EP2824355A1 - Coated springs used as special solution for avoiding resonances - Google Patents

Coated springs used as special solution for avoiding resonances Download PDF

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Publication number
EP2824355A1
EP2824355A1 EP13175815.3A EP13175815A EP2824355A1 EP 2824355 A1 EP2824355 A1 EP 2824355A1 EP 13175815 A EP13175815 A EP 13175815A EP 2824355 A1 EP2824355 A1 EP 2824355A1
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EP
European Patent Office
Prior art keywords
spring
coating
springs
damping element
damping
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP13175815.3A
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German (de)
French (fr)
Inventor
Gabriela Simbierowicz
Antti Saarelainen
Panu Ihalainen
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Kone Corp
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Kone Corp
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Priority to EP13175815.3A priority Critical patent/EP2824355A1/en
Publication of EP2824355A1 publication Critical patent/EP2824355A1/en
Withdrawn legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16FSPRINGS; SHOCK-ABSORBERS; MEANS FOR DAMPING VIBRATION
    • F16F3/00Spring units consisting of several springs, e.g. for obtaining a desired spring characteristic
    • F16F3/08Spring units consisting of several springs, e.g. for obtaining a desired spring characteristic with springs made of a material having high internal friction, e.g. rubber
    • F16F3/10Spring units consisting of several springs, e.g. for obtaining a desired spring characteristic with springs made of a material having high internal friction, e.g. rubber combined with springs made of steel or other material having low internal friction
    • F16F3/12Spring units consisting of several springs, e.g. for obtaining a desired spring characteristic with springs made of a material having high internal friction, e.g. rubber combined with springs made of steel or other material having low internal friction the steel spring being in contact with the rubber spring
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16FSPRINGS; SHOCK-ABSORBERS; MEANS FOR DAMPING VIBRATION
    • F16F1/00Springs
    • F16F1/02Springs made of steel or other material having low internal friction; Wound, torsion, leaf, cup, ring or the like springs, the material of the spring not being relevant
    • F16F1/024Covers or coatings therefor

Definitions

  • the invention pertains to damping elements for the reduction of resonances in machinery assemblies.
  • the resonances of the machinery parts of the same mechanical structure are influenced by a large range of loads, leads, roping options and operation speeds.
  • the entire structure of the motor or the whole machinery assembly could be calculated beforehand.
  • the general solution is not offering enough accuracy.
  • the resonance-frequencies depend on the speed of the car, the actual load, the length of the roping and the movement in the interior of the car. The exact calculation of the influence of all these items to the resonance-frequency or resonance-frequencies is nearly not possible.
  • the resonance frequencies of a part of the machine assembly inevitably shifts if external influences change or if the car actually moves. Thus, if one resonance frequency is excluded by a computed layout, other resonance frequencies may appear in the operation of the real machinery.
  • the object of the invention is to overcome these disadvantages and to provide damping elements optimizing a machinery assembly in regard to the reduction of resonances during operation.
  • a damping element according to the present invention comprises at least one spring-element that is coated with at least one coating-layer (coated spring).
  • Every body made of a material has a certain spring constant k, at least while used in the normal regions of force. Normally, this spring constant results from Hookes Law based on a proportionality between external force F and change of length ⁇ L.
  • F and ⁇ L are not exactly proportional.
  • a spring constant k could also be assigned to these bodies.
  • This spring constant then is an average value of all sub-spring constants dk over the interval of force that may be applied to this body while used normally.
  • the term 'normally' means that the force that is applied lies between 0 and a force that would lead to the destruction of the body or at least to regions where the deformation of the body is irreversible. The skilled person knows, which material is suitable for which force.
  • the spring constant of a spring k(spring) is either well known from the technical papers of the spring or may easily be calculated.
  • the 'whole interval of force' is the region of force between 0 and the maximal admissible force for the certain spring.
  • the spring constant of the coating k(coating) is either well known from the technical papers or may easily be calculated. If an average has to be calculated, this average is calculate for the whole interval of force, or preferably between 10% and 90%, especially between 30 and 70%, of the whole interval of force.
  • the advantageous effect of the present invention lies in the special combination of spring and coating.
  • the coated springs combine the advantages of springs, shifting resonances and enduring high temperatures and many cycles of deformation, and the advantages of rubber, namely the good damping effect.
  • the invention combines the advantage of shifting frequencies with the advantage of diminishing the amplitudes of forced vibrations.
  • the coating material characteristics are delaying and decreasing the response of the springs.
  • the coating of the actual spring-elements differs from coatings preventing corrosion.
  • the coating applies a measurable damping effect to the movement of the spring-elements.
  • the resultant spring constant k(spring) of all spring-elements of the damping element is greater than the spring constant k(coating) of the complete coating, particularly more than 100 times greater, preferably more than 1000 times greater, especially more than 10000 times greater. This has the advantage that the spring elements bear most of the deformation energy.
  • the resultant damping ratio (or 'damping factor') c(spring) of all spring elements of the damping element is smaller than the resultant damping ratio c(coating) of the complete coating, particularly more than 100 times smaller, preferably more than 10000 times smaller.
  • damping of the spring is smaller than 4 dB, preferably smaller than 10 dB, especially smaller than 20 dB. This has the advantage that the coating is able to effectively damp the movement of the spring-elements.
  • Preferred spring-elements are elements selected from the group compression springs, torsion springs, tension springs, wire shaped springs, flat section springs and disk-compressing-springs.
  • Preferred spring shapes are selected from the group comprising helical springs (coil springs), balance springs, leaf springs, V-springs, Belleville springs, spring washers, torsion springs and wave springs.
  • the spring shape is lamellar (e.g. disk-compressing-springs). This shape is advantageous to be used in a limited space. These springs could fit into flat parts of a machinery, for example the machinery of a hoisting system like an elevator.
  • the spring may also comprise or consist of plastic material and/or fiber-material.
  • the spring-element consists of or comprises spring steel.
  • the coating preferably comprises elastic materials and is applied on the surface of at least one of the spring elements, especially all of the spring elements of the damping element.
  • the respective spring elements may be coated on one side, two or more adjacent or opposite sides or all sides, where a complete coating on all sides of the respective spring elements is preferred.
  • the coating comprises or is made of an elastic material with the mass proportional Rayleigh damping coefficient ⁇ lying between 6 s -1 and 16 s -1 , preferably between 10 s -1 and 12 s -1 , and/or the stiffness proportional Rayleigh damping coefficient of the coating ⁇ lying between 0.0001 s -1 and 0.0004 s -1 , preferably between 0.0002 s -1 and 0.0003 s -1 .
  • Preferred materials are materials are elastomers, especially comprising elements of the group natural Polyisoprene, synthetic Polyisoprene, Polybutadiene, Chloroprene rubber, Butyl rubber, Styrene-butadiene rubber, Nitrile rubber, Ethylene Propylene rubber, Epichlorohydrin rubber, Polyacrylic rubber, Silicone rubber, Fluorosilicone rubber, Fluoroelastomers, Perfluoroelastomers, Polyether Block Amides, Chlorosulfonated Polyethylene, and Ethylene-vinyl Acetate.
  • the coating comprises rubber.
  • stiffness and damping may vary with frequency, load or temperature.
  • the Rayleigh formulation is suitable for these materials and the above mentioned damping factor can be used to compare the material with the damping factor of the spring.
  • the influence of the temperature in the non-linear case it is especially set to room temperature or the temperature of the respective part of the machine assembly.
  • the essential comparison of the values should be valid in regard to this temperature or temperature-ranges.
  • the influence of the oscillation-frequency in the non-linear case it is especially set to the region of 1 Hz to 100 Hz in the case of movement of a car of a lift or from 20Hz to 20kHz for vibro-acoustics.
  • the essential comparison of the values should be valid in regard to this frequency or frequency-ranges.
  • At least one damping element is used as damping element in a machinery assembly.
  • At least one coated spring is arranged in at least one certain critical area in the machinery.
  • At least one coated spring is especially arranged between the stator and the frame and/or between the motor and the lower bedplate and/or between the motor and any other supporting/mounting structure.
  • at least one coated spring is especially arranged between the car and sling on the bottom and/or on the top interface.
  • the present invention can be implemented e.g. in hoisting machines comprising motors with resonances for a certain speed, roping and load in car.
  • a preferred damping element comprising a helical spring element 1 that is coated with a coating material 2.
  • the spring forms the core of the damping element and the coating is arranged around the spring element.
  • Figure 2 shows an intersection of a preferred damping element comprising a lamellar spring element 1 that is coated with a coating material 2. This element can be used to damp machinery parts providing only small room for damping elements.

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Springs (AREA)

Abstract

Damping element, for the reduction of resonances in machinery assemblies, comprising at least one spring-element that is coated with at least one layer of coating, wherein the resultant spring constant k(spring) of all spring-elements of the damping element is greater than the spring constant k(coating) of the complete coating, and the resultant damping ratio c(spring) of all spring elements of the damping element is smaller than the resultant damping ratio c(coating) of the complete coating.

Description

  • The invention pertains to damping elements for the reduction of resonances in machinery assemblies.
  • In every machinery comprising moving parts inevitable resonances do occur during normal operation. Especially moving parts comprising imbalances, or if the movement is affected by rolling or sliding means, the respective parts are subject to disturbing resonances that negatively affect the operation of the machinery.
  • Especially in the technical field of hoisting machineries, the resonances of the machinery parts of the same mechanical structure are influenced by a large range of loads, leads, roping options and operation speeds.
  • In order to avoid resonances at nominal speeds, the entire structure of the motor or the whole machinery assembly could be calculated beforehand. However in most cases the general solution is not offering enough accuracy. For example for a hoisting machine, the resonance-frequencies depend on the speed of the car, the actual load, the length of the roping and the movement in the interior of the car. The exact calculation of the influence of all these items to the resonance-frequency or resonance-frequencies is nearly not possible. Regarding a real hoisting machine, the resonance frequencies of a part of the machine assembly inevitably shifts if external influences change or if the car actually moves. Thus, if one resonance frequency is excluded by a computed layout, other resonance frequencies may appear in the operation of the real machinery.
  • Also springs and rubber dampers are used to reduce resonances of machinery parts. However, often these solutions are not offering enough resonance-suppressing effect or show a performance-reduction after a certain time period.
  • The object of the invention is to overcome these disadvantages and to provide damping elements optimizing a machinery assembly in regard to the reduction of resonances during operation.
  • This object is accomplished according to the present invention by the use of damping elements as disclosed in the claims.
  • A damping element according to the present invention comprises at least one spring-element that is coated with at least one coating-layer (coated spring).
  • Every body made of a material has a certain spring constant k, at least while used in the normal regions of force. Normally, this spring constant results from Hookes Law based on a proportionality between external force F and change of length ΔL. In regard of certain materials, there could be bodies where the relation between F and ΔL is not exactly proportional. However, a spring constant k could also be assigned to these bodies. This spring constant then is an average value of all sub-spring constants dk over the interval of force that may be applied to this body while used normally. The term 'normally' means that the force that is applied lies between 0 and a force that would lead to the destruction of the body or at least to regions where the deformation of the body is irreversible. The skilled person knows, which material is suitable for which force.
  • In the following, the spring constant of a spring k(spring) is either well known from the technical papers of the spring or may easily be calculated. The 'whole interval of force' is the region of force between 0 and the maximal admissible force for the certain spring.
  • The spring constant of the coating k(coating) is either well known from the technical papers or may easily be calculated. If an average has to be calculated, this average is calculate for the whole interval of force, or preferably between 10% and 90%, especially between 30 and 70%, of the whole interval of force.
  • The advantageous effect of the present invention lies in the special combination of spring and coating. By using only springs as damping elements, the natural frequencies of the respective parts of the machinery assembly can be shifted, but no or low actual damping of the vibrations is induced in the machinery system. In case of forced vibrations this is a major drawback.
  • On the other hand, by using only dampers, the aging of the material and the damping dependency on speed and temperature are affecting the performance of the machinery system. In case of a motor, the selection of rubber or polyurethane resistant at the normal temperature of the active motor is limited.
  • The coated springs combine the advantages of springs, shifting resonances and enduring high temperatures and many cycles of deformation, and the advantages of rubber, namely the good damping effect. Thus, the invention combines the advantage of shifting frequencies with the advantage of diminishing the amplitudes of forced vibrations. The coating material characteristics are delaying and decreasing the response of the springs.
  • The coating of the actual spring-elements differs from coatings preventing corrosion. Here, the coating applies a measurable damping effect to the movement of the spring-elements.
  • To achieve this, it is an essential feature of the invention, that the resultant spring constant k(spring) of all spring-elements of the damping element is greater than the spring constant k(coating) of the complete coating, particularly more than 100 times greater, preferably more than 1000 times greater, especially more than 10000 times greater. This has the advantage that the spring elements bear most of the deformation energy.
  • In addition, the resultant damping ratio (or 'damping factor') c(spring) of all spring elements of the damping element is smaller than the resultant damping ratio c(coating) of the complete coating, particularly more than 100 times smaller, preferably more than 10000 times smaller.
  • Since damping is often given in dB, it could also be said that the damping of the spring is smaller than 4 dB, preferably smaller than 10 dB, especially smaller than 20 dB. This has the advantage that the coating is able to effectively damp the movement of the spring-elements.
  • Especially in regard of oscillations due to external forces, most of the deforming energy goes into the deformation of the spring elements and the coating is not worn out due to these deformations, while the coating is able to damp the movements of the spring elements resulting in the damping of the oscillations without overstraining the material of the coating.
  • Preferred spring-elements are elements selected from the group compression springs, torsion springs, tension springs, wire shaped springs, flat section springs and disk-compressing-springs.
  • Preferred spring shapes are selected from the group comprising helical springs (coil springs), balance springs, leaf springs, V-springs, Belleville springs, spring washers, torsion springs and wave springs.
  • In a preferred embodiment, the spring shape is lamellar (e.g. disk-compressing-springs). This shape is advantageous to be used in a limited space. These springs could fit into flat parts of a machinery, for example the machinery of a hoisting system like an elevator.
  • Although metal is especially preferred as material for the spring, the spring may also comprise or consist of plastic material and/or fiber-material. In a preferred embodiment the spring-element consists of or comprises spring steel.
  • The coating preferably comprises elastic materials and is applied on the surface of at least one of the spring elements, especially all of the spring elements of the damping element.
  • The respective spring elements may be coated on one side, two or more adjacent or opposite sides or all sides, where a complete coating on all sides of the respective spring elements is preferred.
  • The material damping factor c, could preferably be computed by using the Rayleigh-equation that combines the damp lower mass dependent and higher stiffness dependent frequency range behavior c = α 2 ω + β 2 ω ,
    Figure imgb0001
    where
    α is the mass proportional Rayleigh damping coefficient,
    β is the stiffness proportional Rayleigh damping coefficient and
    ω n is the Eigen angular frequency.
  • In a preferred embodiment, the coating comprises or is made of an elastic material with the mass proportional Rayleigh damping coefficient α lying between 6 s-1 and 16 s-1, preferably between 10 s-1 and 12 s-1, and/or the stiffness proportional Rayleigh damping coefficient of the coating β lying between 0.0001 s-1 and 0.0004 s-1, preferably between 0.0002 s-1 and 0.0003 s-1. Preferred materials are materials are elastomers, especially comprising elements of the group natural Polyisoprene, synthetic Polyisoprene, Polybutadiene, Chloroprene rubber, Butyl rubber, Styrene-butadiene rubber, Nitrile rubber, Ethylene Propylene rubber, Epichlorohydrin rubber, Polyacrylic rubber, Silicone rubber, Fluorosilicone rubber, Fluoroelastomers, Perfluoroelastomers, Polyether Block Amides, Chlorosulfonated Polyethylene, and Ethylene-vinyl Acetate. Commonly, the coating comprises rubber.
  • It may happen that one of the above materials, e.g. rubbers have nonlinear behaviors regarding stiffness and damping. This means that stiffness and damping may vary with frequency, load or temperature.
  • However, the Rayleigh formulation is suitable for these materials and the above mentioned damping factor can be used to compare the material with the damping factor of the spring.
  • Regarding the influence of the temperature in the non-linear case, it is especially set to room temperature or the temperature of the respective part of the machine assembly. In general, it is preferred to make the above mentioned comparison of the spring constants and the damping factors at temperatures or temperature-ranges of the chosen environment of the damping element. The essential comparison of the values (greater/smaller, 100 times, 10000 times) should be valid in regard to this temperature or temperature-ranges.
  • Regarding the influence of the oscillation-frequency in the non-linear case, it is especially set to the region of 1 Hz to 100 Hz in the case of movement of a car of a lift or from 20Hz to 20kHz for vibro-acoustics. In general, it is preferred to make the above mentioned comparison of the spring constants and the damping factors at frequencies or frequency-ranges of the chosen environment of the damping element. The essential comparison of the values (greater/smaller, 100 times, 10000 times) should be valid in regard to this frequency or frequency-ranges.
  • The same is especially valid for loads.
  • According to the present invention, at least one damping element is used as damping element in a machinery assembly.
  • In a preferred embodiment, at least one coated spring is arranged in at least one certain critical area in the machinery.
  • Regarding a motor assembly at least one coated spring is especially arranged between the stator and the frame and/or between the motor and the lower bedplate and/or between the motor and any other supporting/mounting structure. Regarding the case of an inside area of the elevator, at least one coated spring is especially arranged between the car and sling on the bottom and/or on the top interface. The present invention can be implemented e.g. in hoisting machines comprising motors with resonances for a certain speed, roping and load in car.
  • Examples of preferred embodiments of the invention are shown in the figures and described in the following.
    • Figure 1 shows a perspective example of a damping element comprising a helical spring element.
    • Figure 2 shows an example of a damping element comprising a lamellar spring element in side view.
  • In Figure 1, a preferred damping element comprising a helical spring element 1 that is coated with a coating material 2. The spring forms the core of the damping element and the coating is arranged around the spring element.
  • Figure 2 shows an intersection of a preferred damping element comprising a lamellar spring element 1 that is coated with a coating material 2. This element can be used to damp machinery parts providing only small room for damping elements.

Claims (10)

  1. Damping element, for the reduction of resonances in machinery assemblies, comprising at least one spring-element that is coated with at least one layer of coating,
    characterized in that, the resultant spring constant k(spring) of all spring-elements of the damping element is greater than the spring constant k(coating) of the complete coating, and the resultant damping ratio c(spring) of all spring elements of the damping element is smaller than the resultant damping ratio c(coating) of the complete coating.
  2. Damping element as claimed in claim 1,
    characterized in that, the resultant spring constant k(spring) of all spring-elements of the damping element is greater than 100 times, preferably more than 1000 times greater, than the spring constant k(coating) of the complete coating.
  3. Damping element as claimed in claim 1 or 2,
    characterized in that, the resultant damping ratio c(spring) of all spring elements of the damping element is more than 100 times smaller, preferably more than 10000 times smaller, than the resultant damping ratio c(coating) of the coating.
  4. Damping element as claimed in one of claims 1 to 3,
    characterized in that, at least one of the spring-elements is selected from the group comprising compression springs, torsion springs, tension springs, wire shaped springs, flat section springs and disk-compressing-springs, and/or its spring shape is selected from the group comprising helical springs, balance springs, leaf springs, V-springs, Belleville springs, spring washers, torsion springs and wave springs.
  5. Damping element as claimed in one of claims 1 to 4,
    characterized in that, the spring comprises or consists of metal, especially spring steel, and/or plastic material and/or fiber-material.
  6. Damping element as claimed in one of claims 1 to 5,
    characterized in that, the coating comprises or is made of an elastic material with the mass proportional Rayleigh damping coefficient α lying between 6 s-1 and 16 s-1, preferably between 10 s-1 and 12 s-1, and/or the stiffness proportional Rayleigh damping coefficient of the coating α lying between 0.0001 s-1 and 0.0004 s-1, preferably between 0.0002 s-1 and 0.0003 s-1.
  7. Damping element as claimed in one of claims 1 to 6, characterized in that the material of the coating comprises at least one elastomer-material, especially comprising elements of the group Natural Polyisoprene, Synthetic Polyisoprene, Polybutadiene, Chloroprene rubber, Butyl rubber, Styrene-Butadiene rubber, Nitrile rubber, Ethylene Propylene rubber, Epichlorohydrin rubber, Polyacrylic rubber, Silicone rubber, Fluorosilicone rubber, Fluoroelastomers, Perfluoroelastomers, Polyether block amides, Chlorosulfonated Polyethylene, and Ethylene-vinyl Acetate.
  8. Use of at least one damping element as claimed in the above claims as damping element in a machinery assembly.
  9. Use as claimed in claim 8, wherein at least one coated spring is arranged in at least one certain critical area in the machinery, preferably between the stator and the frame of a motor and/or between the motor and the lower bedplate and/or between the motor and any other supporting or mounting structure, or preferably, in the case of an in the elevator, between the car and sling on the bottom and/or on the top interface.
  10. Machine assembly, characterized in that, it comprises at least one damping element as claimed in the above claims 1 to 7.
EP13175815.3A 2013-07-09 2013-07-09 Coated springs used as special solution for avoiding resonances Withdrawn EP2824355A1 (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107855390A (en) * 2017-10-30 2018-03-30 浙江骏马弹簧制造有限公司 A kind of serpentine spring and its production technology for shaft coupling
RU2673435C2 (en) * 2015-08-21 2018-11-26 Владимир Владимирович Харин Hybrid pneumatic spring
CN109575380A (en) * 2018-12-13 2019-04-05 株洲飞马橡胶实业有限公司 A kind of high-damping, high abrasion, isoprene rubber of low creep and its preparation method and application
WO2022013529A1 (en) * 2020-07-14 2022-01-20 Techflow Marine Limited Hose end valve

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5395456A (en) * 1977-02-01 1978-08-21 Matsushita Electric Ind Co Ltd Silent spring
DE7809523U1 (en) * 1978-03-31 1982-07-15 Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt COIL SPRING
US4753423A (en) * 1985-06-03 1988-06-28 Nippon Petrochemicals Co., Ltd Synthetic resin-coated spring and method for making same
US4763882A (en) * 1984-05-21 1988-08-16 Nhk Spring Co., Ltd. Coated coil spring
US20020190453A1 (en) * 2001-06-15 2002-12-19 Colder Products Company Coated spring and method of making the same

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5395456A (en) * 1977-02-01 1978-08-21 Matsushita Electric Ind Co Ltd Silent spring
DE7809523U1 (en) * 1978-03-31 1982-07-15 Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt COIL SPRING
US4763882A (en) * 1984-05-21 1988-08-16 Nhk Spring Co., Ltd. Coated coil spring
US4753423A (en) * 1985-06-03 1988-06-28 Nippon Petrochemicals Co., Ltd Synthetic resin-coated spring and method for making same
US20020190453A1 (en) * 2001-06-15 2002-12-19 Colder Products Company Coated spring and method of making the same

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2673435C2 (en) * 2015-08-21 2018-11-26 Владимир Владимирович Харин Hybrid pneumatic spring
CN107855390A (en) * 2017-10-30 2018-03-30 浙江骏马弹簧制造有限公司 A kind of serpentine spring and its production technology for shaft coupling
CN107855390B (en) * 2017-10-30 2019-04-19 浙江骏马弹簧制造有限公司 A kind of serpentine spring and its production technology for shaft coupling
CN109575380A (en) * 2018-12-13 2019-04-05 株洲飞马橡胶实业有限公司 A kind of high-damping, high abrasion, isoprene rubber of low creep and its preparation method and application
WO2022013529A1 (en) * 2020-07-14 2022-01-20 Techflow Marine Limited Hose end valve

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