EP2961273A1 - Synergic herbicide compositions - Google Patents

Synergic herbicide compositions

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Publication number
EP2961273A1
EP2961273A1 EP14706895.1A EP14706895A EP2961273A1 EP 2961273 A1 EP2961273 A1 EP 2961273A1 EP 14706895 A EP14706895 A EP 14706895A EP 2961273 A1 EP2961273 A1 EP 2961273A1
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EP
European Patent Office
Prior art keywords
genera
component
composition according
weeds
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
EP14706895.1A
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German (de)
French (fr)
Inventor
Aurélien GUICHARD
Jacques FAU
Christophe SEPULCHRE DE CONDE
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Arysta LifeScience SAS
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Arysta LifeScience SAS
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Application filed by Arysta LifeScience SAS filed Critical Arysta LifeScience SAS
Publication of EP2961273A1 publication Critical patent/EP2961273A1/en
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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2

Definitions

  • the present invention relates to herbicidal compositions. More specifically, the subject of this invention relates to a composition comprising a known compound belonging to the family of chloroacetamides, mixed with a known compound, belonging to the family of isoxazolidinones.
  • the first of these compounds is chloroacetamide called "propisochlor”: it penetrates through the underground organs of weeds during germination or at the seedling stage. On the one hand, it inhibits the synthesis of proteins and nucleic acids, on the other hand it inhibits root growth. The reduction in osmotic potential resulting from these actions causes the rapid death of weeds.
  • the second active compound of the composition according to the invention is isoxazolidinone called "clomazone"; this active agent inhibits the biosynthesis of carotenoids; the target enzyme is not clearly defined. It is a selective herbicide absorbed by the roots and shoots and translocated to the aerial organs. Weeds, which are sensitive, emerge but do not have pigmentation.
  • the clomazone molecule belongs to a group of active agents for which few cases of resistant weeds are known; for clomazone, only the resistance of a population of Loliumrigidum in Australia in 1982 is known.
  • Propisochlor has been tested on a very large number of crops; it has been found to be very interesting for many of the crops tested, particularly for maize, sunflower and rapeseed.
  • the weeds that we encounter on these crops and on which propisochlor allows an interesting control are mainly:
  • grasses Echinochloa crus-galli; Setariasp; Digitariasanguinalis, Apera spica venti; Poaannua; Sorghumhalepense;
  • Propisochlor can be applied at different key stages of the crop, ie pre-planting (with incorporation into the soil), post-sowing / pre-emergence, which is its preferred or post-emergence position. early on maize, the application of the herbicide to be carried out "around sowing” on weeds not yet emerged or at a very young stage.
  • propisochloretant absorbed by the weeds in their roots or by all underground parts for germinating seeds the effectiveness of the product is highly dependent on the soil moisture, and therefore the rains that may occur after the application, because the herbicide is absorbed via the liquid phase of the soil. Due to its root action, propisochlor has the ability to control unleavened weeds during processing; the persistence of product is estimated at 2 to 3 months depending on the type of soil and climatic conditions.
  • the product acts by inhibiting elongases and cyclization enzymes of geranyl-geranyl pyrophosphate, which lead to gibberellins.
  • Propisochlor belongs to a group relatively unaffected by resistance problems, which gives it great interest. Some rare cases of resistance to molecules of this group of herbicides have been detected, for example resistances of Echinochloa crus-gallia.u butachlor in China, butachlor and propanil in Thailand, resistance of Loliummultiflorum to flufenacet in the USA and the Loliumrigidum with metolachlor in Australia.
  • propisochlor does not control all the weeds present in the crops, so it has already been proposed to associate it with a partner, for example amicarbazone for maize or dimethenamid-P for rapeseed crops.
  • a partner for example amicarbazone for maize or dimethenamid-P for rapeseed crops.
  • Such an association has also been considered as possible in the European Patent No. EP 2 094093 without however specify for which crops and without any example to define what results could be expected from such an application
  • the present invention therefore relates to a herbicidal composition
  • a herbicidal composition comprising a component [A] and a component [B], wherein the component [A] is the known compound propisochlor of formula (I):
  • the ratio R A / B between the amount by weight of the component [A] and the amount by weight of the component [B] is in the range from 10 to 40, preferably from 20 to According to another variant, the component application amounts [A] are in the range from 500 to 2200 g / ha (ha is the abbreviation of hectare, ie 10,000 m2).
  • the application amounts of component [B] are in the range of 60 to 90 g / ha.
  • composition according to the invention may be in the form of dry powders, wettable powders, emulsifying concentrates, microemulsions, pastes, granules, water-dispersible granules, solutions, suspensions, microcapsules.
  • composition according to the invention may consist of formulation (s) already prepared (s) containing, in the desired quantities, the component [A] and the component [B]; or it can be obtained at the time of use, by mixing the relative amounts of separately formulated component [A] and component [B].
  • composition according to the invention may comprise other subsequent active ingredients such as other herbicides, antidotes, fungicides, insecticides, acaricides, fertilizers.
  • the said other herbicide (s) can be selected (s) in the following list: acifluorfen, aclonifen, AKH-7088, amicarbazone, amitrole, anilofos, azafenidine, azimsulfuron, aziprotryne, BAY MKH 6561, benazoline, benfluralin, bensulfuron, bentazone, bensfendizone, benzofenap, benzthiazuron, bifenox, balanceafos, bispyribac-sodium bromacil, bromofenoxim, butafenacil, butamifos, butenachlor, butralin, butroxydim, butylate, cafenstrole, carbetamide, chlomethoxyfen, chloramben, chlorbromuron, chlorbufam, chlorflurenol,
  • the active substances including [A] and [B] may constitute from 1 to 90% by weight, and preferably from 5 to 75% by weight, relative to the total weight of the composition.
  • the invention also relates to the use of at least one herbicidal composition as defined above for the control of weeds in agricultural crops.
  • Such use can be made for post-emergence and / or pre-emergence control of monocotyledonous and dicotyledonous weeds and / or for the treatment of agricultural crops, meadows, lawns and / or for treatment as a total herbicide in applications. pre-seeding or in the weeding of industrial zones, railways, monuments.
  • Such use may be made, in particular, for the control of plants or weeds of the following list: Abutilon theophrasti, genera Adonis, genera Ambrosia, genera Amaranthus, Amnimaius, Anagallis arvensis, genera Anthemis, Aphanesarvensis, Atriplexpatula, Bidenspilosa, Capsellabursa pastoris , Chenopodium album, Convolvulus sepium, Datura stramonium, Euphorbia genera, Fumariaofficinalis, Galeopsis tetrahit, Galinsogaciliata, Galium aparine, Geranium genera, Helianthus genera, Ipomeas genera, KochiaScoparia, Lamium genera, Linderniaprocumbens, Matricaria genera,
  • Seneciovulgaris Sesbania exaltata, Sida spinosa, Sinapisarvensis, Solanumnigrum, genera Sonchus, Stellaria media, Thlaspi arvense, genera Veronica, genera Vicia, genera Viola, genera Xanthium, Aegilops tauschii, Alisma plantago, Alopecurusmyosuroid.es, genera Apera, Avenafatua, genera Brachiaria, genera Bromus, Butomusumbellatus,
  • Cenchrusechinatus genera Commelina, Cynodondactilon, genera Cyperus, genera Digitaria, genera Echinochloa,
  • Elatinatriandra Eleocharisacicularis, Eleusin indica, Elymus repens, Eragrostispilosa, Eriochloavillosa, genera
  • Eimbristylis genera Heteranthera, genera Leptochloa, genera Lolium, genera Panicum, genera Phalaris, genera Poa, Potamogetonnodosus, Sagittariapygmaea, genera Scirpus, Setariaviridis, genera Sorghum.
  • a use according to the invention can be advantageously made for the treatment of a crop grown in the group consisting of corn, wheat, rapeseed, sunflower, sugar beet, potato, soya, carrot , celery, squash, zucchini, spinach, faba bean, beans, lupine, watermelon, poppy, pea and tobacco.
  • the invention finally relates to a method for controlling weeds in agricultural crops by applying at least one composition according to the invention.
  • clomazone is added to the solvent and stirred until completely dissolved; propisochlor is then added and stirred until a clear solution is obtained; the two emulsifiers are then added to the mixture, followed by the rapeseed oil, and the mixture is homogenized.
  • the product as well obtained is stable and does not crystallize when stored at -10 ° C for 7 days.
  • test products are made to react by spraying the products at the dosages indicated in the 1st column of Tables I to III which follow (for example 2 or 2.5 or 3 1 / ha for the product [X]). Spraying is carried out post-sowing from 10 different weeds whose names are given in the first three rows of Tables I to III (four replicates (pots or trays) per weed). These tests were carried out near Nîmes (France) under controlled conditions, with a temperature and soil moisture maintained at optimum. The efficiencies were recorded at 14, 23 and 30 days (only 8 weeds raised for 14 days, and 9 for 23 days).
  • the figures given for the untreated control correspond to the level of infestation, expressed in number of plants per m 2 .

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to a herbicide composition which includes a component [A] and a component [B], the component [A] being the known compound propisochlor and the component [B] being the known compound clomazone, and [A] + [B] being synergistic.

Description

COMPOSITIONS HERBICIDES SYNERGIQUES  SYNERGISTIC HERBICIDAL COMPOSITIONS
La présente invention concerne des compositions herbicides. Plus spécifiquement, l'objet de cette invention a trait à une composition comprenant un composé connu, appartenant à la famille deschloroacétamides , mélangé avec un composé connu, appartenant à la famille des isoxazolidinones . The present invention relates to herbicidal compositions. More specifically, the subject of this invention relates to a composition comprising a known compound belonging to the family of chloroacetamides, mixed with a known compound, belonging to the family of isoxazolidinones.
Le premier de ces composés est lechloroacétamide appelé« propisochlor » : il pénètre par les organes souterrains des mauvaises herbes en cours de germination ou au stade plantule . D'une part, il inhibe la synthèse de protéines et d'acides nucléiques, d'autre part il inhibe la croissance des racines. La réduction du potentiel osmotique résultant de ces actions cause la mort rapide des mauvaises herbes.  The first of these compounds is chloroacetamide called "propisochlor": it penetrates through the underground organs of weeds during germination or at the seedling stage. On the one hand, it inhibits the synthesis of proteins and nucleic acids, on the other hand it inhibits root growth. The reduction in osmotic potential resulting from these actions causes the rapid death of weeds.
Le deuxième composé actif de la composition selon l'invention est 1 ' isoxazolidinone appelée« clomazone » ; cet agent actif inhibe la biosynthèse des caroténoïdes ; l'enzyme cible n'est pas clairement défini. Il s'agit d'un herbicide sélectif absorbé par les racines et les pousses et transloqué vers les organes aériens. Les mauvaises herbes, qui y sont sensibles, émergent mais ne comportent pas de pigmentation. La molécule clomazone appartient à un groupe d'agents actifs pour lequel on connaît peu de cas de mauvaises herbes résistantes ; pour la clomazone, on ne connaît que la résistance d'une population de Loliumrigidum, en Australie en 1982.  The second active compound of the composition according to the invention is isoxazolidinone called "clomazone"; this active agent inhibits the biosynthesis of carotenoids; the target enzyme is not clearly defined. It is a selective herbicide absorbed by the roots and shoots and translocated to the aerial organs. Weeds, which are sensitive, emerge but do not have pigmentation. The clomazone molecule belongs to a group of active agents for which few cases of resistant weeds are known; for clomazone, only the resistance of a population of Loliumrigidum in Australia in 1982 is known.
Le propisochlor a été testé sur un nombre de cultures très important ; on a constaté qu'il était très intéressant pour un grand nombre des cultures testées, notamment pour le maïs, le tournesol et le colza. Les adventices que l'on rencontre sur ces cultures et sur lesquelles le propisochlor permet un contrôle intéressant sont principalement :  Propisochlor has been tested on a very large number of crops; it has been found to be very interesting for many of the crops tested, particularly for maize, sunflower and rapeseed. The weeds that we encounter on these crops and on which propisochlor allows an interesting control are mainly:
-des graminées : Echinochloa crus- galli ; Setariasp ; Digitariasanguinalis ;Apera spica venti ; Poaannua ; Sorghumhalepense ;  grasses: Echinochloa crus-galli; Setariasp; Digitariasanguinalis, Apera spica venti; Poaannua; Sorghumhalepense;
-des dicotylédones : Capsella Bursa Pastoris ; A aranthusretroflexus ; Chenopodiumspp ; Matricariaspp ; Galium Aparine . Le propisochlor peut s'appliquer à différents stades- clés de la culture, à savoir, en pré-semis (avec une incorporation dans le sol) , en post-semis/pré-levée, qui est son positionnement préférentiel ou en post-levée précoce notamment sur le maïs, l'application de l'herbicide devant se réaliser « autour du semis » sur les adventices non encore levées ou à un stade très jeune. broadleaf weeds: Capsella Bursa Pastoris; A aranthusretroflexus; Chenopodiumspp; Matricariaspp; Galium Aparine. Propisochlor can be applied at different key stages of the crop, ie pre-planting (with incorporation into the soil), post-sowing / pre-emergence, which is its preferred or post-emergence position. early on maize, the application of the herbicide to be carried out "around sowing" on weeds not yet emerged or at a very young stage.
Le propisochlorétant absorbé par les mauvaises herbes au niveau de leurs racines ou par toutes les parties souterraines pour les graines en cours de germination, l'efficacité du produit est très dépendante de l'humidité du sol, et donc des pluies pouvant survenir après l'application, car l'herbicide est absorbé via la phase liquide du sol. En raison de son action racinaire, le propisochlor a la capacité de contrôler des adventices non levées lors du traitement ; la persistance de produit est estimée à 2 à 3 mois en fonction du type de sol et des conditions climatiques. Une fois dans la plante, le produit agit par inhibition des élongases et des enzymes de cyclisation du géranyl-géranyl pyrophosphate, qui conduisent aux gibbérellines .  The propisochloretant absorbed by the weeds in their roots or by all underground parts for germinating seeds, the effectiveness of the product is highly dependent on the soil moisture, and therefore the rains that may occur after the application, because the herbicide is absorbed via the liquid phase of the soil. Due to its root action, propisochlor has the ability to control unleavened weeds during processing; the persistence of product is estimated at 2 to 3 months depending on the type of soil and climatic conditions. Once in the plant, the product acts by inhibiting elongases and cyclization enzymes of geranyl-geranyl pyrophosphate, which lead to gibberellins.
Le propisochlor appartient à un groupe relativement épargné par les problèmes de résistance, ce qui lui confère un grand intérêt. Quelques rares cas de résistance à des molécules de ce groupe d'herbicides ont été détectés, par exemple résistances d' Echinochloa crus-gallia.u butachlore en Chine, au butachlore et au propanil en Thaïlande, résistance du Loliummultiflorum au flufénacet aux USA et du Loliumrigidum au métolachlore en Australie.  Propisochlor belongs to a group relatively unaffected by resistance problems, which gives it great interest. Some rare cases of resistance to molecules of this group of herbicides have been detected, for example resistances of Echinochloa crus-gallia.u butachlor in China, butachlor and propanil in Thailand, resistance of Loliummultiflorum to flufenacet in the USA and the Loliumrigidum with metolachlor in Australia.
Néanmoins, le propisochlor ne contrôle pas toutes les mauvaises herbes présentes dans les cultures, de sorte que l'on a déjà proposé de l'associer à un partenaire, par exemple 1 ' amicarbazone pour les cultures de maïs ou le diméthenamide-P pour des cultures de colza. Une telle association a d'ailleurs aussi été envisagée comme possible dans le brevet européen n° EP 2 094093 sans toutefois aucunement préciser pour quelles cultures et sans qu'aucun exemple ne permette de définir quels résultats on pouvait attendre d'une telle application simultanée .Dans l'état de la technique, on n'a jamais proposé l'utilisation de propisochlor et de clomazone indépendamment de tout autre agent herbicide. Nevertheless, propisochlor does not control all the weeds present in the crops, so it has already been proposed to associate it with a partner, for example amicarbazone for maize or dimethenamid-P for rapeseed crops. Such an association has also been considered as possible in the European Patent No. EP 2 094093 without however specify for which crops and without any example to define what results could be expected from such an application In the state of the art, it has never been proposed to use propisochlor and clomazone independently of any other herbicidal agent.
Or, la société déposante vient de constater que l'utilisation, sur une même culture de propisochlor et de clomazone, permettait de bénéficier d'une synergie d'effets connus et constatés pour ces deux herbicides, synergie d'où il résulte que, pour un même résultat, les quantités d'herbicides à mettre en œuvre sont plus faibles que celles qu'on aurait pu prévoir à partir des effets de chacun de deux herbicides pris isolément .  However, the applicant company has just found that the use, on the same crop of propisochlor and clomazone, allowed to benefit from a synergy of known and observed effects for these two herbicides, synergy from which it follows that, for the same result, the quantities of herbicides to be used are lower than those that could have been predicted from the effects of each of two herbicides taken in isolation.
La présente invention concerne donc une composition herbicide comprenant une composant [A] et un composant [B] , où le composant [A] est le composé connu propisochlor de formule (I) :  The present invention therefore relates to a herbicidal composition comprising a component [A] and a component [B], wherein the component [A] is the known compound propisochlor of formula (I):
(I) et le composant [B] est le composé connu clomazone de formule (II)  (I) and component [B] is the known compound clomazone of formula (II)
( n ;  ( not ;
Selon une variante, dans la composition selon l'invention, le rapport R=A/B entre la quantité en poids du composant [A] et la quantité en poids du composant [B] est compris dans la plage allant de 10 à 40, de préférence de 20 à Selon une autre variante, les quantités d'application de composant [A] sont dans la plage allant de 500à 2200 g/ha (ha est l'abréviation d'hectare à savoir 10 000 m2) . According to one variant, in the composition according to the invention, the ratio R = A / B between the amount by weight of the component [A] and the amount by weight of the component [B] is in the range from 10 to 40, preferably from 20 to According to another variant, the component application amounts [A] are in the range from 500 to 2200 g / ha (ha is the abbreviation of hectare, ie 10,000 m2).
Selon une autre variante, les quantités d'application du composant [B] sont dans la plage allant de 60 à 90 g/ha.  According to another variant, the application amounts of component [B] are in the range of 60 to 90 g / ha.
La composition selon l'invention peut se présenter sous le forme de poudres sèches, poudres mouillables, concentrés émulsifiants, microémulsions , pâtes, granulés, granulés dispersibles dans l'eau, solutions, suspensions, microcapsules .  The composition according to the invention may be in the form of dry powders, wettable powders, emulsifying concentrates, microemulsions, pastes, granules, water-dispersible granules, solutions, suspensions, microcapsules.
La composition selon l'invention peut se composer de formulation (s) déjà préparée (s) contenant, dans les quantités désirées, le composant [A] et le composant [B] ; ou elle peut être obtenue au moment de l'utilisation, en mélangeant les quantités relatives du composant [A] et du composant [B] formulées séparément .  The composition according to the invention may consist of formulation (s) already prepared (s) containing, in the desired quantities, the component [A] and the component [B]; or it can be obtained at the time of use, by mixing the relative amounts of separately formulated component [A] and component [B].
La composition selon l'invention peut comprendre d'autres ingrédients actifs ultérieurs tels que d'autres herbicides, antidotes, fongicides, insecticides, acaricides, fertilisants .  The composition according to the invention may comprise other subsequent active ingredients such as other herbicides, antidotes, fungicides, insecticides, acaricides, fertilizers.
Lorsque la composition selon l'invention comprend au moins un herbicide autre que les composés [A] ou [B] , le (s) dit (s) autre (s) herbicide (s) peu(ven)t être sélectionné (s) dans la liste suivante : acifluorfen, aclonifen, AKH-7088, amicarbazone , amitrole, anilofos, azafenidin, azimsulfuron, aziprotryne, BAY MKH 6561, bénazoline, benfluralin, bensulfuron, bentazone , bensfendizone, benzofenap, benzthiazuron, bifénox, bilanafos, bispyribac- sodium, bromacil, bromofenoxim, butafenacil, butamifos, butenachlor, butralin, butroxydim, butylate, cafenstrole, carbétamide, chlomethoxyfen, chloramben, chlorbromuron, chlorbufam, chlorflurenol , chloridazon, chlorimuron, chlornitrofen, chloroxuron, chlorpropham, chlorthal, chlorthiamide , cinidon éthyle, cinmétylein, cinosulfuron, clethodim, clodinafop, clomeprop, cloransulam- méthyle, cumyluron (JC-940) , cyanazine, cycloate, cyclosuifamuron, cycloxydim, cyhalo- fop-butyl , 2,4-DB, daimuron, dalapon, desmedipham, desmétryne, dichlobenil , dichlorprop, dichlorprop- P, diclofop, diclosulam, diethatyll, difenoxuron, difenzoquat, diflufenzopyr, dimefuron, dimepiperate , dimethachlor, di-methametryn, dinitramine, dinoseb, dinoseb acétate, dinoterb, diphenamid, dipropetryn, diquat, dithiopyr, 1-eglinazine, endothal, EPTC, esprocarb, ethalfluralin, ethametsulfuron-méthyle, ethidimuron, ethiozin (SMY 1500), ethofumesate, ethoxyfen-éthyle (HC-252), ethoxysulfuron, etobenzanid (HW 52) , fenoxaprop, fenoxaprop-P, fenuron, flamprop, flamprop-M, flazasulfuron, florasulam, fluazazifop, fluaziifop-P, fluazolate (JV 485) , flucarbazone- sodium, fluchloralin, flufenpyr éthyle, flumetsulam, flumiclorac-pentyl , flumioxazine , flumipropin, fluometuron, fluoroglycofen, fluoronitrofenflupoxam, flupropanate , flupyrsulfuron, flurenol, fluridone, flurochloridone , flurtamone, fluthiacet-méthyle, fomesafen, foramsulfuron, fosamine, furyloxyfen, haloxyfop, haloxyfop- P-méthyle , hexazinone, imazamethabenz , imazapyr, imazaquin, imazosulfuron, indanofan, iodosulfuron, isopropalin, isouron, isoxaben, isoxachlortole, isoxapyrifop, KPP-421, lenacil, LS830556, MCPB, metamitron, metazachlor, methabenzthiazuron, methazole, methoprotryne, méthyledymron, metobenzuron, metobromuron, metosulam, metoxuron, molinate, monalide, monolinuron, naproanilide, napropamide, naptalam, NC-330, neburon, nicosulfuron, nipyraclofen, norflurazon, orbencarb, oryzalin, oxadiargyl, oxasulfuron, oxaziclomefone , oxyfluorfen, pebulate, pentanochlor, pentoxazone, phenmedipham, piperophos, primisulfuron, prodiamine, profluazol, proglinazine, prométon, propaquizafop, propazine, propham, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyrazogyl (HSA-961) , pyrazolynate , pyrazoxyfen, pyribenzoxim, pyributicarb, pyridafol, pyridate, pyriftalid, pyriminobac- méthyle, pyrithiobac-sodium, quinmerac, quizalofop, quizalofop-P, rimsulfuron, sethoxydim, siduron, simetryn, sulfometuron-méthyle, 2,3,6-TBA, TCA- sodium, tebutam, tebuthiuron, tepraloxydim, terbacil, terbumeton, terbutryn, thenylchlor, thiazafluron, thiazopyr, thidiazimin, thiobencarb, tiocarbazil, tioclorim, tralkoxydim, triallate, traiziflam, trietazine, triflusulfuron-méthyle, tritosulfuron, UBI-C4874, vernolate, mesotrione, sulcotrione, tembotrione, s- metolachlore , acetochlore , pethoxamide, dimethenamid-p, flufenacet, pretilachlore, thiencarbazone, isoproturon, chortoluron, terbuthylazine , metribuzine, isoxaflutole , pendimethaline, diflufenicanil , beflubutamide , When the composition according to the invention comprises at least one herbicide other than the compounds [A] or [B], the said other herbicide (s) can be selected (s) in the following list: acifluorfen, aclonifen, AKH-7088, amicarbazone, amitrole, anilofos, azafenidine, azimsulfuron, aziprotryne, BAY MKH 6561, benazoline, benfluralin, bensulfuron, bentazone, bensfendizone, benzofenap, benzthiazuron, bifenox, balanceafos, bispyribac-sodium bromacil, bromofenoxim, butafenacil, butamifos, butenachlor, butralin, butroxydim, butylate, cafenstrole, carbetamide, chlomethoxyfen, chloramben, chlorbromuron, chlorbufam, chlorflurenol, chloridazon, chlorimuron, chlornitrofen, chloroxuron, chlorpropham, chlorthal, chlorthiamide, cinidon ethyl, cinmetylin, cinosulfuron, clethodim, clodinafop, clomeprop, cloransulam-methyl, cumyluron (JC-940), cyanazine, cycloate, cyclosuifamuron, cycloxydim, cyhalofop-butyl, 2,4-DB, daimuron, dalapon, desmedipham, desmeryl, dichlobenil, dichlorprop, dichlorprop-P, diclofop, diclosulam, diethatyll, difenoxuron, difenzoquat, diflufenzopyr, dimefuron, dimepiperate, dimethachlor, di-methametryn, dinitramine, dinoseb, dinoseb acetate, dinoterb, diphenamid, dipropetryn , diquat, dithiopyr, 1-eglinazine, endothal, EPTC, esprocarb, ethalfluralin, ethametsulfuron-methyl, ethidimuron, ethiozin (SMY 1500), ethofumesate, ethoxyfen-ethyl (HC-252), ethoxysulfuron, andobenzanid (HW 52), fenoxaprop, fenoxaprop-P, fenuron, flamprop, flamprop-M, flazasulfuron, florasulam, fluazazifop, fluaziifop-P, fluazolate (JV 485), flucarbazone-sodium, fluchloralin, flufenpyr ethyl, flumetsulam, flumiclorac-pentyl, flumioxazin, flumipropin, fluometuron, fluoroglycofen fluoronitrofenflupoxam, flupropanate, flupyrsulfuron, flurenol, fluridone, flurochloridone, flurtamone, fluthiacet-methyl, fomesafen, foramsulfuron, fosamine, furyloxyfen, haloxyfop, haloxyfop-P-methyl, h exazinone, imazamethabenz, imazapyr, imazaquin, imazosulfuron, indanofan, iodosulfuron, isopropalin, isouron, isoxaben, isoxachlortole, isoxapyrifop, KPP-421, lenacil, LS830556, MCPB, metamitron, metazachlor, methabenzthiazuron, methazole, methoprotryne, methyledymron, metobenzuron, metobromuron, metosulam, metoxuron, molinate, monalide, monolinuron, naproanilide, napropamide, naptalam, NC-330, neburon, nicosulfuron, nipyraclofen, norflurazon, orbencarb, oryzalin, oxadiargyl, oxasulfuron, oxaziclomefone, oxyfluorfen, pebulate, pentanochlor, pentoxazone, phenmedipham, piperophos, primisulfuron, prodiamine, profluazol, proglinazine, promethon, propaquizafop, propazine, propham, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyrazogyl (HSA-961), pyrazolynate, pyrazoxyfen, pyrimenzoxim, pyrriaficarb, pyridafol, pyridate, pyrimidalid, pyrimidobac-methyl, pyrithiobac sodium, quinmerac, quizalofop, quizalofop-P, rimsulfuron, sethoxydim, siduron, simetryn, sulfometuron-methyl, 2, 3,6-TBA, TCA-sodium, tebutam, tebuthiuron, tepraloxydim, terbacil, terbumeton, terbutryn, thenylchlor, thiazafluron, thiazopyr, thidiazimin, thiobencarb, tiocarbazil, tioclorim, tralkoxydim, triallate, traiziflam, trietazine, triflusulfuron-methyl, tritosulfuron, UBI-C4874, vernolate, mesotrione, sulcotrione, tembotrione, s-metolachlor, acetochlor, pethoxamide, dimethenamid-p, flufenacet, pretilachlor, thiencarbazone, isoproturon, chortoluron, terbuthylazine, metribuzine, isoxaflutole, pendimethalin, diflufenicanil, beflubutamide,
Dans la composition selon l'invention, les substances actives, y compris [A] et [B] , peuvent constituer de 1 à 90% en poids, et de préférence de 5 à 75% en poids, par rapport au poids total de la composition.  In the composition according to the invention, the active substances, including [A] and [B], may constitute from 1 to 90% by weight, and preferably from 5 to 75% by weight, relative to the total weight of the composition.
L'invention a également pour objet l'utilisation d'au moins une composition herbicide telle que ci-dessus définie pour le contrôle de mauvaises herbes dans des cultures agricoles. Une telle utilisation peut être faite pour le contrôle en post-émergence et/ou pré-émergence de mauvaises herbes monocotylédones et dicotylédones et/ou pour le traitement de cultures agricoles, prés, pelouses et/ou pour un traitement comme herbicide total dans des applications de pré- ensemencement ou dans le désherbage de zones industrielles, voies de chemin de fer, monuments.  The invention also relates to the use of at least one herbicidal composition as defined above for the control of weeds in agricultural crops. Such use can be made for post-emergence and / or pre-emergence control of monocotyledonous and dicotyledonous weeds and / or for the treatment of agricultural crops, meadows, lawns and / or for treatment as a total herbicide in applications. pre-seeding or in the weeding of industrial zones, railways, monuments.
Une telle utilisation peut être faite, notamment, pour le contrôle des végétaux ou adventices de la liste suivante : Abutilon theophrasti, genres Adonis, genres Ambrosia, genres Amaranthus, Amnimaius, Anagallis arvensis, genres Anthémis, Aphanesarvensis, Atriplexpatula, Bidenspilosa, Capsellabursa- pastoris, Chenopodium album, Convolvulus sepium, Datura stramonium, genres Euphorbia, Fumariaofficinalis, Galeopsis tetrahit, Galinsogaciliata, Galium aparine, genres Géranium, genres Helianthus, genres Ipomeas, KochiaScoparia, genres Lamium, Linderniaprocumbens, genres Matricaria, Such use may be made, in particular, for the control of plants or weeds of the following list: Abutilon theophrasti, genera Adonis, genera Ambrosia, genera Amaranthus, Amnimaius, Anagallis arvensis, genera Anthemis, Aphanesarvensis, Atriplexpatula, Bidenspilosa, Capsellabursa pastoris , Chenopodium album, Convolvulus sepium, Datura stramonium, Euphorbia genera, Fumariaofficinalis, Galeopsis tetrahit, Galinsogaciliata, Galium aparine, Geranium genera, Helianthus genera, Ipomeas genera, KochiaScoparia, Lamium genera, Linderniaprocumbens, Matricaria genera,
Monochoriavaginalis, Myosotis arvensis, Papaver rhoeas, Phaseolus aureus, genres Polygonum, Portulacaoleracea, Raphanusraphanistrum, Rotalaindica, Rumex crispus,Monochoriavaginalis, Myosotis arvensis, Papaver rhoeas, Phaseolus aureus, Polygonum genera, Portulacaoleracea, Raphanusraphanistrum, Rotalaindica, Rumex crispus,
Seneciovulgaris, Sesbania exaltata, Sida spinosa, Sinapisarvensis, Solanumnigrum, genres Sonchus, Stellaria média, Thlaspi arvense, genres Veronica, genres Vicia, genres Viola, genres Xanthium, Aegilops tauschii, Alisma plantago, Alopecurusmyosuroid.es, genres Apera, Avenafatua, genres Brachiaria, genres Bromus, Butomusumbellatus,Seneciovulgaris, Sesbania exaltata, Sida spinosa, Sinapisarvensis, Solanumnigrum, genera Sonchus, Stellaria media, Thlaspi arvense, genera Veronica, genera Vicia, genera Viola, genera Xanthium, Aegilops tauschii, Alisma plantago, Alopecurusmyosuroid.es, genera Apera, Avenafatua, genera Brachiaria, genera Bromus, Butomusumbellatus,
Cenchrusechinatus, genres Commelina, Cynodondactilon, genres Cyperus, genres Digitaria, genres Echinochloa,Cenchrusechinatus, genera Commelina, Cynodondactilon, genera Cyperus, genera Digitaria, genera Echinochloa,
Elatinatriandra, Eleocharisacicularis, Eleusine indica, Elymus repens, Eragrostispilosa, Eriochloavillosa, genresElatinatriandra, Eleocharisacicularis, Eleusin indica, Elymus repens, Eragrostispilosa, Eriochloavillosa, genera
Eimbristylis, genres Heteranthera, genres Leptochloa, genres Lolium, genres Panicum, genres Phalaris, genres Poa, Potamogetonnodosus, Sagittariapygmaea, genres Scirpus, Setariaviridis, genres Sorghum. Eimbristylis, genera Heteranthera, genera Leptochloa, genera Lolium, genera Panicum, genera Phalaris, genera Poa, Potamogetonnodosus, Sagittariapygmaea, genera Scirpus, Setariaviridis, genera Sorghum.
Une utilisation selon l'invention peut être faite avantageusement pour le traitement d'une culture prise dans le groupe formé par le maïs, le blé, le colza, le tournesol, la betterave à sucre, la pomme de terre, le soja, la carotte, le céleri, la courge, la courgette, l'épinard, la féverole, le haricot, le lupin, la pastèque, le pavot oeillette, le pois et le tabac.  A use according to the invention can be advantageously made for the treatment of a crop grown in the group consisting of corn, wheat, rapeseed, sunflower, sugar beet, potato, soya, carrot , celery, squash, zucchini, spinach, faba bean, beans, lupine, watermelon, poppy, pea and tobacco.
L'invention a enfin pour objet un procédé pour le contrôle de mauvaises herbes dans des cultures agricoles par application d'au moins une composition selon l'invention.  The invention finally relates to a method for controlling weeds in agricultural crops by applying at least one composition according to the invention.
A titre d'exemple, on donne ci-après la formulation d'une composition selon l'invention permettant de constater l'existence d'une synergie entre les composants [A] et [B] .  By way of example, the formulation of a composition according to the invention is given below, making it possible to ascertain the existence of a synergy between the components [A] and [B].
Propisochlor (A) 720 g  Propisochlor (A) 720 g
Clomazone (B) 30 g  Clomazone (B) 30 g
Emulsifiantcalsogen EH 60 g  Emulsifiercalsogen EH 60 g
EmulsifiantEmulsogen EL360 60 g  EmulsifierEmulsogen EL360 60 g
SolvantSolvesso 150 ND 100 g  Solvent Solvesso 150 ND 100 g
Huile de colza Phytorob PHT qsp 1 litre  Phytorob PHT rapeseed oil qs 1 liter
Pour obtenir le produit prêt à épandre en culture on procède comme suit : on ajoute la clomazone au solvant et on agite jusqu'à dissolution complète ; on ajoute ensuite le propisochlor et on agite jusqu'à obtention d'une solution limpide ; on ajoute alors au mélange les deux émulsionnants puis l'huile de colza et l'on homogénéise. Le produit ainsi obtenu est stable et ne cristallise pas quand il est conservé à -10°C pendant 7 jours. In order to obtain the crop-ready product, proceed as follows: clomazone is added to the solvent and stirred until completely dissolved; propisochlor is then added and stirred until a clear solution is obtained; the two emulsifiers are then added to the mixture, followed by the rapeseed oil, and the mixture is homogenized. The product as well obtained is stable and does not crystallize when stored at -10 ° C for 7 days.
Pour établir l'existence de la synergie [A] + [B] , on utilise la formulation ci-dessus indiquée que l'on désigne par [X] pour la description du test effectué mais dont le nom de code pour le test est ALS10HPPC.  To establish the existence of the synergy [A] + [B], the above formulation indicated by [X] is used for the description of the test carried out but whose code name for the test is ALS10HPPC. .
Comme indiqué ci-dessus, on doit comparer l'efficacité de [X] avec celle des deux composants [A] et [B] . Pour le test, le nom de code de [A] est ALS7HPPS et celui de [B] est Centium 36CS.  As indicated above, the efficiency of [X] must be compared with that of the two components [A] and [B]. For the test, the code name of [A] is ALS7HPPS and that of [B] is Centium 36CS.
On fait agir les produits testés en pulvérisant les produits aux dosages indiqués dans la 1ère colonne des tableaux I à III qui suivent (par exemple 2 ou 2,5 ou 3 1/ha pour le produit [X] ) . Les pulvérisations sont effectuées en post-semis-prélevée sur 10 adventices différentes dont les noms sont donnés dans les trois premières lignes des tableaux I à III (quatre répétitions (pots ou barquettes) par adventice) . Ces tests ont été effectués près de Nîmes (France) en conditions contrôlées, avec une température et une humidité du sol maintenues à l'optimum. Les efficacités ont été relevées à 14, 23 et 30 jours (seulement 8 adventices levées pour 14 jours, et 9 pour 23 jours) . The test products are made to react by spraying the products at the dosages indicated in the 1st column of Tables I to III which follow (for example 2 or 2.5 or 3 1 / ha for the product [X]). Spraying is carried out post-sowing from 10 different weeds whose names are given in the first three rows of Tables I to III (four replicates (pots or trays) per weed). These tests were carried out near Nîmes (France) under controlled conditions, with a temperature and soil moisture maintained at optimum. The efficiencies were recorded at 14, 23 and 30 days (only 8 weeds raised for 14 days, and 9 for 23 days).
Résultats à 14 jours après application : TABLEAU I Results at 14 days after application: TABLE I
Les chiffres indiqués pour le témoin non traité (modalité 1) correspondent au niveau d' infestation, exprimé en nombre de plantes par m2. The figures given for the untreated control (modality 1) correspond to the level of infestation, expressed in number of plants per m 2 .
Les chiffres indiqués pour les modalités traitées (2 à 10) sont donnés en % d'efficacité par rapport au témoin non traité.  The figures indicated for the modalities treated (2 to 10) are given in% of effectiveness compared to the untreated control.
Les efficacités calculées avec la formule de Colby (bas du tableau) sont à comparer avec les efficacités observées avec [X] . Les valeurs indiquées en italique avec [X] dans les 3 tableaux permettent de conclure à une synergie au sein de cette formulation. The efficiencies calculated with the Colby formula (bottom of the table) are to be compared with the efficiencies observed with [X]. The values indicated in italics with [X] in the 3 tables allow to conclude to a synergy within this formulation.
Résultats à 23 jours après application : TABLEAU II Results 23 days after application: TABLE II
Les résultats obtenus sur l'adventice « Tabouret des champs » ne peuvent pas être interprétés, car le niveau d' infestation est trop bas (seulement 0.3 plantes/m2 en moyenne sur les 4 répétitions) . The results obtained on the "Stinkweed" weed can not be interpreted because the level of infestation is too low (only 0.3 plants / m 2 on average over the 4 repetitions).
Résultats à 30 jours après application : TABLEAU III Results at 30 days after application: TABLE III
Les résultats de ce test permettent donc de montrer une synergie au sein de la formulation [A] + [B] : The results of this test therefore make it possible to show a synergy within the formulation [A] + [B]:
Très légère sur « Ray-grass italien » à 2.5 à 3.0 1/ha à la dernière notation.  Very light on "Italian ryegrass" at 2.5 to 3.0 1 / ha at the last log.
Légère sur « Véronique des champs » de 2.0 à 3.0 1/ha, mais continue, dès 14 jours après application et jusqu'à 30 j ours .  Light on "Veronique des champs" from 2.0 to 3.0 1 / ha, but continuous, from 14 days after application and up to 30 days.
Forte sur « Gaillet gratteron » à la dernière notation, à 2.0 et 2.5 1/ha. La synergie est sans doute présente à 3.0 1/ha également, mais une valeur surprenante sur la 4e répétition (efficacité anormalement basse par rapport aux 3 autres répétitions) avec le produit [A] + [B] fait baisser sa moyenne .  Strong on "Cleavers" at last log, at 2.0 and 2.5 1 / ha. The synergy is probably present at 3.0 1 / ha also, but a surprising value on the 4th repetition (abnormally low efficiency compared to the 3 other repetitions) with the product [A] + [B] lowers its average.
Très forte sur « Chénopode blanc » et « Renouée liseron » de 2.0 à 3.0 1/ha, et ce sur toute la durée du test.  Very strong on "Lamb's quarters" and "Wild buckwheat" from 2.0 to 3.0 1 / ha, and this throughout the test.

Claims

REVENDICATIONS
1. Composition herbicide comprenant un composant [A] et un composant [B] , où le composant [A] est le composé connu propisochlor de formule (I) : A herbicidal composition comprising a component [A] and a component [B], wherein the component [A] is the known compound propisochlor of formula (I):
( i : et le composant [B] est le composé connu clomazone formule (II) :  (i: and the component [B] is the known compound clomazone formula (II):
(II) les quantités d'application de composant [A] étant dans la plage allant de 500 à 2200 g/ha etles quantités d'application du composant [B] étant dans la plage allant de 60 à 90 g/ha.  (II) the component application amounts [A] being in the range of 500 to 2200 g / ha and the application amounts of the component [B] being in the range of 60 to 90 g / ha.
2. Composition selon la revendication 1, caractérisée en ce que le rapport R=A/B entre la quantité enpoids du composant [A] et la quantité en poids du composant [B] est compris dans la plage allant de 10 à 40, de préférence de 20 à 30.  2. Composition according to claim 1, characterized in that the ratio R = A / B between the weight amount of the component [A] and the amount by weight of the component [B] is in the range from 10 to 40, of preferably from 20 to 30.
3. Composition selon l'une des revendications 1 ou 2 , caractérisée en ce qu'elle se présente sous la forme de poudres sèches, poudres mouillables, concentrés émulsifiants, microémulsions, pâtes, granulés, granulés dispersibles dans l'eau, solutions, suspensions, microcapsules. 3. Composition according to one of claims 1 or 2, characterized in that it is in the form of dry powders, wettable powders, emulsifying concentrates, microemulsions, pastes, granules, granules dispersible in water, solutions, suspensions , microcapsules.
4. Composition selon l'une des revendications 1 à 3, caractérisée en ce qu'elle se compose de formulation (s) déjà préparées (s) contenant, dans les quantités désirées, le composant [A] et le composant [B] ; ou elle est obtenue au moment de l'utilisation, en mélangeant les quantités relatives du composant [A] et du composant [B] formulées séparément. 4. Composition according to one of claims 1 to 3, characterized in that it consists of formulation (s) already prepared (s) containing, in the desired quantities, the component [A] and the component [B]; or it is obtained at the time of use, by mixing the relative amounts of component [A] and component [B] formulated separately.
5. Composition selon l'une des revendications 1 à 4, caractérisée en ce qu'elle comprend d'autres ingrédients actifs ultérieurs tels que d'autres herbicides, antidotes, fongicides, insecticides, acaricides, fertilisants.  5. Composition according to one of claims 1 to 4, characterized in that it comprises other subsequent active ingredients such as other herbicides, antidotes, fungicides, insecticides, acaricides, fertilizers.
6. Composition selon la revendication 5, caractérisée en ce que le (ou les) autre (s) herbicide (s) qu'elle comprend, est (ou sont) sélectionné (s) parmi les herbicides de la liste suivante : acifluorfen, aclonifen, AKH-7088, amicarbazone , amitrole, anilofos, azafenidin, azimsulfuron, aziprotryne, BAY MKH 6561, bénazoline, benfluralin, bensulfuron, bentazone, bensfendizone , benzofenap, benzthiazuron, bifénox, bilanafos, bispyribac-sodium, bromacil, bromofenoxim, butafenacil, butamifos, butenachlor, butralin, butroxydim, butylate, cafenstrole, carbétamide, chlomethoxyfen, chloramben, chlorbromuron, chlorbufam, chlorflurenol , chloridazon, chlorimuron, chlornitrofen, chloroxuron, chlorpropham, chlorthal, chlorthiamide , cinidon éthyle, cinmétylein, cinosulfuron, clethodim, clodinafop, clomeprop, cloransulam- méthyle, cumyluron (JC-940) , cyanazine, cycloate, cyclosuifamuron, cycloxydim, cyhalo- fop-butyl , 2,4-DB, daimuron, dalapon, desmedipham, desmétryne, dichlobenil, dichlorprop, dichlorprop- P, diclofop, diclosulam, diethatyll, difenoxuron, difenzoquat, diflufenzopyr, dimefuron, dimepiperate , dimethachlor, di-methametryn, dinitramine, dinoseb, dinoseb acétate, dinoterb, diphenamid, dipropetryn, diquat, dithiopyr, 1-eglinazine, endothal, EPTC, esprocarb, ethalfluralin, ethametsulfuron-méthyle, ethidimuron, ethiozin (SMY 1500), ethofumesate, ethoxyfen-éthyle (HC-252), ethoxysulfuron, etobenzanid (HW 52) , fenoxaprop, fenoxaprop-P, fenuron, flamprop, flamprop-M, flazasulfuron, florasulam, fluazazifop, fluaziifop-P, fluazolate (JV 485) , flucarbazone- sodium, fluchloralin, flufenpyr éthyle, flumetsulam flumiclorac-pentyl , flumioxazine , flumipropin, fluometuron fluoroglycofen, fluoronitrofenflupoxam, flupropanate flupyrsulfuron, flurenol , fluridone, flurochloridone flurtamone, fluthiacet-méthyle, fomesafen, foramsulfuron fosamine, furyloxyfen, haloxyfop, haloxyfop- P-méthyle hexazinone, imazamethabenz , imazapyr, imazaquin imazosulfuron, indanofan, iodosulfuron, isopropalin, isouron isoxaben, isoxachlortole, isoxapyrifop, KPP-421, lenacil LS830556, MCPB, metamitron, metazachlor, methabenzthiazuron methazole, methoprotryne, méthyledymron, metobenzuron metobromuron, metosulam, metoxuron, molinate, monalide monolinuron, naproanilide , napropamide , naptalam, NC-330 neburon, nicosulfuron, nipyraclofen, norflurazon, orbencarb oryzalin, oxadiargyl, oxasulfuron, oxaziclomefone oxyfluorfen, pebulate, pentanochlor, pentoxazone phenmedipham, piperophos, primisulfuron, prodiamine profluazol, proglinazine, prométon, propaquizafop, propazine propham, propyzamide, prosuifocarb, prosulfuron, pyraclonil pyrazogyl (HSA-961) , pyrazolynate , pyrazoxyfen, pyribenzoxim pyributicarb, pyridafol, pyridate, pyriftalid, pyriminobac méthyle, pyrithiobac-sodium, quinmerac, quizalofop quizalofop-P, rimsulfuron, sethoxydim, siduron, simetryn sulfometuron-méthyle, 2,3,6-TBA, TCA- sodium, tebutam tebuthiuron, tepraloxydim, terbacil, terbumeton, terbutryn thenylchlor, thiazafluron, thiazopyr, thidiazimin thiobencarb, tiocarbazil, tioclorim, tralkoxydim, triallate traiziflam, trietazine, triflusulfuron-méthyle, tritosulfuron UBI-C4874, vernolate, mesotrione, sulcotrione, tembotrione, s metolachlore , acetochlore , pethoxamide, dimethenamid-p flufenacet, pretilachlore, thiencarbazone, isoproturon chortoluron, terbuthylazine , metribuzine, isoxaflutole pendimethaline, diflufenicanil , beflubutamide , 6. Composition according to claim 5, characterized in that the (s) other herbicide (s) it comprises, is (or are) selected (s) among the herbicides of the following list: acifluorfen, aclonifen , AKH-7088, amicarbazone, amitrole, anilofos, azafenidin, azimsulfuron, aziprotryne, BAY MKH 6561, benazoline, benfluralin, bensulfuron, bentazone, bensfendizone, benzofenap, benzthiazuron, bifenox, balanceafos, bispyribac-sodium, bromacil, bromofenoxim, butafenacil, butamifos , butenachlor, butralin, butroxydim, butylate, cafenstrole, carbetamide, chloromethoxyfen, chloramben, chlorbromuron, chlorbufam, chlorflurenol, chloridazon, chlorimuron, chlornitrofen, chloroxuron, chlorpropham, chlorthal, chlorthiamide, cinidon ethyl, cinmetylin, cinosulfuron, clethodim, clodinafop, clomeprop, cloransulam-methyl, cumyluron (JC-940), cyanazine, cycloate, cyclosuifamuron, cycloxydim, cyhalofop-butyl, 2,4-DB, daimuron, dalapon, desmedipham, desmétryne, dichlobenil, dich lorprop, dichlorprop-P, diclofop, diclosulam, diethatyll, difenoxuron, difenzoquat, diflufenzopyr, dimefuron, dimepiperate, dimethachlor, di-methametryn, dinitramine, dinoseb, dinoseb acetate, dinoterb, diphenamid, dipropetryn, diquat, dithiopyr, 1-eglinazine, endothal , EPTC, esprocarb, ethalfluralin, ethametsulfuron-methyl, ethidimuron, ethiozin (SMY 1500), ethofumesate, ethoxyfen-ethyl (HC-252), ethoxysulfuron, andobenzanid (HW 52), fenoxaprop, fenoxaprop-P, fenuron, flamprop, flamprop-M, flazasulfuron, florasulam, fluazazifop, fluaziifop-P, fluazolate (JV 485), flucarbazone-sodium, fluchloralin, flufenpyr ethyl, flumetsulam flumiclorac-pentyl, flumioxazin, flumipropin, fluometuron fluoroglycofen, fluoronitrofenflupoxam, flupropanate flupyrsulfuron, flurenol, fluridone, flurochloridone flurtamone, fluthiacet-methyl, fomesafen, foramsulfuron fosamine, furyloxyfen, haloxyfop, haloxyfop-P-methylhexazinone, imazamethabenz, imazapyr, imazaquin imazosulfuron, indanofan, iodosulfuron, isopropalin, isoxaben isouron, isoxachlortole, isoxapyrifop, KPP-421 , lenacil LS830556, MCPB, metamitron, metazachlor, methabenzthiazuron methazole, methoprotryne, methyledymron, metobenzuron metobromuron, metosulam, metoxuron, molinate, monalide monolinuron, naproanilide, napropamide, naptalam, NC-330 neburon, nicosulfuron, nipyraclofen, norflurazon, orbencarb oryzalin, oxadiargyl oxasulfuron oxaziclomefone oxyfluorfen pebulate pentanochlor p entoxazone phenmedipham, piperophos, primisulfuron, prodiamine profluazol, proglinazine, prometon, propaquizafop, propazine propazine, propyzamide, prosuifocarb, prosulfuron, pyraclonil pyrazogyl (HSA-961), pyrazolynate, pyrazoxyfen, pyrimenzoxim pyributicarb, pyridafol, pyridate, pyriftalid, pyriminobac methyl, pyrithiobac -sodium, quinmerac, quizalofop quizalofop-P, rimsulfuron, sethoxydim, siduron, simetryn sulfometuron-methyl, 2,3,6-TBA, TCA-sodium, tebutam tebuthiuron, tepraloxydim, terbacil, terbumeton, terbutryn thenylchlor, thiazafluron, thiazopyr, thidiazimin thiobencarb, tiocarbazil, tioclorim, tralkoxydim, triallate traiziflam, trietazine, triflusulfuron-methyl, tritosulfuron UBI-C4874, vernolate, mesotrione, sulcotrione, tembotrione, metolachlor, acetochlor, pethoxamide, dimethenamid-p flufenacet, pretilachlor, thiencarbazone, isoproturon chortoluron, terbuthylazine , metribuzin, isoxaflutole pendimethaline, diflufenicanil, beflubutamide,
7. Composition selon l'une des revendications 5 ou 6, caractérisée en ce que les substances actives, y compris [A] et [B] , constituent de 1 à 90% en poids, et de préférence de 5 à 75% en poids, par rapport au poids total de la composition. 7. Composition according to one of claims 5 or 6, characterized in that the active substances, including [A] and [B], constitute from 1 to 90% by weight, and preferably from 5 to 75% by weight , relative to the total weight of the composition.
8. Utilisation d'au moins une composition herbicide selon l'une des revendications 1 à 7 pour le contrôle de mauvaises herbes dans des cultures agricoles.  8. Use of at least one herbicidal composition according to one of claims 1 to 7 for the control of weeds in agricultural crops.
9. Utilisation selon la revendication 8 pour le contrôle en post-émergence et/ou pré-émergence de mauvaises herbes monocotylédones et dicotylédones et/ou pour le traitement de cultures agricoles, prés, pelouses, et/ou pour un traitement comme herbicide total dans des applications de pré-ensemencement ou dans le désherbage de zones industrielles, voies de chemin de fer, monuments.  9. Use according to claim 8 for control in post-emergence and / or pre-emergence of monocotyledonous and dicotyledonous weeds and / or for the treatment of agricultural crops, meadows, lawns, and / or for a treatment as a total herbicide in applications of pre-seeding or in the weeding of industrial areas, railways, monuments.
10. Utilisation selon l'une des revendications 8 ou 9 pour le contrôle des végétaux ou adventices de la liste suivante : Abutilon theophrasti, genres Adonis, genres Ambrosia, genres Amaranthus, Amnimaius, Anagallis arvensis, genres Anthémis, Aphanesarvensis, Atriplexpatula, Bidenspilosa, Capsellabursa-pastoris, Chenopodium album, Convolvulus sepium, Datura stramonium, genres Euphorbia, Fumariaofficinalis, Galeopsis tetrahit, Galinsogaciliata, Galium aparine, genres Géranium, genres Helianthus, genres Ipomeas, KochiaScoparia, genres Lamium, Linderniaprocumbens, genres Matricaria, Monochoriavaginalis, Myosotis arvensis, Papaver rhoeas, Phaseolus aureus, genres Polygonum, Portulacaoleracea, Raphanusraphanistrum, Rotalaindica, Rumex crispus, Seneciovulgaris, Sesbania exaltata, Sida spinosa, Sinapisarvensis, Solanumnigrum, genres Sonchus, Stellaria média, Thlaspi arvense, genres Veronica, genres Vicia, genres Viola, genres Xanthium, Aegilops tauschii, Alisma plantago, Alopecurusmyosuroides, genres Apera, Avenafatua, genres Brachiaria, genres Bromus, Butomusumbellatus, Cenchrusechinatus, genres Commelina, Cynodondactilon, genres Cyperus, genres Digitaria, genres Echinocloa, Elatinatriandra, Eleocharisacicularis, Eleusine indica, Elymus repens, Eragrostispilosa, Eriochloavillosa, genres Fimbristylis, genres Heteranthera, genres Leptochloa, genres Lolium, genres Panicum, genres Phalaris, genres Poa, Potamogetonnodosus, Sagittariapygmaea, genres Scirpus, Setariaviridis, genres Sorghum. 10. Use according to one of claims 8 or 9 for the control of plants or weeds of the following list: Abutilon theophrasti, genera Adonis, genera Ambrosia, genera Amaranthus, Amnimaius, Anagallis arvensis, genera Anthemis, Aphanesarvensis, Atriplexpatula, Bidenspilosa, Capsellabursa-pastoris, Chenopodium album, Convolvulus sepium, Datura stramonium, genera Euphorbia, Fumariaofficinalis, Galeopsis tetrahit, Galinsogaciliata, Galium aparine, genera Geranium, genera Helianthus, genera Ipomeas, KochiaScoparia, genera Lamium, Linderniaprocumbens, genera Matricaria, Monochoriavaginalis, Myosotis arvensis, Papaver rhoeas, Phaseolus aureus, genera Polygonum, Portulacaoleracea, Raphanusraphanistrum, Rotalaindica, Rumex crispus, Seneciovulgaris, Sesbania exaltata, Sida spinosa, Sinapisarvensis, Solanumnigrum, genera Sonchus, Stellaria media, Thlaspi arvense, genera Veronica, genera Vicia, genera Viola, genera Xanthium , Aegilops tauschii, Alisma plantago, Alopecurusmyosur oides, genera Apera, Avenafatua, genera Brachiaria, genera Bromus, Butomusumbellatus, Cenchrusechinatus, genera Commelina, Cynodondactilon, genera Cyperus, genera Digitaria, genera Echinocloa, Elatinatriandra, Eleocharisacicularis, Eleusine indica, Elymus repens, Eragrostispilosa, Eriochloavillosa, Fimbristylis genera, Heteranthera genera, Leptochloa genera, Lolium genera, Panicum genera, Phalaris genera, Poa genera, Potamogetonnodosus, Sagittariapygmaea, Scirpus genera, Setariaviridis, Sorghum genera.
11. Utilisation selon l'une des revendications 8 à 10 pour le traitement d'une culture prise dans le groupe formé par le maïs, le blé, le colza, le tournesol, la betterave à sucre, la pomme de terre, le soja, la carotte, le céleri, la courge, la courgette, l'épinard, la féverole, le haricot, le lupin, la pastèque, le pavot oeillette, le pois et le tabac.  11. Use according to one of claims 8 to 10 for the treatment of a crop in the group formed by corn, wheat, rapeseed, sunflower, sugar beet, potato, soybean, carrots, celery, squash, zucchini, spinach, faba bean, beans, lupine, watermelon, poppy, pea and tobacco.
12. Procédé pour le contrôle de mauvaises herbes dans des cultures agricoles par application d'au moins une composition selon l'une des revendications 1 à 7.  12. A method for controlling weeds in agricultural crops by applying at least one composition according to one of claims 1 to 7.
EP14706895.1A 2013-02-26 2014-02-05 Synergic herbicide compositions Withdrawn EP2961273A1 (en)

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EP3319427B1 (en) 2015-07-10 2019-04-17 BASF Agro B.V. Herbicidal composition comprising cinmethylin and dimethenamid
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