EP2516356A1 - Malleable solid explosive and method for obtaining it - Google Patents
Malleable solid explosive and method for obtaining itInfo
- Publication number
- EP2516356A1 EP2516356A1 EP10810850A EP10810850A EP2516356A1 EP 2516356 A1 EP2516356 A1 EP 2516356A1 EP 10810850 A EP10810850 A EP 10810850A EP 10810850 A EP10810850 A EP 10810850A EP 2516356 A1 EP2516356 A1 EP 2516356A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- explosive
- polyols
- malleable solid
- malleable
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002360 explosive Substances 0.000 title claims abstract description 112
- 239000007787 solid Substances 0.000 title claims abstract description 58
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 40
- 239000000203 mixture Substances 0.000 claims abstract description 36
- 229920005862 polyol Polymers 0.000 claims abstract description 36
- 150000003077 polyols Chemical class 0.000 claims abstract description 36
- 229920000642 polymer Polymers 0.000 claims abstract description 17
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 12
- -1 polysiloxanes Polymers 0.000 claims abstract description 7
- 229920002367 Polyisobutene Polymers 0.000 claims abstract description 6
- 229920000570 polyether Polymers 0.000 claims abstract description 5
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 5
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 8
- TZRXHJWUDPFEEY-UHFFFAOYSA-N Pentaerythritol Tetranitrate Chemical compound [O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O TZRXHJWUDPFEEY-UHFFFAOYSA-N 0.000 claims description 6
- 239000005062 Polybutadiene Substances 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 235000006708 antioxidants Nutrition 0.000 claims description 6
- 239000000028 HMX Substances 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- 238000001514 detection method Methods 0.000 claims description 5
- UZGLIIJVICEWHF-UHFFFAOYSA-N octogen Chemical group [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)CN([N+]([O-])=O)C1 UZGLIIJVICEWHF-UHFFFAOYSA-N 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- FUHQFAMVYDIUKL-UHFFFAOYSA-N fox-7 Chemical compound NC(N)=C([N+]([O-])=O)[N+]([O-])=O FUHQFAMVYDIUKL-UHFFFAOYSA-N 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- 229920005906 polyester polyol Polymers 0.000 claims description 4
- 235000008429 bread Nutrition 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 3
- 230000032683 aging Effects 0.000 claims description 2
- 230000003712 anti-aging effect Effects 0.000 claims description 2
- JDFUJAMTCCQARF-UHFFFAOYSA-N tatb Chemical compound NC1=C([N+]([O-])=O)C(N)=C([N+]([O-])=O)C(N)=C1[N+]([O-])=O JDFUJAMTCCQARF-UHFFFAOYSA-N 0.000 claims 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 239000004033 plastic Substances 0.000 description 17
- 239000004014 plasticizer Substances 0.000 description 11
- 239000002245 particle Substances 0.000 description 10
- 239000011230 binding agent Substances 0.000 description 8
- 235000011837 pasties Nutrition 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000470 constituent Substances 0.000 description 4
- 230000001186 cumulative effect Effects 0.000 description 4
- 230000003078 antioxidant effect Effects 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000003550 marker Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- YSIBQULRFXITSW-OWOJBTEDSA-N 1,3,5-trinitro-2-[(e)-2-(2,4,6-trinitrophenyl)ethenyl]benzene Chemical compound [O-][N+](=O)C1=CC([N+](=O)[O-])=CC([N+]([O-])=O)=C1\C=C\C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O YSIBQULRFXITSW-OWOJBTEDSA-N 0.000 description 2
- MKWKGRNINWTHMC-UHFFFAOYSA-N 4,5,6-trinitrobenzene-1,2,3-triamine Chemical compound NC1=C(N)C([N+]([O-])=O)=C([N+]([O-])=O)C([N+]([O-])=O)=C1N MKWKGRNINWTHMC-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- UQXKXGWGFRWILX-UHFFFAOYSA-N ethylene glycol dinitrate Chemical compound O=N(=O)OCCON(=O)=O UQXKXGWGFRWILX-UHFFFAOYSA-N 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 description 1
- SPDDEEJBIUXPEJ-UHFFFAOYSA-N 4-nitroimidazol-2-one Chemical compound [O-][N+](=O)C1=NC(=O)N=C1 SPDDEEJBIUXPEJ-UHFFFAOYSA-N 0.000 description 1
- NDYLCHGXSQOGMS-UHFFFAOYSA-N CL-20 Chemical compound [O-][N+](=O)N1C2N([N+]([O-])=O)C3N([N+](=O)[O-])C2N([N+]([O-])=O)C2N([N+]([O-])=O)C3N([N+]([O-])=O)C21 NDYLCHGXSQOGMS-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- SNIOPGDIGTZGOP-UHFFFAOYSA-N Nitroglycerin Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)CO[N+]([O-])=O SNIOPGDIGTZGOP-UHFFFAOYSA-N 0.000 description 1
- 239000000006 Nitroglycerin Substances 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- FYDSPEWNDZOWPU-UHFFFAOYSA-N [3-nitrooxy-2,2-bis(nitrooxymethyl)propyl] nitrate;1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1.[O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O FYDSPEWNDZOWPU-UHFFFAOYSA-N 0.000 description 1
- 238000003483 aging Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- DWCLXOREGBLXTD-UHFFFAOYSA-N dmdnb Chemical compound [O-][N+](=O)C(C)(C)C(C)(C)[N+]([O-])=O DWCLXOREGBLXTD-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229960003711 glyceryl trinitrate Drugs 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 239000008347 soybean phospholipid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
Definitions
- the present invention relates to a new malleable solid explosive, which is an alternative, or even an improvement, plastic explosives known to date (see below). It also relates to a process for obtaining said new malleable solid explosive.
- the technical field of the invention is that of (blocks of) malleable solid explosives (pastes), commonly called explosives plastic, initiated by a detonator, for military and civilian use. They are usually used in the form of breads of a few hundred grams. The malleability of these loaves of explosives makes it possible to perfectly adapt their shapes to the contours of the objects or structures to be destroyed.
- the first known plastic explosive known as "gelignite” was invented by Alfred Nobel in 1875. It consisted of nitrocellulose dissolved in nitroglycerin and mixed with wood pulp and saltpetre.
- plastic explosives contain an explosive charge (hexogen (RDX) and / or pentrite, for example), a polymeric rubber binder (most often synthetic such as a butadiene-styrene gum or a polyisobutylene ), a plasticizer (such as bis (2-ethylhexyl) adipate or sebacate, di-n-octyl phthalate, tri-n-butyl citrate), and additives (such as dyes, antioxidants and detection markers) .
- RDX hexogen
- pentrite a polymeric rubber binder
- plasticizer such as bis (2-ethylhexyl) adipate or sebacate, di-n-octyl phthalate, tri-n-butyl citrate
- additives such as dyes, antioxidants and detection markers
- the plasticizer (generally present at mass levels of 2 to 5%) has the role of giving plastic explosives their malleability and better mechanical strength not requiring their packaging in a structure (see the teaching of the prior art recalled ci above, relating to malleable explosives without plasticizer).
- the best known plastic explosives with this type of formulation are C-4 plastic and Semtex®, familiar to those skilled in the art. These plastic explosives therefore contain, in their composition, with reference to their plastic character, a polymeric rubber (solid) binder associated with a plasticizer. These two components, inert, do not participate in the desired explosive effect.
- the controlled dosage of the binder (polymer) and the plasticizer generally introduced at low levels (a few percent) within the energy load of the plastic explosive, complicates the manufacturing process of the plastic explosive.
- the inventor has sought a new type of explosive "plastic”, specifically a new malleable solid explosive, more interesting in terms of composition (without plasticizer), performance (with energy charge “less diluted”) and manufacturing process (simpler).
- the manufacture of these explosives comprises casting a pasty explosive composition in molds and then cross-linking said pasty composition in said molds.
- Said pasty composition is obtained by mixing two components, preconstituted;
- a pasty component A comprising the explosive charge (and optionally other pulverulent ingredients such as aluminum) and a crosslinkable liquid polymer, such as a hydroxytelechelic polybutadiene; and
- liquid component B comprising the crosslinking agent of said crosslinkable liquid polymer
- Said pasty component (obtained by simple mixing of its constituents in a kneader) does not exist in the form of blocks, is never molded. It is formulated only for its mixing with the crosslinking agent and its subsequent crosslinking, leading to the composite solid explosive.
- the present invention therefore relates to an original malleable solid explosive, which is an alternative, or even an improvement, plastic explosives known to date (see above).
- Said explosive is solid in that it does not flow by gravity (at ambient temperature and beyond: in fact, up to the temperature where the explosive charge it contains is no longer stable).
- Said explosive is malleable in that it can be modeled by hand (manually) at temperatures from -40 ° C to + 70 ° C.
- the malleable solid explosive of the invention is characterized in that it is in the form of a block (solid) consisting, for at least 98% of its mass, of a powdery explosive charge and a liquid chosen from among the polyol polymers of the group of polyisobutylene polyols, polybutadiene polyols, polyether polyols, polyester polyols and polysiloxane polyols, the number-average molecular mass of which is between 500 and 10,000, and mixtures thereof.
- the said malleable solid explosive of the invention combines, in an original manner, physical (physical) presentation and composition characteristics.
- the malleable solid explosive of the invention is therefore in the form of a block, i.e. in the form of a compact mass. It is actually a block, obtained by molding or by cutting a paste (see its production process described below).
- the malleable solid explosive of the invention can thus be obtained by molding a pasty component A according to the patent application EP-A-1 333 015.
- the presently claimed invention provides an original outlet for this component A, proposes a use completely original to it (in the context of the invention, said component is not crosslinked but used "as is" after a simple formatting). Note however that the scope of the invention is in no way limited to said components A according to the patent application EP-A-1 333 015.
- the powdery explosive charge (whose particle size (s), which is not original, per se, is (are) conventionally generally between 2 and 500 ⁇ m) of the block contains one or more explosives. (in mixture).
- the (s) explosive (s) present (s) is (are) advantageously to different particle sizes (grain size). It is thus possible to have high charge rates.
- the powdery explosive charge of the block represents at least 85% by weight of the total mass of the block.
- the liquid present also consists of a liquid (chosen from the polyol polymers specified above) or a mixture of liquids (chosen from the polyol polymers specified above). It can be or not a solvent of the powdery explosive charge. In the event that said liquid is a solvent of said charge, it is understood that said charge is present at concentrations above the saturation concentration, insofar as a solid block is involved.
- the malleable solid explosive block is essentially (for at least 98% of its mass) consisting of said charge and said liquid. In addition to said charge and said liquid, it is likely to contain only additives (see below). It can be entirely (at 100%) constituted of said charge and said liquid. No plasticizer is present in its composition.
- the mass ratio (S / L) is a priori high. It has been seen above that the powdery explosive charge of the block advantageously represents less 85% by mass of the total mass of the block. Furthermore, it is advantageous to combine a liquid with a dynamic viscosity of between 0.1 and 1 Pa.s in the temperature range; - 40 ° C and + 70 ° C and an explosive charge particle size between 1 and 150 pm. Very advantageously, a solid explosive charge having a plurality of particle size fractions between 1 and 150 ⁇ m is chosen.
- the explosive charge of the solid explosive blocks of the invention is not per se original. It may in particular consist of octogen (HMX), hexogen (RDX), pentaerythritetritetitrate (pentrite or PETN), hexanitrohexaazaisowurtzitane (CL2O), triaminotrinitrobenzene (TATB), 5-nitro 2,2,4-triazol-3-one (ONTA), hexanitrostilbene (HNS), 1,1-diamino-2,2-dinitroethene (DADNE or Fox-7) or a mixture thereof. It is advantageously chosen from octogen, hexogen, penthrite and CL20. Hexogen is the preferred explosive (energy) charge of the blocks of the invention.
- the liquid is therefore chosen from the polyol polymers below; polyisobutylene polyols, polybutadiene polyols, polyether polyols, polyester polyols and polysiloxane polyols, having a number average molecular weight of from 500 to 10,000, and mixtures thereof.
- Said liquid is advantageously chosen from said polybutadienes polyols and their mixtures.
- Said liquid is very advantageously a hydroxytelechelic polybutadiene of this type.
- the liquid for the malleable solid explosives of the invention are suitably suitable for the commonly used hydroxytelechelic polybutadienes. 2010/052827
- said filler and said liquid constitute from 98% to 100% (by mass) of the malleable solid explosive of the invention, malleable solid explosive blocks of the invention.
- Said explosive blocks are in fact likely to contain additives, including antioxidants, anti-aging agents, chemical detection markers, for at most 2% of their total mass.
- Additives which may be contained in said explosive blocks include;
- At least one antioxidant of the polymer polyol type liquid
- At least one anti-hardening agent in aging, in particular when hot such as, for example, a silicone oil, tetraethylenepentamineacrylonitrile (TEPAN), soya lecithin and mixtures thereof;
- a silicone oil such as, for example, a silicone oil, tetraethylenepentamineacrylonitrile (TEPAN), soya lecithin and mixtures thereof;
- At least one chemical detection marker such as, for example, EGDN (EthyleneGlycol DiNitrate), D DNB (2,3-DiMethyl-2,3-DiNitrobutane), p-MNT (para-MonoNitroToluene) or o-MNT (ortho-mono nitro toluene).
- EGDN EthyleneGlycol DiNitrate
- D DNB 2,3-DiMethyl-2,3-DiNitrobutane
- p-MNT para-MonoNitroToluene
- o-MNT ortho-mono nitro toluene
- the malleable solid explosive block of the invention contains, in percentages by mass:
- a polyol polymer liquid of the type specified above (a single liquid or a mixture of at least two liquids).
- the blocks of the invention generally have a mass of between 100 g and 5 kg. These blocks of malleable solid explosive can be considered as breads (in the sense of plastic explosive bars of the prior art).
- the blocks of the invention have rheological qualities and performance superior to those of malleable explosive blocks incorporating a plasticizer. They can be stored and used in large mass loaves (for example several kilograms) without any precaution with reference to their mechanical strength, unlike the malleable explosives of the prior art without plasticizer.
- the explosive charge and the polymer polyol liquid forming the malleable explosive of the invention interact to impart to said explosive particularly advantageous rheological properties.
- the presence of hydroxy (OH) functions in the chemical formula of the polyol polymers is most certainly at the origin of this particular interaction.
- the present invention relates to a process for obtaining a malleable solid explosive as described above (first object of said invention). Said method comprises:
- a paste by mixing a mixture consisting, for at least 98% of its mass, of a powdery explosive charge and a liquid (as specified above), molding said paste in one or more molds and demolding said molded paste to obtain a block (es) of said malleable solid explosive or cutting said paste to obtain blocks; said malleable solid explosive.
- the mixing powder explosive charge + liquid polymer polyol, for obtaining dough can be implemented at room temperature or hot.
- the mixing temperature is obviously compatible with the safety standards, given the exact nature of the explosive charge. In this spirit, it is generally below 80 ° C.
- the process for obtaining the original explosive of the invention may be carried out continuously or discontinuously.
- the constituents of the blocks of the invention are mixed hot (typically 60 ° C.) in a kneader; the mixture obtained (whose mass may for example vary from 100 kg to 5 tons) is then discharged from the mixer to be introduced into a funnel terminated by a worm; said mixture is driven by the worm to be placed in molds (whose volume may be variable, typically between 100 and 700 cm 3 depending on the intended applications, generally 350 cm 3 ); said mixture contained in each mold is then demolded to obtain a malleable explosive block.
- the constituents of the blocks of the invention are mixed hot (typically 60 ° C.) in a kneader; the mixture obtained (whose mass may for example vary from 100 kg to 5 tons) is then discharged from the mixer to be introduced into a funnel terminated by a worm; said mixture is driven by the worm to be placed in molds (whose volume may be variable, typically between 100 and 700 cm 3 depending on the intended applications, generally 350 cm 3 ); said mixture contained in each mold is then demolded to obtain
- the mixture is obtained by continuous stirring while hot and then directly extruded into molds (whose volume may be variable, typically between 100 and 700 cm 3 depending on the intended applications, generally 350 cm 3 ).
- the mixture is obtained by mixing with continuous hot and then extruded directly, the extruded rod being chopped so as to obtain blocks of specific mass.
- the density of the explosive block obtained may vary according to the amount of air trapped in the explosive charge during the obtaining process. Said density is advantageously between 1300 and 1700 kg / m 3 .
- Table 1 below shows the composition of said malleable solid explosive according to the invention.
- the liquid is a hydroxytelechelic polybutadiene (PBHT).
- PBHT hydroxytelechelic polybutadiene
- This is the PBHT R45HTLO sold by the company Sartomer (Mn 3000). It intervenes at about 10% in mass.
- the powdery explosive charge (which occurs at 88% by weight) consists of RDX. It is more precisely composed of two RDX charges of different particle size, referenced charge 1 and charge 2 in table 1. The particle size of these two charges 1 and 2 is given by three values recorded on the cumulative curve of the particle volume percentages. according to the diameter (equivalent spherical) of the particles, accumulated according to the increasing diameters:
- Dio diameter for which the cumulative volume percentage is equal to 10%
- the mass composition of the malleable solid explosive block also contains additives (an antioxidant, an anti-oxidant, age hardening and a chemical marker), for less than 2 percent of its total mass.
- the constituents of the malleable solid explosive block of the invention are hot-kneaded (60 ° C +/- 10 ° C), each kneading operation involves about 200 kg of material.
- the paste obtained is then discharged and introduced into a funnel provided with an endless screw for filling molds.
- the volume of the molds is about 50 cm 3 .
- the solid block of malleable explosive generated in each mold is then demolded to obtain a malleable explosive bar of about 0.5 kg.
- the density of the explosive loaves obtained by this process may vary depending on the amount of air entrapped in the pulp during the process. Said density is between 1480 and 1520 kg / m 3 .
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0959290A FR2954309B1 (en) | 2009-12-21 | 2009-12-21 | MALLEABLE SOLID EXPLOSIVE AND ITS OBTAINING |
PCT/FR2010/052827 WO2011083249A1 (en) | 2009-12-21 | 2010-12-20 | Malleable solid explosive and method for obtaining it |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2516356A1 true EP2516356A1 (en) | 2012-10-31 |
EP2516356B1 EP2516356B1 (en) | 2020-03-11 |
Family
ID=42269997
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10810850.7A Active EP2516356B1 (en) | 2009-12-21 | 2010-12-20 | Malleable solid explosive and method for obtaining it |
Country Status (14)
Country | Link |
---|---|
US (1) | US20120305148A1 (en) |
EP (1) | EP2516356B1 (en) |
JP (1) | JP2013514962A (en) |
KR (1) | KR20120108014A (en) |
CN (1) | CN102666438B (en) |
AU (1) | AU2010340832B2 (en) |
BR (1) | BR112012015076A2 (en) |
CA (1) | CA2784311C (en) |
ES (1) | ES2796830T3 (en) |
FR (1) | FR2954309B1 (en) |
IL (1) | IL220431A (en) |
RU (1) | RU2541079C2 (en) |
SG (1) | SG181832A1 (en) |
WO (1) | WO2011083249A1 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2991317B1 (en) | 2012-06-04 | 2014-06-20 | Eurenco France | EXPLOSIVE FACTICE SIMULATING AN EXPLOSIVE MALLEABLE AND METHOD OF OBTAINING SAME |
CN102887803B (en) * | 2012-09-22 | 2014-09-24 | 山西北化关铝化工有限公司 | Low-pressure formed explosive |
FR3027598B1 (en) | 2014-10-28 | 2018-05-04 | Arianegroup Sas | COMPOSITE PYROTECHNIC PRODUCT WITH DNA AND RDX LOADS IN PAG TYPE BINDER AND PREPARATION THEREOF |
FR3028852B1 (en) * | 2014-11-21 | 2017-01-06 | Herakles | LOW THICK COMPOSITE EXPLOSIVE PRODUCTS AND THEIR PREPARATION |
CN104447144B (en) * | 2014-11-22 | 2016-07-06 | 山西北化关铝化工有限公司 | Superhigh temperature petroleum perforation charge plastic bonded explosive and preparation method thereof |
RU2610613C1 (en) * | 2015-09-07 | 2017-02-14 | Федеральное Казенное Предприятие "Бийский Олеумный Завод" | Grammonite |
CN106478322B (en) * | 2016-10-13 | 2018-04-17 | 西南科技大学 | A kind of 20 base heat cure explosive emulsion preparation methods of micro-nano CL |
CN112980116B (en) * | 2021-01-22 | 2022-02-15 | 北京理工大学 | Preparation method of energy storage fragment with telescopic spiral structure |
CN113860978A (en) * | 2021-06-09 | 2021-12-31 | 沈阳消应***工程有限公司 | Explosive for metal explosion hardening and preparation method thereof |
WO2024058449A1 (en) * | 2022-09-13 | 2024-03-21 | 국방과학연구소 | Polysiloxane binder-based castable high-energy composition, core explosive composition, shell fuel composition, single thermobaric explosive composition, and warhead including same |
Family Cites Families (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU439A1 (en) * | 1913-10-08 | 1924-09-15 | Адде С. | The method of preparation of plastic explosive composition |
US2999744A (en) * | 1955-05-06 | 1961-09-12 | Hercules Powder Co Ltd | Plastic explosive compositions |
US3113894A (en) * | 1962-06-27 | 1963-12-10 | Atlantic Res Corp | Thixotropic heterogeneous monopropellant compositions |
US4047990A (en) * | 1967-08-01 | 1977-09-13 | The United States Of America As Represented By The Secretary Of The Navy | Plastic bonded explosive composition |
DE2027709C3 (en) * | 1970-06-05 | 1978-10-19 | Dynamit Nobel Ag, 5210 Troisdorf | Plastic, easily deformable explosive mass by hand |
US4214928A (en) * | 1976-11-29 | 1980-07-29 | The United States Of America As Represented By The Secretary Of The Navy | Dimethyl hydantoin bonding agents in solid propellants |
US4293351A (en) * | 1979-08-06 | 1981-10-06 | Johannes Gerald E | Silicone rubber explosive and method of making |
DE3046562A1 (en) * | 1980-12-10 | 1982-07-15 | Dynamit Nobel Ag, 5210 Troisdorf | Plastic high explosive slab shaped block - esp. for penetrating steel plate 20 mm thick has all round foil casing and adhesive tape (NL 01.07.82) |
CA1195122A (en) * | 1981-05-25 | 1985-10-15 | Paul Arni | Process for preparing a high power explosive, high power explosive produced thereby and method for shaping a high power |
JPS5973488A (en) * | 1982-10-20 | 1984-04-25 | 日本油脂株式会社 | Caking agent for solid propellant |
JPS6398562A (en) * | 1986-10-15 | 1988-04-30 | Zenkoku Kayakurui Hoan Kyokai | Method for testing explosion boosting property |
EP0266973A3 (en) * | 1986-11-06 | 1990-01-10 | Thiokol Corporation | Pcp/htpb block copolymer and propellant binder prepared therefrom |
CN1029118C (en) * | 1990-06-27 | 1995-06-28 | 冶金工业部长沙矿冶研究院 | High-dispersity powdery ammonium nitrate fuel oil explosive |
JPH05294773A (en) * | 1992-04-23 | 1993-11-09 | Nissan Motor Co Ltd | Composite propellant |
SE470480B (en) * | 1992-10-02 | 1994-05-24 | Bofors Explosives Ab | Fuel for Air bags |
RU2086525C1 (en) * | 1993-01-12 | 1997-08-10 | Центральный научно-исследовательский институт химии и механики | Explosive composition (variants) |
US5529649A (en) * | 1993-02-03 | 1996-06-25 | Thiokol Corporation | Insensitive high performance explosive compositions |
JPH07232988A (en) * | 1994-02-18 | 1995-09-05 | Nippon Koki Kk | Explosive composition |
JPH08338312A (en) * | 1995-06-14 | 1996-12-24 | Asahi Chem Ind Co Ltd | Non-hypergolic solid propellant |
FR2750421B1 (en) * | 1996-06-28 | 1998-08-07 | Poudres & Explosifs Ste Nale | HIGH SPECIFIC IMPULSE PROPERGOLS WITH FURAZANE DERIVATIVES |
GB9712748D0 (en) * | 1997-06-17 | 1997-08-20 | Dimitrov Stokyo I | Plastic explosive |
US5996501A (en) * | 1997-08-27 | 1999-12-07 | The United States Of America As Represented By The Secretary Of The Air Force | Blast and fragmentation enhancing explosive |
JP2770018B1 (en) * | 1997-11-26 | 1998-06-25 | 旭化成工業株式会社 | Hexanitrohexaazaisowurtzitane composition and high performance explosive composition comprising the composition |
DE19821150C1 (en) * | 1998-05-12 | 1999-10-28 | Daimler Chrysler Ag | Detonative deformable bursting charge useful in guided war heads |
US6009810A (en) * | 1998-07-08 | 2000-01-04 | The United States Of America As Represented By The Secretary Of The Navy | Airbag propellant |
US6736913B1 (en) * | 2000-10-31 | 2004-05-18 | Alliant Techsystems Inc. | Method for processing explosives containing 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo [5.5.0.05,903,11]-dodecan (CL-20) with naphthenic and paraffinic oils |
DE10057673A1 (en) * | 2000-11-21 | 2002-05-23 | Rheinmetall W & M Gmbh | warhead |
FR2835519B1 (en) * | 2002-02-01 | 2004-11-19 | Poudres & Explosifs Ste Nale | SEMI-CONTINUOUS TWO-COMPONENT PROCESS FOR OBTAINING A COMPOSITE EXPLOSIVE CHARGE WITH A POLYURETHANE MATRIX |
US6748842B1 (en) * | 2003-05-09 | 2004-06-15 | The United States Of America As Represented By The Secretary Of The Navy | Darts containing explosives for defeating buried mines |
JP2005274071A (en) * | 2004-03-25 | 2005-10-06 | Nippon Koki Co Ltd | Laminated explosive warhead |
IL165231A (en) * | 2004-11-16 | 2010-12-30 | Rafael Advanced Defense Sys | Highly-filled, high-viscosity paste charge and method and device for the production thereof |
FR2917169B1 (en) * | 2007-06-06 | 2009-09-11 | Eurenco France Sa | METHOD FOR DETERMINING THE SENSITIVE OR INSENSITIVE CHARACTER OF A HEXOGEN |
CN100548937C (en) * | 2007-10-08 | 2009-10-14 | 安徽理工大学 | The compound oil phase that is used for powder ammonium nitrate explosive |
JP2009137820A (en) * | 2007-12-11 | 2009-06-25 | Daicel Chem Ind Ltd | Gelatinous transfer charge for inflator |
US7854811B1 (en) * | 2009-07-11 | 2010-12-21 | Kemzecur, Inc. | Mouldable plastic explosives and inert simulants for mouldable plastic explosives |
CN101813439B (en) * | 2009-12-06 | 2013-09-11 | 湖北凯龙化工集团股份有限公司 | Pressure resistant type pasty or liquid explosive column |
-
2009
- 2009-12-21 FR FR0959290A patent/FR2954309B1/en not_active Expired - Fee Related
-
2010
- 2010-12-20 KR KR1020127019249A patent/KR20120108014A/en not_active Application Discontinuation
- 2010-12-20 RU RU2012129733/05A patent/RU2541079C2/en not_active IP Right Cessation
- 2010-12-20 EP EP10810850.7A patent/EP2516356B1/en active Active
- 2010-12-20 CN CN201080058611.1A patent/CN102666438B/en not_active Expired - Fee Related
- 2010-12-20 AU AU2010340832A patent/AU2010340832B2/en not_active Ceased
- 2010-12-20 JP JP2012545381A patent/JP2013514962A/en active Pending
- 2010-12-20 SG SG2012045522A patent/SG181832A1/en unknown
- 2010-12-20 BR BR112012015076A patent/BR112012015076A2/en not_active IP Right Cessation
- 2010-12-20 ES ES10810850T patent/ES2796830T3/en active Active
- 2010-12-20 WO PCT/FR2010/052827 patent/WO2011083249A1/en active Application Filing
- 2010-12-20 US US13/515,367 patent/US20120305148A1/en not_active Abandoned
- 2010-12-20 CA CA2784311A patent/CA2784311C/en not_active Expired - Fee Related
-
2012
- 2012-06-14 IL IL220431A patent/IL220431A/en not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
See references of WO2011083249A1 * |
Also Published As
Publication number | Publication date |
---|---|
SG181832A1 (en) | 2012-07-30 |
CN102666438A (en) | 2012-09-12 |
AU2010340832B2 (en) | 2015-04-09 |
JP2013514962A (en) | 2013-05-02 |
BR112012015076A2 (en) | 2017-03-07 |
CA2784311C (en) | 2018-03-13 |
IL220431A (en) | 2017-04-30 |
FR2954309B1 (en) | 2012-03-23 |
RU2012129733A (en) | 2014-02-10 |
CN102666438B (en) | 2014-10-08 |
RU2541079C2 (en) | 2015-02-10 |
ES2796830T3 (en) | 2020-11-30 |
EP2516356B1 (en) | 2020-03-11 |
AU2010340832A1 (en) | 2012-07-12 |
US20120305148A1 (en) | 2012-12-06 |
CA2784311A1 (en) | 2011-07-14 |
FR2954309A1 (en) | 2011-06-24 |
WO2011083249A1 (en) | 2011-07-14 |
KR20120108014A (en) | 2012-10-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2784311C (en) | Malleable solid explosive and method for obtaining it | |
EP1790626B1 (en) | Semicontiunuous process for making an explosive composite charge having a polyurethane matrix by using two components | |
CA2418319C (en) | Semi-continuous bicomposite process for obtaining a composite explosive charge with a polyurethane matrix | |
EP0194180A1 (en) | Process for the solventless production of pyrotechnical products having a thermosetting binder | |
FR2746389A1 (en) | PROPERGOL COMPOSITE, PROPULSIVE LOAD AND METHODS OF MAKING THE SAME | |
WO2016066945A1 (en) | Efficient composite pyrotechnic product with no pb in the composition thereof and preparation of same | |
EP3071537B1 (en) | Composite pyrotechnical product with non-crosslinked binder and method for preparing same | |
WO2013182796A1 (en) | Fake explosive simulating a malleable explosive and its manufacturing process | |
EP3071536B1 (en) | Composite pyrotechnical product with crosslinked binder and method for preparing same | |
WO2018055312A1 (en) | Composite pyrotechnic product containing an anti-gleam agent of potassium salt type | |
FR3051188A1 (en) | EXPLOSIVE COMPOSITE WITH SLOW DETONATION SPEED AND PLANE OR LINEAR WAVE GENERATOR INCLUDING | |
CA2968255A1 (en) | Thin composite explosive products and preparation thereof | |
EP3753916A1 (en) | Composite pyrotechnical product | |
FR3051189A1 (en) | EXPLOSIVE MASTERIZED BLOW EFFECT COMPOSITE | |
FR3028853A1 (en) | DETONATING CUTTING ROPES AND THEIR PREPARATION |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20120613 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
DAX | Request for extension of the european patent (deleted) | ||
GBC | Gb: translation of claims filed (gb section 78(7)/1977) | ||
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
17Q | First examination report despatched |
Effective date: 20170320 |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: EURENCO |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20190621 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAJ | Information related to disapproval of communication of intention to grant by the applicant or resumption of examination proceedings by the epo deleted |
Free format text: ORIGINAL CODE: EPIDOSDIGR1 |
|
GRAL | Information related to payment of fee for publishing/printing deleted |
Free format text: ORIGINAL CODE: EPIDOSDIGR3 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTC | Intention to grant announced (deleted) | ||
INTG | Intention to grant announced |
Effective date: 20191024 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1242968 Country of ref document: AT Kind code of ref document: T Effective date: 20200315 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602010063483 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
REG | Reference to a national code |
Ref country code: NO Ref legal event code: T2 Effective date: 20200311 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20200311 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200612 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200611 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200805 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200711 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 1242968 Country of ref document: AT Kind code of ref document: T Effective date: 20200311 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2796830 Country of ref document: ES Kind code of ref document: T3 Effective date: 20201130 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602010063483 Country of ref document: DE |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 |
|
26N | No opposition filed |
Effective date: 20201214 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 602010063483 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20201231 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201220 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201220 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201231 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210701 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201231 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20220412 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200311 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201221 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201231 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20231220 Year of fee payment: 14 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20231218 Year of fee payment: 14 Ref country code: NO Payment date: 20231128 Year of fee payment: 14 Ref country code: IT Payment date: 20231211 Year of fee payment: 14 Ref country code: FR Payment date: 20231222 Year of fee payment: 14 Ref country code: CZ Payment date: 20231114 Year of fee payment: 14 |