EP4069002A1 - Aerosol-generating element comprising a filter with a high content of a polyhydroxyalkanoate polymer or copolymer - Google Patents
Aerosol-generating element comprising a filter with a high content of a polyhydroxyalkanoate polymer or copolymerInfo
- Publication number
- EP4069002A1 EP4069002A1 EP20811356.3A EP20811356A EP4069002A1 EP 4069002 A1 EP4069002 A1 EP 4069002A1 EP 20811356 A EP20811356 A EP 20811356A EP 4069002 A1 EP4069002 A1 EP 4069002A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- aerosol
- filter segment
- pha
- millimetres
- generating article
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 title claims abstract description 151
- 229920000642 polymer Polymers 0.000 title claims abstract description 49
- 229920001577 copolymer Polymers 0.000 title claims abstract description 47
- 229920000903 polyhydroxyalkanoate Polymers 0.000 title description 144
- 239000000463 material Substances 0.000 claims abstract description 108
- 239000000758 substrate Substances 0.000 claims abstract description 81
- 238000001914 filtration Methods 0.000 claims abstract description 79
- 239000000443 aerosol Substances 0.000 claims abstract description 74
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- 229920002301 cellulose acetate Polymers 0.000 claims description 65
- 239000000203 mixture Substances 0.000 claims description 13
- 229920002988 biodegradable polymer Polymers 0.000 claims description 10
- 239000004621 biodegradable polymer Substances 0.000 claims description 10
- 239000004631 polybutylene succinate Substances 0.000 claims description 9
- 229920002961 polybutylene succinate Polymers 0.000 claims description 9
- 229920001896 polybutyrate Polymers 0.000 claims description 9
- -1 polybutylene succinate Polymers 0.000 claims description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 7
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 7
- 229920001610 polycaprolactone Polymers 0.000 claims description 6
- 239000004632 polycaprolactone Substances 0.000 claims description 6
- 229920002472 Starch Polymers 0.000 claims description 5
- 235000019698 starch Nutrition 0.000 claims description 5
- 229920008262 Thermoplastic starch Polymers 0.000 claims description 4
- 229920001222 biopolymer Polymers 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 239000004628 starch-based polymer Substances 0.000 claims description 4
- 229920001282 polysaccharide Polymers 0.000 claims description 3
- 239000005017 polysaccharide Substances 0.000 claims description 3
- 229920002101 Chitin Polymers 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 229920000297 Rayon Polymers 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920002643 polyglutamic acid Polymers 0.000 claims description 2
- 102000004169 proteins and genes Human genes 0.000 claims description 2
- 108090000623 proteins and genes Proteins 0.000 claims description 2
- 239000004627 regenerated cellulose Substances 0.000 claims description 2
- 238000006467 substitution reaction Methods 0.000 claims description 2
- 150000004676 glycans Chemical class 0.000 claims 1
- 241000208125 Nicotiana Species 0.000 description 41
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 41
- 239000000779 smoke Substances 0.000 description 25
- 230000000391 smoking effect Effects 0.000 description 21
- 238000001816 cooling Methods 0.000 description 19
- 238000012360 testing method Methods 0.000 description 18
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 12
- 238000011144 upstream manufacturing Methods 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 238000002074 melt spinning Methods 0.000 description 9
- 238000010521 absorption reaction Methods 0.000 description 8
- 239000000654 additive Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 208000037534 Progressive hemifacial atrophy Diseases 0.000 description 7
- 235000019504 cigarettes Nutrition 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000012017 passive hemagglutination assay Methods 0.000 description 7
- 239000000523 sample Substances 0.000 description 7
- 238000012546 transfer Methods 0.000 description 7
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 6
- 239000001087 glyceryl triacetate Substances 0.000 description 6
- 235000013773 glyceryl triacetate Nutrition 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 238000009987 spinning Methods 0.000 description 6
- 229960002622 triacetin Drugs 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000000796 flavoring agent Substances 0.000 description 5
- 150000002989 phenols Chemical class 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 3
- 238000006065 biodegradation reaction Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- 229920000218 poly(hydroxyvalerate) Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000004537 pulping Methods 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- OVOUKWFJRHALDD-UHFFFAOYSA-N 2-[2-(2-acetyloxyethoxy)ethoxy]ethyl acetate Chemical compound CC(=O)OCCOCCOCCOC(C)=O OVOUKWFJRHALDD-UHFFFAOYSA-N 0.000 description 2
- 229920002522 Wood fibre Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000005030 aluminium foil Substances 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000000994 depressogenic effect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- ZDJFDFNNEAPGOP-UHFFFAOYSA-N dimethyl tetradecanedioate Chemical compound COC(=O)CCCCCCCCCCCCC(=O)OC ZDJFDFNNEAPGOP-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 235000010981 methylcellulose Nutrition 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000004626 polylactic acid Substances 0.000 description 2
- 150000004804 polysaccharides Chemical class 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 1
- 229920000331 Polyhydroxybutyrate Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- IZMOTZDBVPMOFE-UHFFFAOYSA-N dimethyl dodecanedioate Chemical compound COC(=O)CCCCCCCCCCC(=O)OC IZMOTZDBVPMOFE-UHFFFAOYSA-N 0.000 description 1
- 238000012377 drug delivery Methods 0.000 description 1
- 238000001523 electrospinning Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000001891 gel spinning Methods 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229920013819 hydroxyethyl ethylcellulose Polymers 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 210000003000 inclusion body Anatomy 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 239000005015 poly(hydroxybutyrate) Substances 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920000070 poly-3-hydroxybutyrate Polymers 0.000 description 1
- 229920002792 polyhydroxyhexanoate Polymers 0.000 description 1
- 229920002795 polyhydroxyoctanoate Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/062—Use of materials for tobacco smoke filters characterised by structural features
- A24D3/063—Use of materials for tobacco smoke filters characterised by structural features of the fibers
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/04—Cigars; Cigarettes with mouthpieces or filter-tips
- A24D1/045—Cigars; Cigarettes with mouthpieces or filter-tips with smoke filter means
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/20—Cigarettes specially adapted for simulated smoking devices
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/067—Use of materials for tobacco smoke filters characterised by functional properties
- A24D3/068—Biodegradable or disintegrable
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/17—Filters specially adapted for simulated smoking devices
Definitions
- AEROSOL-GENERATING ELEMENT COMPRISING A FILTER WITH A HIGH CONTENT OF A POLYHYDROXYALKANOATE POLYMER OR COPOLYMER
- the present invention relates to a filter for an aerosol-generating article and to an aerosol-generating article comprising the filter.
- the present invention further relates to an aerosol-generating system comprising an aerosol-generating device and one such aerosol generating article.
- Conventional aerosol-generating articles such as filter cigarettes, typically comprise a cylindrical rod of tobacco cut filler surrounded by a paper wrapper and a cylindrical filter axially aligned, most often in an abutting end-to-end relationship, with the wrapped tobacco rod.
- the cylindrical filter typically comprises one or more plugs of a fibrous filtration material, such as cellulose acetate tow, circumscribed by a paper plug wrap.
- the wrapped tobacco rod and the filter are joined by a band of tipping wrapper, normally formed of an opaque paper material that circumscribes the entire length of the filter and an adjacent portion of the wrapped tobacco rod.
- Aerosol-generating articles in which an aerosol-generating substrate, such as a tobacco- containing substrate, is heated rather than combusted, are also known in the art. Typically in such articles an aerosol is generated by the transfer of heat from a heat source to a physically separate aerosol-generating substrate or material.
- aerosol-generating articles have been proposed wherein an aerosol is generated by electrical heating of an aerosol-generating substrate.
- a number of prior art documents disclose aerosol-generating devices for consuming aerosol-generating articles. Such devices include, for example, electrically heated aerosol-generating devices in which an aerosol is generated by the transfer of heat from one or more electrical heater elements of the aerosol-generating device to the aerosol-generating substrate of a heated aerosol-generating article.
- aerosol-generating articles are also known wherein an aerosol is generated by the transfer of heat from a combustible fuel element or heat source to an aerosol-generating substrate.
- the combustible fuel element or heat source may be located in contact with, within, around, or downstream of the aerosol-generating substrate.
- volatile compounds are released from the aerosol-generating substrate by heat transfer and are entrained in air drawn through the aerosol-generating article. As the released compounds cool, they condense to form an aerosol.
- aerosol-generating articles of the types described may include a mouthpiece comprising a filter segment formed of porous filtration material such as cellulose acetate.
- a hollow tubular segment formed of a filtration material such as cellulose acetate is provided at a location between the aerosol-generating substrate and the mouth end of the article to impart structural strength to the article.
- any component of the article comprising filtration material may break down as quickly as possible.
- cellulose acetate, and many other commonly used filtration materials are not highly biodegradable.
- alternative dispersible or biodegradable materials are often not able to provide an acceptable filtration efficiency and smoking experience for the consumer.
- many known dispersible and degradable materials are unsuitable for use in the existing manufacturing processes, and would require too significant a modification of the existing methods and equipment to make their use commercially feasible.
- cellulose acetate has been found to provide a relatively high level of adsorption and trapping of water from the mainstream smoke when used in conventional smoking articles.
- the mainstream smoke delivered to the consumer therefore has a significantly reduced moisture content and may, under certain conditions, be perceived as undesirably ‘dry’. This may have an adverse effect on the overall smoking experience.
- the present disclosure relates to an aerosol-generating article for producing an inhalable aerosol upon heating.
- the aerosol-generating article may comprise a rod of aerosol generating substrate and a filter segment formed of fibrous filtration material.
- the filter segment may be arranged in longitudinal alignment with the rod.
- the filter segment may comprise at least about 85 percent by weight based on the total weight of fibrous filtration material of a polyhydroxyalkanoate (PHA) polymer or copolymer.
- PHA polyhydroxyalkanoate
- the present disclosure relates to a filter for an aerosol-generating article.
- the filter may comprise a filter segment formed of fibrous filtration material.
- the filter segment may comprise at least about 85 percent by weight based on the total weight of fibrous filtration material of fibres comprising a polyhydroxyalkanoate PHA polymer or copolymer.
- the present disclosure relates to a system comprising an aerosol-generating device and an aerosol-generating article for use with the aerosol-generating device.
- the aerosol-generating article may comprise a rod of aerosol-generating substrate and a filter segment formed of fibrous filtration material.
- the filter segment may be arranged in longitudinal alignment with the rod.
- the filter segment may comprise at least about 85 percent by weight based on the total weight of fibrous filtration material of a polyhydroxyalkanoate (PHA) polymer or copolymer.
- PHA polyhydroxyalkanoate
- an aerosol-generating article for producing an inhalable aerosol upon heating, the aerosol-generating article comprising: a rod of aerosol-generating substrate; a filter segment formed of fibrous filtration material, the filter segment arranged in longitudinal alignment with the rod; wherein the filter segment comprises at least about 85 percent by weight based on the total weight of fibrous filtration material of a PHA polymer or copolymer.
- a filter for an aerosol generating article comprising a filter segment formed of fibrous filtration material, wherein the filter segment comprises at least about 85 percent by weight based on the total weight of fibrous filtration material of a PHA polymer or copolymer.
- the term “longitudinal” refers to the direction corresponding to the main longitudinal axis of the aerosol-generating article, which extends between the upstream and downstream ends of the aerosol-generating article.
- the terms “upstream” and “downstream” describe the relative positions of elements, or portions of elements, of the aerosol-generating article in relation to the direction in which the aerosol is transported through the aerosol-generating article during use.
- aerosol-generating article is used herein with reference to the invention to describe an article wherein an aerosol-generating substrate is heated to produce and deliver an aerosol to a consumer.
- aerosol-generating substrate denotes a substrate capable of releasing volatile compounds upon heating to generate an aerosol.
- a conventional cigarette is lit when a user applies a flame to one end of the cigarette and draws air through the other end.
- the localised heat provided by the flame and the oxygen in the air drawn through the cigarette causes the end of the cigarette to ignite, and the resulting combustion generates an inhalable smoke.
- a flavour generating substrate such as, for example, a tobacco-based substrate or a substrate containing an aerosol-former and a flavouring.
- Known heated aerosol-generating articles include, for example, electrically heated aerosol-generating articles and aerosol-generating articles in which an aerosol is generated by the transfer of heat from a combustible fuel element or heat source to a physically separate aerosol forming material.
- an article in accordance with the present invention comprises a filter segment formed of fibrous filtration material and comprising at least about 85 percent by weight based on the total weight of the fibrous filtration material of a PHA polymer or copolymer.
- a PHA polymer or copolymer accounts for at least 85 percent by weight of the fibrous filtration material.
- the remainder of the fibrous filtration material may comprise a material other than a PHA polymer or copolymer.
- other components of the filter segment - such as, for example, a plug wrapper circumscribing the fibrous filtration material, or an insert such as a flow restrictor or an additive delivery material, for example a breakable capsule, which may be provided at a location in the filter segment may comprise a material other than a PHA polymer or copolymer.
- PHA fibres have a lower hydrophilicity compared with fibres of other filtration materials, such as cellulose acetate, of an equivalent weight
- the filter segment has been found to have a significantly lower tendency to absorb water/steam.
- the level of water in the mainstream smoke can advantageously be maintained at a higher level. This directly addresses the issue of “dry smoke” often encountered with conventional smoking articles, and provides an improved smoking experience for the consumer.
- articles in accordance with the present invention are more biodegradable as a whole.
- aerosol-generating articles in accordance with the present invention also provide improved sustainability for the production process.
- the term “denier per filament” corresponds to the weight in grams of a single fibre or filament having a length of 9000 metres. In the present invention, the value of DPF therefore gives an indication of the thickness of each of the individual PHA fibres within the filter segment.
- the denier per filament is expressed in units of denier, where 1 denier corresponds to 1 gram per 9000 metres.
- the total denier of the filtration material comprising the PHA fibres is between about 20,000 and about 50,000 or 40,000, more preferably between about 25,000 and about 30,000.
- total denier of the filtration material defines the total weight in grams of 9000 metres of the combined fibres forming the filtration material.
- the total denier for the filter segment therefore corresponds to the denier per filament multiplied by the total number of fibres in the filter segment.
- the overall weight of the filter may be advantageously controlled, and this may also contribute to help with biodegradation of the filter segment and of the aerosol generating article as a whole.
- PHA properties also lead to good filter hardness, which can be further enhanced by circumscribing the filter segment with a stiff plug wrap.
- Aerosol-generating articles in accordance with the present invention comprise a rod of aerosol-generating substrate.
- the rod of aerosol-generating substrate may be produced using randomly oriented shreds, strands, or strips of tobacco material.
- the rod of aerosol-generating substrate may be formed from one or more gathered sheets of tobacco material.
- Alternative rods for aerosol-generating articles have also been proposed that are formed from strands of homogenised tobacco material, which may be formed by casting, rolling, calendering or extruding a mixture comprising particulate tobacco and at least one aerosol former to form a sheet of homogenised tobacco material.
- a rod of aerosol-generating substrate may be formed from strands of homogenised tobacco material obtained by extruding a mixture comprising particulate tobacco and at least one aerosol former to form continuous lengths of homogenised tobacco material.
- the rod of aerosol generating substrate preferably has an external diameter that is approximately equal to the external diameter of the aerosol generating article.
- the rod of aerosol generating substrate has an external diameter of at least 5 millimetres.
- the rod of aerosol generating substrate may have an external diameter of between about 5 millimetres and about 12 millimetres, for example of between about 5 millimetres and about 10 millimetres or of between about 6 millimetres and about 8 millimetres.
- the rod of aerosol generating substrate has an external diameter of 7.2 millimetres, to within 10 percent.
- the rod of aerosol generating substrate may have a length of between about 5 millimetres and about 100 mm.
- the rod of aerosol generating substrate has a length of at least about 5 millimetres, more preferably at least about 7 millimetres.
- the rod of aerosol generating substrate preferably has a length of less than about 80 millimetres, more preferably less than about 65 millimetres, even more preferably less than about 50 millimetres.
- the rod of aerosol generating substrate has a length of less than about 35 millimetres, more preferably less than 25 millimetres, even more preferably less than about 20 millimetres.
- the rod of aerosol generating substrate may have a length of about 10 millimetres.
- the rod of aerosol generating substrate has a length of about 12 millimetres.
- the rod of aerosol generating substrate has a substantially uniform cross- section along the length of the rod.
- the rod of aerosol generating substrate has a substantially circular cross-section.
- the aerosol-generating substrate comprises one or more gathered sheets of homogenised tobacco material.
- the one or more sheets of homogenised tobacco material are textured.
- the term ‘textured sheet’ denotes a sheet that has been crimped, embossed, debossed, perforated or otherwise deformed.
- Textured sheets of homogenised tobacco material for use in the invention may comprise a plurality of spaced-apart indentations, protrusions, perforations or a combination thereof.
- the rod of aerosol generating substrate comprises a gathered crimped sheet of homogenised tobacco material circumscribed by a wrapper.
- the term ‘crimped sheet’ is intended to be synonymous with the term ‘creped sheet’ and denotes a sheet having a plurality of substantially parallel ridges or corrugations.
- the crimped sheet of homogenised tobacco material has a plurality of ridges or corrugations substantially parallel to the cylindrical axis of the rod according to the invention. This advantageously facilitates gathering of the crimped sheet of homogenised tobacco material to form the rod.
- crimped sheets of homogenised tobacco material for use in the invention may alternatively or in addition have a plurality of substantially parallel ridges or corrugations disposed at an acute or obtuse angle to the cylindrical axis of the rod.
- sheets of homogenised tobacco material for use in the rod of the article of the invention may be substantially evenly textured over substantially their entire surface.
- crimped sheets of homogenised tobacco material for use in the manufacture of a rod for use in an aerosol-generating article in accordance with the invention may comprise a plurality of substantially parallel ridges or corrugations that are substantially evenly spaced-apart across the width of the sheet.
- Sheets or webs of homogenised tobacco material for use in the invention may have a tobacco content of at least about 40 percent by weight on a dry weight basis, more preferably of at least about 60 percent by weight on a dry weight basis, more preferably or at least about 70 percent by weight on a dry basis and most preferably at least about 90 percent by weight on a dry weight basis.
- Sheets or webs of homogenised tobacco material for use in the aerosol-generating substrate may comprise one or more intrinsic binders, that is tobacco endogenous binders, one or more extrinsic binders, that is tobacco exogenous binders, or a combination thereof to help agglomerate the particulate tobacco.
- sheets of homogenised tobacco material for use in the aerosol-generating substrate may comprise other additives including, but not limited to, tobacco and non-tobacco fibres, aerosol-formers, humectants, plasticisers, flavourants, fillers, aqueous and non-aqueous solvents and combinations thereof.
- Suitable extrinsic binders for inclusion in sheets or webs of homogenised tobacco material for use in the aerosol-generating substrate include, but are not limited to: gums such as, for example, guar gum, xanthan gum, arabic gum and locust bean gum; cellulosic binders such as, for example, hydroxypropyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose and ethyl cellulose; polysaccharides such as, for example, starches, organic acids, such as alginic acid, conjugate base salts of organic acids, such as sodium-alginate, agar and pectins; and combinations thereof.
- gums such as, for example, guar gum, xanthan gum, arabic gum and locust bean gum
- cellulosic binders such as, for example, hydroxypropyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose and ethyl
- non-tobacco fibres for inclusion in sheets or webs of homogenised tobacco material for use in the aerosol-generating substrate include, but are not limited to: cellulose fibres; soft-wood fibres; hard-wood fibres; jute fibres and combinations thereof.
- non-tobacco fibres Prior to inclusion in sheets of homogenised tobacco material for use in the aerosol generating substrate, non-tobacco fibres may be treated by suitable processes known in the art including, but not limited to: mechanical pulping; refining; chemical pulping; bleaching; sulphate pulping; and combinations thereof.
- Substrates for heated aerosol-generating articles typically comprise an “aerosol former”, that is, a compound or mixture of compounds that, in use, facilitates formation of the aerosol, and that preferably is substantially resistant to thermal degradation at the operating temperature of the aerosol-generating article.
- suitable aerosol-formers include: polyhydric alcohols, such as propylene glycol, triethylene glycol, 1,3-butanediol and glycerin; esters of polyhydric alcohols, such as glycerol mono-, di- or triacetate; and aliphatic esters of mono-, di- or polycarboxylic acids, such as dimethyl dodecanedioate and dimethyl tetradecanedioate.
- Preferred aerosol formers are polyhydric alcohols or mixtures thereof, such as propylene glycol, triethylene glycol, 1,3-butanediol and, most preferred, glycerine.
- the aerosol-generating substrate comprises at least 10 percent by weight of an aerosol former, more preferably at least 12 percent by weight of an aerosol former, more preferably at least about 15 percent by weight of an aerosol former.
- the aerosol-generating substrate preferably comprises no more than 30 percent by weight of an aerosol former, more preferably no more than about 25 percent by weight of an aerosol former, more preferably no more than about 20 percent by weight of an aerosol former.
- the aerosol-generating substrate may comprise between about 10 percent and about 30 percent by weight of an aerosol former, or between about 12 percent and about 25 percent by weight of an aerosol former, or between about 15 percent and about 20 percent by weight of an aerosol former.
- the aerosol-generating substrate comprises around 18 percent by weight of an aerosol former.
- the filter segment is formed of fibrous filtration material and comprises at least 85 percent by weight of a PHA polymer or copolymer based on the total weight of the fibrous filtration material.
- PHAs are a family of polyhydroxyesters of 3-, 4-, 5- and 6-hydroxyalkanoic acids, which are produced by a variety of bacterial species under nutrient-limiting conditions with excess carbon and are found as discrete cytoplasmic inclusions in bacterial cells. Due to their excellent biocompatibility, PHAs have been proposed for use in a wide variety of biomedical applications, including drug delivery systems and tissue engineering scaffolds.
- a PHA molecule is typically made up of 600 to 35,000 (R)-hydroxy fatty acid monomer units. Depending on the total number of carbon atoms within a PHA monomer, PHA can be classified as either short-chain length PHA (scl-PHA; 3 to 5 carbon atoms), medium-chain length PHA (mcl-PHA; 6 to 14 carbon atoms), or long-chain length PHA (lcl-PHA; 15 or more carbon atoms).
- scl-PHA short-chain length PHA
- mcl-PHA medium-chain length PHA
- lcl-PHA long-chain length PHA
- the first and most prevalent PHA is poly ⁇ -hydroxybutyrate) (PHB).
- PHA poly ⁇ -hydroxybutyrate
- the next member of the PHA family, having a pendant ethyl group, is poly(3-hydroxyvalerate) or PHV. Having an ethyl group (HV unit) instead of the methyl group of PHB gives PHV more flexibility and less crystallinity than PHB.
- the PHA-containing fibres provided within the filter segment of the aerosol-generating articles according to the invention may be formed of any suitable PHA compound, including PHA polymers or copolymers.
- suitable PHA compounds include but are not limited to: polyhydroxypropionate, polyhydroxyvalerate, polyhydroxybutyrate, polyhydroxyhexanoate and polyhydroxyoctanoate.
- the PHA compound is poly(3-hydroxybutyrate).
- the filter segment comprises at least 85 percent by weight of a PHA polymer or copolymer.
- a PHA polymer or copolymer it is understood that higher contents of PHA in the filter segment are generally associated with an improved biodegradability of the filter segment and of the aerosol-generating article as a whole.
- the filter segment comprises at least about 90 percent by weight of a PHA polymer or copolymer.
- higher contents of PHA in the filter segment are generally associated with an improved biodegradability of the filter segment and of the aerosol-generating article as a whole.
- the filter segment comprises at least about 91 percent by weight of a PHA polymer or copolymer or at least about 92 percent by weight of a PHA polymer or copolymer or at least about 93 percent by weight of a PHA polymer or copolymer or at least about 94 percent by weight of a PHA polymer or copolymer. In some particularly preferred embodiments, the filter segment comprises at least about 95 percent by weight of a PHA polymer or copolymer.
- the remainder of the fibres within the PHA filter segment may comprise any suitable material.
- Suitable fibrous materials would be known to the skilled person and include but are not limited to polylactic acid (PLA) and cellulose acetate.
- the filter segment may comprise some cellulose acetate.
- a certain amount of cellulose acetate in the filter segment may impart desirable filtration properties and mechanical properties to the filter segment as well as facilitating manufacture of the filter segment.
- the filter segment comprises at least about 5 percent by weight of cellulose acetate.
- the filter segment may comprise at least about 6 percent by weight of cellulose acetate or at least about 7 percent by weight of cellulose acetate or at least about 8 percent by weight of cellulose acetate or at least about 9 percent by weight of cellulose acetate.
- the filter segment comprises at least about 10 percent by weight of cellulose acetate.
- the filter segment preferably comprises less than about 15 percent by weight of cellulose acetate.
- the filter segment comprises less than about 5 percent by weight of cellulose acetate, preferably less than 3 percent by weight of cellulose acetate, more preferably less than 1 percent by weight of cellulose acetate, even more preferably less than 0.1 percent by weight cellulose acetate. This may favourable further contribute to enhance biodegradability of the filter segment and of the aerosol-generating article as a whole.
- an aerosol-generating article in accordance with the present invention comprises less than or equal to about 10 percent by weight of cellulose acetate measured with reference to the overall weight of the aerosol-generating article. More preferably, an aerosol-generating article in accordance with the present invention comprises less than or equal to about 7 percent by weight of cellulose acetate measured with reference to the overall weight of the aerosol-generating article. Even more preferably, an aerosol-generating article in accordance with the present invention comprises less than or equal to about 5 percent by weight of cellulose acetate measured with reference to the overall weight of the aerosol generating article.
- an aerosol-generating article in accordance with the present invention comprises less than or equal to about 3 percent by weight of cellulose acetate measured with reference to the overall weight of the aerosol-generating article. More preferably, an aerosol-generating article in accordance with the present invention comprises less than or equal to about 2 percent by weight of cellulose acetate measured with reference to the overall weight of the aerosol-generating article. Even more preferably, an aerosol generating article in accordance with the present invention comprises less than or equal to about 1 percent by weight of cellulose acetate measured with reference to the overall weight of the aerosol-generating article.
- an aerosol-generating article in accordance with the present invention is substantially free of cellulose acetate.
- the filter segment further comprises at least about 5 percent by weight of at least one biodegradable polymer selected from the group consisting of starch, polybutylene succinate (PBS), polybutyrate adipate terephthalate (PBAT), thermoplastic starch and thermoplastic starch blends (TPS), polycaprolactone (PCL), polyglycolide (PGA), polyvinyl alcohol (PVOH/PVA), viscose, regenerated cellulose, polysaccharides, cellulose acetate with a degree of substitution (DS) of less than 2.1, polyamides, protein-based biopolymers, chitosan-chitin based biopolymers, and combinations thereof.
- PBS polybutylene succinate
- PBAT polybutyrate adipate terephthalate
- TPS thermoplastic starch and thermoplastic starch blends
- PCL polycaprolactone
- PGA polyglycolide
- PVOH/PVA polyvinyl alcohol
- viscose
- the filter segment comprises at least about 10 percent by weight of one such additional biodegradable polymer. More preferably, the filter segment comprises at least about 11 percent by weight or at least 12 percent by weight or at least 13 percent by weight or at least 14 percent by weight of the additional biodegradable polymer. Even more preferably, the filter segment comprises at least about 15 percent by weight of one such additional biodegradable polymer.
- the at least one biodegradable polymer is one or more of PBAT, PCL and PBS.
- PBAT PBAT
- PCL PCL
- PBS PBS
- the fibrous filtration material comprises at least about 3 percent by weight of a plasticiser selected from triacetin, triethylene glycol diacetate (TEGDA), ethylene vinyl acetate, polyvinyl alcohol, starch or combinations thereof.
- a plasticiser selected from triacetin, triethylene glycol diacetate (TEGDA), ethylene vinyl acetate, polyvinyl alcohol, starch or combinations thereof.
- the fibrous filtration material also further comprises a water based adhesive.
- a water based adhesive This has the effect of structurally reinforcing the structure of the hollow tube segment.
- compounds such as starch adhesive, methyl cellulose or polyvinyl acetate may be used to this purpose.
- the fibrous filtration material of which the filter segment is formed comprises a plurality of fibres comprising a PHA polymer or copolymer and having a denier per filament of at least about 1. More preferably, the fibrous filtration material of which the filter segment is formed comprises a plurality of fibres comprising a PHA polymer or copolymer and having a denier per filament of at least about 2. Even more preferably, the fibrous filtration material of which the filter segment is formed comprises a plurality of fibres comprising a PHA polymer or copolymer and having a denier per filament of at least about 3.2.
- the fibrous filtration material of which the filter segment is formed comprises a plurality of fibres comprising a PHA polymer or copolymer and having a denier per filament of less than or equal to about 10. More preferably, the fibrous filtration material of which the filter segment is formed comprises a plurality of fibres comprising a PHA polymer or copolymer and having a denier per filament of less than or equal to about 7.5. Even more preferably, the fibrous filtration material of which the filter segment is formed comprises a plurality of fibres comprising a PHA polymer or copolymer and having a denier per filament of less than or equal to about 5.
- the fibrous filtration material of which the filter segment is formed comprises a plurality of fibres comprising a PHA polymer or copolymer and having a denier per filament of from about 1 to about 10, more preferably from about 2 to about 10, even more preferably from about 3.2 to about 10.
- the fibrous filtration material of which the filter segment is formed comprises a plurality of fibres comprising a PHA polymer or copolymer and having a denier per filament of from about 1 to about 7.5, more preferably from about 2 to about 7.5, even more preferably from about 3.2 to about 7.5.
- the fibrous filtration material of which the filter segment is formed comprises a plurality of fibres comprising a PHA polymer or copolymer and having a denier per filament of from about 1 to about 5, more preferably from about 2 to about 5, even more preferably from about 3.2 to about 5.
- the inventors have found that when the filter segment is formed with PHA fibres having a relatively low DPF of between 1.5 and 3.2, the filter segment exhibits a relatively low RTD, which may be desirable for the design of certain filters.
- One such low range of DPF also advantageously reduces the overall weight of the filter segment, which further improves the biodegradability of the aerosol-generating article.
- the transverse cross-sectional shape of the PHA fibres may be varied, for example, in order to control the external surface area of the fibres within the filter.
- the total surface area of the PHA fibres that is exposed to the mainstream smoke as it passes through the filter segment may also be controlled. This in turn will control to some extent the filtration properties of the PHA fibres, for example, the amount of water that is adsorbed by the fibres.
- the total external surface area of the PHA fibres within the filter segment is preferably between about 0.15 square metres per gram and about 0.55 square metres per gram (please add subranges).
- the PHA fibres may have a substantially round cross-section.
- the total external surface area of the PHA fibres within the filter segment is preferably between about 0.15 square metres per gram and about 0.30 square metres per gram.
- the PHA fibres may have a Y-shaped cross-section.
- the total external surface are of the PHA fibres within the filter segment is preferably between about 0.25 square metres per gram and about 0.55 square metres per gram.
- the PHA filter segment of the aerosol-generating articles according to the invention may be adapted in order to provide a desired level of resistance to draw (RTD).
- RTD resistance to draw
- the PHA fibres can be arranged to provide a relatively high RTD to the PHA filter segment.
- the PHA filter segment is therefore particularly suitable for use in the filter of a combustible smoking article, where a relatively high RTD is typically desirable.
- the PHA filter segment may be particularly suitable in aerosol-generating articles for which a relatively short mouthpiece or filter is preferred, since an acceptable RTD can still be provided.
- an RTD of the PHA filter segment for a 27 millimetre filter segment is at least about 25 millimetres H2O. More preferably, an RTD of the PHA filter segment for a 27 millimetre filter segment is at least about 50 millimetres H2O , more preferably at least about 100 millimetres H2O. Even more preferably, in aerosol-generating articles in accordance with the present invention an RTD of the PHA filter segment for a 27 millimetre filter segment is at least about 150 millimetres H2O, more preferably at least about 180 millimetres H2O.
- the RTD of the PHA filter segment for a 27 millimetre filter segment is preferably no more than about 300 millimetres H2O, more preferably no more than 250 millimetres H2O.
- the RTD of the PHA filter segment for a 27 millimetre filter segment may be between about 25 millimetres H2O and about 300 millimetres H2O, or between about 50 millimetres H2O and about 300 millimetres H2O, or between about 100 millimetres H2O and about 250 millimetres H2O, or between about 150 millimetres H2O and about 250 millimetres H2O, or between about 180 millimetres H2O and about 250 millimetres H2O, or around 200 millimetres H2O.
- an RTD of the PHA filter segment (based on the length of the PHA filter segment in the article) is at least about 25 millimetres H2O. More preferably, an RTD of the PHA filter segment is at least about 50 millimetres H2O, more preferably at least about 100 millimetres H2O. Even more preferably, in aerosol-generating articles in accordance with the present invention an RTD of the PHA filter segment is at least about 150 millimetres H2O, more preferably at least about 180 millimetres H2O.
- the RTD of the PHA filter segment (based on the length of the PHA filter segment in the article) is preferably no more than about 300 millimetres H2O, more preferably no more than 250 millimetres H2O.
- the RTD of the PHA filter segment may be between about 25 millimetres H2O and about 300 millimetres H2O, or between about 50 millimetres H2O and about 300 millimetres H2O, or between about 100 millimetres H2O and about 250 millimetres H2O, or between about 150 millimetres H2O and about 250 millimetres H2O, or between about 180 millimetres H2O and about 250 millimetres H2O, or around 200 millimetres H2O.
- an RTD of the PHA filter segment (based on the length of the PHA filter segment in the article) is at least about 3020 millimetres H2O. More preferably, an RTD of the PHA filter segment is at least about 22 millimetres H2O, more preferably at least about 25 millimetres H2O. Even more preferably, in aerosol-generating articles in accordance with the present invention an RTD of the PHA filter segment is at least about 28 millimetres H2O, more preferably at least about 30 millimetres H2O.
- the RTD of the PHA filter segment (based on the length of the PHA filter segment in the article) is preferably no more than about 45 millimetres H2O , more preferably no more than 40 millimetres H2O .
- the RTD of the PHA filter segment may be between about 20 millimetres H2O and about 45 millimetres H2O, or between about 22 millimetres H2O and about 45 millimetres H2O, or between about 25 millimetres H2O and about 40 millimetres H2O, or between about 28 millimetres H2O and about 40 millimetres H2O, or between about 30 millimetres H2O and about 40 millimetres H2O, or around 37 millimetres H2O.
- “Resistance to draw” refers to the static pressure difference between the two ends of a sample when it is traversed by an air flow under steady conditions in which the volumetric flow is 17.5 millilitres per second at the output end.
- the RTD of a sample can be measured using the method set out in ISO Standard 6565:2002.
- the filter segment of the aerosol-generating articles according to the invention may have a lower RTD compared to a filter segment of cellulose acetate fibres, which may be desirable for certain applications.
- a relatively low RTD may be advantageous where a relatively low filtration efficiency is desirable or where a relatively long filter is preferred.
- the filter segment of the aerosol-generating article according to the invention has additionally been found to provide a good stability in the RTD, which means that a high variability in the RTD can advantageously be avoided.
- a standard deviation from the target RTD of between 2 percent and 10 percent, more preferably between 2 percent and 5 percent.
- the fibres comprising a PHA polymer or copolymer of the filter segment are crimped.
- the filter segment may comprise one or more additive for reducing certain constituents in the mainstream smoke.
- the filter segment preferably comprises an additive for the reduction of phenols and phenol derivatives.
- Suitable additives would be known to the skilled person and include, but are not limited to: polyethylene glycol (PEG), triacetin, tri-ethyl citrate, cellulose acetate flakes or combinations thereof.
- the filter segment comprises between about 3 percent and about 15 percent by weight of the additive, more preferably between about 5 percent and about 9 percent by weight of the additive.
- the PHA filter segment comprises polyethylene glycol, such as PEG 400.
- PHA fibres generally provide a good filtration efficiency for undesirable smoke constituents but are less effective at the removal of phenolic compounds.
- the filter segment further comprises at least about 5 percent by weight of polyethylene glycol, based on the total weight of the filtration material.
- the filter segment comprises no more than 10 percent by weight of polyethylene glycol, based on the total weight of the filtration material.
- the PHA filter segment further comprises a mixture of cellulose acetate and triacetin.
- the mixture comprises at least 90 percent by weight of triacetin and up to 10 percent by weight cellulose acetate.
- the mixture may be formed by adding cellulose acetate flakes to triacetin to form a solution.
- the solution may then be sprayed onto the PHA fibres in the PHA filter segment. This combination has been found to advantageously replicate the combined effects of triacetin and cellulose acetate fibres in the filter of a conventional cigarette.
- PHA fibres absorb less water from the mainstream smoke than an equivalent amount of cellulose acetate fibres, due to the lower affinity of the PHA fibres to water.
- the amount of water absorbed by a PHA filter segment is significantly lower than the amount of water absorbed by a comparative filter segment formed of an equivalent weight of cellulose acetate fibres.
- the filter segment of the aerosol generating article of the present invention when exposed to water in liquid form, preferably absorbs less than half the amount of water that is absorbed under the same conditions by an equivalent filter segment formed of cellulose acetate fibres.
- the amount of water in the mainstream smoke collected during the smoking of a combustible smoking article comprising a filter according to the invention with PHA fibres under ISO conditions was at least 10 percent higher and preferably at least 15 percent higher than the amount of water in the mainstream smoke collected during the smoking of an equivalent combustible smoking article having a filter segment of cellulose acetate tow under the same conditions.
- Aerosol-generating articles comprising a filter including a PHA filter segment are therefore able to deliver a mainstream smoke having a higher moisture level, which is more sensorially acceptable to the consumer.
- the ‘dry smoke’ effect that may be experienced during smoking of an aerosol-generating article with a conventional cellulose acetate filter can advantageously be reduced.
- the fibres comprising a PHA polymer or copolymer of the filter segment may be manufactured by one of several techniques, including melt spinning, gel spinning, and electrospinning.
- the fibres comprising a PHA polymer or copolymer of the filter segment in aerosol-generating articles in accordance with the present invention are manufactured by melt spinning.
- Melt spinning is often regarded as the most economical process of spinning, since no solvent needs to be recovered or evaporated, as is by contrast the case with solution spinning. Further, the spinning rate with melt spinning is generally fairly high, which is advantageous in terms of overall productivity and manufacturing efficiency.
- a viscous melt of polymer or of a polymer blend is extruded through a spinneret containing a number of holes into a chamber, where a blast of cold air or gas is directed onto the surface of filaments emanating from the spinneret. As the air strikes the filaments, the filaments are solidified and collected such as on a take-up wheel.
- the melt spinning process is advantageously characterised by defined filament cross-section geometries and affords a significant variety of fineness and filament count. By increasing the number of openings in the spinneret, a high spinning capacity can be achieved, which is difficult to match with other spinning processes.
- the filter segment may typically have a length of at least about 4 millimetres.
- a length of the filter segment is at least about 5 millimetres. More preferably, a length of the filter segment is at least about 7 millimetres. Even more preferably, a length of the filter segment is at least about 10 millimetres.
- the filter segment may typically have a length of less than or equal to about 30 millimetres.
- a length of the filter segment is less than or equal to about 27 millimetres. More preferably, a length of the filter segment is less than or equal to about 25 millimetres. Even more preferably a length of the filter segment it less than or equal to about 20 millimetres.
- a length of the filter segment is preferably from about 5 millimetres to about 30 millimetres, more preferably from about 10 millimetres to about 30 millimetres, even more preferably from about 15 millimetres to about 30 millimetres, most preferably from about 20 millimetres to about 30 millimetres.
- a length of the filter segment may be from about 4 millimetres to about 27 millimetres, and preferably is from about 5 millimetres to about 27 millimetres, more preferably from about 10 millimetres to about 27 millimetres, even more preferably from about 15 millimetres to about 27 millimetres, most preferably from about 20 millimetres to about 27 millimetres.
- a length of the filter segment may be from about 4 millimetres to about 25 millimetres, and preferably is from about 5 millimetres to about 25 millimetres, more preferably from about 10 millimetres to about 25 millimetres, even more preferably from about 15 millimetres to about 30 millimetres, most preferably from about 20 millimetres to about 25 millimetres.
- the filter segment preferably has an external diameter that is about equal to the external diameter of the aerosol-generating article.
- the filter segment has an external diameter of at least 5 millimetres.
- the filter segment may have an external diameter of between about 5 millimetres and about 12 millimetres, for example of between about 5 millimetres and about 10 millimetres or of between about 6 millimetres and about 8 millimetres.
- the filter segment has an external diameter of 7.2 millimetres, to within 10 percent.
- the filter segment has an average radial hardness of at least 80 percent, more preferably at least 85 percent.
- the filter segment is therefore able to provide a desirable level of filter hardness, which is comparable to that provided by a conventional cellulose acetate tow filter.
- the radial hardness of the filter segment of aerosol-generating articles in accordance with the invention may be further increased by circumscribing the filter segment by a stiff plug wrap, for example, a plug wrap having a basis weight of at least about 80 grams per square metre (gsm), or at least about 100 gsm, or at least about 110 gsm.
- Radial hardness refers to resistance to compression in a direction transverse to a longitudinal axis of the filter segment. Radial hardness of an aerosol generating article around a filter may be determined by applying a load across the article at the location of the filter, transverse to the longitudinal axis of the article, and measuring the average (mean) depressed diameters of the articles. Radial hardness is given by:
- Radial hardness 100 % where Ds is the original (undepressed) diameter, and D d is the depressed diameter after applying a set load for a set duration. The harder the material, the closer the hardness is to 100%.
- aerosol-generating articles should be aligned parallel in a plane and the same portion of each aerosol-generating article to be tested should be subjected to a set load for a set duration.
- This test is performed using a known DD60A Densimeter device (manufactured and made commercially available by Heinr Borgwaldt GmbH, Germany), which is fitted with a measuring head for aerosol-generating articles, such as cigarettes, and with an aerosol-generating article receptacle.
- the load is applied using two load-applying cylindrical rods, which extend across the diameter of all of the aerosol-generating articles at once.
- the test should be performed such that twenty contact points occur between the aerosol-generating articles and the load applying cylindrical rods.
- the filters to be tested may be long enough such that only ten aerosol-generating articles are needed to form twenty contact points, with each smoking article contacting both load applying rods (because they are long enough to extend between the rods).
- twenty aerosol-generating articles should be used to form the twenty contact points, with each aerosol-generating article contacting only one of the load applying rods, as further discussed below.
- Two further stationary cylindrical rods are located underneath the aerosol-generating articles, to support the aerosol-generating articles and counteract the load applied by each of the load applying cylindrical rods.
- the filter segment described above is the only segment formed of filtration material forming a mouth end filter of the aerosol-generating article.
- the aerosol-generating article may comprise one or more additional filter segments formed of filtration material, which may be provided upstream or downstream of the filter segment comprising a PHA polymer or copolymer as described above.
- the filter segment comprising a PHA polymer or copolymer may be combined with one or more axially aligned filter plugs formed of a fibrous filtration material, which may or may not include PHA-containing fibres.
- the filter segment comprising a PHA polymer or copolymer may be combined with one or more tubular elements, such as a tubular element formed of a fibrous filtration material or a cardboard tube.
- the PHA filter segment may be combined with an aerosol-cooling element.
- the filter segment of aerosol-generating articles according to the invention may optionally comprise a flavourant.
- Flavourants can be incorporated using a variety of different means, which would be known to the skilled person.
- a flavourant may be incorporated in the form of a capsule which may be provided in the filter segment comprising a PHA polymer or copolymer, or in an additional filter segment of the aerosol-generating article.
- the filter segment of aerosol-generating articles according to the invention is preferably circumscribed by an outer wrapper, for example, a tipping wrapper that circumscribes the filter segments, the downstream end of the aerosol-generating substrate and any additional components that may be provided in between.
- the tipping wrapper may comprise a removable tipping wrapper portion, as described in WO-A-2017/162838. This enables at least a portion of the tipping wrapper to be removed before the aerosol-generating article is discarded. The removal of the tipping wrapper exposes the underlying filter segments and may therefore advantageously speed up the rate of biodegradation of the filter materials.
- an aerosol-generating article in accordance with the present invention may further comprise one or more additional elements that are typically assembled with the rod of aerosol-generating substrate in a same wrapper.
- additional elements include a support element adapted to enhance the structural strength to the aerosol generating article, a cooling element adapted to favour cooling of the aerosol prior to reaching the filter segment, and so forth.
- an aerosol-generating article comprises, in linear sequential arrangement, a rod of aerosol-generating substrate, a support element located immediately downstream of the support element, an aerosol-cooling element located downstream of the support element, and an outer wrapper circumscribing the rod, the support element, and the aerosol-cooling element.
- the rod, the support element, and the aerosol cooling element are provided in linear arrangement and upstream of a filter segment as described above.
- the rod, the support element, and the aerosol-cooling element are provided in linear arrangement and immediately upstream of a filter segment as described above.
- a support element may be provided in the form of a tubular element of a fibrous filtration material.
- the fibrous filtration material may comprise cellulose acetate.
- the fibrous filtration comprises a polyhydroxyalkanoate (PHA) polymer or copolymer.
- the aerosol-generating article comprises in a linear sequential arrangement: an aerosol-generating substrate, a transfer element, an aerosol-cooling element, a spacer element and a filter segment as described above.
- the aerosol-generating article further comprises a combustible heat source at the upstream end of the aerosol-generating article, in contact with the upstream end of the aerosol-generating substrate.
- the aerosol-generating article may comprise a carbonaceous heat source at the upstream end, for heating the aerosol-generating substrate to generate an aerosol during use. Suitable carbonaceous heat sources would be known to the skilled person.
- Figure 1 shows a schematic longitudinal cross-sectional view of an aerosol-generating article according to a first embodiment of the invention, for use with an aerosol-generating device comprising a heater element;
- Figure 2 shows a schematic longitudinal cross-sectional view of an aerosol-generating article according to a second embodiment of the invention, comprising an integral heat source;
- Figure 3 shows a schematic longitudinal cross-sectional view of an aerosol-generating article according to a third embodiment of the invention
- Figure 4 shows a schematic longitudinal cross-sectional view of an aerosol-generating system comprising an electrically operated aerosol-generating device and the aerosol generating article shown in Figure 1.
- the aerosol-generating article 10 shown in Figure 1 comprises a rod of aerosol generating substrate 12, a support element provided as a hollow tubular element 14, a cooling element 16, and a mouth end filter segment 18. These four elements are arranged sequentially and in coaxial alignment and are circumscribed by a substrate wrapper 20 to form the aerosol-generating article 10.
- the aerosol-generating article 10 has a mouth end 22 and a distal end 24 located at the opposite end of the article to the mouth end 22.
- the aerosol generating article 10 shown in Figure 1 is particularly suitable for use with an electrically operated aerosol-generating device comprising a heater for heating the rod of aerosol generating substrate.
- the aerosol-generating article In use air is drawn through the aerosol-generating article by a user from the distal end 24 to the mouth end 22.
- the distal end 24 of the aerosol-generating article may also be described as the upstream end of the aerosol-generating article 10 and the mouth end 22 of the aerosol-generating article 10 may also be described as the downstream end of the aerosol generating article 10.
- Elements of the aerosol-generating article 10 located between the mouth end 22 and the distal end 24 can be described as being upstream of the mouth end 22 or, alternatively, downstream of the distal end 24.
- the aerosol-generating substrate 24 is located at the extreme distal or upstream end of the aerosol-generating article 10.
- the aerosol generating substrate 12 comprises a gathered sheet of crimped homogenised tobacco material circumscribed by a wrapper.
- the crimped sheet of homogenised tobacco material comprises glycerin as an aerosol former.
- the support element 14 is located immediately downstream of the aerosol-generating substrate 12 and abuts the aerosol-generating substrate 12.
- the support element is a hollow tube formed of a fibrous filtration material.
- the support element 14 locates the aerosol-generating substrate 12 at the extreme distal end 24 of the aerosol-generating article 10 so that it can be penetrated by a heating element of an aerosol-generating device.
- the support element 14 acts to prevent the aerosol generating substrate 16 from being forced downstream within the aerosol-generating article 10 towards the aerosol-cooling element 16 when a heating element of an aerosol-generating device is inserted into the aerosol-generating substrate 12.
- the support element 14 also acts as a spacer to space the aerosol-cooling element 16 of the aerosol-generating article 10 from the aerosol-generating substrate 12.
- the aerosol-cooling element 16 is located immediately downstream of the support element 14 and abuts the support element 16. In use, volatile substances released from the aerosol-generating substrate 12 pass along the aerosol-cooling element 16 towards the mouth end 22 of the aerosol-generating article 10. The volatile substances may cool within the aerosol-cooling element 16 to form an aerosol that is inhaled by the user.
- the aerosol-cooling element comprises a tubular element 20.
- the crimped and gathered sheet of polylactic acid defines a plurality of longitudinal channels that extend along the length of the aerosol-cooling element 40.
- the filter segment 18 is located immediately downstream of the aerosol-cooling element 16 and abuts the aerosol-cooling element 16.
- the filter segment 18 comprises a single cylindrical plug of a fibrous filtration material formed of a plurality of PHA fibres having a denier per filament of approximately 3 and a total denier of approximately 27,000.
- the PHA fibres have a round cross-sectional shape and are substantially longitudinally aligned with each other along the length of the filter segment.
- the exposed surface area of the PHA fibres corresponds to about 0.16 square metres per gram.
- the PHA fibres have been formed by a melt spinning process and are crimped.
- the fibres contain about 85 percent by weight of a PHA polymer or copolymer combined with 15 percent by weight of a of PBAT/PBS blend with a 1 :1 PBAT to PBS ratio.
- the plug of fibrous filtration material is circumscribed by a plug wrap (not shown).
- the aerosol-generating article 100 shown in Figure 2 comprises a combustible heat source 112, a rod of aerosol-generating substrate 114, a transfer element 116, an aerosol cooling element, 118, a spacer element 120 and a mouthpiece filter segment 122. These elements are arranged sequentially and in coaxial alignment and are circumscribed by a substrate wrapper to form the aerosol-generating article 100.
- the combustible heat source 112 comprises a substantially circularly cylindrical body of carbonaceous material, having a length of about 10 millimetres.
- the combustible heat source 112 is a blind heat source. In other words, the combustible heat source 112 does not comprise any air channels extending therethrough.
- the rod of aerosol-generating substrate 114 is arranged at a proximal end of the combustible heat source 112.
- the aerosol-generating substrate 114 comprises a substantially circularly cylindrical plug of tobacco material 124 circumscribed by filter plug wrap 126.
- a non-combustible, substantially air impermeable first barrier 128 is arranged between the proximal end of the combustible heat source 112 and a distal end of the aerosol-generating substrate 114.
- the first barrier 128 comprises a disc of aluminium foil.
- the first barrier 128 also forms a heat-conducting member between the combustible heat source 112 and the aerosol-generating substrate 114, for conducting heat from the proximal face of the combustible heat source 112 to the distal face of the aerosol-generating substrate 114.
- a heat-conducting element 130 circumscribes a proximal portion of the combustible heat source 112 and a distal portion of the aerosol-forming substrate 114.
- the heat- conducting element 130 comprises a tube of aluminium foil.
- the heat-conducting element 130 is in direct contact with the proximal portion of the combustible heat source 112 and the filter plug wrap 126 of the aerosol-generating substrate 114.
- the mouthpiece filter 122 comprises a single cylindrical plug 126 of a fibrous filtration material formed of a plurality of PHA fibres having a denier per filament of approximately 3 and a total denier of approximately 27,000.
- the PHA fibres have a round cross-sectional shape and are substantially longitudinally aligned with each other along the length of the filter segment.
- the exposed surface area of the PHA fibres corresponds to about 0.16 square metres per gram.
- the PHA fibres have been formed by a melt spinning process and are crimped.
- the plug of fibrous filtration material is circumscribed by a plug wrap (not shown).
- the aerosol-generating article 310 shown in Figure 3 is a combustible smoking article comprising an aerosol-generating substrate 312 and a filter 314 arranged in coaxial alignment with each other.
- the aerosol-generating substrate 312 comprises a tobacco rod circumscribed by an outer wrapper (not shown).
- a tipping wrapper 316 circumscribes both the filter 314 and an end portion of the aerosol-generating substrate 312 and attaches the filter 314 to the aerosol-generating substrate 312.
- the filter 314 comprises a single cylindrical plug 318 of a fibrous filtration material formed of PHA fibres having a denier per filament of approximately 3 and a total denier of approximately 27,000.
- the PHA fibres have a round cross-sectional shape and are substantially longitudinally aligned with each other along the length of the filter segment.
- the exposed surface area of the PHA fibres corresponds to about 0.16 square metres per gram.
- the PHA fibres have been formed by a melt spinning process and are crimped.
- the plug of fibrous filtration material is circumscribed by a plug wrap (not shown).
- Figure 4 shows a portion of an electrically operated aerosol-generating system 200 that utilises a heater blade 210 to heat the rod of aerosol-generating substrate 12 of the aerosol generating article 10 shown in Figure 1.
- the heater blade 210 is mounted within an aerosol generating article chamber within a housing of an electrically operated aerosol-generating device 212.
- the aerosol-generating device 212 defines a plurality of air holes 214 for allowing air to flow to the aerosol-generating article 10, as illustrated by the arrows in Figure 4.
- the aerosol-generating device 212 comprises a power supply and electronics, which are not shown in Figure 4.
- a PHA filter segment according to the invention was prepared from PHA fibres, with the parameters shown in Table 1 below.
- the PHA fibres were formed using a melt spinning process, the fibres were then crimped and formed into a filter segment using standard filter making apparatus.
- a conventional cellulose acetate (CA) tow filter segment was prepared, with similar values of denier per filament (dpf) and total denier.
- the amount of water absorbed by the PHA filter segment according to the invention during the test was therefore less than 40 percent of the amount of water absorbed by the CA filter segment. This test therefore demonstrates the significantly reduced affinity of water of the PHA filter segment according to the invention compared to the conventional CA filter segment.
- %dm percentage difference in mass of the sample
- a third test the absorption of water from the mainstream smoke by a PHA filter segment according to the present invention and a conventional CA filter segment were compared.
- a conventional smoking article was prepared as described above with reference to Figure 3, with a combustible tobacco rod and a single segment of the filtration material forming the filter.
- Each of the smoking articles was then smoked in a cigarette-smoking machine under ISO conditions as set out in ISO 3308:2000 (puff volume 35 ml; 2 second puff duration every 60 seconds) and an analysis of the resultant smoke was carried out.
- the amount of water in the mainstream smoke collected during the smoking test was measured, as shown in Table 4:
- Table 4 Water in mainstream smoke generated during smoking test under ISO conditions
- the smoking article incorporating the PHA filter segment produces a mainstream smoke having a water content that is approximately 20 percent higher than the water content of the mainstream smoke from the smoking article including the CA filter segment.
- the PHA filter segment is absorbing less water from the mainstream smoke than the CA filter segment, thereby reducing the potential problem of dry smoke as described above.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biodiversity & Conservation Biology (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Filtering Materials (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP19386051 | 2019-12-03 | ||
PCT/EP2020/083554 WO2021110540A1 (en) | 2019-12-03 | 2020-11-26 | Aerosol-generating element comprising a filter with a high content of a polyhydroxyalkanoate polymer or copolymer |
Publications (3)
Publication Number | Publication Date |
---|---|
EP4069002A1 true EP4069002A1 (en) | 2022-10-12 |
EP4069002C0 EP4069002C0 (en) | 2023-09-13 |
EP4069002B1 EP4069002B1 (en) | 2023-09-13 |
Family
ID=69105713
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20811356.3A Active EP4069002B1 (en) | 2019-12-03 | 2020-11-26 | Aerosol-generating element comprising a filter with a high content of a polyhydroxyalkanoate polymer or copolymer |
Country Status (7)
Country | Link |
---|---|
US (1) | US20230014600A1 (en) |
EP (1) | EP4069002B1 (en) |
JP (1) | JP2023505462A (en) |
KR (1) | KR20220110533A (en) |
CN (1) | CN114901091A (en) |
BR (1) | BR112022010039A2 (en) |
WO (1) | WO2021110540A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP4166011A1 (en) * | 2021-10-18 | 2023-04-19 | JT International SA | T-vapor stick that can be used for cleaning oven |
CN117652720A (en) * | 2022-08-31 | 2024-03-08 | 上海烟草集团有限责任公司 | Aerosol generating product, preparation method and aerosol generating system |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120000480A1 (en) * | 2010-06-30 | 2012-01-05 | Sebastian Andries D | Biodegradable cigarette filter |
TR201810770T4 (en) | 2011-05-31 | 2018-08-27 | Philip Morris Products Sa | Sticks for use in cigarette objects. |
KR102216911B1 (en) * | 2012-12-31 | 2021-02-19 | 필립모리스 프로덕츠 에스.에이. | Smoking article including flow restrictor in hollow tube |
EP3794966B1 (en) | 2013-07-16 | 2024-07-24 | Philip Morris Products S.A. | Radially firm smoking article filter |
MX2018011277A (en) | 2016-03-24 | 2019-02-13 | Philip Morris Products Sa | Aerosol generating article having removable tipping wrapper portion with tear tab. |
US10524500B2 (en) * | 2016-06-10 | 2020-01-07 | R.J. Reynolds Tobacco Company | Staple fiber blend for use in the manufacture of cigarette filter elements |
-
2020
- 2020-11-26 BR BR112022010039A patent/BR112022010039A2/en unknown
- 2020-11-26 CN CN202080083980.XA patent/CN114901091A/en active Pending
- 2020-11-26 WO PCT/EP2020/083554 patent/WO2021110540A1/en active Search and Examination
- 2020-11-26 KR KR1020227022438A patent/KR20220110533A/en active Search and Examination
- 2020-11-26 JP JP2022533096A patent/JP2023505462A/en active Pending
- 2020-11-26 EP EP20811356.3A patent/EP4069002B1/en active Active
- 2020-11-26 US US17/781,440 patent/US20230014600A1/en active Pending
Also Published As
Publication number | Publication date |
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BR112022010039A2 (en) | 2022-08-16 |
CN114901091A (en) | 2022-08-12 |
KR20220110533A (en) | 2022-08-08 |
EP4069002C0 (en) | 2023-09-13 |
WO2021110540A1 (en) | 2021-06-10 |
JP2023505462A (en) | 2023-02-09 |
US20230014600A1 (en) | 2023-01-19 |
EP4069002B1 (en) | 2023-09-13 |
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