ES2104348T3 - Peliculas de alta resistencia de latices de copolimeros de bloques. - Google Patents

Peliculas de alta resistencia de latices de copolimeros de bloques.

Info

Publication number
ES2104348T3
ES2104348T3 ES94906545T ES94906545T ES2104348T3 ES 2104348 T3 ES2104348 T3 ES 2104348T3 ES 94906545 T ES94906545 T ES 94906545T ES 94906545 T ES94906545 T ES 94906545T ES 2104348 T3 ES2104348 T3 ES 2104348T3
Authority
ES
Spain
Prior art keywords
block
aromatic
conjugated
monomin
daltons
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94906545T
Other languages
English (en)
Inventor
David R Speth
Ronald R Pelletier
Brian W Walther
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2104348T3 publication Critical patent/ES2104348T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/003Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D7/00Producing flat articles, e.g. films or sheets
    • B29D7/01Films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C71/00After-treatment of articles without altering their shape; Apparatus therefor
    • B29C71/02Thermal after-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2009/00Use of rubber derived from conjugated dienes, as moulding material
    • B29K2009/06SB polymers, i.e. butadiene-styrene polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2096/00Use of specified macromolecular materials not provided for in a single one of main groups B29K2001/00 - B29K2095/00, as moulding material
    • B29K2096/04Block polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0058Liquid or visquous
    • B29K2105/0064Latex, emulsion or dispersion
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2353/00Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2353/02Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

SE PRESENTAN PELICULAS PREPARADAS A PARTIR DE DISPERSIONES ACUOSAS DE COPOLIMEROS EN BLOQUES, DILUYENTES Y SURFACTANTES OPCIONALES CORRESPONDIENTES A LA FORMULA: A-B-X{SUB,M}-(BA){SUB,N} EN LA QUE CADA A ES UN POLIMERO EN BLOQUE DE UN MONOMERO AROMATICO DE MONOVINILIDENO Y, OPCIONALMENTE, UN DIENO CONJUGADO, CADA B ES UN POLIMERO EN BLOQUE DE UN DIENO CONJUGADO, X ES EL REMANENTE DE UN AGENTE DE COPULACION MULTIFUNCIONAL, M ES 0 O 1, Y N ES UN ENTERO DE 1 A 5, CADA BLOQUE DE MONOMERO AROMATICO DE MONOVINILIDENO TIENE UN PESO MOLECULAR MEDIO EN PESO DE 8.000 A 15.000 DALTONS, CADA BLOQUE DE DIENO CONJUGADO TIENE UN PESO MOLECULAR MEDIO EN PESO DE 50.000 A 200.000 DALTONS, EL CONTENIDO TOTAL DE A ES DE UN 5 A UN 25 POR CIENTO EN PESO DEL COPOLIMERO EN BLOQUE Y DILUYENTE, Y EL VOLUMEN DE FASE EFECTIVO DEL BLOQUE DE MONOMERO AROMATICO DE MONOVINILIDENO ES DE UN 10 A UN 18,5 POR CIENTO, QUE TIENEN UNAS PROPIEDADES DE RESISTENCIA A LA TENSION MEJORADAS Y SE PUEDEN UTILIZAR A MODO DE ARTICULOS ELASTOMERICOS DELGADOS Y UN PROCESO PARA SU PREPARACION.
ES94906545T 1993-01-08 1994-01-06 Peliculas de alta resistencia de latices de copolimeros de bloques. Expired - Lifetime ES2104348T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US243393A 1993-01-08 1993-01-08

Publications (1)

Publication Number Publication Date
ES2104348T3 true ES2104348T3 (es) 1997-10-01

Family

ID=21700741

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94906545T Expired - Lifetime ES2104348T3 (es) 1993-01-08 1994-01-06 Peliculas de alta resistencia de latices de copolimeros de bloques.

Country Status (9)

Country Link
EP (1) EP0678108B1 (es)
JP (2) JPH08505426A (es)
KR (1) KR100284520B1 (es)
CA (1) CA2150482A1 (es)
DE (1) DE69404125T2 (es)
ES (1) ES2104348T3 (es)
MX (1) MX9400336A (es)
TW (1) TW242632B (es)
WO (1) WO1994015997A1 (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5905097A (en) * 1993-01-08 1999-05-18 The Dow Chemical Company High-strength breathable films of block copolymer lattices
US5500469A (en) * 1994-09-22 1996-03-19 The Dow Chemical Company Preparation of a novel article from a thermally gellable artificial latex
US5567760A (en) * 1994-11-15 1996-10-22 The Dow Chemical Company Films from aqueous dispersions of block copolymers having hydrogenated conjugated diene block
WO1996039462A2 (en) * 1995-06-06 1996-12-12 The Dow Chemical Company High-strength films of block copolymer latices
US6000668A (en) 1996-07-30 1999-12-14 Adf Incorporated Video wall framing system
US5900452A (en) 1996-08-12 1999-05-04 Tactyl Technologies, Inc. S-EB-S block copolymer/oil aqueous dispersion and its use in forming articles
US6639007B2 (en) 1996-11-15 2003-10-28 Tactyl Technologies, Inc. Elastomeric copolymer compositions and articles made therewith
US6066708A (en) * 1997-08-29 2000-05-23 Phillips Petroleum Company Copolymer production, product thereof and diluent removal therefrom
US6426390B1 (en) 1999-06-11 2002-07-30 Dow Global Technology Inc. Hydrogenated block copolymer compositions
BR0012219A (pt) * 1999-06-11 2002-05-07 Dow Chemical Co Composições compreendendo copolìmeros em bloco hidrogenados e aplicações de uso final para as mesmas
CN1171913C (zh) * 1999-06-11 2004-10-20 陶氏环球技术公司 包括氢化嵌段共聚物的组合物及其最终用途
US20020061982A1 (en) 1999-06-11 2002-05-23 Donald Robert J. Compositions comprising hydrogenated block copolymers and end-use applications thereof
US20020061981A1 (en) 1999-06-11 2002-05-23 Donald Robert J. Compositions comprising hydrogenated block copolymers and end-use applications thereof
MY133783A (en) * 1999-07-28 2007-11-30 Dow Global Technologies Inc Hydrogenated block polymers having elasticity and articles made therefrom
US6777082B2 (en) 1999-07-28 2004-08-17 The Dow Chemical Company Hydrogenated block copolymers having elasticity and articles made therefrom
WO2002010296A1 (fr) * 2000-07-31 2002-02-07 Mitsui Chemicals, Inc. Composition de dispersion aqueuse conferant une resistance au piquage
NL2007262C2 (en) * 2011-08-12 2013-02-13 Kraton Polymers Us Llc A process for preparing articles from a latex comprising water and a styrenic block copolymer and such a latex.
US20130225020A1 (en) 2012-02-24 2013-08-29 Kraton Polymers Us Llc High flow, hydrogenated styrene-butadiene-styrene block copolymer and applications
JP2016108364A (ja) * 2014-12-02 2016-06-20 住友精化株式会社 α−オレフィン−酢酸ビニル系エラストマー粒子のアニオン性水性分散体、その製造方法、成形体、及び、レゾルシン−ホルマリン−ラテックス接着剤
KR101698054B1 (ko) * 2014-12-30 2017-01-19 한국기술교육대학교 산학협력단 반응성 라텍스 입자를 포함하는 고분자 필름
US11034799B2 (en) * 2016-02-29 2021-06-15 Zeon Corporation Method for manufacturing polymer latex
FR3048700B1 (fr) * 2016-03-08 2019-11-08 Arkema France Films poreux obtenus a partir de latex de polymeres
KR20210099033A (ko) * 2018-12-05 2021-08-11 카리플렉스 피티이 리미티드 분지형 중합체로 형성된 라텍스 및 라텍스 제품
WO2020117768A1 (en) * 2018-12-05 2020-06-11 Cariflex Pte. Ltd. Process for forming rubber latex from branched polymers

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3360599A (en) * 1963-11-06 1967-12-26 Shell Oil Co Preparation of coherent block copolymer films of high tensile strength and extensibility
BE747591A (fr) * 1969-04-01 1970-09-21 Shell Int Research Blokcopolymeren met eindstandige statistische copolymeerblokkenvan styreen en alfa-methylstyreen
JPS5268249A (en) * 1975-12-02 1977-06-06 Denki Kagaku Kogyo Kk Process for preparing block-copolymer latexes
EP0058952B1 (en) * 1981-02-20 1984-08-22 Asahi Kasei Kogyo Kabushiki Kaisha A film, sheet or tube of a block copolymer or a composition containing the same
JPS61171714A (ja) * 1984-07-23 1986-08-02 Japan Synthetic Rubber Co Ltd 粘着剤組成物
US5120765A (en) * 1990-09-28 1992-06-09 Shell Oil Company Block copolymer dispersions and process to prepare block copolymer dispersions

Also Published As

Publication number Publication date
CA2150482A1 (en) 1994-07-21
DE69404125T2 (de) 1998-01-22
JPH08505426A (ja) 1996-06-11
EP0678108B1 (en) 1997-07-09
JP2003192869A (ja) 2003-07-09
MX9400336A (es) 1994-08-31
KR960700294A (ko) 1996-01-19
WO1994015997A1 (en) 1994-07-21
KR100284520B1 (ko) 2001-03-15
DE69404125D1 (de) 1997-08-14
TW242632B (es) 1995-03-11
EP0678108A1 (en) 1995-10-25

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