EP2779989A2 - Produit servant à la mise en forme temporaire de fibres kératiniques, à base d'une combinaison de polymères filmogènes spécifiques - Google Patents

Produit servant à la mise en forme temporaire de fibres kératiniques, à base d'une combinaison de polymères filmogènes spécifiques

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Publication number
EP2779989A2
EP2779989A2 EP12775032.1A EP12775032A EP2779989A2 EP 2779989 A2 EP2779989 A2 EP 2779989A2 EP 12775032 A EP12775032 A EP 12775032A EP 2779989 A2 EP2779989 A2 EP 2779989A2
Authority
EP
European Patent Office
Prior art keywords
dme
formula
weight
copolymer
cosmetic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12775032.1A
Other languages
German (de)
English (en)
Inventor
Diane Metten
Bernd Richters
Johanna THOMS
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP2779989A2 publication Critical patent/EP2779989A2/fr
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/594—Mixtures of polymers

Definitions

  • keratinic fibers in principle, all animal hair, e.g. Wool, horsehair, angora hair, furs, feathers and products or textiles made from them.
  • animal hair e.g. Wool, horsehair, angora hair, furs, feathers and products or textiles made from them.
  • the keratinic fibers are human hairs.
  • polymers in various cosmetic products is widespread. They are found in agents for the treatment of the skin as well as in means for the treatment of hair, in agents which are washed off or washed off again immediately after use, so-called rinse-off products, as well as in compositions which are applied to the skin or skin Hair remains, so-called leave-on remedies.
  • the polymers are used for various reasons and in each case exploited certain properties of the polymers.
  • agents for skin treatment in shampoos, hair conditioners and hair treatments, the thickening or care properties of the polymers are often in the foreground.
  • styling agents in addition to these properties, above all film-forming and / or strengthening effects are required.
  • polymers also serve as an aid to improve the deposition and fixation of other active ingredients and ingredients on the skin or hair or make it possible.
  • rubbing fastness and the stability of the dyeing can be increased.
  • cosmetic products contain individual polymers that are specially tailored to achieve a very specific effect. If different effects are to be achieved, the addition of several polymers is required. However, using too many different polymers can bring a number of disadvantages. Thus, formulation problems may arise, for example because the polymers react with each other or with other ingredients of the composition and precipitates or decomposes. Certain polymers also tend to deposit so consistently on the skin, and more particularly on the hair, that they are no longer completely removed in an ordinary wash and there is an undesirable accumulation of the polymer and thus ultimately stress on the skin or hair.
  • styling agents it is necessary for the polymers used to give the treated hair the strongest possible hold.
  • styling agents must meet a whole range of other requirements. These may be broadly subdivided into properties on the hair, properties of the particular formulation, eg properties of the foam, of the gel or of the sprayed aerosol, and of properties relating to the handling of the styling agent, the properties of the hair being of particular importance. Particularly noteworthy are moisture resistance, low tackiness and a balanced conditioning effect.
  • a styling agent should be universally applicable as possible for all hair types. If the styling agent is a gel or a paste, the polymers should also have thickening properties.
  • the object of the present invention was therefore to provide further suitable polymer combinations, which are characterized by good film-forming and / or setting properties, have a very high degree of retention without sacrificing flexibility and good moisture resistance - in particular sweat and water resistance and would also be suitable for the production of stable viscous and stable transparent cosmetic compositions.
  • a first subject of the present application is therefore a cosmetic agent containing in a cosmetically acceptable carrier
  • copolymers A used according to the invention are obtained by polymerization of the monomers n-butyl methacrylate, methacrylic acid, ethyl acrylate and ethyl methacrylate and optionally other monomers.
  • Preferred copolymers A consist of at least 90% by weight, preferably at least 95% by weight and in particular at least 97% by weight, of the monomers n-butyl methacrylate, methacrylic acid, ethyl acrylate and ethyl methacrylate.
  • Particularly preferred are copolymers A, which were obtained exclusively from the monomers n-butyl methacrylate, methacrylic acid, ethyl acrylate and ethyl methacrylate.
  • the copolymers A have from 35 to 65% by weight of n-butyl methacrylate, from 10 to 30% by weight of methacrylic acid, from 5 to 15% by weight of ethyl acrylate and from 10 to 35% by weight of ethyl methacrylate, copolymers A with a weight proportion of the monomers of 38 to 60 wt .-% n-butyl methacrylate, 15 to 25 wt .-% methacrylic acid, 8 to 15 wt .-% ethyl acrylate and 15 to 25 wt .-% ethyl methacrylate are particularly preferred.
  • Very particularly preferred copolymers A have a weight fraction of the monomers of from 44 to 56% by weight of n-butyl methacrylate, from 17 to 22% by weight of methacrylic acid, from 9 to 15% by weight of ethyl acrylate and from 15 to 25% by weight of ethyl methacrylate.
  • the weight ratio of the monomers ethyl methacrylate and ethyl acrylate in the copolymers A is preferably 4: 1 to 1: 1, preferably 2: 1 to 1: 1 and in particular 2: 1 to 1, 3: 1.
  • the copolymers A preferably have a molecular weight of about 100 kDa.
  • the glass transition temperature is preferably between 80 and 120 ° C.
  • the particle size of the polymer particles (X-50) is preferably in the range between 50 and 500 ⁇ m, preferably between 200 and 500 ⁇ m.
  • copolymers A described above are, for example, under the name ® Tilamar Fix A1000 (INCI: Acrylates copolymer; CAS Number: 1070166-98-1) from DSM sold.
  • Preferred agents according to the invention are characterized in that the weight fraction of the copolymer A in the total weight of the cosmetic agent is between 0.5 and 10% by weight, preferably between 1, 0 and 8.0% by weight and in particular between 2.0 and 6 , 0 wt .-% is.
  • the copolymer A is used in the cosmetic compositions, preferably in teilneutraliserter or neutralized form.
  • at least one alkanolamine is preferably used.
  • the alkanolamines which can be used as alkalizing agents according to the invention are preferably selected from primary amines having a C 2 -C 6 -alkyl basic body which carries at least one hydroxyl group.
  • alkanolamines are selected from the group formed from 2-aminoethan-1-ol (monoethanolamine), tris (2-hydroxyethyl) amine (triethanolamine), 3-aminopropan-1-ol, 4-aminobutane-1 -ol, 5-aminopentan-1-ol, 1-aminopropan-2-ol, 1-aminobutan-2-ol, 1-aminopentan-2-ol, 1-aminopentan-3-ol, 1-aminopentan-4-ol , 3-Amino-2-methylpropan-1-ol, 1-amino-2-methylpropan-2-ol, 3-aminopropane-1, 2-diol, 2-amino-2-methylpropane-1,3-diol.
  • Very particularly preferred alkanolamines according to the invention are selected from the group consisting of 2-aminoethane-1-ol, 2-amino-2-methylpropan-1-ol and 2-amino-2-methyl-propane-1,3-diol.
  • a particularly suitable neutralizing agent has thereby proven 2-amino-2-methylpropanol.
  • Cosmetic agents preferred according to the invention therefore contain 2-amino-2-methylpropanol.
  • the 2-amino-2-methylpropanol is preferably used in the compositions according to the invention in an amount which does not exceed the amount needed to neutralize the copolymer A.
  • the amounts of 2-amino-2-methylpropanol used in the agents according to the invention are preferably 80 to 100%, particularly preferably 90 to 100% and in particular 95 to 100% of the amount required for the complete neutralization of the copolymer A.
  • the proportion by weight of 2-amino-2-methylpropanol in the total weight of the cosmetic agent is from 0.1 to 4.0% by weight, preferably from 0.2 to 3.0% by weight and in particular from 0.5 to 2 , 0% by weight.
  • copolymers B used according to the invention are obtained by polymerization of the monomers N-vinylpyrrolidone, N-vinylcaprolactam, optionally other monomers.
  • the copolymer B is obtained by copolymerization of the monomers N-vinylpyrrolidone, N-vinylcaprolactam and N, N-dimethylaminoethyl methacrylate.
  • the above-mentioned monomer b3) is N, N-dimethylaminoethyl methacrylate.
  • Preferred copolymers B consist of at least 90% by weight, preferably at least 95% by weight and in particular at least 97% by weight, of the monomers N-vinylpyrrolidone, N-vinylcaprolactam and N, N-dimethylaminoethyl methacrylate.
  • copolymers B were obtained exclusively from the monomers N-vinylpyrrolidone, N-vinylcaprolactam and ⁇ , ⁇ -dimethylaminoethyl methacrylate.
  • Such copolymers can be synthesized, for example, under the trade name Advantage LC-E (INCI name: vinylcaprolactam / VP / dimethylaminoethyl methacrylate copolymer, laurylpyrrolidone, 37% by weight of active substance in ethanol with the addition of N-laurylpyrrolidone) or Advantage LC-A (INCI name: Vinylcaprolactam / VP / dimethylaminoethyl methacrylate copolymer, 37% by weight of active substance in ethanol) from ISP.
  • Advantage LC-E ICI name: vinylcaprolactam / VP / dimethylaminoethyl methacrylate copolymer, laurylpyrrolidone, 37% by
  • the copolymer B is obtained by copolymerization of the monomers N-vinylpyrrolidone, N-vinylcaprolactam and N, N-dimethylaminopropylmethacrylamide.
  • the monomer b3) mentioned above is particularly preferably ⁇ , ⁇ -dimethylaminopropylmethacrylamide.
  • Preferred copolymers B consist of at least 90% by weight, preferably at least 95% by weight and in particular at least 97% by weight, of the monomers N-vinylpyrrolidone, N-vinylcaprolactam and N, N-dimethylaminopropylmethacrylamide.
  • copolymers B were obtained exclusively from the monomers N-vinylpyrrolidone, N-vinylcaprolactam and N, N-dimethylaminopropylmethacrylamide.
  • Such copolymers are available, for example, under the trade name Aquaflex SF 40 (INCI name: VP / Vinyl Caprolactam / DMAPA Acrylates Copolymer, Alcohol Denat, 38-42% by weight of active substance in ethanol) from ISP.
  • Preferred agents according to the invention are characterized in that the weight fraction of the copolymer B in the total weight of the cosmetic composition is between 0.5 and 10% by weight, preferably between 1, 0 and 8.0% by weight and in particular between 2.0 and 6 , 0 wt .-% is.
  • compositions of the invention are distinguished from cosmetic agents with alternative vinylpyrrolidone copolymers in addition to the abovementioned advantages, in particular by an improved degree of hold.
  • a weight ratio of the copolymers A and B has proven to be between 2: 5 and 5: 2, preferably between 1: 2 and 2: 1 and in particular between 2: 3 and 3: 2.
  • Cosmetic agents in which the ratio of the proportions by weight of copolymer A and copolymer B in the composition is between 2: 5 and 5: 2, preferably between 1: 2 and 2: 1 and in particular between 2: 3 and 3: 2, therefore become preferred according to the invention.
  • the proportion by weight of the copolymers A and B in the total weight of the cosmetic agent is preferably between 1.0 and 11% by weight, preferably between 2.0 and 9.0% by weight and in particular between 4.0 and 8.0% by weight .-%
  • the cosmetic agents according to the invention may contain, in addition to the two copolymers A and B described above, further film-forming and / or setting polymers.
  • Preferred film-forming and / or setting polymers are copolymers of maleic anhydride and methyl vinyl ether.
  • Particularly preferred film-forming and / or setting polymers are anionic.
  • an anionic polymer is understood as meaning a polymer which, in standard conditions, contains structural units in a protic solvent with anionic groups which have to be compensated by counterions while maintaining electroneutrality and which has no structural units with permanently cationic groups.
  • Anionic groups include carboxyl and sulfonic acid groups.
  • Copolymer A from the monomers a1) n-butyl methacrylate, a2) methacrylic acid, a3) ethyl acrylate and a4) ethyl methacrylate and optionally other monomers
  • Copolymer B from the monomers b1) N-vinylpyrrolidone, b2) N-vinylcaprolactam and b3) optionally other monomers
  • compositions of the invention contain the polymers in a cosmetically acceptable carrier.
  • Preferred cosmetically acceptable carriers are aqueous, alcoholic or aqueous-alcoholic media.
  • Preferred cosmetic agent contain, based on their total weight, a water content of 0 to 20 wt .-%, preferably 0.5 to 20 wt .-%, preferably from 1, 0 to 15 wt .-% and in particular from 1, 0 to 10% by weight.
  • alcohols it is possible in particular to include the lower alcohols having 1 to 4 carbon atoms usually used for cosmetic purposes, such as, for example, ethanol and isopropanol.
  • Additional co-solvents may include other organic solvents or a mixture of solvents.
  • Particularly suitable as additional co-solvents are unbranched or branched hydrocarbons such as hexane, isopentane and cyclic hydrocarbons such as cyclopentane and cyclohexane.
  • Cosmetic agent containing, based on their total weight, from 20 to 99% by weight, preferably from 20 to 98% by weight, preferably from 40 to 90% by weight and in particular from 60 to 85% by weight of organic solvent preferred according to the invention.
  • the cosmetic compositions preferably have a pH (25 ° C) of from 3.5 to 9.0. Particularly preferred is the pH range of 4.0 to and 7.5 and in particular from 4.0 to 6.0. Agents with these preferred pH values have a particularly good skin tolerance. Due to their pH, corresponding formulations are also suitable for compounding in metallic spray cans, for example aerosol cans.
  • composition of some preferred cosmetic agents can be found in the following tables (data in% by weight based on the total weight of the cosmetic agent, unless stated otherwise).
  • Copolymer A from the monomers a1) n-butyl methacrylate, a2) methacrylic acid, a3) ethyl acrylate and a4) ethyl methacrylate and optionally other monomers ** Copolymer B from the monomers b1) N-vinylpyrrolidone, b2) N-vinylcaprolactam and b3) optionally other monomers
  • the cosmetic compositions of the invention may contain further ingredients.
  • the group of these other ingredients include in particular the cosmetically active auxiliaries and additives.
  • auxiliaries and additives in particular additional care substances are mentioned.
  • a silicone oil and / or a silicone gum can be used as a care material.
  • Silicone oils or silicone gums which are suitable according to the invention are in particular dialkyl and alkylaryl siloxanes, for example dimethylpolysiloxane and methylphenylpolysiloxane, and also their alkoxylated, quaternized or else anionic derivatives. Preference is given to cyclic and linear polydialkylsiloxanes, their alkoxylated and / or aminated derivatives, dihydroxypoly-dimethylsiloxanes and polyphenylalkylsiloxanes.
  • the agent may contain, for example, at least one protein hydrolyzate and / or one of its derivatives.
  • Protein hydrolysates are product mixtures obtained by acid, alkaline or enzymatically catalyzed degradation of proteins (proteins).
  • the term protein hydrolyzates also means total hydrolyzates as well as individual amino acids and their derivatives as well as mixtures of different amino acids.
  • the molecular weight of the protein hydrolysates which can be used according to the invention is between 75, the molecular weight for glycine, and 200,000, preferably the molecular weight is 75 to 50,000 and very particularly preferably 75 to 20,000 daltons.
  • the agent according to the invention may further comprise at least one vitamin, a provitamin, a vitamin precursor and / or one of their derivatives.
  • vitamins, provitamins and vitamin precursors are preferred, which are usually assigned to groups A, B, C, E, F and H.
  • panthenol increases the flexibility of the polymer film formed using the composition of the present invention.
  • compositions according to the invention may further contain at least one plant extract, but also mono- or oligosaccharides and / or lipids.
  • oil bodies are suitable as a care substance.
  • the natural and synthetic cosmetic oil bodies include, for example, vegetable oils, liquid paraffin oils, Isoparaffin oils and synthetic hydrocarbons and di-n-alkyl ethers having a total of between 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms.
  • Esteröle that is, esters of C 6 - C 30 - fatty acids with C 2 - C 30 - fatty alcohols, preferably Monoester of fatty acids with alcohols having from 2 to 24 carbon atoms such as isopropyl myristate (IPM Rilanit ®), isononanoic acid C16-18- alkyl ester (Cetiol ® SN), 2-ethylhexyl palmitate (Cegesoft ® 24), stearic acid-2-ethylhexyl ester (Cetiol ® 868), cetyl oleate, glycerol tricaprylate, cocofatty alcohol-caprinatV caprylate (Cetiol ® LC), n-butyl stearate, oleyl erucate (Cetiol ® J (600), isopropyl palmitate (Rilanit ® IPP), oleyl Oleate (Ceti
  • a preferred cosmetic agent according to the invention is characterized in that the cosmetic agent, based on its total weight, 0.01 to 5.0 wt .-%, preferably 0.02 to 4.0 wt .-% and in particular 0.05 to 2 , 0 wt .-% of an oil body.
  • composition of some preferred cosmetic agents can be found in the following tables (data in% by weight based on the total weight of the cosmetic agent, unless stated otherwise).
  • Alkanolamine *** 80 to 100 90 to 100 95 to 100 98 98
  • Isopropyl myristate 0.01 to 5.0 0.02 to 4.0 0.05 to 2.0 0, 1 0.1
  • Copolymer A from the monomers a1) n-butyl methacrylate, a2) methacrylic acid, a3) ethyl acrylate and a4) ethyl methacrylate
  • Copolymer B from the monomers b1) N-vinylpyrrolidone, b2) N-vinylcaprolactam, b3) N, N-dimethylaminoethyl methacrylate
  • composition of further preferred cosmetic agents can be found in the following tables (data in% by weight based on the total weight of the cosmetic agent, unless stated otherwise).
  • Formula 106 Formula 107 Formula 108 Formula 109 Formula 1 10 Copolymer A * 0.5 to 10 1, 0 to 8.0 2.0 to 6.0 5.2 3.5
  • Alkanolamine *** 80 to 100 90 to 100 95 to 100 98 98
  • Isopropyl myristate 0.01 to 5.0 0.02 to 4.0 0.05 to 2.0 0.1 0.1
  • Mise add 100 add 100 add 100 add 100 pH 3.5 to 9.0 4.0 to 7.5 4.0 to 6.0 5.0 5.0
  • Copolymer A from the monomers a1) n-butyl methacrylate, a2) methacrylic acid, a3) ethyl acrylate and a4) ethyl methacrylate
  • Copolymer B from the monomers b1) N-vinylpyrrolidone, b2) N-vinylcaprolactam, b3) N, N-dimethylaminopropylmethacrylamide
  • dicarboxylic acid esters symmetrical, unsymmetrical or cyclic esters of carbonic acid with fatty alcohols
  • triflic acid esters of saturated and / or unsaturated linear and / or branched fatty acids with glycerol or fatty acid partial glycerides which are understood to mean monoglycerides, diglycerides and technical mixtures thereof.
  • compositions according to the invention can be carried out in all forms customary for cosmetic compositions, for example in the form of solutions which can be applied to the hair as hair lotions, pump or aerosol spray, in the form of creams, emulsions, waxes, gels or surfactant-containing foaming agents Solutions or other preparations suitable for use on the hair.
  • the agents according to the invention are preferably in liquid form, for example in the form of a spray or aerosol spray. However, in an alternative embodiment, these agents may also be in gel or cream form, with transparent gels being particularly preferred.
  • the preferred aerosol sprays contain, in addition to other active ingredients and auxiliaries, a blowing agent.
  • Propellants propellant gases
  • hydrophilic propellants such as carbon dioxide, can be used advantageously in the context of the present invention, when the proportion of hydrophilic gases is selected low and lipophilic propellant gas (eg., Propane / butane) in Excess is present.
  • Particularly preferred are dimethyl ether, propane, n-butane, isobutane and mixtures of these propellants. Very particular preference is given to the use of dimethyl ether as sole propellant gas.
  • compositions containing the propellant based on their total weight in an amount of 10 to 90% by weight, preferably 20 to 80% by weight and more preferably 40 to 70% by weight, are preferred according to the invention. Since the propellants in blowing agent-containing preparations also have a solvent function, such preparations may have a low content of other organic solvents.
  • composition of some preferred propellant-containing cosmetic agents can be seen from the following tables.
  • Form x refers to each one of the exemplary cosmetic compositions set forth in the tables disclosed above.
  • columns two to five in line 12 of the table below describe four cosmetic preparations comprising a cosmetic agent according to formula I 1 (see corresponding table on page 7 above) comprising
  • copolymer A from the monomers a1) n-butyl methacrylate, a2) methacrylic acid, a3) ethyl acrylate and a4) ethyl methacrylate and optionally other monomers;
  • copolymer B from the monomers b1) N-vinylpyrrolidone, b2) N-vinylcaprolactam and b3) optionally other monomers
  • DME dimethyl ether
  • a cosmetic preparation according to row 12, column 5 of the table below comprises a 1: 1 mixture of the propellant-free cosmetic agent according to formula 1 1 with dimethyl ether. Blowing agent [% by weight]
  • Formula 1 80 to 140 100 80 to 140 DME 100 DME
  • Formula 1 80 to 140 100 80 to 140 DME 100 DME
  • Formula 1 12 80 to 140 100 80 to 140 DME 100 DME
  • Formula 1 13 80 to 140 100 80 to 140 DME 100 DME
  • Formula 1 14 80 to 140 100 80 to 140 DME 100 DME
  • Formula 1 15 80 to 140 100 80 to 140 DME 100 DME
  • Formula 1 16 80 to 140 100 80 to 140 DME 100 DME
  • Formula 1 17 80 to 140 100 80 to 140 DME 100 DME
  • Formula 1 18 80 to 140 100 80 to 140 DME 100 DME
  • Formula 1 19 80 to 140 100 80 to 140 DME 100 DME
  • a cosmetic agent according to the invention for the temporary deformation of keratinous fibers is a further subject matter of the present application.
  • the agents according to the invention are characterized in particular by an improved hold during the temporary deformation of keratinous fibers.
  • An additional subject of the present application is therefore the use of a cosmetic agent according to the invention for improving the hold during the temporary deformation of keratinic fibers.
  • compositions were prepared by mixing the specified raw materials (the amounts are understood - unless otherwise stated - in percent by weight of active substance):
  • compositions were tested for their molding properties using a High Humidity Curl Retention Measurement.
  • standardized hair strands of the company Kerling (Item No. 827560) of the hair type "European Natural, Color 6/0" of a length (L max ) of 220 mm and a weight of 0.6 g were used.
  • the strands were washed with a 12.5% by weight sodium laureth sulphate solution.
  • the hair strands were dried overnight in a drying oven at 318K.
  • compositions 1 to 5 were applied to a strand of hair and massaged.
  • the tresses were then wound on a winder (Fripac-medis, diameter 7 mm, Art. No. D-1203) and dried overnight at room temperature.
  • the winder was carefully removed and the strands were hung.
  • the lengths of the curls were each measured (L 0 ) and the strands placed in a climatic chamber. There they were stored at 294 K and a relative humidity of 85% over a period of 24H. Then the lengths of the curls were measured (L t ). For each of Compositions 1 to 5, five test strands were measured.
  • HHCR High-Humidity Curl-Retention
  • the arithmetic mean was formed from the HHCR values of the five test strands.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des produits cosmétiques contenant dans un support cosmétiquement acceptable : a) au moins un copolymère A composé des monomères a1) méthacrylate de n-butyle, a2) acide méthacrylique, a3) acrylate d'éthyle, a4) méthacrylate d'éthyle ainsi qu'éventuellement d'autres monomères ; b) au moins un copolymère B différent du copolymère A et composé des monomères b1) caprolactame de N-vinyle, b2) pyrrolidone de N-vinyle, b3) éventuellement d'autres monomères. Lesdits produits sont particulièrement appropriés pour la mise en forme temporaire de fibres kératiniques.
EP12775032.1A 2011-11-17 2012-10-23 Produit servant à la mise en forme temporaire de fibres kératiniques, à base d'une combinaison de polymères filmogènes spécifiques Withdrawn EP2779989A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE201110086529 DE102011086529A1 (de) 2011-11-17 2011-11-17 Mittel zur temporären Verformung keratinischer Fasern auf Grundlage einer Kombination spezifischer filmbildender Polymere
PCT/EP2012/070922 WO2013072162A2 (fr) 2011-11-17 2012-10-23 Produit servant à la mise en forme temporaire de fibres kératiniques, à base d'une combinaison de polymères filmogènes spécifiques

Publications (1)

Publication Number Publication Date
EP2779989A2 true EP2779989A2 (fr) 2014-09-24

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EP12775032.1A Withdrawn EP2779989A2 (fr) 2011-11-17 2012-10-23 Produit servant à la mise en forme temporaire de fibres kératiniques, à base d'une combinaison de polymères filmogènes spécifiques

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EP (1) EP2779989A2 (fr)
DE (1) DE102011086529A1 (fr)
WO (1) WO2013072162A2 (fr)

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Publication number Priority date Publication date Assignee Title
DE102017217455A1 (de) * 2017-09-29 2019-04-04 Henkel Ag & Co. Kgaa Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern

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WO2011058163A1 (fr) * 2009-11-16 2011-05-19 Dsm Ip Assets B.V. Polymère acrylique
EP2322570A1 (fr) 2009-11-16 2011-05-18 DSM IP Assets B.V. Polymère acrylique

Non-Patent Citations (1)

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Title
See references of WO2013072162A2 *

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DE102011086529A1 (de) 2013-05-23
WO2013072162A2 (fr) 2013-05-23
WO2013072162A3 (fr) 2014-04-10

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