EP3592146A1 - Neue emulsionskonzentrate auf basis von agrochemischen wirkstoffen - Google Patents
Neue emulsionskonzentrate auf basis von agrochemischen wirkstoffenInfo
- Publication number
- EP3592146A1 EP3592146A1 EP18708420.7A EP18708420A EP3592146A1 EP 3592146 A1 EP3592146 A1 EP 3592146A1 EP 18708420 A EP18708420 A EP 18708420A EP 3592146 A1 EP3592146 A1 EP 3592146A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- methyl
- emulsion concentrates
- fluoxastrobin
- particularly preferably
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
Definitions
- the invention relates to the technical field of formulations of active ingredients for use in crop protection. Specifically, the invention relates to formulations for drug combinations containing fluoxastrobin and an ester amide as a solvent, a process for their preparation and their use as crop protection agents.
- Plant protection agents can in principle be formulated in various ways, wherein the properties of the active ingredients and type of formulation can pose problems with regard to manufacturability, stability, applicability and effectiveness of the formulations. This applies in particular to drug combinations which are composed of different active ingredient groups. In addition, certain types of formulation are more advantageous than others for economic and environmental reasons, and therefore preferable.
- prothioconazole and fluoxastrobin as a tank mix
- Addition of the individual formulations of prothioconazole and fluoxastrobin into the spray tank and mixing of these with simultaneous or subsequent dilution with water to the application concentration before administration is known and is successfully used for testing in the field.
- EC formulation emulsifiable concentrate
- NMP N-methyl-pyrrolidone
- DMSO dimethyl sulfoxide
- ⁇ -butyrolactone a non-water-soluble active ingredient
- WO-A 2005/002334 already describes emulsion concentrates based on prothioconazole and fluoxastrobin.
- the emulsion concentrates disclosed therein tend to produce undesirable precipitate formation due to the formation of an insoluble complex of ⁇ -butyrolactone with fluoxastrobin (1: 1).
- This solvate of ⁇ -butyrolactone and fluoxastrobin precipitates as a solid aggregate in the emulsion concentrate.
- This water-insoluble complex prevents application of the plant protection product according to the practice known in the art. Accordingly, in the preparation of the spray mixture, the emulsion concentrate is transferred to the spray mixture, wherein the solvate described above is present as an aggregate in the spray mixture.
- the present invention relates to emulsion concentrates containing fluoxastrobin and one or more agrochemical active compounds, characterized in that they contain, as solvents, compounds of the formula (I)
- emulsion concentrates according to the invention which contain at least one emulsifier from the group of ethylenediamine alkoxylate derivatives.
- the emulsion concentrates according to the invention contain the following components:
- the emulsion concentrates according to the invention preferably contain at least 80 g / L, more preferably 100 g / L, of component (a).
- An emulsion concentrate is usually understood to mean a composition which, when mixed with water, forms an oil-in-water emulsion.
- the emulsion is usually formed spontaneously.
- the concentrate is preferably present as a homogeneous solution. Usually, it is virtually free of dispersed particles.
- Fluoxastrobin (a) is a known fungicidal compound.
- the chemical name is (1 ⁇ ) - [2 - [[6- (2-chlorophenoxy) -5-fluoro-4-pyrimidinyl] oxy] phenyl] (5,6-dihydro-l, 4,2-dioxazine-3 yl) -methanone-0-methyloxime (CAS number 361377-29-9) (reference: DE-A-196 02 095) and the formula (I)
- the proportion of component (a) in the emulsion concentrates according to the invention is 3 to 20% by weight, preferably 4 to 15% by weight, particularly preferably 8 to 12% by weight.
- Component (b) is an agrochemical agent, for example
- Preferred fungicidal agents (b) are (1,021) tebuconazoles, (1,003) epoxiconazoles, (1,013) metconazoles, (1,022) tetraconazoles, (1,002) difenoconazoles, (1,017) propiconazoles, (1,001) cyproconazoles, (1,018) prothioconazoles, (2,001) Benzovindiflupyr, (2.002) bixafen, (2.003) boscalid, (2.005) fluopyram, (2.007) fluxapyroxad, (2.010) isopyrazam (anti-epimeric enantiomer 1R, 4S, 9S), (2.011) isopyrazam (anti-epimeric enantiomer 1S, 4R, 9R), (2.012) isopyrazam (anti-epimeric racemate 1RS, 4SR, 9SR), (2.013) isopyrazam (mixture of the syn-e
- the proportion of component (b) in the emulsion concentrates according to the invention is 3 to 25% by weight, preferably 4 to 20% by weight, particularly preferably 7 to 15% by weight.
- Suitable nonionic emulsifiers (c) are customary surfactants present in formulations of agrochemical active compounds.
- Exemplified compounds (c) are ethoxylated nonylphenols, polyethylene glycol ethers of linear alcohols, end-capped and non-end-capped alkoxylated linear and branched, saturated and unsaturated alcohols, reaction products of alkylphenols with ethylene oxide and / or propylene oxide, ethylene oxide-propylene oxide block copolymers, polyethylene glycols and polypropylene glycols, further fatty acid esters, fatty acid polyglycol ether esters, alkyl sulfonates, alkyl sulfates, aryl sulfates, ethoxylated arylalkylphenols such as tristyrylphenol ethoxylate having an average of 16 ethylene oxide units per molecule, ethoxylated and propoxylated arylalkylphenols, and
- tristrylphenol alkoxylates and fatty acid polyglycol ether esters are particularly preferred.
- tristyrylphenol ethoxylates are particularly preferred.
- tristyrylphenolethoxypropoxylates are particularly preferred.
- castor oil polyglycol ether esters in each case individually or in mixtures.
- additives such as surfactants or esters of fatty acids, which contribute to the improvement of biological effectiveness.
- Suitable nonionic emulsifiers are CL9 for example Soprophor ® 796 / P,
- Suitable nonionic emulsifiers are CL9 for example Soprophor ® 796 / P,
- Suitable nonionic emulsifiers are CL9 for example Soprophor ® 796 / P,
- Suitable nonionic emulsifiers are CL9 for example Soprophor ® 796 / P,
- the proportion of component (c) in the emulsion concentrates according to the invention may be from 2 to 45% by weight, preferably from 3 to 40% by weight, particularly preferably from 4 to 25% by weight.
- component (c) may be composed of various surfactants of said class.
- component (c1) and component (c2) are used.
- Component (c1) is nonionic surfactants from the group of tristyrylphenol ethoxypropoxylates, in each case individually or in mixtures.
- Tristyryl-phenol-ethoxy propoxylates are preferred, very particularly preferably tristyryl-phenol-ethoxy propoxylates having 16 to 30 EO and 2 to 8 PO.
- the proportion of component (c1) in the emulsion concentrates according to the invention can be 3 to 25% by weight, preferably 4 to 20% by weight, particularly preferably 5 to 15% by weight.
- a particularly preferred nonionic surfactant of the component (cl) is Soprophor ® 796 / P (CAS number 70880-56-7). - -
- Component (c2) is nonionic surfactants from the group of tristyryl phenol ethoxylates and castor oil polyglycol ether esters, in each case individually or in mixtures.
- Tristyrylphenol ethoxylates very particularly preferably tristyrylphenol ethoxylates with 10 to 30 EO, are preferred.
- the proportion of component (c2) in the emulsion concentrates according to the invention can be from 2 to 20% by weight, preferably from 3 to 15% by weight, particularly preferably from 4 to 11% by weight.
- a particularly preferred nonionic surfactant of the component (c2) is the tristyryl-phenol ethoxylates Fabrication ® PS16 (CAS number 104376-75-2).
- a penetration promoter (d) are suitable, for example
- the use of propoxy-ethoxylated alcohols as a penetration promoter is particularly preferred.
- alkanol alkoxylates as Zika ® 5902 (CAS 64366-70-7) is.
- the proportion of component (d) in the emulsion concentrates according to the invention can be from 2 to 25% by weight, preferably from 5 to 20% by weight, particularly preferably from 8 to 16% by weight.
- Suitable ethylenediamine alkoxylate derivative emulsifiers (e) are for example ethylene oxide / propylene oxide copolymers based on ethylene diamine such as Synperonic ® T / 304 Croda (CAS 26316-40-5).
- component (e) preference is given to using ethylene oxide / propylene oxide copolymers based on ethylenediamine with CAS no. 26316-40-5 used.
- the proportion of component (e) in the emulsion concentrates according to the invention may be from 2 to 20% by weight, preferably from 3 to 15% by weight, particularly preferably from 4 to 12% by weight.
- the component (f) methyl-5- (dimethylamino) -2-methyl-5-oxopentanoate (CAS number 1174627-68- 9) is sold under the trade names Rhodiasolv ® Polar Clean Solvay. Alternatively, this solvent is sold under the trade name ProMoClean ® TP 183 by the company Inventec.
- the proportion of component (f) in the emulsion concentrates according to the invention may be 5 to 70% by weight, preferably 10 to 60% by weight, particularly preferably 20 to 5% by weight.
- the emulsion concentrates according to the invention contain
- the emulsion concentrates according to the invention may contain further additives (g).
- Suitable additives (g) which may optionally be present in the formulations according to the invention are defoamers (gl), preservatives (g2), antioxidants (g3) and dyes (g4).
- defoamers all substances are suitable which can usually be used in agrochemicals for this purpose. Preference is given to silicone oils, silicone oil preparations, magnesium stearate, phosphinic and phosphonic acids.
- silicone oils silicone oils preparations, magnesium stearate, phosphinic and phosphonic acids.
- Examples are Silcolapse® ® 482 from Bluestar Silicones, Silfoam ® SCI 132 from Wacker [dimethyl siloxanes and -silicones, CAS-No. 63148-62-9], SAG 1538 or SAG 1572 from Momentive [dimethylsiloxanes and silicones, CAS no. 63148-62-9] or Fluowet ® PL 80th
- Possible preservatives (g2) are all substances that can usually be used in agrochemicals for this purpose. Suitable preservatives are, for example, preparations with 5-chloro-2-methyl-4-isothiazolin-3-one [CIT; CAS-No. 26172-55-4], 2-methyl-4-isothiazolin-3-one [MIT, CAS-No. 2682-20-4] or 1,2-benzisothiazol-3 (2H) -one [BIT, CAS-No. 2634- 33-5].
- Antioxidants are all substances which can usually be used in agrochemicals for this purpose. Preference is given to butylhydroxytoluene [3,5-di-tert-butyl-4-hydroxytoluene, CAS no. 128-37-0] and citric acid.
- Possible dyes (g4) are all substances that can usually be used in agrochemicals for this purpose. Examples include titanium dioxide, carbon black, zinc oxide, blue pigments, red pigments and Permanent Red FGR.
- the preparation of the formulations according to the invention is carried out e.g. in such a way that the components (a) to (g) are mixed together in the respectively desired ratios.
- the agrochemical active ingredient is a solid, it is generally employed in either crystalline or amorphous form or in the form of a solution in an organic solvent. It is also possible to use a solid agrochemical active ingredient in the form of a melt.
- the present invention also relates to a process for the preparation of the liquid formulations according to the invention by mixing the components (a), (b), (c) and (d), (e), (f) and (g) and optionally further additives.
- the temperatures can be varied within a certain range when carrying out the process. It is generally carried out at temperatures between 0 ° C and 80 ° C, preferably between 10 ° C and 60 ° C. _ _
- the preparation of an EC is generally carried out in such a way that the active substance or active ingredients are or will first be dissolved in the solvent. The other components are then stirred into the resulting solution.
- customary devices are considered which are used for the production of agrochemical formulations. Even deviating procedures are possible.
- the respective surface and / or object-related application rate of the pesticides of the most varied types of formulation for controlling said harmful organisms varies greatly.
- the application media known to those skilled in the art as customary for the respective field of application are used in the customary amounts for this purpose; for example, from several hundred liters of water per hectare in standard spraying over a few liters of oil per hectare in the 'Ultra Low Volume' aircraft application to a few milliliters of a physiological solutions in injection procedures.
- concentrations of the crop protection agents according to the invention in the corresponding application media therefore vary within a wide range and are dependent on the respective field of use.
- concentrations are used which are known to the person skilled in the art as customary for the respective field of use. Preference is given to concentrations of from 0.01% by weight to 99% by weight, preferably from 0.1% by weight to 90% by weight, particularly preferably from 0.2% by weight to 50% by weight.
- the agrochemical formulations of the invention may be e.g. in the preparation forms customary for liquid preparations, either as such or after prior dilution with water, ie here in particular as emulsions or solutions.
- the application is carried out by conventional methods, e.g. by spraying, pouring or injecting.
- the formulations according to the invention are useful for combating a large number of pests and can be used both for the treatment of plant cultures, but also of inanimate matter and in the household.
- Pests or “harmful organisms” are understood here as all types of pests that are controlled by organic crop protection active ingredients, ie crop protection agents, in particular fungicides and mixtures of fungicides with other crop protection agents _ _
- Control can be kept.
- pest therefore includes plant-damaging organisms, in particular harmful fungi and their spores, but also harmful insects, arachnids, nematodes and harmful plants.
- control includes both the curative treatment, i. the treatment of infested plants with a formulation according to the invention, as well as the protective treatment, i. the treatment of plants for protection against pest infestation.
- the present invention thus also relates to the use of formulations described herein for controlling pests, especially plant pests; and a method for controlling harmful organisms, in particular plant-damaging organisms, comprising contacting the harmful organisms, their habitat, their hosts, such as plants and seeds, and the soil, area and environment in which they may grow or grow , but also of materials, plants, seeds, soil, surfaces or spaces to be protected from attack or infestation by plant-damaging organisms, with an effective amount of the formulations according to the invention.
- Another aspect of the invention relates to the use of the formulations described herein for the protection of plants including seeds, in particular to protect crops from attack by harmful organisms, in particular harmful fungi.
- the present invention thus also relates to the use of the formulations for controlling plant-damaging organisms such as, for example, harmful fungi, insects, arachnids, nematodes and harmful plants, in particular for controlling harmful fungi.
- the formulations of the invention can be used in plant protection especially as foliar, pickling and soil fungicides in a conventional manner for controlling phytopathogenic fungi.
- plants which can be treated with the formulations according to the invention the following may be mentioned: cotton, flax, grapevine, fruits, vegetables, such as Rosaceae sp. (for example, pome fruits such as apple and pear, but also drupes such as apricots, cherries, almonds and peaches and soft fruits such as strawberries), Ribesioidae sp., Juglandaceae sp., Betulaceae sp., Anacardiaceae sp., Fagaceae sp., Moraceae sp., Oleaceae sp., Actinidaceae sp., Lauraceae sp., Musaceae sp.
- Rosaceae sp. for example, pome fruits such as apple and pear, but also drupes such as apricots, cherries, almonds and peaches and soft fruits such as strawberries
- Rosaceae sp. for example, pome fruits such as apple and
- Rubiaceae sp. for example, coffee
- Theaceae sp. Sterculiceae sp.
- Rutaceae sp. for example, lemons, organs and grapefruit
- Solanaceae sp. for example tomatoes
- Liliaceae sp. Asteraceae sp.
- Umbelliferae sp. for example, Cruciferae sp., Chenopodiaceae sp., Cucurbitaceae sp. (for example cucumber), Alliaceae sp. leek, onion), Papilionaceae sp.
- Main crops such as Gramineae sp. (for example corn, turf, cereals such as wheat, rye, rice, barley, oats, millet and triticale), Asteraceae sp. (for example sunflower), Brassicaceae sp. white cabbage, red cabbage, broccoli, cauliflower, Brussels sprouts, pak choi, kohlrabi, - -
- Fabacae sp. for example, bean, peanuts
- Papilionaceae sp. for example, soybean
- Solanaceae sp. for example potatoes
- Chenopodiaceae sp. for example, sugar beet, fodder beet, Swiss chard, beet
- Sugarcane poppy, olive, coconut, cocoa, tobacco and useful plants and ornament
- the formulations according to the invention are preferably used for the treatment of wheat, barley, rye, soya, onions, corn and peanuts.
- Alternaria species on vegetables, oilseed rape, sugarbeet, soya, cereals, cotton, fruits and rice eg A. solani or A. alternata on potato and other plants
- Aphanomyces species on sugar beet and vegetables eg. Ascochyta sp. on cotton and rice, Bipalaris and Drechslera species on maize, cereals, rice and turf (eg teres on barley, D. tritci-repentis on wheat), Blumeria graminis (powdery mildew) on cereals
- Botrytis cinerea (gray horse) on strawberries, Vegetables, flowers and vines, Botryodiplodia sp.
- Mycosphaerella species on cereals, bananas and peanuts M. graminicola on wheat, M. fijiesis on banana
- Phaeoisaripsis sp. on soybeans Phakopsara sp. (eg P. pachyrhizi and P. meibomiae on soybeans)
- Phoma sp. on soya Phomopsis species on soybeans, sunflowers and vines (P. viticola on vines, P. helianthii on sunflowers), Phytophthora infestans on potatoes and tomatoes, Plasmopara viticola on vines, Penecilium sp.
- Pyricularia grisea on lawn and cereals Pythium spp. on lawn, rice, corn, cotton, oilseed rape, sunflowers, sugar beets, vegetables and other plants
- Rhizoctonia species eg R. solani
- Rynchosporium sp. eg R. secalis
- Sclerotinia species eg S. sclerotiorum
- Septoria tritici and Stagonospora nodorum on wheat Erysiphe (syn.
- the formulations according to the invention can be administered undiluted or diluted with water. In general, they are at least one part of water, preferably with 10 parts of water and more preferably with at least 500 parts of water, for example with 1 to 10,000, preferably 10 to 5,000 and most preferably with 50 to 400 parts of water with respect to a part of the formulation diluted.
- an emulsion obtainable by mixing water with the liquid formulation according to the invention.
- the mixing ratio of water to emulsion concentrate may be in the range of 1000 to 1 to 1 to 1, preferably 400 to 1 to 10 to 1.
- the dilution is achieved by pouring the emulsion concentrates according to the invention to the water.
- agitation such as stirring, used.
- agitation is usually not necessary.
- the temperature for the dilution process is an uncritical factor, dilutions are usually carried out at temperatures in the range of 0 ° C to 50 ° C, especially at 10 ° C to 30 ° C or at ambient temperature.
- the water used for dilution is usually tap water or well water. However, the water may already include water-soluble or finely-dispersed compounds used in crop protection, such as nutrients, fertilizers or pesticides.
- oils wetting agents, adjuvants, fertilizers or micronutrients as well as other pesticides (for example herbicides, insecticides, fungicides, growth regulators, safeners) can be added to the emulsion according to the invention as a premix or optionally just before use (tank mix).
- pesticides for example herbicides, insecticides, fungicides, growth regulators, safeners
- These agents can be added to the formulations according to the invention in a weight ratio of 1: 100 to 100: 1, preferably 1:10 to 10: 1.
- the user typically applies the formulation of the invention from a pre-metering device, a backpack syringe, a spray tank, a spray plane or a _ _
- the formulation according to the invention with water, buffer and / or other excipients is diluted to the desired application concentration, thereby obtaining the ready-to-use spray liquid or agrochemical composition of the invention.
- per hectare of agricultural land in the case of spray application 20 to 2000 liters, preferably 50 to 400 liters, the ready-spray mixture applied.
- the required application rates of the pure active ingredients without formulation auxiliaries depend on the intensity of the pest infestation, on the development phase of the plants, on the climatic conditions of the place of use and the method of application.
- the application rate is in the range from 0.001 to 3 kg, preferably from 0.005 to 2 kg, more preferably from 0.01 to 1 kg and most preferably from 25 to 500 g of active ingredient per hectare, wherein active ingredient here Fluoxastrobin plus other possible active ingredients means.
- the generally diluted formulations of the invention are applied primarily by spraying, especially spraying the leaves.
- the application can be carried out by spraying techniques known to the person skilled in the art, for example using water as carrier and spray liquor quantities of about 50 to 1000 liters per hectare, for example from 100 to 300 liters per hectare.
- the EC formulations according to the invention have advantageous properties for the treatment of plants, in particular they are distinguished by good application properties, high stability and high fungicidal activity. With regard to the good application properties, particular mention should be made of the formation of a stable emulsion in the spray mixture in the exclusive use of water-soluble solvents and the avoidance of any known solvation with the active ingredients of the formulations according to the invention.
- Examples 1 to 8 the individual components of the mixture are weighed and combined (see Table 3 and Table 4). Complete dissolution of the components in the mixture is assisted by stirring the combined components. The preparation of the mixture is complete as soon as all the components are dissolved. The production takes place under typical environmental conditions. The order of addition of the individual components is not critical to the preparation of the inventive samples.
- Prothioconazole 178928-70-6 9.1 9.0 9.1 9.1 9.1
- Example 1 to 6 A mixture consisting of components according to Table 3 Example 1 to 6 was mixed and thus produced an EC formulation according to the invention. Subsequently, the test methods "cold stability” and “flow test” were carried out.
- the formulation of the invention is stored at low temperatures for two time periods and then visually observed and described (see Table 5).
- the "no crystals" rating indicates that no solid structures have formed in the solution, so there is no solvate in the mix and the mix can be used as a crop protection product in accordance with professional practice.
- a spray mixture (dilution in water at application concentration) is prepared and required for a defined period of time through a sieve. This process is repeated several times. To readjust the different conditions of use, the test is carried out at different water temperatures (see Table 6 for results). A good result is achieved with several hours of flow without blocking the screen. Thus, there is no solvate in the spray mixture.
- the mixture can be used in accordance with professional practice as a plant protection product.
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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EP17159292.6A EP3372079A1 (de) | 2017-03-06 | 2017-03-06 | Neue emulsionskonzentrate auf basis von agrochemischen wirkstoffen |
PCT/EP2018/055306 WO2018162389A1 (de) | 2017-03-06 | 2018-03-05 | Neue emulsionskonzentrate auf basis von agrochemischen wirkstoffen |
Publications (1)
Publication Number | Publication Date |
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EP3592146A1 true EP3592146A1 (de) | 2020-01-15 |
Family
ID=58231494
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
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EP17159292.6A Ceased EP3372079A1 (de) | 2017-03-06 | 2017-03-06 | Neue emulsionskonzentrate auf basis von agrochemischen wirkstoffen |
EP18708420.7A Pending EP3592146A1 (de) | 2017-03-06 | 2018-03-05 | Neue emulsionskonzentrate auf basis von agrochemischen wirkstoffen |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
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EP17159292.6A Ceased EP3372079A1 (de) | 2017-03-06 | 2017-03-06 | Neue emulsionskonzentrate auf basis von agrochemischen wirkstoffen |
Country Status (4)
Country | Link |
---|---|
EP (2) | EP3372079A1 (de) |
EA (1) | EA201992015A1 (de) |
UA (1) | UA127644C2 (de) |
WO (1) | WO2018162389A1 (de) |
Families Citing this family (1)
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CN114641507A (zh) * | 2019-11-06 | 2022-06-17 | 罗地亚经营管理公司 | 用于自由基聚合的立即终止的组合物及其用途 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19602095A1 (de) | 1996-01-22 | 1997-07-24 | Bayer Ag | Halogenpyrimidine |
DE10329714A1 (de) | 2003-07-02 | 2005-01-20 | Bayer Cropscience Ag | Agrochemischen Formulierungen |
AU2012322977B2 (en) * | 2011-10-13 | 2016-04-21 | Specialty Operations France | Composition, method for producing the composition, and phytosanitary formulation containing same |
FR2993752B1 (fr) * | 2012-07-26 | 2014-08-29 | Rhodia Operations | Compositions phytosanitaires comprenant un compose ether-amide |
AR103332A1 (es) * | 2014-12-31 | 2017-05-03 | Valent Usa Corp | Formulaciones líquidas de diglicolamina dicamba y lactofen |
JP2016145177A (ja) * | 2015-02-09 | 2016-08-12 | 株式会社クレハ | 農園芸用乳剤およびその調製方法 |
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2017
- 2017-03-06 EP EP17159292.6A patent/EP3372079A1/de not_active Ceased
-
2018
- 2018-03-05 WO PCT/EP2018/055306 patent/WO2018162389A1/de unknown
- 2018-03-05 EA EA201992015A patent/EA201992015A1/ru unknown
- 2018-03-05 EP EP18708420.7A patent/EP3592146A1/de active Pending
- 2018-03-05 UA UAA201910206A patent/UA127644C2/uk unknown
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UA127644C2 (uk) | 2023-11-15 |
EP3372079A1 (de) | 2018-09-12 |
WO2018162389A1 (de) | 2018-09-13 |
EA201992015A1 (ru) | 2020-03-04 |
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