ES2083586T3 - Materiales arcillosos compuestos utilizados para eliminar el sox contenido en las emisiones gaseosas. - Google Patents

Materiales arcillosos compuestos utilizados para eliminar el sox contenido en las emisiones gaseosas.

Info

Publication number
ES2083586T3
ES2083586T3 ES91913738T ES91913738T ES2083586T3 ES 2083586 T3 ES2083586 T3 ES 2083586T3 ES 91913738 T ES91913738 T ES 91913738T ES 91913738 T ES91913738 T ES 91913738T ES 2083586 T3 ES2083586 T3 ES 2083586T3
Authority
ES
Spain
Prior art keywords
eliminate
materials used
gaseous emissions
clay materials
composite clay
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91913738T
Other languages
English (en)
Inventor
Thomas J Pinnavaia
Christine A Polansky
Jayantha Amarasekera
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Michigan State University MSU
Original Assignee
Michigan State University MSU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Michigan State University MSU filed Critical Michigan State University MSU
Application granted granted Critical
Publication of ES2083586T3 publication Critical patent/ES2083586T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/508—Sulfur oxides by treating the gases with solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
    • C01B33/44—Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • General Health & Medical Sciences (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

SE DESCRIBE UN METODO PARA LA PREPARACION Y UTILIZACION DE COMPOSICIONES QUE INCLUYEN UNA ARCILLA DE ESMECTITA Y UNA BASE O UN PRECURSOR DE BASE QUE REACCIONA CON SO SUB X EN UN GAS COMBUSTIBLE. LA BASE O EL PRECURSOR DE BASE ES PREFERENTEMENTE LA FASE DISPERSADA EN LA FASE VOLUMETRICA DE LA ARCILLA. LAS COMPOSICIONES SE CALIENTAN PARA FORMAR LA BASE QUE REACCIONA CON EL SO SUB X EN EL GAS COMBUSTIBLE.
ES91913738T 1990-07-16 1991-05-28 Materiales arcillosos compuestos utilizados para eliminar el sox contenido en las emisiones gaseosas. Expired - Lifetime ES2083586T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/553,254 US5219536A (en) 1990-07-16 1990-07-16 Composite clay materials for removal of sox from gas streams

Publications (1)

Publication Number Publication Date
ES2083586T3 true ES2083586T3 (es) 1996-04-16

Family

ID=24208742

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91913738T Expired - Lifetime ES2083586T3 (es) 1990-07-16 1991-05-28 Materiales arcillosos compuestos utilizados para eliminar el sox contenido en las emisiones gaseosas.

Country Status (14)

Country Link
US (2) US5219536A (es)
EP (1) EP0491931B1 (es)
JP (1) JPH0620540B2 (es)
KR (1) KR950008192B1 (es)
CN (1) CN1125157A (es)
AT (1) ATE131414T1 (es)
CA (1) CA2065026C (es)
DE (1) DE69115455T2 (es)
DK (1) DK0491931T3 (es)
ES (1) ES2083586T3 (es)
GR (1) GR3018686T3 (es)
MX (1) MX9100166A (es)
MY (1) MY106358A (es)
WO (1) WO1992001509A1 (es)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2336636A1 (es) * 2009-10-14 2010-04-14 Universidad De Cantabria Procedimiento para la oabtencion de un sorbente captador de so2.

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US5225384A (en) * 1990-07-16 1993-07-06 Board Of Trustees Operating Michigan State University Composite clay materials for removal of sox from gas streams
US5298473A (en) * 1990-07-16 1994-03-29 Board Of Trustees Operating Michigan State University Hydrated lime clay composites for the removal of SOx from flue gas streams
US5234877A (en) * 1990-07-16 1993-08-10 Board Of Trustees Operating Michigan State University Composite clay materials for removal of SOx from gas streams
US5334564A (en) * 1990-07-16 1994-08-02 Board Of Trustees Operating Michigan State University Method for the preparation of highly reactive clay composites for the removal of SOx from flue gas streams
DE4220950A1 (de) * 1992-06-26 1994-01-05 Metallgesellschaft Ag Verfahren zur Abscheidung von HF, HCl, SO¶2¶, SO¶3¶ und/oder H¶2¶S aus Gasen
US5415850A (en) * 1993-02-24 1995-05-16 The Research Foundation Of State Univeristy Of New York Pillared interlayered clay catalysts for the selective reduction of nitrogen oxides with ammonia
DE4417837A1 (de) * 1994-05-20 1995-11-23 Basf Ag Substituierte 3-Phenylpyrazole
WO2000000282A1 (en) * 1998-06-30 2000-01-06 Eastman Chemical Company Basic clay catalyst for the production of glycol monoester
US8124036B1 (en) 2005-10-27 2012-02-28 ADA-ES, Inc. Additives for mercury oxidation in coal-fired power plants
FR2814533B1 (fr) * 2000-09-27 2002-10-31 Alstom Power Nv Procede pour reduire simultanement les emissions de co2 de so2 dans une installation de combustion
CN100483824C (zh) * 2003-12-03 2009-04-29 松下电器产业株式会社 燃料电池***
CA2848601C (en) 2004-06-28 2018-10-30 Nox Ii, Ltd. Reducing sulfur gas emissions resulting from the burning of carbonaceous fuels
RU2494793C2 (ru) 2005-03-17 2013-10-10 НОКС II ИНТЕНЭШНЛ, эЛТиДи. Способ сжигания ртутьсодержащего топлива (варианты), способ снижения количества выброса ртути, способ сжигания угля с уменьшенным уровнем выброса вредных элементов в окружающую среду, способ уменьшения содержания ртути в дымовых газах
PL1872054T5 (pl) * 2005-03-17 2022-08-16 Nox Ii International, Ltd. Zmniejszenie emisji rtęci w spalinach ze spalania węgla
US7531154B2 (en) * 2005-08-18 2009-05-12 Solvay Chemicals Method of removing sulfur dioxide from a flue gas stream
US7481987B2 (en) * 2005-09-15 2009-01-27 Solvay Chemicals Method of removing sulfur trioxide from a flue gas stream
US8150776B2 (en) * 2006-01-18 2012-04-03 Nox Ii, Ltd. Methods of operating a coal burning facility
US20070184394A1 (en) * 2006-02-07 2007-08-09 Comrie Douglas C Production of cementitious ash products with reduced carbon emissions
KR20100043261A (ko) * 2007-08-02 2010-04-28 더 벤타마이트 컴패니, 엘엘씨 배기 가스 탈황을 위한 흡착 입자의 조성물, 제조 및 용도
CN101445250B (zh) * 2008-12-05 2011-06-01 山东师范大学 一种有机物与无机物复合体及其制备方法
US8951487B2 (en) 2010-10-25 2015-02-10 ADA-ES, Inc. Hot-side method and system
US8496894B2 (en) 2010-02-04 2013-07-30 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
AU2011212805B2 (en) 2010-02-04 2016-03-24 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US11298657B2 (en) 2010-10-25 2022-04-12 ADA-ES, Inc. Hot-side method and system
US8524179B2 (en) 2010-10-25 2013-09-03 ADA-ES, Inc. Hot-side method and system
EP2545334B8 (en) 2010-03-10 2018-09-19 ADA-ES, Inc. Process for dilute phase injection of dry alkaline materials into a gas
US8784757B2 (en) 2010-03-10 2014-07-22 ADA-ES, Inc. Air treatment process for dilute phase injection of dry alkaline materials
CN101792617B (zh) * 2010-03-15 2013-01-02 湖南博深实业有限公司 一种用于pp填充的碳酸钙/蒙脱土纳米复合粒子及其制备方法
US8845986B2 (en) 2011-05-13 2014-09-30 ADA-ES, Inc. Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers
US9017452B2 (en) 2011-11-14 2015-04-28 ADA-ES, Inc. System and method for dense phase sorbent injection
DK2644267T4 (da) 2012-03-30 2021-04-12 Rheinkalk Gmbh Aktivering af et materiale, der indeholder jordalkalicarbonat og jordalkalihydroxid, til tør røggasrensning
US10532313B2 (en) 2012-03-30 2020-01-14 Rheinkalk Gmbh Activation of a material containing alkaline-earth metal carbonate and alkaline-earth metal hydroxide for the dry scrubbing of flue gas
US8883099B2 (en) 2012-04-11 2014-11-11 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US8974756B2 (en) 2012-07-25 2015-03-10 ADA-ES, Inc. Process to enhance mixing of dry sorbents and flue gas for air pollution control
US9957454B2 (en) 2012-08-10 2018-05-01 ADA-ES, Inc. Method and additive for controlling nitrogen oxide emissions
AU2014248855A1 (en) * 2013-03-13 2015-10-01 Novinda Corporation Multicomponent compositions for mercury removal
US10350545B2 (en) 2014-11-25 2019-07-16 ADA-ES, Inc. Low pressure drop static mixing system
EP3850270B1 (en) * 2018-09-14 2022-11-02 MinPlus B.V. A method of operating an incinerator comprising a device for capturing ash entrained by flue gas
CN114011234B (zh) * 2021-11-10 2024-04-23 山东鲁碧建材有限公司 一种处理低温烟气的干法脱硫方法
CN115779850B (zh) * 2022-11-01 2024-07-26 深圳市中金岭南有色金属股份有限公司凡口铅锌矿 石粉硅基材料、制备方法以及应用
CN115999499A (zh) * 2022-12-27 2023-04-25 国家电投集团远达环保工程有限公司 一种用于脱除烟气中so3的吸附剂及其制备方法

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2336636A1 (es) * 2009-10-14 2010-04-14 Universidad De Cantabria Procedimiento para la oabtencion de un sorbente captador de so2.

Also Published As

Publication number Publication date
DE69115455T2 (de) 1996-05-02
US5219536A (en) 1993-06-15
US5126300A (en) 1992-06-30
DE69115455D1 (de) 1996-01-25
CA2065026A1 (en) 1992-01-17
EP0491931B1 (en) 1995-12-13
DK0491931T3 (da) 1996-03-04
CA2065026C (en) 1998-04-14
KR950008192B1 (ko) 1995-07-26
ATE131414T1 (de) 1995-12-15
GR3018686T3 (en) 1996-04-30
EP0491931A4 (en) 1993-05-26
MY106358A (en) 1995-05-30
JPH04504979A (ja) 1992-09-03
CN1125157A (zh) 1996-06-26
JPH0620540B2 (ja) 1994-03-23
EP0491931A1 (en) 1992-07-01
KR920702251A (ko) 1992-09-03
MX9100166A (es) 1992-02-28
WO1992001509A1 (en) 1992-02-06

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