EP2971931A1 - Cryogenic fluid cylinder - Google Patents
Cryogenic fluid cylinderInfo
- Publication number
- EP2971931A1 EP2971931A1 EP14767529.2A EP14767529A EP2971931A1 EP 2971931 A1 EP2971931 A1 EP 2971931A1 EP 14767529 A EP14767529 A EP 14767529A EP 2971931 A1 EP2971931 A1 EP 2971931A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- outer vessel
- cryogenic fluid
- vessel
- fluid container
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000012530 fluid Substances 0.000 title claims abstract description 117
- 239000007788 liquid Substances 0.000 claims abstract description 36
- 238000012423 maintenance Methods 0.000 claims abstract description 16
- 238000013022 venting Methods 0.000 claims abstract 2
- 230000001681 protective effect Effects 0.000 claims description 33
- 239000000463 material Substances 0.000 claims description 18
- 229910001369 Brass Inorganic materials 0.000 claims description 4
- 239000010951 brass Substances 0.000 claims description 4
- 238000007789 sealing Methods 0.000 claims description 3
- 238000004891 communication Methods 0.000 description 23
- 239000007789 gas Substances 0.000 description 17
- 239000006200 vaporizer Substances 0.000 description 11
- 239000010935 stainless steel Substances 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 230000008901 benefit Effects 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- -1 for example Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 238000012354 overpressurization Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000009428 plumbing Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000012800 visualization Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C5/00—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures
- F17C5/02—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures for filling with liquefied gases
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C5/00—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures
- F17C5/06—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures for filling with compressed gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C1/00—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
- F17C1/12—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge with provision for thermal insulation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/02—Special adaptations of indicating, measuring, or monitoring equipment
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/02—Special adaptations of indicating, measuring, or monitoring equipment
- F17C13/021—Special adaptations of indicating, measuring, or monitoring equipment having the height as the parameter
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/02—Special adaptations of indicating, measuring, or monitoring equipment
- F17C13/025—Special adaptations of indicating, measuring, or monitoring equipment having the pressure as the parameter
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/04—Arrangement or mounting of valves
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C3/00—Vessels not under pressure
- F17C3/02—Vessels not under pressure with provision for thermal insulation
- F17C3/08—Vessels not under pressure with provision for thermal insulation by vacuum spaces, e.g. Dewar flask
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C9/00—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure
- F17C9/02—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure with change of state, e.g. vaporisation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/01—Shape
- F17C2201/0104—Shape cylindrical
- F17C2201/0109—Shape cylindrical with exteriorly curved end-piece
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/03—Orientation
- F17C2201/032—Orientation with substantially vertical main axis
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/05—Size
- F17C2201/058—Size portable (<30 l)
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/03—Thermal insulations
- F17C2203/0391—Thermal insulations by vacuum
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/03—Thermal insulations
- F17C2203/0391—Thermal insulations by vacuum
- F17C2203/0395—Getter
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
- F17C2203/0602—Wall structures; Special features thereof
- F17C2203/0612—Wall structures
- F17C2203/0626—Multiple walls
- F17C2203/0629—Two walls
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
- F17C2203/0634—Materials for walls or layers thereof
- F17C2203/0636—Metals
- F17C2203/0639—Steels
- F17C2203/0643—Stainless steels
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/01—Mounting arrangements
- F17C2205/0153—Details of mounting arrangements
- F17C2205/0157—Details of mounting arrangements for transport
- F17C2205/0165—Details of mounting arrangements for transport with handgrip
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/01—Mounting arrangements
- F17C2205/0153—Details of mounting arrangements
- F17C2205/018—Supporting feet
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0308—Protective caps
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0323—Valves
- F17C2205/0329—Valves manually actuated
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0338—Pressure regulators
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0388—Arrangement of valves, regulators, filters
- F17C2205/0394—Arrangement of valves, regulators, filters in direct contact with the pressure vessel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/01—Pure fluids
- F17C2221/011—Oxygen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/01—Pure fluids
- F17C2221/013—Carbone dioxide
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/01—Pure fluids
- F17C2221/014—Nitrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/01—Pure fluids
- F17C2221/016—Noble gases (Ar, Kr, Xe)
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0146—Two-phase
- F17C2223/0153—Liquefied gas, e.g. LPG, GPL
- F17C2223/0161—Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/03—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
- F17C2223/033—Small pressure, e.g. for liquefied gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/03—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
- F17C2223/035—High pressure (>10 bar)
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/04—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by other properties of handled fluid before transfer
- F17C2223/042—Localisation of the removal point
- F17C2223/043—Localisation of the removal point in the gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/04—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by other properties of handled fluid before transfer
- F17C2223/042—Localisation of the removal point
- F17C2223/046—Localisation of the removal point in the liquid
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
- F17C2225/01—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the phase
- F17C2225/0107—Single phase
- F17C2225/0123—Single phase gaseous, e.g. CNG, GNC
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
- F17C2225/03—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the pressure level
- F17C2225/035—High pressure, i.e. between 10 and 80 bars
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/01—Propulsion of the fluid
- F17C2227/0107—Propulsion of the fluid by pressurising the ullage
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/03—Heat exchange with the fluid
- F17C2227/0302—Heat exchange with the fluid by heating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/03—Heat exchange with the fluid
- F17C2227/0367—Localisation of heat exchange
- F17C2227/0369—Localisation of heat exchange in or on a vessel
- F17C2227/0376—Localisation of heat exchange in or on a vessel in wall contact
- F17C2227/0381—Localisation of heat exchange in or on a vessel in wall contact integrated in the wall
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
- F17C2250/03—Control means
- F17C2250/032—Control means using computers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
- F17C2250/04—Indicating or measuring of parameters as input values
- F17C2250/0404—Parameters indicated or measured
- F17C2250/0408—Level of content in the vessel
- F17C2250/0413—Level of content in the vessel with floats
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
- F17C2250/04—Indicating or measuring of parameters as input values
- F17C2250/0404—Parameters indicated or measured
- F17C2250/043—Pressure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
- F17C2250/04—Indicating or measuring of parameters as input values
- F17C2250/0486—Indicating or measuring characterised by the location
- F17C2250/0491—Parameters measured at or inside the vessel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
- F17C2250/06—Controlling or regulating of parameters as output values
- F17C2250/0605—Parameters
- F17C2250/0626—Pressure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/05—Applications for industrial use
Definitions
- the field of the present invention relates to storage vessels for cryogenic fluids, and more particularly, to vertically-oriented cylinders for holding cryogenic fluids.
- a typical cryogenic fluid storage vessel or container includes an inner tank for retaining a supply of cryogenic liquid and an outer jacket surrounding the inner tank.
- the outer jacket is spaced from, the inner tank to create an. insulation chamber there between.
- the insulation chamber typically has a vacuum created therein.
- the storage container is configured to reduce radiant and conductive heat transfer between the tanks in order to reduce vaporizatio of the cryogenic liquid stored in the inner tank.
- prior cryogenic fluid storage containers may perform in an adequate manner to store cryogenic flu ds, they are not easy to maintain in a working manner over time, can be difficult to operate, and can be difficult to move or transport. This is particularly true for vertically oriented cryogenic fluid cylinders. Accordingly, there is a need for improved cryogenic iluid containers.
- cryogenic fluid storage vessels or containers which overcome at least one of the deficiencies of the prior art.
- a cryogenic fluid container comprising, in combination, an inner vessel for holding cryogenic fluid, a cylindrically shaped outer vessel having a vertically extending central longitudinal axis and surrounding the inner vessel and forming an insulating space therebetween, and end user operating controls located on a top of the outer vessel including a liquid-use valve for selectively dispensing liquid cryogen from the inner vessel, a pressure-building valve for selectively controlling a pressure building circuit for increasing pressure within the inner vessel, a gas-use valve for selectively dispensing gaseous cryogen from the inner vessel .
- a vertically-oriented cryogenic fluid cylinder comprising, in combination, an inner vessel for holding cryogenic fluid, a cylindrically shaped outer vessel having a vertically extending central longitudinal axis and surrounding the inner vessel and forming an insulating space therebetween, operating controls located on a top of the outer vessel, and a handling ring secured to the top of the outer vessel and encircling the operating controls.
- the handling ring has at least one raised portion for providing additional access beneath the handling ring to at least some of the operating controls while protecting the operating controls.
- a cryogenic fluid container comprising, in combination, an inner vessel for holding cryogenic fluid, a cylindricaily shaped outer vessel having a vertically extending central longitudinal axis and surrounding the inner vessel and forming an insulating space therebetween, operating controls located on a top of the outer vessel including an economizer regulator having an adjustment screw for selectively setting at least one pressure level, and a protective cap covering only a portion of the adjustment screw and configured to prevent the adjustment screw from being rotated to adjust the at least one pressure level.
- a cryogenic fluid container comprising, in combination, an inner vessel for holding cryogenic fluid, a cylindricaily shaped outer vessel having a vertically extending central longitudinal axis and surrounding the inner vessel and forming an insulating space therebetween, operating controls located on a top of the outer vessel, and a pump-out port located in a wall of the outer vessel.
- the pump out port includes a base secured to the oute vessel and having a passage connecting an interior space of the outer vessel with atmosphere about the outer vessel and a plug sealing the passage and configured to be released from the passage at a predetermined pressure within the outer vessel.
- the plug comprises a material which resists galling with the base.
- a cryogenic fluid container comprising, in combination, an inner vessel for holding cryogenic fluid, a cylindricaily shaped outer vessel having a vertically extending central longitudinal axis and surrounding the inner vessel and forming an insulating space therebetween, operating controls located on a top of the outer vessel, and a vacuum gauge port assembly located in a wall of the outer vessel.
- the vacuum gauge port assembly includes a receptacle secured to the wall of outer vessel and having an interior cavity and a digital vacuum sensor secured within the interior cavity of the receptacle and having an electrical connector for removable connection of an externa! vacuum gage for indicating vacuum within the outer vessel. The sensor is exposed to vacuum within the outer vessel through an opening in the receptacle.
- FIG. 1 is a front elevational view of a vertically-oriented cryogenic fluid cylinder according to the present invention.
- FIG. 2 is a diagrammatic view of the top of the cryogenic fluid cylinder of FIG. 1 showing user controls and wherein a centra! lifting lug is remove for clarity.
- FIG. 2A is a diagrammatic view similar to FiG. 2 but showing an alternative arrangement of the user controls.
- FIG. 3 is a cross-sectionai view of the cryogenic fluid cylinder of FIGS. 1 and 2 taken along line 3-3 of FIG. 2.
- FIG. 4 is a schematic view of the plumbing of the cryogenic fluid cylinder of FIGS. 1 to.3.
- FIG. 5 is a top plan view of a manifold of the cryogenic fluid cylinder of FIGS. 1 to 4.
- FIG. 6 is a right side view of the manifold of FIG. 5.
- FIG. 7 is a perspective view of an economizer regulator of the cryogenic fluid cylinder of FIGS. 1 to 4 having a protective cap secured thereto.
- FIG. 8 is an enlarged perspective view of the economizer regulator protective cap of FIG. 7.
- FIG, 9 is a side view of the economizer regulator of FIG. 7.
- FIG. 10 is a is cross-sectional view of the economizer regulator taken along line 10-10 of FIG. 9.
- FIG. 1 1 is an enlarged fragmented view taken from FIG. 10 showing an interface between the economizer regulator and the protective cap,
- FIG. 12 is an enlarged perspective view of a top portion of the cryogenic fluid cylinder of FIGS. 1 to 4 showing an outer vessel pump-out plug and an outer vessel digital vacuum gauge assembly.
- FIG. 13 is a cross sectional view showing the outer vessel pump-out plug of FIG.12.
- FIG. 14 is a top plan view of the of the outer vessel pump-out plug of FIGS. 12 and 13.
- FIG. 15 is a cross-section view of the outer vessel pump-out plug taken along line 1.5- 35 of FIG. 14.
- FIG. 16 is a cross sectional view showing a terminal assembly of the outer vessel digital vacuum gauge assembly of FIG.12 wherein a digital reader or display has be disconnected.
- FIG, 17 is a top plan, view of a receptacle of the terminal assembly of FIG. .16.
- F G. 18 is a cross-section view of the receptacle taken along line 18-18 of FIG. 17,
- FIG. 19 is a perspective view of a vacuum sensor the terminal assembly of FIG. 16.
- FIG. 20 is a top plan view of the vacuum sensor of FIG. 19.
- FIG. 21 is a side view of the vacuum sensor of FIGS. 19 and 20.
- FIG. 22 is a plan bottom view of the vacuum sensor of FIGS. 19 to 21.
- cryogenic fluid storage containers are not necessarily to scale, presenting a somewhat simplified representation of various preferred features illustrative of the basic principles of the invention.
- the specific design features of the cryogenic fluid storage containers as disclosed herein, including, for example, specific dimensions, orientations, locations, and shapes of the various components, will be determined in part by the particular intended application and use environment. Certain features of the illustrated embodiments have been enlarged or distorted relative to others to facilitate visualization and clear understanding. In particular, thin features may be thickened, for example, for clarity or illustration. All. references to direction and position, unless otherwise indicated, refer to the orientation of the cryogenic fluid storage containers illustrated in the drawings.
- FIGS. 1 to 4 illustrate a cryogenic fluid storage container in the form of a vertically-oriented cryogenic fluid cylinder 10 according to the present invention.
- the cryogenic fluid cylinder 10 is designed for the storage and
- the illustrated cryogenic fluid cylinder 10 includes a eylindrically-shaped outer vessel or tank 12 having a vertically extending central longitudinal axis 14 perpendicular to a diameter of the outer vessel 12, an inner vessel or tank 16 located within the outer vessel 12 having a veitically extending central longitudinal axis 18 perpendicular to a diameter of the inner vessel 16 and coaxial with the longitudinal axis 14 of the outer vessel 12, a foot ring 20 secured to the bottom of the outer vessel 12, and a handling or protective ring 22 secured to the top of the outer vessel 12.
- cryogenic liquids such as, for example, liquid nitrogen, liquid oxygen, liquid argon, liquid carbon dioxide, liquid nitrous oxide, and the like.
- the illustrated cryogenic fluid cylinder 10 includes a eylindrically-shaped outer vessel or tank 12 having a vertically extending central longitudinal axis 14 perpendicular to a diameter of the outer vessel 12, an inner vessel or tank 16 located within the outer vessel 12 having a veitically extending central longitudinal axis 18 perpen
- the illustrated outer and inner vessels 12, 16 have elongate longitudinal lengths such that the lengths of the vessels 12, 16 are about 2.5 to 3.0 times larger than the diameters of the vessels 12, 16 but any other suitable size can alternatively be utilized.
- the outer and inner vessels 12, 16, the foot ring 20, and the handling ring 22 preferably comprise stainless steel but any other suitable material can alternatively be utilized.
- the inner vessel 16 has a hollow interior space 24 for containing the cryogenic fluid and is supported within the outer vessel 12 to minimize heat communication between the vessels 12, 16 while providing adequate support of the inner vessel 16.
- the illustrated inner vessel 16 is at least partially supported by a support tube 26 extending from the top of the outer vessel 12 to the top of the inner vessel 16 within the outer vessel 12 and communicating an opening 12a in the top of the outer vessel 12 with an opening 16a in the top of the inner vessel 1 , Vacuum is present in a gap or space 28 between the vessels 12, 16, Additionally, cryogenic thermal insulation and/or vacuum getters can be provided in the space 28 to assist thermally insulating the inner vessel 16.
- all operating controls 30 of the illustrated cryogenic fluid cylinder 10 are located at the top of the outer vessel 12.
- the operating controls 30 enable suppliers or maintenance personnel and customers or end users to control operations of the cryogenic fluid cylinder 10.
- a manually-operable gas-use valve 32 is located at the top of the outer vessel 12and is in communication with a vaporizer coil 34 of an economizer circuit 36 through a manifold or "kiruckle M 38 (best shown in FIGS, 5 and 6).
- the manifold 38 is located outside the outer vessel 12and is secured to the outer vessel 12at the top opening 12a.
- the manifold 38 closes and seals the opening 12a in the outer vessel 12except for the passages therein as discussed in more detail hereinafter.
- the gas-use valve 32 has an outlet and an inlet and has a manually operable turn handle to open aid close the gas-use valve 32.
- the gas-use valve 32 is opened and closed by the end users to selectively supply pressurized cryogenic gas from the cryogenic fluid cylinder 10 to an external device.
- the outlet of gas-use valve 32 is provided with a suitable fitting for attachment of a gas supply line for connecting the gas-use valve 32 with the external device to be supplied with the cryogenic gas.
- An economizer or control regulator 40 is located at the top of the outer vessel 12 for regulating the economizer circuit 36 and a pressure building circuit 42 to automatically maintain desired operating pressures within the inner vessel 12.
- the economizer regulator 40 is in fluid flow communication with an upper portion of the inner vessel 16 via a regulator port 44 of the manifold 38.
- An economizer portion 46 of the economizer regulator 40 is also in fluid flow communication with an economizer tube 48 extending to the vaporizer 50 of the economizer circuit 36 via an economizer port 52 of the manifold 38.
- economizer regulator 40 is connected to the economizer port 52 with external copper tubing 54 but any other suitable connection can alternatively be utilized.
- the economizer regulator 40 is also in fluid flow communication with a manually-operable pressure building valve 56 which is connected to the pressure building coil 58 of the pressure building circuit 42.
- the illustrated economizer regulator 40 is cormected to the pressure build valve 56 with external copper tubing 60 but any other suitable connection can alternatively be utilized.
- the economizer regulator 40 is typically adjusted by the suppliers or maintenance personnel to set an economizer pressure and a pressure building pressure.
- the illustrated economizer regulator 40 automatically sets the economizer setting a predetermined amount higher than the pressure building setting such as, for example, about 15, psig.
- the economizer regulator 40 is automatically closed and cryogenic liquid flows up the liquid tube 64 from the bottom of the inner vessel 16 to the economizer tube 48 via the manifold 38, through the vaporizer 50 within the outer vessel 12 where it is vaporized, from the vaporizer 50 to the gas-use valve 32 through the manifold 38, and through the gas-use valve 32 for delivery to the external device through the gas supply line secured between the gas-use valve 32 and the external device.
- the economizer regulator 40 automatically opens to connect the pressure building valve 56 with the head space 24a within the inner vessel 16 so that, when the pressure building valve 56 is open, cryogen . liquid flows from the bottom of the inner vessel 16 to the pressure building coil 58, through the pressure building coil 58 within the outer vessel 12 where it is vaporized, from the pressure building coil 58 to the pressure building valve 56 through the manifold 38, from the pressure building valve 56 to the economizer regulator 40, and from the economizer regulator 40 to the head space 24a with the inner vessel 16 through the manifold 38.
- the illustrated vaporizer coil 34 and pressure building coil 58 are located between the outer and inner vessels 12, 16 and attached to the inside of the outer vessel 12.
- the customer or end user closes the gas use valve 32.
- the manually-operable pressure building valve 56 is located at the top of the outer vessel 12 and can be selectively operated to isolate the economizer regulator 40 from, the pressure building coil 58,
- the pressure building valve 56 has an outlet and an inlet and has a manually operable turn handle to open and close the pressure building valve 56.
- the pressure building valve 56 is in fluid flow communication with an outlet of the pressure building coil 56 an l is in fluid flow communication with the pressure building portion 66 of the economizer regulator 40.
- the pressure building circuit 42 automatically operates as described above to raise the operating pressure within, the inner vessel 16.
- the pressure building valve 56 is closed, the pressure building circuit 42 does not operate,
- a pressure gauge 68 is located at the top of the outer vessel 12 and is in fluid flow communication with the head space 24a of the inner vessel 16 through the manifold 38.
- the pressure gauge 68 displays the current operating pressure within the inner vessel 16.
- the illustrated pressure gauge 68 is a mechanical dial gauge but it is noted that any other suitable type of pressure gauge can alternatively he utilized,
- a pressure relief device or valve 70 is located at the top of the outer vessel 12 and is in fluid flow communication with the head space 24a within the inner vessel 6 through the manifold 38.
- the pressure relief valve 70 automatically opens when the operating pressure within the inner vessel 16 reaches a predetermined maximum operating pressure. When open, the pressure relief valve 70 vents cryogenic gas from the inner vessel 16 to atmospher via the manifold 38.
- a burst device or disc 72 is also located at the top of the outer vessel 12 and is in fluid i!ow communication with the head space 24a within the inner vessel 16 through the manifold 38.
- the burst disc 72 ruptures to release excess pressure at a predetermined maximum pressure greater than the predetermined maximum pressure of the pressure release device 70 and indicating that the pressure relief device 70 failed to properly operate. When ruptured, the burst disc 72 vents cryogenic gas from the inner vessel 16 to atmosphere through the manifold 38.
- the pressure relief device 70 and the burst device 72 can be of any suitable type.
- a manually-operable liquid-use valve 74 is located at the top of the outer vessel 12 and is in fluid flow communication with the outlet of liquid withdrawal tube 64 located within the inner vessel 16 through the manifold 38.
- the liquid-use valve 74 has an outlet and an inlet and has a manually operable turn handle to open and close the liquid-use valve 74,
- the liquid- use vaSve74 is opened and closed by the customer or end user to selectively supply cryogenic liquid from the inner vessel 16 to an external device.
- the liquid-use valve is provided with a suitable fitting for attachment of a liquid supply line for connecting the liquid-use val ve 72 with the external device to be supplied with the cryogenic liquid.
- a liquid level gauge 76 is mounted at the top of the outer vessel 12 to the manifold 38 and extends into the inner vessel 16 through the manifold 38 to indicate the level of the cryogenic liquid within the inner vessel 16.
- the illustrated liquid level indicator 76 is a float or swing arm type of liquid level gauge and has a mechanical dial but it is noted that any other suitable type of liquid level gauge and/or dial can alternatively be utilized.
- a manually-operable vent valve 78 is located at the top of the outer vessel 12 and is in fluid flow communication with the inner vessel 16 through the manifold 38.
- the vent valve 78 has an outlet and an inlet and has a manually operable turn handle to open and close the vent valve 78.
- the vent valve 78 is opened and closed by maintenance personnel to control liquid filling and/or gas withdrawal.
- the vent valve 78 is provided with a suitable fitting for attachment of a transfer or vent line.
- the illustrated manifold 38 is cylindrical shaped having a planar upper surface 80, a planar lower surface 82 opposite the upper surface 80 and a circular peripheral side surface 84 connecting the upper and lower surfaces 80, 82.
- the manifold 3 is sized and shaped to be secured to the top of the outer vessel 12 and closing and sealing the opening 12a in the top of the outer vessel 12.
- the lower surface 82 is provided with a counter bore 86 for receiving the support tube 26 for the inner vessel 16.
- a main passage 88 extends through the manifold 38 from the upper surfaceSQ to the lower surface 82 within the counter bore 86 on the lower surface so that when the support tube 26 is secured between the inner vessel 16 and the manifold 38, the passage is in fluid flow communication with the head space 24a of the inner vessel 16.
- the illustrated upper surface 80 is provided with a counter bore or cavity 90 about the passage 88 as well as a plurality of spaced-apart threaded fastener openings 92 for securing the liquid level gauge 76 thereto that closes and seals the uppe end of the passage 88,
- the illustrated upper surface 80 is also provided with a plurality of spaced- apart fastener openings 94 for securing a central lifting lug 96 thereto (best shown in FIG. 1).
- the front of the illustrated manifold side surface 84 is provided with a pressure building port 98 for connection of the pressure building valve 56.
- the pressure building port 98 is connected for fluid flow communication, via an internal passage, to a pressure building coil port 100 on the lower surface 82, outside the support tube counter bore 86. for connection of the outlet of the pressure building coil 58 located within the outer vessel 16.
- Adjacent to the pressure building port 98, the front of the illustrated manifold side surface 84 is provided with a gas port 102 for connection of the gas-use valve 32.
- the gas port 102 is connected for fluid flow communication, via an internal passage, to a vaporizer outlet port 104 on the lower surface 82, outside the support tube counter bore 86, for connection of the outlet of the vaporizer coil 34 located within the outer vessel 12, Adjacent to the pressure building port 98 opposite the gas port 102, the front of the illustrated manifold side surface 84 is provided with a liquid port 106 for connection of the liquid-use valve 74.
- the liquid port 106 is connected for fluid flow communication, via an internal passage, to a withdrawal tube port 108 on the lower surface 82, within the support tube counter bore 86, for connection of the outlet of the liquid withdrawal tube 64 located within the inner vessel 16.
- the front of the illustrated manifold side surface 84 Adjacent to the liquid use port 106 opposite the pressure building port 98, the front of the illustrated manifold side surface 84 is provided with an economizer tube port 110 for connecti on of the economizer portion 46 of the economizer regulator 40.
- the economizer tube port 110 is connected for fluid flow
- the inner passage also connects the economizer tube port 110 in fluid flow communication with, the withdrawal tube port 108.
- the liquid port 106 and the withdrawal tube port 108 are each in fluid flow
- the rear of the illustrated manifold side surface 84 is provided with a pressure building regulator port 1 14 for connection of the economizer regulator 40.
- the pressure regulator port 1 14 is connected for fluid flow communication, via an. internal passage, to the main passage 88 and thus the head space 24a of the inner vessel 16.
- Adjacent to the regulator port 114, the rear of the illustrated manifold side surface 84 is provided with a vent port 1 16 for connection of the vent valve 78.
- the vent port 116 is connected for fluid flow communication, via an internal passage, to a port 118 on the lower surface, within the support tube counter bore, 86 to be in fluid flow communication with the head space 24a of the inner vessel 16.
- FIGS. 7 to 1 1 illustrate a protective cover or cap 122 secured to the economizer regulator 40, The illustrated protective cover 122 is sized and shaped to cover a head portion 124 of an adjustment screw or bolt 126 and an adjacent portion 128 of the adjustment screw 126 that is otherwise exposed outside the economizer regulator 40.
- the adjustment screw 126 is rotatabie about its longitudinal axis to selectively adjust the pressure set points of the economizer regulator 40.
- the illustrated protective cover 122 is generally cup-shaped having a planar end wall 130 and a cylindrically-shaped side wall 132 extending from the end wall 130 to form an interior space with a closed end and an open end opposed to the open end.
- the interior space is sized and shaped to receive the exposed portion of the adjustment screw of the economizer regulator therein,
- a plurality of circumferentially spaced-apart detents or protrusions are provide within the interior space that form a one-way snap lock onto the head portion 124 of the adjustment screw 126.
- the protective cover 122 can be snapped onto the screw head 124 so that it is secured thereto but cannot be removed from the head portion 124 of the adjustment screw 126 without breaking or damaging the protective cover 122.
- the head 124 of the adjustment screw 126 retains the protective cap 122 on the adj ustment screw 126. It is noted that the illustrated protective cap 122 only covers a portion of the adjustment screw 126 so that the remainder of the economizer regulator40 remains exposed for inspection.
- the illustrated protective cap 122 has a pair of longitudinally extending slots 136 on opposite sides of the side wall 132.
- the illustrated slots 136 each have a small connecting web 138 that holds the side wall 132 in its circular shape. If it is desired to remove the protective cap 122 from the adjustment screw 126. the relatively small webs 138 can be easily cut to release the protective cap 122 from the adjustment screw 126. With the webs 130 cut, the side wall 132 can be pivoted back to remove the interference between the head 124 of the adjustment screw 126 and the engagement surfaces 140 of the proieciive cap 126, The webs 138 can be easily cut with a knife, scissors, or the like. Once cut, the protective cap 122 ear. be discarded and a new one is used in its place after adjusting the adjustment screw 126. It is noted that the protective cover 122 could alternatively be configured so that it is removable with a special removal tool.
- the illustrated detents each inwardly extend from inner side of the side wall 132 within, the Interior space and have a rearward-facing planar engagement 140 surface that faces and is generally parallel with the end wall 130.
- the illustrated detents also each have an inward facing camming surface 142 that extend radially inwardly in a direction toward the end wall 1.30.
- the detents are secured to the side wail 132 toward their outer ends so that the rearward end forming the engagement surface 140 is resiliently deflectable in a radially outward direction toward the side wall 132.
- the protecti ve caps 122 are preferably molded of a plastic material providing the desired resilient deflection but can alternatively be formed of any other suitable material.
- the protective cap 122 is installed by moving the open end of the cap 122 o ver the head portion 124 of the adjustment screw 126 in the longitudinal direction.
- the detents are deflected radially outwardly so that the detents pass over the head portion 124 as the protective cap 122 continues to move in the forward direction.
- the detents resiliently snap back to their at rest (or undetected) positions. Once placed in this position, the protective cap 122 cannot be removed because the engagement surfaces 140 engage the head portion 124 to prevent further withdrawal.
- the open end of the cap 1.22 is blocked by the economizer regulator 40 so that there is not adequate access to the detents to manually defect them outwardly out of the path of the head portion 124 of the adjustment screw 126.
- the protective cover 122 is sized and shaped so that it freely rotates about. the adjustment screw 126 when secured thereto. Thus, rotation of the protective cover 122 will not rotate the adjustment screw 126.
- the illustrated protective cover 122 is installed onto the adjustment screw .126 of the economizer regulator 40 by supplier or maintenance personnel after the economizer regulator 40 has been adjusted to the desired pressure set points.
- cryogenic fluid cylinder 10 is filled with cryogenic liquid.
- the protective cover 122 With the protective cover 122 in place, end users or others cannot adjust the pressure set points because the adjustment screw 126 cannot be rotated, if the protective cover 122 is damaged or removed, it is a sign that the pressure set points may have been altered.
- the cryogenic fluid cylinder 10 is to be refilled with cryogenic fluid or other maintenance is to be performed requiring adjustment of the economizer regulator 40, the protective cap 122 is cut and removed and a new protective cap 122 is installed at the appropriate time.
- the top of the outer vessel 12 is also provided with, a pump- out or seal plug 144 and a vacuum gauge assembly 146.
- the pump-out or seal plug 144 protects the outer vessel 12 from over pressurization.
- the vacuum gauge assembly 146 provides supplier or maintenance personnel an indication of the pressure or vacuum between the outer and inner vessels 12, 16.
- the illustrated pump-out plug 144 is secured through the outer vessel 12 at the rear side of the top of the cryogenic fluid cylinder 10, As best shown in FIGS. 13 to 15, the illustrated pump-out plug 144 includes a base 148 and a plug 150.
- the illustrated base 148 is generally cylindrical shaped having a central passage 152 therethrough.
- An outer surface of the base is provided with a flange 154 having a bottom surface 156 that engages the outer surface of the outer vessel 12 when, the lower end of the base 148 is inserted into an opening 158 in the outer vessel 12.
- the illustrated base 148 is welded to the outer vessel 12 but the base 148 can alternatively be secured in any other suitable manner or formed integral with the outer vessel 12.
- the illustrated base 148 is formed of stainless steel which can be suitably welded to the stainless steel outer vessel 12 but any other suitable material can alternatively be utilized.
- An. inner surface of the base 148 is provided with an outward facing abutment 160 that is engages by the plug 150 to limit inward movement of the plug 150 through the base 148.
- the illustrated plug 150 is cylindrical shaped for receipt in the passage 152 of the base 148 with a lower end 162 of the plug 150 engaged with the abutment 160 of the base 148.
- the illustrated outer surface of the plug 150 is provided with a pair of circumferetitially extending and longitudinally spaced apart o-rings 164.
- the base 148, the plug 150, and the o-rings 164 are configured so that the plug 150 remains in the base 148 and seals the opening 158 in the outer vessel 12 over a predetermined range of pressures within the outer vessel 12 but the plug 150 is released or pushed out of the base 148 at a predetermined pressure to prevent rupture of the outer vessel 12.
- the illustrated plug 150 is formed of brass but any other suitable material can alternatively utilized.
- the illustrated plug 150 comprises brass to prevent galling between the plug 150 and the base 148. (Sailing is a problem because the metal plug 150 must slide while in tight contact with the metal base 148. Galling can occur regardless of whether the metals are the same or different. Galling is a form of wear caused by adhesion between sliding sin-faces. When a material galls, some of it is pulled with the contacting surface, especially if there is a large amount of feree compressing the surfaces together. This will generally leave some material stuck or even friction welded to the adjacent surface, while the galled material may appear gouged with balled-up or torn lumps of material stuck to its surface.
- the illustrated vacuum gauge assembly 146 is secured through the outer vessel 12 at the rear side of the top of the cryogenic fluid cylinder 10.
- the illustrated vacuum, gauge assembly 146 includes a vacuum gauge port, assembly 166 and an external vacuum gauge reader or display 168 removably securable to the vacuum gauge port assembly 166.
- the vacuum gauge port assembly 166 includes a receptacle 170 and a digital vacuum sensor 172 secured to the receptacle 170.
- the illustrated vacuum gauge port assembly 166 provides a leak tight mechanical connection and sensor feed through so that the vacuum level in the insulation chamber or space 28 betwee the outer and inner vessels 12. 16 can be checked and/or determined.
- the illustrated receptacle 170 is generally cylindrical shaped having a central passage 174 therethrough sized and shaped for receiving the sensor 172 therein.
- An end wall 176 closes the lower end of the passage 174 except for an opening 178 sized and shaped to cooperate with the sensor 172,
- the illustrated opening 178 is provided with internal pipe threads that cooperate with external threads of the sensor 172.
- the receptacle 170 is secured to the outer vessel 12 within an opening 180 in the outer vessel 12.
- the illustrated receptacle 170 is welded to the outer vessel 12 but the receptacle 170 can alternatively be secured in any other suitable manner or formed integral with the outer vessel 12,
- the illustrated receptacle 170 is formed of stainless steel which can be suitably welded to the stainless steel outer vessel 12 but any other suitable material can alternatively be utilized.
- the sensor 172 is sized and shaped for receipt within the receptacle 170 and has an externally threaded portion 182 sized and shaped for cooperation with the threaded opening 178 of the receptacle 170 to secure the sensor 172 within the receptacle 170 and to adequately seal the opening 180 in the outer vessel 12 agains leaks that would cause a loss of vacuum between the vessels 12, 16.
- a suitable hex-shaped wrenching portion 184 is provided on the sensor body so that the sensor 172 can be adequately tightened to and untightened from the receptacle 170.
- the lower end of the sensor 172 is provided with a.
- the outer end of the sensor 172 is provided with an electrical connector 190 sealed with, silicone gel encapsulation.
- the illustrated sensor 172 provides digital output signals representing the level of vacuum but the sensor 172 can alternatively be of any other suitable type.
- a removable protective cover 1 2 can be utilized to selectively close tlie upper open end of tlie receptacle 170 to prevent the entry of dirt and debris and/or to protect the sensor 172.
- a suitable plug can replace the sensor 72 within the receptacle 170 to adequately seal the threaded opening 178 in the receptacle 170.
- the external vacuum gauge reader 168 has an electrical connector 1 4 that can be selectively connected to electrical connector 190 of the vacuum, gauge sensor 172 that energizes and/or communicates with the vacuum gauge sensor 172 to display the level of vacuum within the outer vessel 12.
- the illustrated reader 168 has a digital display 196 that indicates a numerical value for the vacuum level but it is noted that alternatively any other suitable reading device can be alternatively utilized. Because the external reader 168 is removable, a single external reader 168 can be utilized with more than one cryogenic fluid cylinder 10.
- all of the operating controls 30 are located on the top of the outer vessel 12 within the handling ring 22 and are positioned so that all of the operating controls 30 that are typically operated by the customers or end users of the cryogenic fluid cylinder 30 (the liquid-use valve 74, tlie pressure building valve 56. and the gas-use valve 32) are located on the front side of the outer vessel 12 and all of the operating controls 30 that are intended for use only by the suppliers or maintenance personnel (the economizer regulator 40, the pump-out plug 144, the vacuum gauge port 146, and the vent valve 78) are located on the rear side of the cryogenic fluid cylinder 10. Configured in this manner, it is easier for the customers or end users to reach the operating controls or control devices 30 that they need to operate and it is less likely that the customers or end users will purposely or mistakenly operate an incorrect one the control devices.
- the illustrated handling ring 22 is circular when viewed from above and encircles the control devices.
- the handling ring 22 aids in protecting the cryogenic fluid cylinder 10 and particularly the control devices 30 located thereon upon unintended roll over and makes it easier to walk, roll and move the cryogenic fluid cylinder 10.
- the illustrated handling ring 22 is lobe shaped having horizontally extending side portions 198 and upwardly curved or convex front and rear portions 200 that extend higher than the side portions 1 8.
- the handling ring 22 is raised higher in the front and rear sides than it is on the lateral sides to provide better access below the handling ring 22 to the contra! devices 30 located on the top of the cryogenic fluid cylinder 10 at the front and rear sides of the cryogenic fluid cylinder 10.
- handling ring 22 has two raised portions 200
- the handling ring 22 could alternatively have a single raised portion such as, for example, a front lobe at the end user controls, or could alternatively have more than two raised portions, such as, for example, three spaced apart raised portion,
- the illustrated handling ring 22 is secured to the outer vessel 12 by a pair of ring supports 202 that space the handling ring 22 above each of valves.
- the illustrated ring supports 202 are only located at lateral sides of the outer vessel 12 and are secured to the horizontal side portions of the handling ring 22,
- the illustrated handling ring 22 is only attached on the left and right lateral sides so that there is unobstructed access to the valves 32,56, 70, 74, 78 below the handling ring 22 on the front and rear sides of the. cryogenic fluid cylinder 10.
- the handling ring 22 is sized and shaped so that the front and rear portions 200 of the handling ring 22 are high enough to provide access below the handling ring 22 so that the valves 32,56, 70, 74, 78 can be easily operated by directly reaching the valve handles under the handling ring 22 but are low enough that the handling ring 22 still adequately protects the valves 32,56, 70, 74, 78 located on the top of the cryogenic fluid cylinder 10.
- the illustrated, handling ring 22 and side supports 202 are each stainless steel and secured in place by welding but alternatively can be formed of any other suitable material and can alternatively be secured in any other suitable manner.
- the illustrated customer or end user control devices are each located entirely on the front side of the top of the outer vessel 12. Thai is, they are all located entirely within a front sector of the top of the outer vessel 12 of 180 degrees,
- the customer or end user control devices are preferabl all located entirely within the front raised or lobe portion 202 of the handli ng ring 22, which in the illustrated embodiment is a front sector of the top of the outer vessel 12 of about 140 degrees.
- the illustrated customer or end user control devices (the liquid use valve 74, the pressure building valve 56, and the gas-use valve 32) .are all located entirely within a front sector of the top of the outer vessel 12 of about 120 degrees. It is noted that the control devices 30 can extend from the manifold 38 at non-normal (that is, non-perpendicular) angles, either in the horizontally and/or vertical direction so that they can be positioned in a more desirable location for access (best shown in. FIGS. 5 and 6). In the illustrated embodiment, the gas use valve 32 and the liquid use valve 74 are each angled at acute angles (when viewed from above) to position them closer to the pressure building valve 56 ⁇
- the supplier or maintenance personnel control devices are all located entirely on the rear side of the top of the outer vessel 12, That is, they are all located entirely within a rear sector of the top of the outer vessel 12 of 180 degrees.
- the supplier or maintenance personnel control devices are preferably all located entirely within the rear raised or lobe portion 200 of the handling ring 22, which in the illustrated embodiment is a rear sector of the top of the outer vessel 12 of about 140 degrees.
- the illustrated supplier or maintenance personnel control devices are all located entirely within a rear sector of the top of the outer vessel 12 of about 120 degrees.
- the remaining illustrated control devices 30 are also located at rear side of the cryogenic fluid cylinder 10 but it is noted that they can be alternatively located at any other suitable location.
- the illustrated inner vessel pressure gauge 68 is oriented so that the dial laces forward and a pressure level can be observed from the front side of the cryogenic fluid cylinder 10.
- the illustrated inner vessel pressure relief device 70 is directed in a horizontal and generally rearward direction so that any release of cryogenic fluid is unlikely to engage anyone standing in front of the cryogenic fluid cylinder.
- the illustrated inner vessel burst valve 72 is also directed in a generally rearward direction where it is less likely that any persons will be located during normal operating conditions.
- the illustrated liquid level gauge 76 Is centrally located and oriented so that the dial faces forward and the Liquid level can be observed from the front side of the cryogenic fluid cylinder 10.
- FIG. 2A illustrated an alternative user control arrangement of the top of the cryogenic fluid cylinder 0.
- the user controls are substantially the same as described above but this arrangement shows that the user controls can have other arrangements that separate the customer or end user controls from the suppler or maintenance personnel controls.
- This arrangement also shows the inner vessel pressure relief device 70 can be oriented so thai any release of cryogenic fluid directly engages the handling ring support 202.
- the illustrated inner vessel pressure relief device 70 is directed in a horizontal and laterally outward direction and is directed directly toward the ring support 202 so that any release of cryogenic fluid directly engages the ring support 202.
- Such a configuration prevents any person located around the cryogenic fluid cylinder 10 from being directly hit by a sudden release of cryogenic fluid.
- cryogenic fluid containers of the present invention are relatively easy to use and maintain, and are an improvement over prior cryogenic fluid containers
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361799886P | 2013-03-15 | 2013-03-15 | |
US201361866062P | 2013-08-15 | 2013-08-15 | |
PCT/US2014/027413 WO2014152505A1 (en) | 2013-03-15 | 2014-03-14 | Cryogenic fluid cylinder |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2971931A1 true EP2971931A1 (en) | 2016-01-20 |
EP2971931A4 EP2971931A4 (en) | 2017-07-12 |
Family
ID=54842937
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP14767529.2A Withdrawn EP2971931A4 (en) | 2013-03-15 | 2014-03-14 | Cryogenic fluid cylinder |
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Country | Link |
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EP (1) | EP2971931A4 (en) |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3503536A (en) * | 1968-01-18 | 1970-03-31 | Air Reduction | Manipulatable cryogenic container |
US5419143A (en) * | 1992-12-22 | 1995-05-30 | International Cryogenics, Inc. | Cryogenic apparatus for sample protection in a dewar |
US6276143B1 (en) * | 2000-01-18 | 2001-08-21 | Harsco Technologies Corporation | External pressure building circuit for rapid discharge cryogenic liquid cylinder |
FR2930317B1 (en) * | 2008-04-22 | 2010-08-20 | Air Liquide | ASSEMBLY COMPRISING A FAUCET AND A PROTECTIVE HAT, BOTTLE COMPRISING SUCH AN ASSEMBLY |
-
2014
- 2014-03-14 EP EP14767529.2A patent/EP2971931A4/en not_active Withdrawn
Non-Patent Citations (1)
Title |
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See references of WO2014152505A1 * |
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EP2971931A4 (en) | 2017-07-12 |
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