ES2073661T3 - Metodo para la isomerizacion fotoquimica de compuestos organicos bajo la influencia de un fotosensibilizador. - Google Patents
Metodo para la isomerizacion fotoquimica de compuestos organicos bajo la influencia de un fotosensibilizador.Info
- Publication number
- ES2073661T3 ES2073661T3 ES91200828T ES91200828T ES2073661T3 ES 2073661 T3 ES2073661 T3 ES 2073661T3 ES 91200828 T ES91200828 T ES 91200828T ES 91200828 T ES91200828 T ES 91200828T ES 2073661 T3 ES2073661 T3 ES 2073661T3
- Authority
- ES
- Spain
- Prior art keywords
- influence
- cpds
- photosensitizer
- organic compounds
- compounds under
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C401/00—Irradiation products of cholesterol or its derivatives; Vitamin D derivatives, 9,10-seco cyclopenta[a]phenanthrene or analogues obtained by chemical preparation without irradiation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
- C07D333/14—Radicals substituted by singly bound hetero atoms other than halogen
- C07D333/20—Radicals substituted by singly bound hetero atoms other than halogen by nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D333/30—Hetero atoms other than halogen
- C07D333/36—Nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Plural Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Heterocyclic Compounds Containing Sulfur Atoms (AREA)
Abstract
LA INVENCION SE REFIERE A UN METODO PARA LA ISOMERIZACION FOTOQUIMICA DE COMPUESTOS ORGANICOS, EN ESPECIAL PARA LA CONVERSION FOTOQUIMICA DE COMPUESTOS DE TAQUISTEROL EN COMPUESTOS DE PREVITAMINA D Y DE COMPUESTOS DE TRANS-VITAMINA D EN COMPUESTOS DE CIS-VITAMINA D BAJO LA INFLUENCIA DE RADIACION, EXPONIENDO UNA DISOLUCION DEL COMPUESTO ORGANICO QUE VA A CONVERTIRSE EN PRESENCIA DE UN FOTOSENSIBILIZADOR NO-POLIMERICO A UNA LUZ CON UNA LONGITUD DE ONDA APROXIMADA ENTRE 300-1.000 NM, Y LUEGO AISLANDO EL PRODUCTO RESULTANTE, EN EL QUE SE UTILIZA COMO FOTOSENSIBILIZADOR UN DERIVADO DE TIOFENO SUSTITUIDO CON UNA ABSORCION SUSTANCIAL EN LA REGION DE LONGITUD DE ONDA. LA INVENCION TAMBIEN SE REFIERE A UN NUEVO FOTOSENSIBILIZADOR QUE SE UTILIZA EN LA REACCION DE ISOMERIZACION
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP90201071 | 1990-04-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2073661T3 true ES2073661T3 (es) | 1995-08-16 |
Family
ID=8205006
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES91200828T Expired - Lifetime ES2073661T3 (es) | 1990-04-27 | 1991-04-10 | Metodo para la isomerizacion fotoquimica de compuestos organicos bajo la influencia de un fotosensibilizador. |
Country Status (12)
Country | Link |
---|---|
US (1) | US5252191A (es) |
EP (1) | EP0454204B1 (es) |
JP (1) | JP2945505B2 (es) |
AT (1) | ATE124394T1 (es) |
CA (1) | CA2041135C (es) |
CZ (1) | CZ287447B6 (es) |
DE (1) | DE69110739T2 (es) |
DK (1) | DK0454204T3 (es) |
ES (1) | ES2073661T3 (es) |
GR (1) | GR3017441T3 (es) |
IL (1) | IL97934A (es) |
SK (1) | SK281371B6 (es) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5543016A (en) * | 1991-07-12 | 1996-08-06 | Inrad | Photoconversion of steroids in microreactors |
US5578636A (en) * | 1994-04-08 | 1996-11-26 | Purdue Research Foundation | Polythiophene anti-tumor agents |
ITFI940095A1 (it) * | 1994-05-23 | 1995-11-23 | Molteni & C | Coniugati fotodinamici aventi proprieta' biocide |
US20040043971A1 (en) * | 1995-04-03 | 2004-03-04 | Bone Care International, Inc. | Method of treating and preventing hyperparathyroidism with active vitamin D analogs |
US6242434B1 (en) | 1997-08-08 | 2001-06-05 | Bone Care International, Inc. | 24-hydroxyvitamin D, analogs and uses thereof |
US20020183288A1 (en) * | 1995-04-03 | 2002-12-05 | Bone Care International, Inc. | Method for treating and preventing hyperparathyroidism |
EP1007035A4 (en) * | 1996-11-26 | 2000-11-22 | Purdue Research Foundation | POLYTHIOPHENES AS ANTITUARY AGENTS |
CN1148347C (zh) | 1998-05-29 | 2004-05-05 | 骨疗国际公司 | 羟基-25-烯-维生素d类化合物的制备方法 |
US5972917A (en) * | 1998-05-29 | 1999-10-26 | Bone Care Int Inc | 1 α-hydroxy-25-ene-vitamin D, analogs and uses thereof |
US20040186082A1 (en) * | 2003-03-20 | 2004-09-23 | Hartman Raymond A. | Enhanced phototherapy for the treatment of cancer and autoimmune disease |
US7094775B2 (en) | 2004-06-30 | 2006-08-22 | Bone Care International, Llc | Method of treating breast cancer using a combination of vitamin D analogues and other agents |
US8158801B2 (en) | 2005-09-26 | 2012-04-17 | Life Technologies Corporation | Violet laser excitable dyes and their method of use |
LT2605652T (lt) * | 2010-08-18 | 2018-03-12 | Samumed, Llc | Diketonai ir hidroksiketonai kaip katenino signalinio kelio aktyvintojai |
PE20151721A1 (es) | 2013-02-22 | 2015-12-07 | Samumed Llc | Y-dicetonas como activadores de la ruta de senalizacion de wnt/b-catenina |
RS59797B1 (sr) | 2014-08-20 | 2020-02-28 | Samumed Llc | Gama-diketoni za tretman i prevenciju starenja kože i bora |
WO2020230159A1 (en) * | 2019-05-10 | 2020-11-19 | Fermenta Biotech Limited | Irradiation process of pro vitamin d |
US20220298106A1 (en) * | 2019-05-15 | 2022-09-22 | Fermenta Biotech Limited | Improved photochemical synthesis of vitamin d3 using sensitizers |
US20220306615A1 (en) * | 2019-06-06 | 2022-09-29 | Fermenta Biotech Limited | An improved process to synthesize 5-(3pyridyl)-2,2'-bithiophene(sensitizer) |
EP3906228A4 (en) * | 2019-07-09 | 2023-02-15 | Fermenta Biotech Limited | IMPROVED, LOW-COST PROCESS FOR SYNTHESIS OF VITAMIN D3 AND ITS ANALOGUE OF CALCIUM DIOL FROM ERGOSTEROL |
EP3906247A4 (en) * | 2019-07-09 | 2022-10-12 | Fermenta Biotech Limited | SYNTHESIS OF CHOLESTEROL AND VITAMIN D3 FROM PHYTOSTEROLS |
WO2021019559A1 (en) * | 2019-07-30 | 2021-02-04 | Fermenta Biotech Limited | Synthesis of 5-(3-pyridyl)-2,2'-bithiophene(sensitizer) |
WO2021019558A1 (en) * | 2019-07-30 | 2021-02-04 | Fermenta Biotech Limited | An efficient method for synthesis of 5-(3-pyridyl)-2,2'-bithiophene(sensitizer) |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4551214A (en) * | 1983-07-01 | 1985-11-05 | Hoffmann-La Roche Inc. | Photochemical preparation of previtamin D |
DE3346175A1 (de) * | 1983-12-21 | 1985-07-11 | Merck Patent Gmbh, 6100 Darmstadt | Pyridylthiophene |
US4686023A (en) * | 1985-11-26 | 1987-08-11 | Solarchem Research, Division Of Brolor Investments, Ltd. | Sensitized photochemical preparation of vitamin D |
NO872850L (no) * | 1986-07-09 | 1988-01-11 | Solarchem Res | Fotokjemisk sensitiverende materialer. |
DE3890861C2 (de) * | 1987-10-07 | 1994-10-13 | Fuji Electric Co Ltd | Elektrophotographisches Auzeichnungsmaterial |
US4886625A (en) * | 1987-10-29 | 1989-12-12 | Miles Inc. | Functionalized conducting polymers and their use in diagnostic devices |
ATE90075T1 (de) * | 1988-12-12 | 1993-06-15 | Duphar Int Res | Verfahren zur photochemischen umwandlung von tachysterol-derivaten in praevitamin d-derivate und von transvitamin d-derivaten in cisvitamin d- derivate. |
-
1991
- 1991-04-10 EP EP91200828A patent/EP0454204B1/en not_active Expired - Lifetime
- 1991-04-10 ES ES91200828T patent/ES2073661T3/es not_active Expired - Lifetime
- 1991-04-10 DK DK91200828.1T patent/DK0454204T3/da active
- 1991-04-10 AT AT91200828T patent/ATE124394T1/de not_active IP Right Cessation
- 1991-04-10 DE DE69110739T patent/DE69110739T2/de not_active Expired - Fee Related
- 1991-04-23 CZ CS19911149A patent/CZ287447B6/cs not_active IP Right Cessation
- 1991-04-23 SK SK1149-91A patent/SK281371B6/sk unknown
- 1991-04-24 US US07/690,684 patent/US5252191A/en not_active Expired - Lifetime
- 1991-04-24 CA CA002041135A patent/CA2041135C/en not_active Expired - Fee Related
- 1991-04-24 JP JP3119009A patent/JP2945505B2/ja not_active Expired - Fee Related
- 1991-04-24 IL IL9793491A patent/IL97934A/en not_active IP Right Cessation
-
1995
- 1995-09-20 GR GR950402567T patent/GR3017441T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
DK0454204T3 (da) | 1995-08-28 |
GR3017441T3 (en) | 1995-12-31 |
US5252191A (en) | 1993-10-12 |
CA2041135C (en) | 2003-02-11 |
JPH04225951A (ja) | 1992-08-14 |
EP0454204B1 (en) | 1995-06-28 |
IL97934A0 (en) | 1992-06-21 |
DE69110739T2 (de) | 1995-11-23 |
EP0454204A3 (en) | 1992-10-07 |
CS114991A3 (en) | 1992-01-15 |
IL97934A (en) | 1996-09-12 |
EP0454204A2 (en) | 1991-10-30 |
DE69110739D1 (de) | 1995-08-03 |
JP2945505B2 (ja) | 1999-09-06 |
CA2041135A1 (en) | 1991-10-28 |
CZ287447B6 (cs) | 2000-11-15 |
SK281371B6 (sk) | 2001-03-12 |
ATE124394T1 (de) | 1995-07-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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