EP2904339A2 - Process for the separation of air by cryogenic distillation - Google Patents
Process for the separation of air by cryogenic distillationInfo
- Publication number
- EP2904339A2 EP2904339A2 EP13763036.4A EP13763036A EP2904339A2 EP 2904339 A2 EP2904339 A2 EP 2904339A2 EP 13763036 A EP13763036 A EP 13763036A EP 2904339 A2 EP2904339 A2 EP 2904339A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- column
- period
- sent
- nitrogen
- during
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 34
- 238000000926 separation method Methods 0.000 title claims abstract description 12
- 238000004821 distillation Methods 0.000 title claims abstract description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 128
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 64
- 239000007789 gas Substances 0.000 claims abstract description 58
- 239000007788 liquid Substances 0.000 claims abstract description 39
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 20
- 239000001301 oxygen Substances 0.000 claims description 20
- 229910052760 oxygen Inorganic materials 0.000 claims description 20
- 239000000047 product Substances 0.000 claims description 14
- 239000012467 final product Substances 0.000 claims description 5
- 230000005611 electricity Effects 0.000 claims description 4
- 230000006835 compression Effects 0.000 claims description 2
- 238000007906 compression Methods 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000002309 gasification Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229940110728 nitrogen / oxygen Drugs 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical class [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
- F25J3/04163—Hot end purification of the feed air
- F25J3/04169—Hot end purification of the feed air by adsorption of the impurities
- F25J3/04175—Hot end purification of the feed air by adsorption of the impurities at a pressure of substantially more than the highest pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04048—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of cold gaseous streams, e.g. intermediate or oxygen enriched (waste) streams
- F25J3/0406—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of cold gaseous streams, e.g. intermediate or oxygen enriched (waste) streams of nitrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0012—Primary atmospheric gases, e.g. air
- F25J1/0015—Nitrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
- F25J1/0037—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work of a return stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0201—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration
- F25J1/0202—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration in a quasi-closed internal refrigeration loop
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
- F25J1/0234—Integration with a cryogenic air separation unit
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04048—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of cold gaseous streams, e.g. intermediate or oxygen enriched (waste) streams
- F25J3/04054—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of cold gaseous streams, e.g. intermediate or oxygen enriched (waste) streams of air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04078—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
- F25J3/04084—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of nitrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04078—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
- F25J3/0409—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
- F25J3/04187—Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams
- F25J3/04218—Parallel arrangement of the main heat exchange line in cores having different functions, e.g. in low pressure and high pressure cores
- F25J3/04224—Cores associated with a liquefaction or refrigeration cycle
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/04309—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of nitrogen
- F25J3/04315—Lowest pressure or impure nitrogen, so-called waste nitrogen expansion
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
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- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04333—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/04351—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams of nitrogen
- F25J3/04357—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams of nitrogen and comprising a gas work expansion loop
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04375—Details relating to the work expansion, e.g. process parameter etc.
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04406—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
- F25J3/04412—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04436—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using at least a triple pressure main column system
- F25J3/04448—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using at least a triple pressure main column system in a double column flowsheet with an intermediate pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04472—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using the cold from cryogenic liquids produced within the air fractionation unit and stored in internal or intermediate storages
- F25J3/04496—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using the cold from cryogenic liquids produced within the air fractionation unit and stored in internal or intermediate storages for compensating variable air feed or variable product demand by alternating between periods of liquid storage and liquid assist
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/20—Processes or apparatus using separation by rectification in an elevated pressure multiple column system wherein the lowest pressure column is at a pressure well above the minimum pressure needed to overcome pressure drop to reject the products to atmosphere
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/04—Internal refrigeration with work-producing gas expansion loop
- F25J2270/06—Internal refrigeration with work-producing gas expansion loop with multiple gas expansion loops
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
- F25J2290/12—Particular process parameters like pressure, temperature, ratios
Definitions
- the present invention relates to a process for the separation of air by cryogenic distillation.
- the Integrated Gasified Combined Cycle is usually selected to generate clean energy from coal. This clean energy production technique is especially suited for new coal-based power generation projects specified to operate efficiently and with minimal pollution to the environment.
- the air separation unit ASU for the IGCC is a combination of an oxygen plant and a nitrogen generator plant.
- An object of the present invention is to provide an air separation unit with reduced energy consumption but which is capable of producing nitrogen and oxygen with a nitrogen/oxygen ratio of less than 3.6, preferably greater than 4.
- a process for the separation of air by cryogenic distillation in which air is purified, cooled in a heat exchanger and separated in a column system including at least a first column and a second column, the first column operating at a higher pressure than the second column and the top of the first column being thermally linked to the bottom of the second column via a first reboiler-condenser, oxygen enriched liquid is removed from the first column and sent to the second column or liquid derived from the oxygen enriched liquid is sent to the second column, nitrogen enriched liquid is removed from the first column and sent to the second column, oxygen rich liquid is removed from the second column, pressurized and vaporized in the heat exchanger to form an oxygen rich gas, nitrogen rich fluid is removed from the column system and warmed in the heat exchanger to form a first nitrogen rich gas, wherein
- the product ratio being the ratio between the amount of nitrogen rich gas produced and the amount of oxygen rich gas produced, is greater than 2.5
- nitrogen enriched liquid is sent from a storage tank to the column system and a first nitrogen enriched gas from the column system is compressed in a first compressor having an inlet temperature of less than -50°C and then sent to the heat exchanger, and
- the product ratio is less than 2.5 and a second nitrogen rich gas removed from the column system is expanded in a turbine having an inlet temperature lower than the ambient temperature or liquefied in a liquefier and nitrogen enriched liquid is sent to the storage tank from the outlet of the turbine and/or from the column system and/or from the liquefier
- the first nitrogen enriched gas is removed from the second column before being compressed in the first compressor and after compression in the first compressor is warmed in the heat exchanger and removed as a product, in that the second nitrogen rich gas expanded in the turbine is removed from the second column and in that the second column operates at a pressure of at least 2 bars abs.
- the product ratio is greater than 3.
- the product ratio is less than 2.
- nitrogen enriched gas is removed from the second column, compressed in the first compressor without having been warmed and sent to the heat exchanger.
- the nitrogen rich gas removed from the column system is warmed in the heat exchanger expanded in the turbine and then warmed in the heat exchanger.
- the turbine has an inlet temperature of at most -50°C, preferably of at most -100°C.
- the outlet pressure of the turbine is substantially equal to the pressure of the second column.
- no nitrogen rich gas is sent to the turbine during the first period, no gas is sent to the first compressor during the second period, the price of electricity is less in the second period than in the first period, the first compressor does not operate during the second period.
- no nitrogen enriched liquid is sent to the storage tank during the first period.
- At least one cryogenic liquid is withdrawn from the process as a final product and preferably during the first period the same cryogenic liquid is not withdrawn from the process as a final product.
- the first compressor compresses nitrogen enriched gas from the column system, preferably from the second column, and a second compressor compresses the first nitrogen rich gas from the column system downstream of the heat exchanger, the outlet pressures of the first and second compressors being substantially the same.
- the column system includes a third column operating at an intermediate pressure.
- the second column has a second reboiler-condenser at an intermediate position thereof.
- the oxygen rich gas is sent to a gasifier of an IGCC system.
- the first nitrogen rich gas is used to dilute synthesis gas or hydrogen sent to the gas turbine of an IGCC system.
- the first period corresponds to a period when the electricity production of the IGCC system is above a given level and the second period corresponds to a period when that electricity production is below the given level.
- Figure 1 shows a cryogenic air separation process using a standard double column, having a first column 1 1 and a second column 15, the first column operating at a higher pressure than the second column and being placed below the second column.
- the second column 15 operates at at least 2 bars abs.
- the top of the first column 1 1 is thermally linked to the bottom of the second column 15 by means of a vaporizer-condenser 13 placed at the bottom of the second column 15. It is also possible for the second column to use an intermediate vaporizer-condenser (not illustrated).
- the process also uses an intermediate pressure column 17 having a bottom reboiler 65 and a top condenser.
- the presence of the column 17 is not essential.
- an air stream 1 compressed to the operating pressure of the first column 1 1 is divided into two parts.
- One part 3 is cooled in heat exchanger 9 and sent in gaseous form to the first column 1 1 .
- the other part 5 is boosted to a higher pressure by booster compressor 7 and sent to the heat exchanger 7.
- the boosted air 5 is cooled in the heat exchanger 9 and sent to the first column 1 1 after expansion in liquid or partially condensed form.
- oxygen enriched liquid 19 from the bottom of the first column 1 1 is sent to subcooler 25 and then expanded into the column 17.
- Liquid 67 from the bottom of column 17 is sent to the top condenser as stream 64, where it is partially evaporated, the liquid and gas streams formed being sent to the second column 15.
- Part 71 of the liquid is sent from the bottom of column 17 to the second column 15.
- a liquid stream 21 is removed from an intermediate region of the first column and expanded into the second column 15.
- at least part of stream 5 can be sent directly to the second column 15.
- a first nitrogen enriched liquid stream is sent as stream 23 from the first column to the second column, being removed a few trays below the top of the first column.
- a nitrogen enriched gas stream 61 is removed at the top of the first column, condensed in bottom condenser 65 and mixed with stream 23 as stream 63.
- a liquid stream 55 from the top of column 17 is sent to the top of column 15.
- the column system produces a high pressure gaseous oxygen stream 53 by removing liquid oxygen 49 from the bottom of second column 15, pressurizing it via pump 51 and vaporizing the pumped liquid in exchanger 9.
- the column system produces a high pressure gaseous nitrogen stream 47 by removing liquid nitrogen 43 from the top of first column 1 1 , pressurizing it via pump 45 and vaporizing the pumped liquid in exchanger 9.
- pressurized streams may be sent to a gasifier.
- gaseous nitrogen 29, 37 is removed at the top of the second column 15, warmed in subcooler 25, partially warmed in heat exchanger 9 and sent as stream 75 to a turbine 73 having an inlet temperature which is an intermediate temperature of the heat exchanger 9.
- the expanded nitrogen is sent to the cold end of the exchanger and warmed as far as the warm end.
- the nitrogen 75 forms a waste stream.
- Another part of the nitrogen 37 is warmed in the heat exchanger to the warm end, compressed in compressor 39 and sent to a gas turbine via conduit as stream 41 .
- the process uses two particular special operations during two periods.
- the ratio between the amount of nitrogen rich gas produced 41 and the amount of oxygen rich gas 53 produced is greater than 2.5.
- Nitrogen enriched liquid 57A is sent from a storage tank 27 to the column system 1 1 ,15 and nitrogen enriched gas 29, 31 from the second column 15 of the column system is compressed in a compressor 33 having an inlet temperature of less than -50°C and then sent to the cold end of the heat exchanger 9.
- the compressor 33 only operates when nitrogen enriched liquid 57A is sent to the column.
- the gas 31 is then warmed in the heat exchanger and mixed with the gas from compressor 39 to form stream 41. Either no nitrogen is sent to the turbine 73 or some nitrogen may be sent to the turbine 73.
- the product ratio is less than 2.5 and a nitrogen rich gas removed from the column system is expanded in a turbine 73 having an inlet temperature lower than the ambient temperature and nitrogen enriched liquid 57 is sent to the storage tank 27 from the column system. No nitrogen is sent to the compressor 33 and all of stream 29 is removed as stream 37.
- Figure 2 shows a variant of Figure 1 in which the cold turbine 73 is replaced by a liquefier.
- the ratio between the amount of nitrogen rich gas produced 41 and the amount of oxygen rich gas 53 produced (known as the "product ratio"), is greater than 2.5.
- Nitrogen enriched liquid 57A is sent from a storage tank 27 to the column system 1 1 ,15 and nitrogen enriched gas 29,31 from the second column 15 of the column system is compressed in a compressor 33 having an inlet temperature of less than -50°C and then sent to the cold end of the heat exchanger 9.
- the compressor 33 only operates when nitrogen enriched liquid 57A is sent to the column.
- the gas 31 is then warmed in the heat exchanger and mixed with the gas from compressor 39 to form stream 41.
- the product ratio is less than 2.5 and a nitrogen rich gas removed from the column system 37 is warmed as far as the warm end of exchanger 9. Then part of the gas is sent to compressor 39 and the rest 75 is compressed by compressor 101 and divided into two. One part 79 is cooled and liquefied in exchanger 109 to form a partially condensed stream. This stream separates in a phase separator and the liquid formed serves as final product 83. The gas 85 is sent back to the exchanger, warmed and sent to the atmosphere. The other part of gas from compressor 101 is further compressed in boosters 103, 105, is cooled in exchanger 109 and is expanded in a turbine 73 having an inlet temperature lower than the ambient temperature.
- the expanded gas is warmed in the exchanger 109 to an intermediate temperature and divided into two.
- One part 81 is expanded at the intermediate temperature in turbine 173 and rewarmed in the exchanger before being sent to the atmosphere.
- the rest 79 is warmed and recycled upstream of compressor 101 .
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Separation By Low-Temperature Treatments (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13763036.4A EP2904339A2 (en) | 2012-10-01 | 2013-09-13 | Process for the separation of air by cryogenic distillation |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12306195.4A EP2713128A1 (en) | 2012-10-01 | 2012-10-01 | Process for the separation of air by cryogenic distillation |
EP13763036.4A EP2904339A2 (en) | 2012-10-01 | 2013-09-13 | Process for the separation of air by cryogenic distillation |
PCT/EP2013/068965 WO2014053297A2 (en) | 2012-10-01 | 2013-09-13 | Process for the separation of air by cryogenic distillation |
Publications (1)
Publication Number | Publication Date |
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EP2904339A2 true EP2904339A2 (en) | 2015-08-12 |
Family
ID=47022601
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12306195.4A Withdrawn EP2713128A1 (en) | 2012-10-01 | 2012-10-01 | Process for the separation of air by cryogenic distillation |
EP13763036.4A Withdrawn EP2904339A2 (en) | 2012-10-01 | 2013-09-13 | Process for the separation of air by cryogenic distillation |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12306195.4A Withdrawn EP2713128A1 (en) | 2012-10-01 | 2012-10-01 | Process for the separation of air by cryogenic distillation |
Country Status (4)
Country | Link |
---|---|
US (1) | US20150253075A1 (en) |
EP (2) | EP2713128A1 (en) |
CN (1) | CN105431698A (en) |
WO (1) | WO2014053297A2 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
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FR3044747B1 (en) * | 2015-12-07 | 2019-12-20 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | PROCESS FOR LIQUEFACTION OF NATURAL GAS AND NITROGEN |
EP3438585A3 (en) * | 2017-08-03 | 2019-04-17 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method for defrosting a device for air separation by cryogenic distillation and device adapted to be defrosted using this method |
CN111433545B (en) * | 2017-12-28 | 2022-03-04 | 乔治洛德方法研究和开发液化空气有限公司 | Utilization of nitrogen-rich streams produced in air separation units comprising a split core main heat exchanger |
CN109059422A (en) * | 2018-07-12 | 2018-12-21 | 北京拓首能源科技股份有限公司 | A kind of device using dirty nitrogen cold energy precooled air |
CN109341193A (en) * | 2018-11-16 | 2019-02-15 | 杭州凯德空分设备有限公司 | A kind of peak-trough electricity production liquid oxygen liquid nitrogen plan and method |
US20220034584A1 (en) * | 2020-07-30 | 2022-02-03 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Large liquid oxygen and liquefied natural gas production process |
CN112304027A (en) * | 2020-12-04 | 2021-02-02 | 开封空分集团有限公司 | Air separation device for nitrogen circulation flow full liquid preparation and preparation method |
US20220252341A1 (en) * | 2021-02-05 | 2022-08-11 | Air Products And Chemicals, Inc. | Method and system for decarbonized lng production |
US20240035745A1 (en) * | 2022-07-28 | 2024-02-01 | Neil M. Prosser | System and method for cryogenic air separation using four distillation columns including an intermediate pressure column |
US11959701B2 (en) | 2022-07-28 | 2024-04-16 | Praxair Technology, Inc. | Air separation unit and method for production of high purity nitrogen product using a distillation column system with an intermediate pressure kettle column |
Family Cites Families (8)
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JPS5261171A (en) * | 1975-11-17 | 1977-05-20 | Hitachi Ltd | Air separation method to collect liquid product |
DE19803437A1 (en) * | 1998-01-29 | 1999-03-18 | Linde Ag | Oxygen and nitrogen extracted by low-temperature fractional distillation |
FR2807150B1 (en) * | 2000-04-04 | 2002-10-18 | Air Liquide | PROCESS AND APPARATUS FOR PRODUCING OXYGEN ENRICHED FLUID BY CRYOGENIC DISTILLATION |
FR2819046B1 (en) * | 2001-01-03 | 2006-01-06 | Air Liquide | METHOD AND APPARATUS FOR AIR SEPARATION BY CRYOGENIC DISTILLATION |
US7228715B2 (en) * | 2003-12-23 | 2007-06-12 | L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude | Cryogenic air separation process and apparatus |
US7272954B2 (en) * | 2004-07-14 | 2007-09-25 | L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Proceded Georges Claude | Low temperature air separation process for producing pressurized gaseous product |
US20080115531A1 (en) * | 2006-11-16 | 2008-05-22 | Bao Ha | Cryogenic Air Separation Process and Apparatus |
FR2915271A1 (en) * | 2007-04-23 | 2008-10-24 | Air Liquide | Air separating method, involves operating extracted nitrogen gas from high pressure column at pressure higher than pressure of systems operating at low pressure, and compressing gas till pressure is higher than high pressure of systems |
-
2012
- 2012-10-01 EP EP12306195.4A patent/EP2713128A1/en not_active Withdrawn
-
2013
- 2013-09-13 CN CN201380051043.6A patent/CN105431698A/en active Pending
- 2013-09-13 US US14/431,918 patent/US20150253075A1/en not_active Abandoned
- 2013-09-13 WO PCT/EP2013/068965 patent/WO2014053297A2/en active Application Filing
- 2013-09-13 EP EP13763036.4A patent/EP2904339A2/en not_active Withdrawn
Non-Patent Citations (1)
Title |
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See references of WO2014053297A3 * |
Also Published As
Publication number | Publication date |
---|---|
CN105431698A (en) | 2016-03-23 |
WO2014053297A2 (en) | 2014-04-10 |
WO2014053297A3 (en) | 2015-11-19 |
US20150253075A1 (en) | 2015-09-10 |
EP2713128A1 (en) | 2014-04-02 |
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