ES2107207T3 - PROCEDURE FOR THE PREPARATION OF A COMPOSITION OF BLOCK COPOLYMERS. - Google Patents
PROCEDURE FOR THE PREPARATION OF A COMPOSITION OF BLOCK COPOLYMERS.Info
- Publication number
- ES2107207T3 ES2107207T3 ES94913079T ES94913079T ES2107207T3 ES 2107207 T3 ES2107207 T3 ES 2107207T3 ES 94913079 T ES94913079 T ES 94913079T ES 94913079 T ES94913079 T ES 94913079T ES 2107207 T3 ES2107207 T3 ES 2107207T3
- Authority
- ES
- Spain
- Prior art keywords
- monomer
- blocks
- polymer
- block
- derived
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
Abstract
SE PRESENTA UN PROCESO PARA LA PREPARACION DE COMPOSICIONES DE POLIMEROS EN BLOQUE, CUYO PROCESO CONSISTE EN LOS PASOS SIGUIENTES: (1) SE POLIMERIZA UN MONOMERO AROMATICO DE VINILO EN UN SOLVENTE HIDROCARBURO INERTE EN PRESENCIA DE UN INICIADOR DE ORGANOLITIO HASTA QUE TENGA LUGAR UNA CONVERSION SUSTANCIALMENTE COMPLETA; (2) SE AÑADE UN MONOMERO DE DIENO CONJUGADO A LA MEZCLA DE POLIMERIZACION Y SE DEJA QUE DICHO MONOMERO DE DIENO CONJUGADO SE POLIMERICE HASTA QUE TENGA LUGAR UNA CONVERSION SUSTANCIALMENTE COMPLETA; (3) SE AÑADE UNA SEGUNDA PORCION DE UN INICIADOR DE ORGANOLITIO, SEGUIDO DE LA ADICION DE UNA SEGUNDA PORCION DE MONOMERO DE DIENO CONJUGADO Y SE DEJA QUE DICHO MONOMERO DE DIENO CONJUGADO SE POLIMERICE HASTA QUE SE PRODUZCA UNA CONVERSION SUSTANCIALMENTE COMPLETA; (4) SE AÑADE UNA SEGUNDA PORCION DE MONOMERO AROMATICO DE VINILO Y SE DEJA QUE DICHO MONOMERO AROMATICO DE VINILO SE POLIMERICE HASTA QUE SE PRODUZCA UNA CONVERSION SUSTANCIALMENTE COMPLETA; (5) SE AÑADE UN AGENTE FINALIZADOR. ADEMAS, SE PRESENTA UNA COMPOSICION DE POLIMERO EN BLOQUE QUE CONTIENE: (I) UN COPOLIMERO EN TRES BLOQUES A-B--B''-A'' QUE TIENE DOS BLOQUES FINALES POLIMERICOS IGUALES O DIFERENTES A Y A'' DERIVADOS DE UN MONOMERO AROMATICO DE VINILO Y UN BLOQUE INTERMEDIO POLIMERICO B-B'' DERIVADO DEL MONOMERO DE DIENO CONJUGADO Y (II) UN POLIMERO EN DOS BLOQUES B''-A'' QUE TIENE UN BLOQUE POLIMERICO B'' DERIVADO DEL MONOMERO DE DIENO CONJUGADO Y UN BLOQUE POLIMERICO A'' DERIVADO DEL MONOMERO AROMATICO DE VINILO, EN DONDE LA RELACION EN PESO MOLAR A'' (TRES BLOQUES)/A'' (DOS BLOQUES) ES DE 0,9 A 1,1, EN DONDE LOS DOS POLIMEROS EN BLOQUE SE OBTIENEN MEDIANTE UNA POLIMERIZACION SECUENCIAL Y EN DONDE EL POLIMERO EN TRES BLOQUES ASI COMO EL POLIMERO EN DOS BLOQUES TIENEN UN CONTENIDO AROMATICO DE VINILO DEL 55% EN PESO O INFERIOR EN BASE AL PESO TOTAL DEL POLIMERO EN TRES BLOQUES Y DEL COPOLIMERO EN DOS BLOQUES, RESPECTIVAMENTE.A PROCESS FOR THE PREPARATION OF BLOCK POLYMER COMPOSITIONS IS PRESENTED, WHOSE PROCESS CONSISTS OF THE FOLLOWING STEPS: (1) A VINYL AROMATIC MONOMER IS POLYMERIZED INTO A SOLVENT HYDROCARBON INERT IN THE PRESENCE OF AN ORGANOL INITIATOR, ORGANOL. SUBSTANTIALLY COMPLETE; (2) A CONJUGATED DIENO MONOMER IS ADDED TO THE MIXTURE OF POLYMERIZATION AND SUCH CONJUGATED DIENO MONOMER IS ALLOWED TO POLYMERIZE UNTIL A SUBSTANTIALLY COMPLETE CONVERSION HAPPENS; (3) A SECOND PORTION OF AN ORGANOLITHIUM INITIATOR IS ADDED, FOLLOWED BY THE ADDITION OF A SECOND PORTION OF CONJUGATED DIENO MONOMER AND SUCH MONOMER OF CONJUGATED DIENO IS ALLOWED TO POLYMERIZE UNTIL A SUBSTANTIALLY CONVERSION IS PRODUCED; (4) A SECOND PORTION OF AROMATIC VINYL MONOMER IS ADDED AND SUCH AROMATIC VINYL MONOMER IS ALLOWED TO POLYMERIZE UNTIL A SUBSTANTIALLY COMPLETE CONVERSION IS PRODUCED; (5) A FINISHING AGENT IS ADDED. FURTHER, A BLOCK POLYMER COMPOSITION IS PRESENTED THAT CONTAINS: (I) A COPOLYMER IN THREE BLOCKS AB - B '' - A '' THAT HAS TWO FINAL BLOCKS EQUAL OR DIFFERENT A AND A '' DERIVED FROM AN AROMATIC MONOMER VINYL AND A B-B '' INTERMEDIATE POLYMERIC BLOCK DERIVED FROM THE CONJUGATED DIENO MONOMER AND (II) A POLYMER IN TWO BLOCKS B '' - A '' THAT HAS A POLYMERIC BLOCK B '' DERIVED FROM THE CONJUGATED DIENO MONOMER AND A BLOCK POLYMERIC A '' DERIVED FROM THE AROMATIC VINYL MONOMER, WHERE THE RATIO IN MOLAR WEIGHT A '' (THREE BLOCKS) / A '' (TWO BLOCKS) IS 0.9 TO 1.1, WHERE THE TWO BLOCK POLYMERS THEY ARE OBTAINED THROUGH A SEQUENTIAL POLYMERIZATION AND WHERE THE POLYMER IN THREE BLOCKS AS WELL AS THE POLYMER IN TWO BLOCKS HAVE AROMATIC VINYL CONTENT OF 55% BY WEIGHT OR LOWER ON THE BASIS OF THE TOTAL WEIGHT OF THE POLYMER IN THREE BLOCKS AND THREE BLOCKS OF THREE BLOCKS AND RESPECTIVELY.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP93200909 | 1993-03-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2107207T3 true ES2107207T3 (en) | 1997-11-16 |
Family
ID=8213730
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94913079T Expired - Lifetime ES2107207T3 (en) | 1993-03-30 | 1994-03-28 | PROCEDURE FOR THE PREPARATION OF A COMPOSITION OF BLOCK COPOLYMERS. |
Country Status (11)
Country | Link |
---|---|
US (1) | US5405903A (en) |
EP (1) | EP0691991B1 (en) |
JP (1) | JP3258664B2 (en) |
KR (1) | KR100312401B1 (en) |
CN (1) | CN1068344C (en) |
BR (1) | BR9405911A (en) |
DE (1) | DE69405983T2 (en) |
ES (1) | ES2107207T3 (en) |
RU (1) | RU2111220C1 (en) |
TW (1) | TW302374B (en) |
WO (1) | WO1994022931A1 (en) |
Families Citing this family (77)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW283152B (en) * | 1993-11-18 | 1996-08-11 | Shell Internat Res Schappej Bv | |
MX9505304A (en) * | 1994-12-23 | 1997-01-31 | Shell Int Research | Process for manufacturing multiarmed asymmetrical radial block copolymers. |
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Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4096203A (en) * | 1976-07-30 | 1978-06-20 | Shell Oil Company | Process to control cohesive strength of block copolymer composition |
DE2940861A1 (en) * | 1979-10-09 | 1981-04-23 | Basf Ag, 6700 Ludwigshafen | METHOD FOR PRODUCING MIXTURES OF LINEAR THREE-BLOCK COPOLYMERS AND MOLDED PARTS THEREOF |
US4391949A (en) * | 1981-11-12 | 1983-07-05 | Shell Oil Company | Asymmetric block copolymers and corresponding adhesive formulations |
JPS61254650A (en) * | 1985-05-07 | 1986-11-12 | Asahi Chem Ind Co Ltd | Block copolymer composition and production thereof |
ES2036568T3 (en) * | 1986-03-21 | 1993-06-01 | Shell Internationale Research Maatschappij B.V. | HERMETIC CLOSURE COMPOSITIONS OF HOT FUSION. |
US4704434A (en) * | 1986-03-24 | 1987-11-03 | Phillips Petroleum Company | Craze-resistant polymodal linear block copolymers with terminal tapered blocks |
JPH0755999B2 (en) * | 1986-09-05 | 1995-06-14 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | Block copolymer composition |
US5284915A (en) * | 1988-12-23 | 1994-02-08 | Enichem Elastomeri S.P.A. | Styrene-isoprene block copolymers |
CA2028410C (en) * | 1990-01-02 | 1996-09-17 | William J. Trepka | Tapered block styrene/butadiene copolymers |
US5256736A (en) * | 1991-05-08 | 1993-10-26 | Phillips Petroleum Company | Tapered block copolymers of conjugated dienes and monovinylarenes |
-
1994
- 1994-03-09 US US08/208,414 patent/US5405903A/en not_active Expired - Lifetime
- 1994-03-18 TW TW083102382A patent/TW302374B/zh active
- 1994-03-28 DE DE69405983T patent/DE69405983T2/en not_active Expired - Lifetime
- 1994-03-28 ES ES94913079T patent/ES2107207T3/en not_active Expired - Lifetime
- 1994-03-28 KR KR1019950704217A patent/KR100312401B1/en not_active IP Right Cessation
- 1994-03-28 WO PCT/EP1994/000988 patent/WO1994022931A1/en active IP Right Grant
- 1994-03-28 CN CN94191637A patent/CN1068344C/en not_active Expired - Lifetime
- 1994-03-28 RU RU95121813A patent/RU2111220C1/en not_active IP Right Cessation
- 1994-03-28 BR BR9405911A patent/BR9405911A/en not_active IP Right Cessation
- 1994-03-28 JP JP52166794A patent/JP3258664B2/en not_active Expired - Lifetime
- 1994-03-28 EP EP94913079A patent/EP0691991B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
KR100312401B1 (en) | 2001-12-28 |
BR9405911A (en) | 1995-12-26 |
CN1120342A (en) | 1996-04-10 |
DE69405983T2 (en) | 1998-02-12 |
EP0691991B1 (en) | 1997-10-01 |
JP3258664B2 (en) | 2002-02-18 |
DE69405983D1 (en) | 1997-11-06 |
RU2111220C1 (en) | 1998-05-20 |
US5405903A (en) | 1995-04-11 |
EP0691991A1 (en) | 1996-01-17 |
WO1994022931A1 (en) | 1994-10-13 |
CN1068344C (en) | 2001-07-11 |
TW302374B (en) | 1997-04-11 |
KR960701911A (en) | 1996-03-28 |
JPH08508309A (en) | 1996-09-03 |
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