ES2088455T3 - Catalizador soportado para la polimerizacion de etileno y la copolimerizacion de etileno con alfa-olefinas, su preparacion y su uso. - Google Patents
Catalizador soportado para la polimerizacion de etileno y la copolimerizacion de etileno con alfa-olefinas, su preparacion y su uso.Info
- Publication number
- ES2088455T3 ES2088455T3 ES91200481T ES91200481T ES2088455T3 ES 2088455 T3 ES2088455 T3 ES 2088455T3 ES 91200481 T ES91200481 T ES 91200481T ES 91200481 T ES91200481 T ES 91200481T ES 2088455 T3 ES2088455 T3 ES 2088455T3
- Authority
- ES
- Spain
- Prior art keywords
- ethylene
- copolymerization
- alpha
- impregnating
- evaporation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/909—Polymerization characterized by particle size of product
Abstract
SE PRESENTA UN CATALIZADOR SOPORTADO "ZIEGLER-NATTA" ACTIVO EN LA POLIMERIZACION DEL ETILENO Y EN LA COPOLIMERIZACION DEL ETILENO CON OLEFINAS ALFA QUE CONSTA DE: A) UN COCATALIZADOR EN LA FORMA DE UN COMPUESTO ORGANOMETALICO DE ALUMINIO , Y B) UN COMPONENTE CATALIZADOR SOLIDO OBTENIDO MEDIANTE: I) LA IMPREGNACION DE UN SOPORTE SOLIDO GRANULAR CON UNA SOLUCION DE ALCOHOLATO DE TITANIO Y CLORURO DE MAGNESIO EN UN HIDROCARBORO HALIFATICO LIQUIDO, SEGUIDA DE LA EVAPORACION DEL SOLVENTE HIDROCARBONO; II) LA IMPREGNACION DEL SOPORTE TRATADO EN I) CON UNA SOLUCION DE CLORURO DE MAGNESIO EN UN ESTER HALIFATICO LIQUIDO SEGUIDA DE LA EVAPORACION DEL SOLVENTE ESTER; III) LA ACTIVACION DEL SOPORTE TRATADO EN II) MEDIANTE SU PUESTA EN CONTACTO CON UN ALURO DE ALUMINIO DE ALQUIL. EN UNA CONFORMACION MAS ADECUADA SE INTRODUCEN CANTIDADES CONTRASTADAS DE ALURO DE SILICIO EN LA ETAPA I) Y/O II), ESTO MEJORA CONSIDERABLEMENTE LA ACTIVIDAD CATALITICA. EN UNA CONFORMACION PARTICULAR, SE INTRODUCEN ZIRCONIO OHAFNIUM EN EL COMPONENTE CATALIZADOR SOLIDO B) EN ADICION AL TITANIO, PARA OBTENER CATALIZADORES CAPACES DE PRODUCIR POLIETILENOS CON UNA DISTRIBUCION DE PESO MOLECULAR AMPLIADA.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT19698A IT1240611B (it) | 1990-03-16 | 1990-03-16 | Catalizzatore supportato per la polimerizzazione dell'etilene e per lacopolimerizzazione dell'etilene con alfa-olefine, sua preparazione e suo impiego |
| IT02150390A IT1243720B (it) | 1990-09-18 | 1990-09-18 | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e procedimento per la sua preparazione. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2088455T3 true ES2088455T3 (es) | 1996-08-16 |
Family
ID=26327265
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES91200481T Expired - Lifetime ES2088455T3 (es) | 1990-03-16 | 1991-03-06 | Catalizador soportado para la polimerizacion de etileno y la copolimerizacion de etileno con alfa-olefinas, su preparacion y su uso. |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US5278117A (es) |
| EP (1) | EP0446989B1 (es) |
| JP (1) | JP3223301B2 (es) |
| AT (1) | ATE138392T1 (es) |
| BR (1) | BR9101045A (es) |
| CA (1) | CA2038330C (es) |
| CZ (1) | CZ281369B6 (es) |
| DE (1) | DE69119628T2 (es) |
| DK (1) | DK0446989T3 (es) |
| ES (1) | ES2088455T3 (es) |
| FI (1) | FI99207C (es) |
| GR (1) | GR3020578T3 (es) |
| HU (1) | HU212478B (es) |
| RU (1) | RU2022971C1 (es) |
| SK (1) | SK279445B6 (es) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1252041B (it) * | 1990-10-11 | 1995-05-29 | Enimont Anic Srl | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene |
| FI89500C (fi) * | 1991-12-31 | 1993-10-11 | Neste Oy | Prokatalytkomposition foer homo- och sampolymerisering av alfa-olefiner, dess framstaellning och anvaendning |
| US5583083A (en) * | 1991-12-31 | 1996-12-10 | Neste Oy | Procatalyst composition for homo- and copolymerization of alpha olefins, its preparation and its use |
| US5661097A (en) * | 1994-08-12 | 1997-08-26 | The Dow Chemical Company | Supported olefin polymerization catalyst |
| EP0767183B1 (en) * | 1995-10-02 | 1998-11-18 | PCD Polymere AG | Supported catalyst for olefin polymerization |
| ES2126973T3 (es) * | 1995-10-02 | 1999-04-01 | Borealis Ag | Catalizador soportado para la polimerizacion de olefinas. |
| EP0771820A1 (en) * | 1995-11-03 | 1997-05-07 | Union Carbide Chemicals & Plastics Technology Corporation | Supported ziegler-natta catalysts for polyolefin production |
| US6486089B1 (en) | 1995-11-09 | 2002-11-26 | Exxonmobil Oil Corporation | Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution |
| US6417130B1 (en) | 1996-03-25 | 2002-07-09 | Exxonmobil Oil Corporation | One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization |
| JP2000514493A (ja) | 1996-07-15 | 2000-10-31 | モービル・オイル・コーポレーション | 吹込成形およびフィルム用途用コモノマー前処理２金属系触媒 |
| CZ34998A3 (cs) * | 1997-02-17 | 1999-08-11 | Pcd Polymere Gesellschaft M. B. H. | Způsob přípravy pevného nosiče pro katalyzátory polymerace olefinů |
| US6153551A (en) | 1997-07-14 | 2000-11-28 | Mobil Oil Corporation | Preparation of supported catalyst using trialkylaluminum-metallocene contact products |
| US6051525A (en) | 1997-07-14 | 2000-04-18 | Mobil Corporation | Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution |
| WO2000029026A1 (fr) | 1998-11-17 | 2000-05-25 | Taisho Pharmaceutical Co., Ltd. | Suppositoires |
| KR20050035183A (ko) * | 2001-11-30 | 2005-04-15 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 비-단일 부위/단일 부위 촉매 복합물을 이용하여 제조된에틸렌/알파-올레핀 공중합체, 이의 제조 방법 및 용도 |
| ITMI20032206A1 (it) * | 2003-11-14 | 2005-05-15 | Polimeri Europa Spa | Migliorato componente solido di catalizzatore per la (c0)polimerizzazione dell'etilene e processo utilizzante detto. |
| CA2545785C (en) | 2003-11-14 | 2014-01-28 | Polimeri Europa S.P.A. | Improved solid catalyst component and process for the (co) polymerization of ethylene |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| LU65587A1 (es) * | 1972-06-22 | 1973-12-27 | ||
| US4192772A (en) * | 1975-04-14 | 1980-03-11 | Solvay & Cie | Solid catalyst and process for the preparation thereof |
| DE2543181C2 (de) * | 1975-09-27 | 1986-08-28 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Polymerisation von Äthylen oder zu dessen Copolymerisation mit C↓3↓- bis C↓1↓↓0↓-α-Monoolefinen |
| US4383095A (en) * | 1979-02-16 | 1983-05-10 | Union Carbide Corporation | Process for the preparation of high density ethylene polymers in fluid bed reactor |
| US4359561A (en) * | 1979-06-18 | 1982-11-16 | Union Carbide Corporation | High tear strength polymers |
| US4379758A (en) * | 1980-12-24 | 1983-04-12 | Union Carbide Corporation | Catalyst composition for polymerizing ethylene |
| US4354009A (en) * | 1981-07-30 | 1982-10-12 | Union Carbide Corporation | Catalyst composition for copolymerizing ethylene |
| US4370456A (en) * | 1981-11-23 | 1983-01-25 | Union Carbide Corporation | Catalyst composition for copolymerizing ethylene |
| US4562168A (en) * | 1984-05-17 | 1985-12-31 | Phillips Petroleum Company | Catalyst and olefin polymerization |
| IT1203330B (it) * | 1987-02-06 | 1989-02-15 | Enichem Base Spa | Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine |
| US5024982A (en) * | 1988-12-14 | 1991-06-18 | Phillips Petroleum Company | Silica-containing olefin polymerization catalysts and process |
-
1991
- 1991-03-06 DK DK91200481.9T patent/DK0446989T3/da active
- 1991-03-06 DE DE69119628T patent/DE69119628T2/de not_active Expired - Fee Related
- 1991-03-06 EP EP91200481A patent/EP0446989B1/en not_active Expired - Lifetime
- 1991-03-06 AT AT91200481T patent/ATE138392T1/de not_active IP Right Cessation
- 1991-03-06 ES ES91200481T patent/ES2088455T3/es not_active Expired - Lifetime
- 1991-03-08 US US07/666,587 patent/US5278117A/en not_active Expired - Lifetime
- 1991-03-13 CZ CS91655A patent/CZ281369B6/cs not_active IP Right Cessation
- 1991-03-13 SK SK655-91A patent/SK279445B6/sk not_active IP Right Cessation
- 1991-03-14 HU HU91850A patent/HU212478B/hu not_active IP Right Cessation
- 1991-03-15 FI FI911299A patent/FI99207C/fi active
- 1991-03-15 RU SU914894955A patent/RU2022971C1/ru active
- 1991-03-15 JP JP07581591A patent/JP3223301B2/ja not_active Expired - Fee Related
- 1991-03-15 CA CA002038330A patent/CA2038330C/en not_active Expired - Lifetime
- 1991-03-15 BR BR919101045A patent/BR9101045A/pt not_active IP Right Cessation
-
1996
- 1996-07-18 GR GR960401935T patent/GR3020578T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CZ281369B6 (cs) | 1996-09-11 |
| ATE138392T1 (de) | 1996-06-15 |
| JP3223301B2 (ja) | 2001-10-29 |
| HU212478B (en) | 1996-07-29 |
| US5278117A (en) | 1994-01-11 |
| EP0446989A2 (en) | 1991-09-18 |
| GR3020578T3 (en) | 1996-10-31 |
| FI99207C (fi) | 1997-10-27 |
| CS9100655A2 (en) | 1991-10-15 |
| BR9101045A (pt) | 1991-11-05 |
| HUT60295A (en) | 1992-08-28 |
| CA2038330A1 (en) | 1991-09-17 |
| DK0446989T3 (da) | 1996-09-16 |
| FI911299A0 (fi) | 1991-03-15 |
| SK279445B6 (sk) | 1998-11-04 |
| HU910850D0 (en) | 1991-09-30 |
| CA2038330C (en) | 2002-01-15 |
| DE69119628D1 (de) | 1996-06-27 |
| FI911299A (fi) | 1991-09-17 |
| RU2022971C1 (ru) | 1994-11-15 |
| EP0446989B1 (en) | 1996-05-22 |
| FI99207B (fi) | 1997-07-15 |
| DE69119628T2 (de) | 1996-12-05 |
| EP0446989A3 (en) | 1992-03-11 |
| JPH05140220A (ja) | 1993-06-08 |
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| SE8005476L (sv) | Polymerisationskatalysator och forfarande for dess framstellning | |
| IT1251465B (it) | Catalizzatore supportato per la (co)polimerizzazione dell'etilene. | |
| BR9407034A (pt) | Complexos de titânio ( I) ou zircônio (II) e catalisadores de polimerização por adição dos mesmos | |
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| CA2042961A1 (en) | Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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