EP2430215B1 - Device for collecting the solid debris present in the bath and the liquid metal of an electrolysis cell intended for aluminium production, by scraping the bottom of said cell - Google Patents
Device for collecting the solid debris present in the bath and the liquid metal of an electrolysis cell intended for aluminium production, by scraping the bottom of said cell Download PDFInfo
- Publication number
- EP2430215B1 EP2430215B1 EP10727005.0A EP10727005A EP2430215B1 EP 2430215 B1 EP2430215 B1 EP 2430215B1 EP 10727005 A EP10727005 A EP 10727005A EP 2430215 B1 EP2430215 B1 EP 2430215B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- collection unit
- chamber
- rod
- actuator
- hydraulic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000005868 electrolysis reaction Methods 0.000 title claims description 29
- 229910052782 aluminium Inorganic materials 0.000 title claims description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 14
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 239000007787 solid Substances 0.000 title claims description 10
- 238000007790 scraping Methods 0.000 title description 9
- 229910001338 liquidmetal Inorganic materials 0.000 title description 7
- 239000004411 aluminium Substances 0.000 title 1
- 238000004140 cleaning Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 3
- SGPGESCZOCHFCL-UHFFFAOYSA-N Tilisolol hydrochloride Chemical compound [Cl-].C1=CC=C2C(=O)N(C)C=C(OCC(O)C[NH2+]C(C)(C)C)C2=C1 SGPGESCZOCHFCL-UHFFFAOYSA-N 0.000 claims 6
- 238000010586 diagram Methods 0.000 description 5
- 239000003792 electrolyte Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241001080024 Telles Species 0.000 description 2
- 238000012550 audit Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminium flouride Chemical compound F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- 208000031968 Cadaver Diseases 0.000 description 1
- 238000009626 Hall-Héroult process Methods 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229910001610 cryolite Inorganic materials 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B9/00—Cleaning hollow articles by methods or apparatus specially adapted thereto
- B08B9/08—Cleaning containers, e.g. tanks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B66—HOISTING; LIFTING; HAULING
- B66C—CRANES; LOAD-ENGAGING ELEMENTS OR DEVICES FOR CRANES, CAPSTANS, WINCHES, OR TACKLES
- B66C3/00—Load-engaging elements or devices attached to lifting or lowering gear of cranes or adapted for connection therewith and intended primarily for transmitting lifting forces to loose materials; Grabs
- B66C3/02—Bucket grabs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B66—HOISTING; LIFTING; HAULING
- B66C—CRANES; LOAD-ENGAGING ELEMENTS OR DEVICES FOR CRANES, CAPSTANS, WINCHES, OR TACKLES
- B66C3/00—Load-engaging elements or devices attached to lifting or lowering gear of cranes or adapted for connection therewith and intended primarily for transmitting lifting forces to loose materials; Grabs
- B66C3/14—Grabs opened or closed by driving motors thereon
- B66C3/16—Grabs opened or closed by driving motors thereon by fluid motors
Definitions
- the invention relates to the production of aluminum by igneous electrolysis according to the Hall-Héroult method. It relates more particularly to a device for collecting solid debris immersed or floating in the electrolysis bath and the liquid metal, in particular sludge from the electrolytic bath and which accumulate on the bottom of the tank, as well as the remains of carbon and crust debris that originate in particular from the various operations performed before and during the removal of spent anodes.
- Aluminum is produced industrially by igneous electrolysis, according to the well-known Hall-Héroult process, in electrolysis cells.
- the plants contain a large number of electrolysis cells arranged in line, in buildings called halls or electrolysis rooms, and connected electrically in series using connecting conductors, so as to optimize the ground occupation of the cells. factories.
- the cells are generally arranged to form two or more parallel lines that are electrically bonded together by end conductors.
- the electrolyte bath and the liquid metal are contained in a tank, called an "electrolysis cell", comprising a steel box, which is lined internally with refractory and / or insulating materials, and a cathode assembly located at the bottom of the tank.
- Anodes typically of carbonaceous material, are partially immersed in the electrolyte bath.
- an electrolysis plant requires interventions on the electrolysis cells including, in particular, the replacement of spent anodes with new anodes, the removal of liquid metal and the additions or withdrawals of electrolyte.
- the factories are generally equipped with one or more service units comprising a movable bridge that can be translated over and along the series of electrolysis cells, and one or more service modules. , each comprising a carriage, adapted to be moved on the movable bridge, and handling and intervention devices, such as shovels and hoists, commonly called “tools”.
- the service module generally comprises, attached to the carriage, a rotary frame, called tool turret, which is adapted to rotate about a vertical axis and is integral with said tools.
- Each tool can be attached to the end of a cable operated by a winch attached to said turret, or at the end of an arm, the latter being telescopic and / or articulated.
- One of the necessary interventions during the anode replacement is the cleaning of the area occupied by the spent anode and to be occupied by the new anode.
- This zone is essentially constituted by the bath and the liquid metal but can contain many solid debris that it is necessary to remove before setting up the new anode.
- a hard crust of fluorinated cryolite and alumina is formed on the upper surface of the bath. This crust has the advantage of retaining heat within the bath and therefore constitutes an effective heat-insulating envelope. But it is extremely hard and adheres to the wall of the anode block, so it is necessary to break it around the worn anode, to allow the extraction thereof.
- rupturing of the crust is carried out using tools such as piercers, called “crust breakers". Then, during the removal of the spent anode, an orifice in the crust is formed, which orifice is left vacant until the installation of the new anode and which we will call “anodic hole”. Crust failure and handling of the spent anodic block inevitably lead to the formation of solid pieces or parts which float or remain suspended in the electrolysis bath, or which fall to the bottom of the tank. It is then necessary to collect them by means of a collection tool, commonly called “crust”.
- the European patent application EP-A-0 440 488 describes an example of a crust scoop associated with a particular vehicle, distinct from a service machine.
- the European patent application EP-A-0 618 313 describes, but in a little detail, an example of a service machine equipped with a device to ensure the rupture of the crust in the vicinity of a worn anode and the cleaning of the anode hole.
- the crust scoop commonly used is a clamp consisting of two buckets arranged symmetrically with respect to a substantially vertical plane and hinged, pivoting about two substantially horizontal axes, possibly merged. Each bucket has an edge drive, also called "blade", vis-à-vis the leading edge of the other bucket.
- the crust scoop is immersed in the open position in the bath and then the crust scoop is passed from an open position to a closed position, using at least one actuator that acts either directly on a scoop. , or preferably on a linkage designed to bring the cups in a rotational movement substantially symmetrical with respect to each other, the solid debris between the two cups being thus trapped, while the liquid medium mixture of Electrolyte bath and molten metal can still escape, in particular through openings in the walls of the buckets.
- the opening and closing movement of the crustal scoop is driven by the actuation of a pneumatic cylinder which acts on a linkage designed to transform the translation movement of the cylinder in two symmetrical rotation movements of the buckets.
- German patent application DE3131624 proposes a mechanism making it possible to give the end of the blades of the shells of a crust scoop a substantially horizontal overall trajectory during their closing, preventing the blades from scraping the ground.
- the European patent application EP-A-1 178 004 proposes a solution likely to solve the problem explained in the preceding paragraph.
- This solution consists of using a bucket scoop mounted on a vertical arm but not to directly attach the frame secured to the axes of the buckets on said vertical arm.
- the chassis is split into a part called “excavator frame”, which remains attached to the arm attached to the turret and a part called “bucket support frame”, vertically movable relative to the door frame so that, since the instantaneous center of rotation of the buckets can move while the arm remains stationary relative to the bottom of the tank, the leading edges of the buckets can be given a substantially rectilinear trajectory.
- the shovel can be placed so that its leading edges are flush with the bottom of the tank during the entire operation of closing the shovel.
- a complex bucket closure assembly comprising "a transmission rod of forces, one of whose ends is articulatedtinct on the bucketstinct and whose other end is articulated on a rotating actuating rod, itself hinged to the support frame of the buckets, said rotating rod being mechanically connected to the excavator frame by means of a connecting rod compensation means articulated on the excavator frame, said rotary rod being moreover actuated in rotation by means of an actuating cylinder, whose point of application is integral with the support frame of the buckets ".
- Such a solution requires the introduction into the crust with numerous intermediate pieces intended to operate in a hostile environment and to undergo vibrations of high amplitude, in particular because of the stresses associated with the breakdown of the buckets. This involves frequent replacement of these parts subject to rapid wear.
- Said first actuator comprises at least one hydraulic jack which makes it possible to vertically move said vertical mast to which the remainder of the collection unit is attached.
- the manipulator arm of the collection unit is telescopic, so that the rod of said hydraulic cylinder is integral with said vertical mast and the body of said hydraulic cylinder also moves vertically, actuated by an actuator integral with a movable frame which moves in a horizontal plane, for example which is fixed on a carriage able to follow the beam of a traveling crane.
- said collection unit can be moved rapidly and positioned above the working area and then down at the anode hole to perform the collection operation.
- a "symmetrical” solution consisting of making the mobile vertical mast integral with the body of the jack and the rod integral with the movable frame, is also possible.
- it acts on the chamber that is active during the rise of the load.
- the rise of the collection unit is done by imposing a pressure in the chamber side rod, room that we will call later also "chamber-rod” is on the hydraulic circuit feeding said chamber side rod that is introduced a pressure regulator.
- the lifting actuator imposes on the lifting actuator a mode of operation, called compensation, which consists in maintaining the pressure in the chamber on the rod side to a value that allows to hold, at least during the collection of debris, almost the entire weight of said lifting unit.
- compensation consists in maintaining the pressure in the chamber on the rod side to a value that allows to hold, at least during the collection of debris, almost the entire weight of said lifting unit.
- This is in a state close to the hydraulic suspension, with an "apparent weight” limited to said predetermined value, preferably less than 1000 daN, typically between 200 and 600 daN.
- the risks of shocks are substantially related to the substantially vertical movements of the collection unit when it is close to the bottom of the tank, the significant reduction in its apparent weight makes it possible to limit the intensity of the force generated by contacting the leading edge of the bucket against the bottom of the tank when the bucket pivots to collect debris.
- the first actuator may include a plurality of hydraulic cylinders. It is understood that, in this case, all the rod-side chambers can be fed with the same circuit and that they must be subjected, at least when the second actuator is activated, to a substantially constant pressure allowing the assembly said jacks support a load corresponding to the weight of said collection unit, reduced by a predetermined value of effort, preferably less than 1000 daN, typically between 200 and 600 daN.
- Such a device makes it possible in particular to collect debris by scraping the bottom of the tank, that is to say leaving the leading edge of the bucket to move on the bottom of the tank while remaining continuously in contact with the latter: the collection unit, in quasi-hydraulic suspension, can almost freely move up or down depending on the opening of the bucket.
- the support force much lower than the unit's own weight collection, must however have a certain positive value, preferably limited to 1000 daN, typically between 200 and 600 daN, to prevent said collection unit is too easy to go back, in case of difficulty to lift some debris.
- said first actuator also comprises a piston-side chamber that can be powered by the hydraulic circuit: it is a double-acting cylinder.
- the collection of debris is carried out more easily than the collection unit comprises a frame and two buckets mounted on said frame, arranged symmetrically with respect to a substantially vertical plane and articulated, pivoting about two substantially horizontal axes. , possibly confused, each bucket having a leading edge vis-à-vis the leading edge of the other bucket.
- the second actuator integral with said frame, imposes on each of said buckets a substantially symmetrical rotational movement relative to said substantially vertical plane, so that the solid debris between the two buckets are trapped by said buckets. With such a device, the debris can be collected by scraping the bottom of the tank without damaging it.
- the hydraulic circuit supplying the hydraulic cylinder acting as a first actuator comprises, at least at the moment when the second actuator is actuated, a pressure regulator, also called a pressure compensator.
- the pressure regulator is a device designed in such a way that it lets oil flow from the circuit to the reservoir when the pressure in the circuit reaches a certain critical upper value, and that it provides a supply of oil from of the hydraulic power plant when the pressure in the circuit reaches a certain critical lower value.
- Another object according to the invention is a service module intended to be used in an igneous electrolysis aluminum production plant comprising a trolley and handling and intervention devices, characterized in that it also comprises a collection unit according to the invention, as described above.
- Another object according to the invention is a service unit of an igneous electrolysis aluminum production plant comprising a traveling crane and characterized in that it also comprises at least one service module according to the invention, such as previously described.
- Another object according to the invention is the use of a service module according to the invention for the interventions on electrolytic cells intended for the production of aluminum by igneous electrolysis, in particular for the cleaning of the anode holes.
- the figure 1 schematically illustrates a service machine in a typical electrolysis room for the production of aluminum, seen in section.
- the figure 2 illustrates a particular embodiment of a collection unit, which is a crust scoop, mounted on a telescopic vertical guide mast.
- the figure 3 illustrates in perspective, the linkage and bucket bucket of the embodiment of the figure 2 .
- FIGs 4 to 7 illustrate, in four different configurations, the diagram of a hydraulic circuit feeding the first actuator (lifting jack) of a collection unit according to the invention. These configurations correspond to the following operating modes: figure 4 ), fast descent ( figure 5 ), compensation (phase corresponding to scraping) ( figure 6 ) and climb ( figure 7 ).
- Electrolysis plants for aluminum production include a liquid aluminum production area that includes one or more electrolysis rooms.
- the electrolysis room (1) illustrated on the figure 1 comprises electrolysis cells (2) and a service machine (5).
- the electrolysis cells (2) are normally arranged in rows or rows, each row or line typically having more than one hundred cells.
- the cells (2) are arranged so as to clear a circulation aisle along the electrolysis room (1).
- the cells (2) comprise a series of anodes (3) provided with a metal rod (4) for fixing and electrically connecting the anodes to a metal anode frame (not shown).
- the service unit (5) is used to carry out operations on the cells (2) such as the anode changes or the filling of the ground bath supply hoppers and aluminum fluoride (AlF3). It can also be used to handle various loads, such as tank elements, pockets of liquid metal that are used during casting (“ladles”) or anodes. It can also be used to clean the anode hole after removing a worn anode and before installing a new anode.
- AlF3 aluminum fluoride
- the service unit (5) comprises a movable bridge (6) which can be translated over the electrolysis cells (2), and at least one service module (7) comprising a movable carriage (8), said "Tool holder”, adapted to be moved on the movable bridge (6) and equipped with several handling and intervention devices (10), such as tools, among which may be the crust scoop (100 ').
- the tools are here mounted on vertical telescopic poles (9) attached to the movable carriage (8).
- a crust scoop may also be moved and operated from a vehicle other than a service machine.
- the invention applies to any collection unit, regardless of its mode of movement and placement above the work area.
- the figures 2 and 3 illustrate a particular embodiment of a collection unit (100), which is a crust scoop (100 ') attached to the end of a telescopic arm, at the end of the movable arm here called “shovel barrel” ( 11).
- the shovel drum is a movable vertical mast (9 ") sliding in a vertical mast (9 '), which also moves vertically, actuated by an actuator (not shown) integral with the tool turret of the movable carriage (8) of a service module (7)
- the crustal scoop comprises a frame (110) provided with two buckets (120a and 120b) placed facing each other, substantially symmetrically with respect to a substantially vertical plane and articulated pivoting about two substantially horizontal axes (115a and 115b).
- Each bucket (120a, 120b) has a leading edge (128a, 128b) facing the leading edge (128b, 128a) of the another bucket (120b, 120a)
- the second actuator is here in the form of two cylinders (200, 201) integral with the frame (110), operating simultaneously, by imposing on each bucket a substantially symmetrical rotation movement relative to in a substantially vertical plane, so that solid debris located between the two buckets are trapped by said buckets.
- FIGS 4 to 7 illustrate, in four different configurations, the diagram of a hydraulic circuit supplying the first actuator (50) of a collection unit according to the invention, which moreover possesses the characteristics described above ( figures 2 and 3 ).
- the first actuator, or lift cylinder, (50) is a double acting cylinder (51) with a body (55) and a piston (56) associated with a rod (52).
- the rod (52) is integral with the collection unit (not shown on the Figures 4 to 7 ).
- the double-acting cylinder (51) has a stem-like chamber (53), called the lower one, capable of imposing at any moment on the vertical mobile mast (9 ") a vertical upward movement and a piston-like chamber (54), said upper , capable of imposing a vertical downward movement on the vertical mobile mast at any moment,
- the hydraulic circuit comprises two portions (63) and (64) which feed the two chambers (53) and (54) of the double-acting cylinder (51).
- the circuit can be connected via a three-position distributor, which we will call later "direction distributor” (80), to the "pressure line” (P) and to the “return line” (R) d.
- the directional distributor (80) is naturally in the position (802) which corresponds to the rest and can be excited to be put into one of the other two possible positions: the position (803) where the rod ( 52) of the jack moves the collection unit down a differential speed and the position (801) where the stem of u cylinder raises said collection unit.
- the first circuit portion (64) includes a main branch (640) having one end connected to the directional distributor (80) and the other end branching into two branches, the first branch (641) being connected to the chamber - piston (54) of the cylinder (51), the second leg (642) being connected to the return port (73) of the pressure regulator (70).
- the second circuit portion (63) comprises a main branch (630), one end of which is connected to the direction distributor (80) and whose other end branches into two sub-branches, each of which is equipped with a distributor.
- the two sub-branches meet at their other ends to constitute the end portion (633), which feeds the shaft side chamber (53) of the cylinder (51).
- the nonreturned check valve (90) serves two functions: a load holding function (the collection unit) and a safety function, by limiting the pressure inside the the chamber-stem in case of shock. These two functions could be fulfilled by other separate devices, for example a clapper dispenser, used as a load-retaining means, associated with a pressure limiter providing safety.
- the figure 4 illustrates the circuit when the lift cylinder is at rest.
- the direction distributor (80) is naturally in the position (802), which puts the two circuit portions (63) and (64) in connection with each other through their respective main branches (630) and (640).
- the distributor (82) is in the position (821) which blocks the circulation in the second sub-branch and makes the pressure regulator (70) inoperative. Isolated by the distributor (82) in position (821) and by the non-conducting valve (90) (the piloting pressures of the connections (92) and (93) are insufficient to make it flow), the The stem chamber (53) is maintained, apart from any shock, at a substantially constant pressure, associated with the weight of the collection unit.
- the circuit branch (633) is equipped with a safety device, integrated into the function of the check valve (90), to limit the pressure in the stem chamber in the event of an impact.
- the figure 5 illustrates the circuit when the lift cylinder is in rapid descent.
- the direction distributor (80) is energized to occupy the position (803), which places the two circuit portions (63) and (64) in communication with the pressure line (P) of the hydraulic power unit, the two circuit portions (63) and (64) also communicating with each other via their respective main branches (630) and (640) at the direction distributor (80) when in this position (803).
- the dispenser (82) is in the position (821) which makes the pressure regulator (70) inoperative.
- the distributor (81) is in the position (812) and allows the operation of the check valve (90): as soon as the resultant of the forces due to the piloting pressures coming from the one side of the branch (92) (" external control ") and on the other hand the branch (93) (via the valve (91) -" internal control ") is greater than a certain value, the check valve (90) becomes" pass ".
- the check valve (90) is set to a critical value, typically close to 180 bar, so that, as soon as its piloting has sufficient pressure, it becomes free-running and the oil can flow from the stem-chamber ( 53) to the plunger chamber (54), via the branches (630) and (640), which communicate with each other at the direction distributor (80), placed in position (803). In this way, the flow of oil from the hydraulic unit is increased by the flow of oil from the piston chamber. If the x is the ratio (section of the piston chamber (54)) / (section of the shank (52)), the flow from the hydraulic unit is multiplied by x, so that with such a differential arrangement, the piston rod can descend with a speed x times faster than with a conventional assembly.
- the figure 6 illustrates the circuit when the lifting cylinder is in a so-called compensation mode, activated during the collection of debris by scraping the bottom of the tank.
- the direction distributor (80) is energized to occupy the position (801), which places the main branch (630) in connection with the pressure line (P) of the hydraulic power unit and the main branch (640) in connection with the reservoir from the hydraulic power plant, via the return line (R).
- the distributor (82) is in the position (822) and the distributor (81) is in the position (811), which makes the pressure regulator (70) operational: if the pressure inside the chamber -tige (53) is greater than a given value, typically chosen to around 58 bar, the oil flows from the rod-chamber (53) to the piston chamber (54). If, on the other hand, the pressure inside the rod-chamber (53) is lower than this given value, the oil coming from the hydraulic power unit supplies said rod-chamber.
- the pressure in the shaft-side chamber (53) increases because the jack has to bear a load corresponding to the weight of the tank unit. collection, greater than the predetermined load.
- the pilot of the pressure regulator compares the force provided by the setting spring (71) with the force due to the pressure prevailing in the branch (72) which is connected to the stem-side chamber (53) via the part ( 632 ') of the second sub-branch, the distributor (82) in position (822) and the end portion (633).
- the controller communicates, via the output (73), the portion (632 ') of the second sub-branch with the branch (642) of the first circuit portion (64) , so that the regulator is rendered "passing" between the chamber-rod (53) and the tank of the hydraulic unit, via the return line (R). In this way, the pressure in the rod chamber decreases and the apparent weight of the collection unit re-increases.
- the pressure in the stem-side chamber (53) is lower than the predetermined load.
- the pilot of the pressure regulator which compares the force provided by the setting spring (71) with the force due to the pressure prevailing in the branch (72) which communicates with the stem-side chamber (53), then sets communicating, via the output (74), the portion (632 ') of the second sub-branch with the other portion (632) of the second sub-branch, so that the regulator is "switched" between the rod (53) and the pressure line (P) of the hydraulic power unit. In this way, the pressure in the rod chamber (53) increases and the apparent weight of the collection unit decreases.
- the figure 7 illustrates the circuit when the lift cylinder raises the rod (52).
- the direction distributor (80) is energized to occupy the position (801), which places the main branch (630) in connection with the pressure line (P) of the hydraulic power unit and the main branch (640) in communication with the reservoir from the hydraulic power plant, via the return line (R).
- the distributor (82) is in the position (821) and the distributor (81) is in the position (812), which makes the pressure regulator (70) inoperative.
- the pressurized oil passes through the main branch (630), passes through the distributor (81) in position (812) and joins the portions (631 ") and (633) via the non-return valve (91), to supply the stem chamber (53) As the piston rises, the oil in the piston chamber (54) is discharged to the return line (R) of the hydraulic unit via the main branch (640). ).
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Description
L'invention concerne la production d'aluminium par électrolyse ignée selon le procédé de Hall-Héroult. Elle concerne plus particulièrement un dispositif destiné à collecter les débris solides en immersion ou flottant dans le bain d'électrolyse et le métal liquide, notamment les boues provenant du bain électrolytique et qui s'accumulent sur le fond de cuve, ainsi que les restes de carbone et les débris de croûte qui proviennent en particulier des diverses opérations effectuées avant et pendant l'enlèvement des anodes usées.The invention relates to the production of aluminum by igneous electrolysis according to the Hall-Héroult method. It relates more particularly to a device for collecting solid debris immersed or floating in the electrolysis bath and the liquid metal, in particular sludge from the electrolytic bath and which accumulate on the bottom of the tank, as well as the remains of carbon and crust debris that originate in particular from the various operations performed before and during the removal of spent anodes.
L'aluminium est produit industriellement par électrolyse ignée, selon le procédé bien connu de Hall-Héroult, dans des cellules d'électrolyse. Les usines contiennent un grand nombre de cellules d'électrolyse disposées en ligne, dans des bâtiments appelés halls ou salles d'électrolyse, et raccordées électriquement en série à l'aide de conducteurs de liaison, de façon à optimiser l'occupation au sol des usines. Les cellules sont généralement disposées de manière à former deux ou plusieurs files parallèles qui sont électriquement liées entre elles par des conducteurs d'extrémité. Dans chaque cellule, le bain d'électrolyte et le métal liquide sont contenus dans une cuve, dite « cuve d'électrolyse », comprenant un caisson en acier, qui est revêtu intérieurement de matériaux réfractaires et/ou isolants, et un ensemble cathodique situé au fond de la cuve. Des anodes, typiquement en matériau carboné, sont partiellement immergées dans le bain d'électrolyte.Aluminum is produced industrially by igneous electrolysis, according to the well-known Hall-Héroult process, in electrolysis cells. The plants contain a large number of electrolysis cells arranged in line, in buildings called halls or electrolysis rooms, and connected electrically in series using connecting conductors, so as to optimize the ground occupation of the cells. factories. The cells are generally arranged to form two or more parallel lines that are electrically bonded together by end conductors. In each cell, the electrolyte bath and the liquid metal are contained in a tank, called an "electrolysis cell", comprising a steel box, which is lined internally with refractory and / or insulating materials, and a cathode assembly located at the bottom of the tank. Anodes, typically of carbonaceous material, are partially immersed in the electrolyte bath.
En fonctionnement, une usine d'électrolyse nécessite des interventions sur les cellules d'électrolyse parmi lesquelles figurent, notamment, le remplacement des anodes usées par des anodes neuves, le prélèvement de métal liquide et les ajouts ou prélèvements d'électrolyte. Afin d'effectuer ces interventions, les usines sont en général équipées d'une ou plusieurs unités de service comprenant un pont mobile qui peut être translaté au-dessus et le long des séries des cellules d'électrolyse, et un ou plusieurs modules de service, chacun comprenant un chariot, apte à être déplacé sur le pont mobile, et des organes de manutention et d'intervention, tels que des pelles et des palans, appelés communément "outils". Ces unités de service sont souvent appelées "machines de service électrolyse" ou "M.S.E" ("PTA" ou "Pot Tending Assembly" ou "PTM" ou "Pot Tending Machine" en langue anglaise). Le module de service comprend en général, attaché au chariot, un châssis rotatif, appelé tourelle porte-outils, qui est apte à tourner autour d'un axe vertical et est solidaire desdits outils. Chaque outil peut être fixé au bout d'un câble manoeuvré par un treuil attaché à ladite tourelle, ou encore au bout d'un bras, ce dernier pouvant être télescopique et/ou articulé.In operation, an electrolysis plant requires interventions on the electrolysis cells including, in particular, the replacement of spent anodes with new anodes, the removal of liquid metal and the additions or withdrawals of electrolyte. In order to carry out these interventions, the factories are generally equipped with one or more service units comprising a movable bridge that can be translated over and along the series of electrolysis cells, and one or more service modules. , each comprising a carriage, adapted to be moved on the movable bridge, and handling and intervention devices, such as shovels and hoists, commonly called "tools". These service units are often referred to as "electrolysis service machines" or "MSE"("PTA" or "Pot Tending Assembly" or "PTM" or "Pot Tending Machine" in English). The service module generally comprises, attached to the carriage, a rotary frame, called tool turret, which is adapted to rotate about a vertical axis and is integral with said tools. Each tool can be attached to the end of a cable operated by a winch attached to said turret, or at the end of an arm, the latter being telescopic and / or articulated.
L'une des interventions nécessaires au cours du remplacement des anodes est le nettoyage de la zone qui était occupée par l'anode usée et qui doit être occupée par la nouvelle anode. Cette zone est essentiellement constituée par le bain et le métal liquide mais peut contenir de nombreux débris solides qu'il est nécessaire d'enlever avant de mettre en place la nouvelle anode. Au cours de l'électrolyse, il se forme à la surface supérieure du bain une croûte dure de cryolithe fluorée et d'alumine. Cette croûte présente l'avantage de conserver la chaleur au sein du bain et constitue donc une enveloppe calorifuge efficace. Mais elle est extrêmement dure et adhère à la paroi du bloc anodique, de sorte qu'il s'avère nécessaire de la rompre autour de l'anode usée, afin de permettre l'extraction de celle-ci. Typiquement, la rupture de la croûte est réalisée à l'aide d'outils tels que des piqueurs, appelés "piqueurs brise-croûte". Il se forme alors, lors de l'enlèvement de l'anode usée, un orifice dans la croûte, orifice qui est laissé vacant jusqu'à l'installation de la nouvelle anode et que nous appellerons par la suite "trou anodique". La rupture de la croûte et les manipulations du bloc anodique usé engendrent inévitablement la formation de morceaux ou parties solides qui surnagent ou restent en suspension dans le bain d'électrolyse, ou encore qui tombent au fond de la cuve. Il est alors nécessaire de les prélever au moyen d'un outil de collecte, appelé communément "pelle à croûte".One of the necessary interventions during the anode replacement is the cleaning of the area occupied by the spent anode and to be occupied by the new anode. This zone is essentially constituted by the bath and the liquid metal but can contain many solid debris that it is necessary to remove before setting up the new anode. During the electrolysis, a hard crust of fluorinated cryolite and alumina is formed on the upper surface of the bath. This crust has the advantage of retaining heat within the bath and therefore constitutes an effective heat-insulating envelope. But it is extremely hard and adheres to the wall of the anode block, so it is necessary to break it around the worn anode, to allow the extraction thereof. Typically, rupturing of the crust is carried out using tools such as piercers, called "crust breakers". Then, during the removal of the spent anode, an orifice in the crust is formed, which orifice is left vacant until the installation of the new anode and which we will call "anodic hole". Crust failure and handling of the spent anodic block inevitably lead to the formation of solid pieces or parts which float or remain suspended in the electrolysis bath, or which fall to the bottom of the tank. It is then necessary to collect them by means of a collection tool, commonly called "crust".
La demande de brevet européen
Traditionnellement, le mouvement d'ouverture et de fermeture de la pelle à croûte est animé par l'actionnement d'un vérin pneumatique qui agit sur un embiellage conçu pour transformer le mouvement de translation du vérin en deux mouvements de rotation symétriques des godets. Avant de placer la nouvelle anode dans la cellule, il faut s'assurer que l'ensemble des débris de croûte et de carbone qui se trouvent dans le trou anodique a été enlevé. Comme certains d'entre eux peuvent reposer sur le fond de la cuve, il est nécessaire de plonger la pelle à croûte dans le milieu liquide constitué par le bain et le métal de sorte que ses bords d'attaque affleurent le fond de la cuve. Mais comme les bords d'attaque des godets décrivent des trajectoires circulaires lorsque la pelle à croûte se ferme pour ramasser les débris, la manoeuvre de la pelle est très délicate, car l'ensemble cathodique qui constitue le fond de la cuve risque de subir un endommagement important lors de cette opération. Pour éviter une telle détérioration, il faudrait imposer à l'axe ou aux axes de pivotement des godets une position en altitude telle que les bords d'attaque des godets ne touchent jamais le fond de la cuve pendant la manoeuvre, tout en étant les plus proches possible de ce fond de façon à ce que le nettoyage soit efficace. Toutefois, cette position est difficile à évaluer car il n'y a pas d'accès visuel au fond de cuve. D'autre part, cette position théorique rend, en raison du décrit circulaire des lames, la pelle à croûte peu efficace dans les phases où celles-ci sont les plus éloignées du fond de cuve, une partie des débris reposant sur le fond de cuve risquant de ne pas être collectée.Traditionally, the opening and closing movement of the crustal scoop is driven by the actuation of a pneumatic cylinder which acts on a linkage designed to transform the translation movement of the cylinder in two symmetrical rotation movements of the buckets. Before placing the new anode in the cell, ensure that all crust and carbon debris in the anode hole has been removed. As some of them can rest on the bottom of the tank, it is necessary to plunge the scoop in the liquid medium consisting of the bath and the metal so that its leading edges are flush with the bottom of the tank. But as the leading edges of the buckets describe circular trajectories when the crust shovel closes to pick up the debris, the maneuvering of the shovel is very delicate, because the cathodic assembly which constitutes the bottom of the tank risks to undergo a significant damage during this operation. To avoid such deterioration, it would be necessary to impose on the axis or pivot axes of the buckets a position in altitude such that the leading edges of the buckets never touch the bottom of the tank during the maneuver, while being the most possible close to this bottom so that the cleaning is effective. However, this position is difficult to evaluate because there is no visual access to the bottom of the tank. On the other hand, this theoretical position makes, because of the circular circular blades, the crust scoop inefficient in the phases where they are furthest from the bottom of the tank, a part of the debris resting on the bottom of the tank risk of not being collected.
La demande de brevet allemande
Ainsi, cette opération de nettoyage du trou d'anode à l'aide de la pelle à croûte se heurte à deux difficultés antagonistes: soit on est trop près du fond de cuve et, dans ce cas, on risque de le détériorer, soit on en est trop éloigné et le nettoyage est insuffisant. Quelle que soit la façon de procéder, il subsiste un risque non négligeable d'instabilité générale d'ordre électrique et magnétique dans le fonctionnement de la cuve, conduisant à une baisse de rendement de l'installation.Thus, this cleaning operation of the anode hole using the crust shovel encounters two antagonistic difficulties: either it is too close to the bottom of the tank and, in this case, there is a risk of damaging it, or is too far away and cleaning is insufficient. What whatever the procedure, there remains a significant risk of general instability of electrical and magnetic order in the operation of the tank, leading to a decline in efficiency of the installation.
La demande de brevet européen
Le but que s'est fixé la demanderesse a été de réaliser, sans risque d'endommagement du fond de cuve, un nettoyage efficace du trou d'anode lors du remplacement des anodes, tout en faisant appel à un outil simple, peu coûteux , facile à nettoyer, à entretenir et à maintenir.
Un premier objet selon l'invention est une unité de collecte destinée à collecter les débris solides et les boues se trouvant dans les milieux liquides d'une cellule de production d'aluminium, tels que le bain d'électrolyse et le métal liquide, en particulier destinée au nettoyage des trous anodiques, comprenant:
- a) un mât vertical actionné par un premier actionneur, appelé également actionneur de levage, qui permet de déplacer ledit mât vertical suivant la direction verticale;
- b) un châssis fixé sur ledit mât vertical;
- c) au moins un godet articulé, pivotant autour d'un axe sensiblement horizontal, monté sur ledit châssis, présentant un bord d'attaque sensiblement horizontal et actionné par un deuxième actionneur, appelé également actionneur de fermeture, solidaire dudit châssis, imposant audit godet un mouvement de rotation autour dudit axe sensiblement horizontal,
A first object according to the invention is a collection unit intended to collect solid debris and sludge present in the liquid media of an aluminum production cell, such as the electrolysis bath and the liquid metal, in particular for cleaning anode holes, comprising:
- a) a vertical mast actuated by a first actuator, also called lifting actuator, for moving said vertical mast in the vertical direction;
- b) a frame fixed on said vertical mast;
- c) at least one articulated bucket, pivoting about a substantially horizontal axis, mounted on said frame, having a substantially horizontal leading edge and actuated by a second actuator, also called closing actuator, secured to said frame, imposing said bucket a rotational movement about said substantially horizontal axis,
Ledit premier actionneur comprend au moins un vérin hydraulique qui permet de déplacer verticalement ledit mât vertical auquel est attaché le reste de l'unité de collecte. De préférence, le bras manipulateur de l'unité de collecte est télescopique, de sorte que la tige dudit vérin hydraulique est solidaire dudit mât vertical et le corps dudit vérin hydraulique se déplace également verticalement, actionné par un actionneur solidaire d'un châssis mobile qui se déplace dans un plan horizontal, par exemple qui est fixé sur un chariot capable de longer la poutre d'un pont roulant. De la sorte, ladite unité de collecte peut être déplacée rapidement et positionnée au-dessus de la zone de travail puis être descendue au niveau du trou anodique pour effectuer l'opération de collecte.Said first actuator comprises at least one hydraulic jack which makes it possible to vertically move said vertical mast to which the remainder of the collection unit is attached. Preferably, the manipulator arm of the collection unit is telescopic, so that the rod of said hydraulic cylinder is integral with said vertical mast and the body of said hydraulic cylinder also moves vertically, actuated by an actuator integral with a movable frame which moves in a horizontal plane, for example which is fixed on a carriage able to follow the beam of a traveling crane. In this way, said collection unit can be moved rapidly and positioned above the working area and then down at the anode hole to perform the collection operation.
Bien évidemment, une solution "symétrique", consistant à rendre le mât vertical mobile solidaire du corps du vérin et la tige solidaire du châssis mobile, est également possible. Selon l'invention, on agit sur la chambre qui est active lors de la montée de la charge. Comme dans les deux cas la montée de l'unité de collecte se fait en imposant une pression dans la chambre côté tige, chambre que nous appellerons par la suite également "chambre-tige", c'est sur le circuit hydraulique alimentant ladite chambre côté tige que l'on introduit un régulateur de pression.Of course, a "symmetrical" solution, consisting of making the mobile vertical mast integral with the body of the jack and the rod integral with the movable frame, is also possible. According to the invention, it acts on the chamber that is active during the rise of the load. As in both cases the rise of the collection unit is done by imposing a pressure in the chamber side rod, room that we will call later also "chamber-rod" is on the hydraulic circuit feeding said chamber side rod that is introduced a pressure regulator.
Selon l'invention, on impose à l'actionneur de levage un régime de fonctionnement, dit de compensation, qui consiste à maintenir la pression dans la chambre côté tige à une valeur qui permet de tenir, au moins lors de la collecte des débris, la quasi-totalité du poids de ladite unité de levage. Celle-ci se trouve dans un état proche de la suspension hydraulique, avec un "poids apparent" limité à ladite valeur prédéterminée, de préférence inférieure à 1000 daN, typiquement comprise entre 200 et 600 daN. Comme les risques de chocs sont substantiellement liés aux mouvements sensiblement verticaux de l'unité de collecte au moment où elle se trouve à proximité du fond de cuve, la nette diminution de son poids apparent permet de limiter l'intensité de l'effort engendré par le contact du bord d'attaque du godet contre le fond de cuve lorsque le godet pivote pour collecter des débris.According to the invention, it imposes on the lifting actuator a mode of operation, called compensation, which consists in maintaining the pressure in the chamber on the rod side to a value that allows to hold, at least during the collection of debris, almost the entire weight of said lifting unit. This is in a state close to the hydraulic suspension, with an "apparent weight" limited to said predetermined value, preferably less than 1000 daN, typically between 200 and 600 daN. As the risks of shocks are substantially related to the substantially vertical movements of the collection unit when it is close to the bottom of the tank, the significant reduction in its apparent weight makes it possible to limit the intensity of the force generated by contacting the leading edge of the bucket against the bottom of the tank when the bucket pivots to collect debris.
Ledit premier actionneur peut comprendre plusieurs vérins hydrauliques. Il est entendu que, dans ce cas, l'ensemble des chambres côté tige peuvent être alimentées avec le même circuit et qu'elles doivent être soumises, au moins lorsque le deuxième actionneur est activé, à une pression sensiblement constante permettant à l'ensemble desdits vérins de supporter une charge correspondant au poids de ladite unité de collecte, diminué d'un effort de valeur prédéterminée, de préférence inférieure à 1000 daN, typiquement comprise entre 200 et 600 daN.The first actuator may include a plurality of hydraulic cylinders. It is understood that, in this case, all the rod-side chambers can be fed with the same circuit and that they must be subjected, at least when the second actuator is activated, to a substantially constant pressure allowing the assembly said jacks support a load corresponding to the weight of said collection unit, reduced by a predetermined value of effort, preferably less than 1000 daN, typically between 200 and 600 daN.
Un tel dispositif permet en particulier d'effectuer une collecte des débris en raclant le fond de cuve, c'est-à-dire en laissant le bord d'attaque du godet se déplacer sur le fond de cuve tout en restant continuellement en contact avec ce dernier: l'unité de collecte, en quasi-suspension hydraulique, peut quasi-librement monter ou descendre en fonction de l'ouverture du godet. La force d'appui, nettement plus faible que le poids propre de l'unité de collecte, doit cependant avoir une certaine valeur positive, de préférence limitée à 1000 daN, typiquement comprise entre 200 et 600 daN, pour éviter que ladite unité de collecte ne remonte trop facilement, en cas de difficulté à soulever certains débris.Such a device makes it possible in particular to collect debris by scraping the bottom of the tank, that is to say leaving the leading edge of the bucket to move on the bottom of the tank while remaining continuously in contact with the latter: the collection unit, in quasi-hydraulic suspension, can almost freely move up or down depending on the opening of the bucket. The support force, much lower than the unit's own weight collection, must however have a certain positive value, preferably limited to 1000 daN, typically between 200 and 600 daN, to prevent said collection unit is too easy to go back, in case of difficulty to lift some debris.
Avantageusement, pour assurer avec le même dispositif l'ensemble des fonctions de descente et de montée, ledit premier actionneur comprend également une chambre côté piston qui peut être alimentée par le circuit hydraulique: c'est un vérin double effet.Advantageously, to ensure with the same device all of the descent and rise functions, said first actuator also comprises a piston-side chamber that can be powered by the hydraulic circuit: it is a double-acting cylinder.
Bien évidemment, la collecte des débris est effectuée d'autant plus aisément que l'unité de collecte comprend un châssis et deux godets montés sur ledit châssis, disposés symétriquement par rapport à un plan sensiblement vertical et articulés, pivotant autour de deux axes sensiblement horizontaux, éventuellement confondus, chaque godet présentant un bord d'attaque en vis-à-vis du bord d'attaque de l'autre godet. De préférence, le deuxième actionneur, solidaire dudit châssis, impose à chacun desdits godets un mouvement de rotation sensiblement symétrique par rapport audit plan sensiblement vertical, de façon à ce que les débris solides situés entre les deux godets se trouvent piégés par lesdits godets. Avec un tel dispositif, on peut collecter les débris en raclant le fond de cuve sans endommager celui-ci.Of course, the collection of debris is carried out more easily than the collection unit comprises a frame and two buckets mounted on said frame, arranged symmetrically with respect to a substantially vertical plane and articulated, pivoting about two substantially horizontal axes. , possibly confused, each bucket having a leading edge vis-à-vis the leading edge of the other bucket. Preferably, the second actuator, integral with said frame, imposes on each of said buckets a substantially symmetrical rotational movement relative to said substantially vertical plane, so that the solid debris between the two buckets are trapped by said buckets. With such a device, the debris can be collected by scraping the bottom of the tank without damaging it.
Selon l'invention, le circuit hydraulique alimentant le vérin hydraulique faisant office de premier actionneur comprend, au moins au moment où le second actionneur est actionné, un régulateur de pression, appelé également compensateur de pression. Le régulateur de pression est un dispositif conçu de telle sorte qu'il laisse s'écouler de l'huile du circuit vers le réservoir lorsque la pression dans le circuit atteint une certaine valeur supérieure critique, et qu'il assure une alimentation en huile provenant de la centrale hydraulique lorsque la pression dans le circuit atteint une certaine valeur inférieure critique.According to the invention, the hydraulic circuit supplying the hydraulic cylinder acting as a first actuator comprises, at least at the moment when the second actuator is actuated, a pressure regulator, also called a pressure compensator. The pressure regulator is a device designed in such a way that it lets oil flow from the circuit to the reservoir when the pressure in the circuit reaches a certain critical upper value, and that it provides a supply of oil from of the hydraulic power plant when the pressure in the circuit reaches a certain critical lower value.
Avantageusement, le premier actionneur qui permet de déplacer le mât vertical est un vérin double effet dont la tige est solidaire de ladite unité de collecte, avec une chambre côté tige, dite inférieure, apte à imposer à tout moment au dit mât vertical un mouvement vertical vers le haut et une chambre côté piston, dite supérieure, apte à imposer à tout moment au dit mât vertical un mouvement vertical vers le bas. Avantageusement, les deux chambres peuvent être connectées, par l'intermédiaire d'un distributeur, à la "ligne pression" ou à la "ligne retour" d'une centrale hydraulique, le circuit d'alimentation comprenant plusieurs portions de circuits qui permettent de réaliser les schémas d'alimentation hydraulique suivants:
- a) un schéma différentiel, où la chambre côté tige et la chambre côté piston sont connectées à la la ligne pression de la centrale hydraulique, permettant d'assurer la descente à grande vitesse du mât;
- b) un schéma correspondant au repos, l'unité de collecte restant suspendue: le circuit est aménagé de telle sorte que ladite unité de collecte reste soumise à des efforts limités en cas de rencontre d'obstacle lors de ses déplacements verticaux vers le haut ou vers le bas;
- c) un schéma, où la chambre côté tige est connectée à la ligne pression de la centrale hydraulique, correspondant à la montée de l'unité de collecte;
- d) un schéma "en compensation", correspondant à la phase de raclage de l'unité de collecte sur le fond de cuve, où la pression dans la portion de circuit alimentant la chambre côté tige est régulée pour être maintenue aux environs d'une valeur correspondant au poids de ladite unité de collecte, diminué d'un effort de valeur prédéterminée, de préférence inférieure à 1000 daN, typiquement comprise
entre 200 daN et 600 daN.
- a) a differential diagram, in which the rod-side chamber and the piston-side chamber are connected to the pressure line of the hydraulic power unit, making it possible to ensure the high-speed descent of the mast;
- b) a diagram corresponding to the rest, the collection unit remaining suspended: the circuit is arranged such that said collection unit remains subject to limited efforts in case of obstacle encounter during its upward vertical movements or down;
- c) a diagram, where the rod side chamber is connected to the pressure line of the hydraulic unit, corresponding to the rise of the collection unit;
- d) a "compensation" pattern, corresponding to the scraping phase of the collection unit on the bottom of the tank, where the pressure in the circuit portion feeding the rod-side chamber is regulated to be maintained around a value corresponding to the weight of said collection unit, reduced by a predetermined value of effort, preferably less than 1000 daN, typically between 200 daN and 600 daN.
Dans l'exemple présenté ci-après, nous décrivons plus en détail ces différentes phases de fonctionnement de l'unité de collecte.In the example presented below, we describe in more detail these different operating phases of the collection unit.
Un autre objet selon l'invention est un module de service destiné à être utilisé dans une usine de production d'aluminium par électrolyse ignée et comprenant un chariot et des organes de manutention et d'intervention, caractérisé en ce qu'il comprend en outre une unité de collecte selon l'invention, telle que décrite précédemment.Another object according to the invention is a service module intended to be used in an igneous electrolysis aluminum production plant comprising a trolley and handling and intervention devices, characterized in that it also comprises a collection unit according to the invention, as described above.
Un autre objet selon l'invention est une unité de service d'une usine de production d'aluminium par électrolyse ignée comprenant un pont roulant et caractérisée en ce qu'elle comprend également au moins un module de service selon l'invention, tel que décrit précédemment.Another object according to the invention is a service unit of an igneous electrolysis aluminum production plant comprising a traveling crane and characterized in that it also comprises at least one service module according to the invention, such as previously described.
Un autre objet selon l'invention est l'utilisation d'un module de service selon l'invention pour les interventions sur des cellules d'électrolyse destinées à la production d'aluminium par électrolyse ignée, en particulier pour le nettoyage des trous anodiques.Another object according to the invention is the use of a service module according to the invention for the interventions on electrolytic cells intended for the production of aluminum by igneous electrolysis, in particular for the cleaning of the anode holes.
La
La
La
Les
Les usines d'électrolyse destinées à la production d'aluminium comprennent une zone de production d'aluminium liquide qui comprend une ou plusieurs salles d'électrolyse. La salle d'électrolyse (1) illustrée sur la
L'unité de service (5) sert à effectuer des opérations sur les cellules (2) telles que les changements d'anodes ou le remplissage des trémies d'alimentation en bain broyé et en fluorure d'aluminium (AlF3). Elle peut également servir à manutentionner des charges diverses, telles que des éléments de cuve, des poches de métal liquide qui sont employées lors des coulées ("poches de coulée") ou encore des anodes. Elle peut également être utilisée pour nettoyer le trou d'anode, après l'enlèvement d'une anode usée et avant la mise en place d'une anode neuve.The service unit (5) is used to carry out operations on the cells (2) such as the anode changes or the filling of the ground bath supply hoppers and aluminum fluoride (AlF3). It can also be used to handle various loads, such as tank elements, pockets of liquid metal that are used during casting ("ladles") or anodes. It can also be used to clean the anode hole after removing a worn anode and before installing a new anode.
L'unité de service (5) comprend un pont mobile (6) qui peut être translaté au-dessus des cellules d'électrolyse (2), et au moins un module de service (7) comprenant un chariot mobile (8), dit "porte-outils", apte à être déplacé sur le pont mobile (6) et équipé de plusieurs organes de manutention et d'intervention (10), tels que des outils, parmi lesquelles peut figurer la pelle à croûte (100'). Les outils sont ici montés sur des mâts télescopiques verticaux (9) attachés au chariot mobile (8). Comme nous l'avons déjà vu, par exemple dans la demande de brevet européen
Les
Les
Le premier actionneur, ou vérin de levage, (50) est un vérin double effet (51) avec un corps (55) et un piston (56) associé à une tige (52). La tige (52) est solidaire de l'unité de collecte (non représentée sur les
La première portion de circuit (64) comprend une branche principale (640) dont une extrémité est connectée au distributeur de sens (80) et dont l'autre extrémité se ramifie en deux branches, la première branche (641) étant connectée à la chambre - piston (54) du vérin (51), la seconde branche (642) étant connectée à l'orifice retour (73) du régulateur de pression (70).The first circuit portion (64) includes a main branch (640) having one end connected to the directional distributor (80) and the other end branching into two branches, the first branch (641) being connected to the chamber - piston (54) of the cylinder (51), the second leg (642) being connected to the return port (73) of the pressure regulator (70).
La deuxième portion de circuit (63) comprend une branche principale (630) dont une extrémité est connectée au distributeur de sens (80) et dont l'autre extrémité se ramifie en deux sous-branches, dont chacune est équipée d'un distributeur à deux positions (81, 82), la première sous-branche (631, 631', 631") étant associée à une valve de retenue (90), la seconde sous-branche (632, 632', 632") étant associée au dispositif régulateur de pression (70). Les deux sous-branches se rejoignent en leurs autres extrémités pour constituer la portion d'extrémité (633), qui alimente la chambre côté tige (53) du vérin (51). La valve de retenue (90), lorsqu'elle n'est pas passante, remplit deux fonctions: une fonction de maintien de la charge (l'unité de collecte) et une fonction de sécurité, en limitant la pression à l'intérieur de la chambre-tige en cas de choc. Ces deux fonctions pourraient être remplies par d'autres dispositifs séparés, par exemple un distributeur à clappet, utilisé en tant que moyen de retenue de charge, associé à un limiteur de pression assurant la sécurité.The second circuit portion (63) comprises a main branch (630), one end of which is connected to the direction distributor (80) and whose other end branches into two sub-branches, each of which is equipped with a distributor. two positions (81, 82), the first sub-branch (631, 631 ', 631 ") being associated with a holding valve (90), the second sub-branch (632, 632', 632") being associated with the pressure regulating device (70). The two sub-branches meet at their other ends to constitute the end portion (633), which feeds the shaft side chamber (53) of the cylinder (51). The nonreturned check valve (90) serves two functions: a load holding function (the collection unit) and a safety function, by limiting the pressure inside the the chamber-stem in case of shock. These two functions could be fulfilled by other separate devices, for example a clapper dispenser, used as a load-retaining means, associated with a pressure limiter providing safety.
La
La
La valve de retenue (90) est réglée à une valeur critique, typiquement voisine de 180 bars, de sorte que, dès que ses pilotages disposent des pressions suffisantes, elle devient passante et l'huile peut s'écouler de la chambre-tige (53) vers la chambre-piston (54), via les branches (630) et (640), qui communiquent entre elles au niveau du distributeur de sens (80), placé en position (803). De la sorte, le débit d'huile provenant de la centrale hydraulique se trouve augmenté du débit d'huile provenant de la chambre-piston. Si le x est le rapport (section de la chambre-piston (54)) / (section de la tige (52)), le débit provenant de la centrale hydraulique est multiplié par x, de sorte qu'avec un tel montage différentiel, la tige de piston peut descendre avec une vitesse x fois plus rapide qu'avec un montage classique.The check valve (90) is set to a critical value, typically close to 180 bar, so that, as soon as its piloting has sufficient pressure, it becomes free-running and the oil can flow from the stem-chamber ( 53) to the plunger chamber (54), via the branches (630) and (640), which communicate with each other at the direction distributor (80), placed in position (803). In this way, the flow of oil from the hydraulic unit is increased by the flow of oil from the piston chamber. If the x is the ratio (section of the piston chamber (54)) / (section of the shank (52)), the flow from the hydraulic unit is multiplied by x, so that with such a differential arrangement, the piston rod can descend with a speed x times faster than with a conventional assembly.
La
Si l'unité de collecte, au cours du raclage, n'est plus en contact avec le fond de cuve, la pression dans la chambre côté tige (53) augmente car le vérin doit supporter une charge correspondant au poids de l'unité de collecte, supérieure à la charge prédéterminée. Le pilote du régulateur de pression compare l'effort fourni par le ressort de tarage (71) avec l'effort dû à la pression qui règne dans la branche (72) qui est connectée à la chambre côté tige (53) via la partie (632') de la deuxième sous-branche, le distributeur (82) en position (822) et la portion d'extrémité (633). Si l'effort de tarage est plus faible, le régulateur met en communication, via la sortie (73), la partie (632') de la deuxième sous-branche avec la branche (642) de la première portion de circuit (64), de sorte que le régulateur est rendu "passant" entre la chambre-tige (53) et le réservoir de la centrale hydraulique, via la ligne retour (R). De la sorte, la pression dans la chambre tige diminue et le poids apparent de l'unité de collecte ré-augmente.If the collection unit, during scraping, is no longer in contact with the bottom of the tank, the pressure in the shaft-side chamber (53) increases because the jack has to bear a load corresponding to the weight of the tank unit. collection, greater than the predetermined load. The pilot of the pressure regulator compares the force provided by the setting spring (71) with the force due to the pressure prevailing in the branch (72) which is connected to the stem-side chamber (53) via the part ( 632 ') of the second sub-branch, the distributor (82) in position (822) and the end portion (633). If the tare force is lower, the controller communicates, via the output (73), the portion (632 ') of the second sub-branch with the branch (642) of the first circuit portion (64) , so that the regulator is rendered "passing" between the chamber-rod (53) and the tank of the hydraulic unit, via the return line (R). In this way, the pressure in the rod chamber decreases and the apparent weight of the collection unit re-increases.
Inversement, si l'unité de collecte, au cours du raclage, appuie trop sur le fond de cuve, la pression dans la chambre côté tige (53) est inférieure à la charge prédéterminée. Le pilote du régulateur de pression, qui compare l'effort fourni par le ressort de tarage (71) avec l'effort dû à la pression régnant dans la branche (72) qui communique avec la chambre côté tige (53), met alors en communication, via la sortie (74), la partie (632') de la deuxième sous-branche avec l'autre partie (632) de la deuxième sous-branche, de sorte que le régulateur est rendu "passant" entre la chambre-tige (53) et la ligne pression (P) de la centrale hydraulique. De la sorte, la pression dans la chambre tige (53) augmente et le poids apparent de l'unité de collecte diminue.Conversely, if the collection unit, during scraping, is pressing too much on the bottom of the tank, the pressure in the stem-side chamber (53) is lower than the predetermined load. The pilot of the pressure regulator, which compares the force provided by the setting spring (71) with the force due to the pressure prevailing in the branch (72) which communicates with the stem-side chamber (53), then sets communicating, via the output (74), the portion (632 ') of the second sub-branch with the other portion (632) of the second sub-branch, so that the regulator is "switched" between the rod (53) and the pressure line (P) of the hydraulic power unit. In this way, the pressure in the rod chamber (53) increases and the apparent weight of the collection unit decreases.
La
Claims (11)
- A collection unit (100) designed to collect the solid debris and mud in the liquid media of a cell for producing aluminum, such as the electrolytic bath and the molten metal, in particular a crust shovel (100') designed for deaning anode holes, comprising:a) a vertical mast (9") actuated by a first actuator (50), used to move said vertical mast in the vertical direction;b) a frame (110) fixed onto said vertical mast;c) at least one articulated bucket (120a, 120b), swiveling around a substantially horizontal axis (115a, 115b), fitted to said frame, with a substantially horizontal leading edge (128a, 128b) actuated by a second actuator (200, 201), interdependent with said frame, causing said bucket to adopt a rotary movement around saièi substantially horizontal axis,characterized in that said first actuator (50) is composed of at least one hydraulic jack (51) which indudes a body (55), a piston (56) together with a rod (52) and a chamber on the rod sicle (53), and which is powered by a hydraulic system arranged so that, at least when the second actuator is activated, oil pressure in the chamber on the rod side (53) is maintained at a substantially constant value allowing said jack to support a load corresponding to the weight of said collection unit, less a Joad of predetermined value, preferably lower than 1000 daN, and typically ranging between 200 and 600 daN.
- Collection unit (100, 100') according to daim 1 characterized in that the portion of circuit (63) which feeds said chamber on the rod sicle is provided with a pressure regulator (70) which makes it possible to maintain the pressure within said chamber on the rod sicle in the vicinity of said substantially constant value.
- Collection unit (100, 100') according to daim 1 or 2 characterized in that said rad (52) of said hydraulic actuating cylinder (51) is interdependent with said vertical mast (9").
- Collection unit (100, 100') according to any of daims 1 to 3 characterized in that said first actuator is a double-acting jack.
- Coll_ection unit (100, 100') according to any of daims 1 to 4, characterized in that it includes a frame (110) and two buckets (120a, 120b) fitted said frame, laid out symmetrically in relation to a substantially vertical plane and articulated, swiveling around two substantially horizontal axes (115a, 115b), each bucket having a leading edge (128a, 128b) opposite the leading edge of the other bucket.
- Collection unit (100, 100') according to daim 5, in which the second actuator, interdependent with said frame, causes each of said buckets to make a substantially symmetrical rotation movement in relation to the substantially vertical plane, so that the solid debris located between the two buckets is trapped by said buckets.
- Collection unit (100, 100') according to any of daims 1 to 6, in which said first actuator is a double-acting jack whose two chambers may be connccted, via a distributor (80), to the pressure line (P) or the return line (R) of a hydraulic unit, the feeding circuit including several portions of circuits which make it possible to provide the following hydraulic supply configurations:a) a differential configuration, in which both chambers are connected to the hydraulic unit, allowing the mast to descend at high speed;b) a configuration corresponding to the rest position;c) a configuration in which the chamber on the rod sicle is connected to the hydraulic unit, corresponding to the upward movement of the collection unit;d) a "compensation" configuration, corresponding to the phase when the collection unit scrapes the bottom f the pot, in which the pressure in the portion of circuit feeding the chamber on the rod sicle is controlled so as to be maintained around a value corresponding to the weight of said collection unit, less a Joad of predetênnined value, preferably lower than 1000 daN, and typically ranging between 200 daN and 600 daN.
- Collection unit (100, 100') according to daim 7, in which said hydraulic system includes two portions (63) and (64) which feed the chamber on the rod side (53) and the chamber on the piston sicle (54) of the double-acting jack,a) the first portion of circuit (64) indudes a main branch (640) one end of which is connected to said distributor (80) and whose other end splits into two branches, the first branch (641) being oMected to the piston-chamber (54) of jack (51), the second branch (642) being used to feed the pressure regulator (70);b) the second portion of circuit (63) including a main branch (630) one end of whichis connected to the direction distributor (80) and whose other end splits into two sub-branches, cach of which is provided with a two-position distributor (81, 82), the fust sub-branch (631, 631', 631") being associated with a load-retaining means, typically a poppet valve or a shut-off valve (90), the second sub-branch (632, 632', 632") being associated with a pressure regulating device (70), the two sub-branches meeting at their other ends to make up the end portion (633), which feeds the rod -chamber (53) of said jack (51).
- Service module (J) designed to be used in a plant for the production of aluminum by igneous electrolysis and comprising a carriage (8) and handling and servicing devices (10), characterized in that it also includes a collection unit (100) according to any of daims 1 to 8.
- Pot Tending Assembly (5) for a plant producing aluminum by igneous electrolysis including an overhead travelling crane (6) characterized in that it includes also at least one service module (7) according to daim 9.
- Use of a service module (7) according to daim 9 for servicing work on electrolytic cells (2) designed for the production of aluminum by igneous electrolysis, in particular for cleaning the anode holes.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0902252A FR2945296B1 (en) | 2009-05-11 | 2009-05-11 | DEVICE FOR COLLECTING THE SOLID DEBRIS PRESENT IN THE BATH AND LIQUID METAL OF AN ELECTROLYSIS TANK INTENDED FOR THE PRODUCTION OF ALUMINUM BY SCRAPPING THE BOTTOM OF THE SAME |
PCT/FR2010/000360 WO2010130892A1 (en) | 2009-05-11 | 2010-05-10 | Device for collecting the solid debris present in the bath and the liquid metal of an electrolysis cell intended for aluminium production, by scraping the bottom of said cell |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2430215A1 EP2430215A1 (en) | 2012-03-21 |
EP2430215B1 true EP2430215B1 (en) | 2019-08-21 |
Family
ID=41137236
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10727005.0A Active EP2430215B1 (en) | 2009-05-11 | 2010-05-10 | Device for collecting the solid debris present in the bath and the liquid metal of an electrolysis cell intended for aluminium production, by scraping the bottom of said cell |
Country Status (8)
Country | Link |
---|---|
US (1) | US20120047668A1 (en) |
EP (1) | EP2430215B1 (en) |
CN (1) | CN102421943B (en) |
AU (1) | AU2010247248B2 (en) |
CA (1) | CA2761504A1 (en) |
FR (1) | FR2945296B1 (en) |
RU (1) | RU2522411C2 (en) |
WO (1) | WO2010130892A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL2014296B1 (en) * | 2015-02-13 | 2016-10-13 | Hendricus Liet Cornelis | Device for loosening feed. |
CN105626618B (en) * | 2016-04-06 | 2018-04-24 | 青海桥头铝电股份有限公司 | A kind of Multifunctional crown block hydraulic system to prolong the service life |
US11047111B2 (en) * | 2018-08-21 | 2021-06-29 | Deere & Company | Work vehicle with constant velocity implement actuation |
PE20212012A1 (en) * | 2018-10-05 | 2021-10-18 | New Tech Copper S P A | SELF-SUPPORTING STRUCTURE SYSTEM ASSEMBLY BY PIECES AND ADAPTABLE TO THE SPACE FOR THE ELECTRO-OBTAINING OF METALS, BOTH IN A CELL ALREADY OPERATING OR IN A TANK, (SELE NG); ASSEMBLY METHOD; AND SLUDGE EXTRACTION METHOD |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3131624A1 (en) * | 1980-09-02 | 1982-06-16 | VEB Schwermaschinenbaukombinat TAKRAF-Stammbetrieb-Betrieb für Anlagenbau und Rationalisierung, DDR 7010 Leipzig | Grab with controllable movement pattern of the cutting edges of grab shells |
IT1221994B (en) * | 1987-07-09 | 1990-08-31 | Techmo Car Spa | EQUIPMENT FOR THE MECHANIZED CHANGE OF THE ANODES IN THE ELECTROLYTIC CELLS FOR THE PRODUCTION OF ALUMINUM |
NO176283C (en) * | 1990-02-02 | 1995-03-08 | Hydeq As | Kjöretöy mainly designed for cleansing of crust and charcoal residues from electrolytic cells |
IT1263968B (en) * | 1993-02-25 | 1996-09-05 | Gianfranco Zannini | AUTOMATED EQUIPMENT FOR THE CHANGE OF THE ELECTROLYTIC CELL ANODES FOR THE PRODUCTION OF ALUMINUM |
CN2269402Y (en) * | 1996-02-17 | 1997-12-03 | 抚顺铝厂科学研究所 | Flue ash, waste materials and adsorptive pitch aluminium oxide boiling baking device for aluminium electrolysis |
SI1178004T1 (en) * | 2000-08-04 | 2006-08-31 | Reel | Collecting, cleaning and calibrating unit for aluminium production electrolytic cells |
FR2872175B1 (en) * | 2004-06-25 | 2006-07-28 | Ecl Soc Par Actions Simplifiee | COMPACT SERVICE MODULE FOR ALUMINUM PRODUCTION FACILITIES BY ELECTROLYSIS |
CN2758325Y (en) * | 2004-11-12 | 2006-02-15 | 中国铝业股份有限公司 | Special material suction device for electrolytic bath |
-
2009
- 2009-05-11 FR FR0902252A patent/FR2945296B1/en not_active Expired - Fee Related
-
2010
- 2010-05-10 EP EP10727005.0A patent/EP2430215B1/en active Active
- 2010-05-10 CA CA2761504A patent/CA2761504A1/en not_active Abandoned
- 2010-05-10 RU RU2011150237/02A patent/RU2522411C2/en not_active IP Right Cessation
- 2010-05-10 WO PCT/FR2010/000360 patent/WO2010130892A1/en active Application Filing
- 2010-05-10 AU AU2010247248A patent/AU2010247248B2/en not_active Ceased
- 2010-05-10 US US13/319,470 patent/US20120047668A1/en not_active Abandoned
- 2010-05-10 CN CN201080020749.2A patent/CN102421943B/en active Active
Non-Patent Citations (1)
Title |
---|
None * |
Also Published As
Publication number | Publication date |
---|---|
CA2761504A1 (en) | 2010-11-18 |
EP2430215A1 (en) | 2012-03-21 |
WO2010130892A1 (en) | 2010-11-18 |
US20120047668A1 (en) | 2012-03-01 |
FR2945296B1 (en) | 2011-04-29 |
FR2945296A1 (en) | 2010-11-12 |
CN102421943A (en) | 2012-04-18 |
RU2011150237A (en) | 2013-06-20 |
AU2010247248A1 (en) | 2011-11-24 |
CN102421943B (en) | 2014-06-04 |
RU2522411C2 (en) | 2014-07-10 |
AU2010247248B2 (en) | 2013-11-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2737927C (en) | Service machine used for intervention on electrolysis cells for producing aluminium by igneous electrolysis | |
EP2430215B1 (en) | Device for collecting the solid debris present in the bath and the liquid metal of an electrolysis cell intended for aluminium production, by scraping the bottom of said cell | |
EP1740740B1 (en) | Compact service module which is intended for electrolytic aluminium production plants | |
CA2591495C (en) | Handling device for hoods of a cell for electrolytic aluminium production | |
EP2510136B1 (en) | Device intended for collecting solid debris in an electrolytic cell intended for the production of aluminium | |
CA2807888A1 (en) | Handling tool, for secure handling of connectors of electrolysis cells intended for aluminium production | |
EP2373567B1 (en) | Device for attaching containers for collecting solid debris and pivoting at the end of a mobile arm, in particular a device for attaching hinged buckets of a scale scoop | |
EP2761061B1 (en) | Compact service module and use thereof in a plant for producing aluminum by electrolysis | |
EP3114257B1 (en) | System for carrying out operations linked to the use of cells of a facility for producing aluminium by means of electrolysis | |
EP1178004B1 (en) | Collecting, cleaning and calibrating unit for aluminium production electrolytic cells | |
WO2012001242A1 (en) | Device for removing short-circuiting blocks when bringing on-line an electrolysis cell for the productin of aluminium | |
OA16284A (en) | Device for extracting short-circuiting shims when switching on an electrolysis cell for aluminum production. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20111201 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR |
|
DAX | Request for extension of the european patent (deleted) | ||
17Q | First examination report despatched |
Effective date: 20140731 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: C25C 3/06 20060101AFI20190326BHEP Ipc: B66C 3/02 20060101ALI20190326BHEP Ipc: B08B 9/08 20060101ALI20190326BHEP Ipc: B66C 3/16 20060101ALI20190326BHEP |
|
INTG | Intention to grant announced |
Effective date: 20190417 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: FIVES ECL |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602010060648 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1169858 Country of ref document: AT Kind code of ref document: T Effective date: 20190915 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: NV Representative=s name: VALIPAT S.A. C/O BOVARD SA NEUCHATEL, CH |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: FP |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191223 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191121 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191121 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191221 Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191122 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 1169858 Country of ref document: AT Kind code of ref document: T Effective date: 20190821 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200224 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602010060648 Country of ref document: DE |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG2D | Information on lapse in contracting state deleted |
Ref country code: IS |
|
26N | No opposition filed |
Effective date: 20200603 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20200531 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200510 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200510 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200531 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20230420 Year of fee payment: 14 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20240418 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20240419 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20240418 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20240602 Year of fee payment: 15 |