EP3465030A1 - Dispositif cryogenique a echangeur compact - Google Patents
Dispositif cryogenique a echangeur compactInfo
- Publication number
- EP3465030A1 EP3465030A1 EP17735183.0A EP17735183A EP3465030A1 EP 3465030 A1 EP3465030 A1 EP 3465030A1 EP 17735183 A EP17735183 A EP 17735183A EP 3465030 A1 EP3465030 A1 EP 3465030A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- pellets
- capillary
- cold
- generating device
- mandrel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000008188 pellet Substances 0.000 claims abstract description 33
- 239000012530 fluid Substances 0.000 claims abstract description 32
- 239000000463 material Substances 0.000 claims abstract description 7
- 239000011148 porous material Substances 0.000 claims abstract description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 10
- 229910052709 silver Inorganic materials 0.000 claims description 9
- 239000004332 silver Substances 0.000 claims description 9
- 125000006850 spacer group Chemical group 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 239000003365 glass fiber Substances 0.000 claims description 6
- 229910000570 Cupronickel Inorganic materials 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 2
- 238000004804 winding Methods 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims 1
- 238000009413 insulation Methods 0.000 claims 1
- 238000010586 diagram Methods 0.000 description 3
- 238000005457 optimization Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 229920004933 Terylene® Polymers 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 239000002470 thermal conductor Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B41/00—Fluid-circulation arrangements
- F25B41/30—Expansion means; Dispositions thereof
- F25B41/37—Capillary tubes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
- F25B9/02—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point using Joule-Thompson effect; using vortex effect
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/02—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being helically coiled
- F28D7/024—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being helically coiled the conduits of only one medium being helically coiled tubes, the coils having a cylindrical configuration
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/04—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being spirally coiled
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F13/00—Arrangements for modifying heat-transfer, e.g. increasing, decreasing
- F28F13/003—Arrangements for modifying heat-transfer, e.g. increasing, decreasing by using permeable mass, perforated or porous materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2309/00—Gas cycle refrigeration machines
- F25B2309/02—Gas cycle refrigeration machines using the Joule-Thompson effect
- F25B2309/022—Gas cycle refrigeration machines using the Joule-Thompson effect characterised by the expansion element
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2341/00—Details of ejectors not being used as compression device; Details of flow restrictors or expansion valves
- F25B2341/06—Details of flow restrictors or expansion valves
- F25B2341/062—Capillary expansion valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2400/00—General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
- F25B2400/05—Compression system with heat exchange between particular parts of the system
- F25B2400/052—Compression system with heat exchange between particular parts of the system between the capillary tube and another part of the refrigeration cycle
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S165/00—Heat exchange
Definitions
- the invention lies in the general field of cold machines, and more particularly in cold generating devices intended to allow the operation of certain types of detectors, and more particularly infra-red detectors of the type cooled, also called quantum infra-red detectors. It is more particularly devices of the type in question implementing as a source of cold, the principle of relaxation called "Joule-Thomson".
- the devices of the prior art implement a Hampson-type countercurrent exchanger, in which the high-pressure fluid circulates in a capillary surrounding a cylindrical sleeve or mandrel, closed off by an insulating foam.
- the heat exchange occurs at the periphery of the sleeve, at which the low-pressure fluid flows counter-currently.
- the invention is aimed at a device of the type in question which makes it possible at the same time to increase the efficiency of such a device, in particular by reducing the TMF, that is to say the cooling time of the installation. without altering the size of the existing devices or conversely, at constant TMF, to reduce the size of such devices.
- the invention proposes a cold generating device implementing the "Joule-Thomson" expansion principle, comprising an exchanger in which a fluid under high pressure and under low pressure flows in countercurrent.
- the heat exchanger consists of the stack of pellets made of porous material, and in particular sintered, constituting a cylindrical mandrel, in contact with which is wound a capillary in which the high pressure fluid circulates, the low fluid pressure circulating against the current inside the porous mandrel thus formed.
- a porous thermal insulating fabric typically made of glass fibers.
- the invention basically consists in replacing the mandrel and fins of the prior art with a stack of sintered and porous material, favoring the heat exchange of the low-pressure fluid with the high-pressure fluid circulating in the capillary. peripheral in contact with said material.
- This optimization of the exchange results from the nature of the material constituting the mandrel, and also makes it possible to dispense with the fins optimizing the heat exchange of the prior art, and consequently, makes it possible to optimize the concentration of turns of the capillary in which circulates the high pressure fluid, and consequently allows to optimize the compactness of the cold generating device.
- thermally insulating grids typically made of glass fiber
- axial conduction is reduced and corollary optimizes the operation of the cold generator device .
- the pellets are made from sintered silver or sintered copper.
- the capillary is meanwhile made of metal typically copper, stainless steel or even cupronickel alloy.
- the turns of the capillary are not in contact with each other.
- a thermally insulating wire typically made of glass fiber and acting as a spacer, is coiled with the said capillary.
- Such a wire provides different functions:
- Figure 1 is a diagram illustrating the principle of relaxation "Joule-Thomson" implemented at the level of the cold generator device.
- Figure 2 is a schematic representation of the device of the invention.
- Figure 3 is a view similar to Figure 2 illustrating the respective circuit of the high pressure fluid and low pressure;
- FIG. 4 is a schematic representation of a cryostat
- FIG. 5 is a schematic representation in partial sagittal section of one of the portions of the cryostat of FIG. 4.
- FIG. 1 therefore shows the operating diagram of a device implementing the "Joule-Thomson" trigger.
- This diagram shows the source of high pressure fluid HP, this fluid can be a typically argon gas, nitrogen or air, and the return of said fluid after expansion.
- the double coil (1) shows the countercurrent heat exchanger between the high pressure fluid emanating from the high pressure source HP and the low pressure fluid after expansion at the evaporator (2).
- an expansion valve (3) being mounted before the evaporator.
- the assembly is integrated within a vacuum chamber (4).
- FIG. 2 shows the heart of the exchanger according to the invention.
- This is constituted by the stack of pellets (5), made of porous material, and in particular sintered silver base.
- Silver is indeed a very good thermal conductor and is also easy to sinter.
- copper instead of silver.
- the porosity of these pellets is close to 100 nanometers.
- the orifices generated by the sintering of the pellets have a typical diameter of 100 nanometers.
- pellets (5) are for example assembled to each other by means of fixing rods (6) emanating from the high-pressure connector (7) and provided with nuts (8) at their lower base. .
- the pellets can be glued together.
- these pellets (5) are separated from each other by a spacer or grid (9), made of a non-conductive porous material, typically consisting of a fiberglass woven fabric.
- spacers have a typical thickness of 0.3 millimeters. The implementation of such spacers tends to oppose any axial thermal conduction, optimizing the heat exchange surface between the two streams, respectively low pressure and high pressure.
- the assembly thus constituted by the pellets and the spacers constitutes a cylindrical mandrel, in contact with which is wound a capillary (10), in which flows the high pressure fluid.
- This capillary is for example made of copper, stainless steel or a cupro-nickel alloy. It typically has an outer diameter of 0.5 millimeters and an inner diameter of 0.3 millimeters.
- the low pressure fluid passes through them and cools them.
- the pellets cool the high pressure fluid that circulates in the capillary. In fact, a good thermal contact is necessary between the capillary and the pellets.
- the pellets (5) are produced using a mold shaped according to the desired shape of said pellets.
- the silver powder is poured into the mold, and the temperature of the mold is raised to a temperature below the melting temperature of the silver, in order to obtain a simple sintering without causing the melting of the powder.
- the thermal insulating elements (9) After completion of the pellets, their stacking is carried out by intercalating the thermal insulating elements (9), the latter having an external diameter less than or equal to that of the pellets (5), so that they can not come into contact with the capillary (10).
- pellets and the spacers are threaded onto the holding rods (6), for example threaded, and locked by means of the nuts (8).
- a mandrel is therefore de facto constituted.
- the capillary for example made of cupro-nickel alloy undergoes treatment consisting of a silver deposit, for example by electrolysis, if the pellets are made of silver sintered. This deposit is intended to promote subsequent contact with the pellets (5), especially when proceeding to the fixing of said capillary by welding or solder.
- the assembly is placed in an oven to generate the soldering phenomenon.
- thermal conductive binder for example consisting of a type of "solgel” type of glue film loaded with metal powder, whitewashed in the capillary / pellet area.
- the device of the invention is intended to be integrated in a cylindrical well of a cryostat, as shown in FIG. 4.
- a cryostat As shown in FIG. 4.
- Such a cryostat (11) is traditionally maintained under empty. It receives within the enclosure that defines an infrared detector (12), positioned vertically above a window (13) transparent to the radiation to be detected.
- an infrared detector (12) positioned vertically above a window (13) transparent to the radiation to be detected.
- it comprises two wells (14), within which are inserted in each of them a device according to the invention, in order to generate the cold necessary for the operation of said detector.
- FIG. 5 shows a schematic view in partial sagittal section of one of the wells (14) provided with the device of the invention.
- the wire (15) is thus wound along the mandrel and then fixed at its two ends, typically by gluing.
- this wire avoids any thermal bridge between the turns on the one hand, and between the turns and the well (14).
- the consecutive turns of the capillary (10) are therefore thermally isolated from each other.
- the turns of the capillary (10) are thermally isolated from the well (14).
- the presence of the wire (15) provides a seal of the device relative to said well, forcing the low pressure fluid to pass through the pellets (5), and therefore contributing to optimize the efficiency of the device of the invention.
- the operating temperature of the latter is typically between 77K and 250K.
- the pressure of the high pressure fluid is typically between a few tens to a few hundred bars.
- the device according to the invention makes it possible to considerably increase the heat exchange area in comparison with the devices of the prior art, of the type comprising a finned capillary, typically 1000 times with constant bulk. It is therefore readily apparent that the efficiency of such a cold machine is itself increased, or that the size of such a cold machine can be significantly reduced, while maintaining the same performance as the devices of the invention. prior art. These results are particularly significant in the context of cooled infrared detectors.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SI201730180T SI3465030T1 (sl) | 2016-06-06 | 2017-06-02 | Kriogena naprava s kompaktnim izmenjevalcem |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1655128A FR3052245B1 (fr) | 2016-06-06 | 2016-06-06 | Dispositif cryogenique a echangeur compact |
PCT/FR2017/051390 WO2017212148A1 (fr) | 2016-06-06 | 2017-06-02 | Dispositif cryogenique a echangeur compact |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3465030A1 true EP3465030A1 (fr) | 2019-04-10 |
EP3465030B1 EP3465030B1 (fr) | 2020-01-29 |
Family
ID=57233543
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17735183.0A Active EP3465030B1 (fr) | 2016-06-06 | 2017-06-02 | Dispositif cryogenique a echangeur compact |
Country Status (8)
Country | Link |
---|---|
US (1) | US20190120529A1 (fr) |
EP (1) | EP3465030B1 (fr) |
KR (1) | KR102260700B1 (fr) |
CN (1) | CN109073293B (fr) |
FR (1) | FR3052245B1 (fr) |
IL (1) | IL262395B (fr) |
SI (1) | SI3465030T1 (fr) |
WO (1) | WO2017212148A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111912132A (zh) * | 2020-06-05 | 2020-11-10 | 中国空间技术研究院 | 焦耳-汤姆逊制冷器件及其制备方法 |
CN114087810B (zh) * | 2021-11-16 | 2022-08-05 | 西安交通大学 | 一种节流制冷器 |
CN114754507A (zh) * | 2022-03-11 | 2022-07-15 | 上海铂钺制冷科技有限公司 | 极低温区制冷机用复合型低温负压间壁式换热器 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB945223A (en) * | 1961-09-22 | 1963-12-23 | Atomic Energy Authority Uk | Improvements in or relating to refrigerators |
FR2477406A1 (fr) * | 1980-03-06 | 1981-09-11 | Commissariat Energie Atomique | Cryosonde chirurgicale |
SU903667A1 (ru) * | 1980-05-12 | 1982-02-07 | Предприятие П/Я М-5727 | Микрохолодильник |
JPH0684852B2 (ja) * | 1986-01-20 | 1994-10-26 | 株式会社東芝 | 極低温冷凍機 |
US4781033A (en) * | 1987-07-16 | 1988-11-01 | Apd Cryogenics | Heat exchanger for a fast cooldown cryostat |
JP3674791B2 (ja) * | 1994-07-14 | 2005-07-20 | アイシン精機株式会社 | 冷却装置 |
US20010030040A1 (en) * | 1999-12-23 | 2001-10-18 | Jia Hua Xiao | Miniature cryogenic heat exchanger |
WO2003081145A1 (fr) * | 2002-03-22 | 2003-10-02 | Sumitomo Heavy Industries, Ltd. | Dispositif de stockage a temperature cryogenique et refrigerateur |
US7160291B2 (en) * | 2003-06-25 | 2007-01-09 | Endocare, Inc. | Detachable cryosurgical probe |
JP2005342280A (ja) * | 2004-06-04 | 2005-12-15 | Mie Kagaku Kogyo Kk | 保温袋体 |
JP2013504029A (ja) * | 2009-09-02 | 2013-02-04 | インヴェンサー ゲーエムベーハー | 収着機内の熱交換器のための冷媒の表面供給及び分配 |
CN103423911B (zh) * | 2012-06-25 | 2015-10-28 | 上海理工大学 | 制冷器 |
CN103615823B (zh) * | 2013-12-09 | 2015-11-25 | 武汉高芯科技有限公司 | 一种可快速制冷的斯特林-节流复合型制冷机 |
US20170146268A1 (en) * | 2015-11-24 | 2017-05-25 | General Electric Company | Water Chiller Apparatus |
-
2016
- 2016-06-06 FR FR1655128A patent/FR3052245B1/fr active Active
-
2017
- 2017-06-02 US US16/094,328 patent/US20190120529A1/en not_active Abandoned
- 2017-06-02 EP EP17735183.0A patent/EP3465030B1/fr active Active
- 2017-06-02 SI SI201730180T patent/SI3465030T1/sl unknown
- 2017-06-02 WO PCT/FR2017/051390 patent/WO2017212148A1/fr unknown
- 2017-06-02 KR KR1020187030498A patent/KR102260700B1/ko active IP Right Grant
- 2017-06-02 CN CN201780025154.8A patent/CN109073293B/zh active Active
-
2018
- 2018-10-15 IL IL262395A patent/IL262395B/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
EP3465030B1 (fr) | 2020-01-29 |
SI3465030T1 (sl) | 2020-03-31 |
FR3052245B1 (fr) | 2019-06-14 |
KR102260700B1 (ko) | 2021-06-03 |
IL262395A (en) | 2018-12-31 |
IL262395B (en) | 2020-10-29 |
FR3052245A1 (fr) | 2017-12-08 |
KR20190015202A (ko) | 2019-02-13 |
WO2017212148A1 (fr) | 2017-12-14 |
US20190120529A1 (en) | 2019-04-25 |
CN109073293A (zh) | 2018-12-21 |
CN109073293B (zh) | 2020-07-03 |
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