EP3164375B1 - Pyrotechnic igniting agent - Google Patents

Pyrotechnic igniting agent Download PDF

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Publication number
EP3164375B1
EP3164375B1 EP15734332.8A EP15734332A EP3164375B1 EP 3164375 B1 EP3164375 B1 EP 3164375B1 EP 15734332 A EP15734332 A EP 15734332A EP 3164375 B1 EP3164375 B1 EP 3164375B1
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Prior art keywords
additive
pyrotechnic
igniting agent
alkali
agent according
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German (de)
French (fr)
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EP3164375A1 (en
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Ulrich Bley
Aleksej Hoschenko
Ulf Lawrentz
Peter Simon Lechner
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RWS GmbH
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RUAG Ammotec GmbH
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Priority to SI201531000T priority Critical patent/SI3164375T1/en
Priority to RS20191481A priority patent/RS60020B1/en
Priority to PL15734332T priority patent/PL3164375T3/en
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    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B43/00—Compositions characterised by explosive or thermic constituents not provided for in groups C06B25/00Ā -Ā C06B41/00
    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
    • C06C7/00—Non-electric detonators; Blasting caps; Primers

Definitions

  • the present invention is a pyrotechnic igniter.
  • Pyrotechnic igniters in the context of the invention are substances or mixtures which can develop a pyrotechnic effect.
  • the subject of the present invention is a pyrotechnic igniting agent which can be used in mechanical, electrical or opto-electric ignition systems.
  • a 5,5'-azotetrazolate explosive which comprises an iron, cobalt, nickel, copper, cadmium or guanyl urea salt of a 5,5'-azotetrazole or a mixture of at least one 5,5'-azotetrazolate and at least one bistetrazolyl triazenate or at least one further metal salt or guanyl urea salt of a 5,5'-azotetrazole.
  • the salts described therein are neutral, ie neither acidic nor basic.
  • Zinc and chromium salts of 5,5'-azotetrazole are according to the document DE 102010025104 A1 not storable.
  • tetracene-containing pyrotechnic mixtures are thermally not sufficiently stable, since tetrazene decomposes already at 120 Ā° C.
  • DE 10 2010 036 950 A1 discloses the use of basic 5,5'-azotetrazolate salts of general formula ([ML m X n ] p + ) q (C 1 N 4 R 1 - ) r , where M is an element of the third-twelfth group of the periodic table in the range of 21-80, as initial explosive.
  • the object of the present invention was to provide a further pyrotechnic igniter.
  • Another object of the present invention was to provide a pyrotechnic igniter which can be used in mechanical, electrical or opto-electric ignition systems.
  • this object is surprisingly achieved by the features of the main claim.
  • novel basic azotetrazolate compounds according to the invention have defoaming temperatures in the range from 180 Ā° C to 240 Ā° C, friction sensitivities of 0.1 N to 1.0 N and impact sensitivity of 0.1 J to 0.5 J.
  • the pyrotechnic igniter is one which contains as an additive 10 to 60 wt .-% of an oxidizing agent selected from one or more of the nitrates of the alkali and / or alkaline earth metals and / or ammonium, the perchlorates of the alkali and / or alkaline earth metals and / or the ammonium, the peroxides of the alkali and / or alkaline earth metals and / or zinc.
  • an oxidizing agent selected from one or more of the nitrates of the alkali and / or alkaline earth metals and / or ammonium, the perchlorates of the alkali and / or alkaline earth metals and / or the ammonium, the peroxides of the alkali and / or alkaline earth metals and / or zinc.
  • the pyrotechnic igniting agent contains as additive 0 to 10 wt .-% of a sensitizer, preferably tetracene.
  • the pyrotechnic igniting agent according to the invention preferably contains as an additive 0 to 20 wt .-% of a reducing agent selected from one or more of aluminum, antimony sulfide, calcium silicide, titanium, titanium hydride, boron, borohydride, zirconium, zirconium hydride, silicon, graphite, activated carbon, carbon black or Friction agent preferably glass breakage.
  • a reducing agent selected from one or more of aluminum, antimony sulfide, calcium silicide, titanium, titanium hydride, boron, borohydride, zirconium, zirconium hydride, silicon, graphite, activated carbon, carbon black or Friction agent preferably glass breakage.
  • the pyrotechnic igniting agent contains as additive 0.1 to 5 wt .-% of a binder selected from one or more of cellulose and derivatives thereof, polyvinyl butyrals, Polynitropolyphenylen, Polynitrophenylether, Plexigum, polyvinyl acetate and copolymers.
  • a binder selected from one or more of cellulose and derivatives thereof, polyvinyl butyrals, Polynitropolyphenylen, Polynitrophenylether, Plexigum, polyvinyl acetate and copolymers.
  • the pyrotechnic igniting agents according to the invention are used in mechanical, electrical or opto-electric ignition systems.
  • the substances are characterized by lead and barium freedom, a high ignition power, short reaction times and corresponding sensitivities. These features enable a reduction in the mass of explosives needed for safe ignition.
  • Table 1 shows decomposition temperatures, friction and impact sensitivities of selected examples.
  • the measurement of the friction and impact sensitivities was carried out according to methods of the Federal Institute for Materials Research (BAM) in the BAM Report 142 (1987), while the measurement of the decomposition temperatures by differential scanning calorimetry (DSC) (Mettler) at a heating rate of 10 K. per minute took place.
  • BAM Federal Institute for Materials Research
  • DSC differential scanning calorimetry
  • Table 1 lists the compositions of 5 different basic salts of 5,5'-azotetrazole. ā‡ b> Table 1 ā‡ / b> Compositions, deflagration temperatures and friction and impact sensitivities of selected basic salts of 5,5'-azotetrazole. No. Molecular formula T Verp .

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  • Organic Chemistry (AREA)
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Description

Gegenstand der vorliegenden Erfindung ist ein pyrotechnisches AnzĆ¼ndmittel.The present invention is a pyrotechnic igniter.

Pyrotechnische AnzĆ¼ndmittel im Sinne der Erfindung sind Stoffe oder Stoffgemische, die eine pyrotechnische Wirkung entfalten kƶnnen.Pyrotechnic igniters in the context of the invention are substances or mixtures which can develop a pyrotechnic effect.

Insbesondere Gegenstand der vorliegenden Erfindung ist ein pyrotechnisches AnzĆ¼ndmittel, das in mechanischen, elektrischen oder opto-elektrischen AnzĆ¼ndsystemen eingesetzt werden kann.In particular, the subject of the present invention is a pyrotechnic igniting agent which can be used in mechanical, electrical or opto-electric ignition systems.

Aus dem Dokument DE 102010025104 A1 ist ein 5,5'-Azotetrazolat-Sprengstoff bekannt, der ein Eisen-, Kobalt-, Nickel-, Kupfer-, Cadmium- oder Guanylharnstoffsalz eines 5,5'-Azotetrazols oder ein Gemisch aus mindestens einem 5,5'-Azotetrazolat und mindestens einem Bistetrazolyltriazenat oder mindestens einem weiteren Metallsalz oder Guanylharnstoffsalz eines 5,5'-Azotetrazols umfasst. Die dort beschriebenen Salze sind neutral, d.h. weder sauer noch basisch. Zink- und Chromsalze des 5,5'-Azotetrazols sind gemƤƟ dem Dokument DE 102010025104 A1 nicht lagerbestƤndig. Weiterhin besteht das Problem, dass Tetrazen enthaltende pyrotechnische Gemische thermisch nicht hinreichend stabil sind, da sich Tetrazen bereits bei 120 Ā°C zersetzt.From the document DE 102010025104 A1 a 5,5'-azotetrazolate explosive is known which comprises an iron, cobalt, nickel, copper, cadmium or guanyl urea salt of a 5,5'-azotetrazole or a mixture of at least one 5,5'-azotetrazolate and at least one bistetrazolyl triazenate or at least one further metal salt or guanyl urea salt of a 5,5'-azotetrazole. The salts described therein are neutral, ie neither acidic nor basic. Zinc and chromium salts of 5,5'-azotetrazole are according to the document DE 102010025104 A1 not storable. Furthermore, there is the problem that tetracene-containing pyrotechnic mixtures are thermally not sufficiently stable, since tetrazene decomposes already at 120 Ā° C.

DE 10 2010 036 950 A1 offenbart die Verwendung von basischen 5,5'-Azotetrazolatsalzen mit allgemeiner Summenformel ([MLmXn]p +)q(C1N4R1 -)r, wobei M ein Element der dritten-zwƶlften Gruppe des Periodensystems mit einer Ordnungszahl im Bereich von 21-80 ist, als Initialsprengstoff. DE 10 2010 036 950 A1 discloses the use of basic 5,5'-azotetrazolate salts of general formula ([ML m X n ] p + ) q (C 1 N 4 R 1 - ) r , where M is an element of the third-twelfth group of the periodic table in the range of 21-80, as initial explosive.

Aufgabe der vorliegenden Erfindung war die Bereitstellung eines weiteren pyrotechnischen AnzĆ¼ndmittels. Eine weitere Aufgabe der vorliegenden Erfindung war die Bereitstellung eines pyrotechnischen AnzĆ¼ndmittels, das in mechanischen, elektrischen oder opto-elektrischen AnzĆ¼ndsystemen eingesetzt werden kann.The object of the present invention was to provide a further pyrotechnic igniter. Another object of the present invention was to provide a pyrotechnic igniter which can be used in mechanical, electrical or opto-electric ignition systems.

ErfindungsgemƤƟ wird diese Aufgabe Ć¼berraschenderweise durch die Merkmale des Hauptanspruchs gelƶst.According to the invention, this object is surprisingly achieved by the features of the main claim.

Weitere Ausgestaltungen der Erfindung sind in den UnteransprĆ¼chen dargelegt.Further embodiments of the invention are set forth in the subclaims.

Ɯberraschenderweise wurde ein pyrotechnisches AnzĆ¼ndmittel gefunden, wobei es
Zn2+ 2(C2N10 2-)(CO3 2-), Zn2+ 3(C2N10 2-)2(CO3 2-), Zn2+ 4(C2N10 2-)2(CO3 2-)(OH-)2, Zn2+ 2(C2N10 2-)(OH-)2 oder Zn2+ 3(C2N10 2-)2(OH-)2.
enthƤlt, wobei gilt:
(C2N10 2-) Azotetrazolatdianion mit der Struktur

Figure imgb0001
wobei der Anteil der basischen Azotetrazolatkomponente 30 bis 100 Gew.-% betrƤgt und 0 bis 70 Gew.-% eines Zusatzstoffes oder Mischungen mehrerer Zusatzstoffe enthalten sind. Die erfindungsgemƤƟen neuen basischen Azotetrazolatverbindungen besitzen Verpuffungstemperaturen im Bereich von 180 Ā°C bis 240 Ā°C, Reibempfindlichkeiten von 0,1 N bis 1,0 N und Schlagempfindlichkeit von 0,1 J bis 0,5 J. Die thermische StabilitƤt der erfindungsgemƤƟen basischen Azotetrazolatverbindungen ist gegeben. Lagerungen bei 71 Ā°C zeigen nach 28 Tagen keine Zersetzung der erfindungsgemƤƟen basischen Azotetrazolatverbindung.
Vorzugsweise ist das pyrotechnische AnzĆ¼ndmittel eines, welches als Zusatzstoff 10 bis 60 Gew.-% eines Oxidationsmittels enthƤlt, ausgewƤhlt aus einem oder mehreren der Nitrate der Alkali- und/oder Erdalkalimetalle und/oder des Ammoniums, der Perchlorate der Alkali- und/oder Erdalkalimetalle und/oder des Ammoniums, der Peroxide der Alkali- und/oder Erdalkalimetalle und/oder des Zinks.Surprisingly, a pyrotechnic igniter was found, wherein
Zn 2+ 2 (C 2 N 10 2- ) (CO 3 2- ), Zn 2+ 3 (C 2 N 10 2- ) 2 (CO 3 2- ), Zn 2+ 4 (C 2 N 10 2- ) 2 (CO 3 2- ) (OH - ) 2 , Zn 2+ 2 (C 2 N 10 2- ) (OH - ) 2 or Zn 2+ 3 (C 2 N 10 2- ) 2 (OH - ) 2 ,
contains, where:
(C 2 N 10 2- ) azotetrazolate dianion having the structure
Figure imgb0001
 wherein the proportion of the basic Azotetrazolatkomponente is 30 to 100 wt .-% and 0 to 70 wt .-% of an additive or mixtures of several additives are included. The novel basic azotetrazolate compounds according to the invention have defoaming temperatures in the range from 180 Ā° C to 240 Ā° C, friction sensitivities of 0.1 N to 1.0 N and impact sensitivity of 0.1 J to 0.5 J. The thermal stability of the basic Azotetrazolatverbindungen invention given. Storage at 71 Ā° C show no decomposition of the basic Azotetrazolatverbindung invention after 28 days.
Preferably, the pyrotechnic igniter is one which contains as an additive 10 to 60 wt .-% of an oxidizing agent selected from one or more of the nitrates of the alkali and / or alkaline earth metals and / or ammonium, the perchlorates of the alkali and / or alkaline earth metals and / or the ammonium, the peroxides of the alkali and / or alkaline earth metals and / or zinc.

Besonders bevorzugt enthƤlt das pyrotechnische AnzĆ¼ndmittel als Zusatzstoff 0 bis 10 Gew.-% eines Sensibilisators, vorzugsweise Tetrazen.Particularly preferably, the pyrotechnic igniting agent contains as additive 0 to 10 wt .-% of a sensitizer, preferably tetracene.

Das erfindungsgemƤƟe pyrotechnische AnzĆ¼ndmittel enthƤlt vorzugsweise als Zusatzstoff 0 bis 20 Gew.-% eines Reduktionsmittels, ausgewƤhlt aus einem oder mehreren von Aluminium, Antimonsulfid, Calciumsilicid, Titan, Titanhydrid, Bor, Borhydrid, Zirkon, Zirkonhydrid, Silicium, Graphit, Aktivkohle, RuƟ oder Friktionsmittel vorzugsweise Glasbruch.The pyrotechnic igniting agent according to the invention preferably contains as an additive 0 to 20 wt .-% of a reducing agent selected from one or more of aluminum, antimony sulfide, calcium silicide, titanium, titanium hydride, boron, borohydride, zirconium, zirconium hydride, silicon, graphite, activated carbon, carbon black or Friction agent preferably glass breakage.

Besonders bevorzugt enthƤlt das pyrotechnische AnzĆ¼ndmittel als Zusatzstoff 0,1 bis 5 Gew.-% eines Bindemittels, ausgewƤhlt aus einem oder mehreren von Cellulose und deren Derivaten, Polyvinylbutyrale, Polynitropolyphenylen, Polynitrophenylether, Plexigum, Polyvinylacetat und Copolymeren.Particularly preferably, the pyrotechnic igniting agent contains as additive 0.1 to 5 wt .-% of a binder selected from one or more of cellulose and derivatives thereof, polyvinyl butyrals, Polynitropolyphenylen, Polynitrophenylether, Plexigum, polyvinyl acetate and copolymers.

Die erfindungsgemƤƟen pyrotechnischen AnzĆ¼ndmittel finden Verwendung in mechanischen, elektrischen oder opto-elektrischen AnzĆ¼ndsystemen.The pyrotechnic igniting agents according to the invention are used in mechanical, electrical or opto-electric ignition systems.

Als Zusatzstoffe kƶnnen verwendet werden:

  1. 1. Oxidationsmittel (einzeln oder in Mischungen) ausgewƤhlt aus der Gruppe bestehend aus:
    Nitrate der Alkali- oder Erdalkalimetalle oder des Ammoniums wie Natrium-, Kalium- oder Ammoniumnitrat, Perchlorate der Alkali- oder Erdalkalimetalle oder des Ammoniums, Peroxide der Alkali- oder Erdalkalimetalle oder des Zinks.
  2. 2. Energiereiche ZuschlƤge (einzeln oder in Mischungen) von Hexogen, Oktogen , Nitrocellulose.
  3. 3. Reduktionsmittel (einzeln oder in Mischungen) ausgewƤhlt aus der Gruppe bestehend aus:
    Aluminium, Titan, Titanhydrid, Bor, Borhydrid, Zirkon, Zirkonhydrid, Silicium, Gra-phit, Aktivkohle, RuƟ.
  4. 4. Bindemittel (einzeln oder in Mischungen) ausgewƤhlt aus der Gruppe bestehend aus:
    Cellulose sowie deren Derivate, Polyvinylbutyrale, Polynitropolyphenylen, Polynitrophenylether, Plexigum, Polyvinylacetat, Copolymere.
  5. 5. Abbrandmoderatoren, Stabilisatoren und Verarbeitungshilfen (einzeln oder in Mischungen) ausgewƤhlt aus der Gruppe bestehend aus:
    Zinkoxid, Zinkcarbonat, Silikate, Kieselgele, KieselsƤuren, beispielsweise Aerosil (Fa. Degussa), Bornitrid.
As additives can be used:
  1. 1. Oxidizing agent (individually or in mixtures) selected from the group consisting of:
    Nitrates of alkali or alkaline earth metals or ammonium such as sodium, potassium or ammonium nitrate, perchlorates of alkali or alkaline earth metals or of ammonium, peroxides of alkali or alkaline earth metals or zinc.
  2. 2. High-energy supplements (individually or in mixtures) of hexogen, octogen, nitrocellulose.
  3. 3. Reducing agent (individually or in mixtures) selected from the group consisting of:
    Aluminum, titanium, titanium hydride, boron, borohydride, zirconium, zirconium hydride, silicon, graphite, activated carbon, carbon black.
  4. 4. Binders (individually or in mixtures) selected from the group consisting of:
    Cellulose and its derivatives, polyvinyl butyrals, Polynitropolyphenylen, Polynitrophenylether, Plexigum, polyvinyl acetate, copolymers.
  5. 5. burnout moderators, stabilizers and processing aids (singly or in mixtures) selected from the group consisting of:
    Zinc oxide, zinc carbonate, silicates, silica gels, silicas, for example Aerosil (Degussa), boron nitride.

Die Substanzen zeichnen sich durch Blei- und Bariumfreiheit aus, einer hohen AnzĆ¼ndleistung, kurzen Reaktionszeiten und entsprechenden Empfindlichkeiten. Diese Eigenschaften ermƶglichen eine Reduzierung der zur sicheren AnzĆ¼ndung benƶtigten Masse an Explosivstoffen.The substances are characterized by lead and barium freedom, a high ignition power, short reaction times and corresponding sensitivities. These features enable a reduction in the mass of explosives needed for safe ignition.

In Tabelle 1 sind Zersetzungstemperaturen, Reib- und Schlagempfindlichkeiten ausgewƤhlter Beispiele dargestellt. Die Messung der Reib- und Schlagempfindlichkeiten erfolgte nach Methoden der Bundesanstalt fĆ¼r Materialforschung (BAM) angeben im BAM-Bericht 142 (1987), wƤhrend die Messung der Zersetzungstemperaturen mit der Dynamischen Differenzkalorimetrie (DSC) (Fa. Mettler) bei einer Aufheizrate von 10 K pro Minute erfolgte.Table 1 shows decomposition temperatures, friction and impact sensitivities of selected examples. The measurement of the friction and impact sensitivities was carried out according to methods of the Federal Institute for Materials Research (BAM) in the BAM Report 142 (1987), while the measurement of the decomposition temperatures by differential scanning calorimetry (DSC) (Mettler) at a heating rate of 10 K. per minute took place.

Gegenstand der vorliegenden Erfindung ist im Einzelnen:

  • ein pyrotechnisches AnzĆ¼ndmittel, wobei es
    Zn2+ 2(C2N10 2-)(CO3 2-), Zn2+ 3(C2N10 2-)2(CO3 2-), Zn2+ 4(C2N10 2-)2(CO3 2-)(OH-)2, Zn2+ 2(C2N10 2-)(OH-)2 oder Zn2+ 3(C2N10 2-)2(OH-)2.
    enthƤlt, wobei gilt:
    (C2N10 2-) Azotetrazolatdianion mit der Struktur
    Figure imgb0002
     wobei der Anteil der basischen Azotetrazolatkomponente 30 bis 100 Gew.-% betrƤgt und 0 bis 70 Gew.-% eines Zusatzstoffes oder Mischungen mehrerer ZusƤtzstoffe enthalten sind.
  • ein pyrotechnisches AnzĆ¼ndmittel, welches als Zusatzstoff 10 bis 60 Gew.-% eines Oxidationsmittels enthƤlt, ausgewƤhlt aus einem oder mehreren der Nitrate der Alkali- und/oder Erdalkalimetalle und/oder des Ammoniums, der Perchlorate der Alkali- und/oder Erdalkalimetalle und/oder des Ammoniums, der Peroxide der Alkali- und/oder Erdalkalimetalle und/oder des Zinks;
  • ein pyrotechnisches AnzĆ¼ndmittel, welches als Zusatzstoff 0 bis 10 Gew.-% eines Sensibilisators, vorzugsweise Tetrazen enthƤlt;
  • ein pyrotechnisches AnzĆ¼ndmittel, welches als Zusatzstoff 0 bis 20 Gew.-% eines Reduktionsmittels enthƤlt, ausgewƤhlt aus einem oder mehreren von Aluminium, Antimonsulfid, Calciumsilicid, Titan, Titanhydrid, Bor, Borhydrid, Zirkon, Zirkonhydrid, Silicium, Graphit, Aktivkohle, RuƟ oder Friktionsmittel vorzugsweise Glasbruch;
  • ein pyrotechnisches AnzĆ¼ndmittel, welches als Zusatzstoff 0,1 bis 5 Gew.-% eines Bindemittels enthƤlt, ausgewƤhlt aus einem oder mehreren von Cellulose und deren Derivaten, Polyvinylbutyrale, Polynitropolyphenylen, Polynitrophenylether, Plexigum, Polyvinylacetat und Copolymeren;
  • die Verwendung eines pyrotechnischen AnzĆ¼ndmittels in mechanischen, elektrischen oder opto-elektrischen AnzĆ¼ndsystemen.
The subject of the present invention is in detail:
  • a pyrotechnic igniter, wherein it
    Zn 2+ 2 (C 2 N 10 2- ) (CO 3 2- ), Zn 2+ 3 (C 2 N 10 2- ) 2 (CO 3 2- ), Zn 2+ 4 (C 2 N 10 2- ) 2 (CO 3 2- ) (OH - ) 2 , Zn 2+ 2 (C 2 N 10 2- ) (OH - ) 2 or Zn 2+ 3 (C 2 N 10 2- ) 2 (OH - ) 2 ,
    contains, where:
    (C 2 N 10 2- ) azotetrazolate dianion having the structure
    Figure imgb0002
     wherein the proportion of the basic Azotetrazolatkomponente is 30 to 100 wt .-% and 0 to 70 wt .-% of an additive or mixtures of several additives are included.
  • a pyrotechnic igniting agent containing as an additive 10 to 60 wt .-% of an oxidizing agent selected from one or more of the nitrates of the alkali and / or alkaline earth metals and / or of Ammonium, the perchlorates of the alkali and / or alkaline earth metals and / or ammonium, the peroxides of the alkali and / or alkaline earth metals and / or zinc;
  • a pyrotechnic igniting agent containing as an additive 0 to 10 wt .-% of a sensitizer, preferably tetracene;
  • a pyrotechnic igniting agent containing as an additive 0 to 20 wt .-% of a reducing agent selected from one or more of aluminum, antimony sulfide, calcium silicide, titanium, titanium hydride, boron, borohydride, zirconium, zirconium hydride, silicon, graphite, activated carbon, carbon black or Friction agent preferably glass breakage;
  • a pyrotechnic igniter containing, as an additive, 0.1 to 5% by weight of a binder selected from one or more of cellulose and derivatives thereof, polyvinyl butyrals, polynitropolyphenylene, polynitrophenyl ether, plexigum, polyvinyl acetate and copolymers;
  • the use of a pyrotechnic igniter in mechanical, electrical or opto-electric ignition systems.

Die Erfindung wird durch die folgenden Beispiele nƤher erlƤutert, ohne sie darauf einzuschrƤnken:
In Tabelle 1 sind die Zusammensetzungen von 5 verschiedenen basischen Salze des 5,5'-Azotetrazols aufgefĆ¼hrt. Tabelle 1 Zusammensetzungen, Verpuffungstemperaturen und Reib- und Schlagempfindlichkeiten ausgewƤhlter basischer Salze des 5,5'-Azotetrazols. Nr. Summenformel T Verp.[a] in Ā°C F Reib [b] in N E Schlag [c] in J 1 Zn2+ 2(C2N10 2-)(CO3 2-) 227 0,7 0,3 2 Zn2+ 3(C2N10 2-)2(CO3 2-) 223 0,5 0,1 3 Zn2+ 4(C2N10 2-)2(CO3 2-) 215 0,7 0,3 4 Zn2+ 2(C2N10 2-)(OH-)2 210 0,5 0,2 5 Zn2+ 3(C2N10 2-)2(OH-)2 207 0,3 0,1 [a]: Verpuffungstemperatur; [b]: Reibempfindlichkeit; [c]: Schlagempfindlichkeit. The invention is explained in more detail by the following examples, without limiting them:
Table 1 lists the compositions of 5 different basic salts of 5,5'-azotetrazole. <b> Table 1 </ b> Compositions, deflagration temperatures and friction and impact sensitivities of selected basic salts of 5,5'-azotetrazole. No. Molecular formula T Verp . [a] in Ā° C F friction [b] in N E stroke [c] in J 1 Zn 2+ 2 (C 2 N 10 2- ) (CO 3 2- ) 227 0.7 0.3 2 Zn 2+ 3 (C 2 N 10 2- ) 2 (CO 3 2- ) 223 0.5 0.1 3 Zn 2+ 4 (C 2 N 10 2- ) 2 (CO 3 2- ) 215 0.7 0.3 4 Zn 2+ 2 (C 2 N 10 2- ) (OH - ) 2 210 0.5 0.2 5 Zn 2+ 3 (C 2 N 10 2- ) 2 (OH - ) 2 207 0.3 0.1 [a]: deflagration temperature; [b]: friction sensitivity; [c]: impact sensitivity.

Claims (6)

  1. A pyrotechnic igniting agent, characterized in that it contains
    Zn2+ 2(C2N10 2-)(CO3 2-), Zn2+ 3(C2N10 2-)2(CO3 2-),Zn2+ 4(C2N10 2-)2(CO3 2-)(OH-)2, Zn2+ 2(C2N10 2-)(OH-)2 or Zn2+ 3(C2N10 2-)2(OH-)2,
    wherein:
    (C2N10) is azotetrazolate dianion having the structure
    Figure imgb0004
     wherein the proportion of the basic azotetrazolate component is 30 to 100 wt%, and 0 to 70 wt% of an additive or mixtures of a plurality of additives is contained.
  2. A pyrotechnic igniting agent according to claim 1, characterized in that it contains, as additive, 10 to 60 wt% of an oxidizing agent selected from one or more of the nitrates of the alkali and/or alkaline earth metals and/or of ammonium, the perchlorates of the alkali and/or alkaline earth metals and/or of ammonium, the peroxides of the alkali and/or alkaline earth metals and/or of zinc.
  3. A pyrotechnic igniting agent according to claim 1, characterized in that it contains, as additive, 0 to 10 wt% of a sensitizer, preferably tetrazene.
  4. A pyrotechnic igniting agent according to claim 1, characterized in that it contains, as additive, 0 to 20 wt% of a reducing agent selected from one or more of aluminum, antimony sulfide, calcium silicide, titanium, titanium hydride, boron, boron hydride, zirconium, zirconium hydride, silicon, graphite, activated carbon, carbon black or friction modifiers, preferably cullet.
  5. A pyrotechnic igniting agent according to claim 1, characterized in that it contains, as additive, 0.1 to 5 wt% of a binder selected from one or more of cellulose and derivatives thereof, polyvinyl butyrals, polynitropolyphenylene, polynitrophenyl ether, plexigum, polyvinyl acetate and copolymers.
  6. The use of a pyrotechnic igniting agent according to one or more of claims 1 to 5 in mechanical, electrical or optoelectrical ignition systems.
EP15734332.8A 2014-07-03 2015-06-29 Pyrotechnic igniting agent Active EP3164375B1 (en)

Priority Applications (4)

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SI201531000T SI3164375T1 (en) 2014-07-03 2015-06-29 Pyrotechnic igniting agent
RS20191481A RS60020B1 (en) 2014-07-03 2015-06-29 Pyrotechnic igniting agent
PL15734332T PL3164375T3 (en) 2014-07-03 2015-06-29 Pyrotechnic igniting agent
HRP20192094TT HRP20192094T1 (en) 2014-07-03 2019-11-20 Pyrotechnic igniting agent

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DE102014009807 2014-07-03
PCT/EP2015/064729 WO2016001161A1 (en) 2014-07-03 2015-06-29 Pyrotechnic igniting agent

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CN108456126B (en) * 2017-02-20 2020-02-21 ęƔäŗščæŖč‚”ä»½ęœ‰é™å…¬åø Transfer powder of gas generator, preparation method of transfer powder and gas generator for automobile safety airbag
CN110937962A (en) * 2019-12-03 2020-03-31 北äŗ¬ē†å·„大学 Alloy type carmine cold firework chemical and preparation method thereof

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FR2228043B1 (en) * 1972-10-17 1977-03-04 Poudres & Explosifs Ste Nale
US4566921A (en) * 1985-02-08 1986-01-28 L'etat Francais Represente Par Le Delegue Ministeriel Pour L'armement Priming composition which is sensitive to percussion and a method for preparing it
DE19505568A1 (en) * 1995-02-18 1996-08-22 Dynamit Nobel Ag Gas generating mixtures
JP5388573B2 (en) * 2005-06-02 2014-01-15 ćƒ«ć‚¢ć‚° ć‚¢ćƒ¢ćƒ†ćƒƒć‚Æ ć‚²ć‚¼ćƒ«ć‚·ćƒ£ćƒ•ćƒˆ 惟惃惈 ćƒ™ć‚·ćƒ„ćƒ¬ćƒ³ć‚Æćƒ†ćƒ« ćƒćƒ•ćƒ„ćƒ³ć‚° Pyrotechnical active substance
CN101434617A (en) * 2008-08-20 2009-05-20 č„æ北大学 Energetic coordination complex based on azo tetrazole azotetrazole and use thereof
DE102010025104B4 (en) * 2010-04-14 2015-06-11 Diehl Bgt Defence Gmbh & Co. Kg initiating explosive
DE102010036950B4 (en) * 2010-08-11 2014-04-03 Nammo Germany Gmbh Explosive metal complexes, their preparation and use, as well as detonators
CN102731425A (en) * 2011-04-12 2012-10-17 南äŗ¬ē†å·„大学 Preparation method of zinc 5, 5'-azotetrazole
CZ2013858A3 (en) * 2013-11-07 2015-09-02 Sellier & Bellot Bismuth-based energetic materials

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DK3164375T3 (en) 2019-11-25
RU2017103493A (en) 2018-08-03
BR112016030839A2 (en) 2017-08-22
HUE046300T2 (en) 2020-02-28
RU2695200C2 (en) 2019-07-22
CN107074674B (en) 2020-12-08
JP2017524638A (en) 2017-08-31
SI3164375T1 (en) 2020-07-31
PT3164375T (en) 2019-12-02
AU2015282658A1 (en) 2017-02-02
RS60020B1 (en) 2020-04-30
JP6559164B2 (en) 2019-08-14
PL3164375T3 (en) 2020-06-01
WO2016001161A1 (en) 2016-01-07
EP3164375A1 (en) 2017-05-10
US20170137339A1 (en) 2017-05-18
CN107074674A (en) 2017-08-18
ES2757934T3 (en) 2020-04-30
HRP20192094T1 (en) 2020-02-21
AU2015282658B2 (en) 2019-10-10
LT3164375T (en) 2019-12-10
BR112016030839B1 (en) 2022-04-19
RU2017103493A3 (en) 2019-02-08

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