EP2607469A1 - Flüssiges Waschmittel mit Protease und Lipase - Google Patents

Flüssiges Waschmittel mit Protease und Lipase Download PDF

Info

Publication number: EP2607469A1
Authority: EP; European Patent Office
Prior art keywords: composition according; composition; surfactant; protease; lipase
Prior art date: 2011-12-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

EP11194459.1A

Other languages

English (en)

French (fr)

Inventor

Andrew Thomas Cook

Andrew David Green

Paul Simon Stevenson

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2011-12-20

Filing date

2011-12-20

Publication date

2013-06-26

2011-12-20 Application filed by Unilever PLC filed Critical Unilever PLC

2011-12-20 Priority to EP11194459.1A priority Critical patent/EP2607469A1/de

2013-06-26 Publication of EP2607469A1 publication Critical patent/EP2607469A1/de

Status Withdrawn legal-status Critical Current

Links

239000007788 liquid Substances 0.000 title claims abstract description 31
108091005804 Peptidases Proteins 0.000 title claims abstract description 27
239000004365 Protease Substances 0.000 title claims abstract description 26
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 title claims abstract description 26
102000004882 Lipase Human genes 0.000 title claims abstract description 22
108090001060 Lipase Proteins 0.000 title claims abstract description 22
239000003599 detergent Substances 0.000 title claims abstract description 21
239000004367 Lipase Substances 0.000 title claims abstract description 18
235000019421 lipase Nutrition 0.000 title claims abstract description 18
239000000203 mixture Substances 0.000 claims abstract description 47
102000004190 Enzymes Human genes 0.000 claims abstract description 25
108090000790 Enzymes Proteins 0.000 claims abstract description 25
239000004094 surface-active agent Substances 0.000 claims abstract description 18
238000004140 cleaning Methods 0.000 claims abstract description 16
239000003945 anionic surfactant Substances 0.000 claims abstract description 11
150000001412 amines Chemical class 0.000 claims abstract description 8
239000002736 nonionic surfactant Substances 0.000 claims abstract description 7
150000004996 alkyl benzenes Chemical class 0.000 claims abstract description 5
229920000642 polymer Polymers 0.000 claims description 13
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 5
239000002689 soil Substances 0.000 claims description 5
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 3
239000003352 sequestering agent Substances 0.000 claims description 3
-1 alkyl ether sulphate Chemical class 0.000 claims description 2
229920000728 polyester Polymers 0.000 claims description 2
238000005406 washing Methods 0.000 claims 3
238000007865 diluting Methods 0.000 claims 1
238000010790 dilution Methods 0.000 claims 1
239000012895 dilution Substances 0.000 claims 1
229910021653 sulphate ion Inorganic materials 0.000 claims 1
239000008399 tap water Substances 0.000 claims 1
235000020679 tap water Nutrition 0.000 claims 1
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
230000000694 effects Effects 0.000 description 8
239000002253 acid Substances 0.000 description 7
229920002873 Polyethylenimine Polymers 0.000 description 4
239000002304 perfume Substances 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
230000001010 compromised effect Effects 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
230000002255 enzymatic effect Effects 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
QTDIEDOANJISNP-UHFFFAOYSA-N 2-dodecoxyethyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOCCOS(O)(=O)=O QTDIEDOANJISNP-UHFFFAOYSA-N 0.000 description 1
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
101100313763 Arabidopsis thaliana TIM22-2 gene Proteins 0.000 description 1
KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
102000035195 Peptidases Human genes 0.000 description 1
229920002125 Sokalan® Polymers 0.000 description 1
241000187747 Streptomyces Species 0.000 description 1
108090000787 Subtilisin Proteins 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
230000000845 anti-microbial effect Effects 0.000 description 1
239000004599 antimicrobial Substances 0.000 description 1
229960003237 betaine Drugs 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000004744 fabric Substances 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
239000004519 grease Substances 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000000415 inactivating effect Effects 0.000 description 1
230000002779 inactivation Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
235000019626 lipase activity Nutrition 0.000 description 1
239000003002 pH adjusting agent Substances 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
239000004753 textile Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile

Definitions

This invention relates to aqueous liquid detergents comprising surfactants, at least one polymer and protease and lipase enzymes.
Aqueous liquid detergents are typically formulated to have an in-bottle pH of about 8 to 8.5.
the stability of enzymes in these liquids may not be good. This is especially so for proteases in the presence of TEA and lipases in the presence of protease.
W02009/153184 (Unilever) proposes a detergent liquid comprising polymers, enzymes and surfactants. The low in wash surfactant level is compensated by the polymers and enzymes. Combinations of protease and lipase enzymes are proposed. We have now found that these enzymes have poor stability at an in-bottle pH of about 8.3 when using the preferred surfactant system in W02009/153184 comprising: neutralised linear alkyl benzene sulphonic acid (LAS), neutralised fatty acid, ethoxylated fatty alcohol nonionic and carbobetaine amphoteric. The amphoteric is desirable because of its synergy with ethoxylated polyethyleneimine polymers when that type of polymer is also used.
LAS neutralised linear alkyl benzene sulphonic acid
the amphoteric is desirable because of its synergy with ethoxylated polyethyleneimine polymers when that type of polymer is also used.
liquid detergent compositions comprising protease and lipase. Most of them are non-specific about the performance of these compositions when they have been stored for a reasonable length of time to simulate actual supply and use of the composition in a domestic environment. A few of the disclosures claim some stability benefit for the protease.
the stability of the lipase is not normally disclosed. We have determined that lipase stability is not good enough for a commercial composition that also comprises protease if the in-bottle pH is above 7.0 and the composition comprises LAS.
US2010240562A discloses an enzyme stabilization system. Lipase is shown to be more stable in nonionic surfactant based systems containing amines if they are formulated at acidic pH. Surprisingly, preferred ratios of acid to amine are effective at stabilizing enzymes. Nonionic surfactants and solvents also positively contribute to enzyme stability. The amine may be an antimicrobial amine. Cleaning systems based on nonionic are very expensive and have poor performance against some types of common laundry soils and stains. US2002019326 (Unilever) relates to a concentrated and physically stable isotropic liquid detergent composition with good protease stability suitable for cleaning textile articles.
Comparative Example A shows that the system at pH 8 (with NaOH) leads to very unstable protease.
Examples 5 & 6 have both protease and Lipase at pH 8. The activity is not measured. Sulphite and borate render the liquids non isotropic.
US2006234895A discloses a liquid laundry detergent for improved grease and oil cleaning having a first wash lipase enzyme, a modified polyethyleneimine polymer and a liquid carrier. Additional enzymes can be included in effective amounts. Their choice is governed by several factors such as pH-activity and/or stability optima, thermostability, stability versus active detergents, builders and so on.
the detergent compositions may also optionally contain low levels of materials which serve to adjust or maintain the pH of the detergent compositions at optimum levels.
the pH of the compositions herein should range from about 7.8 to 8.5, more preferably from about 8.0 to 8.5. Materials such as NaOH can be added to alter composition pH, if necessary.
US2008221008A discloses detergent compositions with enhanced stability of non protease enzymes present in the compositions.
Table 3 of example 1 shows that the stability of the inventive mixture of subtilisin KL protease and lipase is similar to that we find at alkaline pH (the commercial liquid used in Example 1 is almost certainly alkaline and most likely contains LAS as virtually all commercial liquids are based on LAS).
the test at elevated temperature in table 7 seems to suggest that the lipase benefit has gone after 4 weeks storage at elevated temperature.
US2010095987A and US2009111161A disclose a streptomyces protease and its use in cleaning compositions. It is contemplated that liquid fabric cleaning composition of particular utility under Japanese machine wash conditions be prepared in accordance with the invention. Those compositions may comprise lipase or protease.
a composition is given which has both lipase and protease. It has a low level of LAS (6 wt%), SLES, AO, PAS a low level of nonionic, sequestrant, MEA and sodium hydroxide and some soil release polymer. This composition V is believed to be alkaline.
the cleaning composition comprises a sufficient amount of a pH modifier to provide said composition with a neat pH of from about 3 to about 5. These embodiments do not comprise protease.
An aqueous concentrated isotropic laundry liquid comprising 15 to 60 wt% of a surfactant system comprising at least one anionic surfactant, at least one nonionic surfactant and at least one surfactant from the group comprising carbobetaine and amine oxide, wherein the anionic surfactant comprises a minimum of 5 wt%, based on the total composition, linear alkyl benzene sulphonate (LAS), the composition further comprising, EPEI and at least two enzymes; which enzymes comprise a cleaning effective amount of at least one protease and a cleaning effective amount of at least one lipase, characterised in that the in-bottle pH of the composition is buffered to 6.0 to less than 7, preferably 6.3 to 6.7.
LAS linear alkyl benzene sulphonate
in-bottle we mean in whatever container or pack the liquid is stored. It could be a plastic pack in the form of a bottle, squeezable or rigid, stored upright or inverted, or a unit dose format such as a soluble pouch, or a sachet.
the lower amount of surfactant means that the effect of having some LAS acid on both wash performance and in-wash pH is much reduced compared to the effect that would be observed in a conventional liquid that delivers a more conventional level of surfactant to the wash. This, taken together with the improved performance resulting from the better enzyme stability, makes the overall wash performance improve.
the liquid further comprises HEDP as sequestrant.
the amount of HEDP in the composition is preferably at least 1 wt%, more preferably at least 1.5 wt%, and most preferably at least 2 wt%.
the in-product pH of the specific detergent liquids is reduced from 8.3 to about 6.5 the enzymatic stability or the protease and lipase enzyme system is significantly improved without compromising the cleaning performance of the liquid.

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Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

EP11194459.1A 2011-12-20 2011-12-20 Flüssiges Waschmittel mit Protease und Lipase Withdrawn EP2607469A1 (de)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
EP11194459.1A EP2607469A1 (de)	2011-12-20	2011-12-20	Flüssiges Waschmittel mit Protease und Lipase

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
EP11194459.1A EP2607469A1 (de)	2011-12-20	2011-12-20	Flüssiges Waschmittel mit Protease und Lipase

Publications (1)

Publication Number	Publication Date
EP2607469A1 true EP2607469A1 (de)	2013-06-26

Family

ID=45349084

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP11194459.1A Withdrawn EP2607469A1 (de)	2011-12-20	2011-12-20	Flüssiges Waschmittel mit Protease und Lipase

Country Status (1)

Country	Link
EP (1)	EP2607469A1 (de)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2020005879A1 (en) *	2018-06-28	2020-01-02	The Procter & Gamble Company	Fabric treatment compositions with polymer system and related processes
CN111286424A (zh) *	2018-12-06	2020-06-16	南风化工集团股份有限公司	一种超浓缩洗洁精组合物
US11015143B2 (en)	2015-07-10	2021-05-25	Colgate-Palmolive Company	Cleaning compositions and methods for enhancing fragrance performance
EP4012012A1 (de) *	2020-12-14	2022-06-15	Henkel AG & Co. KGaA	Flüssige waschmittelzusammensetzung mit keratin

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GB2346153A (en) *	1999-01-29	2000-08-02	Yplon S A	Cleaning formulation
US20020019326A1 (en)	2000-06-15	2002-02-14	Unilever Home & Personal Care Usa, Division Of Conopco, Inc.	Concentrated liquid detergent composition
US20060234895A1 (en)	2005-04-15	2006-10-19	Souter Philip F	Liquid laundry detergent compositions with modified polyethyleneimine polymers and lipase enzyme
US20070032395A1 (en)	2003-06-13	2007-02-08	Darlo Fornara	Aqueous liquid detergent compositions comprising anionic esters of alkylpolyglycosides and enzymes
US20080221008A1 (en)	2006-10-06	2008-09-11	Novozymes A/S	Detergent compositions and the use of enzyme combinations therein
WO2008114171A1 (en) *	2007-03-20	2008-09-25	The Procter & Gamble Company	Liquid laundry detergent compositions comprising performance boosters
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US20100240562A1 (en)	2009-01-20	2010-09-23	Ecolab Inc.	Stable aqueous antimicrobial enzyme compositions

2011
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US11015143B2 (en)	2015-07-10	2021-05-25	Colgate-Palmolive Company	Cleaning compositions and methods for enhancing fragrance performance
WO2020005879A1 (en) *	2018-06-28	2020-01-02	The Procter & Gamble Company	Fabric treatment compositions with polymer system and related processes
JP2021528540A (ja) *	2018-06-28	2021-10-21	ザプロクターアンドギャンブルカンパニーＴｈｅＰｒｏｃｔｅｒ＆ＧａｍｂｌｅＣｏｍｐａｎｙ	ポリマー系を含む布地処理組成物及び関連方法
US11692305B2 (en)	2018-06-28	2023-07-04	The Procter & Gamble Company	Fabric treatment compositions with polymer system and related processes
CN111286424A (zh) *	2018-12-06	2020-06-16	南风化工集团股份有限公司	一种超浓缩洗洁精组合物
EP4012012A1 (de) *	2020-12-14	2022-06-15	Henkel AG & Co. KGaA	Flüssige waschmittelzusammensetzung mit keratin

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2014-06-18	18D	Application deemed to be withdrawn	Effective date: 20140103

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