EP3694967B1 - Detergent composition comprising hydrate-forming salt particles coated with betaine - Google Patents
Detergent composition comprising hydrate-forming salt particles coated with betaine Download PDFInfo
- Publication number
- EP3694967B1 EP3694967B1 EP18762870.6A EP18762870A EP3694967B1 EP 3694967 B1 EP3694967 B1 EP 3694967B1 EP 18762870 A EP18762870 A EP 18762870A EP 3694967 B1 EP3694967 B1 EP 3694967B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- hydrate
- detergent composition
- filler agent
- composition
- betaine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000000203 mixture Substances 0.000 title claims description 116
- 150000003839 salts Chemical class 0.000 title claims description 70
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 title claims description 25
- 229960003237 betaine Drugs 0.000 title claims description 22
- 239000003599 detergent Substances 0.000 title description 38
- 239000002245 particle Substances 0.000 title description 5
- 239000000945 filler Substances 0.000 claims description 69
- 235000002639 sodium chloride Nutrition 0.000 claims description 68
- 239000003795 chemical substances by application Substances 0.000 claims description 55
- 150000001875 compounds Chemical class 0.000 claims description 32
- 239000013042 solid detergent Substances 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 16
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 10
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 10
- 239000003945 anionic surfactant Substances 0.000 claims description 9
- IZWSFJTYBVKZNK-UHFFFAOYSA-O N-dodecyl-N,N-dimethyl-3-ammonio-1-propanesulfonic acid Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS(O)(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-O 0.000 claims description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- 235000011152 sodium sulphate Nutrition 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 5
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 239000001632 sodium acetate Substances 0.000 claims description 4
- 235000017281 sodium acetate Nutrition 0.000 claims description 4
- 239000004280 Sodium formate Substances 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims description 3
- 235000019254 sodium formate Nutrition 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 239000012153 distilled water Substances 0.000 claims description 2
- -1 polyoxyethylene Polymers 0.000 description 38
- 229920000642 polymer Polymers 0.000 description 22
- 125000004432 carbon atom Chemical group C* 0.000 description 18
- 239000000975 dye Substances 0.000 description 16
- 125000000217 alkyl group Chemical group 0.000 description 15
- 239000000463 material Substances 0.000 description 15
- 239000004094 surface-active agent Substances 0.000 description 15
- 239000007787 solid Substances 0.000 description 13
- 239000011734 sodium Substances 0.000 description 12
- 238000005406 washing Methods 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- 239000002689 soil Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- 239000010457 zeolite Substances 0.000 description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- 229910021536 Zeolite Inorganic materials 0.000 description 8
- 239000013078 crystal Substances 0.000 description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 8
- 239000002736 nonionic surfactant Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 239000004744 fabric Substances 0.000 description 7
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 229920002125 SokalanĀ® Polymers 0.000 description 6
- 239000002304 perfume Substances 0.000 description 6
- 239000003352 sequestering agent Substances 0.000 description 6
- 235000017550 sodium carbonate Nutrition 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 150000004996 alkyl benzenes Chemical class 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 229940088598 enzyme Drugs 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910000027 potassium carbonate Inorganic materials 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical class C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000007850 fluorescent dye Substances 0.000 description 3
- 150000004677 hydrates Chemical class 0.000 description 3
- 230000036571 hydration Effects 0.000 description 3
- 238000006703 hydration reaction Methods 0.000 description 3
- 229910017053 inorganic salt Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 229920005646 polycarboxylate Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KKMIHKCGXQMFEU-UHFFFAOYSA-N 2-[dimethyl(tetradecyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O KKMIHKCGXQMFEU-UHFFFAOYSA-N 0.000 description 2
- LISBNJIORNYYHL-UHFFFAOYSA-N 3-[diethyl(hexadecyl)azaniumyl]propanoate Chemical compound CCCCCCCCCCCCCCCC[N+](CC)(CC)CCC([O-])=O LISBNJIORNYYHL-UHFFFAOYSA-N 0.000 description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229960001484 edetic acid Drugs 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical class OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920001444 polymaleic acid Polymers 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- ZMLPKJYZRQZLDA-UHFFFAOYSA-N 1-(2-phenylethenyl)-4-[4-(2-phenylethenyl)phenyl]benzene Chemical group C=1C=CC=CC=1C=CC(C=C1)=CC=C1C(C=C1)=CC=C1C=CC1=CC=CC=C1 ZMLPKJYZRQZLDA-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- QTDIEDOANJISNP-UHFFFAOYSA-N 2-dodecoxyethyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOCCOS(O)(=O)=O QTDIEDOANJISNP-UHFFFAOYSA-N 0.000 description 1
- IXOCGRPBILEGOX-UHFFFAOYSA-N 3-[3-(dodecanoylamino)propyl-dimethylazaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)CS([O-])(=O)=O IXOCGRPBILEGOX-UHFFFAOYSA-N 0.000 description 1
- MXMWUQAFMKOTIQ-UHFFFAOYSA-N 4-(carboxymethoxy)-4-oxobutanoic acid Chemical class OC(=O)CCC(=O)OCC(O)=O MXMWUQAFMKOTIQ-UHFFFAOYSA-N 0.000 description 1
- YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 102100032487 Beta-mannosidase Human genes 0.000 description 1
- AHCDZZIXAMDCBJ-UHFFFAOYSA-N CCC[Na] Chemical compound CCC[Na] AHCDZZIXAMDCBJ-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 150000001204 N-oxides Chemical class 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 108700020962 Peroxidase Proteins 0.000 description 1
- 102000003992 Peroxidases Human genes 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 239000001744 Sodium fumarate Substances 0.000 description 1
- AHWXCYJGJOLNFA-UHFFFAOYSA-N [1,4]benzoxazino[2,3-b]phenoxazine Chemical compound O1C2=CC=CC=C2N=C2C1=CC1=NC3=CC=CC=C3OC1=C2 AHWXCYJGJOLNFA-UHFFFAOYSA-N 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 108010055059 beta-Mannosidase Proteins 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
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- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
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- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 108010005400 cutinase Proteins 0.000 description 1
- 150000004691 decahydrates Chemical class 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- MSJMDZAOKORVFC-SEPHDYHBSA-L disodium fumarate Chemical compound [Na+].[Na+].[O-]C(=O)\C=C\C([O-])=O MSJMDZAOKORVFC-SEPHDYHBSA-L 0.000 description 1
- VUJGKADZTYCLIL-YHPRVSEPSA-L disodium;5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfonatophenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 VUJGKADZTYCLIL-YHPRVSEPSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- IZWSFJTYBVKZNK-UHFFFAOYSA-N lauryl sulfobetaine Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS([O-])(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-N 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 235000001055 magnesium Nutrition 0.000 description 1
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
- 239000011654 magnesium acetate Substances 0.000 description 1
- 235000011285 magnesium acetate Nutrition 0.000 description 1
- 229940069446 magnesium acetate Drugs 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 150000002690 malonic acid derivatives Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 230000002911 mydriatic effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 108010087558 pectate lyase Proteins 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000196 poly(lauryl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- WFIZEGIEIOHZCP-UHFFFAOYSA-M potassium formate Chemical compound [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 229920006261 self reinforced polyphenylene Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940005573 sodium fumarate Drugs 0.000 description 1
- 235000019294 sodium fumarate Nutrition 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003900 succinic acid esters Chemical class 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
Definitions
- the present invention relates to solid detergent compositions having improved solubility. More particularly, it relates to solid laundry detergent compositions having hydrate-forming salts with improved cold-water solubility.
- detergent builder granules which contain a water-soluble inorganic salt containing an inorganic salt having and/or being capable of forming a hydrate crystal, and a clay mineral.
- the detergent builder granules have excellent dispersibility in cold water.
- EP229671A2 (Kao, 1987 ) disclosing a high-density granular detergent composition in which high dispersibility and solubility in cold water is achieved by including particles of water-soluble crystalline, inorganic salt carrying thereon an organic substance having a melting point of 40Ā°C or lower which inhibits hydration of the coated particles.
- the organic substance is defined to be a non-ionic surfactant.
- the non-ionic surfactants include polyoxyethylene, polyhydric alcohols and alkanolamides surfactants.
- Hydrated salts can easily form during low temperatures in the powder-dispensing drawer of washing machines when appropriate conditions are present. Low water content, low temperatures are conditions particularly favourable for the formation of hydrates. The formation of hydrates often results in loss of surfactant available for washing and these may deposit on fabric, which resemble white stain-like spots on the washed fabric.
- the present inventors have investigated ways of providing solid detergent composition that has improved solubility in cold-water conditions specifically at temperatures lower than 10Ā°C, more preferably lower than 5Ā°C, and towards providing a coated filler agent for use in detergent composition, which coated filler agent considerably inhibits formation of crystalline masses, which are difficult to disperse and dispense.
- a coated filler agent having high dispersibility and solubility in cold water at temperatures lower than 10Ā°C, more preferably lower than 5Ā°C can be obtained by at least partially coating the hydrate-forming salt with a betaine class of zwitterionic compound.
- the invention provides a coated filler agent for use in a solid detergent composition comprising a hydrate-forming salt and a betaine class of zwitterionic compound wherein the hydrate-forming salt is at least partially coated with the zwitterionic compound.
- the invention provides a filler composition according to the invention having the coated filler agent and a water-soluble salt.
- the invention provides use of a coated filler agent or a filler composition according to the invention in a detergent composition for providing improved solubility.
- the invention relates to a coated filler agent for use in a solid detergent composition
- a coated filler agent for use in a solid detergent composition
- a solid detergent composition comprising a hydrate-forming salt and a betaine class of zwitterionic compound wherein the hydrate-forming salt is at least partially coated with the zwitterionic compound.
- the coated filler agent of the present invention includes a betaine class of zwitterionic compound.
- the betaine class of zwitterionic compound is preferably a zwitterionic surfactant or a zwitterionic polymer, preferably a zwitterionic surfactant.
- Suitable zwitterionic surfactants are known in the art, and include, for example, those surfactants broadly described as derivatives of aliphatic quaternary ammonium, phosphonium and sulfonium compounds, in which the aliphatic radicals can be straight or branched chain, and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic group such as carboxyl, sulfonate, sulfate, phosphate or phosphonate.
- suitable zwitterionic surfactants include alkyl betaines, such as cocodimethyl carboxymethyl betaine, lauryl dimethyl carboxymethyl betaine, lauryl dimethyl alphacarboxy-ethyl betaine, cetyl dimethyl carboxymethyl betaine, lauryl bis-(2- hydroxy-ethyl)carboxy methyl betaine, stearyl bis-(2-hydroxypropyl)carboxymethyl betaine, oleyl dimethyl gamma-carboxypropyl betaine, and lauryl bis-(2-hydroxypropyl)alpha-carboxyethyl betaine, alkyl arnidopropyl betaines, and alkyl sultaines, such as cocodimethyl sulfopropyl betaine, stearyldimethyl sulfopropyl betaine, lauryl dimethyl sulfoethyl betaine, lauryl bis-(2-hydroxy-ethyl)sulfo
- Preferred examples of phospho-betaine includes but are not limited to propyl Monosodium Phosphobetaine, Cocamido Disodium Ethyl Phosphobetaine, Coeamido Disodium 3-I-lydroxypropyl Phospho-betaine, Why myriatic Amido 3-Hydroxypropyl Phospho-betaine.
- Useful betaines have the structure as given in formula 1 wherein
- Specific useful sultaines are for example 3-(dodecyldimethylammonio)propane-1-sulfonate and 3-(tetradecyldimethylammonio) ethane- 1 -sulfonate.
- the zwitterionic surfactant is most preferably a carbo-betaine, sulpho-betaine, phospho-betaine, carboxy-betaine or mixtures thereof.
- the zwitterionic compound is preferably a zwitterionic polymer.
- Preferred zwitterionic polymers include but are not limited to poly(phosphobetaine methacrylate), poly(sulfobetaine methacrylate), poly(carboxybetaine methacrylate), poly(serine methacrylate).
- the betaine class of zwitterionic compound is present in an amount ranging from 0.5 to 20wt% based on the coated filler agent.
- the amount of zwitterionic compound in the coated filler agent is at least 1wt%, still preferably at least 2.5wt%, further preferably at least 3wt% and most preferably at least 5wt%, but typically not more than 10wt%, still preferably not more than 15wt% and most preferably not more than 20wt% based on the coated filler agent.
- the betaine class of zwitterionic compound according to the present invention is at least partially coating the hydrate-forming salt. More preferably, the zwitterionic compound completely covers the hydrate-forming salt.
- the coated filler agent of the present invention comprises a hydrate-forming salt.
- the hydrate-forming salt of the present invention is at least partially coated with a betaine class of zwitterionic compound.
- Non-limiting examples of the hydrate-forming salt are sulphate, carbonate or bicarbonate salt of alkaline earth metal or alkali metal and mixtures thereof.
- Preferred examples of the hydrate-forming salt according to the present invention are selected from the group consisting of sodium carbonate, sodium sulphate, sodium bicarbonate, sodium tripolyphosphate, sodium pyrophosphate, sodium orthophosphate, magnesium sulphate or mixtures thereof.
- the hydrate-forming salt is sodium carbonate, sodium sulphate or mixtures thereof.
- Present invention is particularly suitable for any salt that exhibits significant change in solubility with decrease in temperature.
- This is specifically suitable for salts which easily crystallises from the aqueous solution at a relatively low temperature to form crystals which easily coalesce together to form a firm structure. Without being bound by theory it is believed that this crystal formation inhibits the dispersibility and solubility of the detergent composition.
- sodium carbonate generates a large amount of heat upon hydration and dissolves even in cold water to form a solution having a high concentration with the generation of heat. The heat is later taken up by the low-temperature surrounding and with the lowered temperature the solubility of the hydrated salt reduces and the salt precipitates as crystals.
- sodium carbonate is in the form of its decahydrate and it has a large amount of water of crystallization.
- the hydration increases the volume of the undissolved crystals and such hydrated crystals coalesce together easily to form a firmer structure. Therefore, the problem of residue formation is particularly higher in compositions with sodium carbonate.
- the hydrate-forming salt is present in an amount ranging from 80 to 99wt% based on the coated filler agent.
- the amount of hydrate-forming salt in the coated filler agent is at least 80wt%, still preferably at least 85wt%, further preferably at least 87wt% and most preferably at least 90wt%, but typically not more than 99wt%, still preferably not more than 97.5wt% and most preferably not more than 95wt% based on the coated filler agent.
- the method for preparing the coated filler agent comprises the steps of:
- a preferred method of coating includes spraying or pouring the zwitterionic compound onto the hydrate-forming salt.
- the hydrate-forming salt is constantly mixed during the process of coating.
- the hydrate-forming salt is taken in a plough shear mixer or other high speed mixers, which can keep the hydrate-forming salt at high speed rotation during the coating process.
- the coated filler agent obtained from the process are according to the present invention and the zwitterionic compound at least partially covers or coats the hydrate-forming salt.
- the hydratable salt is taken in a sigma or a z-blender during the coating process in which the zwitterionic compound is constantly sprayed or poured onto the hydrate-forming salt.
- Another method of preparing the coated filler agent of the present invention involves a first step of preparing an aqueous slurry comprising the hydrate-forming salt and the zwitterionic compound, the slurry is thereafter dried preferably by spray drying route, the coated filler agent obtained is according to the present invention in which the zwitterionic compound at least partially covers the hydrate-forming salt.
- a filler composition having the coated filler agent of the first aspect and a water-soluble salt.
- the filler composition according to the second aspect of the present invention comprises a water-soluble salt that has a solubility of more than 30 grams/100mL in distilled water when measured at a temperature of 10Ā°C, the water-soluble salt being present separate from the hydrate-forming salt.
- the water-soluble salt has a solubility of at least 35grams/100mL, still preferably at least 40 grams/100mL, further preferably at least 45grams/100mL.
- Non-limiting examples of the water-soluble salt includes potassium carbonate, potassium chloride, potassium formate, potassium acetate, sodium chloride, sodium acetate, sodium formate, calcium acetate, magnesium chloridesodium di-hydrogen phosphate, potassium bi-sulphate, magnesium acetate, sodium fumarate. More preferably the water-soluble salt is selected from sodium chloride, sodium acetate or sodium formate.
- the amount of water-soluble salt in the filler composition is at least 5wt%, still preferably at least 10wt%, further preferably at least 15wt% and most preferably at least 20wt%, but typically not more than 40wt%, still preferably not more than 50wt% and most preferably not more than 60wt% based on the filler composition.
- a solid detergent composition comprising a coated filler agent according to the first aspect or a filler composition according to the second aspect of the present invention.
- a solid detergent composition according to the present disclosure encompasses powders as well as a variety of cast and extruded forms including, for example, pellets, blocks, particles and tablets. It should be understood that the term āsolidā refers to the state of the detergent composition under the expected conditions of storage and use of the solid detergent composition. In general, it is expected that the detergent composition will remain a solid when provided at a temperature of up to about 100Ā°F. Preferably the solid detergent composition is a powder, tablet, granular or a particulate composition.
- the detergent composition is provided in the form of a unit dose.
- a unit dose refers to a detergent composition in unit size so that the entire unit is used during a single washing cycle.
- the solid detergent composition is provided as a unit dose, it is preferably provided as a cast solid, an extruded particle or pellet, or a tablet having a size of between about 1 gram and about 50 grams. In other embodiments, a cast solid, an extruded pellet, or a tablet having a size of between 50 grams up through 250 grams, or an extruded solid with a weight of about 100 grams or greater.
- the solid detergent composition can be provided as a cast solid, an extruded pellet, or a tablet so that a plurality of the solids will be available in a package having a size of between about 40 grams and about 11,000 grams.
- the solid detergent composition is provided in the form of a multiple-use solid, such as, a block or a plurality of pellets, and can be repeatedly used to generate aqueous detergent composition for multiple washing cycles.
- the solid detergent composition is provided as a powder, cast solid, an extruded block, or a tablet having a mass of between about 5 grams and 10 kilograms.
- a multiple-use form of the solid detergent composition has a mass between about 1 and 10 kilograms, more preferably 1 kg to 5 kg.
- the solid detergent composition includes 2wt% to 40wt% of the coated filler agent.
- the amount of coated filler agent in the solid detergent composition is at least 2wt%, still preferably at least 5wt%, further preferably at least 10wt% and most preferably at least 15wt%, but typically not more than 30wt%, still preferably not more than 35wt% and most preferably not more than 40wt% based on the detergent composition.
- the detergent composition includes a filler composition having a coated filler agent and a water-soluble salt.
- the detergent composition preferably includes a filler composition in an amount which is at least 5wt%, still preferably at least 8wt%, further preferably at least 10wt% and most preferably at least 15wt% based on the weight of the detergent composition, but typically not more than 30wt%, still preferably not more than 40wt% and most preferably not more than 50wt% based on the weight of the detergent composition.
- the detergent composition includes a surfactant selected from anionic, non-ionic, zwitterionic, cationic or amphoteric surfactant.
- Suitable anionic detergent compounds which may be used are usually water- soluble alkali metal salts of organic sulphates and sulphonates having alkyl radicals containing from about 8 to about 22 carbon atoms, the term alkyl being used to include the alkyl portion of higher acyl radicals.
- suitable synthetic anionic detergent compounds are sodium and potassium alkyl sulphates, especially those obtained by sulphating higher C 8 to C 18 alcohols, produced for example from tallow or coconut oil, sodium and potassium alkyl C 9 to C 20 benzene sulphonates, particularly sodium linear secondary alkyl C 10 to C 15 benzene sulphonates; and sodium alkyl glyceryl ether sulphates, especially those ethers of the higher alcohols derived from tallow or coconut oil and synthetic alcohols derived from petroleum.
- the anionic surfactant is preferably selected from: linear alkyl benzene sulphonate; alkyl sulphates; alkyl ether sulphates; soaps; alkyl (preferably methyl) ester sulphonates, and mixtures thereof.
- the most preferred anionic surfactants are selected from: linear alkyl benzene sulphonate; alkyl sulphates; alkyl ether sulphates and mixtures thereof.
- the alkyl ether sulphate is a C 12 to C 14 n-alkyl ether sulphate with an average of 1 to 3EO (ethoxylate) units.
- Sodium lauryl ether sulphate is particularly preferred (SLES).
- the linear alkyl benzene sulphonate is a sodium C 11 to C 15 alkyl benzene sulphonates.
- the alkyl sulphates is a linear or branched sodium C 12 to C 18 alkyl sulphates.
- Sodium dodecyl sulphate is particularly preferred, (SDS, also known as primary alkyl sulphate).
- the solid detergent composition includes 2wt% to 80wt% of the anionic surfactant.
- the nonionic surfactant component preferably comprises alcohol ethoxylate.
- the alcohol ethoxylates are formed from the reaction of primary or secondary alcohols with ethylene oxide. Typically, an aliphatic C 8 to C 18 primary or secondary linear or branched alcohol is reacted with ethylene oxide in the required molar amount to produce the alcohol ethoxylate.
- Preferred alcohol ethoxylates have from 2 to 40, preferably from 3 to 30, more preferably from 5 to 20 ethylene oxide 20 units attached to the aliphatic chain.
- the surfactants may be chosen from the surfactants described in " Surface Active Agentsā Vol. 1, by Schwartz & Perry, Interscience 1949 , Vol. 2 by Schwartz, Perry & Berch, Interscience 1958 , in the current edition of "McCutcheon's Emulsifiers and Detergentsā published by Manufacturing Confectioners Company or in " Tenside-Taschenbuch", H. Stache, 2nd Edn. , Carl Hauser Verlag, 1981 .
- the surfactants used are saturated.
- Suitable nonionic detergent compounds which may be used include, in particular the reaction products of compounds having a hydrophobic group and a reactive hydrogen atom, for example, aliphatic alcohols, acids, amides or alkyl phenols with alkylene oxides, especially ethylene oxide either alone or with propylene oxide.
- Specific nonionic detergent compounds are C 6 to C 22 alkyl phenolethylene oxide condensates, generally 5 to 25 EO, i.e. 5 to 25 units of ethylene oxide per molecule, and the condensation products of aliphatic C 8 to C 18 primary or secondary linear or branched alcohols with ethylene oxide, generally 5 to 40 EO.
- the total amount of surfactant present in the composition is preferably at least 5 wt. %, more preferably at least 10 wt. %, More preferably the total amount of surfactant is from 15 to 65 wt. %, preferably from 10 to 50 wt. %
- surfactants such as cationic surfactants and amphoteric/zwitterionic surfactants such as betaines may also be present in addition to the aforementioned nonionic and anionic surfactants.
- Builder materials may be selected from 1) calcium sequestrant materials, 2) precipitating materials, 3) calcium ion-exchange materials and 4) mixtures thereof.
- calcium sequestrant builder materials examples include alkali metal polyphosphates, such as sodium tripolyphosphate and organic sequestrants, such as ethylene diamine tetra-acetic acid.
- precipitating builder materials examples include sodium orthophosphate.
- Examples of calcium ion-exchange builder materials include various types of water-insoluble crystalline or amorphous aluminosilicates, of which zeolites are well known representatives thereof, e.g. zeolite A, zeolite B (also known as zeolite P), zeolite C, zeolite X, zeolite Y and also the zeolite P-type described in EP-A-0,384,070 .
- zeolites are well known representatives thereof, e.g. zeolite A, zeolite B (also known as zeolite P), zeolite C, zeolite X, zeolite Y and also the zeolite P-type described in EP-A-0,384,070 .
- the detergent compositions may also optionally contain relatively low levels of organic detergent builder or sequestrant material.
- organic detergent builder or sequestrant material examples include the alkali metal, citrates, succinates, malonates, carboxymethyl succinates, carboxylates, polycarboxylates and polyacetyl carboxylates.
- Specific examples include sodium, potassium and lithium salts of oxydisuccinic acid, mellitic acid, benzene polycarboxylic acids, ethylene diamine tetra-acetic acid, diethylenetriaminepentaacetic acid, alkyl- or alkenylsuccinic acid, nitrilotriacetic acid, and citric acid.
- DEQUESTTM organic phosphonate type sequestering agents sold by Monsanto and alkanehydroxy phosphonates.
- suitable organic builders include the higher molecular weight polymers and copolymers known to have builder properties.
- such materials include appropriate polyacrylic acid, polymaleic acid, and polyacrylic/polymaleic acid copolymers and their salts, such as those sold by BASF under the name SOKALANTM.
- the builder materials may comprise from about 0.5% to 20 wt%, preferably from 1 wt% to 10 wt%, of the composition.
- the preferred builder level is less than 10 wt% and preferably less than 5 wt% of the composition.
- the laundry detergent formulation is a non-phosphate built laundry detergent formulation, i.e., contains less than 1 wt. % of phosphate.
- Shading dyes deposit to fabric during the wash or rinse step of the washing process providing a visible hue to the fabric. Shading of white garments may be done with any colour depending on consumer preference. Blue and Violet are particularly preferred shades and consequently preferred dyes or mixtures of dyes are ones that give a blue or violet shade on white fabrics.
- the shading dyes used are preferably blue or violet.
- the shading dye chromophore is preferably selected from the group comprising: mono-azo, bis-azo, triphenylmethane, triphenodioxazine, phthalocyanin, naptholactam, azine and anthraquinone. Most preferably mono-azo, bis-azo, azine and anthraquinone. Most preferably the dye bears at least one sulfonate group.
- Preferred shading dyes are selected from direct dyes, acid dyes, hydrophobic dyes, cationic dyes and reactive dyes.
- the shading dye is present is present in the composition in range from 0.0001 to 0.01 wt %.
- the composition preferably comprises a fluorescent agent (optical brightener).
- fluorescent agents are well known and many such fluorescent agents are available commercially. Usually, these fluorescent agents are supplied and used in the form of their alkali metal salts, for example, the sodium salts.
- the total amount of the fluorescent agent or agents used in the composition is generally from 0.005 to 2 wt. %, more preferably 0.01 to 0.1 wt. %.
- Preferred classes of fluorescer are: Di-styryl biphenyl compounds, e.g. Tinopal (Trade Mark) CBS-X, Di-amine stilbene di-sulphonic acid compounds, e.g.
- Preferred fluorescers are: sodium 2-(4-styryl-3-sulfophenyl)-2H-napthol[1, 2-d]trazole, disodium 4,4'-bis([(4-anilino-6-(N methyl-N-2 hydroxyethyl) amino 1,3,5-triazin-2-yl)]amino)stilbene-2-2' disulfonate, disodium 4,4'-bis([(4-anilino-6-morpholino-1,3,5-triazin-2-yl)]amino) stilbene-2-2' disulfonate, and disodium 4,4'-bis(2-sulfoslyryl)biphenyl.
- the composition comprises a perfume.
- the perfume is preferably in the range from 0.001 to 3 wt. %, most preferably 0.1 to 1 wt. %.
- CTFA Cosmetic, Toiletry and Fragrance Association
- compositions of the present invention it is envisaged that there will be four or more, preferably five or more, more preferably six or more or even seven or more different perfume components.
- the composition may comprise one or more polymers.
- Polymers can assist in the cleaning process by helping to retail soil in solution or suspension and/or preventing the transfer of dyes. Polymers can also assist in the soil removal process. Dye transfer, anti-redeposition and soil-release polymers are described in further detail below.
- the composition may comprise one or more polymers.
- polymers are carboxymethylcellulose, hydroxyethyl cellulose, hydroxpropyl cellulose, poly(ethylene glycol), poly(vinyl alcohol), ethoxylated polyamines, polycarboxylates such as polyacrylates, maleic/acrylic acid copolymers and lauryl methacrylate/acrylic acid copolymers.
- Modern detergent compositions typically employ polymers as so-called 'dye-transfer inhibitors'. These prevent migration of dyes, especially during long soak times.
- dye-transfer inhibiting agents include polyvinyl pyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, manganese pthalocyanine, peroxidases, and mixtures thereof, and are usually present at a level of from 0.01 to 10 wt. % based on total amount in the laundry composition.
- Anti-redeposition polymers are designed to suspend or disperse soil. Typically 25 antiredeposition polymers are ethoxylated and or propoxylated polyethylene imine or polycarboxylate materials, for example, Acrylic acid based homo or copolymers available under the trade mark ACUSOL from Dow Chemical, Alcosperse from Akzonobel or Sokolan from BASF.
- suitable soil release polymers include graft copolymers of poly(vinyl ester), e.g., C 1 - C 6 vinyl esters, preferably poly(vinyl acetate) grafted onto polyalkylene oxide backbones.
- Commercially available soil release agents of this kind include the SOKALAN type of material, e.g., SOKALAN HP-22, available from BASF (West Germany).
- Further suitable soil release polymers of a different type include the commercially available material ZELCON 5126 (from DuPont) and MILEASE T (from ICI). If present, the soil release polymer may be included at a level of from 0.01 to 10 wt. % based on total amount in the laundry composition.
- Further examples of soil release polymers are terephthalic acid / glycol copolymers sold under the tradenames Texcare, Repel-o-tex, Gerol, Marloquest, Cirrasol.
- Enzymes can also be present in the formulation.
- Preferred enzymes include protease, lipase, pectate lyase, amylase, cutinase, cellulase, mannanase.
- a coated filler agent of the first aspect or a filler composition of the second aspect in a detergent composition for improving cold water solubility and/or dispersibility.
- Example 1 Evaluation of the solubility and dispersibility.
- compositions tested were prepared and tested in the following manner. The compositions tested are given in table 1.
- Example 1 10 grams of sodium sulphate (hydrate-forming salt) was taken in a plough shear mixer and rotated at high speed, during the mixing 0.05 grams of sulphobetaine was sprayed onto the salt and after 5 minutes of mixing the coated filler agent was obtained and tested for solubility.
- Example 2 the coated filler agent was prepared similar to example 1 and thereafter the sodium chloride was added to obtain the filler composition. Similarly, in Example 3 a different filler composition having sodium chloride and potassium carbonate was obtained.
- Example B the preparation of the filler agent was similar to that of Example 1 except that instead of the sulphobetaine, given amount of Neodol EO7 (ethoxylated non-ionic surfactant) was used.
- Table 1 Filler agent Ex A (grams) Ex 1 (grams) Ex 2 (grams) Ex 3 (grams) Ex B (grams) Na 2 SO 4 10 10 10 10 10 sulphobetaine - 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Non-ionic surfactant - - - - 0.05 Sodium chloride - - 2 1 - Potassium carbonate - - - 1 - Residue obtained 9.5 7.3 3.2 2.2 7.3 Nature of residue Hard Soft Very soft and powder like Very soft and powder like Hard and similar to example A
- the table above shows that best results for solubility when dissolved at 5Ā°C are obtained when the sodium sulphate (hydrate-forming salt) is at least partially coated with the sulphobetaine (Ex 2) according to the present invention.
- the table also indicates that the solubility of the filler agent is lower and the residue formed is hard in Ex A, and Ex B which has either no coating or coated with a compound outside the scope of the present invention.
- Further filler composition of Ex 2 and 3 having a coated filler agent and a water-soluble salt shows improved solubility and the nature of residue is also soft.
- the illustrated examples provide a coated filler agent having a hydrate-forming salt at least partially coated with the zwitterionic compound provides improved cold water solubility and dispersibility.
Description
- The present invention relates to solid detergent compositions having improved solubility. More particularly, it relates to solid laundry detergent compositions having hydrate-forming salts with improved cold-water solubility.
- The problem of providing improved dispensing, dispersing and easily dissolving laundry detergent powders is well-known and has been addressed many times in the past. It is undesirable, for example, to have a solid laundry composition with slow dispensing and low solubility, which forms a residue in the drawer of many automatic washing machines.
- Furthermore, in some regions during winter, cold water at around 10Ā°C or lower is usually used for washing fabrics. Under such washing conditions noticeable lumps form in the dispensing drawer of a washing machine that may appear as visible solid white masses in the drawer as well as on the washed fabrics. The problem further worsens when the order of addition to the washing machine is laundry detergent product first, clothes second, and water last.
- During the release of cold water, into the washing machine, water gradually penetrates into the mass of the solid detergent composition, without substantial physical or mechanical power applied thereto, and hydrates the surfactant and also the hydrate-forming salts present in the composition. Surfactants especially the anionic surfactants present in the detergent compositions form a highly viscous pasty phase. The hydrated water-soluble salts precipitate out in the form of crystals, which further harden the viscous pasty phase of the surfactant. The formed crystals also connect with one another to convert the phase per se into a firm, hydrated solid phase, which is difficult to disperse or dissolve by a mechanical force applied thereafter. The detergent composition under such conditions remains in an undissolved state during ordinary washing time. Such a phenomenon is undesirable for the users.
- Some prior art documents have tried to address the problem of low dispersion and dissolution of detergent compositions in cold water caused primarily by the presence of the hydrate-forming crystalline salts.
- In
US 2010/0261633 , detergent builder granules are described, which contain a water-soluble inorganic salt containing an inorganic salt having and/or being capable of forming a hydrate crystal, and a clay mineral. The detergent builder granules have excellent dispersibility in cold water. InEP229671A2 (Kao, 1987 - Hydrated salts can easily form during low temperatures in the powder-dispensing drawer of washing machines when appropriate conditions are present. Low water content, low temperatures are conditions particularly favourable for the formation of hydrates. The formation of hydrates often results in loss of surfactant available for washing and these may deposit on fabric, which resemble white stain-like spots on the washed fabric.
- The present inventors have investigated ways of providing solid detergent composition that has improved solubility in cold-water conditions specifically at temperatures lower than 10Ā°C, more preferably lower than 5Ā°C, and towards providing a coated filler agent for use in detergent composition, which coated filler agent considerably inhibits formation of crystalline masses, which are difficult to disperse and dispense.
- After intensive investigations made for the purposes of solving the problem, the inventors have found that a coated filler agent having high dispersibility and solubility in cold water at temperatures lower than 10Ā°C, more preferably lower than 5Ā°C can be obtained by at least partially coating the hydrate-forming salt with a betaine class of zwitterionic compound.
- Accordingly, in a first aspect the invention provides a coated filler agent for use in a solid detergent composition comprising a hydrate-forming salt and a betaine class of zwitterionic compound wherein the hydrate-forming salt is at least partially coated with the zwitterionic compound.
- In a second aspect, the invention provides a filler composition according to the invention having the coated filler agent and a water-soluble salt.
- In a third aspect, the invention provides use of a coated filler agent or a filler composition according to the invention in a detergent composition for providing improved solubility.
- These and other aspects, features and advantages will become apparent to those of ordinary skill in the art from a reading of the following detailed description and the appended claims. For the avoidance of doubt, any feature of one aspect of the present invention may be utilized in any other aspect of the invention. The word "comprising" is intended to mean "including" but not necessarily "consisting of" or "composed of." In other words, the listed steps or options need not be exhaustive. It is noted that the examples given in the description below are intended to clarify the invention and are not intended to limit the invention to those examples per se. Similarly, all percentages are weight/weight percentages unless otherwise indicated. Except in the operating and comparative examples, or where otherwise explicitly indicated, all numbers in this description indicating amounts of material or conditions of reaction, physical properties of materials and/or use are to be understood as modified by the word "about". Numerical ranges expressed in the format "from x to y" are understood to include x and y. When for a specific feature multiple preferred ranges are described in the format "from x to y", it is understood that all ranges combining the different endpoints are also contemplated.
- In a first aspect, the invention relates to a coated filler agent for use in a solid detergent composition comprising a hydrate-forming salt and a betaine class of zwitterionic compound wherein the hydrate-forming salt is at least partially coated with the zwitterionic compound.
- The coated filler agent of the present invention includes a betaine class of zwitterionic compound.
- The betaine class of zwitterionic compound is preferably a zwitterionic surfactant or a zwitterionic polymer, preferably a zwitterionic surfactant. Suitable zwitterionic surfactants are known in the art, and include, for example, those surfactants broadly described as derivatives of aliphatic quaternary ammonium, phosphonium and sulfonium compounds, in which the aliphatic radicals can be straight or branched chain, and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic group such as carboxyl, sulfonate, sulfate, phosphate or phosphonate.
- Specific examples of suitable zwitterionic surfactants include alkyl betaines, such as cocodimethyl carboxymethyl betaine, lauryl dimethyl carboxymethyl betaine, lauryl dimethyl alphacarboxy-ethyl betaine, cetyl dimethyl carboxymethyl betaine, lauryl bis-(2- hydroxy-ethyl)carboxy methyl betaine, stearyl bis-(2-hydroxypropyl)carboxymethyl betaine, oleyl dimethyl gamma-carboxypropyl betaine, and lauryl bis-(2-hydroxypropyl)alpha-carboxyethyl betaine, alkyl arnidopropyl betaines, and alkyl sultaines, such as cocodimethyl sulfopropyl betaine, stearyldimethyl sulfopropyl betaine, lauryl dimethyl sulfoethyl betaine, lauryl bis-(2-hydroxy-ethyl)sulfopropyl betaine, cocamidopropyl hydroxysultaine and alkylamidopropylhydroxy sultaines. Preferred examples of phospho-betaine includes but are not limited to propyl Monosodium Phosphobetaine, Cocamido Disodium Ethyl Phosphobetaine, Coeamido Disodium 3-I-lydroxypropyl Phospho-betaine, Laurie myriatic Amido 3-Hydroxypropyl Phospho-betaine.
-
- Mā :
- is selected from a sulphonate (SO3)-, phosphonate (PO4 -), carbonate (CO3 -)
- R1 :
- is an alkyl group having from 1 to 14 carbon atoms, preferably 1 to 2 carbon atoms and is preferably a straight chain or branched chain.
- R2 :
- is an alkyl group having from 1 to 14 carbon atoms, preferably 1 to 2 carbon atoms and is preferably a straight chain or branched chain.
- R3 :
- is an alkyl group having from 6 to 14 carbon atoms, preferably 10 to 14 carbon atoms and is preferably a straight chain or branched chain or
-
- Mā :
- is selected from a sulphonate (SO3)-, phosphonate (PO4 -), carbonate (CO3 -)
- R1 :
- is an alkyl group having from 1 to 14 carbon atoms, preferably 1 to 2 carbon atoms and is preferably a straight chain or branched chain.
- R2 :
- is an alkyl group having from 1 to 14 carbon atoms, preferably 1 to 2 carbon atoms and is preferably a straight chain or branched chain.
- R3 :
- is an alkyl group having from 6 to 14 carbon atoms, preferably 10 to 14 carbon atoms and is preferably a straight chain or branched chain or
- Specific useful sultaines are for example 3-(dodecyldimethylammonio)propane-1-sulfonate and 3-(tetradecyldimethylammonio) ethane- 1 -sulfonate.
- The zwitterionic surfactant is most preferably a carbo-betaine, sulpho-betaine, phospho-betaine, carboxy-betaine or mixtures thereof.
-
- The betaine class of zwitterionic compound is present in an amount ranging from 0.5 to 20wt% based on the coated filler agent.
- Preferably the amount of zwitterionic compound in the coated filler agent is at least 1wt%, still preferably at least 2.5wt%, further preferably at least 3wt% and most preferably at least 5wt%, but typically not more than 10wt%, still preferably not more than 15wt% and most preferably not more than 20wt% based on the coated filler agent.
- The betaine class of zwitterionic compound according to the present invention is at least partially coating the hydrate-forming salt. More preferably, the zwitterionic compound completely covers the hydrate-forming salt.
- The coated filler agent of the present invention comprises a hydrate-forming salt. The hydrate-forming salt of the present invention is at least partially coated with a betaine class of zwitterionic compound.
- Non-limiting examples of the hydrate-forming salt are sulphate, carbonate or bicarbonate salt of alkaline earth metal or alkali metal and mixtures thereof.
- Preferred examples of the hydrate-forming salt according to the present invention are selected from the group consisting of sodium carbonate, sodium sulphate, sodium bicarbonate, sodium tripolyphosphate, sodium pyrophosphate, sodium orthophosphate, magnesium sulphate or mixtures thereof. Preferably the hydrate-forming salt is sodium carbonate, sodium sulphate or mixtures thereof.
- Present invention is particularly suitable for any salt that exhibits significant change in solubility with decrease in temperature. This is specifically suitable for salts which easily crystallises from the aqueous solution at a relatively low temperature to form crystals which easily coalesce together to form a firm structure. Without being bound by theory it is believed that this crystal formation inhibits the dispersibility and solubility of the detergent composition. Among the known salts used in the detergent composition, sodium carbonate generates a large amount of heat upon hydration and dissolves even in cold water to form a solution having a high concentration with the generation of heat. The heat is later taken up by the low-temperature surrounding and with the lowered temperature the solubility of the hydrated salt reduces and the salt precipitates as crystals. At a temperature of 32Ā°C or below, sodium carbonate is in the form of its decahydrate and it has a large amount of water of crystallization. The hydration increases the volume of the undissolved crystals and such hydrated crystals coalesce together easily to form a firmer structure. Therefore, the problem of residue formation is particularly higher in compositions with sodium carbonate.
- The hydrate-forming salt is present in an amount ranging from 80 to 99wt% based on the coated filler agent. Preferably the amount of hydrate-forming salt in the coated filler agent is at least 80wt%, still preferably at least 85wt%, further preferably at least 87wt% and most preferably at least 90wt%, but typically not more than 99wt%, still preferably not more than 97.5wt% and most preferably not more than 95wt% based on the coated filler agent.
- Any of the methods known in the art for coating may be used for the present invention.
- Preferably the method for preparing the coated filler agent comprises the steps of:
- a. providing a hydrate-forming salt;
- b. applying a coating onto the hydrate-forming salt by either spraying or pouring betaine class of zwitterionic compound or intimately mixing the hydrate forming salt and the zwitterionic compound or preparing a slurry of the hydrate-forming salt and the zwitterionic compound and thereafter drying the slurry.
- A preferred method of coating includes spraying or pouring the zwitterionic compound onto the hydrate-forming salt. The hydrate-forming salt is constantly mixed during the process of coating. Preferably the hydrate-forming salt is taken in a plough shear mixer or other high speed mixers, which can keep the hydrate-forming salt at high speed rotation during the coating process. The coated filler agent obtained from the process are according to the present invention and the zwitterionic compound at least partially covers or coats the hydrate-forming salt. In another preferred method, the hydratable salt is taken in a sigma or a z-blender during the coating process in which the zwitterionic compound is constantly sprayed or poured onto the hydrate-forming salt.
- Another method of preparing the coated filler agent of the present invention involves a first step of preparing an aqueous slurry comprising the hydrate-forming salt and the zwitterionic compound, the slurry is thereafter dried preferably by spray drying route, the coated filler agent obtained is according to the present invention in which the zwitterionic compound at least partially covers the hydrate-forming salt.
- According to a second aspect of the present invention, disclosed is a filler composition having the coated filler agent of the first aspect and a water-soluble salt.
- The filler composition according to the second aspect of the present invention comprises a water-soluble salt that has a solubility of more than 30 grams/100mL in distilled water when measured at a temperature of 10Ā°C, the water-soluble salt being present separate from the hydrate-forming salt. Preferably the water-soluble salt has a solubility of at least 35grams/100mL, still preferably at least 40 grams/100mL, further preferably at least 45grams/100mL.
- Non-limiting examples of the water-soluble salt includes potassium carbonate, potassium chloride, potassium formate, potassium acetate, sodium chloride, sodium acetate, sodium formate, calcium acetate, magnesium chloridesodium di-hydrogen phosphate, potassium bi-sulphate, magnesium acetate, sodium fumarate. More preferably the water-soluble salt is selected from sodium chloride, sodium acetate or sodium formate.
- Preferably the amount of water-soluble salt in the filler composition is at least 5wt%, still preferably at least 10wt%, further preferably at least 15wt% and most preferably at least 20wt%, but typically not more than 40wt%, still preferably not more than 50wt% and most preferably not more than 60wt% based on the filler composition.
- According to a third aspect of the present invention disclosed is a solid detergent composition comprising a coated filler agent according to the first aspect or a filler composition according to the second aspect of the present invention.
- A solid detergent composition according to the present disclosure encompasses powders as well as a variety of cast and extruded forms including, for example, pellets, blocks, particles and tablets. It should be understood that the term "solid" refers to the state of the detergent composition under the expected conditions of storage and use of the solid detergent composition. In general, it is expected that the detergent composition will remain a solid when provided at a temperature of up to about 100Ā°F. Preferably the solid detergent composition is a powder, tablet, granular or a particulate composition.
- In certain embodiments, the detergent composition is provided in the form of a unit dose. A unit dose refers to a detergent composition in unit size so that the entire unit is used during a single washing cycle. When the solid detergent composition is provided as a unit dose, it is preferably provided as a cast solid, an extruded particle or pellet, or a tablet having a size of between about 1 gram and about 50 grams. In other embodiments, a cast solid, an extruded pellet, or a tablet having a size of between 50 grams up through 250 grams, or an extruded solid with a weight of about 100 grams or greater.
- Furthermore, it should be appreciated that the solid detergent composition can be provided as a cast solid, an extruded pellet, or a tablet so that a plurality of the solids will be available in a package having a size of between about 40 grams and about 11,000 grams.
- In other embodiments, the solid detergent composition is provided in the form of a multiple-use solid, such as, a block or a plurality of pellets, and can be repeatedly used to generate aqueous detergent composition for multiple washing cycles. In certain embodiments, the solid detergent composition is provided as a powder, cast solid, an extruded block, or a tablet having a mass of between about 5 grams and 10 kilograms. In certain embodiments, a multiple-use form of the solid detergent composition has a mass between about 1 and 10 kilograms, more preferably 1 kg to 5 kg.
- Preferably the solid detergent composition includes 2wt% to 40wt% of the coated filler agent. Preferably the amount of coated filler agent in the solid detergent composition is at least 2wt%, still preferably at least 5wt%, further preferably at least 10wt% and most preferably at least 15wt%, but typically not more than 30wt%, still preferably not more than 35wt% and most preferably not more than 40wt% based on the detergent composition.
- In a further embodiment of the present invention, the detergent composition includes a filler composition having a coated filler agent and a water-soluble salt.
- The detergent composition preferably includes a filler composition in an amount which is at least 5wt%, still preferably at least 8wt%, further preferably at least 10wt% and most preferably at least 15wt% based on the weight of the detergent composition, but typically not more than 30wt%, still preferably not more than 40wt% and most preferably not more than 50wt% based on the weight of the detergent composition.
- Preferably, the detergent composition includes a surfactant selected from anionic, non-ionic, zwitterionic, cationic or amphoteric surfactant.
- Suitable anionic detergent compounds which may be used are usually water- soluble alkali metal salts of organic sulphates and sulphonates having alkyl radicals containing from about 8 to about 22 carbon atoms, the term alkyl being used to include the alkyl portion of higher acyl radicals.
- Examples of suitable synthetic anionic detergent compounds are sodium and potassium alkyl sulphates, especially those obtained by sulphating higher C8 to C18 alcohols, produced for example from tallow or coconut oil, sodium and potassium alkyl C9 to C20 benzene sulphonates, particularly sodium linear secondary alkyl C10 to C15 benzene sulphonates; and sodium alkyl glyceryl ether sulphates, especially those ethers of the higher alcohols derived from tallow or coconut oil and synthetic alcohols derived from petroleum.
- The anionic surfactant is preferably selected from: linear alkyl benzene sulphonate; alkyl sulphates; alkyl ether sulphates; soaps; alkyl (preferably methyl) ester sulphonates, and mixtures thereof.
- The most preferred anionic surfactants are selected from: linear alkyl benzene sulphonate; alkyl sulphates; alkyl ether sulphates and mixtures thereof. Preferably the alkyl ether sulphate is a C12 to C14 n-alkyl ether sulphate with an average of 1 to 3EO (ethoxylate) units. Sodium lauryl ether sulphate is particularly preferred (SLES). Preferably the linear alkyl benzene sulphonate is a sodium C11 to C15 alkyl benzene sulphonates. Preferably the alkyl sulphates is a linear or branched sodium C12 to C18 alkyl sulphates. Sodium dodecyl sulphate is particularly preferred, (SDS, also known as primary alkyl sulphate). Preferably the solid detergent composition includes 2wt% to 80wt% of the anionic surfactant.
- The nonionic surfactant component preferably comprises alcohol ethoxylate. The alcohol ethoxylates are formed from the reaction of primary or secondary alcohols with ethylene oxide. Typically, an aliphatic C8 to C18 primary or secondary linear or branched alcohol is reacted with ethylene oxide in the required molar amount to produce the alcohol ethoxylate. Preferred alcohol ethoxylates have from 2 to 40, preferably from 3 to 30, more preferably from 5 to 20 ethylene oxide 20 units attached to the aliphatic chain.
- The surfactants may be chosen from the surfactants described in "Surface Active Agents" Vol. 1, by Schwartz & Perry, Interscience 1949, Vol. 2 by Schwartz, Perry & Berch, Interscience 1958, in the current edition of "McCutcheon's Emulsifiers and Detergents" published by Manufacturing Confectioners Company or in "Tenside-Taschenbuch", H. Stache, 2nd Edn. , Carl Hauser Verlag, 1981. Preferably the surfactants used are saturated.
- Suitable nonionic detergent compounds which may be used include, in particular the reaction products of compounds having a hydrophobic group and a reactive hydrogen atom, for example, aliphatic alcohols, acids, amides or alkyl phenols with alkylene oxides, especially ethylene oxide either alone or with propylene oxide. Specific nonionic detergent compounds are C6 to C22 alkyl phenolethylene oxide condensates, generally 5 to 25 EO, i.e. 5 to 25 units of ethylene oxide per molecule, and the condensation products of aliphatic C8 to C18 primary or secondary linear or branched alcohols with ethylene oxide, generally 5 to 40 EO.
- The total amount of surfactant present in the composition is preferably at least 5 wt. %, more preferably at least 10 wt. %, More preferably the total amount of surfactant is from 15 to 65 wt. %, preferably from 10 to 50 wt. %
- Other surfactants such as cationic surfactants and amphoteric/zwitterionic surfactants such as betaines may also be present in addition to the aforementioned nonionic and anionic surfactants.
- Builder materials may be selected from 1) calcium sequestrant materials, 2) precipitating materials, 3) calcium ion-exchange materials and 4) mixtures thereof.
- Examples of calcium sequestrant builder materials include alkali metal polyphosphates, such as sodium tripolyphosphate and organic sequestrants, such as ethylene diamine tetra-acetic acid.
- Examples of precipitating builder materials include sodium orthophosphate.
- Examples of calcium ion-exchange builder materials include various types of water-insoluble crystalline or amorphous aluminosilicates, of which zeolites are well known representatives thereof, e.g. zeolite A, zeolite B (also known as zeolite P), zeolite C, zeolite X, zeolite Y and also the zeolite P-type described in
EP-A-0,384,070 . - The detergent compositions may also optionally contain relatively low levels of organic detergent builder or sequestrant material. Examples include the alkali metal, citrates, succinates, malonates, carboxymethyl succinates, carboxylates, polycarboxylates and polyacetyl carboxylates. Specific examples include sodium, potassium and lithium salts of oxydisuccinic acid, mellitic acid, benzene polycarboxylic acids, ethylene diamine tetra-acetic acid, diethylenetriaminepentaacetic acid, alkyl- or alkenylsuccinic acid, nitrilotriacetic acid, and citric acid. Other examples are DEQUESTā¢, organic phosphonate type sequestering agents sold by Monsanto and alkanehydroxy phosphonates.
- Other suitable organic builders include the higher molecular weight polymers and copolymers known to have builder properties. For example, such materials include appropriate polyacrylic acid, polymaleic acid, and polyacrylic/polymaleic acid copolymers and their salts, such as those sold by BASF under the name SOKALANā¢.
- If utilized, the builder materials may comprise from about 0.5% to 20 wt%, preferably from 1 wt% to 10 wt%, of the composition. The preferred builder level is less than 10 wt% and preferably less than 5 wt% of the composition. Preferably the laundry detergent formulation is a non-phosphate built laundry detergent formulation, i.e., contains less than 1 wt. % of phosphate.
- Shading dyes deposit to fabric during the wash or rinse step of the washing process providing a visible hue to the fabric. Shading of white garments may be done with any colour depending on consumer preference. Blue and Violet are particularly preferred shades and consequently preferred dyes or mixtures of dyes are ones that give a blue or violet shade on white fabrics. The shading dyes used are preferably blue or violet. The shading dye chromophore is preferably selected from the group comprising: mono-azo, bis-azo, triphenylmethane, triphenodioxazine, phthalocyanin, naptholactam, azine and anthraquinone. Most preferably mono-azo, bis-azo, azine and anthraquinone. Most preferably the dye bears at least one sulfonate group. Preferred shading dyes are selected from direct dyes, acid dyes, hydrophobic dyes, cationic dyes and reactive dyes.
- If included, the shading dye is present is present in the composition in range from 0.0001 to 0.01 wt %.
- The composition preferably comprises a fluorescent agent (optical brightener). Fluorescent agents are well known and many such fluorescent agents are available commercially. Usually, these fluorescent agents are supplied and used in the form of their alkali metal salts, for example, the sodium salts. The total amount of the fluorescent agent or agents used in the composition is generally from 0.005 to 2 wt. %, more preferably 0.01 to 0.1 wt. %. Preferred classes of fluorescer are: Di-styryl biphenyl compounds, e.g. Tinopal (Trade Mark) CBS-X, Di-amine stilbene di-sulphonic acid compounds, e.g. Tinopal DMS pure Xtra and Blankophor (Trade Mark) HRH, and Pyrazoline compounds, e.g. Blankophor SN. Preferred fluorescers are: sodium 2-(4-styryl-3-sulfophenyl)-2H-napthol[1, 2-d]trazole, disodium 4,4'-bis([(4-anilino-6-(N methyl-N-2 hydroxyethyl) amino 1,3,5-triazin-2-yl)]amino)stilbene-2-2' disulfonate, disodium 4,4'-bis([(4-anilino-6-morpholino-1,3,5-triazin-2-yl)]amino) stilbene-2-2' disulfonate, and disodium 4,4'-bis(2-sulfoslyryl)biphenyl.
- Preferably the composition comprises a perfume. The perfume is preferably in the range from 0.001 to 3 wt. %, most preferably 0.1 to 1 wt. %. Many suitable examples of perfumes are provided in the CTFA (Cosmetic, Toiletry and Fragrance Association) 1992 International Buyers Guide, published by CFTA Publications and OPD 1993Chemicals Buyers Directory 80th Annual Edition, published by Schnell Publishing Co.
- It is commonplace for a plurality of perfume components to be present in a formulation. In the compositions of the present invention it is envisaged that there will be four or more, preferably five or more, more preferably six or more or even seven or more different perfume components.
- The composition may comprise one or more polymers. Polymers can assist in the cleaning process by helping to retail soil in solution or suspension and/or preventing the transfer of dyes. Polymers can also assist in the soil removal process. Dye transfer, anti-redeposition and soil-release polymers are described in further detail below.
- The composition may comprise one or more polymers. Examples are carboxymethylcellulose, hydroxyethyl cellulose, hydroxpropyl cellulose, poly(ethylene glycol), poly(vinyl alcohol), ethoxylated polyamines, polycarboxylates such as polyacrylates, maleic/acrylic acid copolymers and lauryl methacrylate/acrylic acid copolymers.
- Modern detergent compositions typically employ polymers as so-called 'dye-transfer inhibitors'. These prevent migration of dyes, especially during long soak times. Generally, such dye-transfer inhibiting agents include polyvinyl pyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, manganese pthalocyanine, peroxidases, and mixtures thereof, and are usually present at a level of from 0.01 to 10 wt. % based on total amount in the laundry composition.
- Anti-redeposition polymers are designed to suspend or disperse soil. Typically 25 antiredeposition polymers are ethoxylated and or propoxylated polyethylene imine or polycarboxylate materials, for example, Acrylic acid based homo or copolymers available under the trade mark ACUSOL from Dow Chemical, Alcosperse from Akzonobel or Sokolan from BASF.
- Examples of suitable soil release polymers include graft copolymers of poly(vinyl ester), e.g., C1 - C6 vinyl esters, preferably poly(vinyl acetate) grafted onto polyalkylene oxide backbones. Commercially available soil release agents of this kind include the SOKALAN type of material, e.g., SOKALAN HP-22, available from BASF (West Germany). Further suitable soil release polymers of a different type include the commercially available material ZELCON 5126 (from DuPont) and MILEASE T (from ICI). If present, the soil release polymer may be included at a level of from 0.01 to 10 wt. % based on total amount in the laundry composition. Further examples of soil release polymers are terephthalic acid / glycol copolymers sold under the tradenames Texcare, Repel-o-tex, Gerol, Marloquest, Cirrasol.
- Enzymes can also be present in the formulation. Preferred enzymes include protease, lipase, pectate lyase, amylase, cutinase, cellulase, mannanase.
- According to another aspect of the present invention disclosed is use of a coated filler agent of the first aspect or a filler composition of the second aspect in a detergent composition for improving cold water solubility and/or dispersibility.
- The invention will now be explained in greater details with non-limiting examples of compositions according to the present invention.
- To determine the solubility of the hydrate-forming salts in the coated filler agent different compositions were prepared and tested in the following manner. The compositions tested are given in table 1.
- 10 grams of the composition having the hydrate-forming salt as given in Table 1 was taken in a beaker. To this 100mL of water maintained at a temperature of 5Ā°C is added and left undisturbed for 5 minutes. After 5 minutes the solution was gently mixed 5 times in clockwise direction and another 5 times in anticlockwise direction using a glass rod. The solution was then slowly decanted to separate out the solid portion. The collected residue was dried at a temperature of 60Ā°C and the weight of the residue was weighed and recorded in table 1.
- In Example 1, 10 grams of sodium sulphate (hydrate-forming salt) was taken in a plough shear mixer and rotated at high speed, during the mixing 0.05 grams of sulphobetaine was sprayed onto the salt and after 5 minutes of mixing the coated filler agent was obtained and tested for solubility.
- In Example 2, the coated filler agent was prepared similar to example 1 and thereafter the sodium chloride was added to obtain the filler composition. Similarly, in Example 3 a different filler composition having sodium chloride and potassium carbonate was obtained.
- In example B, the preparation of the filler agent was similar to that of Example 1 except that instead of the sulphobetaine, given amount of Neodol EO7 (ethoxylated non-ionic surfactant) was used.
Table 1 Filler agent Ex A (grams) Ex 1 (grams) Ex 2 (grams) Ex 3 (grams) Ex B (grams) Na2SO4 10 10 10 10 10 sulphobetaine - 0.05 0.05 0.05 Non-ionic surfactant - - - - 0.05 Sodium chloride - - 2 1 - Potassium carbonate - - - 1 - Residue obtained 9.5 7.3 3.2 2.2 7.3 Nature of residue Hard Soft Very soft and powder like Very soft and powder like Hard and similar to example A - The table above shows that best results for solubility when dissolved at 5Ā°C are obtained when the sodium sulphate (hydrate-forming salt) is at least partially coated with the sulphobetaine (Ex 2) according to the present invention. The table also indicates that the solubility of the filler agent is lower and the residue formed is hard in Ex A, and Ex B which has either no coating or coated with a compound outside the scope of the present invention. Further filler composition of Ex 2 and 3 having a coated filler agent and a water-soluble salt shows improved solubility and the nature of residue is also soft.
- 3 different solid detergent compositions as shown in Table 2 were evaluated. 100 grams of each of the solid detergent composition was packed in pouches and kept at a temperature of 5Ā°C for 24 hours. Thereafter 100grams of each of the solid detergent composition was poured in the powder-dispensing drawer of Samsung automatic top loading machine. Water maintained at a temperature of 5Ā°C was allowed to contact the powder at the required flow rate as given in Table 2 and then followed by the fuzzy cycle. The residue remaining in powder dispensing drawer at the end of the cycle was taken and dried at a temperature of 60Ā°C for 24 hours. After drying, the residue was weight and the amount of residue was determined as provided in Table 2.
Table 2 Solid detergent composition Ex C Ex 4 Ex 5 Spray dried base powder Anionic surfactant 12 12 12 Na silicate 6 6 6 Na caboxymethyl cellulose 0.14 0.14 0.14 Na carbonate 11.52 11.52 11.52 Na sulphate 27.67 27.67 27.67 Dyes, polymers, moisture etc. 2.67 2.67 2.67 Post dosed ingredients Zeolite 3.64 3.64 3.64 Sodium sulphate 23.82 22.82 18.82 Sodium carbonate 9.48 9.48 9.48 Enzymes, SRPs etc 3.06 3.06 3.06 Sulphobetaine (49% purity) 0 1.0 1.0 Potassium carbonate 0 0 2.0 Sodium acetate 0 0 2.0 Residue when the flow rate of water at 5Ā°C was maintained at 2.5 litres per minute (grams) 68.88 60.15 Not evaluated at this flow rate Residue when the flow rate of water at 5Ā°C was maintained at 5 litres per minute (grams) 17.27 Not evaluated at this flow rate 5.76 - The table above shows that best results for solubility when dissolved at 5Ā°C are obtained when the sodium sulphate (hydrate-forming salt) is at least partially coated with the sulphobetaine (Ex 4) according to the present invention. Further filler composition of Ex 5 having a coated filler agent and a water-soluble salt shows improved solubility and dispersibility as compared to detergent composition of comparative example C having only the hydrate-forming salt.
- It will be appreciated that the illustrated examples provide a coated filler agent having a hydrate-forming salt at least partially coated with the zwitterionic compound provides improved cold water solubility and dispersibility.
- It should be understood that the specific forms of the invention herein illustrated and described are intended to be representative only as certain changes may be made therein without departing from the clear teachings of the disclosure.
- Although the invention has been described with reference to specific embodiments, it will be appreciated by those skilled in the art that the invention may be embodied in many other forms.
Claims (15)
- A coated filler agent for use in a solid detergent composition comprising a hydrate-forming salt and a betaine class of zwitterionic compound wherein the hydrate-forming salt is at least partially coated with the zwitterionic compound.
- A coated filler agent according to claim 1 wherein the hydrate-forming salt is selected from the group consisting of sulphate, carbonate or bicarbonate salt of alkaline earth metal or alkali metal and mixtures thereof.
- A coated filler agent as claimed in claim 2 wherein the hydrate-forming salt is selected from sodium carbonate, sodium sulphate or mixtures thereof.
- A coated filler agent according to any one of the preceding claims wherein zwitterionic compound is a zwitterionic surfactant.
- A coated filler agent according to claim 4 wherein the zwitterionic surfactant is selected from a carbo-betaine/carboxy-betaine, sulpho-betaine, phospho-betaine, or mixtures thereof.
- A coated filler agent according to any one of the preceding claims wherein the zwitterionic surfactant is present an amount from 0.5 to 20wt% based on the coated filler agent.
- A coated filler agent according to any one of the preceding claims wherein the hydrate-forming salt is present in an amount from 80 to 99 wt% based on the coated filler agent.
- A filler composition comprising a coated filler agent according to any one of the preceding claims and a water-soluble salt with a solubility of more than 30grams/100mL in distilled water when measured at a temperature of 10Ā°C, the water-soluble salt being present separate from the hydrate-forming salt.
- A filler composition according to claim 8 wherein the water-soluble salt is selected from sodium chloride, sodium formate or sodium acetate.
- A solid detergent composition comprising a coated filler agent according to any one of the preceding claims 1 to 7 or a filler composition according to claim 8 or 9.
- A solid detergent composition according to claim 10 wherein the coated filler agent is in an amount ranging from 2wt% to 40wt% based on the solid detergent composition.
- A solid detergent composition according to claim 10 wherein the filler composition is in an amount ranging from 5wt% to 50wt% based on the solid detergent composition.
- A solid detergent composition according to claim 10 or 11 wherein the composition is a powder, tablet, granular or a particulate composition.
- A solid detergent composition according to any one of the claims 10 to 12 wherein the composition comprises 2 wt% to 80wt% anionic surfactant.
- Use of a coated filler agent according to any one of the claims 1 to 6 or a filler composition according to claims 8 or 9 in a solid detergent composition for improving cold water solubility and/or dispersibility.
Applications Claiming Priority (2)
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EP17196421 | 2017-10-13 | ||
PCT/EP2018/074304 WO2019072468A1 (en) | 2017-10-13 | 2018-09-10 | Detergent composition comprising hydrate-forming salt particles coated with betaine |
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EP3694967B1 true EP3694967B1 (en) | 2021-10-27 |
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EP (1) | EP3694967B1 (en) |
CN (1) | CN111212896B (en) |
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DE3768509D1 (en) | 1986-01-17 | 1991-04-18 | Kao Corp | HIGH DENSITY GRANULATED DETERGENT. |
CA2001927C (en) | 1988-11-03 | 1999-12-21 | Graham Thomas Brown | Aluminosilicates and detergent compositions |
CN1233275A (en) * | 1996-03-15 | 1999-10-27 | ē¾å½å®å©ęéå ¬åø | Free-flowing agglomerated nonionic surfactant detergent composition and process for making same |
US6258859B1 (en) * | 1997-06-10 | 2001-07-10 | Rhodia, Inc. | Viscoelastic surfactant fluids and related methods of use |
CN101868526B (en) * | 2007-11-16 | 2014-07-16 | č±ēę Ŗå¼ä¼ē¤¾ | Detergent builder granule |
CN102492573B (en) * | 2011-12-06 | 2013-04-03 | 大čæęéŖåč“øęéå ¬åø | Laundry sheet |
GB2516261A (en) * | 2013-07-16 | 2015-01-21 | Solent Internat Ltd | Cleaning product |
CN103849495A (en) * | 2014-03-17 | 2014-06-11 | åčÆ蓵 | Detergent for kitchenware and manufacture method thereof |
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WO2019072468A1 (en) | 2019-04-18 |
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CN111212896A (en) | 2020-05-29 |
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