EP3908135A1 - Verdampfer mit positivem temperaturkoeffizienten des widerstandserwärmers - Google Patents

Verdampfer mit positivem temperaturkoeffizienten des widerstandserwärmers

Info

Publication number
EP3908135A1
EP3908135A1 EP20704967.7A EP20704967A EP3908135A1 EP 3908135 A1 EP3908135 A1 EP 3908135A1 EP 20704967 A EP20704967 A EP 20704967A EP 3908135 A1 EP3908135 A1 EP 3908135A1
Authority
EP
European Patent Office
Prior art keywords
temperature
electrical resistivity
ptcr
ohm
heating element
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP20704967.7A
Other languages
English (en)
French (fr)
Inventor
William W. Alston
Adam Bowen
Ian GARCIA-DOTY
Joshua A. KURZMAN
James Monsees
Paul R. VIEIRA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Juul Labs Inc
Original Assignee
Juul Labs Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Juul Labs Inc filed Critical Juul Labs Inc
Priority claimed from PCT/US2020/013224 external-priority patent/WO2020146828A1/en
Publication of EP3908135A1 publication Critical patent/EP3908135A1/de
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/40—Constructional details, e.g. connection of cartridges and battery parts
    • A24F40/46—Shape or structure of electric heating means
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/50—Control or monitoring
    • A24F40/57—Temperature control
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/02—Details
    • H05B3/06—Heater elements structurally combined with coupling elements or holders
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/40—Heating elements having the shape of rods or tubes
    • H05B3/42—Heating elements having the shape of rods or tubes non-flexible
    • H05B3/46—Heating elements having the shape of rods or tubes non-flexible heating conductor mounted on insulating base
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/10—Devices using liquid inhalable precursors
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/20—Devices using solid inhalable precursors
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/30—Devices using two or more structurally separated inhalable precursors, e.g. using two liquid precursors in two cartridges
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/60—Devices with integrated user interfaces
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/65—Devices with integrated communication means, e.g. wireless communication means
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
    • H05B2203/02—Heaters using heating elements having a positive temperature coefficient
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
    • H05B2203/022—Heaters specially adapted for heating gaseous material

Definitions

  • vaporizer devices such as portable personal vaporizer devices for generating an inhalable aerosol from one or more vaporizable materials and including a heating element utilizing semi- conductive material with nonlinear positive temperature coefficient of resistivity (PTCR).
  • PTCR nonlinear positive temperature coefficient of resistivity
  • Vaporizer devices which can also be referred to as electronic vaporizer devices or e-vaporizer devices, can be used for delivery of an aerosol (also sometimes referred to as“vapor”) containing one or more active ingredients by inhalation of the aerosol by a user of the vaporizing device.
  • Electronic cigarettes which may also be referred to as e-cigarettes, are a class of vaporizer devices that are typically battery powered and that may be used to simulate the experience of cigarette smoking, but without burning of tobacco or other substances.
  • a vaporizer device In use of a vaporizer device, the user inhales an aerosol, commonly called vapor, which may be generated by a heating element that vaporizes (which generally refers to causing a liquid or solid to at least partially transition to the gas phase) a vaporizable material, which may be liquid, a solution, a solid, a wax, or any other form as may be compatible with use of a specific vaporizer device.
  • a user may, in certain examples, activate the vaporizer device by taking a puff, by pressing a button, or by some other approach.
  • a puff refers to inhalation by the user in a manner that causes a volume of air to be drawn through the vaporizer device such that the inhalable aerosol is generated by combination of vaporized vaporizable material with the air.
  • a typical approach by which a vaporizer device (e.g., which can include an air inlet, an air outlet in fluid conjunction with a mouthpiece, and with a vaporization chamber between) generates an inhalable aerosol from a vaporizable material involves heating the vaporizable material in a vaporization chamber (also sometimes referred to as a heater chamber) to cause the vaporizable material to be converted to the gas (vapor) phase.
  • a vaporization chamber generally refers to an area or volume in the vaporizer device within which a heat source causes heating of a vaporizable material to produce a mixture of air, and the vaporizable material in some equilibrium between the gas and condensed (e.g., liquid and/or solid) phases.
  • Certain components of the gas-phase vaporizable material may condense after being vaporized due to cooling and/or changes in pressure to thereby form an aerosol that includes particles of a condensed phase (e.g., liquid and/or solid) suspended in at least some of the air drawn into the vaporizer device via the puff.
  • a condensed phase e.g., liquid and/or solid
  • the inhalable aerosol may include that semi-volatile compound in some local equilibrium between the gas and condensed phases.
  • a vaporizer device in an aspect, includes a housing including an air inlet.
  • the vaporizer device also includes a heating element within the housing.
  • the heating element including a nonlinear positive temperature coefficient of resistance material.
  • the vaporizer device also includes a heat exchanger thermally coupled to the heating element and arranged to receive an airflow from the air inlet.
  • the heat exchanger is configured to transfer heat between the heating element and the airflow to produce a heated airflow.
  • the heated airflow exiting the heat exchanger is configured to vaporize a vaporizable material.
  • the heat exchanger can include a first heat exchanger thermally coupled to a first side of the heating element.
  • the heat exchanger can include a second heat exchanger thermally coupled to a second side of the heating element.
  • the heat exchanger can include a plurality of fin features.
  • the heat exchanger can be made from aluminum, copper, steel, stainless steel, or titanium.
  • the heat exchanger can be made from a thermally conductive material extrusion.
  • the device can include a flow diverter located in a path of the airflow configured to divert a portion of the airflow through the heat exchanger.
  • the housing can include a heater assembly cover containing the heat exchanger.
  • the device can include a power source configured to provide electrical energy to heat the heating element.
  • the device can include a cartridge located downstream of the heating element and oriented to receive the heated airflow, wherein downstream is with respect to the airflow.
  • the housing can include a connector configured to couple the housing to a cartridge including a vaporizable material.
  • the vaporizable material can be solid vaporizable material.
  • the vaporizer device can include a cartridge configured to contain a vaporizable material.
  • the cartridge can include a first air inlet.
  • the housing can include a connector configured to couple the housing to the cartridge.
  • the cartridge can include a solid vaporizable material.
  • the cartridge can include a reservoir, liquid vaporizable material within the reservoir, and a wick in fluidic communication with the liquid vaporizable material, wherein the cartridge is configured to receive the heated airflow and direct the heated airflow over the wick.
  • the cartridge can include a mouthpiece, and the wick can be located in a path of the airflow between the heating element and the mouthpiece.
  • the cartridge can include a second air inlet configured to draw a second airflow into the cartridge for mixing with the heated airflow and within a condensation chamber located in a path of the airflow downstream from the heat exchanger and the vaporizable material.
  • the cartridge can include a reservoir, liquid vaporizable material within the reservoir, and a wick in fluidic communication with the liquid vaporizable material.
  • the wick can be arranged to receive the heated airflow from the heat exchanger to produce vaporized vaporizable material in the form of a vapor and/or a first aerosol.
  • a solid vaporizable material can be arranged to receive the vapor and/or the first aerosol and produce a second aerosol.
  • a mouthpiece can be configured to receive the second aerosol after the vapor and/or the first aerosol passes through the solid vaporizable material.
  • the vaporizer device can include a first cartridge including the vaporizable material, a first air inlet, and a wick.
  • the vaporizable material can be a liquid vaporizable material and the wick can be in fluidic communication with the liquid vaporizable material.
  • the wick can be arranged to receive the heated airflow through the first air inlet from the heat exchanger to vaporize the vaporizable material to produce a vapor and/or a first aerosol.
  • the vaporizer device can also include a second cartridge that includes a solid vaporizable material and a mouthpiece. The solid vaporizable material can be arranged to receive the vapor and/or the first aerosol to produce a second aerosol.
  • the mouthpiece can be configured to receive the second aerosol after the vapor and/or the first aerosol passes through the solid vaporizable material.
  • the first cartridge can be removably coupled to the housing.
  • the second cartridge can be removably coupled to the housing and/or the first cartridge.
  • the first cartridge and the second cartridge can be disposable cartridges.
  • the second cartridge can include a second air inlet for mixing ambient temperature air with the vaporized vaporizable material after the vaporized vaporizable material passes through the solid vaporizable material.
  • the device can include a fibrous body arranged to receive and cool the second aerosol after the vapor and/or the first aerosol passes through the solid vaporizable material.
  • the nonlinear positive temperature coefficient of resistance material includes an electrical resistivity transition zone in which the electrical resistivity increases over a temperature range, such that when the heating element is heated above a first temperature within the electrical resistivity transition zone, current flow from a power source is reduced to a level that limits further temperature increases of the heating element.
  • the electrical resistivity transition zone can begin at a first temperature of between 150 °C and 350 °C.
  • the electrical resistivity transition zone can begin at a first temperature of between 220 °C and 300 °C.
  • the electrical resistivity transition zone can begin at a first temperature between 240 °C and 280 °C.
  • the increase in the electrical resistivity over the temperature range of the electrical resistivity transition zone can include an increase factor of at least 10, an increase factor of at least 100, or an increase factor of at least 1000.
  • the increase factor characterizing a relative change in electrical resistivity between electrical resistivity at a first temperature associated with a start of the electrical resistivity transition zone and electrical resistivity at a second temperature associated with an end of the electrical resistivity transition zone.
  • the electrical resistivity transition zone can begin at a first temperature, and the electrical resistivity of the heating element at temperatures below the first temperature can be between 0.2 ohm-cm and 200 ohm-cm, between 2.0 ohm-cm and 20 ohm-cm, or between 20 ohm-cm and 200 ohm-cm.
  • the device can include a power source configured to provide a current flow at a voltage between 3 Volts and 50 Volts to the heating element, a pressure sensor, and a controller coupled to the pressure sensor and configured to detect inhalation, and in response electrically connect the power source to the heating element.
  • the housing can be cylindrical, the heating element can be cylindrical, and the heat exchanger can be cylindrical.
  • the housing can also be rectangular, the heating element can also be rectangular, and the heat exchanger can also be rectangular.
  • the power source can provide either direct current (DC) or alternating current (AC).
  • the vaporizer device can include an input configured to electrically connect the power source to the PTCR heating element (PTCR heater) in response to a user input.
  • the input can include a pushbutton.
  • the PTCR heating element of the vaporizer device is self-regulating to maintain a predetermined temperature when activated.
  • the vaporizer device does not require a pressure sensor, and/or a controller coupled to the pressure sensor to electrically connect the power source to the PTCR heating element and regulate a temperature thereof.
  • a method can include receiving, by the vaporizer device, a user input; heating, using the vaporizer device, a vaporizable material; and producing an inhalable aerosol.
  • the heat exchanger is configured to transfer heat to the airflow.
  • a positive temperature coefficient of resistivity (PTCR) heating element is thermally coupled to the heat exchanger.
  • the PTCR heating element is configured to electrically couple to the power source to receive the current flow and heat the vaporizable material to form an aerosol.
  • the PTCR heating element comprises a PTCR material having an electrical resistivity that varies based on temperature.
  • the electrical resistivity includes an electrical resistivity transition zone in which the electrical resistivity increases over a temperature range, such that when the PTCR heating element is heated above a first temperature within the transition zone, current flow from the power source is reduced to a level that limits further temperature increases of the PTCR heating element.
  • the heat exchanger can include a first heat exchanger thermally coupled to a first side of the heating element.
  • the heat exchanger can include a second heat exchanger thermally coupled to a second side of the heating element.
  • the heat exchanger can include a plurality of fin features.
  • the heat exchanger can be made from aluminum, copper, steel, stainless steel, or titanium.
  • the heat exchanger can be made from a thermally conductive material extrusion.
  • the heat exchanger can be made from a metal foam, for example, an aluminum foam.
  • the heater assembly cover can comprise a non-electrically conductive material.
  • the heater assembly cover can comprise a non-thermally conductive material.
  • the heater assembly cover can comprise a metal with a non-electrically conductive coating isolating the heater assembly cover from the heat exchanger.
  • the heater assembly cover can comprise pol ytetrafl uoroethyl en e (PTFE).
  • the electrical resistivity transition zone can begin at the first temperature of between 150 °C and 350 °C.
  • the electrical resistivity transition zone can also begin at the first temperature of between 220 °C and 300 °C.
  • the electrical resistivity transition zone can also begin at the first temperature between 240 °C and 280 °C.
  • the first temperature can be greater than 225 °C.
  • the PTCR heating element can be heated to an operating temperature between 240 °C and 280 °C.
  • the PTCR heating element can be heated to an operating temperature between 245 °C and 255 °C.
  • the PTCR heating element can be heated to an operating temperature of about 250 °C.
  • the PTCR heater assembly can increase in the electrical resistivity over the temperature range of the electrical resistivity transition zone by an increase factor of at least 10, of at least 100, or of at least 1000.
  • the increase factor characterizing a relative change in electrical resistivity between electrical resistivity at the first temperature associated with a start of the electrical resistivity transition zone and electrical resistivity at a second temperature associated with an end of the electrical resistivity transition zone.
  • the electrical resistivity transition zone can begin at the first temperature and end at a second temperature with the difference between the first temperature and the second temperature being 500 °C or less, 200 °C or less, 100 °C or less, or 50 °C or less.
  • the electrical resistivity transition zone can begin at the first temperature and the electrical resistivity of the PTCR heating element at temperatures below the first temperature is between 0.2 ohm-cm and 2.0 ohm-cm, between 2.0 ohm-cm and 20 ohm-cm, or between 20 ohm-cm and 200 ohm-cm.
  • a vaporizer device for vaporizing a solid vaporizable material with a heated airflow includes a housing including an air inlet and a power source configured to provide a current flow at a voltage, and a PTCR heater assembly within the housing.
  • the PTCR heater assembly includes a heating element within the housing and be configured to electrically couple to the power source to receive the current flow.
  • the PTCR heating element comprises a PTCR material having an electrical resistivity that varies based on temperature.
  • the electrical resistivity includes an electrical resistivity transition zone in which the electrical resistivity increases over a temperature range, such that when the PTCR heating element is heated above a first temperature within the transition zone, current flow from the power source is reduced to a level that limits further temperature increases of the PTCR heating element.
  • the heater assembly also includes a heat exchanger thermally coupled to the heating element and arranged to receive airflow from the air inlet. The heat exchanger is configured to transfer heat between the heating element and the airflow to produce the heated airflow. The heated airflow exiting the heat exchanger is configured to vaporize the solid vaporizable material.
  • the solid vaporizable material can be included with the vaporizer device.
  • the solid vaporizable material can be a tobacco containing media.
  • the vaporizer device can include an input configured to electrically connect the power source to the PTCR heating element in response to a user input.
  • the input can include a pushbutton.
  • the vaporizer device may not comprise a controller.
  • the vaporizer device may not comprise a pressure sensor.
  • the vaporizer device comprises a pressure sensor, and a controller coupled to the pressure sensor and configured to detect inhalation, and in response, electrically connect the power source to the PTCR heating element.
  • the heat exchanger can include a first heat exchanger thermally coupled to a first side of the heating element.
  • the heat exchanger can include a second heat exchanger thermally coupled to a second side of the heating element.
  • the heat exchanger can include a plurality of fin features.
  • the heat exchanger can be made from aluminum, copper, steel, stainless steel, or titanium.
  • the heat exchanger can be made from a thermally conductive material extrusion.
  • the heat exchanger can be made from a metal foam, for example, an aluminum foam.
  • the PTCR heater assembly can include a heater assembly cover.
  • the heater assembly cover can comprise a non- electrically conductive material.
  • the heater assembly cover can comprise a non- thermally conductive material.
  • the heater assembly cover can comprise a metal with a non-el ectrically conductive coating isolating the heater assembly cover from the heat exchanger.
  • the heater assembly cover can comprise polytetrafluoroethylene (PTFE).
  • the electrical resistivity transition zone can begin at the first temperature of between 150 °C and 350 °C.
  • the electrical resistivity transition zone can also begin at the first temperature of between 220 °C and 300 °C.
  • the electrical resistivity transition zone can also begin at the first temperature between 240 °C and 280 °C.
  • the first temperature can be greater than 225 °C.
  • the PTCR heating element can be heated to an operating temperature between 240 °C and 280 °C.
  • the PTCR heating element can be heated to an operating temperature between 245 °C and 255 °C.
  • the PTCR heating element can be heated to an operating temperature of about 250 °C.
  • the PTCR heater assembly can increase in the electrical resistivity over the temperature range of the electrical resistivity transition zone by an increase factor of at least 10, an increase factor of at least 100, or an increase factor of at least 1000.
  • the increase factor characterizing a relative change in electrical resistivity between electrical resistivity at the first temperature associated with a start of the electrical resistivity transition zone and electrical resistivity at a second temperature associated with an end of the electrical resistivity transition zone.
  • the electrical resistivity transition zone can begin at the first temperature and end at a second temperature with the difference between the first temperature and the second temperature being 500 °C or less, 200 °C or less, 100 °C or less, or 50 °C or less.
  • the electrical resistivity transition zone can begin at the first temperature and the electrical resistivity of the PTCR heating element at temperatures below the first temperature is between 0.2 ohm-cm and 2.0 ohm-cm, between 2.0 ohm- cm and 20 ohm-cm, or between 20 ohm-cm and 200 ohm-cm.
  • a method of vaporizing a vaporizable material includes receiving, by a vaporizer device, a user input, and heating an airflow to produce a heated airflow using a PTCR heater assembly including a heat exchanger thermally coupled to a PTCR heating element.
  • the PTCR heating element configured to electrically couple to a power source.
  • the PTCR heating element includes an electrical resistivity that varies based on temperature.
  • the electrical resistivity includes an electrical resistivity transition zone including an increase in electrical resistivity over a temperature range from a first temperature to a second temperature such that, when the PTCR heating element is heated between the first temperature and the second temperature, current flow from the power source is reduced to a level that limits further temperature increases of the PTCR heating element from current flow.
  • the method also includes vaporizing the vaporizable material with the heated airflow.
  • the vaporizable material can comprise nicotine.
  • FIG. 1 illustrates the behavior of thermal power generation within an isotropic PTCR material
  • FIG. 2 is a block diagram illustrating an example vaporizer device according to some implementations of the current subject matter that can provide for uniform heating of vaporizable material utilizing convective heating;
  • FIG. 3 is a block diagram of an example vaporizer device and cartridge with liquid vaporizable material that can provide for uniform heating of vaporizable material utilizing convective heating;
  • FIG. 4 is a cross section view of an example vaporizer device with liquid vaporizable material
  • FIG. 5 is a cross section view of an example vaporizer device with solid vaporizable material (e.g., heat-not-burn product);
  • solid vaporizable material e.g., heat-not-burn product
  • FIG. 6 is a block diagram of an example vaporizer device and cartridge with liquid vaporizable material and solid vaporizable material that can provide for uniform heating of vaporizable material utilizing convective heating;
  • FIG. 7 is a block diagram of an example vaporizer device with multiple cartridges
  • FIG. 8 is a cross section view of an example vaporizer device with both liquid vaporizable material and solid vaporizable material;
  • FIG. 9 is a plot illustrating an example resistivity vs. temperature curve for a nonlinear positive temperature coefficient of resistivity (PTCR) material;
  • FIG. 10 presents a table of resistivity vs. temperature curve data for the nonlinear PTCR semiconducting material illustrated in FIG. 9;
  • FIG. 11 is a plot illustrating an example resistivity vs. temperature curve for a nonlinear positive temperature coefficient of resistivity (PTCR) material
  • FIG. 12A is a diagram illustrating an example PTCR heating element that can enable improved vaporizer heating
  • FIG. 12B is a cross section of the example PTCR heating element illustrated in FIG. 9A;
  • FIG. 13 A - FIG. 13E illustrate modeled temperatures of the example PTCR heater
  • FIG. 14A - FIG. 14F illustrate modeled temperatures of an example PTCR heater
  • FIG. 15 illustrates modeled temperatures of an example heater 6.0 seconds after application of a voltage in a free convective state
  • FIG. 16A illustrates a modeled surface temperature as a function of time for an example heater
  • FIG. 16B illustrates a modeled and measured maximum surface temperatures as a function of time of an example heater
  • FIG. 16C illustrates a modeled and measured average surface temperatures as a function of time of an example heater
  • FIG. 17 illustrates a transient current response as a function of time for an example heater
  • FIG. 18 is a perspective view of an example vaporizer assembly including a PTCR heater and heat exchanger elements that can enable convective heating and improved uniform heating of vaporizable materials;
  • FIG. 19 is an exploded view of a rectangular PTCR vaporization device including an exploded view of the example vaporizer assembly
  • FIG. 20 is a perspective view of an example PTCR vaporization assembly
  • FIG. 21 is a perspective, transparent view of an example PTCR vaporization assembly and disposable rectangular product
  • FIG. 22 is a perspective, transparent view of an example PTCR vaporization assembly and disposable rectangular product 0.2 seconds after activation;
  • FIG. 23 is a perspective, transparent view of an example PTCR vaporization assembly and disposable rectangular product 0.5 seconds after activation;
  • FIG. 24 is a perspective, transparent view of an example PTCR vaporization assembly and disposable rectangular product 1.0 seconds after activation;
  • FIG. 25 is a perspective, transparent view of an example PTCR vaporization assembly and disposable rectangular product 2.0 seconds after activation;
  • FIG. 26 is a perspective, transparent view of an example PTCR vaporization assembly and disposable rectangular product 3.0 seconds after activation;
  • FIG. 27 is a perspective view of an example PTCR heater with cylindrical geometry
  • FIG. 28 is an exploded view illustrating a cylindrical example PTCR heater
  • FIG. 29 is a perspective view of the example assembled PTCR heater;
  • FIG. 30 is a perspective view of the example PTCR vaporization device with external covers and cylindrical flow diverter removed;
  • FIG. 31 is a perspective view of the example PTCR vaporization device
  • FIG. 32 is a plot of the logarithm of resistivity of a cylindrical example vaporization device with PTCR heater as a function of temperature
  • FIG. 33 is a cross sectional plot showing temperature simulations of the example implementation of the cylindrical vaporization device with PTCR heater.
  • FIGs. 34A - 34G are cut plots showing transient response of temperature as color for an example implementation of the cylindrical vaporization device with PTCR heater.
  • a vaporizer heater that utilizes a nonlinear positive temperature coefficient of resistivity (PTCR) heating element, also referred to as a PTCR heater, for use as a convective heater.
  • PTCR nonlinear positive temperature coefficient of resistivity
  • a convective heater for a vaporizer air is heated by the heating element and passed over or through a vaporizable material to form a vapor and/or aerosol for inhalation.
  • the vaporizable material may include a solid vaporizable material (e.g., loose-leaf materials commonly utilized in heat-not-bum (HNB) vaporizers) and/or a liquid vaporizable material (e.g., pre-filled cartridges, pods, and the like).
  • a PTCR heating element used for convective heating can enable more uniform heating of the vaporizable material. Improved uniformity in heating can provide a number of advantages, including avoiding differential temperature within vaporizable materials that act as an insulator, prevention of contamination of the heating element, and the like. And because the heating element can be formed from PTCR material, the heating element can be temperature self-limiting and, given a known range of applied voltages, will not heat beyond a specific temperature, thereby avoiding formation of unwanted, and potentially dangerous, chemical byproducts.
  • the thermal power generation within an isotropic PTCR material can be characterized such that, for every control volume dx , dy, dz within an isotropic PTCR material subject to a voltage gradient VP, the control volume dx, dy, dz will heat to a temperature within the PTCR transition zone and hold that temperature within a wide range of VP as illustrated in FIG. 1A.
  • Thermal power generation can be r (VV) 2
  • control volume e.g., dx, dy, dz
  • p resistivity
  • PTCR heating element By utilizing a PTCR heating element some implementations can enable temperature to be controlled over a range of applied voltages and without the need for temperature sensors, electronic circuitry, microprocessors and/or algorithms providing power control to the heating element.
  • solid vaporizable material generally refers to vaporizable material that includes solid materials.
  • some vaporizer devices heat materials having origin as plant leaves or other plant components in order to extract plant specific flavor aromatics and other products as vapor.
  • These plant materials may be chopped and blended into a homogenized construct with a variety of plant products that may include tobacco, in which case nicotine and/or nicotine compounds may be produced and delivered in aerosol form to the user of such a vaporizer device.
  • the homogenized construct may also include vaporizable liquids such as propylene glycol and glycerol in order to enhance the vapor density and aerosol produced when heated.
  • vaporizer devices of this type benefit from heaters having temperature control means.
  • Such vaporizer devices that heat plant leaves or homogenized construct as described above such that temperatures are kept below combustion levels are generally referred to as heat not bum (HNB) devices.
  • HNB heat not bum
  • liquid vaporizable material generally refers to vaporizable material without solid materials.
  • the liquid vaporizable material can include, for example, a liquid, a solution, a wax, or any other form as may be compatible with use of a specific vaporizer device.
  • a liquid vaporizable material can include any form suitable to utilize a wick or wicking element to draw the vaporizable material into a vaporization chamber.
  • the liquid vaporizable material can include a component of plant origin, such as nicotine and/or a nicotine compound.
  • the liquid vaporizable material can include vaporizable liquids such as propylene glycol and glycerol.
  • Vaporizer devices operate by heating the vaporizable material to an appropriate temperature to create an aerosol but without burning or charring of the vaporizable material.
  • One class vaporizer device is more sophisticated in that it utilizes relatively tight temperature control in order to prevent overheating and the related formation of HPHCs.
  • Such sophistication typically requiring electronic circuitry including a microprocessor, is typically difficult in HNB devices because of the inherent non-uniformity and related spatially inconsistent thermal properties of the vaporizable materials to be heated. This results in over temperature regions and potential HPHC production. And some existing solution fail to control local temperatures within vaporizer devices, resulting in a high probability of producing vaporizable material over temperature regions and HPHCs.
  • Another class of vaporizer device is simpler in that no means of temperature control is provided, such that the construction of the vaporizer device may be less expensive but includes a danger of overheating and thereby causing unwanted chemical byproducts.
  • HNB vaporizer devices e.g., where the vaporizable material is solid
  • some existing methods lack the ability to impose uniform temperatures for one or more of the following reasons.
  • to-be-heated solid vaporizable materials have low thermal diffusivity such that diffusion of high temperatures from a heating element into the solid vaporizable materials can be both slow and result in high thermal gradients.
  • non-uniform heating can be an unavoidable consequence.
  • the heating element temperature control typically addresses an average temperature such that heating of non-uniform solid vaporizable material via high temperatures within the heating element can result in high temperatures within the solid vaporizable materials.
  • some existing HNB devices require preheating times that may equal or exceed 30 seconds with accompanying cost in both energy consumption, battery drain, and user inconvenience.
  • a solution to this problem can be to incorporate the heating element into a disposable part of the vaporizer such that the heating element is replaced with each new disposable part and thereby limiting, but not eliminating, heating element contamination.
  • some implementations of the current subject matter can provide for the preheating of air using one or a plurality of PTCR heating elements in conjunction with a heat exchanger.
  • a user draws air into a vaporizer device, the incoming airflow is heated to a controlled temperature as it passes over the heat exchanger and then passes through or over the to-be-heated vaporizable material.
  • the vaporizable material can be a solid material (e.g., as in a HNB material) or a liquid (e.g., fluid with a porous wick).
  • the airflow can pass over the heat exchanger and then pass over and/or through a porous wick saturated with liquid vaporizable material, then through a solid vaporizable material (e.g., a HNB material), and then to the user.
  • a porous wick saturated with liquid vaporizable material e.g., a HNB material
  • geometry for influx of cooling air may be included between the wick and the user, for example, a balanced air inlet (i.e. a second air inlet).
  • the current subject matter can provide for a PTCR heater having intrinsic temperature control such, for a given range of supply voltage (which can be variable by a factor of ten or more in some implementations), a designed peak temperature will not be exceeded. Such an approach can result in improved uniform heating of vaporizable material as compared to some conventional approaches.
  • FIG. 2 is a block diagram illustrating an example vaporizer device 100 according to some implementations of the current subject matter that can provide for uniform heating of vaporizable material utilizing convective heating.
  • the example vaporizer device 100 includes an air inlet 105, a PTCR heater with heat exchanger 110, and a power source 115, such as a battery, capacitor, and/or the like.
  • the example vaporizer device 100 can include a housing 120, which can couple to one or more of the PTCR heater with heat exchanger 110 and power source 115.
  • the example vaporizer device 100 can include an optional controller 102 and an optional pressure sensor 107.
  • the housing 120 can define the air inlet 105.
  • the PTCR heater with heat exchanger 110 can include a heating element formed of PTCR material, which is described in more detail below.
  • the heat exchanger can be thermally coupled to the heating element and can be configured to transfer heat between the heating element and airflow that passes over and/or through the PTCR heater with heat exchanger 110 to produce a heated airflow.
  • the PTCR heater with heat exchanger 110 can include multiple heat exchangers, for example, coupled to different sides of the heating element and can include a flow diverter for diverting the airflow through and/or over fins of the heat exchanger to improve heat transfer. A more detailed discussion of example PTCR heaters with heat exchanger 110 is found below with reference to FIGS. 9-34G.
  • the example vaporizer device 100 can include a connector 117 (shown in FIGs. 4, 5, and 8) for coupling the housing 120 to one or more cartridges 125 that include a vaporizable material 130.
  • the cartridge 125 can include a mouthpiece 135.
  • the coupling is removable such that the cartridge 125 can be coupled and decoupled from the vaporizer device 100 via connector 117 easily and by a user.
  • the vaporizer device 100 and cartridge 125 can be arranged to define an airflow path from the air inlet 105, through and/or over the PTCR heater with heat exchanger 110, through a first air inlet of the cartridge, through the vaporizable material 130, and out the mouthpiece 135.
  • the optional controller 102 e.g., a processor, circuitry, etc., capable of executing logic
  • the optional controller is for controlling delivery of heat to cause a vaporizable material to be converted from a condensed form (e.g., a solid, a liquid, a solution, a suspension, a part of an at least partially unprocessed plant material, etc.) to the gas phase.
  • a condensed form e.g., a solid, a liquid, a solution, a suspension, a part of an at least partially unprocessed plant material, etc.
  • PCBs printed circuit boards
  • Power source 115 can include any source suitable for applying electrical power to the PTCR heater with heat exchanger 110.
  • the power source 115 can include a batter, a capacitor (even with resistor-capacitor (RC) decay), and/or the like.
  • the power source 115 can provide a voltage, which can be chosen from a wide range of voltages.
  • the power source 115 can provide a voltage between 3 volts and 50 volts or more.
  • voltage supplied to the PTCR heater with heat exchanger 110 can vary by an order of magnitude with little effect on the PTCR heater with heat exchanger 110 performance.
  • the power source 115 can include multiple power sources, which can be selected based on operating conditions and/or desired vaporizer device performance.
  • a user can draw air through the mouthpiece 135 (e.g., puff), which can be detected by the optional controller 102 using the optional pressure sensor 107.
  • the optional controller 102 can cause application of current from the power source 115 to the PTCR heater with heat exchanger 110, thereby causing the PTCR heater with heat exchanger 110 to warm. Because the PTCR heater with heat exchanger 110 is formed of PTCR material, heating will be self-limiting and the heating element will not overheat.
  • the airflow passes through the air inlet 105 and over and/or through the PTCR heater with heat exchanger 110, causing air in the airflow to uniformly heat.
  • the heated airflow continues on to the vaporizable material 130 causing the vaporizable material 130 to also uniformly heat and to form a vapor (gas).
  • the vaporizable material 130 can include a liquid, a solution, a solid, a wax, or any other form.
  • incoming air passing along the airflow path passes over, through, and the like, a region or chamber (e.g., an atomizer), where gas phase vaporizable material is entrained into the air.
  • cartridge 125 includes a balanced air inlet (i.e. a second air inlet) 140 that can serve to provide ambient temperature air for mixing with the heated airflow entering the cartridge through a first air inlet.
  • the ambient temperature air can be mixed with the heated airflow in a condensation chamber.
  • the balanced air inlet 140 is positioned after the heated airflow passes through the vaporizable material (e.g., downstream from the heat exchanger and the vaporizable material), thereby cooling the heated airflow prior to inhalation by the user.
  • the balanced air inlet 140 is integrated with mouthpiece 135.
  • Activation of the PTCR heating element may be caused by automatic detection of the puff based on one or more of signals generated by one or more sensors, such as optional pressure sensor 107 or sensors disposed to detect pressure along the airflow path relative to ambient pressure (or optionally to measure changes in absolute pressure), one or more motion sensors of the vaporizer, one or more flow sensors of the vaporizer, a capacitive lip sensor of the vaporizer; in response to detection of interaction of a user with one or more input devices (e.g., buttons or other tactile control devices of the vaporizer such as a manual toggle switch, pushbutton switch, pressure switch, and the like), receipt of signals from a computing device in communication with the vaporizer; and/or via other approaches for determining that a puff is occurring or imminent.
  • sensors such as optional pressure sensor 107 or sensors disposed to detect pressure along the airflow path relative to ambient pressure (or optionally to measure changes in absolute pressure), one or more motion sensors of the vaporizer, one or more flow sensors of the vaporizer, a capacitive
  • a vaporizer consistent with implementations of the current subject matter may be configured to connect (e.g., wirelessly or via a wired connection) to a computing device (or optionally two or more devices) in communication with the vaporizer.
  • the optional controller 102 may include communication hardware.
  • the optional controller 102 may also include a memory.
  • a computing device can be a component of a vaporizer system that also includes the vaporizer, and can include its own communication hardware, which can establish a wireless communication channel with the communication hardware of the vaporizer.
  • a computing device used as part of a vaporizer system may include a general purpose computing device (e.g., a smartphone, a tablet, a personal computer, some other portable device such as a smartwatch, or the like) that executes software to produce a user interface for enabling a user of the device to interact with a vaporizer.
  • a general purpose computing device e.g., a smartphone, a tablet, a personal computer, some other portable device such as a smartwatch, or the like
  • a general purpose computing device e.g., a smartphone, a tablet, a personal computer, some other portable device such as a smartwatch, or the like
  • such a device used as part of a vaporizer system can be a dedicated piece of hardware such as a remote control or other wireless or wired device having one or more physical or soft (e.g., configurable on a screen or other display device and selectable via user interaction with a touch-sensitive screen or some other input device like a mouse, pointer, trackball, cursor buttons, or the like) interface controls.
  • the vaporizer can also include one or more output features or devices for providing information to the user.
  • a computing device that is part of a vaporizer system as defined above can be used for any of one or more functions, such as controlling dosing (e.g., dose monitoring, dose setting, dose limiting, user tracking, etc.), controlling sessioning (e.g., session monitoring, session setting, session limiting, user tracking, and the like), controlling nicotine delivery (e.g., switching between nicotine and non-nicotine vaporizable material, adjusting an amount of nicotine delivered, and the like), obtaining locational information (e.g., location of other users, retailer/commercial venue locations, vaping locations, relative or absolute location of the vaporizer itself, and the like), vaporizer personalization (e.g., naming the vaporizer, locking/password protecting the vaporizer, adjusting one or more parental controls, associating the vaporizer with a user group, registering the vaporizer with a manufacturer or warranty maintenance organization, and the like), engaging in social activities (e.g., games, social media communications, interacting with one or more groups,
  • the terms“sessioning”,“session”,“vaporizer session,” or “vapor session,” are used genetically to refer to a period devoted to the use of the vaporizer.
  • the period can include a time period, a number of doses, an amount of vaporizable material, and/or the like.
  • a computing device provides signals related to activation of the PTCR heating element
  • the computing device executes one or more computer instructions sets to provide a user interface and underlying data handling.
  • detection by the computing device of user interaction with one or more user interface elements can cause the computing device to signal the vaporizer to activate the PTCR heating element to a full operating temperature for creation of an inhalable dose of vapor/aerosol.
  • Other functions of the vaporizer may be controlled by interaction of a user with a user interface on a computing device in communication with the vaporizer.
  • the temperature of a PTCR heating element of a vaporizer may depend on a number of factors, including conductive heat transfer to other parts of the electronic vaporizer and/or to the environment, latent heat losses due to vaporization of a vaporizable material from the wicking element and/or the atomizer as a whole, and convective heat losses due to airflow (e.g., air moving across the heating element or the atomizer as a whole when a user inhales on the electronic vaporizer).
  • a vaporizer may, in some implementations of the current subject matter, make use of signals from optional pressure sensor 107 to determine when a user is inhaling.
  • the optional pressure sensor 107 can be positioned in the airflow path and/or can be connected (e.g., by a passageway or other path) to an airflow path connecting air inlet 105 for air to enter the device and an outlet (e.g., in mouthpiece 135) via which the user inhales the resulting vapor and/or aerosol such that the optional pressure sensor experiences pressure changes concurrently with air passing through the vaporizer device from the air inlet 105 to the air outlet.
  • the PTCR heating element may be optionally activated in association with a user’s puff, for example by automatic detection of the puff, for example by the optional pressure sensor 107 detecting a pressure change in the airflow path.
  • a switch is an input device that may be used to electrically complete a circuit between the power source and the PTCR heating element.
  • an input device that includes a relay, a solenoid, and/or a solid-state device that may be used to electrically complete a circuit between the power source and the PTCR heating element to activate the vaporizer device.
  • the optional pressure sensor 107 (as well as any other sensors) can be positioned on or coupled (e.g., electrically or electronically connected, either physically or via a wireless connection) to the optional controller 102 (e.g., a printed circuit board assembly or other type of circuit board).
  • the optional controller 102 e.g., a printed circuit board assembly or other type of circuit board.
  • the seal which can be a gasket, may be configured to at least partially surround the optional pressure sensor 107 such that connections of the optional pressure sensor 107 to internal circuitry of the vaporizer are separated from a part of the optional pressure sensor 107 exposed to the airflow path.
  • the seal or gasket may also separate parts of one or more electrical connections between a vaporizer body and a vaporizer cartridge.
  • Such arrangements of a gasket or seal in a vaporizer can be helpful in mitigating against potentially disruptive impacts on vaporizer components resulting from interactions with environmental factors such as water in the vapor or liquid phases, other fluids such as the vaporizable material, etc., and/or to reduce escape of air from the designed airflow path in the vaporizer.
  • Unwanted air, liquid or other fluid passing and/or contacting circuitry of the vaporizer can cause various unwanted effects, such as alter pressure readings, and/or can result in the buildup of unwanted material, such as moisture, the vaporizable material, etc., in parts of the vaporizer where they may result in poor pressure signal, degradation of the optional pressure sensor or other components, and/or a shorter life of the vaporizer.
  • Leaks in the seal or gasket can also result in a user inhaling air that has passed over parts of the vaporizer device containing or constructed of materials that may not be desirable to be inhaled.
  • the cartridge 125 can include a fibrous body for cooling the heated airflow after it passes through the vaporizable material 130.
  • the vaporizable material 130 can include solid vaporizable material (e.g., HNB materials) and/or liquid vaporizable material (e.g., a liquid, a solution, and the like).
  • FIG. 3 is a block diagram of an example vaporizer device 100 and cartridge 125 with liquid vaporizable material that can provide for uniform heating of vaporizable material utilizing convective heating.
  • the vaporizable material 130 includes an atomizer including a porous wick 150 in fluidic communication with a fluid tank or reservoir 145. The porous wick 150 is located within the path of the heated airflow between the PTCR heater with heat exchanger 110 and the mouthpiece 135.
  • the porous wick 150 is located such that, in operation, heated airflow passes over and/or through the porous wick 150, which is saturated with the vaporizable fluid, causing vaporization of the liquid vaporizable material saturating the porous wick 150 thereby forming a vapor and/or aerosol.
  • the porous wick 150 may allow air to enter the reservoir 145 to replace the volume of liquid removed.
  • capillary action pulls liquid vaporizable material into the wick 150 for vaporization by the heated airflow, and air may, in some implementations of the current subject matter, return to the reservoir 145 through the wick to at least partially equalize pressure in the reservoir 145.
  • FIG. 4 is a cross section view of an example vaporizer device with liquid vaporizable material
  • FIG. 5 is a cross section view of an example vaporizer device with solid vaporizable material (e.g., HNB product).
  • the vaporizable material 130 can include both a liquid vaporizable material and a solid vaporizable material.
  • FIG. 6 is a block diagram of an example vaporizer device 100 and cartridge 125 with liquid vaporizable material and solid vaporizable material that can provide for uniform heating of vaporizable material utilizing convective heating.
  • the vaporizable material 130 includes a reservoir 145 containing liquid vaporizable material within the reservoir 145, a wick 150 in fluidic communication with the liquid vaporizable material, and a solid vaporizable material 155 located downstream (with respect to airflow) of the porous wick 150.
  • the porous wick 150 is arranged to receive the heated airflow from the heater with heat exchanger 110 to vaporize the vaporizable material to produce a vapor and/or a first aerosol.
  • the solid vaporizable material 155 is arranged to receive the vapor and/or the first aerosol from the wick and to produces second aerosol.
  • the mouthpiece 135 is configured to receive the second aerosol after the vaporized vaporizable material passes through the solid vaporizable material 155.
  • FIG. 7 is a block diagram of an example vaporizer device 100 with multiple cartridges.
  • a first cartridge 605 includes liquid vaporizable material (including reservoir 145 and porous wick 150) and a second cartridge 610 includes solid vaporizable material 130 that can provide for uniform heating of vaporizable material utilizing convective heating.
  • the first cartridge 605 can removably couple to the vaporizer device 100 and the second cartridge 610 can removably couple to the first cartridge 605.
  • the first cartridge 605 includes the reservoir 145 (e.g., tank), liquid vaporizable material within the reservoir 145, and the wick 150 in fluidic communication with the liquid vaporizable material.
  • the wick 150 is arranged to receive the heated airflow from the heater with heat exchanger 110 to vaporize the vaporizable material to produce a vapor and/or a first aerosol.
  • the second cartridge 610 includes the solid vaporizable material 130, balanced air inlet 140, and mouthpiece 135.
  • the solid vaporizable material 130 is arranged to receive the vapor and/or the first aerosol from the wick 150 and to produce a second aerosol.
  • the mouthpiece 135 is configured to receive the second aerosol after the vapor and/or the first aerosol passes through the solid vaporizable material 155.
  • the balanced air inlet (i.e. the second air inlet) 140 can provide ambient temperature air for cooling the heated second aerosol having passed through the solid vaporizable material 155.
  • FIG. 8 is a cross section view of an example vaporizer device with both liquid vaporizable material and solid vaporizable material.
  • This convective heating approach can provide several advantages for vaporizing solid materials (e.g., HNB materials), as compared to conventional conductive heating approaches. For example, instead of poor conduction into insulative material (e.g., solid vaporizable material) in a direction normal to airflow, producing volatiles and differential porosity of the to-be-heated vaporizable material, some implementations of the current subject matter can provide incoming preheated air that enters the vaporizable material uniformly as a wave uniformly covering the cross- section of the vaporizable material. Volatiles are then released, coincident with increase in porosity, in a direction parallel to the flow of heated air.
  • insulative material e.g., solid vaporizable material
  • the problem of differential flow path can be eliminated in some implementations.
  • the problem of deteriorating conductive heat transfer through the product can be removed in some implementations of the current subject matter.
  • some implementations of the current subject matter can eliminate a previously required preheating period, such that the current subject matter may provide aerosol on-demand from heated vaporizable material.
  • this convective heating approach can provide several advantages for vaporizing liquid vaporizable materials. For example, instead of applying heat directly to the liquid vaporizable material using a heater element in direct contact with the liquid vaporizable material, some implementations of the current subject matter can provide incoming preheated air as a wave uniformly covering the cross-section of the porous wick saturated with the fluid to be vaporized, thereby avoiding differential temperatures and potential for heating element contamination.
  • intrinsic temperature control behavior of the PTCR heater can simplify the electrical power delivery circuitry in that no specific thermal feedback is required.
  • Electrical power delivery circuitry to PTCR heater can be further simplified by eliminating the need, typical of electrical power delivery systems, for the power source to provide relatively constant voltage.
  • applied voltage may vary by more than an order of magnitude without significantly affecting resulting heater element temperatures.
  • PTCR includes semiconducting materials that possess an electrical resistivity that changes nonlinearly with increasing temperature.
  • Typical PTCR material resistivity is relatively low while temperature remains below a temperature transition zone. Above the temperature transition zone, the PTCR material resistivity is higher than the resistivity of the same PTCR material at temperatures below the temperature transition zone.
  • the resistivity change can be orders of magnitude increase over a temperature transition zone of 50 degrees Celsius or less.
  • a heating element can utilize nonlinear PTCR material to enable intrinsic temperature control.
  • a heating element at an ambient temperature can be connected to a power source providing a voltage gradient and resulting current flow. Because the resistivity of the heating element is relatively low at ambient temperature (e.g., ambient temperature is below the transition zone), current will flow through the heating element. As current flows through the nonlinear PTCR material, heat is generated by resistance (e.g., dissipation of electrical power). The generated heat raises the temperature of the heating element, thereby causing the resistivity of the heating element to change. When the temperature of the heating element reaches the transition zone, the resistivity increases significantly over a small temperature range. The change in resistivity can be caused by the physical properties of the material.
  • a phase transition may occur in the material.
  • Such an increase in resistivity reduces current flow such that heat generation is reduced.
  • the transition zone includes a temperature at which there is an inflection point such that heat generation will be insufficient to further raise the temperature of the heating element, thereby limiting the temperature of the heating element. So long as the power source remains connected and supplying current, the heating element will maintain a uniform temperature with minimal temperature variance.
  • the temperature of the PTCR heating element drops thereby reducing the resistance thereby increasing the current flow through the PTCR heating element.
  • the temperature of the PTCR heating element increases thereby increasing the resistance thereby decreasing the current flow through the PTCR heating element.
  • the resistance of the PTCR heating element increase logarithmically.
  • the operating temperature at which a PTCR heating element is limited can be affected by the element materials, element geometry, element resistivity as a function of temperature characteristics, power source, circuit characteristics (e.g., voltage gradient, current, time-variance properties), and the like.
  • FIG. 9 is a plot illustrating an example resistivity vs. temperature curve for a nonlinear PTCR material.
  • the vertical axis is logarithmic.
  • a heating element constructed (e.g., formed) of a nonlinear PTCR material can include advantageous characteristics. For example, with application of sufficient voltage gradient (e.g., VV), a PTCR heater will generate heat and increase in temperature until the transition zone is reached. In the curve illustrated in FIG. 9, the transition zone spans between temperatures Ti and T2. In the curve illustrated in FIG. 9, the resistivity versus temperature curve appears nonlinear between Ti and T2, but in other embodiments, the resistivity versus temperature curve may be near linear or linear or other shapes.
  • implementations of a PTCR heater can be considered to be temperature self-limiting and, given a known range of applied voltages, will not heat beyond a temperature just above the low point Ti of the temperature transition zone.
  • Performance of a PTCR heater can depend on PTCR behavior as in FIG. 9 and on heater geometry.
  • a PTCR heater having relatively long and narrow geometry and with electrical contacts for applying differential voltage at each end of the longer dimension of the PTCR heater can be ineffective in that resistivity of nonlinear PTCR materials is typically too high at temperatures below Ti.
  • Nonlinear PTCR materials having steep transition zones where the temperature difference between Ti and T2 is less than 10° C may cause all voltage drop to be within a small fraction of the length of said long and narrow geometry and given inevitable spatial nonuniformities within any material. Therefore, some implementations of a PTCR heater include an electrode construct for a PTCR heater such that a nonlinear PTCR material is provided within a parallel circuit.
  • the PTCR heater geometry can include a thin section of nonlinear PTCR material sandwiched between electrical conductors or electrically conductive coatings to which differential voltages may be applied.
  • FIG. 10 presents a table of resistivity vs. temperature curve data for the nonlinear PTCR semiconducting material illustrated in FIG. 9.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 100 ohm-cm at 100 °C and a resistivity of between 50000 ohm-cm and 150000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 20 ohm-cm and 200 ohm-cm at 100 °C and a resistivity of between 100000 ohm-cm and 200000 ohm-cm at 265 °C.
  • the PTCR heating element has a resistivity of less than 100 ohm-cm at 100 °C and a resistivity greater than 100000 ohm-cm at 260 °C. In implementations, the PTCR heating element has a resistivity of less than 100 ohm-cm at 100 °C and a resistivity greater than 250000 ohm-cm at 275 °C. In implementations, the PTCR heating element has a resistivity of less than 100 ohm-cm at 100 °C and a resistivity greater than 300000 ohm-cm at 295 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 110 ohm-cm at 25 °C and a resistivity of between 10 ohm-cm and 110 ohm-cm at 100 °C and a resistivity of between 100000 ohm-cm and 325000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 150 ohm-cm at 25 °C and a resistivity of between 10 ohm-cm and 150 ohm-cm at 100 °C and a resistivity of between 100000 ohm-cm and 350000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 200 ohm-cm at 25 °C and a resistivity of between 10 ohm-cm and 200 ohm-cm at 100 °C and a resistivity of between 100000 ohm-cm and 375000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 300 ohm-cm at 25 °C and a resistivity of between 10 ohm-cm and 300 ohm-cm at 100 °C and a resistivity of between 100000 ohm-cm and 400000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 400 ohm-cm at 25 °C and a resistivity of between 10 ohm-cm and 400 ohm-cm at 100 °C and a resistivity of between 100000 ohm-cm and 450000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 500 ohm-cm at 25 °C and a resistivity of between 10 ohm-cm and 500 ohm-cm at 100 °C and a resistivity of between 100000 ohm-cm and 500000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 110 ohm-cm at 25 °C and a resistivity of between 50 ohm-cm and 110 ohm-cm at 100 °C and a resistivity of between 150000 ohm-cm and 325000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 150 ohm-cm at 25 °C and a resistivity of between 50 ohm-cm and 150 ohm-cm at 100 °C and a resistivity of between 150000 ohm-cm and 350000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 200 ohm-cm at 25 °C and a resistivity of between 50 ohm-cm and 200 ohm-cm at 100 °C and a resistivity of between 150000 ohm-cm and 375000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 300 ohm-cm at 25 °C and a resistivity of between 50 ohm-cm and 300 ohm-cm at 100 °C and a resistivity of between 150000 ohm-cm and 400000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 400 ohm-cm at 25 °C and a resistivity of between 50 ohm-cm and 400 ohm-cm at 100 °C and a resistivity of between 150000 ohm-cm and 450000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 500 ohm-cm at 25 °C and a resistivity of between 50 ohm-cm and 500 ohm-cm at 100 °C and a resistivity of between 150000 ohm-cm and 500000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 90 ohm-cm and 110 ohm-cm at 25 °C and a resistivity of between 90 ohm-cm and 110 ohm-cm at 100 °C and a resistivity of between 200000 ohm-cm and 325000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 90 ohm-cm and 150 ohm-cm at 25 °C and a resistivity of between 90 ohm-cm and 150 ohm-cm at 100 °C and a resistivity of between 200000 ohm-cm and 350000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 90 ohm-cm and 200 ohm-cm at 25 °C and a resistivity of between 90 ohm-cm and 200 ohm-cm at 100 °C and a resistivity of between 200000 ohm-cm and 375000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 90 ohm-cm and 300 ohm-cm at 25 °C and a resistivity of between 90 ohm-cm and 300 ohm-cm at 100 °C and a resistivity of between 200000 ohm-cm and 400000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 90 ohm-cm and 400 ohm-cm at 25 °C and a resistivity of between 90 ohm-cm and 400 ohm-cm at 100 °C and a resistivity of between 200000 ohm-cm and 450000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 90 ohm-cm and 500 ohm-cm at 25 °C and a resistivity of between 90 ohm-cm and 500 ohm-cm at 100 °C and a resistivity of between 200000 ohm-cm and 500000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 110 ohm-cm at 50 °C and a resistivity of between 10 ohm-cm and 50 ohm-cm at 150 °C and a resistivity of between 50000 ohm-cm and 125000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 150 ohm-cm at 50 °C and a resistivity of between 10 ohm-cm and 100 ohm-cm at 150 °C and a resistivity of between 50000 ohm-cm and 150000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 200 ohm-cm at 50 °C and a resistivity of between 10 ohm-cm and 150 ohm-cm at 150 °C and a resistivity of between 50000 ohm-cm and 175000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 300 ohm-cm at 50 °C and a resistivity of between 10 ohm-cm and 200 ohm-cm at 150 °C and a resistivity of between 50000 ohm-cm and 200000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 400 ohm-cm at 50 °C and a resistivity of between 10 ohm-cm and 250 ohm-cm at 150 °C and a resistivity of between 50000 ohm-cm and 250000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 500 ohm-cm at 50 °C and a resistivity of between 10 ohm-cm and 300 ohm-cm at 150 °C and a resistivity of between 50000 ohm-cm and 300000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 110 ohm-cm at 50 °C and a resistivity of between 20 ohm-cm and 50 ohm-cm at 150 °C and a resistivity of between 75000 ohm-cm and 125000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 150 ohm-cm at 50 °C and a resistivity of between 20 ohm-cm and 100 ohm-cm at 150 °C and a resistivity of between 75000 ohm-cm and 150000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 200 ohm-cm at 50 °C and a resistivity of between 20 ohm-cm and 150 ohm-cm at 150 °C and a resistivity of between 75000 ohm-cm and 175000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 300 ohm-cm at 50 °C and a resistivity of between 20 ohm-cm and 200 ohm-cm at 150 °C and a resistivity of between 75000 ohm-cm and 200000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 400 ohm-cm at 50 °C and a resistivity of between 20 ohm-cm and 250 ohm-cm at 150 °C and a resistivity of between 75000 ohm-cm and 250000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 500 ohm-cm at 50 °C and a resistivity of between 20 ohm-cm and 300 ohm-cm at 150 °C and a resistivity of between 75000 ohm-cm and 300000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 75 ohm-cm and 110 ohm-cm at 50 °C and a resistivity of between 30 ohm-cm and 50 ohm-cm at 150 °C and a resistivity of between 100000 ohm-cm and 125000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 75 ohm-cm and 150 ohm-cm at 50 °C and a resistivity of between 30 ohm-cm and 100 ohm-cm at 150 °C and a resistivity of between 100000 ohm-cm and 150000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 75 ohm-cm and 200 ohm-cm at 50 °C and a resistivity of between 30 ohm-cm and 150 ohm-cm at 150 °C and a resistivity of between 100000 ohm-cm and 175000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 75 ohm-cm and 300 ohm-cm at 50 °C and a resistivity of between 30 ohm-cm and 200 ohm-cm at 150 °C and a resistivity of between 100000 ohm-cm and 200000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 75 ohm-cm and 400 ohm-cm at 50 °C and a resistivity of between 30 ohm-cm and 250 ohm-cm at 150 °C and a resistivity of between 100000 ohm-cm and 250000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 75 ohm-cm and 500 ohm-cm at 50 °C and a resistivity of between 30 ohm-cm and 300 ohm-cm at 150 °C and a resistivity of between 100000 ohm-cm and 300000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 110 ohm-cm at 25 °C and a resistivity of between 10 ohm-cm and 50 ohm-cm at 150 °C and a resistivity of between 100000 ohm-cm and 325000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 150 ohm-cm at 25 °C and a resistivity of between 10 ohm-cm and 100 ohm-cm at 150 °C and a resistivity of between 100000 ohm-cm and 350000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 200 ohm-cm at 25 °C and a resistivity of between 10 ohm-cm and 150 ohm-cm at 150 °C and a resistivity of between 100000 ohm-cm and 375000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 300 ohm-cm at 25 °C and a resistivity of between 10 ohm-cm and 200 ohm-cm at 150 °C and a resistivity of between 100000 ohm-cm and 400000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 400 ohm-cm at 25 °C and a resistivity of between 10 ohm-cm and 250 ohm-cm at 150 °C and a resistivity of between 100000 ohm-cm and 450000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 500 ohm-cm at 25 °C and a resistivity of between 10 ohm-cm and 300 ohm-cm at 150 °C and a resistivity of between 100000 ohm-cm and 500000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 110 ohm-cm at 25 °C and a resistivity of between 20 ohm-cm and 50 ohm-cm at 150 °C and a resistivity of between 150000 ohm-cm and 325000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 150 ohm-cm at 25 °C and a resistivity of between 20 ohm-cm and 100 ohm-cm at 150 °C and a resistivity of between 150000 ohm-cm and 350000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 200 ohm-cm at 25 °C and a resistivity of between 20 ohm-cm and 150 ohm-cm at 150 °C and a resistivity of between 150000 ohm-cm and 375000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 300 ohm-cm at 25 °C and a resistivity of between 20 ohm-cm and 200 ohm-cm at 150 °C and a resistivity of between 150000 ohm-cm and 400000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 400 ohm-cm at 25 °C and a resistivity of between 20 ohm-cm and 250 ohm-cm at 150 °C and a resistivity of between 150000 ohm-cm and 450000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 500 ohm-cm at 25 °C and a resistivity of between 20 ohm-cm and 300 ohm-cm at 150 °C and a resistivity of between 150000 ohm-cm and 500000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 90 ohm-cm and 110 ohm-cm at 25 °C and a resistivity of between 30 ohm-cm and 50 ohm-cm at 150 °C and a resistivity of between 200000 ohm-cm and 325000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 90 ohm-cm and 150 ohm-cm at 25 °C and a resistivity of between 30 ohm-cm and 100 ohm-cm at 150 °C and a resistivity of between 200000 ohm-cm and 350000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 90 ohm-cm and 200 ohm-cm at 25 °C and a resistivity of between 30 ohm-cm and 150 ohm-cm at 150 °C and a resistivity of between 200000 ohm-cm and 375000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 90 ohm-cm and 300 ohm-cm at 25 °C and a resistivity of between 30 ohm-cm and 200 ohm-cm at 150 °C and a resistivity of between 200000 ohm-cm and 400000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 90 ohm-cm and 400 ohm-cm at 25 °C and a resistivity of between 30 ohm-cm and 250 ohm-cm at 150 °C and a resistivity of between 200000 ohm-cm and 450000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 90 ohm-cm and 500 ohm-cm at 25 °C and a resistivity of between 30 ohm-cm and 300 ohm-cm at 150 °C and a resistivity of between 200000 ohm-cm and 500000 ohm-cm at 280 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 110 ohm-cm at 50 °C and a resistivity of between 10 ohm-cm and 110 ohm-cm at 100 °C and a resistivity of between 50000 ohm-cm and 125000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 150 ohm-cm at 50 °C and a resistivity of between 10 ohm-cm and 150 ohm-cm at 100 °C and a resistivity of between 50000 ohm-cm and 150000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 200 ohm-cm at 50 °C and a resistivity of between 10 ohm-cm and 200 ohm-cm at 100 °C and a resistivity of between 50000 ohm-cm and 175000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 300 ohm-cm at 50 °C and a resistivity of between 10 ohm-cm and 300 ohm-cm at 100 °C and a resistivity of between 50000 ohm-cm and 200000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 400 ohm-cm at 50 °C and a resistivity of between 10 ohm-cm and 400 ohm-cm at 100 °C and a resistivity of between 50000 ohm-cm and 250000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 10 ohm-cm and 500 ohm-cm at 50 °C and a resistivity of between 10 ohm-cm and 500 ohm-cm at 100 °C and a resistivity of between 50000 ohm-cm and 300000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 110 ohm-cm at 50 °C and a resistivity of between 50 ohm-cm and 110 ohm-cm at 100 °C and a resistivity of between 75000 ohm-cm and 125000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 150 ohm-cm at 50 °C and a resistivity of between 50 ohm-cm and 150 ohm-cm at 100 °C and a resistivity of between 75000 ohm-cm and 150000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 200 ohm-cm at 50 °C and a resistivity of between 50 ohm-cm and 200 ohm-cm at 100 °C and a resistivity of between 75000 ohm-cm and 175000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 300 ohm-cm at 50 °C and a resistivity of between 50 ohm-cm and 300 ohm-cm at 100 °C and a resistivity of between 75000 ohm-cm and 200000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 400 ohm-cm at 50 °C and a resistivity of between 50 ohm-cm and 400 ohm-cm at 100 °C and a resistivity of between 75000 ohm-cm and 250000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 50 ohm-cm and 500 ohm-cm at 50 °C and a resistivity of between 50 ohm-cm and 500 ohm-cm at 100 °C and a resistivity of between 75000 ohm-cm and 300000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 75 ohm-cm and 110 ohm-cm at 50 °C and a resistivity of between 90 ohm-cm and 110 ohm-cm at 100 °C and a resistivity of between 100000 ohm-cm and 125000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 75 ohm-cm and 150 ohm-cm at 50 °C and a resistivity of between 90 ohm-cm and 150 ohm-cm at 100 °C and a resistivity of between 100000 ohm-cm and 150000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 75 ohm-cm and 200 ohm-cm at 50 °C and a resistivity of between 90 ohm-cm and 200 ohm-cm at 100 °C and a resistivity of between 100000 ohm-cm and 175000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 75 ohm-cm and 300 ohm-cm at 50 °C and a resistivity of between 90 ohm-cm and 300 ohm-cm at 100 °C and a resistivity of between 100000 ohm-cm and 200000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 75 ohm-cm and 400 ohm-cm at 50 °C and a resistivity of between 90 ohm-cm and 400 ohm-cm at 100 °C and a resistivity of between 100000 ohm-cm and 250000 ohm-cm at 260 °C.
  • the PTCR heating element has a resistivity of between 75 ohm-cm and 500 ohm-cm at 50 °C and a resistivity of between 90 ohm-cm and 500 ohm-cm at 100 °C and a resistivity of between 100000 ohm-cm and 300000 ohm-cm at 260 °C.
  • FIG. 11 illustrates another example PTCR resistivity versus temperature curve.
  • the PTCR material has a density of 5700 kg/m3, a heat capacity of 520 J/kg K, and a thermal conductivity of 2.1 W/m K.
  • the coefficient of resistivity begins to initially increase at a temperature after about 440 K and then sharply increases between 503 K and 518 K.
  • the resistivity of the PTCR material forming the PTCR heating element is 0.168 ohm-m, and at 373 K the resistivity of the PTCR material forming the PTCR heating element is 0.105 ohm-m, and at 518 K the resistivity of the PTCR material forming the PTCR heating element is 3.669 ohm- m.
  • the PTCR material has a density between 5000 kg/m3 and 7000 kg/m3, a heat capacity between 450 J/kg K and 600 J/kg K, and a thermal conductivity between 1.5 W/m K and 3.0 W/m K.
  • FIG. 12A is a diagram illustrating an example PTCR heating element 50 that can enable improved vaporizer heating.
  • a thin section of nonlinear PTCR material 10 is shown in FIG. 12A, where nonlinear PTCR material 10 is sandwiched between electrically conductive layers 20, which in turn are attached to conductive leads 30 such that conductive leads 30 may have differential voltage applied.
  • FIG. 9B is a cross section of the example PTCR heating element 50 illustrated in FIG. 12 A.
  • a PTCR heater 50 includes the geometry illustrated in FIG. 12A with nonlinear PTCR material thickness of 0.5 mm (height) and 5.0 mm (length and width) in the other dimensions.
  • the nonlinear PTCR material electrical characteristics includes these values: Ti value between 150 °C and 300 °C, such as between 220 °C and 280 °C; resistivity at temperatures below Ti between 0.01 Ohm-m and 100 Ohm-m, such as between 0.1 Ohm-m and 1 Ohm-m; resistivity change between Ti and T2 having an increase of a factor exceeding 10 such as exceeding 100; and temperature difference between Ti and T2 less than 200 °C such as less than 50 °C.
  • FIG. 13 A - FIG. 13E illustrate modeled temperatures of the example PTCR heater 50.
  • the nonlinear PTCR material 10 included a plate geometry with dimensions of 5 mm x 5 mm x 0.5 mm; the conductive layers 20 were formed of silver (Ag) with dimensions of 5 mm x 5 mm x 0.025 mm; and the conductive leads 30 were formed of copper (CU) with dimensions of 12 mm x 2 mm x 0.2 mm.
  • the nonlinear PTCR material 10 included a PTCR resistivity versus temperature curve as illustrated in FIG. 32, with a nonlinear transition zone of about 240 °C to about 300 °C.
  • FIG. 13 A - FIG. 13E illustrate respectively 0.0, 0.2, 0.5, 1.0, and 2.0 seconds after application of the voltage differential.
  • the temperature beyond 1.0 second is relatively uniform and the peak temperatures at the surface of conductive layers 20 is less than 270 °C.
  • FIG. 14A - FIG. 14F illustrate modeled temperatures of another example of a PTCR heater 50.
  • a gradient temperature scale is shown on the left side of each figure with red representing the hottest temperature of about 255 °C and continues through the colors of the visible light spectrum in order (i.e. red, orange, yellow, green, blue, and violet) to the coolest temperature of about 23 °C.
  • the nonlinear PTCR material 10 includes a plate geometry with dimensions of about 5 mm x 5 mm x 0.5 mm; the conductive layers 20 were formed of silver (Ag) with dimensions of about 5 mm x 5 mm x 0.025 mm; and the conductive leads 30 were formed of copper (CU) with dimensions of about 12 mm x 2 mm x 0.2 mm.
  • the plate geometry can include two parallel sides including conductive layers 20 with conductive leads 30 attached thereto.
  • the conductive leads 30 are centrally attached to conductive layers 20 on each side of the PTCR heating element 50 with a connection 40.
  • the connection 40 is a clamp, a clip, a conductive paste, a high-temperature, lead-free solder, and/or combinations thereof.
  • FIG. 14A illustrates the temperature 1.0 second after activation by applying a current to the PTCR heating element 50.
  • the violet colored conductive leads 30 are still about 25 °C.
  • the majority of the PTCR material 10 and conductive layer 20 has increased in temperature to about 120 °C, with the area including connection 40 in the center being slightly cooler at a temperature around 80 °C.
  • FIG. 14B illustrates the temperature 2.0 seconds after activation by applying a current to the PTCR heating element 50.
  • the blue/green colored conductive leads 30 have increased in temperature to about 90 °C.
  • the majority of the PTCR material 10 and conductive layer 20 has increased in temperature to about 210 °C, with the area including connection 40 in the center being cooler at a temperature around 160 °C.
  • FIG. 14C illustrates the temperature 3.0 seconds after activation by applying a current to the PTCR heating element 50.
  • the green colored conductive leads 30 have increased in temperature to about 140 °C.
  • the majority of the PTCR material 10 and conductive layer 20 has increased in temperature to about 250 °C, with the area including connection 40 in the center being cooler at a temperature around 200 °C.
  • FIG. 14D illustrates the temperature 4.0 seconds after activation by applying a current to the PTCR heating element 50.
  • the green colored conductive leads 30 have increased in temperature to about 160 °C.
  • the majority of the PTCR material 10 and conductive layer 20 remains at temperature to about 250 °C, with the area including connection 40 in the center being cooler at a temperature around 215 °C.
  • FIG. 14E illustrates the temperature 5.0 seconds after activation by applying a current to the PTCR heater 50.
  • the green/yellow colored conductive leads 30 have increased in temperature to about 180 °C.
  • the majority of the PTCR material 10 and conductive layer 20 remains at temperature to about 250 °C, with the area including connection 40 in the center being slightly cooler at a temperature around 225 °C.
  • FIG. 14F illustrates the temperature 6.0 seconds after activation by applying a current to the PTCR heating element 50.
  • the yellow colored conductive leads 30 have increased in temperature to about 200 °C.
  • the majority of the PTCR material 10 and conductive layer 20 remains at temperature to about 250 °C, with the area including connection 40 in the center being just slightly cooler at a temperature around 235 °C.
  • FIG. 15 illustrates modeled temperatures of an example heater 6.0 seconds after application of a voltage in a free convective state.
  • FIG. 16A illustrates a modeled surface temperature as a function of time for an example PTCR heating element.
  • the surface temperature of the PTCR heater starts at 25 °C (i.e. room temperature) at time zero. After an electrical current is applied, the surface temperature increases linearly for about 2 seconds to a temperature of about 225 °C. After about 2 seconds, the rate of the temperature increase tapers off to a steady-state operating temperature of about 250 °C that is achieve about 3 seconds after activation.
  • the nonlinear PTCR material is in a non-contact, free convective state, and the emitted radiation was measured from a distance.
  • the PTCR heating element is heated to an operating temperature between 240 °C and 280 °C. In implementations, the PTCR heating element is heated to an operating temperature between 245 °C and 255 °C. In implementations, the PTCR heating element is heated to an operating temperature about 250 °C.
  • FIG. 16B illustrates a modeled and measured maximum surface temperatures as a function of time for an example PTCR heater.
  • Four measurements were repeated using an infrared camera to measure the maximum surface temperatures of the PTCR heater as a function of time, which were then plotted against the model of the maximum surface temperature.
  • the nonlinear PTCR material is in a non-contact, free convective state and the emitted radiation was measured from a distance.
  • the maximum surface temperature of the PTCR heating element starts at about 25 °C (i.e. room temperature) at time zero. After an electrical current is applied, the maximum surface temperature increases linearly for about 2 seconds to a temperature of about 225 °C.
  • the rate of the temperature increase tapers off to a steady-state operating temperature of about 250 °C that is achieve about 3 seconds after activation.
  • the PTCR heating element is heated to an operating temperature between 240 °C and 280 °C. In implementations, the PTCR heating element is heated to an operating temperature between 245 °C and 255 °C. In implementations, the PTCR heating element is heated to an operating temperature about 250 °C.
  • FIG. 16C illustrates a modeled and measured average surface temperatures as a function of time for an example PTCR heating element.
  • Four measurements were repeated using an infrared camera to measure the average surface temperatures of the PTCR heating element as a function of time, which were then plotted against the model of the average surface temperature.
  • the average surface temperature of the PTCR heating element starts at about 25 °C (i.e. room temperature) at time zero. After an electrical current is applied, the maximum surface temperature increases linearly for about 2 seconds to a temperature of about 225 °C.
  • the rate of the temperature increase tapers off to a steady-state operating temperature of about 250 °C that is achieve about 3 seconds after activation.
  • the PTCR heating element is heated to an operating temperature between 240 °C and 280 °C. In implementations, the PTCR heating element is heated to an operating temperature between 245 °C and 255 °C. In implementations, the PTCR heating element is heated to an operating temperature about 250 °C.
  • FIG. 17 illustrates a transient current response as a function of time of an example heater, consistent with implementations of the current subject matter.
  • the current is measured in amps, which increases at a near linear rate, and reaches a peak draw after about 1.5 seconds from activation. Thereafter, the resistance quickly increases to reduce the current draw as the PTCR heater achieves a self- regulating operating temperature.
  • Uniform temperature can be a desirable performance attribute of PTCR heaters, providing a distinct advantage over series coil heaters, including series heaters having power input controlled by temperature sensors, electronic circuits with microprocessors, and sophisticated algorithms dedicated to the purpose of temperature control.
  • These existing series heaters can have overall power modulated in response to temperature measurement at a point or by average temperature estimated by overall electrical resistivity in combination with TCR (temperature coefficient of resistivity) of the typical series heating element.
  • temperatures within the series heater can vary by 40° C or more because local differences in the thermal mass of the surrounding medium, and local differences in losses to the sounding medium, lead to variations in the local resistivity along the series heater.
  • a PTCR heater 50 constructed with material having a nonlinear PTCR resistivity vs. temperature curve the same or similar to that shown in FIG. 9, with parallel geometry such as that shown in FIG. 12A-12B, and with an adequate (e.g., 3 V to 6V) differential voltage applied to conductive leads 30, each of a given control volume within such a PTCR heater will have a temperature within a narrow range, typically less than 10° C. This can be achieved even with differential thermal loading.
  • the less than 10° C range can be tailored for vaporization by controlling the materials and geometric arrangement of the PTCR heating element.
  • the PTCR heater can include a heat exchanger for the purpose of preheating air entering and passing through vaporizable materials.
  • FIG. 18 is a perspective view of an example PTCR heater assembly 395 including a PTCR heater 390 and heat exchanger elements 320 that can enable convective heating and improved uniform heating of vaporizable materials.
  • the example PTCR heater assembly 395 (also referred to as a rectangular PTCR air heater assembly) includes PTCR heater 390 including a PTCR material 300 sandwiched between electrically conductive layers 305.
  • heat exchanger elements 320 In contact with the electrically conductive layers 305 are heat exchanger elements 320, which can be made of, for example, aluminum or other thermally conductive material. Heat exchanger elements 320 can be made from a thermally conductive material extrusion or assembly. In implementations, the heat exchanger elements 320 can be a metal foam, e.g. an aluminum foam. Heat exchanger elements 320 can be made by extruding, machining, milling, casting, foaming, printing, injection molding, forging, stamping, sintering, and other metal shaping methods.
  • the heater assembly cover 350 Surrounding heat exchanger elements 320 is heater assembly cover 350.
  • the heater assembly cover 350 comprises a non-electrically conductive material.
  • the heater assembly cover 350 comprises a non-thermally conductive material.
  • the heater assembly cover 350 comprises a metal with a non- electrically conductive coating isolating the heater assembly cover 350 from the heat exchanger elements 320.
  • the heater assembly cover 350 comprises pol ytetrafl uoroethyl en e (PTFE).
  • FIG. 19 is an exploded view of a PTCR vaporization assembly 398 including an exploded view of the example PTCR heater assembly 395.
  • the PTCR vaporization assembly 398 is rectangular.
  • the PTCR vaporization assembly 398 includes the example PTCR heater assembly 395 and a product cover 380 for containing a disposable product 360.
  • the product cover 380 and disposable product 360 are each rectangular.
  • the disposable product 360 within a product cover 380 can include a disposable containing a solid vaporizable material.
  • product cover 380 is a disposable liquid cartridge (e.g., pod) configured to contain a liquid vaporizable material.
  • product cover 380 is a disposable liquid cartridge (e.g., pod) including a first air inlet and/or wick, and is configured to contain a liquid vaporizable material.
  • FIG. 20 is a perspective view of an assembled example PTCR vaporization assembly 398.
  • the product cover 380 containing the disposable product therein can be attached via an interference fit, press-fit, snap-fit coupling, magnetic coupling, adhesive, and other fastening means to the heater assembly cover 350, the PTCR heater assembly, and/or the adj oining segment on the opposite side of the product cover 380.
  • the product cover 380 can be releasably attached such that it can be separated from the vaporizer device to replace the disposable product and then reassembled.
  • FIG. 21 is a perspective, transparent view of an example PTCR vaporization assembly 398 and disposable product 360.
  • the disposable product 360 and product cover 380 can include a disposable containing a solid vaporizable material.
  • the disposable product 360 and product cover 380 can include a disposable liquid cartridge (e.g., pod) containing a liquid vaporizable material.
  • the disposable product 360 and product cover 380 can include a disposable liquid cartridge (e.g., pod) having a first air inlet and/or wick, and contains a liquid vaporizable material.
  • a PTCR heater is not shown in FIG. 21, the PTCR heater is inserted in the volume 304 between heat exchanger elements 320.
  • Heat exchanger elements 320 provides an increased surface area for heating more of the incoming air, as compared to just having a PTCR heater (without heat exchanger) to heat the incoming air. Surrounding heat exchanger elements 320 is heater assembly cover 350. In implementations, the flow rate of the incoming air through the PTCR heater assembly 395 is about 1.4 liters per minute. The heat exchanger elements 320 can reach a steady state temperature of over 200 °C in order to rapidly heat the incoming air. The heat exchanger elements 320 can be designed to maximize the specific surface area (mm 2 /mm 3 ), which provides for improved heat transfer from the PTCR heater to the heat exchanger elements 320, and also provides for improved heat transfer from the heat exchanger elements 320 to the incoming air.
  • mm 2 /mm 3 specific surface area
  • heat exchanger elements 320 can be a finned design made from a thermally conductive material (e.g. metals such as aluminum, copper, steel, stainless steel, titanium).
  • FIG. 22 is a perspective, transparent view of an example PTCR vaporization assembly 398 and a disposable product 360 about 0.2 seconds after activation of the PTCR heater 390.
  • PTCR heater 390 heats the heat exchanger elements 320, which transfer the heat to the air entering the PTCR heater assembly 395.
  • the air exiting the PTCR heater assembly 395 has been heated to a temperature of between about 110 °C and about 160 °C.
  • the heated airflow flows through disposable product 360 (e.g.
  • the vapor and/or aerosol exiting the PTCR vaporization assembly 398 contains the vaporized material released from the disposable product 360 at a temperature of between about 50 °C and about 150 °C.
  • FIG. 23 is a perspective, transparent view of an example PTCR vaporization assembly 398 and a disposable product 360 about 0.5 seconds after activation of the PTCR heater 390.
  • PTCR heater 390 heats the heat exchanger elements 320, which transfer the heat to the air entering the PTCR heater assembly 395.
  • the air exiting the PTCR heater assembly 395 has been heated to a temperature of between about 150 °C and about 210 °C.
  • the heated airflow flows through disposable product 360 (e.g. a tobacco containing media) at a flow rate of about 1.4 liters per minute.
  • the vapor and/or aerosol exiting the PTCR vaporization assembly 398 contains the vaporized material released from the disposable product 360 at a temperature of between about 100 °C and about 210 °C.
  • FIG. 24 is a perspective, transparent view of an example PTCR vaporization assembly 398 and a disposable product 360 about 1.0 second after activation of the PTCR heater 390.
  • PTCR heater 390 heats the heat exchanger elements 320, which transfer the heat to the air entering the PTCR heater assembly 395.
  • the air exiting the PTCR heater assembly 395 has been heated to a temperature of between about 170 °C and about 230 °C.
  • the heated airflow flows through disposable product 360 (e.g. a tobacco containing media) at a flow rate of about 1.4 liters per minute.
  • the vapor and/or aerosol exiting the PTCR vaporization assembly 398 contains the vaporized material released from the disposable product 360 at a temperature of between about 110 °C and about 220 °C.
  • FIG. 25 is a perspective, transparent view of an example PTCR vaporization assembly 398 and a disposable product 360 about 2.0 seconds after activation of the PTCR heater 390.
  • PTCR heater 390 heats the heat exchanger elements 320, which transfer the heat to the air entering the PTCR heater assembly 395.
  • the air exiting the PTCR heater assembly 395 has been heated to a temperature of between about 180 °C and about 240 °C.
  • the heated airflow flows through disposable product 360 (e.g. a tobacco containing media) at a flow rate of about 1.4 liters per minute.
  • the vapor and/or aerosol exiting the PTCR vaporization assembly 398 contains the vaporized material released from the disposable product 360 at a temperature of between about 120 °C and about 230 °C.
  • FIG. 26 is a perspective, transparent view of an example PTCR vaporization assembly 398 and a disposable product 360 about 3.0 seconds after activation of the PTCR heater 390.
  • PTCR heater 390 heats the heat exchanger elements 320, which transfer the heat to the air entering the PTCR heater assembly 395.
  • the air exiting the PTCR heater assembly 395 has been heated to a temperature of between about 180 °C and about 240 °C.
  • the heated airflow flows through disposable product 360 (e.g. a tobacco containing media) at a flow rate of about 1.4 liters per minute.
  • the vapor and/or aerosol exiting the PTCR vaporization assembly 398 contains the vaporized material released from the disposable product 360 at a temperature of between about 120 °C and about 230 °C.
  • the current subject matter is not limited to rectangular geometries.
  • the PTCR heater is a polygon that is not a rectangle.
  • alternative designs of a PTCR heater may depart from planar geometry in many possible configurations produced by extrusion or injection molding.
  • FIG. 27 is a perspective view of an example PTCR heater 290 with cylindrical geometry.
  • PTCR heater 290 includes PTCR material 200 with surface conductive layers 205, each of which is cylindrical.
  • FIG. 28 is an exploded view illustrating an example PTCR heater assembly 295, which includes the example PTCR heater 290, external heat exchanger 210, internal heat exchanger 220, flow diverter 230, and Heater assembly cover 250, each of which is cylindrical.
  • FIG. 29 is a perspective view of the example PTCR heater assembly 295.
  • FIG. 30 is a perspective view of the example PTCR vaporization assembly 298 with external covers and flow diverter 230 removed, thereby showing orientation of PTCR heater 290, external heat exchanger 210 and internal heat exchanger 220 aligned with disposable product 260.
  • FIG. 31 is a perspective view of the example PTCR vaporization assembly 298 including the PTCR heater 290, external heat exchanger 210, internal heat exchanger 220, flow diverter 230, Heater assembly cover 250, and product cover 280 (which, in FIG. 18, obscures disposable product 260).
  • FIG. 32 is a plot of the logarithm of resistivity of an example vaporization device with PTCR heater as a function of temperature.
  • the performance illustrated in FIG. 32 is according to example calculations characterizing a performance of an example implementation of a cylindrical PTCR vaporization assembly 298.
  • S voi o 1000 m 2 /kg from which volumetric heat exchange coefficient v " Y h p (S voi ) o 6.0 E5 W/m 3 K.
  • the calculated vaporization device with PTCR heater included electrically conductive layers 205 that were silver, a cylindrical external heat exchanger 210 and a cylindrical internal heat exchanger 220 that were aluminum extrusions, flow diverter 230 and Heater assembly cover 250 were made from PTFE, and product cover 280 was made from paper.
  • FIG. 33 is a cross sectional plot showing temperature simulations of the example implementation of the PTCR vaporization assembly 298 that is also described above with respect to FIG. 32.
  • the PTCR vaporization assembly 298 includes a PTCR heater assembly 295 for heating of a disposal product (e.g. a solid vaporizable material) 260.
  • FIGs. 34A - 34G are cut plots showing transient response of temperature as color for the example implementation of the PTCR vaporization assembly 298 with PTCR heater assembly 295.
  • FIGs. 34A-34G demonstrate that temperatures everywhere never exceed 280 °C, well below combustion temperature of disposable product 260. It can also be seen in FIGs. 34A - 34G that heating of disposal product (e.g. a solid vaporizable material) 260 proceeds in a wave from upstream to downstream such that cross-sectional hot spots and resulting differential porosity voids are eliminated.
  • disposal product e.g. a solid vaporizable material
  • phrases such as“at least one of’ or“one or more of’ may occur followed by a conjunctive list of elements or features.
  • the term“and/or” may also occur in a list of two or more elements or features. Unless otherwise implicitly or explicitly contradicted by the context in which it is used, such a phrase is intended to mean any of the listed elements or features individually or any of the recited elements or features in combination with any of the other recited elements or features.
  • the phrases“at least one of A and B;”“one or more of A and B;” and“A and/or B” are each intended to mean“A alone, B alone, or A and B together.”
  • a similar interpretation is also intended for lists including three or more items.
  • phrases“at least one of A, B, and C;”“one or more of A, B, and C;” and“A, B, and/or C” are each intended to mean“A alone, B alone, C alone, A and B together, A and C together, B and C together, or A and B and C together.”
  • use of the term“based on,” above and in the claims is intended to mean, “based at least in part on,” such that an unrecited feature or element is also permissible.

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EP20704967.7A 2019-01-11 2020-01-10 Verdampfer mit positivem temperaturkoeffizienten des widerstandserwärmers Pending EP3908135A1 (de)

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US201962791709P 2019-01-11 2019-01-11
US201962816452P 2019-03-11 2019-03-11
US201962898522P 2019-09-10 2019-09-10
PCT/US2020/013224 WO2020146828A1 (en) 2019-01-11 2020-01-10 Vaporizer including positive temperature coefficient of resistivity heater

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Publication number Priority date Publication date Assignee Title
US5144962A (en) * 1989-12-01 1992-09-08 Philip Morris Incorporated Flavor-delivery article
US9427022B2 (en) * 2012-03-12 2016-08-30 UpToke, LLC Electronic vaporizing device and methods for use
EP4393336A2 (de) * 2018-11-08 2024-07-03 Juul Labs, Inc. Verdampfervorrichtung mit mehr als einem heizelement

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