EP2435669A2 - Process for utilizing the sythesis gas originating from a gasifier - Google Patents
Process for utilizing the sythesis gas originating from a gasifierInfo
- Publication number
- EP2435669A2 EP2435669A2 EP09795332A EP09795332A EP2435669A2 EP 2435669 A2 EP2435669 A2 EP 2435669A2 EP 09795332 A EP09795332 A EP 09795332A EP 09795332 A EP09795332 A EP 09795332A EP 2435669 A2 EP2435669 A2 EP 2435669A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- gas
- fed
- gas turbine
- burner
- compressed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims description 12
- 239000007789 gas Substances 0.000 claims abstract description 59
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 13
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 13
- 238000003860 storage Methods 0.000 claims abstract description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000001301 oxygen Substances 0.000 claims abstract description 6
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 6
- 238000000926 separation method Methods 0.000 claims description 12
- 238000010248 power generation Methods 0.000 abstract description 3
- 238000005194 fractionation Methods 0.000 abstract 1
- 238000002309 gasification Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000006835 compression Effects 0.000 description 5
- 238000007906 compression Methods 0.000 description 5
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002006 petroleum coke Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/34—Gas-turbine plants characterised by the use of combustion products as the working fluid with recycling of part of the working fluid, i.e. semi-closed cycles with combustion products in the closed part of the cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/20—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
- F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
- F01K23/06—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
- F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
- F01K23/06—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
- F01K23/067—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle the combustion heat coming from a gasification or pyrolysis process, e.g. coal gasification
- F01K23/068—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle the combustion heat coming from a gasification or pyrolysis process, e.g. coal gasification in combination with an oxygen producing plant, e.g. an air separation plant
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/04—Gas-turbine plants characterised by the use of combustion products as the working fluid having a turbine driving a compressor
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/20—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
- F02C3/26—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being solid or pulverulent, e.g. in slurry or suspension
- F02C3/28—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being solid or pulverulent, e.g. in slurry or suspension using a separate gas producer for gasifying the fuel before combustion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
- F02C6/18—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
- Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/32—Direct CO2 mitigation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Definitions
- the starting point of the present invention is also a fuel gasification for the production of synthesis gas, wherein any kind of gasification is included here.
- synthesis gas should then be more economical and optimal Be used manner, in particular for power generation, in which case simultaneously occurring CO 2 storage should be supplied.
- the invention uses in a simple way by the combustion of the synthesis gas, the immediate one or two-stage compression of the C0 2 -Gastromes to pressures that makes possibly a storage of CO 2 possible after further compression.
- the product is then fed to the subsequent CO 2 conversion 6, this step serving to increase the synthesis gas temperature and to convert COS into H 2 S and HCN into NH 3 and CO.
- the conversion 6 joins the hydrolysis 7 to the carbonoxysulfide removal.
- the carbon oxysulfide present in the gas which is difficult to wash with water and other customary solvents, is converted into hydrogen sulphide by catalytic hydrolysis, the carbon dioxide oxide in the gas phase being mixed with steam according to the reaction equation COS + H 2 O - ⁇ H 2 S + CO 2 reacts.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Industrial Gases (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Air Supply (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008063055A DE102008063055A1 (en) | 2008-12-23 | 2008-12-23 | Process for using the gas from a gasifier synthesis gas |
PCT/EP2009/008864 WO2010072337A2 (en) | 2008-12-23 | 2009-12-11 | Process for utilizing the sythesis gas originating from a gasifier |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2435669A2 true EP2435669A2 (en) | 2012-04-04 |
Family
ID=42288174
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09795332A Withdrawn EP2435669A2 (en) | 2008-12-23 | 2009-12-11 | Process for utilizing the sythesis gas originating from a gasifier |
Country Status (13)
Country | Link |
---|---|
US (1) | US9410480B2 (en) |
EP (1) | EP2435669A2 (en) |
KR (1) | KR20110114546A (en) |
CN (1) | CN102405340B (en) |
AU (1) | AU2009331944B2 (en) |
CA (1) | CA2745227C (en) |
DE (1) | DE102008063055A1 (en) |
NZ (1) | NZ593060A (en) |
RU (1) | RU2011130188A (en) |
TW (1) | TW201033458A (en) |
UA (1) | UA105651C2 (en) |
WO (1) | WO2010072337A2 (en) |
ZA (1) | ZA201105376B (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8881659B2 (en) * | 2009-12-04 | 2014-11-11 | Kinetix Ag | Folding table for attachment to the rear side of a vehicle seat part |
US8535418B2 (en) * | 2010-11-22 | 2013-09-17 | General Electric Company | Gaseous byproduct removal from synthesis gas |
US20130133337A1 (en) * | 2011-11-30 | 2013-05-30 | General Electric Company | Hydrogen assisted oxy-fuel combustion |
EP2657469A1 (en) * | 2012-04-25 | 2013-10-30 | Burmeister & Wain Energy A/S | Biomass fuelled power production system |
JP2013241923A (en) * | 2012-05-23 | 2013-12-05 | Babcock Hitachi Kk | Gasification power generation system of carbon-based fuel |
JP6057674B2 (en) * | 2012-11-08 | 2017-01-11 | 三菱日立パワーシステムズ株式会社 | Gasification system for high moisture solid fuel |
CN103388497B (en) * | 2013-08-09 | 2015-05-20 | 中国能源建设集团广东省电力设计研究院 | Preheating clean synthesis gas method and system for improving IGCC (integrated gasification combined cycle) power generation facility performances |
CN108368750B (en) | 2015-09-01 | 2020-08-18 | 八河流资产有限责任公司 | Using an Embedded CO2System and method for cyclic power generation |
DE102015218502A1 (en) * | 2015-09-25 | 2017-03-30 | Siemens Aktiengesellschaft | Steam turbine power plant with hydrogen combustion with the involvement of a gasification device |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1546077A (en) | 1975-06-13 | 1979-05-16 | Novo Industri As | Chemical compounds process for preparing said compounds and process for preparing 6-(p-hydroxyphenyl-glycylamido)-penam or 7-(p-hydroxyphenyl-glycylamido)-cephem compounds |
DE3501456A1 (en) * | 1985-01-17 | 1986-07-17 | Linde Ag, 6200 Wiesbaden | Process for reducing the SO2 and NOx content of gases |
CA2081189C (en) * | 1992-10-22 | 1998-12-01 | Tony E. Harras | Co2 recycle for a gas-fired turbogenerator |
US5388395A (en) * | 1993-04-27 | 1995-02-14 | Air Products And Chemicals, Inc. | Use of nitrogen from an air separation unit as gas turbine air compressor feed refrigerant to improve power output |
US5724805A (en) * | 1995-08-21 | 1998-03-10 | University Of Massachusetts-Lowell | Power plant with carbon dioxide capture and zero pollutant emissions |
DE69729038T2 (en) * | 1996-09-20 | 2005-05-12 | Kabushiki Kaisha Toshiba, Kawasaki | Power plant with separation and recovery of carbon dioxide |
US6025403A (en) | 1997-07-07 | 2000-02-15 | Mobil Oil Corporation | Process for heat integration of an autothermal reformer and cogeneration power plant |
DE69943019D1 (en) | 1998-02-04 | 2011-01-20 | Ge Energy Usa Llc | COMBINED SEPARATOR FOR DEEP-COOLED AIR AND INTEGRATED EVAPORATOR |
JP4509267B2 (en) | 1999-11-15 | 2010-07-21 | 日揮株式会社 | Oil fuel-fired combined power generation facility and method thereof |
WO2001075277A1 (en) * | 2000-03-31 | 2001-10-11 | Northern Research And Engineering Corporation | Solid-fueled power generation system with carbon dioxide sequestration and method therefor |
US20030008183A1 (en) | 2001-06-15 | 2003-01-09 | Ztek Corporation | Zero/low emission and co-production energy supply station |
WO2006009029A1 (en) | 2004-07-15 | 2006-01-26 | Dai Nippon Printing Co., Ltd. | Semiconductor device and semiconductor device producing substrate and production method for semiconductor device producing substrate |
US7691714B2 (en) | 2005-01-25 | 2010-04-06 | Texas Instruments Incorporated | Semiconductor device having a dislocation loop located within a boundary created by source/drain regions and a method of manufacture therefor |
DE102007022168A1 (en) * | 2007-05-11 | 2008-11-13 | Siemens Ag | Process for generating motor energy from fossil fuels with removal of pure carbon dioxide |
US20090084035A1 (en) * | 2007-09-28 | 2009-04-02 | General Electric Company | Polygeneration systems |
-
2008
- 2008-12-23 DE DE102008063055A patent/DE102008063055A1/en not_active Withdrawn
-
2009
- 2009-12-11 RU RU2011130188/05A patent/RU2011130188A/en not_active Application Discontinuation
- 2009-12-11 US US12/998,863 patent/US9410480B2/en not_active Expired - Fee Related
- 2009-12-11 CA CA2745227A patent/CA2745227C/en not_active Expired - Fee Related
- 2009-12-11 NZ NZ593060A patent/NZ593060A/en not_active IP Right Cessation
- 2009-12-11 UA UAA201109106A patent/UA105651C2/en unknown
- 2009-12-11 KR KR1020117014624A patent/KR20110114546A/en active Search and Examination
- 2009-12-11 AU AU2009331944A patent/AU2009331944B2/en not_active Ceased
- 2009-12-11 CN CN200980151734.7A patent/CN102405340B/en not_active Expired - Fee Related
- 2009-12-11 EP EP09795332A patent/EP2435669A2/en not_active Withdrawn
- 2009-12-11 WO PCT/EP2009/008864 patent/WO2010072337A2/en active Application Filing
- 2009-12-21 TW TW098143823A patent/TW201033458A/en unknown
-
2011
- 2011-07-21 ZA ZA2011/05376A patent/ZA201105376B/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO2010072337A3 (en) | 2012-07-05 |
AU2009331944A1 (en) | 2011-06-23 |
NZ593060A (en) | 2012-11-30 |
UA105651C2 (en) | 2014-06-10 |
CA2745227A1 (en) | 2010-07-01 |
ZA201105376B (en) | 2012-12-27 |
CN102405340A (en) | 2012-04-04 |
TW201033458A (en) | 2010-09-16 |
US20110248513A1 (en) | 2011-10-13 |
WO2010072337A4 (en) | 2012-09-07 |
US9410480B2 (en) | 2016-08-09 |
RU2011130188A (en) | 2013-01-27 |
CA2745227C (en) | 2016-07-12 |
DE102008063055A1 (en) | 2010-08-05 |
WO2010072337A2 (en) | 2010-07-01 |
AU2009331944B2 (en) | 2015-03-05 |
KR20110114546A (en) | 2011-10-19 |
CN102405340B (en) | 2015-06-03 |
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