EP2736967A1 - Method for producing a sole or a sole part of a shoe - Google Patents

Method for producing a sole or a sole part of a shoe

Info

Publication number
EP2736967A1
EP2736967A1 EP12738038.4A EP12738038A EP2736967A1 EP 2736967 A1 EP2736967 A1 EP 2736967A1 EP 12738038 A EP12738038 A EP 12738038A EP 2736967 A1 EP2736967 A1 EP 2736967A1
Authority
EP
European Patent Office
Prior art keywords
sole
plastic body
shoe
plastic
binder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12738038.4A
Other languages
German (de)
French (fr)
Inventor
Matthias Hartmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Puma SE
Original Assignee
Puma SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
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Application filed by Puma SE filed Critical Puma SE
Publication of EP2736967A1 publication Critical patent/EP2736967A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D35/00Producing footwear
    • B29D35/06Producing footwear having soles or heels formed and joined on to preformed uppers using a moulding technique, e.g. by injection moulding, pressing and vulcanising
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D35/00Producing footwear
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/02Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
    • B29C44/12Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
    • B29C44/1285Incorporating or moulding on preformed parts, e.g. inserts or reinforcements the preformed part being foamed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D35/00Producing footwear
    • B29D35/0009Producing footwear by injection moulding; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D35/00Producing footwear
    • B29D35/0054Producing footwear by compression moulding, vulcanising or the like; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D35/00Producing footwear
    • B29D35/12Producing parts thereof, e.g. soles, heels, uppers, by a moulding technique
    • B29D35/122Soles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/22After-treatment of expandable particles; Forming foamed products
    • C08J9/228Forming foamed products
    • C08J9/232Forming foamed products by sintering expandable particles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/22After-treatment of expandable particles; Forming foamed products
    • C08J9/228Forming foamed products
    • C08J9/236Forming foamed products using binding agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/33Agglomerating foam fragments, e.g. waste foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/48Wearing apparel
    • B29L2031/50Footwear, e.g. shoes or parts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/12Polyester-amides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2475/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2475/04Polyurethanes

Definitions

  • the invention relates to a method for producing a sole or a sole part of a shoe, in particular a sports shoe.
  • the selection of the plastic results in being able to influence, within certain limits, both the weight and the density of the midsole as well as their return property (i.e., the way the curved sole moves back to its original position).
  • the object of the invention is to provide a method with which the weight of the sole or its return property can be influenced to a greater extent than heretofore. Accordingly, due to the low weight of the sole a particularly light shoe should be produced as well as one which is characterized by a good return property.
  • the solution to this problem by the invention is characterized in that the method comprises the steps of: a) producing plastic bodies whose expansion in the three spatial directions is between 2 mm and 15 mm, preferably between 3 mm and 9 mm, wherein the Plastic bodies of foamed urethane-based thermoplastic elastomer (TPU, E-TPU, TPE-U) and / or based on polyether block amide (PEBA); b) introducing the plastic body in a mold having a cavity which corresponds to the shape of the sole or the sole part to be produced; c) connecting the plastic body lying in the mold with each other, wherein for bonding a binder is introduced into the mold and / or is allowed to act on the heat bonding plastic body.
  • TPU foamed urethane-based thermoplastic elastomer
  • PEBA polyether block amide
  • the plastic body preferably have a spherical or ellipsoidfb '-shaped form; a kidney-'-shaped form has proved successful.
  • the starting material for the production of the plastic body preferably has a hardness between 75 to 90 Shore A, more preferably a hardness between 80 and 85 Shore A.
  • the plastic body preferably have a bulk density between 100 and 300 kg / m 3 , which depends on the size of Plastic body is dependent.
  • the joining of the plastic body according to the above step c) is carried out according to a preferred embodiment, by adding a binder with a weight fraction between 5% and 30% based on the finished sole or the finished sole member the plastic bodies in the tool.
  • the binder can be injected or poured into or onto the plastic body located in the tool.
  • the binder has elastic properties.
  • a 2-component polyurethane system has proven particularly useful. Particular preference is given to using a system which consists of a polyether-based polyol and an MDI prepolymer (MDI: diphenylmethane diisocyanate).
  • Prepolymers are known to be a group of substances which is a reactive intermediate between monomeric isocyanates and polyurethane polymers. They are prepared by reacting a polyol component with an excess of a polyisocyanate component.
  • the properties of the prepolymers and of the finished adhesives produced therefrom can be determined in a wide range by the choice of the polyol component (for example polyester or polyether) and the polyisocyanate component (for example aromatic or aliphatic), the molar ratio
  • the polyol component for example polyester or polyether
  • the polyisocyanate component for example aromatic or aliphatic
  • the joining of the plastic bodies according to the above step c) can be carried out according to an alternative embodiment by passing water vapor under pressure into the mold. It has proven useful if the pressure of the steam between 1, 6 and 2.4 bar, preferably between 1, 9 and 2, 1 bar, is located.
  • thermoplastic elastomer suitable for use with the present invention is known in the art and commercially available.
  • the polymer blend may contain at least one further thermoplastic polymer.
  • a further thermoplastic polymer is in particular polyamide (PA), polymethyl methacrylate (PMMA), polycarbonate (PC), polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), cellulose or polyoxymethylene (POM) in question.
  • FIG. 1 shows the side view of a shoe having a sole according to the invention
  • Fig. 2 shows schematically three plastic body as part of the sole of
  • a shoe 2 can be seen, which has a sole 1.
  • the entire sole 2 consists of a body made of plastic, whose components are plastic body 3, which are shown in more detail in Fig. 2.
  • the plastic body 3 are spherical, ellipsoidal or kidney-shaped; in Fig. 2 ellipsoid plastic body 3 are outlined. Each plastic body 3 expands in the three spatial directions by an extension a, b or c. According to the invention, the values for the dimensions a, b and c are between 2 mm and 15 mm, with values between 3 mm and 9 mm having proven particularly useful.
  • the first possibility is based on the fact that the individual plastic bodies are connected to one another with a binder, ie adhesively bonded.
  • the blending proportion of the binder is at least 5% by weight; accordingly, then 95% by weight of foamed plastic bodies (pellets) would be present.
  • a proportion of 30% by weight of binder is usually not exceeded, although the process also works with a higher proportion of binder.
  • the binder should be yellowing resistant and as elastic as possible.
  • a binder for example, a polyurethane foam can be used, with which the plastic body are foamed.
  • the blend composition of plastic bodies and PU foam can be chosen to give a desired density. That of the PU foam is between 250 kg / m 3 and 600 kg / m 3 ; In addition come the plastic body, which are selected according to their size.
  • the advantage of this solution is that the PU foam is very flexible and lightweight and firmer in the composite. However, the PU foam is not transparent, which may be detrimental to the visual appearance of the sole.
  • the second possibility is based on a welding of the individual plastic body at the contact point.
  • a preferred possibility is the supply of water vapor, but also a direct heat, which can melt the plastic body on its surface, is possible.
  • a Stauffyfahrweise the plastic body are first compressed before the input of water vapor with a dynamic pressure of 3 to 5 bar, preferably 4 bar.
  • a Crackfahrweise the plastic body are placed uncompressed in the mold cavity and then introduced steam.
  • Typical achievable densities of the sole material are values between 50 kg / m 3 and 180 kg / m 3 ; for applications as outer or as a midsole, a preferred range of 130 kg / m 3 to 140 kg / m 3 is provided. If the process for the production of a sandal is used, a value is aimed at the density of the finished sole between 1 10 kg / m 3 and 120 kg / m 3 .
  • the plastic body can be filled in an alternative manner in a recess in a sole element and then provided with a PU foam.
  • the plastic body are selected according to their size, with the above-mentioned limits are observed.
  • the achievable molding density is between 180 kg / m 3 and 320 kg / m 3 depending on the concrete method used (higher values when using the dynamic pressure mentioned above).

Abstract

The invention relates to a method for producing a sole (1) or a sole part of a shoe (2), in particular of a sports shoe. In order to obtain a lightweight shoe which has good rebound characteristics, the invention provides the following steps: a) producing plastic elements (3), the extent (a, b, c) of which in the three spatial directions lies between 2 mm and 15 mm, preferably between 3 mm and 9 mm, wherein the plastic elements (3) consist of a foamed thermoplastic elastomer based on urethane (TPU, E-TPU, TPE-U) and/or based on polyester block amide (PEBA); b) introducing the plastic elements (3) into a molding tool which has a cavity which corresponds to the shape of the sole (1) or the sole part to be produced; and c) connecting the plastic elements (3) located in the molding tool to one another, wherein a binder is put into the molding tool to make the connection and/or wherein heat is allowed to act on the plastic elements (3) to make the connection.

Description

Verfahren zur Herstellung einer Sohle oder eines  Process for the preparation of a sole or a
Sohlenteils eines Schuhs Sole part of a shoe
Die Erfindung betrifft ein Verfahren zur Herstellung einer Sohle oder eines Sohlenteils eines Schuhs, insbesondere eines Sportschuhs. The invention relates to a method for producing a sole or a sole part of a shoe, in particular a sports shoe.
Bei der Herstellung von Schuhsohlen ist es hinlänglich bekannt, das Kunststoffmaterial in schmelzflüssiger Form in die Kavität eines Spritzgießwerkzeugs einzuspritzen bzw. einzugießen, um so die gewünschte Sohlenform zu erhalten. In the manufacture of shoe soles, it is well known to inject the plastic material in molten form into the cavity of an injection molding tool so as to obtain the desired sole shape.
Die Auswahl des Kunststoffs fuhrt dazu, dass innerhalb bestimmter Grenzen sowohl das Gewicht bzw. die Dichte der Zwischensohle als auch deren Rückstelleigenschaft (d. h. die Weise, wie sich die gebogene Sohle wieder in die Ursprungslage zurückbewegt) beeinflusst werden können. The selection of the plastic results in being able to influence, within certain limits, both the weight and the density of the midsole as well as their return property (i.e., the way the curved sole moves back to its original position).
Der Erfindung liegt die A u f g a b e zugrunde, ein Verfahren bereit- zustellen, mit dem in stärkerer Weise als bislang das Gewicht der Sohle bzw. deren Rückstelleigenschaft beeinflusst werden kann. Demgemäß soll infolge des geringen Gewichts der Sohle ein besonders leichter Schuh herstellbar sein sowie ein solcher, der sich durch eine gute Rückstelleigenschaft auszeichnet. Die L ö s u n g dieser Aufgabe durch die Erfindung ist dadurch gekennzeichnet, dass das Verfahren die Schritte vorsieht: a) Herstellen von Kunststoffkörpern deren Ausdehnung in den drei Raumrichtungen zwischen 2 mm und 15 mm, vorzugsweise zwischen 3 mm und 9 mm, liegt, wobei die Kunststoffkörper aus geschäumtem Thermoplastischen Elastomer auf Urethanbasis (TPU, E-TPU, TPE-U) und/oder auf der Basis von Polyether- Block-Amid (PEBA) bestehen; b) Einbringen der Kunststoffkörper in ein Formwerkzeug, das eine Kavität aufweist, die der Form der herzustellenden Sohle oder des Sohlenteils entspricht; c) Verbinden der im Formwerkzeug aneinander liegenden Kunststoffkörper miteinander, wobei zum Verbinden ein Bindemittel ins Formwerkzeug eingegeben wird und/oder wobei zum Verbinden Wärme auf die Kunststoffkörper einwirken gelassen wird. The object of the invention is to provide a method with which the weight of the sole or its return property can be influenced to a greater extent than heretofore. Accordingly, due to the low weight of the sole a particularly light shoe should be produced as well as one which is characterized by a good return property. The solution to this problem by the invention is characterized in that the method comprises the steps of: a) producing plastic bodies whose expansion in the three spatial directions is between 2 mm and 15 mm, preferably between 3 mm and 9 mm, wherein the Plastic bodies of foamed urethane-based thermoplastic elastomer (TPU, E-TPU, TPE-U) and / or based on polyether block amide (PEBA); b) introducing the plastic body in a mold having a cavity which corresponds to the shape of the sole or the sole part to be produced; c) connecting the plastic body lying in the mold with each other, wherein for bonding a binder is introduced into the mold and / or is allowed to act on the heat bonding plastic body.
Die Kunststoffkörper haben dabei bevorzugt eine kugelförmige oder ellipsoidfb'rmige Gestalt; auch eine nierenf 'rmige Gestalt hat sich bewährt. The plastic body preferably have a spherical or ellipsoidfb '-shaped form; a kidney-'-shaped form has proved successful.
Das Ausgangsmaterial für die Herstellung der Kunststoffkörper weist bevorzugt eine Härte zwischen 75 bis 90 Shore A auf, besonders bevorzugt eine Härte zwischen 80 und 85 Shore A. Die Kunststoffkörper haben bevorzugt eine Schüttdichte zwischen 100 und 300 kg/m3, was von der Größe der Kunststoffkörper abhängig ist. Das Verbinden der Kunststoffkörper gemäß obigem Schritt c) erfolgt gemäß einer bevorzugten Ausfuhrungsform, indem ein Bindemittel mit einem Gewichtsanteil zwischen 5 % und 30 % bezogen auf die fertige Sohle bzw. das fertige Sohlenteil den Kunststoffkörpern in das Werkzeug zugegeben wird. Das Bindemittel kann in die bzw. auf die sich im Werkzeug befindlichen Kunststoffkörper eingespritzt bzw. eingegossen werden. The starting material for the production of the plastic body preferably has a hardness between 75 to 90 Shore A, more preferably a hardness between 80 and 85 Shore A. The plastic body preferably have a bulk density between 100 and 300 kg / m 3 , which depends on the size of Plastic body is dependent. The joining of the plastic body according to the above step c) is carried out according to a preferred embodiment, by adding a binder with a weight fraction between 5% and 30% based on the finished sole or the finished sole member the plastic bodies in the tool. The binder can be injected or poured into or onto the plastic body located in the tool.
Bevorzugt hat das Bindemittel elastische Eigenschaften. Als Binder zum Verbinden der einzelnen aneinandergrenzenden Kunststoffkörper hat sich besonders ein 2-Komponenten-Polyurethan-System bewährt. Besonders bevorzugt kommt ein System zum Einsatz, das aus einem Polyether-basierten Polyol und einem MDI-Prepolymer besteht (MDI: Diphenyl-Methan-Diisocyanat). Preferably, the binder has elastic properties. As a binder for connecting the individual adjoining plastic body, a 2-component polyurethane system has proven particularly useful. Particular preference is given to using a system which consists of a polyether-based polyol and an MDI prepolymer (MDI: diphenylmethane diisocyanate).
Prepolymere sind bekanntlich eine Stoffgruppe, die eine reaktive Zwischenstufe zwischen monomeren Isocyanaten und Polyurethanpolymeren darstellt. Sie werden durch Reaktion einer Polyolkomponente mit einem Überschuss einer Polyisocyanat-Komponente hergestellt. Prepolymers are known to be a group of substances which is a reactive intermediate between monomeric isocyanates and polyurethane polymers. They are prepared by reacting a polyol component with an excess of a polyisocyanate component.
Die Eigenschaften der Prepolymere und der daraus hergestellten fertigen Klebstoffe können in weiten Bereichen durch die Wahl der Polyol- Komponente (z. B. Polyester bzw. Polyether) und der Polyisocyanat- komponente (z. B. aromatisch bzw. aliphatisch), dem molaren Verhältnis dieser beiden Reaktionspartner sowie der anschließenden Formulierung (z. B. Katalysator, Füllstoff und/oder Weichmacher) eingestellt werden, was auch bei der vorliegenden Anwendung genutzt werden kann. Das Verbinden der Kunststoffkörper gemäß obigem Schritt c) kann gemäß einer alternativen Ausführungsform erfolgen, indem Wasserdampf unter Druck in das Formwerkzeug geleitet wird. Dabei hat es sich bewährt, wenn der Druck des Wasserdampfs zwischen 1 ,6 und 2,4 bar, vorzugsweise zwischen 1 ,9 und 2, 1 bar, liegt. The properties of the prepolymers and of the finished adhesives produced therefrom can be determined in a wide range by the choice of the polyol component (for example polyester or polyether) and the polyisocyanate component (for example aromatic or aliphatic), the molar ratio These two reaction partners and the subsequent formulation (eg, catalyst, filler and / or plasticizer) can be adjusted, which can also be used in the present application. The joining of the plastic bodies according to the above step c) can be carried out according to an alternative embodiment by passing water vapor under pressure into the mold. It has proven useful if the pressure of the steam between 1, 6 and 2.4 bar, preferably between 1, 9 and 2, 1 bar, is located.
Es ist mit der vorgeschlagenen Lösung möglich, die gesamte Sohle des Schuhs zu fertigen. Es ist aber auch möglich, nur einen Teil derselben zu fertigen, insbesondere eine Zwischensohle des Schuhs. It is possible with the proposed solution to manufacture the entire sole of the shoe. But it is also possible to produce only a part of the same, in particular a midsole of the shoe.
Thermoplastisches Elastomer auf Urethanbasis, das sich für die Nutzung der vorliegenden Erfindung eignet, ist als solches im Stand der Technik bekannt und im Handel verfügbar. Diesbezüglich wird ausdrücklich beispielsweise auf die WO 2010/010010 AI hingewiesen, in der ein expandierbarer, treibmittelhaltiger thermoplastischer Polymer-Blend offenbart wird, der thermoplastisches Polyurethan und Styrolpolymerisat enthält. Der Polymer- Blend kann dabei mindestens ein weiteres thermoplastisches Polymer enthalten. Als weiteres thermoplastisches Polymer kommt insbesondere Polyamid (PA), Polymethylmethacrylat (PMMA), Polycarbonat (PC), Polyethylen (PE), Polypropylen (PP), Polyvinylchlorid (PVC), Cellulose bzw. Polyoxymethylen (POM) in Frage. As such, urethane-based thermoplastic elastomer suitable for use with the present invention is known in the art and commercially available. In this respect, reference is expressly made, for example, to WO 2010/010010 Al, in which an expandable blowing agent-containing thermoplastic polymer blend is disclosed which contains thermoplastic polyurethane and styrene polymer. The polymer blend may contain at least one further thermoplastic polymer. As a further thermoplastic polymer is in particular polyamide (PA), polymethyl methacrylate (PMMA), polycarbonate (PC), polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), cellulose or polyoxymethylene (POM) in question.
Wie bereits erwähnt, kann die gesamte Sohle und auch nur ein Teil derselben - insbesondere die Zwischen- oder Außensohle - erfindungsgemäß hergestellt werden. Möglich ist es auch, dass Sandalen auf diese Weise hergestellt werden, wobei die Sohle dann nur noch ein Halteband für den Fuß benötigt. Möglich ist auch der Einsatz eines erfindungsgemäß hergestellten Sohlenteils als Schaumersatz im Schuh bzw. in der Sohle (z. B. in Form einer Einlegesohle). In der Zeichnung ist ein Ausfuhrungsbeispiel der Erfindung dargestellt. Es zeigen: Fig. 1 die Seitenansicht eines Schuhs, der eine erfindungsgemäße Sohle aufweist, und As already mentioned, the entire sole and only a part of it - in particular the intermediate or outsole - can be produced according to the invention. It is also possible that sandals are made in this way, the sole then only needs a tether for the foot. It is also possible to use a sole part produced according to the invention as a foam substitute in the shoe or in the sole (for example in the form of an insole). In the drawing, an embodiment of the invention is shown. FIG. 1 shows the side view of a shoe having a sole according to the invention, and FIG
Fig. 2 schematisch drei Kunststoffkörper als Bestandteil der Sohle des Fig. 2 shows schematically three plastic body as part of the sole of
Schuhs.  Shoe.
In Fig. 1 ist ein Schuh 2 zu sehen, der eine Sohle 1 aufweist. Vorliegend besteht die gesamte Sohle 2 aus einem aus Kunststoff gefertigten Körper, dessen Bestandteile Kunststoffkörper 3 sind, die in Fig. 2 näher dargestellt sind. In Fig. 1, a shoe 2 can be seen, which has a sole 1. In the present case, the entire sole 2 consists of a body made of plastic, whose components are plastic body 3, which are shown in more detail in Fig. 2.
Die Kunststoffkörper 3 sind kugelförmig, ellipsoid oder nierenförmig ausgebildet; in Fig. 2 sind ellipsoide Kunststoffkörper 3 skizziert. Jeder Kunststoffkörper 3 dehnt sich in den drei Raumrichtungen um eine Ausdehnung a, b bzw. c aus. Erfindungsgemäß vorgesehen ist, dass die Werte für die Ausdehnungen a, b und c zwischen 2 mm und 15 mm liegen, wobei sich Werte zwischen 3 mm und 9 mm besonders bewährt haben. The plastic body 3 are spherical, ellipsoidal or kidney-shaped; in Fig. 2 ellipsoid plastic body 3 are outlined. Each plastic body 3 expands in the three spatial directions by an extension a, b or c. According to the invention, the values for the dimensions a, b and c are between 2 mm and 15 mm, with values between 3 mm and 9 mm having proven particularly useful.
Für die dauerhafte Verbindung der einzelnen Kunststoffkörper stehen im wesentlichen zwei verschiedene bevorzugte Möglichkeiten zur Verfügung. For the permanent connection of the individual plastic body are essentially two different preferred options available.
Die erste Möglichkeit stellt darauf ab, dass die einzelnen Kunststoffkörper mit einem Binder miteinander verbunden, d. h. verklebt werden. Der Mischungsanteil des Binders (Klebers) beträgt (einschließlich gegebenenfalls vorhandener Farbe) mindestens 5 Gewichts-%; demgemäß wären dann 95 Gewichts-% geschäumte Kunststoffkörper (Pellets) vorhanden. Ein Anteil von 30 Gewichts-% Binder wird meist nicht überschritten, wenngleich das Verfahren auch noch mit einem höheren Anteil an Binder arbeitet. The first possibility is based on the fact that the individual plastic bodies are connected to one another with a binder, ie adhesively bonded. The blending proportion of the binder (including any color present) is at least 5% by weight; accordingly, then 95% by weight of foamed plastic bodies (pellets) would be present. A proportion of 30% by weight of binder is usually not exceeded, although the process also works with a higher proportion of binder.
Der Binder sollte vergilbungsbeständig und möglichst elastisch sein. Als Binder kann beispielsweise auch ein Polyurethanschaum eingesetzt werden, mit dem die Kunststoffkörper eingeschäumt werden. Die Mischungszusammensetzung von Kunststoffkörpern und PU-Schaum kann so gewählt werden, dass sich eine gewünschte Dichte ergibt. Diejenige des PU- Schaums liegt zwischen 250 kg/m3 und 600 kg/m3; hinzu kommen die Kunststoffkörper, die von ihrer Größe her entsprechend ausgewählt werden. Der Vorteil dieser Lösung besteht darin, dass der PU-Schaum sehr flexibel und leicht ist und fester im Verbund. Allerdings ist der PU-Schaum nicht transparent, was gegebenenfalls hinsichtlich des optischen Erscheinungsbildes der Sohle nachteilig sein kann. The binder should be yellowing resistant and as elastic as possible. As a binder, for example, a polyurethane foam can be used, with which the plastic body are foamed. The blend composition of plastic bodies and PU foam can be chosen to give a desired density. That of the PU foam is between 250 kg / m 3 and 600 kg / m 3 ; In addition come the plastic body, which are selected according to their size. The advantage of this solution is that the PU foam is very flexible and lightweight and firmer in the composite. However, the PU foam is not transparent, which may be detrimental to the visual appearance of the sole.
Die zweite Möglichkeit stellt auf ein Verschweißen der einzelnen Kunststoffkörper an deren Kontaktstelle ab. The second possibility is based on a welding of the individual plastic body at the contact point.
Eine bevorzugte Möglichkeit ist das Zuleiten von Wasserdampf, aber auch eine direkte Hitzeeinwirkung, die die Kunststoffkörper an ihrer Oberfläche aufschmelzen lässt, ist möglich. Bei einer Staudruckfahrweise werden die Kunststoffkörper vor der Eingabe von Wasserdampf zunächst mit einem Staudruck von 3 bis 5 bar, vorzugsweise von 4 bar, komprimiert. Bei einer Crackfahrweise werden die Kunststoffkörper unkomprimiert in die Werkzeugkavität gegeben und dann Wasserdampf eingeleitet. A preferred possibility is the supply of water vapor, but also a direct heat, which can melt the plastic body on its surface, is possible. In a Staudruckfahrweise the plastic body are first compressed before the input of water vapor with a dynamic pressure of 3 to 5 bar, preferably 4 bar. In a Crackfahrweise the plastic body are placed uncompressed in the mold cavity and then introduced steam.
Typische erreichbare Dichten des Sohlenmaterials sind dabei Werte zwischen 50 kg/m3 und 180 kg/m3; für Anwendungen als Außen- bzw. als Zwischensohle ist ein bevorzugter Bereich von 130 kg/m3 bis 140 kg/m3 vorgesehen. Kommt das Verfahren für die Herstellung einer Sandale zum Einsatz, wird ein Wert die Dichte der fertigen Sohle zwischen 1 10 kg/m3 und 120 kg/m3 angestrebt. Die Kunststoffkörper können nach einer alternativen Vorgehensweise auch in eine Aussparung in einem Sohlenelement eingefüllt und dann mit einem PU- Schaum versehen werden. Typical achievable densities of the sole material are values between 50 kg / m 3 and 180 kg / m 3 ; for applications as outer or as a midsole, a preferred range of 130 kg / m 3 to 140 kg / m 3 is provided. If the process for the production of a sandal is used, a value is aimed at the density of the finished sole between 1 10 kg / m 3 and 120 kg / m 3 . The plastic body can be filled in an alternative manner in a recess in a sole element and then provided with a PU foam.
Bei allen Varianten werden die Kunststoffkörper hinsichtlich ihrer Größe entsprechend ausgewählt, wobei die genannten Grenzbereiche beachtet werden. In all variants, the plastic body are selected according to their size, with the above-mentioned limits are observed.
Bei der Durchführung des Verfahrens wird in der Regel mit Zykluszeiten des Formgebungsprozesses im Formwerkzeug zwischen 150 und 400 s gearbeitet. Die erreichbare Formteildichte liegt zwischen 180 kg/m3 und 320 kg/m3 in Abhängigkeit des konkret eingesetzten Verfahrens (höhere Werte bei Einsatz des erwähnten Staudrucks). Bezugszeichenliste: In the implementation of the method is usually worked with cycle times of the molding process in the mold between 150 and 400 s. The achievable molding density is between 180 kg / m 3 and 320 kg / m 3 depending on the concrete method used (higher values when using the dynamic pressure mentioned above). LIST OF REFERENCE NUMBERS
Sohle sole
Schuhs shoe
Kunststoffkörper  Plastic body
Ausdehnung in Achsrichtung Expansion in the axial direction
Ausdehnung in Achsrichtung Expansion in the axial direction
Ausdehnung in Achsrichtung Expansion in the axial direction

Claims

Patentansprüche: claims:
1. Verfahren zur Herstellung einer Sohle (1 ) oder eines Sohlenteils eines Schuhs (2), insbesondere eines Sportschuhs, umfassend die Schritte: a) Herstellen von Kunststoffkörpern (3) deren Ausdehnung (a, b, c) in den drei Raumrichtungen zwischen 2 mm und 15 mm, vorzugsweise zwischen 3 mm und 9 mm, liegt, wobei die Kunststoffkörper (3) aus geschäumtem Thermoplastischen Elastomer auf Urethanbasis (TPU, E-TPU, TPE-U) und/oder auf der Basis von Polyether-Block-Amid (PEBA) bestehen; b) Einbringen der Kunststoffkörper (3) in ein Formwerkzeug, das eine Kavität aufweist, die der Form der herzustellenden Sohle (1 ) oder des Sohlenteils entspricht; c) Verbinden der im Formwerkzeug aneinander liegenden Kunst- stoffkörper (3) miteinander, wobei zum Verbinden ein Bindemittel ins Formwerkzeug eingegeben wird und/oder wobei zum Verbinden Wärme auf die Kunststoffkörper (3) einwirken gelassen wird. 1. A method for producing a sole (1) or a sole part of a shoe (2), in particular a sports shoe, comprising the steps: a) producing plastic bodies (3) whose extent (a, b, c) in the three spatial directions between 2 mm and 15 mm, preferably between 3 mm and 9 mm, wherein the plastic body (3) of foamed thermoplastic urethane-based elastomer (TPU, E-TPU, TPE-U) and / or on the basis of polyether block amide (PEBA); b) introducing the plastic body (3) into a mold having a cavity which corresponds to the shape of the sole (1) or the sole part to be produced; c) connecting the plastic body (3) which adjoins one another in the molding tool, wherein a binder is introduced into the molding tool for joining and / or heat is applied to the plastic body (3) for bonding.
2. Verfahren nach Anspruch 1 , dadurch gekennzeichnet, dass die Kunststoffkörper (3) eine kugelförmige oder ellipsoidförmige Gestalt haben. 2. The method according to claim 1, characterized in that the plastic body (3) have a spherical or ellipsoidal shape.
3. Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass das Ausgangsmaterial für die Herstellung der Kunststoffkörper (3) eine Härte zwischen 75 bis 90 Shore A aufweist, vorzugsweise zwischen 80 und 85 Shore A. 3. The method according to claim 1 or 2, characterized in that the starting material for the production of the plastic body (3) has a hardness between 75 to 90 Shore A, preferably between 80 and 85 Shore A.
4. Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Kunststoffkörper (3) eine Schüttdichte zwischen 100 und 300 kg/m3 aufweisen. 4. The method according to any one of claims 1 to 3, characterized in that the plastic body (3) have a bulk density between 100 and 300 kg / m 3 .
5. Verfahren nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass das Verbinden der Kunststoffkörper (3) gemäß Schritt c) von Anspruch 1 erfolgt, indem ein Bindemittel mit einem Gewichtsanteil zwischen 5 % und 30 % bezogen auf die fertige Sohle (1 ) bzw. das fertige Sohlenteil den Kunststoffkörpern (3) zugegeben wird. 5. The method according to any one of claims 1 to 5, characterized in that the bonding of the plastic body (3) according to step c) of claim 1, by a binder with a weight fraction between 5% and 30% based on the finished sole (1 ) or the finished sole part is added to the plastic bodies (3).
6. Verfahren nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass das Bindemittel elastische Eigenschaften aufweist. 6. The method according to any one of claims 1 to 6, characterized in that the binder has elastic properties.
7. Verfahren nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass das Verbinden der Kunststoffkörper (3) gemäß Schritt c) von Anspruch 1 erfolgt, indem Wasserdampf unter Druck in das Formwerkzeug geleitet wird. 7. The method according to any one of claims 1 to 5, characterized in that the joining of the plastic body (3) according to step c) of claim 1 is carried out by water vapor is passed under pressure into the mold.
8. Verfahren nach Anspruch 7, dadurch gekennzeichnet, dass der Druck des Wasserdampfs zwischen 1 ,6 und 2,4 bar, vorzugsweise zwischen 1 ,9 und 2, 1 bar, liegt. 8. The method according to claim 7, characterized in that the pressure of the steam between 1, 6 and 2.4 bar, preferably between 1, 9 and 2, 1 bar, is located.
9. Verfahren nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass die gesamte Sohle (1) des Schuhs (2) mit dem Verfahren gefertigt wird. 9. The method according to any one of claims 1 to 8, characterized in that the entire sole (1) of the shoe (2) is manufactured by the method.
10. Verfahren nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass eine Zwischensohle des Schuhs (2) mit dem Verfahren gefertigt wird. 10. The method according to any one of claims 1 to 8, characterized in that a midsole of the shoe (2) is manufactured by the method.
EP12738038.4A 2011-07-28 2012-07-16 Method for producing a sole or a sole part of a shoe Withdrawn EP2736967A1 (en)

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DE102011108744.7A DE102011108744B4 (en) 2011-07-28 2011-07-28 Method for producing a sole or a sole part of a shoe
PCT/EP2012/002970 WO2013013784A1 (en) 2011-07-28 2012-07-16 Method for producing a sole or a sole part of a shoe

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DE102011108744B4 (en) 2014-03-13
JP2014521418A (en) 2014-08-28
DE102011108744A1 (en) 2013-01-31
BR112014001548A2 (en) 2017-02-14
CA2843334A1 (en) 2013-01-31
CN103717658A (en) 2014-04-09
US20140151918A1 (en) 2014-06-05
AU2012289311A1 (en) 2014-02-20
RU2014107535A (en) 2015-09-10
WO2013013784A1 (en) 2013-01-31

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