EP3619416A1 - Steel piston having a phosphate layer - Google Patents
Steel piston having a phosphate layerInfo
- Publication number
- EP3619416A1 EP3619416A1 EP18722516.4A EP18722516A EP3619416A1 EP 3619416 A1 EP3619416 A1 EP 3619416A1 EP 18722516 A EP18722516 A EP 18722516A EP 3619416 A1 EP3619416 A1 EP 3619416A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- phosphate layer
- piston
- steel
- steel piston
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910019142 PO4 Inorganic materials 0.000 title claims abstract description 24
- 239000010452 phosphate Substances 0.000 title claims abstract description 24
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title claims abstract description 24
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 19
- 239000010959 steel Substances 0.000 title claims abstract description 19
- 238000002485 combustion reaction Methods 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 15
- 238000000576 coating method Methods 0.000 claims description 13
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 11
- 239000002966 varnish Substances 0.000 claims description 10
- 230000001050 lubricating effect Effects 0.000 claims description 9
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 6
- CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 abstract description 4
- 239000007787 solid Substances 0.000 abstract description 4
- 239000011159 matrix material Substances 0.000 description 4
- 235000011007 phosphoric acid Nutrition 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- -1 M0S2 Chemical compound 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- QVLTXCYWHPZMCA-UHFFFAOYSA-N po4-po4 Chemical compound OP(O)(O)=O.OP(O)(O)=O QVLTXCYWHPZMCA-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/18—Orthophosphates containing manganese cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F3/00—Pistons
- F02F3/10—Pistons having surface coverings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2080/00—Special pretreatment of the material to be lubricated, e.g. phosphatising or chromatising of a metal
Definitions
- the present invention relates to a steel piston
- Eating usually provided with a shaft coating.
- a bonded coating which contains one or more solid lubricants, eg graphite or M0S 2 .
- solid lubricants eg graphite or M0S 2 .
- the piston In order to ensure the adhesion of the bonded coating over the entire service life of the piston, the piston must be pretreated.
- a manganese phosphating is used, which is applied by means of dipping method.
- an interruption of the usual manufacturing process and manual handling of the piston is necessary. This can lead to contamination on the surface of the piston.
- the steel piston it is possible for the steel piston to be only neutral, before applying the lubricating varnish.
- this object is achieved by a special phosphating process and a steel piston with an available, amorphous phosphate layer.
- the invention relates to a steel piston, preferably a steel piston for an internal combustion engine, which comprises an amorphous phosphate layer at least in one region. Furthermore, the invention relates to a method for producing such a steel piston.
- amorphous phosphate layer means that the layer has an amorphous structure in plan view.
- Manganese phosphate or zinc phosphate layers with crystalline structure with crystalline structure.
- the amorphous structure of the layer affects the properties of the layer, e.g. their roughness and
- the method according to the invention comprises the following
- step (3) optionally forming a manganese phosphate layer.
- the amorphous phosphate layer formed according to the invention has capillaries and thereby enables a better
- the amorphous phosphate layer acts as a passivation layer, so that a renewed oxidation of the piston is avoided.
- a thin, amorphous phosphate layer can be applied.
- it may be thinner than a conventional, crystalline phosphate layer. This in turn allows lower manufacturing tolerances.
- the amorphous phosphate layer has a thickness of 0.05 ym to 5 ym, more preferably 0.1 ym to 3 ym.
- the amorphous phosphate layer can be applied to the entire piston or individual regions, for example the piston skirt or the pin bore.
- the layer is applied to the entire piston
- a lubricating varnish (2) may further be applied to the amorphous phosphate layer. If appropriate, in step (3) on the piston thus obtained
- the piston can also be coated exclusively with the lubricating varnish.
- the phosphoric acid-containing solution used according to the invention can be applied by spraying, so that the amorphous phosphate layer can be generated inline. By doing so leaves avoid manual handling of the piston, and the risk of contamination of the surface of the piston is reduced.
- the inventive method can be integrated into the process for producing the piston without great expense.
- the solution used in step (1) preferably contains a surfactant in addition to phosphoric acid (ortho-phosphoric acid). In this way, the wetting of the surface can be improved, so that a more uniform layer is formed. Further, the solution may contain other ingredients.
- Suitable nitrates e.g. Sodium nitrate, manganese nitrate and
- Zinc nitrate, and / or sulfonates proved.
- the nitrate, and / or sulfonates proved.
- the solution preferably has a pH of from 1 to 3.
- step (1) After completion of step (1), the solution, e.g. by rinsing, be removed from the surface of the flask.
- step (2) is carried out by a method known to the person skilled in the art.
- a manganese phosphate layer can subsequently be formed in a further step (3).
- This process can be carried out in a manner known to those skilled in the art.
- the treatment according to the invention of the steel piston leads to a better adhesion of the lubricating varnish.
- the lubricating varnish is preferably one
- Anti-friction varnish comprising a polymer matrix.
- a polymer matrix the usual starting materials for piston coatings, such as phenolic resins, epoxy resins, polyamide,
- Polyamide-imide and / or PTFE are used, preferred are phenolic resins and / or epoxy resins.
- a crosslinkable polymer is used as the matrix for the coating, then it is crosslinked after application.
- the crosslinking of the matrix can be effected thermally or by means of radiation, for example by UV or IR radiation.
- the bonded coating further particularly preferred
- Solid lubricant (s) preferably substances with a laminar crystallizing structure used, such as graphite, M0S2, WS2, -BN. Furthermore, polymers such as e.g. PTFE can be used.
- amorphous phosphate layer according to the invention can be improved, are e.g. in DE 10 2009 002 716 AI and 10 2009 002 715 AI described.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Treatment Of Metals (AREA)
- Pistons, Piston Rings, And Cylinders (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL18722516T PL3619416T3 (en) | 2017-05-05 | 2018-05-04 | Steel piston having a phosphate layer |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102017207591.0A DE102017207591A1 (en) | 2017-05-05 | 2017-05-05 | Steel piston with a phosphate layer |
PCT/EP2018/061497 WO2018202849A1 (en) | 2017-05-05 | 2018-05-04 | Steel piston having a phosphate layer |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3619416A1 true EP3619416A1 (en) | 2020-03-11 |
EP3619416B1 EP3619416B1 (en) | 2021-10-13 |
Family
ID=62116459
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP18722516.4A Active EP3619416B1 (en) | 2017-05-05 | 2018-05-04 | Steel piston having a phosphate layer |
Country Status (8)
Country | Link |
---|---|
US (1) | US20200102656A1 (en) |
EP (1) | EP3619416B1 (en) |
CN (1) | CN110892142B (en) |
BR (1) | BR112019023182A2 (en) |
DE (1) | DE102017207591A1 (en) |
PL (1) | PL3619416T3 (en) |
RU (1) | RU2769041C2 (en) |
WO (1) | WO2018202849A1 (en) |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1083779A (en) * | 1965-09-08 | 1967-09-20 | Pyrene Co Ltd | Production of phosphate coatings on metal |
IT1004936B (en) * | 1974-02-13 | 1976-07-20 | Mondial Piston Ec Spa | PISTON WITH SLOTS FOR HOUSING THE SEGMENTS COATED WITH A LAYER OF AMORPHOUS NICKEL-PHOSPHORUS CATALYTICALLY DEPOSITED |
SE441105B (en) * | 1976-04-05 | 1985-09-09 | Amchem Prod | PROCEDURE FOR PREPARING AN AMORPH, LIGHT, HARD FIXED PHOSPHATE COATING |
GB2148950B (en) * | 1983-10-26 | 1987-02-04 | Pyrene Chemical Services Ltd | Phosphating composition and processes |
US5597465A (en) * | 1994-08-05 | 1997-01-28 | Novamax Itb S.R.L. | Acid aqueous phosphatic solution and process using same for phosphating metal surfaces |
DE4433946A1 (en) * | 1994-09-23 | 1996-03-28 | Henkel Kgaa | Phosphating process without rinsing |
DE19629399B4 (en) * | 1996-07-20 | 2008-10-16 | Mahle Gmbh | Piston for internal combustion engines with a piston crown or piston top |
JP2000249063A (en) * | 1999-02-26 | 2000-09-12 | Toyota Autom Loom Works Ltd | Piston for piston type compressor |
JP2000313967A (en) * | 1999-04-27 | 2000-11-14 | Sumitomo Metal Ind Ltd | Surface treated steel sheet excellent in corrosion resistance |
US20040118483A1 (en) * | 2002-12-24 | 2004-06-24 | Michael Deemer | Process and solution for providing a thin corrosion inhibiting coating on a metallic surface |
DE102005055365A1 (en) * | 2004-12-10 | 2006-06-22 | Mahle International Gmbh | Piston for an internal combustion engine and method for coating its hub bores |
ES2423901T3 (en) * | 2005-03-29 | 2013-09-25 | Nippon Steel & Sumitomo Metal Corporation | Threaded joint for steel pipes |
US7687098B1 (en) * | 2005-08-26 | 2010-03-30 | Charlie W. Chi | Chemical mechanical vapor deposition device for production of bone substitute material |
DE102005042474A1 (en) * | 2005-09-07 | 2007-03-08 | Ks Aluminium-Technologie Ag | Coating of a thermally and erosively loaded functional component, and a release agent and a method for producing the coating |
JP5021396B2 (en) * | 2007-08-24 | 2012-09-05 | 日本ピストンリング株式会社 | piston ring |
JP2009052706A (en) * | 2007-08-29 | 2009-03-12 | Nok Corp | Method for manufacturing steel component integral with rubber part |
TWI457433B (en) * | 2008-01-30 | 2014-10-21 | Chemetall Gmbh | Process for coating metallic surfaces with a phosphate layer and then with a polymer lubricant layer |
DE102009002716A1 (en) | 2009-04-29 | 2010-11-11 | Federal-Mogul Nürnberg GmbH | Wear-resistant bonded coating for the coating of engine pistons |
DE102009002715B4 (en) | 2009-04-29 | 2017-02-09 | Federal-Mogul Nürnberg GmbH | Use of a waterborne lubricating varnish for the coating of engine pistons |
DE102012215666A1 (en) * | 2012-09-04 | 2014-03-06 | Schaeffler Technologies AG & Co. KG | Functional part, preferably bearing part, sealing or O-ring, useful in bearing of engine compartment of internal combustion engine, comprises base body with partially provided friction-reducing coating comprising lubricating paint |
DE102014001248A1 (en) * | 2014-02-03 | 2015-08-06 | Gkn Sinter Metals Engineering Gmbh | Connecting rod and piston assembly with a connecting rod with ball head |
DE102014217040A1 (en) * | 2014-08-27 | 2016-03-03 | Bayerische Motoren Werke Aktiengesellschaft | Coating for metal components, method for coating a metal component, pistons for internal combustion engines and motor vehicles |
RU156583U1 (en) * | 2015-05-08 | 2015-11-10 | Федеральное государственное унитарное предприятие "Центральный институт авиационного моторостроения им. П.И. Баранова" | PISTON OF THE INTERNAL COMBUSTION ENGINE CYLINDER |
-
2017
- 2017-05-05 DE DE102017207591.0A patent/DE102017207591A1/en not_active Ceased
-
2018
- 2018-05-04 PL PL18722516T patent/PL3619416T3/en unknown
- 2018-05-04 US US16/611,030 patent/US20200102656A1/en not_active Abandoned
- 2018-05-04 WO PCT/EP2018/061497 patent/WO2018202849A1/en active Application Filing
- 2018-05-04 CN CN201880029961.1A patent/CN110892142B/en active Active
- 2018-05-04 EP EP18722516.4A patent/EP3619416B1/en active Active
- 2018-05-04 RU RU2019139407A patent/RU2769041C2/en active
- 2018-05-04 BR BR112019023182A patent/BR112019023182A2/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
RU2019139407A (en) | 2021-06-07 |
CN110892142B (en) | 2022-12-06 |
US20200102656A1 (en) | 2020-04-02 |
BR112019023182A2 (en) | 2020-05-19 |
RU2019139407A3 (en) | 2021-10-06 |
EP3619416B1 (en) | 2021-10-13 |
RU2769041C2 (en) | 2022-03-28 |
DE102017207591A1 (en) | 2018-11-08 |
CN110892142A (en) | 2020-03-17 |
WO2018202849A1 (en) | 2018-11-08 |
PL3619416T3 (en) | 2022-03-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AT394681B (en) | LAYERING MATERIAL FOR SLIDING ELEMENTS AND METHOD FOR THE PRODUCTION THEREOF | |
DE102017218844A1 (en) | Coating process for a bearing ring | |
DE102012202787A1 (en) | Method for painting a workpiece | |
EP3019644A1 (en) | Method for producing a corrosion-resistant and wear-capable aluminum substrate | |
EP3109340A2 (en) | Method of fabrication of a connecting element and connection element | |
EP2311928A3 (en) | Aqueous solution containing an organic phosphoric acid ester for producing a metal sheet coated with lubricant with improved reforming characteristics | |
EP1455101A1 (en) | Screw and process for making a screw with a protective coating | |
DE3841215A1 (en) | METAL BODY WITH HEAT AND CORROSION RESISTANT SURFACE | |
DE202006008314U1 (en) | Combined fastening arrangement with coating | |
EP2742170A1 (en) | Method for increasing the resistance of a burnishing layer and component having a burnishing layer | |
EP3619416B1 (en) | Steel piston having a phosphate layer | |
EP2971718B1 (en) | Coated pistons and method for the production thereof | |
DE19929090A1 (en) | Process for coating a workpiece with a lubricant | |
EP3594969A1 (en) | Method for producing a conductor wire coated with electro-insulating enamel and electro-insulating enamel | |
DE10320875A1 (en) | Process for lubricating aluminum or aluminum alloy elements | |
EP0399425B1 (en) | Process for applying a phosphate running layer on a bearing metal layer | |
EP0761844A1 (en) | Process for chrome plating | |
DE2046449B2 (en) | Method and device for applying protective coatings to metal objects and application of the method | |
DE742791C (en) | Process for improving the non-cutting deformability of metals, in particular steel | |
DE10311142A1 (en) | Paint system for parts subject to friction, e.g. steel parts in plants for high-purity products, contains wear-resistant and friction-reducing additives concentrated towards the inside and outside respectively | |
DE2360523B2 (en) | Use of an intermediate layer that improves the adhesive substrate | |
DE2443885B2 (en) | METHOD FOR SURFACE TREATMENT OF IRON ALLOYS BY GALVANIC DEPOSITION OF A COPPER-TIN ALLOY AND SUBSEQUENT THERMAL DIFFUSION TREATMENT | |
DE202013002328U1 (en) | storage system | |
DE112014005584T5 (en) | Piston ring and heat treatment process | |
WO2017021387A1 (en) | Abrasion- and peel-resistant sol-gel coating on aluminium and method for producing a coating of this type |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: UNKNOWN |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20191125 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20210507 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 502018007438 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1438363 Country of ref document: AT Kind code of ref document: T Effective date: 20211115 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG9D |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20211013 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220113 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220213 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220214 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220113 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220114 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 502018007438 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20220714 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20220531 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20220504 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20220504 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20220531 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20220531 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20220504 Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20220531 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20220504 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20220531 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230528 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20230419 Year of fee payment: 6 Ref country code: CZ Payment date: 20230421 Year of fee payment: 6 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: PL Payment date: 20230424 Year of fee payment: 6 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211013 |