EP4293141A1 - Anodenwartungsanordnung für eine aluminium-elektrolyseanlage und verfahren zum betreiben dafür - Google Patents
Anodenwartungsanordnung für eine aluminium-elektrolyseanlage und verfahren zum betreiben dafür Download PDFInfo
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- EP4293141A1 EP4293141A1 EP22178734.4A EP22178734A EP4293141A1 EP 4293141 A1 EP4293141 A1 EP 4293141A1 EP 22178734 A EP22178734 A EP 22178734A EP 4293141 A1 EP4293141 A1 EP 4293141A1
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- Prior art keywords
- anode
- assembly
- servicing
- lifting
- elongated body
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- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 37
- 239000004411 aluminium Substances 0.000 title claims abstract description 31
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 31
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims description 28
- 230000000712 assembly Effects 0.000 claims abstract description 29
- 238000000429 assembly Methods 0.000 claims abstract description 29
- 239000000463 material Substances 0.000 claims description 17
- 239000000969 carrier Substances 0.000 claims description 16
- 230000008859 change Effects 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 12
- 238000011017 operating method Methods 0.000 claims description 9
- 238000010079 rubber tapping Methods 0.000 claims description 8
- 238000010407 vacuum cleaning Methods 0.000 claims description 6
- 238000013519 translation Methods 0.000 claims description 5
- 239000011538 cleaning material Substances 0.000 claims description 2
- 238000005580 one pot reaction Methods 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 14
- 229910052799 carbon Inorganic materials 0.000 description 14
- 239000003792 electrolyte Substances 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000009626 Hall-Héroult process Methods 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000001473 noxious effect Effects 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000003575 carbonaceous material Substances 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000006073 displacement reaction Methods 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminium flouride Chemical compound F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910001610 cryolite Inorganic materials 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000011244 liquid electrolyte Substances 0.000 description 2
- 229910001338 liquidmetal Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000009291 secondary effect Effects 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
- C25C3/10—External supporting frames or structures
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
- C25C3/12—Anodes
- C25C3/125—Anodes based on carbon
Definitions
- the invention relates to the field of fused salt electrolysis, and more precisely to anodes for use in the Hall-Héroult process for making aluminium by fused salt electrolysis and to the methods for replacing anode assemblies. Carbon anodes are consumed in the course of the electrolysis process; they need to be replaced regularly.
- the invention relates to a device for replacing anode assemblies in electrolytic cells that is used in conjunction with a dedicated overhead crane, forming with the latter a system for replacing anode assemblies and for carrying out certain maintenance operations related to the replacement of anode assemblies.
- the Hall-Heroult process is the only continuous industrial process for producing metallic aluminium from aluminium oxide.
- Aluminium oxide Al 2 O 3
- a molten cryolite Na 3 AlF 6
- the dissolved alumina is electrochemically decomposed with the aid of a consumable anode at a temperature that is typically comprised between 950 °C and 970 °C in an electrolytic cell.
- the typically rectangular electrolytic cell (also called “pot”) used for all modern Hall-Héroult cells typically comprises a steel shell (so-called potshell), the base of which contains a thermally insulating lining that includes refractory bricks and supports heat, and an array of transversely positioned cathode blocks usually made from graphite, anthracite or a mixture of both. These blocks are jointed to each other and each one has an embedded metal bar or bars for connection to the negative side of a DC power source.
- the sidewall is also sealed to carbonaceous lining base with carbonaceous material making a leakproof container for the liquid aluminium produced, and the less dense electrolyte containing the dissolved alumina.
- An electrically isolated superstructure is fixed on the top of the steel pot shell, and this is designed to contain consumable materials (alumina and aluminium fluoride) hoppers, breakers and feeders.
- the superstructure supports a height adjustable aluminium busbar (also called “anode beam”) to which the anodes are clamped, and enable enclosing the atmosphere so that emissions can be collected and appropriately treated.
- Anodes in the Hall-Heroult process are usually prebaked cuboids made from a carbonaceous material.
- the anodes are fixedly connected to so-called anode hangers.
- Anode hangers are fixed to the overhanging anode beam in a detachable manner using a system comprising hooks and clamps.
- Anode hangers comprise an upper part called “anode rod”, which is connected to the anode beam, and a lower part, called “anode yoke”.
- the anode yoke has a number of legs each of which terminates in a cylindrical stub that is embedded in pre-formed stub holes of the carbon anodes and is fixed with cast iron acting as temperature-resistant, electrically conductive contact element. This process is called “rodding”.
- the assembly formed by a carbon anode fixed to its anode hanger is called an “anode assembly”.
- the plurality of anodes supported by the adjustable anode beam and which are usually in two rows are immersed into the molten salt electrolyte to the required height above the liquid aluminium cathode.
- Anodes and cathodes are connected to external busbar circuitry to enable electrical current through the cell at a controller determined voltage that is invariably somewhere between 3.8 V and 5 V.
- This arrangement combined with the electrical energy provided enables electrochemical decomposition of the ionic species arising from dissolving the aluminium oxide in the molten fluoride-based solvent.
- the aluminium containing cationic species formed from the alumina dissolution are electrochemically reduced at the metal pad surface to liquid aluminium.
- the oxy-anions formed from alumina are reactively oxidised to carbon monoxide and more dominantly to carbon dioxide at the carbon-anode interface.
- the resulting metallic aluminium is not miscible with the liquid electrolyte, has a higher density than the liquid electrolyte and will thus accumulate as a liquid metal pad on the cathode surface from where it needs to be removed from time to time, usually by suction into a crucible (so-called "tapping" procedure), said crucible being typically carried by a vehicle moving on the ground floor or by an overhead crane.
- each anode assembly Because of the electrochemical consumption of the carbon, each anode assembly has a finite life. Furthermore in order to maintain metal quality, and thus ensure no metallic part of the anode assembly comes into contact with the electrolyte, only approximately 80% of each anode is consumed electrochemically and chemically before it is considered to be a "spent anode assembly", thus needing replacement. Depending on the design and dimensions of the carbon block, the anode assembly, usually has an operating lifetime between 18 to 30 days. Knowing that a modern electrolysis cell typically comprises between 16 and 40 anodes, the replacement of an anode or a pair of anodes occurs between 24 and 48 hours in each pot and more often every 32 hours.
- the replacement of all spent anode assemblies are scheduled at a regular interval such that each is changed once in the operating life cycle.
- the replacement of an anode or anode pair will occur at intervals somewhere between once every approximately 24 to 48 hours for each cell.
- anode change is the most frequent periodic maintenance operation in the Hall-Heroult process, which is, as such, a continuous process.
- Anode change is carried out by replacing a spent anode assembly by a new anode assembly.
- the spent anode assemblies are transported to a dedicated workshop in the plant, where the remains of the spent carbon anode are removed from the anode yokes, and the anode hangers of the spent anode assemblies, are cleaned and reused in new anode assemblies; new carbon anodes are fixed to the anode yoke, thereby creating a "new anode assembly".
- the present technology and work practices associated with removing a spent anode assembly and replacing it with a new anode assembly has numerous manual labour intensive steps that not only lead to excessive harmful emissions, but are also wasteful of the stored energy as well as introducing performance harming disturbances, and presenting a health hazard to workers.
- the said cathode blocks that form the bottom of the electrolytic cell undergo a series of very slow degradation steps, limiting their lifetime to typically between five to eight years.
- the superstructure is removed and the spent potshell is lifted using a heavy overhead crane (so-called "Cathode Transport Crane", abridged CTC), enabling a replacement pre-lined pot shell to be positioned, ready for commissioning.
- Said cathode transport crane needs to have a very high lifting power, typically of more than 200 tonnes.
- gaseous emissions of the Hall-Heroult electrolytic process also comprise fine particulate condensed fluoride arising from the electrolyte as well as hydrogen fluoride, originating from impurities in the smelter grade alumina that also dissolve in the electrolytic bath, and minor amounts of SO 2 originating from impurities in the anode carbon. These are noxious to workers and to the environment. Therefore, since the 1970s, gaseous emissions of Hall-Heroult cells are no longer released into the environment but undergo purification. More precisely, gaseous emissions from electrolytic pots are collected using protection devices such as hooding systems and are treated in gas treatment stations to remove fluorine compounds and other noxious compounds before releasing the collected air into the environment. The prior art work practice for replacing spent anodes results in some of these harmful chemicals escaping into the working environment.
- the hooding system at the level of the electrolytic cell comprises an arrangement of movable hood panels, which are typically disposed on an elongated frame which extends substantially parallel to each of the two parallel lines of anodes.
- This frame supports two fixed end walls, located at the opposite extremities of the anodes line, and facing the front side of the anodes, several panels (so-called “hood panels”) are provided between these end walls.
- hood panels are typically shaped such as to ensure an optimal protection and tightness. They also act as heat shields, thereby limiting thermal losses of the electrolytic cell and protecting the workers.
- the hood panels can be removed, as needed, to gain access to the anode hangers.
- anode assembly replacement (this operation is more conventionally called “anode change", and this expression will be used in the following) is usually carried out using a so-called pot tending machine and a floor operator.
- anode change a number of individual operations need to be carried out, starting with the removal of at least one of the pot hood panels (and more frequently, of two adjacent hood panels) in order to access to the anode assembly to be removed.
- the removal of the anode assembly is also done by the pot tending machine which is controlled by an operator.
- the preparatory operation prior to this is to break the solidified electrolyte/vapours/alumina crust used to conserve heat and prevent air access to the anode carbon surface that is not immersed in the electrolyte.
- the actual removal operation of the spent anode assembly involves unfastening the clamps by which the anode rod is fixed to the height adjustable anode beam, vertical lifting of the spent anode assembly, and positioning of the removed anode assembly on the floor level (usually in a pallet).
- Good work practice usually then requires cleaning the cavity of the crust of solidified electrolyte that has entered the electrolyte by using a cavity scoop.
- the new anode assembly is inserted into the cavity, fixed to the anode beam and precisely positioned; in particular, the anode bottom needs to be positioned at a given height for accurate control of the anode-cathode distance.
- the hood panel/s is/are put in place (possibly after having been inspected, or another hood panel in good condition is used).
- This procedure invariably takes between ten and twenty minutes. As noxious gases may escape from the pot when the hood is open, it is desirable to minimize both the time during which the hood is open and the presence of a floor operator.
- Pot tending machines have been available for many years, manufactured by ECL (Fives group) or Noell-NKM (REEL group). Their basic function is to carry the anode assembly during an operation known as anode beam raising. Since the carbon anodes are gradually consumed during the electrolysis process, the anode beam, which is holding all the anodes in position, has to be lowered gradually in order to maintain a constant anode-cathode distance. Eventually, the position of the anode beam reaches a physical lower limit. At this point, the anode beam has to be raised by use of a special anode-beam raising equipment (ABRE) carried by the pot-tending machine.
- ABRE anode-beam raising equipment
- the anode rods remain in electrical contact with the anode-beam although they are mechanically disconnected (anode connectors loosened) from the anode beam while the anode beam is raised sliding against the anode rods to maintain the electrical contact.
- the anodes are hold in position by said ABRE, which presses the anode rods against the anode beam to maintain the electrical contact.
- Modern pot tending machines have several additional functions. They can be combined with the overhead travelling crane (also called bridge crane), and a cabin for the PTM operator. They can also be used for carrying the crucible during the tapping procedure.
- the lifting power of modern pot tending machines is usually in excess of 25 metric tons, and more frequently in excess of 35 or 40 metric tons, especially when they are designed for tapping.
- Anode changing devices also exist mounted on dedicated ground vehicles; these are usually specifically designed trucks. Such anode changing vehicles are offered for sale by GLAMA company, as well as by HENCON and TECHMO. They may be too large to be usable in potlines having a very small distance between two neighboring electrolysis cells. Furthermore and more generally, it may be undesirable to use vehicles at the floor level between the electrolysis cells, and as a matter of policy, it may be deemed even more undesirable to use long metallic tools extending horizontally at the floor level between the electrolysis cells and the potroom building, as this implies electrical hazards.
- Pot tending machines integrated on an overhead crane are designed to avoid such electrical hazards. Pot tending machines that carry out specific tasks in the anode assembly replacement process in Hall-Heroult cells have been described in a large number of patent publications. These machines may have a variable degree of automatization.
- WO 2004/079046 and US 8,888,156 describe handling grippers for gripping anode rods prior to their transportation by a crane.
- WO 2004/101853 describes a tool for unlocking and locking the clamps by which the anode rod is fixed to the anode beam.
- US 8,066,856 describes a pneumatic impact generator that may improve the electrical contact between the anode rod and the anode beam when mounting the new anode assembly.
- WO 2005/095676 describes a service module for anode changing equipped with different tools that can be mounted on an overhead crane; this movable service module comprises a cabin for the operator.
- WO 2006/010816 and US 2007/0205104 describe further tools for such service modules.
- US 8,273,223 describes tools for handling hood panels.
- WO 2010/079266 describes a service module equipped with a crust shovel for cleaning the cavity during anode change; WO 2011/130892 and US 2012/0234690 disclose other designs for crust shovels.
- US 2008/0251392 describes a method for changing an anode, comprising a step of positioning the anode assembly replacing a spent anode assembly that can be automatized.
- WO 2006/030092 describes another such method that includes a device for measuring the vertical distances travelled by the tool using electromagnetic or acoustic waves.
- WO 2016/128631 and FR 3 032 457 disclose a pot tending machine comprising two separate service modules that can carry out different functions in parallel, which speeds up the anode changing process. All the patents mentioned in this paragraph are assigned to E.C.L.
- New ECL embedded service robot Towards an automated, efficient and green smelter
- J. Guérin and A.G. Hequet published in 2015 in Light Metals (TMS)
- p. 695-697 announces even a fully automatic anode change robot that no longer requires a crane operator.
- This new robot comprises a telescopic mast fixed to the overhead travelling crane, said mast bearing a plurality of individual tools, each being dedicated to an individual task.
- This system has a number of shortcomings. First of all, whether or not there is a floor operator, it is desirable to shorten the time interval during which the hood is open, in order to minimize the release of noxious gases into the atmosphere which would otherwise be sucked into the exhaust gas purification system. Secondly, the existing automatic or semi-automatic anode changing machines, while they do simplify the work of operators, take longer than conventional methods for changing an anode. And thirdly, all existing automatic or semi-automatic anode changing machines depend on the availability of an overhead travelling crane.
- the present invention presents a new anode servicing assembly for an aluminium electrolysis plant capable of changing anodes.
- Changing anodes is a rather complex procedure, referring to a certain number of individual operations, such as removing (and replacing) hood panels, unlocking (and locking) anode hooks, removing (and replacing) the anode assembly, vacuum cleaning, and so on.
- the term "servicing" as used herein refers to general servicing operations, and according to the invention, the anode servicing assembly can carry out one or more task related to anode change, and possibly additional task not related to anode change.
- Said anode servicing assembly comprises a crane beam and a specific servicing machine; said servicing machine comprises movable operating devices.
- the latter are capable of carrying out one or more individual operations carried out on individual anode assemblies (such as locking and unlocking anode hooks, and lifting used anode assemblies), and/or one or more individual operations carried out in relation with the change of individual anode assemblies (such as opening and closing anode hoods, and vacuum cleaning in the vicinity of the anode in the pot).
- the problem is solved by two independent means that can be combined.
- the anode servicing assembly is based on an additional, independent crane beam, adapted to move on the rails of the existing overhead travelling crane and/or on the rails of the existing pot tending machine (which may be all the same rails), but that is much lighter than conventional pot tending machines, because of dedicated, independent tools instead of complex multifunction service modules.
- a lifting force of less than about 20 tons, and preferably less than about 10 tons is sufficient for an anode servicing assembly according to the invention.
- the anode servicing assembly comprises a plurality of independent tools, each of which is mounted on a separate service module. This allows a total independence of the different tools, each of which is dedicated to a given function. This total independence may allow, in certain cases, that two or more tools are carrying out movements simultaneously, and may allow, in certain cases, that two or more tools are carrying out different functions simultaneously.
- a first object of the invention is an anode servicing assembly for an aluminium electrolysis plant, said aluminium electrolysis plant comprising at least one line (L1, L2) of electrolysis cells (C1-Cn, C'1-C'n) connected in series, each cell being connected to a cathodic busbar and each cell having a plurality of anode assemblies connected to an anode beam,
- At least one support assembly comprises at least one carrier movable with respect to said elongated body along said longitudinal axis (L31) of said body, said respective operating device being fixed with respect to said carrier, at least in translation.
- At least one support assembly comprises at least one carrier movable with respect to said elongated body along said longitudinal axis of said elongated body, as well as at least one drive member provided with driving means, adapted to move said operating device with respect to said carrier along said vertical axis (ZZ).
- At least one support assembly can comprise two carriers as well as two drive members, said driving means being adapted to move one single operating device with respect to said carriers along said vertical axis.
- Said elongated body can comprise at least one, and in particular at least two parallel rails, at least one rail being provided with at least one track for translation motion of at least one carrier.
- Said specific anode servicing function(s) is (are) advantageously chosen amongst: lifting a new anode, vacuum cleaning anode cover material surrounding and/or covering an anode, sawing solid crust material surrounding an anode, lifting of the spent anode, placing the new anode at specific height, adding anode cover material on and around an anode, recording images representative of the position and the shape of an anode, moving a hood panel giving access to an anode, and moving back the hood panels after completing the anode change.
- each operating device is inferior to 20 metric tons, preferably less than 15 metric tons, and even more preferably less than 10 metric tons.
- an anode servicing assembly comprises at least two so-called lifting operating devices, each being adapted for lifting a respective anode assembly.
- it may comprise (or further comprise) a so-called multi use operating device, said multi use operating device being provided with a head, said head being adapted to cooperate with
- a second object of the invention is an aluminium electrolysis plant comprising at least one line of electrolysis cells of substantially rectangular shape, said plant further comprising means for electrically connecting said cells in series and means for connecting the cathodic busbar of a cell to the anode beam of a downstream cell,
- This plant may further comprise at least one common running path usable by running means of said anode servicing assembly, adapted to cooperate with running means of the heavy lifting assembly and/or with the running means of said pot tending assembly, in particular two common running paths, provided on either side of said cells, with reference to transversal axis of said line.
- a third object of the invention is a method of operating an anode servicing assembly according to the present invention, said anode servicing assembly being in particular part of an aluminium electrolysis plant according to the invention, said operating method comprising:
- Said operating method can further comprise:
- Yet another object of the present invention is a method for making aluminium by the Hall-Héroult electrolysis process, characterized in that said method is carried out in an aluminium electrolysis plant according to the invention.
- Electrolytic cell prior art
- Second anode servicing assembly 40 Carrier for 45 41,42 Sidewalls of potshell 45 Hopper 50 Carrier for 55 55 Crust breaker 60 Carrier for 65 62 Platform for 65 65 Bucket shove
- the present invention is directed to the arrangement of a plant, also called aluminium smelting plant or aluminium smelter, using the Hall-Heroult process.
- This plant comprises a plurality of electrolysis cells (potline) connected in series.
- the Hall-Heroult process as such, the way to operate the latter, as well as the general structure of above electrolysis cells are known to a person skilled in the art and will not be described here.
- the terms “upper” and “lower” refer to mechanical elements in use, with respect to a horizontal working surface.
- conductive means “electrically conductive”.
- the aluminium smelter of the invention comprises a plurality of electrolytic cells, typically arranged along two parallel lines L1 and L2, each of which comprises n cells, i.e. C1 to Cn and C'1 to C'n.
- the electrolysis current therefore passes in a cascade fashion from one cell to the next cell, along arrow DC.
- the number of cells in a series is typically comprised between 50 and over 250, even over 400 in the most recent smelters, but this figure is not substantial for the present invention.
- the electrolytic cells are rectangular shaped and are arranged transversally (side by side), in reference of the line they constitute. In other words, the main dimension, or length, of each cell is substantially orthogonal to the main direction of the line, i.e. the circulation direction of current. The large sides of two adjacent cells are parallel.
- the electrolytic cells, or pots can implement various technological variants that do not form a part of the present invention; such pots are known to a person skilled in the art. On the figure 1 , only the contour of the external metal (steel) shell, or "potshell", of the cells is shown.
- a typical cell 1 includes a potshell comprising a first longitudinal sidewall 2, a second longitudinal sidewall 2', first and second transversal end walls (not visible on figure 1 ) and a bottom 4.
- the potshell walls define a space lined on its bottom and sides with refractory materials 3 (maintaining the thermal balance during the electrolysis process) along with the cathode blocks 8, thereby defining a volume containing the molten metal and electrolyte.
- the side lining 3 comprises a layer of carbonaceous material (not shown on the figures) protected in steady state operation by solid electrolyte in contact with molten liquid material.
- Said cathode blocks 8 comprise one or more cathode collector bars 9. They protrude out of the potshell.
- Anode assemblies 5 are also provided, each comprising an anode rod 6 and an anode 7. Electrical current enters the cell through anodes 7 (suspended above the cell by anode rods 6 attached to an aluminium beam called anode beam, which is supported by the cell superstructure 10 ), passes through the molten electrolytic bath 11 and the molten aluminium pad 12, and then enters the carbon cathode block 8. The current is carried out of the cell by the cathode collector bar 9 connected to the cathode busbar not shown on figure 2 .
- the cell 1 is closed by a set of hood panels 13. In a way known as such, clamps 14, which are schematically represented, ensure removable fixing of anode rods to anode beam.
- each cell of the plant has the same structure.
- Two sheds 16,16' are also provided, each covering a respective line. On figure 1 , these sheds are illustrated in phantom lines. As shown on figures 3 and 4 , said shed 16,16' comprises sidewalls 17,18 as well as top walls 19. The shed 16,16' can be open or closed, at one or both longitudinal ends. With reference to these figures, each cell is arranged so as to leave running paths 20, 21 on internal faces of side walls 17,18 of said shed 16,16'. These paths allow the displacement of anode servicing assemblies along main axis of each line, as will be explained here after. Each path is provided with appropriate means, such as rails, for cooperating with complementary means of anode servicing assembly, such as wheels.
- the anode servicing assembly advantageously uses the same running paths as the heavy lifting assembly and/or the pot tending assembly.
- the heavy lifting machine When the heavy lifting machine is not needed, it does not stay in the line but (usually) in the pot repair area (not shown on the figures), from where it is moved into the pot line with a transboarding machine (not shown on the figures) generally located in the central passage.
- a plant according to the invention is provided with a pot tending assembly 25, schematically shown on figure 3 .
- the latter comprises an elongated body 26, such as a beam, which is equipped with above-mentioned complementarity means, so as to run along above-described paths.
- said pot tending assembly is provided with a so called pot tending machine 27.
- this lifting machine is adapted to carry out the function of raising an anode beam. In this respect, the lifting power of this lifting machine is sufficient to fulfil this lifting.
- this lifting machine is not adapted to fulfil some other functions, such as replacing a spent anode assembly by a new anode assembly; adding a specific anode changing machine to the pot tending machine is possible, but will add unnecessary cost, and will not provide sufficient flexibility of use.
- a plant according to the invention is usually also provided with a heavy lifting assembly (not shown on the figures), which comprises an elongated body, such as a beam, which is equipped with above-mentioned complementarity means, so as to run along above-described paths.
- said heavy lifting assembly is provided with a so called heavy lifting machine which, in a way known as such, is adapted to carry out the function of lifting a potshell and lifting a superstructure.
- the lifting power of this lifting machine is sufficient to fulfil this lifting.
- this heavy lifting machine is not adapted to fulfil some other functions, such as pot tending functions (such as raising anode beams) or anode servicing functions.
- a plant according to the invention is also provided with at least one so called anode servicing assembly.
- anode servicing assembly schematically shown on figure 4 , comprises an elongated body 31, such as a beam, which is equipped with above-mentioned complementarity means, so as to run along above described paths.
- said anode servicing assembly 30,35 is provided with a so called anode servicing machine 32.
- the present invention is directed to said anode servicing assembly 30,35, and to said anode servicing machine 32.
- This machine 32 is provided with several operating devices, which will be described more in detail hereafter. These operating devices are adapted to carry out a specific anode servicing function, such as replacing a spent anode assembly by a new anode assembly. These operating devices are not adapted to carry out the lifting of a cell or the raising of an anode beam. In this respect, the lifting power of each operating device is not sufficient to fulfil this lifting. Typically the lifting power of each of those operating devices is inferior to 20 metric tons, and can be inferior to 10 metric tons. This will simplify its structure.
- the heavy lifting machine is adapted to fulfil certain functions, such as lifting a whole cell, and a superstructure which cannot be fulfilled by the anode servicing machine 32 because the latter does not have enough lifting power.
- the pot tending machine is adapted to fulfil certain pot tending operations, which cannot be carried out by the anode servicing machine 32 because the latter does not have enough lifting power.
- the anode servicing machine 32 is adapted to fulfil at least one so called distinctive function, such as automatically (i.e. without a human operator) replacing a spent anode assembly, which cannot be fulfilled automatically by a pot tending machine.
- the heavy lifting machine of the heavy lifting assembly is not adapted to replace a spent anode assembly by a new one, because it is lacking specific tools.
- each line of the plant with a plurality of anode servicing assemblies, depending of the number of cells to be served.
- a first anode servicing assembly 30, 30' and a second anode servicing assembly 35, 35' are shown to allow changing anodes simultaneously on different cells of the same line of cells.
- the pot tending assembly 25, 25' faces one first given cell Ci, C'i located close to the rectifier end of the line on said figure.
- said pot tending assembly may be positioned between two neighboring cells.
- this pot tending assembly may carry out a first type of operation on said cell(s), such as a lifting of the latter.
- all the other cells may be dealt by the two anode servicing assemblies. Indeed top cells C1 to Ci-1, C'1 to C'i-1 may be dealt by first anode servicing assembly 35,35', whereas bottom cells Ci+1 to Cn, C'i+1 to C'n may be dealt by second anode servicing assembly 30,30'.
- pot tending assembly 25,25' has moved from its position of figure 5 , so as to face one second given cell Cj, C'j located close to the non-rectifier end of the line on said figure.
- all the other cells still may be dealt by the two anode servicing assemblies. Indeed top cells C1 to Cj-1 C'1 to C'j-1 may be dealt by first anode servicing assembly 35,35', whereas bottom cells Cj+1 to Cn, C'j+1 to C'n may be dealt by second anode servicing assembly 30,30'.
- the first and second anode servicing assemblies 30, 30', 35 35' may carry out servicing operations on cells, which may be the same servicing operations or different servicing operations. In particular, they may proceed to the change of the spent anode, so as to replace it by a new one.
- an anode servicing machine capable of such a replacement, will now be given.
- Elongated body 31 of said anode servicing machine 30 comprises in particular two parallel rails 33,33', extending along transversal axis YY. As a consequence, this axis is coincident with a so-called main axis L31 of elongated body 31, which is shown in particular on figure 8 .
- each rail 33,33' has opposite top and bottom walls, as well as opposite inner and outer walls. So-called inner wall of one rail faces the other rail.
- Tracks 34, 34', 34" are provided on at least one side wall of at least one rail. Said track, the structure of which is of any appropriate type, permits the displacement of carriers which will be described here under.
- both inner and outer walls of first rail are provided with respective tracks, whereas outer wall of second rail is provided with a respective track.
- each track 34,34',34" cooperates with at least one carrier 40,50,60,70,80,81,90,91 which is mounted on this track.
- Said carrier is mobile on said track, along main axis L31 of the elongated body 31.
- said carrier is equipped with appropriate running means, such as rolling means.
- Each carrier 40,50,60,70,80,81,90,91 is adapted to support one or more operating devices 45,55,65,75,85,95.
- two carriers 90,91 are provided on outer wall of first rail 33, three more carriers 40,50,70 are provided on inner wall of first rail 33, whereas three further more carriers 60,80,81 are provided on outer wall of second rail 33'.
- Said carriers may cooperate with the above-mentioned operating devices, in two distinct modes.
- a first mode one carrier may directly form a support assembly for a respective operating device.
- a given operating device is immobilized, at least in translation, with respect to said carrier.
- said operating devices 45,55 are independently movable, along only longitudinal axis L31 of the elongated body 31.
- some carriers may support operating devices while allowing a further displacement of the latter.
- an intermediate platform is fixed on said carrier, said platform permitting the movement of device along the vertical axis ZZ; this axis is shown on Figure 9 .
- said platform is equipped with appropriate driving means, such as a servo motor.
- a support assembly is then formed by said carrier and said platform.
- single carrier 60 cooperates with single platform 62 which in turn supports an operating device, which is a bucket shovel 65.
- single carrier 70 cooperates with single platform 72 which in turn supports an operating device, which is a first robot 75, the structure of which will be described in further detail below.
- two different carriers may be provided for one single operating device, in particular in case the latter is heavy and or has great dimensions.
- two carriers 80 and 81 support two respective platforms 82 and 83, on which a first lifting robot 85 is mounted.
- two more carriers 90 and 91 support two respective platforms 92 and 93, on which a second lifting robot 95 is mounted.
- Lifting robots 85 and 95 are typically adapted to lift an anode, in a way known as such.
- said operating devices 65, 75, 85, 95 are independently movable, along not only longitudinal axis L31 of the elongated body 31, but also vertical axis ZZ.
- this robot 75 first comprises, starting from platform 72, a deck 750 which is pivotably mounted on this platform around a vertical axis. Furthermore three successive arms are provided, namely a proximal arm 752 pivotably mounted on deck 750 around horizontal axis A752, an intermediate arm 753 pivotably mounted on arm 752 around horizontal axis A753, as well as a distal arm 754 pivotably mounted on arm 753 around horizontal axis A754.
- a rotator 756 is further pivotably mounted on distal arm around longitudinal axis L754 of said arm.
- Said rotator is provided with a multi-use head 758, which is pivotably mounted around horizontal axis A758. As illustrated in particular on figures 13 and 14 , this head is adapted to detachably receive specific tools 77, 78 and 79 which will be further described. In particular these tools may be detachably fixed on platform 72. Moreover, this head 758 is provided with a camera 76, which is of any appropriate type, in particular of the 3D type. Contrary to tools 77 to 79, this camera is preferably attached to this head in a permanent way.
- FIG. 10 illustrates end cell C1, as well as a group RG of replacement anode assemblies which are gathered in the vicinity of this cell C1. Then said anode servicing assembly 30 moves to the group of replacement anode assemblies, by running along paths 20, 21 which are shown on figures 3 and 4 .
- Figure 10 shows rail 33 of anode servicing assembly 30, one 20 of these running paths, as well as robots 75 and 85.
- the 3-D camera 76 first localizes the position of the replacement anode rod 6R (see capture 76A). Then the lifting robot 85 is moved so as, first to pick up the replacement anode assembly, and then lift this picked up assembly as shown on Figure 11 (see arrow L1). Once this replacement anode assembly has been lifted, the 3-D camera determines the position of this replacement anode (see capture 76B). After this determination step the anode servicing assembly 30, which carries the replacement anode assembly 5R, is driven back along the paths (see arrow F30 on this figure 11 ) until it reaches the location of the spent anode.
- Robot 75 is then moved, so as to equip its head 758 with a U shaped gripper 77 (see figure 12 ).
- This gripper 77 which is detachably fixed on platform 72 (see in particular Figure 14 which shows this gripper on this platform), is adapted to cooperate with the hood panels 13.
- each anode assembly of a given cell is associated with two adjacent hoods panels, i.e. it is necessary to remove two adjacent hood panels to access to a given anode assembly.
- the spent anode assembly 5U is associated with hood panels 13A and 13B.
- the camera 76 first localizes right hood panel 13A, and thereafter gripper 77 lifts said hood panel and places it onto neighboring hood noted 13C as shown on this figure 12 .
- the same operation (not shown on this figure 12 ) is carried out on the left hood panel 13B, which is localized, gripped and then placed onto neighboring hood panel 13D.
- Robot 75 is then moved, so as to release back the gripper 77 on platform.
- Head 758 is then equipped with above described nozzle 55.
- This nozzle makes it possible to aspirate hot material (crushed bath and alumina mixture) called hereafter ACRM (Anode Cover Recycled Material), from the vicinity of spent anode along arrow F55. This step is illustrated on figure 13 . Said nozzle is then placed back on its carrier 50.
- 3-D camera 76 determines then the position of this spent anode, as shown on Figure 16 (see capture 76C).
- Said figure 16 illustrates, on the one hand lifting robot 85 and replacement anode assembly 5R, on the other hand lifting robot 95 and spent anode assembly 5U. It shall be noted that providing two distinct lifting robots 85, 95 brings about specific advantages. Indeed it makes it possible to operate two anode assemblies at the same time, without moving anode servicing assembly between spent anode assembly and the group of replacement anode assemblies. This makes it possible to save time, for what concerns the global processing of the plant.
- Said camera 76 also checks the shape of spent anode assembly 5U as well as the position of the pot opening PO, created by the removal of hood panels 13A and 13B.
- FIG 17 only first removed panel 13A is illustrated above panel 13C, bearing in mind that other removed panel 13B is placed above panel 13D.
- Replacement anode assembly 5R is then put in place, into the above-mentioned pot opening. This step is illustrated on Figure 17 , the arrow D showing the downwards motion of both robot 85 and replacement anode assembly 5R.
- the final position of said replacement anode is adjusted on the basis of images, which have been captured by the above camera 76 as above described.
- Clamp 14R is locked by a tool 86, analogous to that 96, which is provided on robot 85.
- multi use head 758 of robot 75 grasps then the above described nozzle 55.
- the latter contains a quantity of recycled hot ACRM, which is poured at the vicinity of replacement anode along arrow f55.
- some cold ACRM is further poured on top of above poured ACRM, until right thickness is reached (said step is not illustrated).
- This further quantity of ACRM is fed to nozzle 55, from hopper 45.
- multi-use head of robot 75 places back hood panels 13A and 13B in their original position, so as to close pot opening PO.
- Camera 76 checks then that the new anode is situated at the right height.
- multi-use head grasp tool 79 which is adapted to measure the current intensity and to determine proper anode settings.
- anode servicing assembly which comprises a camera configured to determine and control the anode height is particularly advantageous.
- Prior art devices use either external reference systems or laser height measurement devices.
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- Chemical Kinetics & Catalysis (AREA)
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- Electrolytic Production Of Metals (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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EP22178734.4A EP4293141A1 (de) | 2022-06-13 | 2022-06-13 | Anodenwartungsanordnung für eine aluminium-elektrolyseanlage und verfahren zum betreiben dafür |
PCT/IB2023/056086 WO2023242730A1 (en) | 2022-06-13 | 2023-06-13 | Anode servicing assembly for an aluminium electrolysis plant, and methods for operating the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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EP22178734.4A EP4293141A1 (de) | 2022-06-13 | 2022-06-13 | Anodenwartungsanordnung für eine aluminium-elektrolyseanlage und verfahren zum betreiben dafür |
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EP4293141A1 true EP4293141A1 (de) | 2023-12-20 |
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EP22178734.4A Pending EP4293141A1 (de) | 2022-06-13 | 2022-06-13 | Anodenwartungsanordnung für eine aluminium-elektrolyseanlage und verfahren zum betreiben dafür |
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EP (1) | EP4293141A1 (de) |
WO (1) | WO2023242730A1 (de) |
Citations (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2013244A (en) * | 1977-12-22 | 1979-08-08 | Ardal Og Sunndal Verk | Transporting pots for aluminium production |
WO2004079046A2 (fr) | 2003-02-28 | 2004-09-16 | E.C.L | Pince de manutention d'une machine de service de cellules d'electrolyse pour la production d'aluminium |
WO2004101853A2 (fr) | 2003-05-12 | 2004-11-25 | E.C.L. | Organe de manutention de connecteurs d’electrode de cellules d'electrolyse destinees a la production d'aluminium |
WO2005095676A2 (fr) | 2004-03-25 | 2005-10-13 | E.C.L | Module de service compact destine aux usines de production d'aluminium par electrolyse |
WO2006010816A2 (fr) | 2004-06-25 | 2006-02-02 | E.C.L. | Module de service compact destiné aux usines de production d'aluminium par électrolyse |
WO2006030092A2 (fr) | 2004-09-08 | 2006-03-23 | E.C.L. | Procédé de changement d'anode dans une cellule de production d'aluminium par électrolyse incluant un ajustement de la position de l'anode et dispositif pour le mettre en oeuvre |
US20070205104A1 (en) | 2006-03-03 | 2007-09-06 | E.C.L. | Remote controllable pot tending module for use in aluminum production plants |
US20080251392A1 (en) | 2004-10-14 | 2008-10-16 | E.C.L. | Process For Changing an Anode In an Electrolytic Aluminium Production Cell Including Adjustment of the Position of the Anode and Pot Tending Machine For Implementing It |
WO2010079266A1 (fr) | 2009-01-08 | 2010-07-15 | E.C.L. | Dispositif d'attache de recipients pour collecter des debris solides et pivotant a l'extremite d'un bras mobile, en particulier dispositif d'attache des godets articules d'une pelle a croute |
US20110194916A1 (en) * | 2008-10-16 | 2011-08-11 | E.C.L. | Pot tending machine for working on electrolysis cells for the production of aluminum by igneous electrolysis |
WO2011130892A1 (zh) | 2010-04-23 | 2011-10-27 | 苏州东方楷模医药科技有限公司 | 治疗流感的中药组合物及其制备方法和应用 |
US8066856B2 (en) | 2007-03-23 | 2011-11-29 | E.C.L. | Service module with at least one anode clamp and means for applying a force or a shock on the anode rod |
US20120234690A1 (en) | 2009-12-11 | 2012-09-20 | E.C.L. | Device designed for collecting solid debris in an electrolysis cell for the production of aluminium |
US8273223B2 (en) | 2004-12-21 | 2012-09-25 | E.C.L. | Handling device for hoods of a cell for electrolytic aluminium production |
US8888156B2 (en) | 2010-09-08 | 2014-11-18 | E.C.L. | Handling tool, for secure handling of connectors of electrolysis cells intended for aluminium production |
WO2015132479A2 (fr) | 2014-03-05 | 2015-09-11 | E.C.L. | Système pour la réalisation d'opérations liées à l'exploitation de cellules d'une installation de production d'aluminium par électrolyse |
FR3032457A1 (fr) | 2015-02-09 | 2016-08-12 | Ecl | Module de service pour l'exploitation d'une installation de production d'aluminium |
WO2016128631A1 (fr) | 2015-02-09 | 2016-08-18 | Fives Ecl | Installation de production d'aluminium par électrolyse ignée |
EP3084331A1 (de) * | 2013-12-17 | 2016-10-26 | Fives Ecl | Wagen und maschine zum betrieb eines ofens in einer anodenbefeuerungsanlage |
US20220136120A1 (en) * | 2019-03-14 | 2022-05-05 | Rio Tinto Alcan International Limited | Intervention tool for the operation of an electrolytic cell |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE60300977T2 (de) * | 2003-01-31 | 2006-04-20 | E.C.L. | Bedienungsmaschine für Elektrolysezellen bei der Aluminiumproduktion |
CN110528028B (zh) * | 2019-09-02 | 2023-10-24 | 益阳鸿源稀土有限责任公司 | 一种稀土电解槽母线抬升***及母线抬升方法 |
CN114045532A (zh) * | 2021-12-01 | 2022-02-15 | 贵阳铝镁设计研究院有限公司 | 一种铝电解多功能机组双阳极同步升降装置 |
-
2022
- 2022-06-13 EP EP22178734.4A patent/EP4293141A1/de active Pending
-
2023
- 2023-06-13 WO PCT/IB2023/056086 patent/WO2023242730A1/en unknown
Patent Citations (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2013244A (en) * | 1977-12-22 | 1979-08-08 | Ardal Og Sunndal Verk | Transporting pots for aluminium production |
WO2004079046A2 (fr) | 2003-02-28 | 2004-09-16 | E.C.L | Pince de manutention d'une machine de service de cellules d'electrolyse pour la production d'aluminium |
WO2004101853A2 (fr) | 2003-05-12 | 2004-11-25 | E.C.L. | Organe de manutention de connecteurs d’electrode de cellules d'electrolyse destinees a la production d'aluminium |
WO2005095676A2 (fr) | 2004-03-25 | 2005-10-13 | E.C.L | Module de service compact destine aux usines de production d'aluminium par electrolyse |
WO2006010816A2 (fr) | 2004-06-25 | 2006-02-02 | E.C.L. | Module de service compact destiné aux usines de production d'aluminium par électrolyse |
WO2006030092A2 (fr) | 2004-09-08 | 2006-03-23 | E.C.L. | Procédé de changement d'anode dans une cellule de production d'aluminium par électrolyse incluant un ajustement de la position de l'anode et dispositif pour le mettre en oeuvre |
US20080251392A1 (en) | 2004-10-14 | 2008-10-16 | E.C.L. | Process For Changing an Anode In an Electrolytic Aluminium Production Cell Including Adjustment of the Position of the Anode and Pot Tending Machine For Implementing It |
US8273223B2 (en) | 2004-12-21 | 2012-09-25 | E.C.L. | Handling device for hoods of a cell for electrolytic aluminium production |
US20070205104A1 (en) | 2006-03-03 | 2007-09-06 | E.C.L. | Remote controllable pot tending module for use in aluminum production plants |
US8066856B2 (en) | 2007-03-23 | 2011-11-29 | E.C.L. | Service module with at least one anode clamp and means for applying a force or a shock on the anode rod |
US20110194916A1 (en) * | 2008-10-16 | 2011-08-11 | E.C.L. | Pot tending machine for working on electrolysis cells for the production of aluminum by igneous electrolysis |
WO2010079266A1 (fr) | 2009-01-08 | 2010-07-15 | E.C.L. | Dispositif d'attache de recipients pour collecter des debris solides et pivotant a l'extremite d'un bras mobile, en particulier dispositif d'attache des godets articules d'une pelle a croute |
US20120234690A1 (en) | 2009-12-11 | 2012-09-20 | E.C.L. | Device designed for collecting solid debris in an electrolysis cell for the production of aluminium |
WO2011130892A1 (zh) | 2010-04-23 | 2011-10-27 | 苏州东方楷模医药科技有限公司 | 治疗流感的中药组合物及其制备方法和应用 |
US8888156B2 (en) | 2010-09-08 | 2014-11-18 | E.C.L. | Handling tool, for secure handling of connectors of electrolysis cells intended for aluminium production |
EP3084331A1 (de) * | 2013-12-17 | 2016-10-26 | Fives Ecl | Wagen und maschine zum betrieb eines ofens in einer anodenbefeuerungsanlage |
WO2015132479A2 (fr) | 2014-03-05 | 2015-09-11 | E.C.L. | Système pour la réalisation d'opérations liées à l'exploitation de cellules d'une installation de production d'aluminium par électrolyse |
FR3032457A1 (fr) | 2015-02-09 | 2016-08-12 | Ecl | Module de service pour l'exploitation d'une installation de production d'aluminium |
WO2016128631A1 (fr) | 2015-02-09 | 2016-08-18 | Fives Ecl | Installation de production d'aluminium par électrolyse ignée |
US20220136120A1 (en) * | 2019-03-14 | 2022-05-05 | Rio Tinto Alcan International Limited | Intervention tool for the operation of an electrolytic cell |
Non-Patent Citations (2)
Title |
---|
J. GUERINA.G. HEQUET: "New ECL embedded service robot: Towards an automated, efficient and green smelter", LIGHT METALS (TMS, 2015, pages 695 - 697 |
N. DUPAS: "''Electrolysis pots anode changing automation: impact on process and safety performance", LIGHT METALS, 2009, pages 515 - 518 |
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