ES2128486T3 - Complejos metalocenicos racemicos y procedimiento para su obtencion. - Google Patents
Complejos metalocenicos racemicos y procedimiento para su obtencion.Info
- Publication number
- ES2128486T3 ES2128486T3 ES94116511T ES94116511T ES2128486T3 ES 2128486 T3 ES2128486 T3 ES 2128486T3 ES 94116511 T ES94116511 T ES 94116511T ES 94116511 T ES94116511 T ES 94116511T ES 2128486 T3 ES2128486 T3 ES 2128486T3
- Authority
- ES
- Spain
- Prior art keywords
- arilalquil
- substitutes
- general formula
- cyclopentadienil
- aril
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052720 vanadium Inorganic materials 0.000 abstract 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 229910052732 germanium Inorganic materials 0.000 abstract 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 239000013067 intermediate product Substances 0.000 abstract 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical group [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical group [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/0805—Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms
- C07F7/0807—Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms comprising Si as a ring atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
LA INVENCION SE REFIERE A UN COMPLEJO METALOCENO DE LA FORMULA GENERAL I EN DONDE LOS SUSTITUYENTES TIENEN EL SIGUIENTE SIGNIFICADO: M ES TITANIO, ZIRCONIO, HAFNIO, VANADIO, NIOBIO O TANTALIO, X SIGNIFICA FLUOR, CLORO, BROMO, YODO, HIDROGENO, C1 HASTA C10 ALQUIL, C6 IFICA C1 L, ARILALQUIL, FLUORALQUIL O FLUORARIL CON 1 HASTA 10 ATOMOS DE CARBONO EN RESTO ALQUIL Y 6 HASTA 20 ATOMOS DE C EN RESTO ARIL. R1 HASTA R6 SIGNIFICAN HIDROGENO, C1 HASTA C10 CLOALQUIL DE 5 HASTA 7 MIEMBROS, QUE PUEDE PORTAR COMO SUSTITUYENTES POR SU PARTE C1 ARIL O ARILALQUIL, DONDE EVENTUALMENTE TAMBIEN DOS RESTOS VECINOS PUEDEN ESTAR CONJUNTAMENTE CON GRUPOS CICLICOS QUE MUESTRAN 4 HASTA 15 ATOMOS DE C, O SI(R8)3 CON R8 SIGNIFICA C1 C10 QUIL, Z ES SILICIO, GERMANIO, ESTAÑO O CARBONO, Y1, Y2 DONDE R9 HASTA R16 SIGNIFICAN HIDROGENO, C1 LQUIL DE 5 HASTA 7 MIEMBROS, QUE POR SU PARTE PUEDE PORTAR COMO SUSTITUYENTES C1 ARILALQUIL, DONDE EVENTUALMENTE DOS RESTOS VECINOS PUEDEN ESTAR CONJUNTAMENTE CON GRUPOS CICLICOS QUE MUESTRAN 4 HASTA 15 ATOMOS DE C, O SI(R17)3, CON R17 SIGNIFICA C1 L, C6 V, W SON UNA CIFRA COMPLETA DESDE 1 HASTA 7, CON LA CONDICION DE QUE U + V + W ES MAYOR IGUAL A 2, ASI COMO COMPUESTOS CICLOPENTADIENIL DE LA FORMULA GENERAL II Y COMPUESTOS CICLOPENTADIENIL DE LA FORMULA GENERAL III COMO PRODUCTOS INTERMEDIOS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4337232A DE4337232A1 (de) | 1993-10-30 | 1993-10-30 | Racemische Metallocenkomplexe und Verfahren zu ihrer Herstellung |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2128486T3 true ES2128486T3 (es) | 1999-05-16 |
Family
ID=6501518
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94116511T Expired - Lifetime ES2128486T3 (es) | 1993-10-30 | 1994-10-20 | Complejos metalocenicos racemicos y procedimiento para su obtencion. |
Country Status (4)
Country | Link |
---|---|
US (2) | US5554776A (es) |
EP (1) | EP0650973B1 (es) |
DE (2) | DE4337232A1 (es) |
ES (1) | ES2128486T3 (es) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4337232A1 (de) * | 1993-10-30 | 1995-05-04 | Basf Ag | Racemische Metallocenkomplexe und Verfahren zu ihrer Herstellung |
FI945959A (fi) * | 1993-12-21 | 1995-06-22 | Hoechst Ag | Metalloseenejä ja niiden käyttö katalyytteinä |
FI945958A (fi) * | 1993-12-21 | 1995-06-22 | Hoechst Ag | Menetelmä polyolefiinien valmistamiseksi |
DE19517851A1 (de) * | 1995-05-16 | 1996-11-21 | Hoechst Ag | Organometallverbindung |
DE19527047A1 (de) * | 1995-07-25 | 1997-01-30 | Danubia Petrochem Deutschland | Metallocene mit silylsubstituierten Brücken und deren Einsatz für die Olefinpolymerisation |
DE19527652A1 (de) * | 1995-07-28 | 1997-01-30 | Hoechst Ag | Metallocenverbindung |
FI104825B (fi) | 1996-01-26 | 2000-04-14 | Borealis As | Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö |
EP0846696B1 (en) | 1996-12-09 | 2003-06-18 | Mitsubishi Chemical Corporation | Catalyst for polymerization of alpha-olefins |
US5900497A (en) * | 1996-12-20 | 1999-05-04 | Union Carbide Chemicals & Plsatics Technology Corporation | Process for preparing metallocene procatalysts |
US5866706A (en) * | 1997-06-09 | 1999-02-02 | Boulder Scientific Co. | Preparation and separation of RAC and MESO compound mixtures |
US5965759A (en) * | 1998-09-23 | 1999-10-12 | Albemarle Corporation | Catalytic process for isomerizing metallocenes |
US6340651B1 (en) * | 1999-04-26 | 2002-01-22 | Phillips Petroleum Company | Multicyclic metallocycle metallocenes and their use |
CA2554119A1 (en) * | 2004-01-22 | 2005-08-04 | University Of Ottawa | Thermally modulated antioxidants |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IL89525A0 (en) * | 1988-03-21 | 1989-09-10 | Exxon Chemical Patents Inc | Silicon-bridged transition metal compounds |
EP0544308B1 (en) * | 1991-11-28 | 1998-02-18 | Showa Denko Kabushikikaisha | Novel metallocene and process for producing polyolefin using the same |
DE4337232A1 (de) * | 1993-10-30 | 1995-05-04 | Basf Ag | Racemische Metallocenkomplexe und Verfahren zu ihrer Herstellung |
-
1993
- 1993-10-30 DE DE4337232A patent/DE4337232A1/de not_active Withdrawn
-
1994
- 1994-10-20 EP EP94116511A patent/EP0650973B1/de not_active Expired - Lifetime
- 1994-10-20 ES ES94116511T patent/ES2128486T3/es not_active Expired - Lifetime
- 1994-10-20 DE DE59407909T patent/DE59407909D1/de not_active Expired - Fee Related
- 1994-10-28 US US08/328,777 patent/US5554776A/en not_active Expired - Fee Related
-
1996
- 1996-03-22 US US08/620,318 patent/US5670683A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE59407909D1 (de) | 1999-04-15 |
EP0650973A1 (de) | 1995-05-03 |
US5554776A (en) | 1996-09-10 |
DE4337232A1 (de) | 1995-05-04 |
US5670683A (en) | 1997-09-23 |
EP0650973B1 (de) | 1999-03-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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