EP2830575A1 - Composition auto - emulsionnante comprenant un ester de polyglycerol et un ester de saccharose - Google Patents
Composition auto - emulsionnante comprenant un ester de polyglycerol et un ester de saccharoseInfo
- Publication number
- EP2830575A1 EP2830575A1 EP13722476.2A EP13722476A EP2830575A1 EP 2830575 A1 EP2830575 A1 EP 2830575A1 EP 13722476 A EP13722476 A EP 13722476A EP 2830575 A1 EP2830575 A1 EP 2830575A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- composition according
- carbon atoms
- ester
- fatty acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 93
- 150000002148 esters Chemical class 0.000 title claims abstract description 38
- 229930006000 Sucrose Natural products 0.000 title claims abstract description 18
- 229920000223 polyglycerol Polymers 0.000 title claims abstract description 17
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 title claims abstract description 9
- 235000013681 dietary sucrose Nutrition 0.000 title abstract 2
- 229960004793 sucrose Drugs 0.000 title abstract 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000004615 ingredient Substances 0.000 claims abstract description 16
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- 239000002537 cosmetic Substances 0.000 claims abstract description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 34
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 31
- 229930195729 fatty acid Natural products 0.000 claims description 31
- 239000000194 fatty acid Substances 0.000 claims description 31
- 150000004665 fatty acids Chemical class 0.000 claims description 31
- -1 glycerol ester Chemical class 0.000 claims description 28
- 235000011187 glycerol Nutrition 0.000 claims description 21
- 239000005720 sucrose Substances 0.000 claims description 16
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000000344 soap Substances 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 8
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 8
- 150000007513 acids Chemical class 0.000 claims description 7
- 235000021314 Palmitic acid Nutrition 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 6
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- 150000003445 sucroses Chemical class 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 238000005809 transesterification reaction Methods 0.000 claims description 5
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 4
- 229910052740 iodine Inorganic materials 0.000 claims description 4
- 239000011630 iodine Substances 0.000 claims description 4
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 claims description 4
- 239000005639 Lauric acid Substances 0.000 claims description 3
- 125000004429 atom Chemical group 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 150000003626 triacylglycerols Chemical class 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 239000008158 vegetable oil Substances 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 41
- 239000000047 product Substances 0.000 description 33
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 28
- 238000009472 formulation Methods 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000006071 cream Substances 0.000 description 12
- 150000005690 diesters Chemical class 0.000 description 8
- 239000002304 perfume Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 150000005691 triesters Chemical class 0.000 description 7
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 5
- 230000005404 monopole Effects 0.000 description 5
- 239000003755 preservative agent Substances 0.000 description 5
- 230000002335 preservative effect Effects 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 235000013311 vegetables Nutrition 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N Lactic Acid Natural products CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 235000013336 milk Nutrition 0.000 description 4
- 239000008267 milk Substances 0.000 description 4
- 210000004080 milk Anatomy 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- GJVUMEONPPTZEY-UHFFFAOYSA-N 2,3-dihydroxypropyl undec-10-enoate Chemical compound OCC(O)COC(=O)CCCCCCCCC=C GJVUMEONPPTZEY-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 2
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 2
- NKEQOUMMGPBKMM-UHFFFAOYSA-N 2-hydroxy-2-[2-(2-hydroxy-3-octadecanoyloxypropoxy)-2-oxoethyl]butanedioic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CC(O)(C(O)=O)CC(O)=O NKEQOUMMGPBKMM-UHFFFAOYSA-N 0.000 description 2
- XBBMJUWOCGWHRP-UHFFFAOYSA-N 3-octanoyloxypropyl octanoate Chemical compound CCCCCCCC(=O)OCCCOC(=O)CCCCCCC XBBMJUWOCGWHRP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 235000021360 Myristic acid Nutrition 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 2
- HLLPKVARTYKIJB-MCQPFKOBSA-N [(2r,3s,4s,5r,6r)-6-[(2s,3s,4s,5r)-3,4-dihydroxy-2,5-bis(octadecanoyloxymethyl)oxolan-2-yl]oxy-3,4,5-trihydroxyoxan-2-yl]methyl octadecanoate Chemical compound O[C@H]1[C@H](O)[C@@H](COC(=O)CCCCCCCCCCCCCCCCC)O[C@@]1(COC(=O)CCCCCCCCCCCCCCCCC)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](COC(=O)CCCCCCCCCCCCCCCCC)O1 HLLPKVARTYKIJB-MCQPFKOBSA-N 0.000 description 2
- SZYSLWCAWVWFLT-UTGHZIEOSA-N [(2s,3s,4s,5r)-3,4-dihydroxy-5-(hydroxymethyl)-2-[(2r,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxolan-2-yl]methyl octadecanoate Chemical group O([C@@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@]1(COC(=O)CCCCCCCCCCCCCCCCC)O[C@H](CO)[C@@H](O)[C@@H]1O SZYSLWCAWVWFLT-UTGHZIEOSA-N 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 239000002781 deodorant agent Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 229940048848 lauryl glucoside Drugs 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 229940035652 propanediol dicaprylate Drugs 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229940031439 squalene Drugs 0.000 description 2
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000000185 sucrose group Chemical group 0.000 description 2
- 230000000475 sunscreen effect Effects 0.000 description 2
- 239000000516 sunscreening agent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- UESKBWLOSBQYHI-UHFFFAOYSA-N 2,3-dihydroxypropyl octadecanoate;2-hydroxypropanoic acid Chemical compound CC(O)C(O)=O.CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO UESKBWLOSBQYHI-UHFFFAOYSA-N 0.000 description 1
- QSNJNCHUFWULBZ-UHFFFAOYSA-N 2-ethylhexyl 16-methylheptadecanoate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCCCCCCCC(C)C QSNJNCHUFWULBZ-UHFFFAOYSA-N 0.000 description 1
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 235000006491 Acacia senegal Nutrition 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 239000004287 Dehydroacetic acid Substances 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 244000062730 Melissa officinalis Species 0.000 description 1
- 235000010654 Melissa officinalis Nutrition 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 244000018633 Prunus armeniaca Species 0.000 description 1
- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 1
- FOLJTMYCYXSPFQ-CJKAUBRRSA-N [(2r,3s,4s,5r,6r)-6-[(2s,3s,4s,5r)-3,4-dihydroxy-5-(hydroxymethyl)-2-(octadecanoyloxymethyl)oxolan-2-yl]oxy-3,4,5-trihydroxyoxan-2-yl]methyl octadecanoate Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@@H](COC(=O)CCCCCCCCCCCCCCCCC)O[C@@H]1O[C@@]1(COC(=O)CCCCCCCCCCCCCCCCC)[C@@H](O)[C@H](O)[C@@H](CO)O1 FOLJTMYCYXSPFQ-CJKAUBRRSA-N 0.000 description 1
- GCSPRLPXTPMSTL-IBDNADADSA-N [(2s,3r,4s,5s,6r)-2-[(2s,3s,4s,5r)-3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[C@@]1([C@]2(CO)[C@H]([C@H](O)[C@@H](CO)O2)O)O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O GCSPRLPXTPMSTL-IBDNADADSA-N 0.000 description 1
- ZPVGIKNDGJGLCO-VGAMQAOUSA-N [(2s,3r,4s,5s,6r)-2-[(2s,3s,4s,5r)-3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] hexadecanoate Chemical group CCCCCCCCCCCCCCCC(=O)O[C@@]1([C@]2(CO)[C@H]([C@H](O)[C@@H](CO)O2)O)O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O ZPVGIKNDGJGLCO-VGAMQAOUSA-N 0.000 description 1
- UEYVMVXJVDAGBB-ZHBLIPIOSA-N [(2s,3s,4s,5r)-3,4-dihydroxy-5-(hydroxymethyl)-2-[(2r,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxolan-2-yl]methyl tetradecanoate Chemical group O([C@@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@]1(COC(=O)CCCCCCCCCCCCC)O[C@H](CO)[C@@H](O)[C@@H]1O UEYVMVXJVDAGBB-ZHBLIPIOSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000010477 apricot oil Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229940116224 behenate Drugs 0.000 description 1
- UKMSUNONTOPOIO-UHFFFAOYSA-M behenate Chemical compound CCCCCCCCCCCCCCCCCCCCCC([O-])=O UKMSUNONTOPOIO-UHFFFAOYSA-M 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 229940082500 cetostearyl alcohol Drugs 0.000 description 1
- ALSTYHKOOCGGFT-UHFFFAOYSA-N cis-oleyl alcohol Natural products CCCCCCCCC=CCCCCCCCCO ALSTYHKOOCGGFT-UHFFFAOYSA-N 0.000 description 1
- 229940071124 cocoyl glutamate Drugs 0.000 description 1
- 239000007957 coemulsifier Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000019258 dehydroacetic acid Nutrition 0.000 description 1
- 229940061632 dehydroacetic acid Drugs 0.000 description 1
- JEQRBTDTEKWZBW-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1=C(O)OC(C)=CC1=O JEQRBTDTEKWZBW-UHFFFAOYSA-N 0.000 description 1
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Natural products CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 1
- GLSRFBDXBWZNLH-UHFFFAOYSA-L disodium;2-chloroacetate;2-(4,5-dihydroimidazol-1-yl)ethanol;hydroxide Chemical compound [OH-].[Na+].[Na+].[O-]C(=O)CCl.OCCN1CCN=C1 GLSRFBDXBWZNLH-UHFFFAOYSA-L 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 229940087068 glyceryl caprylate Drugs 0.000 description 1
- 229940074052 glyceryl isostearate Drugs 0.000 description 1
- 229940075529 glyceryl stearate Drugs 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000008172 hydrogenated vegetable oil Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 description 1
- 239000000865 liniment Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 235000010958 polyglycerol polyricinoleate Nutrition 0.000 description 1
- 229940048845 polyglyceryl-3 diisostearate Drugs 0.000 description 1
- GHBFNMLVSPCDGN-UHFFFAOYSA-N rac-1-monooctanoylglycerol Chemical compound CCCCCCCC(=O)OCC(O)CO GHBFNMLVSPCDGN-UHFFFAOYSA-N 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229940066675 ricinoleate Drugs 0.000 description 1
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940096501 sodium cocoamphoacetate Drugs 0.000 description 1
- 229940079781 sodium cocoyl glutamate Drugs 0.000 description 1
- 229940045944 sodium lauroyl glutamate Drugs 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- IJRHDFLHUATAOS-DPMBMXLASA-M sodium ricinoleate Chemical compound [Na+].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O IJRHDFLHUATAOS-DPMBMXLASA-M 0.000 description 1
- 229940045898 sodium stearoyl glutamate Drugs 0.000 description 1
- 229940080352 sodium stearoyl lactylate Drugs 0.000 description 1
- ODFAPIRLUPAQCQ-UHFFFAOYSA-M sodium stearoyl lactylate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O ODFAPIRLUPAQCQ-UHFFFAOYSA-M 0.000 description 1
- KDHFCTLPQJQDQI-BDQAORGHSA-M sodium;(4s)-4-amino-5-octadecanoyloxy-5-oxopentanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC([O-])=O KDHFCTLPQJQDQI-BDQAORGHSA-M 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- GGHPAKFFUZUEKL-UHFFFAOYSA-M sodium;hexadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCOS([O-])(=O)=O GGHPAKFFUZUEKL-UHFFFAOYSA-M 0.000 description 1
- QKHBMQWPOUUMQZ-BDQAORGHSA-M sodium;hydron;(2s)-2-(octadecanoylamino)pentanedioate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC([O-])=O QKHBMQWPOUUMQZ-BDQAORGHSA-M 0.000 description 1
- 239000001959 sucrose esters of fatty acids Substances 0.000 description 1
- 235000010965 sucrose esters of fatty acids Nutrition 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/28—Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
Definitions
- the present invention relates to a self-emulsifying composition of vegetable origin which finds applications in particular in the field of cosmetics.
- a composition is said to be self-emulsifying if it is self-sufficient. It thus allows the stability of an emulsion, that is to say that at a certain rate of incorporation in an aqueous medium this emulsion is stable without adding a co-emulsifier or any wax.
- Another object of the present invention is to provide such an exclusively vegetable composition5 allowing a simple implementation for a formulator by providing the least possible mechanical energy and integrating all the ingredients in a monopole (English name “.one pot ”) That is to say in the same tank.
- a self-emulsifying composition comprising, based on the total weight of the ingredients:
- sucrose esters of different HLB 5 to 60% by weight of one or more sucrose esters of different HLB
- the amount of polyglycerol ester is between 5 and 35% by weight and even between 10 and 30% by weight.
- the polyglycerol ester is chosen from esters derived from the reaction of polyglycerols comprising from 2 to 12 glycerol units, preferably from 3 to 6 glycerol units, with at least one vegetable oil, partially hydrogenated or not hydrogen, with an iodine number between 1 and 145, and in particular between 5 and
- the amount of sucrose esters is between 10 and 50% by weight and even between 20 and 45% by weight.
- sucrose ester or esters are chosen from esters resulting from the reaction of sucrose with fatty acids comprising from 10 to 22 carbon atoms, preferably from 12 to 20 carbon atoms, in particular from 12 to 18 atoms. of carbon.
- the fatty acids are selected from lauric acid, myristic acid, palmitic acid, and stearic acid or a mixture of at least two of these fatty acids.
- the glycerol ester is chosen from the esters resulting from the reaction of glycerine with fatty acids or from the transesterification of triglycerides of fatty acids and of glycerine, the fatty acids comprising from 8 to 22 carbon atoms, from preferably from 10 to 20 carbon atoms, more preferably from 14 to 18 carbon atoms.
- fatty acids include myristic acid, palmitic acid, stearic acid or a mixture of at least two of these acids.
- the amount of glycerol ester is between 15 to 45% by weight, more preferably 20 to 40% by weight relative to the total weight of the composition.
- the ester of glycerol and vegetable fatty acid is esterified.
- the amount of surfactant is between 1 and 20% by weight.
- the surfactant is a soap of fatty acids or esterified soaps comprising from 2 to 22 carbon atoms, and preferably from 3 to 20 carbon atoms.
- the amount of fatty alcohol is between 1 to 20% by weight, more preferably between 8 and 20% by weight relative to the total weight of the composition.
- the fatty alcohol comprises from 8 to 22 carbon atoms, the carbon chains being saturated or unsaturated or functionalized or linear or a mixture thereof, preferably from 10 to 18 carbon atoms, and in particular from 12 to 12 carbon atoms. at 18 carbon atoms.
- a composition according to the present invention can be used for the manufacture of cosmetic products, such as for example sunscreen, milk, spray, serum, balm and cream for cosmetic use, foam product, makeup products and personal hygiene.
- cosmetic products such as for example sunscreen, milk, spray, serum, balm and cream for cosmetic use, foam product, makeup products and personal hygiene.
- the polyglycerol ester can be obtained from fatty acid or by trans-esterification from oil or oil mixtures.
- the fatty acids used comprise from 8 to 22 carbon atoms, preferably from 10 to 18 carbon atoms, and in particular from 12 to 18 carbon atoms.
- These acids can be linear or branched, saturated or unsaturated, possess one or more side hydroxyl functions.
- the oils may be saturated or unsaturated, from liquid to solid at room temperature, and optionally have hydroxyl functional groups, preferably having an iodine number between 1 and 145, and in particular from 5 to 105.
- the ester is preferably chosen from esters derived from the reaction of polyglycerols comprising from 2 to 12 glycerol units, preferably from 3 to 6 glycerol units, with at least one partially hydrogenated or non-hydrogenated vegetable oil of iodine number. between 1 and 1 5, and in particular from 5 to 105.
- each chemical body will be identified according to its INCI name and / or its commercial name or reference.
- ester resulting from the reaction of polyglycerol-3 and isostearic acid such as the product marketed by Stéarnerie DUBOIS under the reference DUB ISO G3
- ester derived from polyglycerol-3 and ricinoleic acid such as that marketed by Stéarinerie DUBOIS under the reference DUB PGPR
- ester resulting from the trans-esterification reaction between a vegetable oil and a polyglycerol such as that marketed by Stéarinerie DUBOIS under the reference DUB COCOROSE + (Palme), as well as the following esters marketed by Stéarinerie under the reference DUBOIS DUB APRILOSE + (Apricot) or DUB LILIROSE + (Sunflower).
- the amount of polyglycerol ester (s) in the composition may range, for example, from 5 to 45% by weight, preferably from 5 to 30% by weight, more preferably from 10 to 30% by weight relative to the total weight of the composition.
- the ester of sucrose and of vegetable fatty acid is preferably chosen from esters resulting from the reaction of sucrose and fatty acid (s) comprising from 10 to 22 carbon atoms, preferably from 12 to at 20 atoms carbon, preferably from 12 to 18 carbon atoms such as lauric acid and / or myristic acid and / or palmitic acid and / or stearic acid or a mixture.
- sucrose esters of fatty acids may be chosen from mono-, di-, tri- and tetraesters, polyesters and mixtures thereof. Esters with a low degree of esterification, for example monoesters, diesters, tri-esters of sucrose and fatty acids, or a mixture, are preferably used.
- sucrose ester of fatty acid an ester with a low degree of esterification is preferred, in particular where the mono-esters or di-esters are the majority.
- the sucrose ester of fatty acid used in the present invention has an HLB of between 1 and 16 and preferably between 5 and 11.
- HLB Hydrophilic / Lipophilic Balance
- esters or mixtures of sucrose esters and fatty acids are:
- INCI is sucrose laurate, comprising about 80% monoester, the rest of the mixture being composed of di- and triesters, and marketed under this name by Mitsubichi-Kagaku Foods Corporation,
- the Surfhope SE COSME C-14 6 having a HLB of 16, whose INCI name is sucrose myristate, comprising about 80% of monoester, the remainder of the mixture being composed of di- and triesters, and marketed under this name by the Mitsubichi-Kagaku Foods Corporation,
- the Surfhope SE COSME C-715 having an HLB of 15, whose INCI name is sucrose oleate, comprising about 70% of monoester, the remainder of the mixture being composed of di- and triesters, and marketed under this name by the company Mitsubichi-Kagaku Foods Corporation, DUP SE 15P, with an HLB of 15, whose INCI name is sucrose palmitate, comprising approximately 70% of monoester, the remainder of the mixture being composed of di- and triesters, and marketed under this name by Stéarinerie DUBOIS,
- DUB SE 15S having an HLB of 15, whose INCI name is sucrose stearate, comprising approximately 70% of monoester, the remainder of the mixture being composed of di- and triesters, and marketed under this name by Stéarinerie DUBOIS,
- DUB SE 11 S having an HLB of 11, whose INCI name is sucrose stearate, comprising approximately 60% of monoester, the remainder of the mixture being composed of di- and triesters, and marketed under this name by Stéarinerie DUBOIS ,
- DUB SE 5S having a HLB of 5, whose INCI name is sucrose distearate, comprising approximately 30% of monoester, the remainder of the mixture being composed of di-triesters and polyesters and marketed under this name by Stéarnerie DUBOIS,
- DUB SE 3S having an HLB of 3, whose INCI name is sucrose tristearate, comprising approximately 20% of monoester, the rest of the mixture being composed of di-triesters and polyesters, and marketed under this name by Stéarnerie DUBOIS,
- the amount of sucrose ester (s) may range, for example, from 5 to 60% by weight, preferably from 10 to 50% by weight, and even more preferably from 20 to 45% by weight relative to the total weight of the composition.
- the ester of glycerol and of fatty acid is chosen from esters, whether total or partial, resulting from the reaction of glycerine and fatty acids or from the transesterification of triglycerides.
- fatty acids with glycerine comprise from 8 to 22 carbon atoms, preferably from 10 to 20 carbon atoms, better still from 14 to 18 carbon atoms such as myristic acid and / or palmitic acid and / or stearic acid or a mix.
- These acids can be linear or branched, saturated or unsaturated possess one or more lateral hydroxyl functions.
- the glycerol esters may be further esterified with acetic, lactic, citric or tartaric acid. Lactic acid or citric acid is preferably used.
- DUB GMS (INCI: glyceryl stearate), a product sold under this name by Stéarinerie Dubois
- DUB OG (INCI: glyceryl oleate), a product marketed under this name by Stéarinerie Dubois
- DUB ISG INCI: glyceryl isostearate
- Radiamuls citrem 2931 (INCI: glyceryl stearate citrate), product marketed under this name by the company Oleon, Axol C62 pellets (INCI glyceryl stearate citrate), a product sold under this name by Evonik France SAS or Radiamuls Lactem 2950 (INCI: glyceryl stea
- the amount of ester (s) esterified glycerol may range, for example, from 1 to 50% by weight, preferably from 15 to 45% by weight, more preferably from 20 to 40% by weight relative to the total weight of the composition .
- the surfactant may be a fatty acid soap, or esterified soap, or fatty alcohol salts linked by a sulfate bond.
- fatty acid soaps are chosen from the soaps resulting from the reaction between sodium hydroxide or potassium hydroxide and acids or diacids, with possibly one or more hydroxyl functions.
- the acids may comprise from 2 to 22 carbon atoms, more preferably from 3 to 20 carbon atoms.
- These soaps can be in powder form or in solution.
- Examples include:
- Amisoft HS 11 a product marketed under this name by the company Ajinomoto Co (INCI name: Sodium stearoyl glutamate),
- Amisoft CS 11 a product marketed under this name by the company Ajinomoto Co (INCI name: Sodium cocoyl glutamate),
- LANETTE E (INCI name: cetearyl sulphate sodium), product marketed under this name by BASF,
- DUB RNA 40 a product marketed under this name by Stéarinerie DUBOIS (INCI name: Sodium ricinoleate)
- DUB SNA VE a product marketed under this name by Stéarinerie DUBOIS (INCI name: Sodium stearate (and) Sodium palmitate)
- the amount of soap may range, for example, from 1 to 30%, preferably from 1 to 20%.
- the fatty alcohols used comprise from 8 to 22 carbon atoms which are saturated or unsaturated or functionalized or linear or in a mixture, of product marketed under this name with 10 to 18 carbon atoms, and in particular from 12 to 18 carbon atoms.
- cetyl alcohol (LOROL C1698, product sold under this name by the company BASF or VEGAROL 1698, product marketed under this name by the company Berg & Schmidt or ECOROL 1698, product marketed under this name by the company ECOGREEN)
- HD-OCENOL 90/95 / V product sold under this name by the company BASF
- REFANOL 90/95 / V product marketed under this name by the company ECOGREEN
- the amount of fatty alcohol can range, for example, from 1 to 30% by weight, preferably from 1 to 20% by weight, and still more preferably from 8 to 20% by weight relative to the total weight of the composition.
- compositions according to the present invention are charged in a suitable container. All the ingredients are melted then under rapid stirring, the sucrose ester is introduced. When the mixture is homogeneous, the surfactant is introduced and cooled.
- Table I below are grouped various examples of formulation of compositions according to the present invention:
- composition of the present invention for making various cosmetics, all percentages being by weight. All the compositions produced are stable at 3000 rpm centrifugation for 5 minutes.
- This base is prepared having the following formulation:
- Phases A and B are separately heated to a temperature of 60 ° C with stirring. A is then added to B with moderate agitation.
- the mixture is then cooled with gentle stirring.
- the viscosity is adjusted by adding 4.5% sodium chloride and the pH between 5 and 6 by adding a citric acid solution.
- the final product is an innovative washing cream with a mother-of-pearl appearance of vegetable origin and without the addition of ethoxylated products generally used in this type of application.
- phase A is heated to about 80 ° C.
- phase B The ingredients of phase B are mixed and the resulting mixture is added to phase C preheated to about 80 ° C.
- This mixture is mixed for about 10 minutes.
- Phase A previously prepared with moderate stirring of the deflocculating type is then added thereto.
- phase D is added thereto.
- This mixture is homogenized for about 10 minutes with gentle stirring.
- the final product is in the form of a creamy cream
- This cream is prepared having the following formulation:
- Citric acid Qs pH 5.6
- the propanediol dicaprylate and the mixture obtained according to one of Examples 1 to 8 are mixed.
- Half the amount of water is added at 80 ° C. to the above mixture until a gel is obtained.
- This cream is prepared having the following formulation:
- phase A is introduced and heated to about 80 ° C.
- phase B is heated to about 80 ° C. with stirring: when this phase B is homogeneous, phase C is dispersed therein.
- phase D is introduced into the mixer containing phase A while maintaining the temperature and then phase B.
- This deodorant is prepared as follows.
- glyceryl undecylenate, glyceryl caprylate and the mixture obtained according to one of Examples 1 to 8 are mixed. Half of the amount of water is added at 80 ° C. to the preceding mixture.
- This formulation makes it possible to integrate all the ingredients into a monopole.
- This spray is prepared having the following formulation:
- Citric acid QS pH 4-5 In a container, glyceryl undecylenate, squalene, propanediol and the mixture obtained according to one of Examples 1 to 8 are mixed. Half the amount of water is added at 80 ° C. to the preceding mixture.
- This formulation makes it possible to integrate all the ingredients into a monopole.
- This milk is prepared having the following formulation
- This formulation makes it possible to integrate all the ingredients into a monopole.
- This foaming product is prepared as follows.
- cocoyl glutamate sodium lauryl glucoside carboxylate
- Citric acid Qs pH 4.8
- This formulation makes it possible to integrate all the ingredients into a monopole.
- This foaming cream is prepared having the following formulation:
- phase A is introduced and heated to about 80 ° C.
- phase B is prepared; once the phase is homogeneous, add it to phase A.
- a premix is prepared with phase C; then introduced phase C into the mixer at about 50 ° C. Cool to about 30 ° C and introduce phase D; the pH is adjusted with a citric acid solution.
- This cream is prepared having the following formulation:
- Phase A is heated to about 80 ° C.
- phase C In an auxiliary container, a premix is prepared with phase C: once this premix is obtained, it is added to phase B preheated to about 80.degree.
- Phase A previously prepared, is then added with moderate deflocculating stirring;
- phase D is added thereto.
- the final product is in the form of a creamy cream
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1200955A FR2988587B1 (fr) | 2012-03-30 | 2012-03-30 | Composition auto-emulsionnante |
PCT/FR2013/000083 WO2013144462A1 (fr) | 2012-03-30 | 2013-03-29 | Composition auto - emulsionnante comprenant un ester de polyglycerol et un ester de saccharose |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2830575A1 true EP2830575A1 (fr) | 2015-02-04 |
EP2830575B1 EP2830575B1 (fr) | 2018-11-28 |
Family
ID=48430822
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13722476.2A Active EP2830575B1 (fr) | 2012-03-30 | 2013-03-29 | Composition auto-emulsionnante comprenant un ester de polyglycerol et un ester de saccharose |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2830575B1 (fr) |
FR (1) | FR2988587B1 (fr) |
WO (1) | WO2013144462A1 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3053587B1 (fr) * | 2016-07-06 | 2019-07-05 | Oleon Nv | Composition notamment de type emulsion multiple et procede de preparation |
WO2023159563A1 (fr) * | 2022-02-28 | 2023-08-31 | L'oreal | Composition pour le soin et/ou le nettoyage de la peau |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0541830A1 (fr) * | 1991-11-09 | 1993-05-19 | ISP Van Dyk Inc. | Base d'absorption contenant un ester de sucrose |
-
2012
- 2012-03-30 FR FR1200955A patent/FR2988587B1/fr active Active
-
2013
- 2013-03-29 WO PCT/FR2013/000083 patent/WO2013144462A1/fr active Application Filing
- 2013-03-29 EP EP13722476.2A patent/EP2830575B1/fr active Active
Non-Patent Citations (1)
Title |
---|
See references of WO2013144462A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2013144462A1 (fr) | 2013-10-03 |
FR2988587B1 (fr) | 2014-08-29 |
EP2830575B1 (fr) | 2018-11-28 |
FR2988587A1 (fr) | 2013-10-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4527530B2 (ja) | ベシクル分散物およびこれを含有する化粧料 | |
JP2007532695A (ja) | スキンケア組成物 | |
JP4335003B2 (ja) | ワサビノキ油およびその誘導体を含む超安定組成物およびその使用 | |
CA2101760C (fr) | Composition formee d'une dispersion aqueuse de vesicules de lipides amphiphiles non-ioniques stabilisees | |
JP5083993B2 (ja) | 水中油型乳化組成物 | |
KR20180023537A (ko) | 고함량의 세라마이드를 포함하는 수중유형 에멀젼 조성물 및 이를 포함하는 화장료 조성물 | |
JP2016094398A (ja) | 乳化組成物 | |
JP2013001698A (ja) | 油性ゲル状クレンジング用組成物 | |
JP7179248B2 (ja) | 組成物、特に多重エマルジョン型の組成物及びその製造方法 | |
EP2830575B1 (fr) | Composition auto-emulsionnante comprenant un ester de polyglycerol et un ester de saccharose | |
US20050233015A1 (en) | Lanolin substitute based on shea butter | |
JP5973256B2 (ja) | スキンケア方法およびこれに用いる化粧料 | |
FR2918903A1 (fr) | "emulsions multiples naturelles" | |
JP4722351B2 (ja) | 酸化的に安定な長鎖エチルエステル皮膚軟化薬 | |
EP3630297B1 (fr) | Composition cosmétique foisonnée à haute teneur en beurre végétal | |
US20150004139A1 (en) | Emollient Compounds Useful for Treating Dry Skin Conditions | |
WO2024090431A1 (fr) | Ester d'acide gras de polyglycéryle | |
FR3088197A1 (fr) | Composition cosmetique apte a se transformer en poudre | |
BE1029000B1 (fr) | Composition cosmétique multi-actions | |
JP7470237B1 (ja) | クレンジングウォーター | |
WO2023117730A1 (fr) | Composition cosmétique foisonnée | |
EP4373458A1 (fr) | Composition cosmetique sous la forme d'emulsion huile-dans-eau a forte teneur en ingredients d'origine naturelle | |
JP2023056884A (ja) | 多層クレンジング化粧料 | |
CN117398300A (zh) | 水包油型乳化化妆品 | |
MXPA06003815A (es) | Composiciones humectantes. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20141030 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
DAX | Request for extension of the european patent (deleted) | ||
17Q | First examination report despatched |
Effective date: 20160406 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20180626 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1069396 Country of ref document: AT Kind code of ref document: T Effective date: 20181215 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602013047424 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: NV Representative=s name: RAPISARDI INTELLECTUAL PROPERTY SA, CH |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20181128 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 1069396 Country of ref document: AT Kind code of ref document: T Effective date: 20181128 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190228 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190328 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190228 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190301 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190328 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602013047424 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 |
|
26N | No opposition filed |
Effective date: 20190829 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190329 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20190331 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190329 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190331 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20130329 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181128 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20240307 Year of fee payment: 12 Ref country code: GB Payment date: 20240325 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20240325 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20240402 Year of fee payment: 12 |