EP2974841B1 - Verfahren zur herstellung einer faserplatte - Google Patents
Verfahren zur herstellung einer faserplatte Download PDFInfo
- Publication number
- EP2974841B1 EP2974841B1 EP15175533.7A EP15175533A EP2974841B1 EP 2974841 B1 EP2974841 B1 EP 2974841B1 EP 15175533 A EP15175533 A EP 15175533A EP 2974841 B1 EP2974841 B1 EP 2974841B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- acid
- wood
- lignocellulose
- containing material
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000004519 manufacturing process Methods 0.000 title claims description 21
- 239000002023 wood Substances 0.000 claims description 123
- 239000000463 material Substances 0.000 claims description 99
- 239000002253 acid Substances 0.000 claims description 89
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 80
- 238000000034 method Methods 0.000 claims description 64
- 230000008961 swelling Effects 0.000 claims description 37
- 238000011282 treatment Methods 0.000 claims description 35
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 33
- 229920002522 Wood fibre Polymers 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 26
- 238000004026 adhesive bonding Methods 0.000 claims description 20
- 239000011230 binding agent Substances 0.000 claims description 20
- 150000003839 salts Chemical class 0.000 claims description 15
- 238000003825 pressing Methods 0.000 claims description 11
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 8
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 8
- 241000294754 Macroptilium atropurpureum Species 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- 239000007848 Bronsted acid Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 2
- 239000010419 fine particle Substances 0.000 claims 1
- 230000002879 macerating effect Effects 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 43
- 239000012978 lignocellulosic material Substances 0.000 description 41
- 235000011007 phosphoric acid Nutrition 0.000 description 40
- 230000008569 process Effects 0.000 description 32
- 239000000835 fiber Substances 0.000 description 26
- 239000011094 fiberboard Substances 0.000 description 25
- 239000002025 wood fiber Substances 0.000 description 25
- 239000002245 particle Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
- 238000010306 acid treatment Methods 0.000 description 11
- 230000009467 reduction Effects 0.000 description 10
- 210000002421 cell wall Anatomy 0.000 description 8
- 229920001568 phenolic resin Polymers 0.000 description 8
- 239000002131 composite material Substances 0.000 description 7
- GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 description 6
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 6
- 229920001807 Urea-formaldehyde Polymers 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 229920002678 cellulose Polymers 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 235000000346 sugar Nutrition 0.000 description 6
- 229920002488 Hemicellulose Polymers 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 238000005470 impregnation Methods 0.000 description 5
- 229920005610 lignin Polymers 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 4
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000007385 chemical modification Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- HMJMQKOTEHYCRN-UHFFFAOYSA-N formaldehyde;phenol;1,3,5-triazine-2,4,6-triamine;urea Chemical compound O=C.NC(N)=O.OC1=CC=CC=C1.NC1=NC(N)=NC(N)=N1 HMJMQKOTEHYCRN-UHFFFAOYSA-N 0.000 description 3
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 239000004890 Hydrophobing Agent Substances 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 2
- 229920003180 amino resin Polymers 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 125000001547 cellobiose group Chemical group 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical group 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- JMFRWRFFLBVWSI-NSCUHMNNSA-N coniferol Chemical compound COC1=CC(\C=C\CO)=CC=C1O JMFRWRFFLBVWSI-NSCUHMNNSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000009408 flooring Methods 0.000 description 2
- 229930182830 galactose Natural products 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 238000007731 hot pressing Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000013067 intermediate product Substances 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- 150000007517 lewis acids Chemical class 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 230000008092 positive effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000002522 swelling effect Effects 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- LZFOPEXOUVTGJS-ONEGZZNKSA-N trans-sinapyl alcohol Chemical compound COC1=CC(\C=C\CO)=CC(OC)=C1O LZFOPEXOUVTGJS-ONEGZZNKSA-N 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241001662103 Cryptocarya corrugata Species 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 1
- QRRBCZAFPPNLIP-UHFFFAOYSA-N O[PH2]=O.OP(O)=O Chemical compound O[PH2]=O.OP(O)=O QRRBCZAFPPNLIP-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropanol Chemical group CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical class CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011093 chipboard Substances 0.000 description 1
- LZFOPEXOUVTGJS-UHFFFAOYSA-N cis-sinapyl alcohol Natural products COC1=CC(C=CCO)=CC(OC)=C1O LZFOPEXOUVTGJS-UHFFFAOYSA-N 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 229940119526 coniferyl alcohol Drugs 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000009189 diving Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- GATNOFPXSDHULC-UHFFFAOYSA-N ethylphosphonic acid Chemical compound CCP(O)(O)=O GATNOFPXSDHULC-UHFFFAOYSA-N 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002402 hexoses Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000012432 intermediate storage Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005341 metaphosphate group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 150000002912 oxalic acid derivatives Chemical class 0.000 description 1
- 229930015763 p-coumaryl alcohol Natural products 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 150000002972 pentoses Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000017854 proteolysis Effects 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- -1 siloxanes Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- PTNLHDGQWUGONS-UHFFFAOYSA-N trans-p-coumaric alcohol Natural products OCC=CC1=CC=C(O)C=C1 PTNLHDGQWUGONS-UHFFFAOYSA-N 0.000 description 1
- PTNLHDGQWUGONS-OWOJBTEDSA-N trans-p-coumaryl alcohol Chemical compound OC\C=C\C1=CC=C(O)C=C1 PTNLHDGQWUGONS-OWOJBTEDSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 1
- 125000002264 triphosphate group Chemical group [H]OP(=O)(O[H])OP(=O)(O[H])OP(=O)(O[H])O* 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 239000010876 untreated wood Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N1/00—Pretreatment of moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N1/00—Pretreatment of moulding material
- B27N1/006—Pretreatment of moulding material for increasing resistance to swelling by humidity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N1/00—Pretreatment of moulding material
- B27N1/02—Mixing the material with binding agent
Definitions
- the invention relates to a method for producing a source-reduced fiber board.
- Wood-based materials are used, for example, in construction as an insulating, constructive or cladding element as well as flooring.
- Wood materials are made from wood shavings, wood chips or wood fibers as well as from sawn timber or veneers of various types of wood with the addition of natural and / or synthetic binders and other additives.
- the properties of the wood are known to be significantly determined by the moisture content of the wood. As the absorption of water increases, as a rule the wood moisture increases, the strength and dimensional stability of the wood decrease, and the susceptibility to wood-destroying microorganisms increases.
- the protruding fibers are then mechanically torn off, whereby the flooring has optically clear damage that leads to increased and accelerated wear. Furthermore, this behavior has a crucial importance in building materials.
- swelling in addition to increased stress, an increased internal swelling pressure can arise, which counteracts the external mechanical load and also has an influence on the load capacity of the standing under continuous load wood construction.
- Wood generally has as builders mainly cellulose, hemicelluloses and lignin. In the cell wall polymers free hydroxyl groups are found, which can make strong hydrogen bonds with water molecules, which hold the water molecules in the cells and thereby induce swelling.
- Wood fibers are hydrophobized with wax dispersions for the production of modified wood materials. As a result, the thickness swelling and the water absorption rate of the wood materials produced with it should be delayed.
- a reduction of the swellable fractions in the corresponding wood products is also a known strategy.
- the DE 102 008 056 650 A1 proposed to wood fibers with wood extraneous components such as glass, metal, ceramic and / or plastics to produce wood-based materials.
- non-swelling shares a delayed thickness swelling of the wood panels to be achieved.
- the EP 1 762 671 B1 describes a building board, which has a reduced swelling and shrinkage behavior and on which a waterproof final layer of polyurethane, plastic or paint or mixtures thereof is applied.
- the EP 2 181 818 A2 describes a process for the production of wood fiber materials and wood fiber materials from wood fibers, which are obtained after plasticization of wood and which should have a reduced emission of volatile organic compounds (VOC).
- the wood fiber materials are prepared so that the uncut and / or comminuted wood is contacted with a formulation containing at least one compound to establish a neutral to basic pH and at least one complexing agent.
- the EP 0 139 530 A3 describes a process for the preparation of lignocellulose-containing composites, films and the like with a di- or polyisocyanate based on a binder system in which a mineral acid is used.
- a mineral acid HNO 3 , HCl, H 2 SO 4
- PMDI gluing agent
- the known methods have in common that a delay of the swelling is achieved by the coating and chemical modification. This is presumably due to the fact that a shielding, occupation or substitution of the free hydroxyl groups of the cell wall polymers is carried out and the hygroscopicity is lowered. In this way, presumably the interaction between water molecules and free hydroxyl groups of the cell wall polymers is reduced, thereby achieving a reduction in the swelling rate.
- a disadvantage of the measures described above is that this only a delay of the absorption of water is achieved.
- the chemical modification described above increases the weight of the wood material, which can be detrimental to processing and suitability as a building material.
- the WO 2008/028183 A1 describes a process for producing a medium density fiberboard (MDF) wherein lignocellulosic fibers are pretreated with oxalic acid or oxalic acid derivatives prior to the refining step in a type of digester.
- MDF medium density fiberboard
- the DE 697 10 748 T2 describes in Example 2 a process for producing an MDF board in which wood chips are treated with dilute sulfuric acid for 6 minutes at a temperature of 184 ° C and a pressure of 10 bar.
- a disadvantage of the treatment in Vorkocher is that due to the prevailing heat, the pressure and the high degree of dissociation of the acid, the wood fibers can be severely damaged. Under these hydrolysis conditions, the cellulose contained in the wood can easily be broken down. Not only can this result in a reduction in the quality of the fiber in general, but also the structure of the fiber can be so severely damaged that the fiber material can no longer be suitable for producing a fiberboard.
- the invention has for its object to provide an effective, cost-effective method, with the source-reduced wood materials, especially a reduced source fiber board, standard processes used in the wood industry without increased time and cost can be produced.
- the Er may be applied to a method for producing a reduced-source fiberboard by gluing lignocellulosic material, wherein the lignocellulosic material is treated prior to gluing with an acid, wherein the treatment is carried out at a temperature of 70 to 200 ° C and a pressure of 1 to 12 bar and wherein the acid is a Brönsted acid selected from the group consisting of phosphoric acid, phosphorous acid, hypophosphorous acid and mixtures thereof, and wherein the acid is an acid having a pKa of less than 4.
- the inventive method for producing a reduced-source fiberboard provides that the lignocellulosic material is treated prior to gluing with an acid, wherein the treatment is carried out at a temperature of 70 to 200 ° C and a pressure of 1 to 12 bar.
- the acid according to the invention is in particular a Bronsted acid selected from the group consisting of phosphoric acid, phosphorous acid, hypophosphorous acid and phosphonic acid.
- the swelling capacity of fiberboard can be reduced in a particularly simple and cost-effective manner if the lignocellulose-containing material before gluing under the said pressure and temperature conditions with one of these acids and / or a mixture of the acid and its salts, esters or adducts (hereinafter "acid treatment").
- acid treatment a mixture of the acid and its salts, esters or adducts
- the addition of the acid to the precooker or digester takes place.
- Particularly preferred is an addition before the refiner, in particular between the digester and refiner.
- the addition of the acid may be e.g. in a feed or discharge screw that conveys the lignocellulosic material from the precooker / digester to the refiner.
- water is partially or completely squeezed or removed between the digester and refiner steps.
- the acid treatment is carried out on such a pressed or dehydrated lignocellulose-containing material.
- Such a mixture of pressed lignocellulose-containing material and acid can then be fed to the refiner.
- reducing the swelling capacity is believed to be due to elimination of the free-standing hydroxyl groups of the cell wall polymers mediated by the acid treatment, resulting in less interaction with the water molecules and resulting in hydrophobization of the material.
- the acid treatment can be integrated in a simple manner into the usual processes in the wood industry for the production of fiberboard, i. Complex intermediate steps (e.g., drying) or process interruptions are not required.
- acids used according to the invention for example phosphoric acid
- the acids used according to the invention are available inexpensively and readily available.
- Lignocellulosic material By “lignocellulosic material” is meant any type of material containing lignocellulose.
- Lignocellulose according to the invention contains cellulose and / or hemicellulose and lignin.
- Cellulose is an unbranched polysaccharide consisting of several hundred to ten thousand cellobiose units. These cellobiose units, in turn, consist of two molecules of glucose linked by a ⁇ -1,4-glucosidic bond.
- Hemicellulose is a collective name for various components of plant cell walls.
- the hemicelluloses are branched polysaccharides with a lower chain length - usually less than 500 sugar units - which are composed of different sugar monomers.
- Hemicellulose is composed essentially of various sugar monomers such as glucose, xylose, arabinose, galactose and mannose, which sugars may have acetyl and methyl substituted groups. They have a random, amorphous structure and are readily hydrolyzable.
- Xylose or arabinose consist for the most part Part of sugar monomers with five carbon atoms (pentoses).
- Mannose or galactose consist mainly of sugar monomers with six carbon atoms (hexoses).
- Ligans are amorphous, irregularly branched aromatic macromolecules, which occur in nature as part of cell walls and there cause the lignification (lignification) of the cell. They are composed of substituted phenylpropanol units, have a lipophilic character and are insoluble in room temperature in neutral solvents such as water. Precursors of lignin are, for example, p-coumaryl alcohol, coniferyl alcohol and sinapyl alcohol. The molecular weights of lignin are usually between 10,000 and 20,000 g / mol.
- the lignocellulosic material may be in a frayed and / or unscreened state.
- the lignocellulose-containing material is first added in undefiberated state (for example as wood chips) and then undergoes a defibering and / or comminution (for example in the refiner) in the course of the process.
- undefiberated state for example as wood chips
- defibering and / or comminution for example in the refiner
- the treatment of the lignocellulosic material may be in both defibred, partially defibred, and / or uncorrugated state.
- the acid treatment is preferably carried out on a lignocellulose-containing material which has a water content of from 30 to 400% by weight, in particular from 40 to 200% by weight, in particular from 50 to 150, based on the total weight of the lignocellulose-containing material.
- lignocellulose-containing material which can be used according to the invention are wood particles, for example any form of finely divided wood material, ie in particular wood chips, wood chips, OSB strands, wood fibers and / or wood flour.
- wood particles for example any form of finely divided wood material, ie in particular wood chips, wood chips, OSB strands, wood fibers and / or wood flour.
- the wood particles especially if they are chips, fibers or strands, substantially or completely native wood.
- substantially herein is meant up to 80, 85, 90, 95, 98, or 99 weight percent, based on the total weight of the lignocellulosic material. Chips, fibers and / or strands of native wood have proved to be particularly suitable.
- the lignocellulosic material may be selected from the group consisting of finely divided wood material, wood fibers, wood shavings, and wood chips.
- wood material is understood to mean a wide variety of materials that consist of wood or contain wood, examples of wood materials are wood boards, laminates, floor coverings, worktops, table tops, pallets and / or wood shaped parts, in particular composite materials of individual wood particles may be any of cellulose products such as wood particles, especially wood shavings, finely divided wood material, wood strands, wood fibers, wood chips and / or wood veneers.Wood materials disclosed herein are particularly those based on solid wood, veneer materials, chipboard, fiber materials, fiberboard or other composites.
- the process disclosed herein is particularly well suited for the production of pressed wood materials, in particular for the production of fiberboard.
- a fiberboard is for example a UDF, LDF, MDF, or HDF board into consideration.
- the fiberboard, or the preliminary or intermediate product of the fiberboard consists essentially of lignocellulose-containing material.
- essential here means up to 80, 85, 90, 95, 98 or 99 wt .-%, based on the Total weight of the wood material.
- the fiberboard, or the precursor or intermediate contains further additives.
- the lignocellulosic material which is treated with acid in the process of the present invention may be different.
- the fiberboard can be produced, for example, by comminuting cellulose-containing materials and then joining the structural elements together.
- the precursor or intermediate can be selected, for example, from the lignocellulose-containing starting material and / or the structural elements obtained by comminution, such as, for example, the wood particles, wood chips, wood strands, wood chips, wood fibers or wood veneers.
- source-reduced fiberboard can be produced.
- reduced swelling is meant a reduction in swelling compared to the untreated material.
- swelling is meant the consequences of the contact of the wood fibers with water or water vapor. In particular, a wet swelling and / or a wet expansion can occur due to the contact with water. Swelling is understood to mean swelling capacity or thickness swelling.
- the swelling capacity can be determined according to European standard EN 317 “Particleboard and fiberboard”.
- Thickness swelling can be determined “after water storage” or ISO 24336 "Laminate floor coverings. Determination of thickness swelling after partial immersion in water”.
- a reduction of the swelling by at least 10%, based on the untreated material is achieved by the inventive method.
- the swelling can be determined according to EN 317 or ISO 24336.
- the content of the acid is 0.1 to 15% by weight, preferably 0.1 to 10% by weight, in particular 0.1, 0.2, 0.5, 1, 2, 3, 5, 7, 9, 10 or 12% by weight, based on the dry matter (atro) of the lignocellulose-containing material.
- the acid may be used in admixture with one of its salts, esters or adducts.
- the term "acid” includes Bronsted acids and / or Lewis acids. Examples of usable Brönsted acids described herein are, for example, mineral acids. Acids which can be used according to the invention preferably have a pK s value of less than 4, preferably less than 3.5, 3, 2.75, 2.5, 2.3 or 2. The acid can be used alone or in combination with one of its salts, esters or adducts.
- the Brönsted acids may be selected, for example, from the group consisting of phosphoric acid, phosphorous acid, hypophosphorous acid, phosphonic acid, sulfuric acid, sulfonic acid, p-toluenesulfonic acid, benzenesulfonic acid, sulfosuccinic acid, methylsulfonic acid, methylphosphonic acid and ethylphosphonic acid or mixtures thereof.
- the acid is selected from phosphoric acid, phosphorous acid, hypophosphorous acid and phosphonic acid and mixtures thereof. Particular preference is given to using phosphoric acid, in particular ortho- phosphoric acid.
- a treatment with a mixture of phosphoric acid and a salt of phosphoric acid has proved to be advantageous.
- the salts may, for example, be alkali salts, alkaline earth salts and / or ammonium salts.
- phosphoric acid phosphorous acid, hypophosphorous acid or mixtures thereof are used. Practical experiments have shown that this can reduce the risk of strongly acidic reactions with the lignocellulose-containing material and the concomitant reduction in quality of the lignocellulose-containing fiber or of the end product.
- Another advantage lies that the phosphoric acid is less corrosive, so that the process equipment is less stressed.
- Phosphoric acids in the context of this invention are those which have a free HO-P group.
- Examples of phosphoric acids which can be used according to the invention are orthophosphoric acid, phosphonic acid and / or phosphinic acid.
- phosphoric acid is especially ortho- phosphoric acid into consideration.
- the phosphoric acid can be used as a 10 to 85 wt .-% solution in water. If the treatment with phosphoric acid is carried out in the refiner, it is preferable to use a 50 to 85% strength by weight solution in water, in particular a 70 to 85% strength by weight solution in water.
- salts of ortho- phosphoric acid in particular phosphates, hydrogen phosphates and / or dihydrogen phosphates are meant.
- the salts of phosphoric acid may be, for example, their alkali salts, alkaline earth salts and / or ammonium salts or compounds. Salts of phosphoric acid which can be used according to the invention are also phosphonates and / or phosphinates.
- Alkyl esters are particularly suitable as the phosphoric acid esters, the alkyl chain length preferably being 1 to 12 carbon atoms, preferably 1 to 10 carbon atoms, particularly preferably 1 to 5 carbon atoms and very particularly preferably 1 to 3 carbon atoms.
- the adducts of phosphoric acid may be, for example, di-, tri- or meta-phosphates.
- Lewis acids described herein are, for example, boron trifluoride, boron chloride, aluminum trichloride, iron (III) chloride and / or zinc chloride.
- the addition of the acid can be done at any point in the process prior to gluing or gluing.
- a treatment in the preheater and / or in the digester has proved to be advantageous.
- the treatment may take place under elevated pressure (with respect to atmospheric pressure) and / or under elevated temperature (with respect to room temperature).
- the treatment normally takes place under normal pressure and / or at a temperature of up to 100 ° C.
- a further embodiment according to the invention provides that the treatment takes place after the digester, in particular in the intermediate stage after the digester and before the refiner or in the refiner.
- the treatment is carried out at a temperature of 70 to 200 ° C, in particular 160 to 200 ° C. In one embodiment, the treatment may be carried out at a temperature of 120 to 180 ° C. According to the invention, the treatment is carried out at a pressure of 1 to 12 bar, in particular 2 to 10 bar. In one embodiment, the treatment may be carried out at a pressure of 6 to 9 bar.
- the duration of the treatment may be 0.01 to 15 minutes, especially 0.3 to 5 minutes.
- the acid is added before and / or during the crushing process in the refiner.
- the treatment of the lignocellulosic material with the acid in a conventional refiner in the industry is usually carried out at a process temperature of 160 to 200 ° C and / or a pressure of 2 to 10 bar, in particular from 5 to 9 bar.
- Refiner is understood to mean the machine used in the wood industry, which is used for comminution, in particular for grinding of fibers.
- suitable refiners are disc refiners, cone refiners or cylindrical refiners. Refiner are for example in the “ Taschenbuch der Holztechnik ", Wagen1.2 / Scholz, 2nd ed. 2012, p. 235 ff , described.
- In the refiner wood particles are treated at a process temperature of 70 to 200 ° C, in particular at 120 to 180 ° C, and / or a pressure between 1 to 10 bar, in particular at 5 to 9 bar.
- treating is meant the processing or contacting of the lignocellulosic material (or a precursor or intermediate thereof) with the acid under the conditions described.
- the lignocellulosic material may be present in the treatment in un-fibered, shredded and / or partially defibred state.
- the acid is added after the precooker or digester.
- this addition of acid takes place before the refiner, more preferably the acid is added to the still hot, lignocellulosic material that has leaked from the digester.
- This is particularly practical in a feed or discharge screw, which conveys the lignocellulosic material from the pre-cooker or digester to the refiner.
- the acid may be added according to another embodiment in the refiner and / or between the digester and refiner.
- cooker is understood to mean the machine commonly used in the wood industry, which is used to soften the wood chips under the effect of temperature and excess water.
- the common wood chips preparation for MDF production by means of a cooker and subsequent refining step is described, for example, in US Pat. Holzwerkstoffe ", Soiné, DRW-Verlag 1995, chapter 1.2.2.6 s.
- the greater the surface area of the lignocellulose-containing material to be treated i.e., the precursor or intermediate product of the wood material
- the surface is known to increase with decreasing particle size.
- a higher reaction rate is achieved if the lignocellulose-containing material to be treated has a small particle size.
- the material to be treated is brought into contact with the acid with simultaneous comminution.
- the acid treatment takes place during the comminution of the lignocellulose-containing material (for example in the refiner).
- the lignocellulosic material undergoes the swelling-reducing treatment, a swelling reduction is ensured down to the core of the entire wood material with low cost and process complexity and within the running of the process chain.
- the reaction of the acid, in particular the phosphoric acid, with the surface of the lignocellulosic material may begin with the introduction of the acid in the preheater or the digester or only between the digester and the refiner and in the refiner. Due to the thermomechanical conditions in the refiner, the distribution and / or the reaction is further accelerated. By discharging water in the dryer and / or the further thermally induced drying of the nonwoven fabric during plate formation in the press, the reaction can also be driven forward become. The final reaction is often complete only after the finished plate has cooled in the warehouse.
- Another advantage of the method according to the invention is that the diffusion process takes place here within a few minutes.
- a further advantage is the short treatment time in Voriserrmbetude, Vorkocher and / or refiner or in between. This is generally not longer than 15 minutes, preferably 0.01 to 10 minutes, particularly preferably 0.1 to 5 minutes, in particular 0.3 to 2 minutes.
- the inventive method is compatible with current production processes of the wood industry. It can be used within an ongoing production without significantly changing the productivity of the equipment used.
- step a) the lignocellulosic material to be processed is preheated to the desired temperature.
- the lignocellulose-containing material is digested in the digester under elevated pressure and at elevated temperature.
- steps a) and / or b) take place using an excess of water.
- the proportion of water in the mixture of water and the lignocellulose-containing material in step a) and / or b) can be from 100 to 400% by weight, in particular from 150 to 300% by weight, based on the total weight of the lignocellulose-containing material.
- the addition of the acid may occur in step a) and / or b). Due to the increased water content in step a) and / or b), the added acid is diluted again. This may be advantageous because, according to Ostwald's law of dilution, the degree of proteolysis increases with increasing dilution. This allows a particularly effective use of the acid used.
- the reaction of the acid is further enhanced by the increased surface area of the fiberized lignocellulosic material and / or the elevated temperature and consequent pore opening of the fibers.
- step a) and / or b) can be problematic since exact dosing is difficult due to the considerable and sometimes fluctuating dilution. It can easily happen that either too little acid is added or too much, which then causes the reaction of the acid with the lignocellulose-containing material to proceed so strongly that it suffers from the quality of the lignocellulose-containing material and thus also the quality of the end product. Due to the dilution effect of the water present, it may also happen that not enough acid penetrates into the lignocellulosic material, which is why in turn the treatment time in step a) and / or b) must be extended.
- step c the lignocellulosic material is fed to the refiner (step c)).
- This phase between the digester and the refiner is referred to herein as "intermediate step bc)". It has proven to be particularly practical if the acid treatment takes place in this intermediate step bc).
- Step bc) involves the transfer of the lignocellulosic material from the digester to the refiner, but may also include other processes, in particular intermediate storage or further processing of the lignocellulose-containing material.
- the defibrated lignocellulose-containing material obtained from step b) becomes the refiner used in step c) by means of a feed or discharge screw fed.
- the still hot lignocellulosic material is carried out of the digester and transported in the direction of refiner. Since the previous step a) and / or b) has an increased water content, which is not desired in the following process steps, the water from the lignocellulose-containing material is usually at least partially pressed or removed in the intermediate transport step bc).
- the lignocellulosic material After pressing, the lignocellulosic material typically has a water content of from 50 to 200% by weight, in particular from 75 to 150% by weight, based on the total weight of the lignocellulose-containing material.
- the acid treatment is carried out after such pressing or removal of the water, which takes place after removal from the digester.
- the lignocellulosic material still has an elevated temperature during transport from the precooker to the refiner. This has a positive effect on the acid treatment.
- the addition of the acid is particularly preferably carried out in intermediate step bc).
- the addition of the acid in intermediate step bc) can be carried out by initially squeezing or removing water completely or partially and then adding the acid.
- the acid may be added after or during at least partial squeezing or removal of the water from the lignocellulosic material.
- the treatment time with the acid in intermediate step bc) can be 0.1 seconds to 2 minutes, preferably from 0.5 seconds to 1 minute and particularly preferably from 1 second to 30 seconds.
- the disadvantages, as they exist in the addition in step a) and / or b) can be largely avoided by the acid addition in intermediate step bc).
- the acid is not diluted so much, which also ensures better dosage and the risk Uncontrolled reactions can be reduced.
- the treatment time can be reduced, which can have a positive effect on the production costs.
- the lignocellulosic material has an increased surface area and elevated temperature such that the pores of the lignocellulosic material are at least partially opened or widened, allowing the acid to more easily diffuse into the lignocellulosic material.
- step bc) the acid is added in intermediate step bc) or step c) and thus can remain in the lignocellulose-containing material in the further process. If the acid is added in step a) and / or b), the acid is at least partially removed by the removal or removal of the water in step c) and can then no longer be available for the reaction.
- the acid used is a Bronsted acid selected from the group consisting of phosphoric acid, phosphorous acid, hypophosphorous acid phosphonic acid and mixtures thereof in intermediate step bc) and / or step c).
- the acid can be used in an amount of from 0.1 to 10% by weight, based on the lignocellulose-containing material (atro).
- Phosphoric acid is particularly preferred according to the invention as the acid.
- the phosphoric acid can be added in admixture with one of its salts, esters or adducts in intermediate step bc) and / or step c).
- the lignocellulose-containing material (refiner) is comminuted.
- the acid is before and / or during the crushing process added in the refiner.
- the treatment of the lignocellulosic material with the acid in a conventional refiner in the industry is usually carried out at a process temperature of 160 to 200 ° C and / or a pressure of 2 to 10 bar, in particular from 5 to 9 bar. These conditions allow for rapid diffusion of the acid molecules into the core of the lignocellulosic material.
- the acid treatment can be done in each step before gluing or gluing.
- the treatment preferably takes place in at least one of the steps a), b), bc) and / or c).
- the acid treatment may also be carried out before or after at least one of steps a), b), c) and d). Examples of this are the feeding of the acid in feed or Austragsschnecken which carry the lignocellulosic material.
- the acid may be added directly to the preheater, precooker and / or refiner. Most preferably, the addition of the acid is between steps b) and c), i. in intermediate step bc), and / or during step c). In a preferred embodiment, the acid is added in step bc).
- the acid used is a Bronsted acid which is selected from the group consisting of phosphoric acid, phosphorous acid, hypophosphorous acid and phosphonic acid and mixtures thereof.
- the acid can be used in an amount of from 0.1 to 10% by weight, based on the lignocellulose-containing material (atro).
- Phosphoric acid is particularly preferred according to the invention as the acid.
- the phosphoric acid may be added in admixture with one of its salts, esters or adducts.
- step e) the lignocellulose-containing material is glued with a binder.
- Suitable binders are in particular a melamine and / or urea resin.
- gluing it can be understood as wholly or partially wetting with a composition that contains a binder.
- Such compositions are also referred to by the person skilled in the art as “glue liquor”.
- Gluing can in particular also mean the uniform distribution of the binder-containing composition on the wood particles.
- the application of the binder-containing composition can be carried out, for example, by impregnation or spraying, in particular in a blowline.
- a blow-line connects to the refiner.
- surface-modifying agents which neutralize the surface and / or encapsulate the fiber can optionally also be sprayed on in the blowline.
- the amount of the binder used in the gluing or gluing is preferably 0.1 to 20 wt .-%, in particular 1.0 to 16 wt .-%, more preferably 4.0 to 14.0 wt .-%, based on the Wood dry weight (solid resin / atro). For many applications, it is particularly practical if the binder in an amount of 0.1 to 15 wt .-% based on the dry weight of wood (solid resin / atro) is used.
- the application of the binder can be carried out, for example, in the blowline known to the person skilled in the art.
- the method according to the invention is suitable for a multiplicity of binder-wood particle combinations.
- binders which can be used according to the invention are aminoplasts, phenoplasts, vinyl acetates, isocyanates, epoxy resins and / or acrylic resins.
- Particularly preferred binders are urea-formaldehyde resin (UF), melamine-formaldehyde resin, phenol-formaldehyde resin (PF), polyvinyl acetate and / or white glue.
- the binder used for the gluing is a system based on urea-formaldehyde resins (UF), melamine-reinforced urea-formaldehyde resins (MUF), melamine-urea-phenol-formaldehyde resins (MUPF), Phenol-formaldehyde resins (PF), polymeric diisocyanates (PMDI) and / or isocyanates used.
- the binder is an aminoplast resin.
- the binder used in the process of the invention may further contain hardeners.
- the curing can also be carried out by pressing the composite material under the action of heat.
- a drying of the glued mixture containing the lignocellulose-containing material can be carried out between the gluing (step e) and the pressing (step g).
- step g) the mixture containing the lignocellulose-containing material is finally pressed into a fiberboard.
- a pressing temperature of at least about 150 ° C.
- the glued wood particles are pressed in step g) into a wood chip material.
- a wood chip material Preferably it is in step g) is a hot pressing.
- the press factor during hot pressing is from 2 to 10 s / mm, preferably from 3 to 6 s / mm.
- Press factor is understood to mean in particular the residence time of the lignocellulose-containing wood chip material in seconds per millimeter thickness or thickness of the finished pressed lignocellulose-containing wood chip material in the press.
- Suitable temperatures for the compression in step g) of the process according to the invention or one of its embodiments are temperatures of 150 ° C to 250 ° C, preferably from 160 ° C to 240 ° C, particularly preferably from 180 ° C to 230 ° C. At temperatures in these ranges, the process can be carried out particularly economically.
- Also described herein is a fiberboard obtainable by the method of the invention or one of its embodiments and by further processing the fiber board available laminate, a floor covering, a worktop, table top or pallet.
- the wood chips arrive for hydrothermal pretreatment in a preheating, where they are "pre-steamed” together with 1 wt .-% ortho- phosphoric acid (based on the total amount of water and wood chips) at atmospheric pressure at a temperature of up to 100 ° C.
- the partially plasticized and modified wood chips then pass through the vibration discharge floor and a screw conveyor in the digester.
- the pitch of the helix decreases continuously, compressing the chips into a relatively pressure-tight plug. With this plug, the seal takes place to the stove.
- the chips are "cooked” at a vapor pressure between 6 and 10 bar at 140 to 180 ° C.
- the chips remain about 1 to 6 minutes before being fed by a screw conveyor (discharge screw) and via the feed screw into the refiner and pulverized into fibers at a vapor pressure of 6 to 10 bar.
- a screw conveyor discharge screw
- further hydrophobing agents as well as surface-modifying agents which neutralize the surface or encapsulate the fiber can be sprayed on in the blowline adjoining the refiner.
- the glued fibers now enter the dryer and are dried to the desired residual moisture.
- the fibers on a circumferential Forming band scattered and the height of the resulting fiber mat is adjusted by calibration rollers (scalper). After precompression, the endless fiber mat is pressed in a continuous hot press at 200 ° C and 30 bar for about 3 minutes to its desired thickness.
- the wood fiberboard thus obtained has a significantly reduced thickness swelling.
- the wood chips arrive for hydrothermal pretreatment in a Vorierrm actuallyer, where they are "pre-damped” at atmospheric pressure of a temperature of up to 100 ° C.
- the partially plasticized and modified woodchips then pass through the vibration discharge floor and / or a screw conveyor in the digester.
- the pitch of the helix decreases continuously, compressing the chips into a relatively pressure-tight plug. With this plug, the seal takes place to the stove.
- the chips are "cooked” at a vapor pressure between 6 and 10 bar at 140 to 180 ° C.
- the chips remain about 1 to 6 minutes before being fed by a screw conveyor (discharge screw) together with ortho- phosphoric acid in an amount of 10% by weight, based on the amount of the wood material, into the refiner and at be pulverized to fibers to a vapor pressure of 6 to 10 bar.
- a screw conveyor discharge screw
- ortho- phosphoric acid in an amount of 10% by weight, based on the amount of the wood material
- further hydrophobing agents as well as surface-modifying agents which neutralize the surface or encapsulate the fiber can be sprayed on in the blowline adjoining the refiner.
- the glued fibers now enter the dryer and are dried to the desired residual moisture.
- the fibers are scattered on a rotating forming belt and the height of the resulting fiber mat is adjusted by calibration rollers (scalper). After precompression, the endless fiber mat is pressed in a continuous hot press at 200 ° C and 30 bar for about 3 minutes to its desired thickness.
- the wood fiberboard thus obtained has a significantly reduced thickness swelling.
- the wood fibers were subjected to a pulping process. For this wood chips were cooked in a pre-cooker. The wood fibers were fed from the precooker to the refiner by means of a discharge screw while pressing off water. Even before the wood fibers reached the refiner, phosphoric acid was added. The wood fibers thus obtained were examined for their swelling properties. For this purpose, in a beaker, wood fibers, both the reference fibers (0% phosphoric acid) and those treated with phosphoric acid, were weighed (weighed, EW) and covered with water so that they were completely covered. The proportion of phosphoric acid is given in Table 1 as wt .-% phosphoric acid based on the total weight of wood fibers (atro).
- the swelling was calculated as follows: WAV REFERENCE - WAV sample * 100 / WAV REFERENCE
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DE102016100078B3 (de) * | 2016-01-04 | 2017-04-13 | Fritz Egger Gmbh & Co. Og | Faserplatte mit erhöhter Beständigkeit gegen Pilzbefall sowie Verfahren zu deren Herstellung |
CN109366677B (zh) * | 2018-10-18 | 2021-03-05 | 陕西森尚建材科技有限公司 | 一种环保型生态植物纤维板及其制备方法 |
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JPS60101004A (ja) * | 1983-10-19 | 1985-06-05 | アトランテイツク・リツチフイールド・カンパニー | リグノセルロース系複合成形品の製造方法 |
WO1998017727A1 (en) * | 1996-10-18 | 1998-04-30 | Kronospan Gmbh | Treatment of lignocellulosic material |
EP1716995B1 (de) * | 2005-04-22 | 2009-02-25 | Georg-August-Universität Göttingen | Schutzmittel für lignocellulosisches Material auf Basis von Fettsäure- und Paraffinderivaten |
DE102005042658B3 (de) | 2005-09-08 | 2007-03-01 | Kronotec Ag | Bauplatte, insbesondere Fußbodenpaneel |
DE102006029313A1 (de) | 2006-06-23 | 2007-12-27 | Sasol Wax Gmbh | Wachsdispersion aus ölhaltigen Weichwachsen, Verwendung von Weichwachsen als Hydrophobierungsmittel in Holzwerkstoffen und Verfahren zur Einbringung von Weichwachsen in Holzwerkstoffe |
US20080264588A1 (en) * | 2006-09-01 | 2008-10-30 | Masood Akhtar | Method of Making Medium Density Fiberboard |
EP2181818A3 (de) * | 2008-10-28 | 2012-08-22 | IHD Institut für Holztechnologie Dresden gGmbH | Verfahren zur Herstellung von Holzfaserwerkstoffen sowie Holzfaserwerkstoffe mit verringerter Emission an flüchtigen VOC |
DE102008056650A1 (de) | 2008-11-10 | 2010-05-12 | Martin Dreisman | Zusammensetzung und Verfahren zur Herstellung einer Holz- oder Holzfaserplatte |
-
2014
- 2014-07-04 DE DE102014009884.2A patent/DE102014009884A1/de not_active Ceased
-
2015
- 2015-07-06 PT PT15175533T patent/PT2974841T/pt unknown
- 2015-07-06 TR TR2019/01611T patent/TR201901611T4/tr unknown
- 2015-07-06 HU HUE15175533A patent/HUE042921T2/hu unknown
- 2015-07-06 EP EP15175533.7A patent/EP2974841B1/de active Active
- 2015-07-06 ES ES15175533T patent/ES2710393T3/es active Active
- 2015-07-06 PL PL15175533T patent/PL2974841T3/pl unknown
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PL2974841T3 (pl) | 2019-05-31 |
EP2974841A1 (de) | 2016-01-20 |
HUE042921T2 (hu) | 2019-07-29 |
TR201901611T4 (tr) | 2019-02-21 |
ES2710393T3 (es) | 2019-04-24 |
PT2974841T (pt) | 2019-02-13 |
DE102014009884A1 (de) | 2016-01-07 |
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