical stacked neural networks |
ES2559405T3 (es) * | 2011-04-11 | 2016-02-12 | Nuplex Resins B.V. | Procedimiento para preparar dispersiones acuosas de polímero de vinilo |
ES2800278T3 (es) | 2015-09-23 | 2020-12-29 | Basf Se | Masas de dos componentes para recubrimiento |
WO2018156933A1 (en) | 2017-02-24 | 2018-08-30 | Hewlett-Packard Development Company, L.P. | Three-dimensional printing |
BR112019010426A2 (pt) | 2017-02-24 | 2019-09-03 | Hewlett Packard Development Co | impressão tridimensional (3d) |
JP7156284B2 (ja) * | 2017-07-19 | 2022-10-19 | 日本ゼオン株式会社 | フォームラバーの製造方法 |
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GB1182253A (en) * | 1966-03-25 | 1970-02-25 | Doverstrand Ltd | Improvements in or relating to Aqueous Compositions for Pigment Coating Permeable Substrates. |
NL130671C (es) * | 1966-04-02 | 1900-01-01 | ||
DE1645526C3 (de) * | 1966-09-26 | 1979-03-15 | Toray Industries, Inc., Tokio | Suspensionspolymerisationsverfahren |
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US4125700A (en) * | 1977-03-22 | 1978-11-14 | E. I. Du Pont De Nemours And Company | Preparation of methyl methacrylate polymer powders for use in plastisols |
US4130523A (en) * | 1977-07-18 | 1978-12-19 | Union Carbide Corporation | High solids latexes |
US4269959A (en) * | 1979-10-22 | 1981-05-26 | Whittaker Corporation | Method of preparing improved imbibitive polymer |
DE3036969A1 (de) * | 1980-10-01 | 1982-05-13 | Hoechst Ag, 6000 Frankfurt | Schutzkolloidfreie kunststoffdispersionen mit bimodaler partikelgroessenverteilung |
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US4810763A (en) * | 1987-12-23 | 1989-03-07 | Avery International Corporation | Suspension polymerization in an organic medium |
US5133992A (en) * | 1988-03-21 | 1992-07-28 | Eastman Kodak Company | Colloidally stabilized suspension process |
DE3917456A1 (de) * | 1989-05-30 | 1990-12-06 | Basf Ag | Stark dilatante copolymerdispersion mit hoher dauerlastbestaendigkeit |
US5051464A (en) * | 1989-09-01 | 1991-09-24 | E. I. Du Pont De Nemours And Company | Waterborne acrylourethane pigment dispersant polymer |
EP0439941B1 (en) * | 1990-01-22 | 1997-01-29 | Minnesota Mining And Manufacturing Company | Aqueous, repositionable, high peel strength pressure sensitive adhesives |
EP0515719B1 (de) * | 1991-05-31 | 1995-03-15 | Sellotape AG | Selbstklebende Acrylat-Copolymere, Verfahren zu deren Herstellung, und selbstklebende Flächengebilde, die diese enthalten |
DE4213967A1 (de) * | 1992-04-29 | 1993-11-04 | Basf Ag | Waessrige polymerisatdispersion |
US5541253A (en) * | 1994-10-11 | 1996-07-30 | The B. F. Goodrich Company | High solids copolymer dispersion from a latex and its use in sealants |
-
1994
- 1994-10-11 US US08/321,288 patent/US5541253A/en not_active Expired - Fee Related
-
1995
- 1995-10-03 MY MYPI95002944A patent/MY112737A/en unknown
- 1995-10-04 AU AU38891/95A patent/AU703054B2/en not_active Ceased
- 1995-10-04 RO RO97-00704A patent/RO116479B1/ro unknown
- 1995-10-04 ES ES95938150T patent/ES2133828T3/es not_active Expired - Lifetime
- 1995-10-04 DK DK95938150T patent/DK0785970T3/da active
- 1995-10-04 CA CA002202378A patent/CA2202378C/en not_active Expired - Fee Related
- 1995-10-04 HU HU9800786A patent/HU219677B/hu not_active IP Right Cessation
- 1995-10-04 NZ NZ295529A patent/NZ295529A/en unknown
- 1995-10-04 AT AT95938150T patent/ATE179444T1/de not_active IP Right Cessation
- 1995-10-04 EP EP95938150A patent/EP0785970B1/en not_active Expired - Lifetime
- 1995-10-04 CN CN95196193A patent/CN1085701C/zh not_active Expired - Fee Related
- 1995-10-04 BR BR9509330A patent/BR9509330A/pt not_active IP Right Cessation
- 1995-10-04 SK SK465-97A patent/SK282482B6/sk unknown
- 1995-10-04 JP JP8512647A patent/JPH10507221A/ja active Pending
- 1995-10-04 RU RU97108270/04A patent/RU2177013C2/ru active
- 1995-10-04 PL PL95319632A patent/PL181430B1/pl unknown
- 1995-10-04 EE EE9700108A patent/EE03572B1/xx not_active IP Right Cessation
- 1995-10-04 MX MX9702678A patent/MX9702678A/es not_active IP Right Cessation
- 1995-10-04 CZ CZ971124A patent/CZ112497A3/cs unknown
- 1995-10-04 WO PCT/US1995/012762 patent/WO1996011234A1/en active IP Right Grant
- 1995-10-04 DE DE69509404T patent/DE69509404T2/de not_active Expired - Fee Related
- 1995-10-06 IL IL11553595A patent/IL115535A/xx not_active IP Right Cessation
- 1995-10-09 MA MA24033A patent/MA23688A1/fr unknown
- 1995-12-23 TW TW084113827A patent/TW406092B/zh not_active IP Right Cessation
-
1996
- 1996-07-26 US US08/690,288 patent/US5744544A/en not_active Expired - Fee Related
-
1997
- 1997-04-11 KR KR1019970702473A patent/KR970707234A/ko active IP Right Grant
- 1997-04-11 NO NO19971666A patent/NO311365B1/no not_active IP Right Cessation
- 1997-05-08 LT LT97-084A patent/LT4278B/lt not_active IP Right Cessation
- 1997-05-08 LV LVP-97-88A patent/LV11903B/en unknown
-
1999
- 1999-04-29 GR GR990400837T patent/GR3030075T3/el unknown
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