ES2046349T3 - Procedimiento para la preparacion de polimeros de 1-olefinas. - Google Patents
Procedimiento para la preparacion de polimeros de 1-olefinas.Info
- Publication number
- ES2046349T3 ES2046349T3 ES198989103941T ES89103941T ES2046349T3 ES 2046349 T3 ES2046349 T3 ES 2046349T3 ES 198989103941 T ES198989103941 T ES 198989103941T ES 89103941 T ES89103941 T ES 89103941T ES 2046349 T3 ES2046349 T3 ES 2046349T3
- Authority
- ES
- Spain
- Prior art keywords
- procedure
- preparation
- olephine
- polymers
- catalyst system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PROCEDIMIENTO PARA LA OBTENCION DE POLIMEROS 1 - OLEFINA, CONSTA DE UN SISTEMA CATALIZADOR MUY EFICAZ PARA LA POLIMERIZACION DE 1 OLEFINAS A PARTIR DE UN AMINOXANO Y UN METALOCENO, EL CUAL ES UN COMPUESTO DE LA FORMULA (I): DONDE R1 Y R2 SON ATOMOS DE HIDROGENO, HALOGENO O HIDRATOS DE CARBONO SOLIDOS Y R3 Y R4 SON RESTOS DE HIDRATOS DE CARBONO CON 1 O MAS ANILLOS, LOS CUALES SE PUEDEN FORMAR CON EL ATOMO CENTRAL DE UNA ESTRUCTURA SANDWICH, Y QUE SE PUEDEN ENLAZAR POR UN PUENTE - RM EXP6 - R EXP5 - RN EXP7 QUE CONTIENE UN HETEROATOMO POR UNO O MAS MIEMBROS. EL SISTEMA CATALIZADOR SUMINISTRA UN POLIMERO CON UNA MASA MOLECULAR MUY ALTA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3808267A DE3808267A1 (de) | 1988-03-12 | 1988-03-12 | Verfahren zur herstellung von 1-olefinpolymeren |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2046349T3 true ES2046349T3 (es) | 1994-02-01 |
ES2046349T5 ES2046349T5 (es) | 1997-08-01 |
Family
ID=6349551
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES89103941T Expired - Lifetime ES2046349T5 (es) | 1988-03-12 | 1989-03-07 | Procedimiento para la preparacion de polimeros de 1-olefinas. |
Country Status (7)
Country | Link |
---|---|
US (1) | US5679811A (es) |
EP (1) | EP0336127B2 (es) |
JP (1) | JP2854013B2 (es) |
CA (1) | CA1319785C (es) |
DE (2) | DE3808267A1 (es) |
ES (1) | ES2046349T5 (es) |
ZA (1) | ZA891801B (es) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3825814A1 (de) * | 1988-07-29 | 1990-02-01 | Hoechst Ag | Verfahren zur herstellung von l-olefinpolymeren |
KR900009719A (ko) * | 1988-12-16 | 1990-07-05 | 엠. 데이비드 레오나이드 | 신규 에틸렌-프로필렌 공중합체 |
DE4005947A1 (de) * | 1990-02-26 | 1991-08-29 | Basf Ag | Loesliche katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
CA2067525C (en) * | 1991-05-09 | 1998-09-15 | Helmut G. Alt | Organometallic fluorenyl compounds, preparation and use |
DE4228812A1 (de) * | 1992-08-29 | 1994-03-03 | Hoechst Ag | Siegelbare Polypropylen-Mehrschichtfolie, Verfahren zu ihrer Herstellung und ihre Verwendung |
DE4434640C1 (de) * | 1994-09-28 | 1996-02-01 | Hoechst Ag | Verfahren zur Herstellung verbrückter Metallocene |
EP0755779B1 (de) * | 1995-05-31 | 2000-08-09 | Hoechst Aktiengesellschaft | Biaxial orientierte Polypropylenfolie mit erhöhter Dimensionsstabilität |
EP0745477A1 (de) * | 1995-05-31 | 1996-12-04 | Hoechst Aktiengesellschaft | Biaxial orientierte Polypropylenfolie mit verbessertem Migrationswiderstand |
DE19637669A1 (de) | 1996-09-16 | 1998-03-19 | Hoechst Ag | Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung |
US6252019B1 (en) * | 1997-05-13 | 2001-06-26 | Montell Technology Company Bv | Process for polymerizing tactioselective polyolefins in condensed phase using hafnocenes |
US5905162A (en) * | 1997-08-12 | 1999-05-18 | Albemarle Corporation | Enhanced production of bridged hafnocenes |
EP1115761B1 (en) * | 1998-08-26 | 2013-09-18 | ExxonMobil Chemical Patents Inc. | Branched polypropylene compositions |
EP1284981B1 (de) | 2000-05-31 | 2007-07-11 | Basell Polyolefine GmbH | Verfahren zur herstellung von übergangsmetallverbindungen und deren verwendung zur polymerisation von olefinen |
ITMI20012085A1 (it) | 2000-10-17 | 2003-04-09 | Ciba Sc Holding Ag | Polpropilene metallocene stabilizzato |
EP1403288A1 (en) * | 2002-09-27 | 2004-03-31 | ATOFINA Research | Dual site catalyst system comprising a hafnocene component for the production of bimodal polyolefins |
WO2004094490A1 (en) * | 2003-04-15 | 2004-11-04 | Exxonmobil Chemical Patents Inc. | Catalysts for propylene copolymers, polymerization process and copolymer of propylene |
US8399725B2 (en) * | 2008-06-20 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Functionalized high vinyl terminated propylene based oligomers |
US8372930B2 (en) * | 2008-06-20 | 2013-02-12 | Exxonmobil Chemical Patents Inc. | High vinyl terminated propylene based oligomers |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA627588A (en) * | 1961-09-19 | S. Breslow David | Polymerization of ethylene | |
DE3127133A1 (de) * | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
FR2539133A1 (fr) * | 1983-01-11 | 1984-07-13 | Raffinage Cie Francaise | Procede de preparation de compositions catalytiques pour la polymerisation d'olefines, compositions catalytiques preparees par ce procede et application desdites compositions |
FR2546522B1 (fr) * | 1983-05-25 | 1985-07-26 | Ato Chimie | Procede de preparation d'une composante de metal de transition pour un systeme catalytique de polymerisation d'olefines |
CA1231702A (en) * | 1983-06-06 | 1988-01-19 | John A. Ewen | Process and catalyst for producing reactor blend polyolefins |
US4522982A (en) * | 1983-06-06 | 1985-06-11 | Exxon Research & Engineering Co. | Isotactic-stereoblock polymers of alpha-olefins and process for producing the same |
ZA844157B (en) * | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
US4937299A (en) * | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
US4530914A (en) * | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
DE3443087A1 (de) * | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
DE3508887A1 (de) * | 1985-03-13 | 1986-09-25 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von optisch aktiven polyolefinen |
US4808561A (en) * | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
CA1268754A (en) * | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Supported polymerization catalyst |
US4897455A (en) * | 1985-06-21 | 1990-01-30 | Exxon Chemical Patents Inc. | Polymerization process |
US4701432A (en) * | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
IL80888A (en) * | 1985-12-12 | 1991-12-12 | Exxon Chemical Patents Inc | Olefin polymerization catalysts,their preparation and use thereof |
US5077255A (en) * | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
EP0260999A1 (en) * | 1986-09-19 | 1988-03-23 | Exxon Chemical Patents Inc. | High pressure, high temperature polymerization of ethylene |
US5084534A (en) * | 1987-06-04 | 1992-01-28 | Exxon Chemical Patents, Inc. | High pressure, high temperature polymerization of ethylene |
CA1338046C (en) * | 1986-09-19 | 1996-02-06 | Howard Curtis Welborn Jr. | High pressure high temperature polymerization of ethylene |
ATE133690T1 (de) * | 1987-04-03 | 1996-02-15 | Fina Technology | Metallocen-katalysatorsysteme für die polymersation von olefinen, mit einer silizium- hydrocarbyl-brücke. |
US4794096A (en) * | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
DE3726067A1 (de) * | 1987-08-06 | 1989-02-16 | Hoechst Ag | Verfahren zur herstellung von 1-olefinpolymeren |
JP2587251B2 (ja) * | 1987-11-09 | 1997-03-05 | チッソ株式会社 | 立体規則性オレフィン重合体製造用触媒 |
DE3742934A1 (de) * | 1987-12-18 | 1989-06-29 | Hoechst Ag | Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung |
US5017714A (en) * | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
US5120867A (en) * | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
-
1988
- 1988-03-12 DE DE3808267A patent/DE3808267A1/de not_active Withdrawn
-
1989
- 1989-03-07 EP EP89103941A patent/EP0336127B2/de not_active Expired - Lifetime
- 1989-03-07 DE DE8989103941T patent/DE58903308D1/de not_active Expired - Fee Related
- 1989-03-07 ES ES89103941T patent/ES2046349T5/es not_active Expired - Lifetime
- 1989-03-09 ZA ZA891801A patent/ZA891801B/xx unknown
- 1989-03-10 CA CA000593402A patent/CA1319785C/en not_active Expired - Fee Related
- 1989-03-10 JP JP1056527A patent/JP2854013B2/ja not_active Expired - Fee Related
-
1995
- 1995-05-30 US US08/453,953 patent/US5679811A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
ZA891801B (en) | 1989-10-25 |
EP0336127A2 (de) | 1989-10-11 |
AU3122289A (en) | 1989-09-14 |
EP0336127B1 (de) | 1993-01-20 |
CA1319785C (en) | 1993-06-29 |
ES2046349T5 (es) | 1997-08-01 |
JPH01275608A (ja) | 1989-11-06 |
AU616246B2 (en) | 1991-10-24 |
US5679811A (en) | 1997-10-21 |
EP0336127A3 (en) | 1989-10-25 |
JP2854013B2 (ja) | 1999-02-03 |
EP0336127B2 (de) | 1997-04-09 |
DE58903308D1 (de) | 1993-03-04 |
DE3808267A1 (de) | 1989-09-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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