Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/88—Ampholytes; Electroneutral compounds
  • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/37—Mixtures of compounds all of which are anionic
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/0005—Other compounding ingredients characterised by their effect
  • C11D3/0089—Pearlescent compositions; Opacifying agents
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/20—Organic compounds containing oxygen
  • C11D3/2093—Esters; Carbonates
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
  • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
  • C11D1/29—Sulfates of polyoxyalkylene ethers
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/88—Ampholytes; Electroneutral compounds
  • C11D1/90—Betaines

Definitions

• the present invention relates to a liquid cleaning composition
• a liquid cleaning composition comprising a special mixture of an anionic detergent and a mono(Cio-C24)alkylester of a (C2-C3)alkylenediol.
• the present invention also describes a method of using such a liquid composition to clean hard surfaces or soft surfaces.
• cleaning compositions There are now a number of constraints on the formulation of cleaning compositions. These include the intended use, which influences product form, and legal restrictions and also the processing route taken. Further considerations relate to the main use of the cleaning composition, i.e. if the composition will be used in hand-washing, in twin-tub or in automatic (front loading) washing machines or in a dish wash process of automatic dish washing (ADW) or hand dish washing (HDW).
• ADW automatic dish washing
• HDW hand dish washing
• a favourable cleaning agent should have benefits in the cleaning power, outer appearance and costs. Furthermore, a cleaning agent must be stable during storage.
• pearly luster of a liquid detergent composition can be achieved by using inorganic pigments like mica.
• Said inorganic pigments are costly and difficult to disperse in liquid cleaning compositions.
• polymeric thickening agents have to be added to the liquid detergent compositions in order to prevent sedimentation of said inorganic pigments.
• Said compositions have a (preferably golden) luster and a superior cleaning power on hard surfaces or soft surfaces.
• R means a linear or branched, substituted or unsubstituted (C8-C20)-alkyl group, an aryl group or an (C8-C2o)-alkylaryl group, preferably a linear, unsubstituted (Cs-C2o)-alkyl group
• A means ethane-1 ,2-diyl- or propane-1 ,2-diyl, preferably ethane-1 -2-diyl,
• n means an integer from 1 to 50, preferably from 1 to 20, especially from 2 to 10, most preferably for 2, 3, 4, 5, 6, 7 or 8,
• X + means a monovalent cation or an equivalent of a polyvalent cation, at least one compound of formula (III)
• R 2 means a linear or branched (Cg-C23)-alkyl group, preferably a linear (Cg-Ci9)-alkyl group
• G means ethane-1 ,2-diyl, propane-1 ,2-diyl or propane-1 ,3-diyl, preferably ethane-1 ,2-diyl, water.
• R denotes preferably a group selected from decyl-, undecyl-, dodecyl-, tridecyl-, tetradecyl, pentadecyl-, hexadecyl-, heptadecyl-, octadecyl-, nonadecyl-, eicosyl group or mixtures thereof, whereas the before mentioned groups having an even number of carbon atoms are particularly preferred.
• Most preferred residues R are derived from Ci2-Ci8-fatty alcohols. Examples are Coco fatty alcohol, tallow fatty alcohol, lauryl-, myristyl-, cetyl- oder stearyl alcohol or from C10-C20- Oxoalcohols.
• X + of formula (I) is preferably selected from alkali metal ions, especially Na + or K + , whereas Na + is most preferred.
• Other cations X + may be selected from NHV, 1 ⁇ 2 Zn 2+ ,1 ⁇ 2 Mg 2+ ,1 ⁇ 2 Ca 2+ ,1 ⁇ 2 Mn 2+ , or mixtures thereof.
• Preferred liquid compositions of this invention comprise an anionic surfactant of formula I, selected from at least one anionic surfactant of formula (1-1 )
• k means an integer of 1 1 to 19, preferably 2, 3, 4, 5, 6, 7 or 8.
• Particularly preferred liquid compositions comprise an anionic surfactant of formula (I) chosen from sodium-Ci2-i4 fatty alcohol ether sulfate with two units of ethylene oxide (according to formula (1-1 ) k means an integer of 1 1 to 13 and n is 2).
• liquid compositions according to this invention comprise said portion of anionic surfactant of formula (I) in an amount of 0,05 to 7,0 wt.%, preferably of 2,0 to 5,0 wt.%. All amounts given in percent by weight (wt.%) are based on the total weight of the respective composition unless otherwise noted.
• the liquid composition comprises additionally at least one alkylbenzene sulfonate as an anionic surfactant.
• the alkylbenzene sulphonate is preferably a linear alkylbenzene sulphonate having an alkyl chain length of Cs-C-is .
• the linear alkylbenzene sulphonate is a C9-C13 alkyl benzene sulphonate, a C10-C13 alkyl benzene sulphonate or a C10-C15 alkyl benzene sulphonate.
• the amount of linear alkylbenzene sulphonate is preferably from 0 to 20 % by weight of said washing liquid composition, more preferably from 15 to 20 % by weight of said composition.
• the alkylbenzene sulphonate can be present in the form of the sodium, potassium, or ammonium salts and as soluble salts of organic bases such as mono-, di-, or triethanolamine.
• the alkylbenzene sulphonate are preferably present in the form of their sodium or potassium salts; in particular in the form of the sodium salts.
• liquid composition additionally comprises at least one anionic surfactant of formula (II) wherein the combination of R ' and R " comprises 9 to 19, preferably 11 to 15 carbon atoms,
• Y + means a monovalent cation or an equivalent of a polyvalent cation.
• liquid composition comprises as the anionic surfactant of formula (II) an anionic surfactant of formula 11-1 )
• liquid composition comprises at least one anionic surfactant according to formula (II) it is preferred, if the liquid composition comprises said portion of anionic surfactant of formula (II) in an amount of 0 to 20 wt.%, preferably 15,0 to 20,0 wt.%.
• the liquid composition comprises as at least one compound of formula (III) wherein R 2 means a linear or branched (C9-C23)-alkyl group, preferably a linear (Ci i-Ci9)-alkyl group and G means ethane-1 ,2-diyl.
• the liquid compositions comprise said portion of compound of formula (III) in an amount of 0,01 to 0,5 wt.%, preferably of 0,1 to 0,4 wt.%.
• R means a linear or branched, substituted or unsubstituted (Cs-C2o)-alkyl group, an aryl group or an (Cs-C2o)-alkylaryl group, preferably a linear, unsubstituted (Cs-C2o)-alkyl group,
• A means ethane-1 ,2-diyl- or propane-1 ,2-diyl, preferably ethane-1 -2-diyl,
• n means an integer from 1 to 50, preferably from 1 to 20, especially from 2 to 10, most preferably for 2, 3, 4, 5, 6, 7 or 8,
• X + means a monovalent cation or an equivalent of a polyvalent cation
• R 2 means a linear or branched (C9-C23)-alkyl group, preferably a linear (C9-Ci9)-alkyl group
• G means ethane-1 ,2-diyl, propane-1 ,2-diyl or propane-1 ,3-diyl, preferably ethane-1 ,2-diyl, 0 to 20 wt.%, preferred 15,0 to 20,0 wt.%, of at least one anionic surfactant of formula (II)
• R ' and R " comprises 9 to 19, preferably 11 to 15 carbon atoms
• Y + means a monovalent cation or an equivalent of a polyvalent cation. water.
• k means an integer of 1 1 to 19, preferably 2, 3, 4, 5, 6, 7 or 8,
• R 2 means a linear or branched (C9-C23)-alkyl group, preferably a linear (C9-Ci9)-alkyl group
• G means ethane-1 ,2-diyl, propane-1 ,2-diyl or propane-1 ,3-diyl, preferably ethane-1 ,2-diyl, 0 to 20 wt.% preferred 15,0 to 20,0 wt.%, of at least one anionic surfactant of formula (II)
• R ' and R " comprises 9 to 19, preferably 11 to 15 carbon atoms
• Y + means a monovalent cation or an equivalent of a polyvalent cation.
• R means a linear or branched, substituted or unsubstituted (C8-C20)-alkyl group, an aryl group or an (C8-C2o)-alkylaryl group, preferably a linear, unsubstituted (Cs-C2o)-alkyl group
• A means ethane-1 ,2-diyl- or propane-1 ,2-diyl, preferably ethane-1 -2-diyl,
• n means an integer from 1 to 50, preferably from 1 to 20, especially from 2 to 10, most preferably for 2, 3, 4, 5, 6, 7 or 8
• X + means a monovalent cation or an equivalent of a polyvalent cation
• R 2 means linear (C9-Ci9)-alkyl group
• G means ethane-1 ,2-diyl
• R ' and R " comprises 9 to 19, preferably 11 to 15 carbon atoms
• Y + means a monovalent cation or an equivalent of a polyvalent cation.
• k means an integer of 1 1 to 19, preferably 2, 3, 4, 5, 6, 7 or 8,
• R 2 means linear (C9-Ci9)-alkyl group
• G means ethane-1 ,2-diyl
• Y + means a monovalent cation or an equivalent of a polyvalent cation.
• R means a linear or branched, substituted or unsubstituted (C8-C20)-alkyl group, an aryl group or an (C8-C2o)-alkylaryl group, preferably a linear, unsubstituted (Cs-C2o)-alkyl group
• A means ethane-1 ,2-diyl- or propane-1 ,2-diyl, preferably ethane-1 -2-diyl,
• n means an integer from 1 to 50, preferably from 1 to 20, especially from 2 to 10, most preferably for 2, 3, 4, 5, 6, 7 or 8,
• X + means a monovalent cation or an equivalent of a polyvalent cation
• 0,01 to 0,5 wt.% preferably of 0,1 to 0,4 wt.%, of at least one compound selected from ethylene glycol monostearate, ethylene glycol monohexadecanoate, ethylene glycol monotetradecanoate, ethylene glycol monododecanoate or mixtures thereof,
• R ' and R " comprises 9 to 19, preferably 11 to 15 carbon atoms
• Y + means a monovalent cation or an equivalent of a polyvalent cation.
• k means an integer of 1 1 to 19, preferably 2, 3, 4, 5, 6, 7 or 8,
• 0,01 to 0,5 wt.% preferably of 0,1 to 0,4 wt.%, of at least one compound selected from ethylene glycol monostearate, ethylene glycol monohexadecanoate, ethylene glycol monotetradecanoate, ethylene glycol monododecanoate or mixtures thereof, 0 to 20 wt.%, preferred 15,0 to 20,0 wt.%, of at least one anionic surfactant of formula (II)
• R ' and R " comprises 9 to 19, preferably 11 to 15 carbon atoms
• Y + means a monovalent cation or an equivalent of a polyvalent cation.
• the use of the compound of formula (III) in said liquid composition delivers a pearly luster also without use of inorganic pearlescent pigments.
• the liquid composition comprises at most 0.001 wt.% of an inorganic pearlescent agent. It is particularly preferred, if the liquid composition of the invention is free of inorganic pearlescent pigments.
• the composition additionally comprises a nonionic detergent active compound.
• a nonionic detergent active compound improves the cleaning power of the fabric washing liquid composition and helps to stably and homogenously disperse the perfume in the liquid cleaning composition.
• the nonionic active detergent species that can be used are by preference alkoxylated, advantageously ethoxylated, in particular primary alcohols having by preference 8 to 18 carbon atoms and an average of 1 to 12 mol ethylene oxide (EO) per mol of alcohol, in which the alcohol residue can be linear or preferably methyl-branched in the 2-position, or can contain mixed linear and methyl-branched residues, such as those that are usually present in oxo alcohol residues.
• the preferred ethoxylated alcohols include, for example, C12-14 alcohols with 3 EO, 4 EO, 5 EO, or 7 EO, C9-11 alcohols with 7 EO, C13-15 alcohols with 3 EO, 5 EO, 7 EO, or 8 EO, C12-18 alcohols with 3 EO, 5 EO, or 7 EO, and mixtures thereof, such as mixtures of C12-14 alcohol with 3 EO and C12-18 alcohol with 7 EO.
• the degrees of ethoxylation indicated represent statistical averages, which can correspond to an integral or a fractional number for a specific product.
• Preferred alcohol ethoxylates exhibit a restricted distribution of homologs (narrow range ethoxylates, NRE).
• Nonionic active detergent species that contain EO and PO groups together in the molecule are also usable according to the present invention.
• mixed alkoxylated nonionic active detergent species in which EO and PO units are distributed statistically rather than in block fashion. Such products are obtainable by the simultaneous action of ethylene oxide and propylene oxide on fatty alcohols.
• These nonionic active detergent species are obtainable, for example, under the commercial name Dehydol ® (from Cognis).
• nonionic active detergent species are mixtures of a (more) branched ethoxylated fatty alcohol and a non-branched ethoxylated fatty alcohol, such as mixtures of C16-18 fatty alcohol having 7 EO and 2-propylheptanol having 7 EO.
• the fabric washing liquid composition comprises a C12-18 fatty alcohol having 7 EO or a C13-15 oxo alcohol having 7 EO as nonionic surfactant.
• the composition additionally comprises an amphoteric detergent active compound, preferably a (C8-C2o)alkylamido-(C2-C3)-alkyl betaine.
• an amphoteric detergent active compound especially of a betaine improves the cleaning power of the cleaning liquid composition and enhances the foam level of the fabric washing liquid composition.
• the liquid composition may also additionally comprise an amphoteric active detergent compound at a preferred level up to 15 wt.% of the fabric washing liquid composition.
• the amphoteric active detergent compound is particularly preferably present in the fabric washing liquid composition in an amount of from 0 to 5,0 wt.%.
• the amphoteric active detergent compound is a betaine.
• a betaine is any neutral chemical compound with a positively charged cationic functional group such as a quaternary ammonium or phosphonium cation (generally: onium ions) which bears no hydrogen atom and with a negatively charged functional group such as a carboxylate group which may not be adjacent to the cationic site.
• Suitable betaines comprise compounds represented by the following formula
• R 3 is a linear or branched, substituted or unsubstituted alkyl-, aryl- or alkylarylgroup, and o is an integer of from 1 to 4, preferably 3.
• Preferred surfactants represented by formula (IV) are those wherein
• R 3 is a linear or branched, substituted or unsubstituted Cs-C-is-alkylgroup, preferably an alkylgroup which is derived from coconut oil, and
• o 3.
• a preferred betaine for use in the fabric washing liquid composition is cocamidopropyl betaine (CAPB), an organic compound derived from coconut oil and dimethylaminopropylamine.
• CAPB cocamidopropyl betaine
• the liquid composition additionally comprises at least one dye.
• Particularly preferred dyes are selected from at least one dye with at least one sulfonic acid group or their salts.
• the liquid composition of the invention comprises at least one dye selected from azo dyes with at least one sulfonic acid group or their salts. Particularly preferred the liquid composition of the invention comprises at least one dye selected from azo dyes with
• liquid composition of the invention comprises (preferably in addition to above mentioned dyes) at least one dye selected from methylene dyes having
• liquid composition of the invention comprises (preferably in addition to above stated dyes) at least one dye selected from anthrachinone dyes having
• liquid composition of the invention comprises a combination of dyes of a) at least one dye-compound selected from methylene dyes comprising
• the liquid composition also preferably contains a detergency builder mixture of citric acid and phosphonic acid.
• a detergency builder mixture of citric acid and phosphonic acid is advantageous since they are water-soluble organic detergency builders.
• the citric acid or its salt is preferably present in the fabric washing liquid composition in an amount of from 0.5 to 2 % by weight.
• Phosphonic acids and their phosphonate salts are strong chelating agents.
• Suitable phosphonates to be used herein may include alkali metal ethane 1 -hydroxy diphosphonates (HEDP), alkylene poly (alkylene phosphonate), as well as amino phosphonate compounds, including amino aminotri(methylene phosphonic acid) (ATMP), nitrilo trimethylene phosphonates (NTP), ethylene diamine tetra methylene phosphonates, and diethylene triamine penta methylene phosphonates (DTPMP).
• the phosphonate compounds may be present either in their acid form or as salts of different cations on some or all of their acid functionalities.
• Preferred phosphonates to be used herein are diethylene triamine penta methylene phosphonate (DTPMP) and ethane 1 -hydroxy diphosphonate (HEDP).
• DTPMP diethylene triamine penta methylene phosphonate
• HEDP ethane 1 -hydroxy diphosphonate
• the phosphonic acid or its salt is preferably present in the fabric washing liquid composition in an amount of from 0.3 to 0.8 % by weight.
• the liquid composition additionally comprises a perfume.
• suitable perfumes include blooming perfumes, perfume oils, and perfume raw materials comprising alcohols, ketones, aldehydes, esters, ethers, nitriles alkenes, and mixtures thereof.
• the liquid composition comprises an encapsulated perfume and a free perfume.
• the liquid composition is an aqueous fabric washing liquid composition.
• a liquid composition may contain further ingredients that further improve the applications-engineering or aesthetic properties of the liquid composition.
• the liquid composition by preference additionally contains one or more substances from the group of bleaching agents, bleach activators, bleach catalysts, enzymes, non-aqueous solvents, pH adjusting agents, thickeners, fluorescing agents, dyes, hydrotopes, silicone oils, anti-redeposition agents, anti-gray agents, shrinkage preventers, wrinkle protection agents, dye transfer inhibitors, antimicrobial active substances, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, antistatic agents, bittering agents, ironing adjuvants, proofing and impregnation agents, swelling and anti-slip agents, softening compounds and UV absorbers.
• the liquid composition is manufactured using usual and known methods and processes.
• the constituents of the liquid composition can be simply mixed in agitator vessels, the water, non-aqueous solvent, and active detergent compounds usefully being prepared first. After cooling under stirring the further constituents are then added in portions.
• composition according to the present invention can be used to clean hard surfaces or soft surfaces.
• Ceramics e.g. toilet or bath tub
• table or other furniture e.g., table or other furniture, mirrors, dishes etc
• surfaces of non-woven cloth or woven cloth or of textiles or of fibers are especially understood being so called soft surfaces.
• liquid composition of this invention in a hand dish wash process, especially to clean hard surfaces.
• Another object of this invention is a Hand-dish-wash method for cleaning hard surfaces, wherein at least on hard surface is cleaned in a liquid cleaning medium comprising a liquid composition of any of the claims 1 to 1 1 .
• Said liquid medium is prepared by using the liquid composition according to this invention. It is preferred, that the liquid medium has a temperature from 10°C to 30°C.
• Table 1 shows the composition of a liquid composition according to the present invention. Quantities are indicated in wt% of active matter.
• the composition E1 had a pearly golden luster and was stable during storage for 6 weeks at 40°C.
• the cleaning power of E1 was determined in standardized a hand dish wash process and was rated by test persons as strong.

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• Chemical & Material Sciences (AREA)
• Life Sciences & Earth Sciences (AREA)
• Engineering & Computer Science (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Wood Science & Technology (AREA)
• Organic Chemistry (AREA)
• Health & Medical Sciences (AREA)
• Emergency Medicine (AREA)
• Detergent Compositions (AREA)

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• 2015
  • 2015-09-02 WO PCT/EP2015/070068 patent/WO2016034635A1/en active Application Filing
  • 2015-09-02 EP EP15756931.0A patent/EP3189126A1/de not_active Withdrawn

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