EP3208653B1 - Brillenglas und brille - Google Patents
Brillenglas und brille Download PDFInfo
- Publication number
- EP3208653B1 EP3208653B1 EP15850996.8A EP15850996A EP3208653B1 EP 3208653 B1 EP3208653 B1 EP 3208653B1 EP 15850996 A EP15850996 A EP 15850996A EP 3208653 B1 EP3208653 B1 EP 3208653B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- lens
- layer
- spectacle lens
- eyeball
- eye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000000463 material Substances 0.000 claims description 53
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 29
- 238000007740 vapor deposition Methods 0.000 claims description 21
- 229910010272 inorganic material Inorganic materials 0.000 claims description 4
- 239000011147 inorganic material Substances 0.000 claims description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 3
- 210000005252 bulbus oculi Anatomy 0.000 description 31
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 20
- 230000004313 glare Effects 0.000 description 17
- 210000001508 eye Anatomy 0.000 description 15
- 229910052681 coesite Inorganic materials 0.000 description 13
- 229910052906 cristobalite Inorganic materials 0.000 description 13
- 239000000377 silicon dioxide Substances 0.000 description 13
- 229910052682 stishovite Inorganic materials 0.000 description 13
- 229910052905 tridymite Inorganic materials 0.000 description 13
- 238000011156 evaluation Methods 0.000 description 12
- 238000000034 method Methods 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 238000005259 measurement Methods 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 238000000869 ion-assisted deposition Methods 0.000 description 4
- -1 isocyanate compound Chemical class 0.000 description 4
- 239000004973 liquid crystal related substance Substances 0.000 description 4
- 241000511976 Hoya Species 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000010030 laminating Methods 0.000 description 3
- 230000000116 mitigating effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- JHQVCQDWGSXTFE-UHFFFAOYSA-N 2-(2-prop-2-enoxycarbonyloxyethoxy)ethyl prop-2-enyl carbonate Chemical compound C=CCOC(=O)OCCOCCOC(=O)OCC=C JHQVCQDWGSXTFE-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010884 ion-beam technique Methods 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Chemical compound O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 description 2
- 238000013041 optical simulation Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 206010015958 Eye pain Diseases 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 208000003464 asthenopia Diseases 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical compound C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 1
- 150000002440 hydroxy compounds Chemical class 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 229910003471 inorganic composite material Inorganic materials 0.000 description 1
- 238000007733 ion plating Methods 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/10—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/10—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
- G02C7/104—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses having spectral characteristics for purposes other than sun-protection
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/10—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
- G02C7/107—Interference colour filters
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/28—Interference filters
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C2202/00—Generic optical aspects applicable to one or more of the subgroups of G02C7/00
- G02C2202/16—Laminated or compound lenses
Definitions
- the present invention relates to a spectacle lens and spectacles equipped with the spectacle lens.
- blue light is light having the wavelength of 430 to 450 nm in the following description.
- JP 2012-093689 A or its English family member US 2013/222913 A1 proposes an optical product including a multilayer film having a characteristic of reflecting light having the wavelength of 400 to 450 nm including the wavelength range of blue light.
- Comparable spectacle lenses are described in EP 1 174 734 , EP 2 775 341 and WO 29014/050930 .
- blue light reflective characteristic As measures against blue light, by imparting a characteristic of reflecting blue light (hereinafter, also referred to as a "blue light reflective characteristic") to a spectacle lens surface, the amount of blue light entering the eyes of a wearer is reduced through the spectacle lens, and which can mitigate the burden of blue light on the eyes.
- the spectacle lens is required to be usable by a wearer of spectacles with a good wearing feeling.
- the inventors have found, from their studies, that the spectacle lens to which the blue light reflective characteristic is imparted does not always have a good wearing feeling and further improvement is desired.
- a purpose of the present invention is to provide a spectacle lens capable of mitigating the burden of blue light on the eyes and having a good wearing feeling.
- JP 2012-093689 A discloses that a multilayer film is provided to impart a blue light reflective characteristic to each surface of a spectacle lens. It is effective to provide the multilayer film to impart the blue light reflective characteristic to each surface of the spectacle lens in mitigating the burden of the blue light on the eyes.
- light entering the eyes of a wearer of spectacles is not limited to the incident light from the object-side surface, and the light diagonally entering the eyeball-side surface of the lens from the rear side also enters the eyes of the wearer as reflection light from the eyeball-side surface.
- the reflection light from the eyeball-side surface includes, in addition to the light reflected on the eyeball-side surface, the light incident from the eyeball side, reflected on the object-side surface, and emitted from the lens as return light.
- the inventors concluded that, with the spectacle lens in which a higher blue light reflective characteristic is imparted to the object-side surface than the eyeball-side surface, glare was caused because the blue light reflected on the different surfaces entered the eyes, and which contributed to deterioration of the wearing feeling.
- a spectacle lens including a lens base material and a multilayer film provided on each surface of an eyeball-side surface and an object-side surface of the lens base material, in which a normal incidence mean reflectance R eye in a wavelength range of 430 to 450 nm measured on the eyeball-side surface of the spectacle lens and a normal incidence mean reflectance R object in a wavelength range of 430 to 450 nm measured on the object-side surface of the spectacle lens each are more than 0%, and R eye is greater than R object
- R eye is greater than R object
- the present invention relates to spectacles including the spectacle lens and a frame equipped with the spectacle lens.
- the present invention it is possible to provide a spectacle lens which mitigates the burden of blue light on the eyes and has a good wearing feeling, and spectacles equipped with the spectacle lens.
- a spectacle lens according to the present invention is a spectacle lens including a lens base material, and a multilayer film provided on each surface of an eyeball-side surface and an object-side surface of the lens base material, in which a normal incidence mean reflectance R eye in a wavelength range of 430 to 450 nm measured on the eyeball-side surface of the spectacle lens and a normal incidence mean reflectance R object in a wavelength range of 430 to 450 nm measured on the object-side surface of the spectacle lens each are in the range of 2.00-9.00 %, and (R object + 7.00) % ⁇ R eye ⁇ (R object + 0.90) %.
- the spectacle lens is described below in more detail.
- the normal incidence mean reflectance R eye in the wavelength range of 430 to 450 nm measured on the eyeball-side surface and the normal incidence mean reflectance R object in the wavelength range of 430 to 450 nm measured on the object-side surface each are more than 2% .
- the eyeball-side surface and the object-side surface of the spectacle lens each have a characteristic of reflecting incident light having the wavelength range of 430 to 450 nm (a blue light reflective characteristic) .
- R eye and R object each are equal to or more than 2.00%, and further preferably equal to or more than 3.00%.
- the normal incidence mean reflectance means the arithmetic mean value of the normal incidence reflectance in the wavelength range of 430 to 450 nm measured for each arbitrary wavelength (with an arbitrary pitch) at the optical center of a surface to be measured.
- the measurement wavelength interval (pitch) can be arbitrarily set in the range of, for example, 1 nm to 10 nm.
- the normal incidence mean reflectance R eye in the wavelength range of 430 to 450 nm on the eyeball-side surface is greater than the normal incidence mean reflectance R object in the wavelength range of 430 to 450 nm on the object-side surface.
- R eye is equal to or more than (R object + 0.90) %, that is, the difference between R eye and R object (R eye - R object ) is equal to or more than 0.90% , more preferably equal to or more than 1.00%, further preferably equal to or more than 2.00%, and still further preferably equal to or more than 3.00%. Furthermore, the difference is less than or equal to 7.00% For example, the difference may be less than or equal to 18.00%, less than or equal to 12.00%, or the like.
- the ratio of R eye to R object is preferably more than 1.00 and less than or equal to 6.50, more preferably more than 1.00 and less than or equal to 5.00, and further preferably equal to or more than 1.20 and less than or equal to 5.00.
- the multilayer film provided on each surface of the eyeball-side surface and the object-side surface of the lens base material can impart the blue light reflective characteristic to the spectacle lens.
- the eyeball-side surface is a surface disposed at the eyeball side when a wearer wears spectacles equipped with the spectacle lens of the present invention
- the object-side surface is a surface disposed at the object side.
- the multilayer film is provided on the surface of the lens base material directly or indirectly through one or more other layers .
- the lens base material is not specifically limited, and can be styrene resin including (meth) acrylic resin, polycarbonate resin, allyl resin, allyl carbonate resin such as diethyleneglycol bis (allylcarbonate) resin (CR-39), vinyl resin, polyester resin, polyether resin, urethane resin obtained through reaction between an isocyanate compound and a hydroxy compound such as diethylene glycol, thiourethane resin obtained through reaction between an isocyanate compound and a polythiol compound, transparent resin obtained by curing a polymerizable composition containing a (thio) epoxy compound having one or more intermolecular disulfide bonds, or the like.
- inorganic glass may be used.
- the lens base material may not be dyed (hereinafter, referred to as a clear lens) or may be dyed (a dyed lens) .
- the refractive index of the lens base material is, for example, approximately 1.60 to 1.75.
- the refractive index of the lens base material is not limited to the above, and may be within the above range, or over or under the above range.
- the refractive index is the refractive index ne to the e-line (wavelength 546.07 nm).
- the spectacle lens may be various lenses, such as a monofocal lens, a multifocal lens, or a progressive power lens .
- a type of the lens is determined based on the shapes of both surfaces of the lens base material.
- the lens base material surface may be a convex surface, a concave surface, or a flat surface.
- the object-side surface is a convex surface
- the eyeball-side surface is a concave surface.
- the present invention is not limited to the above.
- the multilayer film for imparting the blue light reflective characteristic may be provided on the lens base material surface directly or indirectly through one or more other layers.
- a layer which can be formed between the lens base material and the multilayer film is, for example, a hard coat layer.
- a hard coat layer By providing a hard coat layer, it is possible to impart flaw resistance (abrasion resistance) to the spectacle lens and to improve durability (strength) of the spectacle lens.
- flaw resistance abrasion resistance
- strength durability
- a primer layer may be formed between the lens base material and the coat to enhance adhesion.
- the paragraphs 0029 to 0030 of JP 2012-128135 A can be referred to.
- the multilayer film provided on each surface of the eyeball-side surface and the object-side surface of the lens base material is not specifically limited as long as the one which can impart a characteristic of reflecting incident light having the wavelength range of 430 to 450 nm (the blue light reflective characteristic) to the spectacle lens surface having the multilayer film.
- Such a multilayer film can be preferably formed by sequentially laminating a high refractive index layer and a low refractive index layer. More specifically, the multilayer film can be formed by determining the film thickness of each layer through optical simulation by a known method based on a refractive index of a film material for forming the high refractive index layer and the low refractive index layer and the wavelength of light to be reflected, i.e.
- the film forming material may be an inorganic material, an organic material, or an organic-inorganic composite material, and is preferably an inorganic material from the perspective of film formation and ease of availability.
- R eye measured on the eyeball-side surface and R object measured on the object-side surface each can be controlled to a desired value by adjusting the type, the film thickness, the laminating order, or the like of the film forming material.
- a high refractive material for forming the high refractive index layer can be oxide selected from the group consisting of ZrO 2 , Ta 2 O 5 , TiO 2 , Al 2 O 3 , Y 2 O 2 , HfO 2 , and Nb 2 O 5 .
- a low refractive index material for forming the low refractive index layer can be SiO 2 or MgF 2 . Note that, oxide and fluoride are expressed here in a stoichiometric composition for convenience, but oxide or fluoride in which oxygen or fluorine is deficient or excessive as compared to the stoichiometric composition may also be used as a high refractive index material or a low refractive index material.
- a layer configuration of the multilayer film can be, for example, a configuration in which, a first layer (low refractive index layer), a second layer (high refractive index layer), a third layer (low refractive index layer), a fourth layer (high refractive index layer), a fifth layer (low refractive index layer), a sixth layer (high refractive index layer), and a seventh layer (low refractive index layer) are laminated in this order from the lens base material to the outermost side of the lens, a configuration in which a first layer (high refractive index layer), a second layer (low refractive index layer), a third layer (high refractive index layer), a fourth layer (low refractive index layer), a fifth layer (high refractive index layer), and a sixth layer (low refractive index layer) are laminated in this order from the lens base material to the outermost side of the lens, or the like.
- a preferable combination of a low refractive index layer and a high refractive index layer can be, for example, a combination of a coat including silicon oxide as the principal component and a coat including zirconium oxide as the principal component, and a preferable multilayer film can be, for example, a multilayer film including at least one laminated structure in which the coats of these two layers are adjacent.
- each layer is a coat including the high refractive index material or the low refractive index material as the principal component.
- the principal component is a component which accounts for the largest part of the coat and usually accounts for approximately 50 to 100 mass%, or even 90 to 100 mass%.
- Such a coat can be formed by the film formation using the film forming material including the above material (for example, a vapor deposition source) as the principal component.
- the principal component of the film forming material is the same as the above.
- the coat and the film forming material can include a minute amount of impurities which are inevitably mixed, and may include another component such as another inorganic substance or a known additive component which supports the film formation as long as the component does not degrade the function of the principal component.
- the film formation can be performed by a known film formation method, and preferably by vapor deposition from the perspective of ease of the film formation.
- the vapor deposition in the present invention includes a dry method such as a vacuum vapor deposition method, an ion plating method, or a sputtering method.
- a dry method such as a vacuum vapor deposition method, an ion plating method, or a sputtering method.
- an ion beam assist method in which an ion beam is applied concurrently to vapor deposition may be used.
- the multilayer film may also include, in addition to the above high refractive index layer and low refractive index layer, a coat including conductive oxide as the principal component, preferably one or more conductive oxide layers formed by vapor deposition using a vapor deposition source including conductive oxide as the principal component in an arbitrary position in the multilayer film.
- a coat including conductive oxide as the principal component preferably one or more conductive oxide layers formed by vapor deposition using a vapor deposition source including conductive oxide as the principal component in an arbitrary position in the multilayer film.
- conductive oxide especially preferable from the perspective of transparency and conductivity can be tin oxide or indium-tin oxide (ITO).
- a functional film may be further formed on the multilayer film.
- the functional film can be various functional films of a water repellent or hydrophilic antifouling film, an anti-fogging film, a polarizing film, a dimming film, or the like. Any known techniques can be applied to the functional films without any restriction.
- the above described spectacle lens of the present invention can effectively suppress the entering of the blue light which burdens the eyes to the eyes, and provide a good wearing feeling. Furthermore, according to the present invention, it is possible to provide spectacles including such a spectacle lens and a frame equipped with the spectacle lens. Any known techniques can be applied to a structure of the spectacles without any restriction.
- a multilayer vapor deposition film having eight layers in total was sequentially formed by ion assisted deposition using oxygen gas and nitrogen gas as assist gas.
- the multilayer vapor deposition film was formed such that, on each side of the convex surface side and the concave surface side, the first layer, the second layer ... were laminated in this order from the lens base material side (hard coat side) to the spectacle lens surface and the outermost layer on the spectacle lens surface side was to be the eighth layer using the vapor deposition sources shown in Table 1.
- the normal incidence mean reflectances R eye and R object were controlled by changing the film thickness of one or more layers constituting the multilayer vapor deposition film using the vapor deposition sources consisting of oxide shown in Table 1 except for impurities which can be inevitably mixed.
- Vapor deposition source First layer SiO 2 Second layer ZrO 2 Third layer SiO 2 Fourth layer ZrO 2 Fifth layer SiO 2 Sixth layer ZrO 2 Seventh layer ITO Eighth layer SiO 2
- a multilayer vapor deposition film having eight layers in total was sequentially formed by ion assisted deposition using oxygen gas and nitrogen gas as assist gas.
- the multilayer vapor deposition film was formed such that, on each side of the convex surface side and the concave surface side, the first layer, the second layer ... were laminated in this order from the lens base material side (hard coat side) to the spectacle lens surface and the outermost layer on the spectacle lens surface side was to be the eighth layer using the vapor deposition sources shown in Table 2 and with the film thickness (physical film thickness) shown in Table 2.
- the vapor deposition sources consisting of oxide shown in Table 2 except for impurities which can be inevitably mixed were used.
- the lens base materials shown in Table 2 have the dioptric powers shown in Table 2: the material having the refractive index 1.60 is product name EYAS manufactured by HOYA Corporation, the material having the refractive index 1.50 is product name HILUX (refractive index 1.50) manufactured by HOYA Corporation, and the material having the refractive index 1.74 is EYVIA manufactured by HOYA Corporation, and a hard coat having the refractive index shown in Table 2 is provided on each surface of the materials.
- the material having the refractive index 1.60 is product name EYAS manufactured by HOYA Corporation
- the material having the refractive index 1.50 is product name HILUX (refractive index 1.50) manufactured by HOYA Corporation
- the material having the refractive index 1.74 is EYVIA manufactured by HOYA Corporation
- a hard coat having the refractive index shown in Table 2 is provided on each surface of the materials.
- a normal incidence reflection spectral characteristic in the wavelength range of 380 to 780 nm was measured (measurement pitch: 1 nm) using a micro spectrophotometer USPM manufactured by Olympus corporation. From the measurement results, R eye , R object and the dominant wavelength were acquired.
- the dominant wavelength means a reflection maximum wavelength in a spectral reflection spectrum showing a normal incidence reflection spectral characteristic in the wavelength range of 380 to 780 nm.
- the spectacle lens in an aspect of the present invention preferably has the dominant wavelength in the wavelength range of 400 to 500 nm from the perspective of the blue light reflective characteristic.
- the manufactured spectacle lens was observed from the eyeball side under normal brightness in a room, and the strength of the light reflected by the inside of the object-side surface (glare) was organoleptically evaluated by the eyes of an observer based on the following evaluation criteria.
- the results are shown in Table 2. As shown in Table 2, it has been confirmed that the spectacle lens in Examples suppressed the occurrence of glare compared to the spectacle lens in Comparative Example.
- the glare evaluated in the above evaluation 2. can be caused by blue light entering the object-side surface of the spectacle lens.
- a part of the blue light entering the object-side surface of the spectacle lens is reflected by the object-side surface, but a part of the blue light passes through the object-side surface and enters the spectacle lens. Due to multiple reflection of the incident blue light inside the spectacle lens, a phenomenon called ghost in which a wearer of spectacles observes a double image can be caused. In order to improve the wearing feeling of the spectacle lens, it is desirable that occurrence of ghost is suppressed.
- the manufactured spectacle lens was observed at the position of 30 cm from the eyeball side under fluorescent light in a dark room, the generation or degree of ghost (double image) was organoleptically evaluated by the eyes of an observer based on the following evaluation criteria.
- Table 2 it has been confirmed that the spectacle lens in Examples suppressed the occurrence of ghost compared to the spectacle lens in Comparative Example.
- the inventors inferred that the occurrence of ghost was suppressed by imparting a higher blue light reflective characteristic to the eyeball-side surface than the object-side surface.
- Example 1 Example 2
- Example 3 Example 4
- Example 5 Example 6
- Example 7 Example 8
- a spectacle lens including a lens base material and a multilayer film provided on each surface of an eyeball-side surface and an object-side surface of the lens base material, in which a normal incidence mean reflectance R eye in a wavelength range of 430 to 450 nm measured on the eyeball-side surface of the spectacle lens and a normal incidence mean reflectance R object in a wavelength range of 430 to 450 nm measured on the object-side surface of the spectacle lens each are in the range of 2.00-9.00 %, and (R object + 7.00) % ⁇ R eye ⁇ (R object + 0.90) %.
- spectacles including the spectacle lens and a frame equipped with the spectacle lens.
- the spectacle lens is a spectacle lens in which a higher blue light reflective characteristic is imparted to the eyeball-side surface than the object-side surface in the above manner, and can mitigate the burden of blue light on eyes and provide a wearing feeling to a wearer wearing spectacles equipped with the spectacle lens.
- R eye and R object each are in a range of 2.00 to 21.00%, and R eye is greater than R object .
- R eye and R object each are in a range of 2.00 to 10.00%, and R eye is greater than R object .
- the difference between R eye and R object is equal to or more than 0.90%.
- the ratio of R eye to R object is in a range of more than 1.00 and less than or equal to 6.50.
- the multilayer film is a multilayer film in which a plurality of coats including an inorganic material as a principal component is laminated.
- the multilayer film includes at least one laminated structure in which a coat including silicon oxide as a principal component and a coat including zirconium oxide as a principal component are adjacent.
- the multilayer film includes at least one layer of a coat including conductive oxide as a principal component.
- the present invention is useful in the field of manufacturing spectacle lenses and spectacles.
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- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Ophthalmology & Optometry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- General Health & Medical Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Eyeglasses (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Optical Filters (AREA)
Claims (8)
- Linse, die ein Brillenglas ist, umfassend:(i) ein Linsenbasismaterial; und(ii) einen mehrschichtigen Film, der auf jeder Oberfläche der augapfelseitigen Oberfläche und der objektseitigen Oberfläche des Linsenbasismaterials vorgesehen ist,worin
der mittlere Reflexionsgrad R bei normalem Einfall im Wellenlängenbereich von 430-450 nm, gemessen auf der augapfelseitigen Oberfläche des Brillenglases (RAuge) und gemessen auf der objektseitigen Oberfläche des Brillenglases (RObjekt), jeweils in einem Bereich von 2,00-9,00% liegt, und - Linse gemäß Anspruch 1, worin 1,00 < RAuge/Robjekt ≤ 6,50.
- Linse gemäß Anspruch 1 oder 2, worin in dem mehrschichtigen Film mehrere Beschichtungen, einschließlich eines anorganischen Materials als ein Hauptbestandteil, laminiert sind.
- Linse gemäß einem der Ansprüche 1-3, worin der mehrschichtige Film mindestens eine laminierte Struktur enthält, in welcher eine Beschichtung, die Siliziumoxid als Hauptkomponente enthält, und eine Beschichtung, die Zirconiumoxid als Hauptkomponente enthält, aneinandergrenzen.
- Linse gemäß Anspruch 3 oder 4, worin der mehrschichtige Film mindestens eine Schicht aus einer Beschichtung enthält, die ein leitfähiges Oxid als Hauptkomponente enthält.
- Linse gemäß einem der Ansprüche 3-5, worin die Beschichtung ein dampfbeschichteter Film ist.
- Linse gemäß einem der Ansprüche 1-6, die auf dem Linsenbasismaterial über mindestens eine Hartschicht, mindestens entweder den mehrschichtigen Film auf der augapfelseitigen Oberfläche oder den mehrschichtigen Film auf der objektseitigen Oberfläche des Linsenbasismaterials enthält.
- Brille, umfassend eine Linse gemäß einem der Ansprüche 1-7 und einen Rahmen, in den die Linse eingesetzt ist.
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JP2014212988 | 2014-10-17 | ||
PCT/JP2015/079354 WO2016060257A1 (ja) | 2014-10-17 | 2015-10-16 | 眼鏡レンズおよび眼鏡 |
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EP3208653A1 EP3208653A1 (de) | 2017-08-23 |
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EP3208653B1 true EP3208653B1 (de) | 2022-06-08 |
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JP (1) | JP6415587B2 (de) |
KR (1) | KR101941798B1 (de) |
CN (1) | CN107077010B (de) |
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CN103984120B (zh) * | 2014-05-30 | 2015-06-10 | 奥特路(漳州)光学科技有限公司 | 一种防蓝光光学镜片的制造方法 |
KR102349699B1 (ko) | 2017-05-31 | 2022-01-10 | 엘지디스플레이 주식회사 | 터치 스크린 일체형 표시장치와 그의 제조방법 |
JP6473281B1 (ja) * | 2017-09-29 | 2019-02-20 | ホヤ レンズ タイランド リミテッドHOYA Lens Thailand Ltd | 眼鏡レンズおよび眼鏡 |
JP6873880B2 (ja) | 2017-09-29 | 2021-05-19 | ホヤ レンズ タイランド リミテッドHOYA Lens Thailand Ltd | 眼鏡レンズおよび眼鏡 |
CA3038083C (en) * | 2017-09-29 | 2020-10-13 | Hoya Lens Thailand Ltd. | Spectacle lens and spectacles |
JP6473282B1 (ja) * | 2017-09-29 | 2019-02-20 | ホヤ レンズ タイランド リミテッドHOYA Lens Thailand Ltd | 眼鏡レンズおよび眼鏡 |
AU2018334589B2 (en) * | 2017-09-29 | 2020-03-26 | Hoya Lens Thailand Ltd. | Spectacle lens and spectacles |
EP3528037A1 (de) * | 2018-02-15 | 2019-08-21 | Essilor International | Getöntes brillenglas |
KR102627742B1 (ko) | 2022-09-23 | 2024-01-23 | 주식회사 진양정밀 | 엔코더링 착자기의 요크 냉각장치 |
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JP2012093689A (ja) * | 2010-09-29 | 2012-05-17 | Nikon-Essilor Co Ltd | 光学部品およびその製造方法 |
EP2775341A4 (de) | 2011-10-31 | 2015-10-14 | Hoya Corp | Linse für eine brille |
JP5969195B2 (ja) * | 2011-10-31 | 2016-08-17 | Hoya株式会社 | 眼鏡レンズの製造方法 |
JP5625127B2 (ja) * | 2012-02-17 | 2014-11-12 | 株式会社ニコン・エシロール | 眼鏡レンズ用光学部品、およびその製造方法 |
EP2916148A4 (de) * | 2012-11-05 | 2016-10-05 | Nikon Essilor Co Ltd | Optische komponente, verfahren zur herstellung der optischen komponente und verfahren zur quantifizierten bestimmung von irrlichtern |
US8911082B2 (en) * | 2013-03-14 | 2014-12-16 | Indizen Optical Technologies, SLL. | Eyewear lenses with controlled filters for night driving |
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EP3208653A1 (de) | 2017-08-23 |
KR20170067889A (ko) | 2017-06-16 |
CA2964444A1 (en) | 2016-04-21 |
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JPWO2016060257A1 (ja) | 2017-08-03 |
AU2015331263B2 (en) | 2018-09-13 |
EP3208653A4 (de) | 2018-05-30 |
JP6415587B2 (ja) | 2018-10-31 |
US20170242273A1 (en) | 2017-08-24 |
CA2964444C (en) | 2020-04-14 |
CN107077010A (zh) | 2017-08-18 |
CN107077010B (zh) | 2020-09-01 |
KR101941798B1 (ko) | 2019-01-23 |
WO2016060257A1 (ja) | 2016-04-21 |
US11402666B2 (en) | 2022-08-02 |
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