EP2291505B1 - Solid fabric care composition with a polysaccharide - Google Patents

Solid fabric care composition with a polysaccharide Download PDF

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Publication number
EP2291505B1
EP2291505B1 EP09772336A EP09772336A EP2291505B1 EP 2291505 B1 EP2291505 B1 EP 2291505B1 EP 09772336 A EP09772336 A EP 09772336A EP 09772336 A EP09772336 A EP 09772336A EP 2291505 B1 EP2291505 B1 EP 2291505B1
Authority
EP
European Patent Office
Prior art keywords
fabric care
care composition
cellulose
solid
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP09772336A
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German (de)
French (fr)
Other versions
EP2291505A1 (en
Inventor
Noelle Wrubbel
Karl-Heinz Scheffler
Daniel Tigges
Rene-Andres Artiga Gonzalez
Matthias Sunder
Mario Sturm
Tobias Segler
Konstanze Mayer
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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Publication date
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Priority claimed from DE102008031212A external-priority patent/DE102008031212A1/en
Priority claimed from DE200810047233 external-priority patent/DE102008047233A1/en
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to PL09772336T priority Critical patent/PL2291505T3/en
Publication of EP2291505A1 publication Critical patent/EP2291505A1/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C11D3/502—Protected perfumes
    • C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/26—Organic compounds, e.g. vitamins containing oxygen
    • C11D9/262—Organic compounds, e.g. vitamins containing oxygen containing carbohydrates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile

Definitions

  • the invention relates to a solid, textile-care composition and its use and preparation. Furthermore, the invention relates to a washing or cleaning agent containing the solid, textile care composition.
  • cationic fabric softening compounds include, for example, methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium compounds or N, N-dimethyl-N, N-di (tallowacyloxyethyl) ammonium compounds.
  • the WO 2007/113326 A1 discloses a solid fabric treatment composition containing a water-soluble carrier of an alkali metal, alkaline earth metal and / or ammonium compound, a water-soluble polymer, a fabric-care compound and a perfume.
  • It is therefore an object of the present invention to provide a solid textile treatment agent comprising a water-soluble carrier having a coating of a water-soluble polymer, a perfume and a fabric-care compound, which does not or significantly less aggregates in the production and / or storage or clumps forms.
  • a solid, textile-care composition comprising a water-soluble carrier, a water-soluble polymer, a fabric-care compound, a polysaccharide and a perfume, wherein the water-soluble carrier is in particulate form and at least partially an enclosure of the water-soluble Polymer and the perfume and a mixture of the fabric-care compound and the polysaccharide is at least partially present in and / or at least partially on the enclosure.
  • the coating comprises a mixture of the textile care agent and a polysaccharide. Neither in production nor during storage did such coated textile-care compositions show tendencies to clump or agglomerate. In addition, such wrapped textile treatment agent particles are more flowable. Furthermore, it has been shown that the freshly prepared textile treatment agent particles can be filled at higher final product temperatures, resulting in shorter production times.
  • textile treatment agent particles whose coating comprises a mixture of the textile-care compound and a polysaccharide retain their crystalline appearance for a longer time.
  • the solid, textile-care composition can be used in the wash cycle of a laundry cleaning process and so the textile-care compound and the perfume are already transported directly to the laundry at the beginning of the washing process and so can develop their full potential. Furthermore, this solid composition is easier and better to handle than liquid compositions, since no drops remain on the edge of the bottle, which lead to subsequent storage of the bottle to edges on the ground or to unsightly deposits in the region of the closure. The same applies in the event that some of the composition is accidentally spilled during dosing. The spilled composition can also be removed easier and cleaner.
  • the water-soluble carrier is selected from the group consisting of inorganic alkali metal salts, organic alkali metal salts, inorganic alkaline earth metal salts, organic alkaline earth metal salts, organic acids, carbohydrates, silicates, urea and mixtures thereof.
  • These materials are not only inexpensive, but dissolve very well in water. In addition, these materials are odorless or odorless.
  • the solid textile care composition contains 50 to 99% by weight, preferably 75 to 95% by weight, of the water-soluble carrier.
  • the fabric care composition is composed of fabric softening compounds, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, crease inhibitors, color transfer inhibitors, antimicrobials, germicides, fungicides, antioxidants, antistatic agents, ironing aids , Phobic and impregnating agents, swelling and anti-slip agents, UV absorbers and mixtures thereof.
  • the fabric care compound is a fabric softening compound. It is most preferred that the fabric softening compound is selected from polysiloxanes, fabric softening clays, cationic polymers and mixtures thereof.
  • Such a fabric conditioner can be used in the main wash of an automatic washing or cleaning process.
  • the textile-care composition can be added, for example, together with the detergent or cleaning agent in the drum or the dispenser of a washing machine. This has the advantage that no additional rinse is necessary and no unsightly deposits occur in the dispenser
  • polysiloxanes and / or cationic polymers as a fabric care compound in the fabric care composition is advantageous because they not only have a softening effect but also enhance the perfume impression on the laundry.
  • softening clays as textile-care compound in the textile-care composition is advantageous because they additionally have a water-softening effect and thus lime deposits are prevented on the laundry.
  • a fabric care composition may contain a combination of at least two fabric care compounds.
  • the water-soluble polymer is selected from polyalkylene glycols, polyvinyl alcohols and mixtures thereof. These water-soluble polymers function as binders.
  • the water-soluble carrier prefferably has particle sizes in the range from 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm.
  • Textile-care compositions with particle sizes in the range from 0.8 to 7 mm and particularly preferably in the range from 1 to 3 mm can be metered particularly well and in a targeted manner.
  • the polysaccharide is selected from the group comprising glycogen, starch, chitin, callose, cellulose, dextran, tunicin, inulin, alginic acid, xanthan, gellan, guar, locust bean gum, carrageenan, derivatives of these compounds or mixtures of these compounds and their derivatives.
  • the mixture as polysaccharide is cellulose or a cellulose derivative selected from the group comprising methylcellulose, ethylcellulose, propylcellulose, methylethylcellulose, carboxymethylcellulose, ethylcarboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylhydroxyethylcellulose, methylhydroxyethylcellulose hydroxypropylmethylcellulose, ethylhydroxyethylcellulose, methylethylhydroxyethylcellulose, quaternized cellulose, quaternized cellulose derivatives, Amine-modified cellulose, amine-modified cellulose derivatives or mixtures of these compounds.
  • Cellulose and its derivatives are particularly effective in preventing sticking of the particles of the textile treatment agent. It has also been found that in particular cellulose or its derivatives increase the color stability of colored, solid textile-care compositions.
  • the fabric care composition may contain additional ingredients, preferably selected from the group consisting of dyes, fillers, pearlescers, skin care compounds, bittering agents, and mixtures thereof.
  • the fabric care composition contains from 0.1% to 15%, preferably from 1% to 10%, and most preferably from 2% to 7%, by weight of perfume.
  • the mixture of the textile-care compound and the polysaccharide is at least partially incorporated into the sheath.
  • the advantages described above are particularly pronounced.
  • the sheath or sheath and non-coated portions of the water-soluble carrier are at least partially coated with a mixture of the fabric care compound and the polysaccharide.
  • the invention also relates to the use of a solid textile-care composition according to the invention for conditioning textile fabrics.
  • the invention relates to a process for producing a solid textile-care composition
  • a process for producing a solid textile-care composition comprising a particulate water-soluble carrier, a water-soluble polymer, a fabric-care compound, a polysaccharide and a perfume in which the water-soluble polymer is melted in the molten state is mixed with the perfume, the resulting melt is added to the particulate carrier in such a way that it is at least partially enveloped and then incorporated into the still molten envelope a mixture of the fabric-care compound and the polysaccharide.
  • the invention also relates to a process for producing a solid textile-care composition
  • a process for producing a solid textile-care composition comprising a particulate water-soluble carrier, a water-soluble polymer, a fabric-care compound, a polysaccharide and a perfume in which the water-soluble polymer is melted in the molten state the perfume is added, the resulting melt is added to the particulate carrier in such a way that it is at least partially enveloped and the at least partially coated particulate carrier is coated with a mixture of the fabric-care compound and the polysaccharide.
  • the invention relates to a washing or cleaning agent comprising a solid, textile-care composition according to the invention.
  • the consumer By introducing the textile-care composition according to the invention into a washing or cleaning agent, the consumer is provided with a textile-care washing or cleaning agent ("2in1" washing or cleaning agent) and does not need to dose two agents.
  • a textile-softening composition is introduced into a washing or cleaning agent, the consumer is then provided with a fabric-softening washing or cleaning agent ("2in1" washing or cleaning agent) and does not need two detergents or cleaners Fabric softener) and no separate rinse.
  • the washing or cleaning agent and the textile-care composition are not necessary to perfume the washing or cleaning agent and the textile-care composition, but only one of the two agents, preferably the textile-care composition. Not only does this result in lower costs, it is also beneficial for consumers with sensitive skin and / or allergies.
  • the solid textile care composition contains as essential ingredients a water-soluble carrier, a water-soluble polymer, a fabric-care compound, a polysaccharide and a perfume.
  • An essential component of the fabric care composition is the water-soluble carrier.
  • This preferably includes inorganic alkali metal salts such as sodium chloride, potassium chloride, sodium sulfate, sodium carbonate, potassium sulfate, potassium carbonate, sodium bicarbonate, potassium bicarbonate or mixtures thereof, organic alkali metal salts such as sodium acetate, potassium acetate, sodium citrate, sodium tartrate or potassium sodium tartrate, inorganic alkaline earth metal salts such as calcium chloride, magnesium sulfate or magnesium chloride, organic alkaline earth metal salts such as calcium lactate, carbohydrates, organic acids such as citric acid or tartaric acid, silicates such as water glass, sodium silicate or potassium silicate, urea and mixtures thereof.
  • inorganic alkali metal salts such as sodium chloride, potassium chloride, sodium sulfate, sodium carbonate, potassium sulfate, potassium carbonate, sodium bicarbonate, potassium bicarbonate or mixtures thereof
  • organic alkali metal salts such
  • the water-soluble carrier may comprise a carbohydrate selected, for example, from the group consisting of dextrose, fructose, galactose, isoglucose, glucose, sucrose, raffinose, isomalt, xylitol, and mixtures thereof.
  • the carbohydrate used may be, for example, candy or hail sugar.
  • Citric acid as a carrier has the advantage that the textile-care composition at the same time has a builder for lowering the water hardness.
  • the water-soluble carrier may also contain mixtures of said materials.
  • the water-soluble carrier is particulate and has particle sizes in the range of 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm.
  • a textile care compound is understood to mean any compound which gives textile fabrics treated therewith a beneficial effect, such as, for example, a textile softening effect, crease resistance or the harmful or negative effects which result during cleaning and / or conditioning and / or or wearing, such as fading, graying, etc., reduced.
  • the fabric care composition may include, for example, a fabric softening compound, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, wrinkle inhibitors, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, antistatic agents, ironing aids, phobizers and the like Impregnating, swelling and slipping agents, UV absorbers and mixtures thereof. Concrete examples of these fabric-care compounds can be found in the description of the washing or cleaning agent of the invention and can also be used in the solid, textile-care composition.
  • the fabric conditioning compound is preferably a fabric softening compound and is, for example, a polysiloxane, a fabric softening clay, a cationic polymer, or a blend of at least two of these fabric care compounds. Accordingly, the fabric care composition is preferably a fabric softening composition.
  • Polydimethylpolysiloxanes are known as efficient fabric care compounds.
  • Suitable polydimethysiloxanes include DC-200 (ex Dow Corning), Baysilone® M 50, Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 or Baysilone® M 5000 (all ex GE Bayer Silicones).
  • the polysiloxane contains the structural units a) and b).
  • a particularly preferred polysiloxane has the following structure: (CH 3 ) 3 Si [O-Si (CH 3 ) 2 ] n - [O-Si (CH 3 ) ⁇ (CH 2 ) 3 -NH- (CH 2 ) 2 -NH 2 ⁇ ] x -OSi ( CH 3 ) 3 where the sum n + x is a number between 2 and 10,000.
  • Suitable polysiloxanes having the structural units a) and b) are for example commercially available under the trade names DC2-8663, DC2-8035, DC2-8203, DC05-7022 or DC2-8566 (all ex Dow Corning). According to the invention are also suitable for example the products commercially available Dow Corning ® 7224, Dow Corning ® 929 Cationic Emulsion or Formasil 410 (GE Silicones).
  • a suitable fabric softening clay is, for example, a smectite clay.
  • Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontronite clays, saponite clays, sauconite clays, and mixtures thereof.
  • Montmorillonite clays are the preferred softening clays.
  • Bentonites contain mainly montmorillonites and can serve as a preferred source of fabric softening clay. The bentonites can be used as powder or crystals.
  • Suitable bentonites are sold, for example, under the names Laundrosil® by Süd-Chemie or under the name Detercal by Laviosa. It is preferable that the textile-care composition contains a powdery bentonite as a fabric-care compound.
  • the fabric care composition contains a fabric softening compound and one or more other fabric care compounds.
  • the amount of fabric care compound in the fabric care composition is 0.1 to 15 weight percent and preferably between 2 and 12 weight percent.
  • Suitable water-soluble polymers preferably have a melting or softening point in the range of 48 ° C to 300 ° C and may include polyalkylene glycols, especially polyethylene glycols, and / or polyvinyl alcohols. Most preferably, the water-soluble polymers have a melting or softening point in the range of 48 ° C to 120 ° C.
  • melting point is meant the transition from a solid state to a liquid (free flowing) state.
  • the softening temperature describes the transition from a solid state to a rubbery to viscous melt.
  • the melting and softening temperatures may each be either a certain temperature or a smaller range within the range of 48 ° C to 300 ° C.
  • Suitable polyalkylene glycols include in particular polyethylene glycols, which are liquid or solid polymers depending on the chain length. From a molecular weight of 3000, the polyethylene glycols are solid substances and are sold as flakes or powders. Hardness and melting range increase with increasing molecular weight. Preferred for the present invention are polyethylene glycols having an average molecular weight between 3,000 and 12,000, more preferably having an average molecular weight between 4,000 and 10,000, and most preferably having an average molecular weight between 6,000 and 8,000.
  • Polyvinyl alcohols are commercially available as white-yellowish powders or granules with degrees of polymerization in the range of about 500-2500 (molar masses of about 20,000 - 100,000 g / mol).
  • the degree of hydrolysis is 98-99 or 87-89 mol% and thus the polyvinyl alcohols still contain a residual content of acetyl groups.
  • the polyvinyl alcohols are characterized by the manufacturer by indicating the degree of polymerization of the starting polymer, the degree of hydrolysis and / or the saponification number.
  • Fully saponified polyvinyl alcohols have a softening temperature of 85 ° C and a melting point of 228 ° C.
  • the corresponding values for partially hydrolyzed (87-89%) products are significantly lower at approx. 58 ° C (softening point) or 186 ° C (melting point).
  • the water-soluble polymer may also contain a mixture of said materials.
  • the textile care composition comprises a polyalkylene glycol and in particular a polyethylene glycol as the water-soluble polymer.
  • perfume oils or fragrances individual fragrance compounds, e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type are used. Preferably, however, mixtures of different fragrances are used, which together produce an attractive fragrance.
  • perfume oils may also contain natural fragrance mixtures as are available from plant sources.
  • the amount of perfume in the textile-care composition is preferably between 0.1 and 15 wt .-%, particularly preferably between 0.5 and 10 wt .-% and most preferably between 1 and 7 wt .-%.
  • microcapsules may be water-soluble and / or water-insoluble microcapsules.
  • melamine-urea-formaldehyde microcapsules melamine-formaldehyde microcapsules, urea-formaldehyde microcapsules, or starch microcapsules can be used.
  • the textile-care composition contains as essential ingredient a polysaccharide.
  • Suitable polysaccharides include, for example, glycogen, starch, chitin, callose, cellulose, dextran, tunicin, inulin, alginic acid, xanthan, gellan, guar, locust bean gum, carrageenan, derivatives of these compounds or mixtures of these compounds and derivatives thereof.
  • the polysaccharide comprises cellulose or a cellulose derivative. It is particularly preferred that the polysaccharide comprises a cellulose derivative.
  • Suitable cellulose derivatives include, for example, methylcellulose, ethylcellulose, propylcellulose, Methylethylcellulose, carboxymethylcellulose, ethylcarboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylhydroxyethylcellulose, methylhydroxypropylcellulose, methylhydroxyethylcellulose hydroxypropylmethylcellulose, ethylhydroxyethylcellulose, methylethylhydroxyethylcellulose, quaternized cellulose, quaternized cellulose derivatives, amine-modified cellulose, amine-modified cellulose derivatives or mixtures of these compounds.
  • Suitable methylhydroxypropylcelluloses are available, for example, under the names Methocel® J 40 MS or Methocel® J 5 S (both ex Dow Chemical). Hydroxyethyl celluloses which can be used in the present invention include, for example, Cellosize® HEC QP (ex Dow Chemical). Suitable methylcelluloses include, for example, Methocel® A (ex Dow Chemical).
  • Suitable cationic cellulose derivatives are the Polyquaternium 10 compounds Celquat® SC-240 (ex National Starch) or UCARE® Polymer JR-125, UCARE® Polymer JR-400, UCARE® Polymer JR-30M, UCARE® Polymer LR 400, UCARE ® Polymer LR 30M and Ucare® Polymer SR-10 (all ex Amerchol).
  • Celquat® SC-240 Ex National Starch
  • UCARE® Polymer JR-125 UCARE® Polymer JR-400
  • UCARE® Polymer JR-30M UCARE® Polymer LR 400
  • UCARE ® Polymer LR 30M Ucare® Polymer SR-10
  • Finnfix BDA ex Kelco
  • cellulose and / or cellulose derivatives are used in powder form.
  • the ratio of fabric care compound to polysaccharide is preferably between 15: 1 and 1: 5, more preferably between 12: 1 and 1: 1, and most preferably between 9: 1 and 4: 1.
  • the fabric care composition may optionally contain other ingredients.
  • dyestuffs In order to improve the aesthetic impression of the textile-care composition, they can be dyed with suitable dyes.
  • Preferred dyestuffs the selection of which presents no difficulty to a person skilled in the art, should have a high storage stability and insensitivity to the other ingredients of the detergents or to light and no pronounced substantivity to textile fibers in order not to stain them.
  • the fabric care composition may contain a filler such as silica.
  • the amount of filler may be between 0.1 and 10 wt .-% and is preferably 1 to 5 wt .-%.
  • the fabric care composition may also contain a pearlescer to increase gloss.
  • suitable pearlescing agents are ethylene glycol mono- and distearate (for example Cutina®AGS from Cognis) and PEG-3-distearate.
  • the fabric care composition may comprise a skin care compound.
  • a skin-care compound is understood as meaning a compound or a mixture of compounds which, upon contact of a textile with the detergent, are applied to the textile and on contact give the textile with skin an advantage on the skin compared to a textile which has not been treated with the detergent and cleaning agent according to the invention.
  • This benefit may include, for example, the transfer of the skin care compound from the textile to the skin, less water transfer from the skin to the textile, or less friction on the skin surface through the textile.
  • the amount of skin-care compound is preferably between 0.01 and 10% by weight, preferably between 0.1 and 5% by weight and very particularly preferably between 0.3 and 3% by weight, based on the solid, textile nourishing composition. It may be that the skin-nourishing compound additionally has a textile care effect.
  • the fabric care composition may contain a bittering agent such as Bitrex® (ex Macfarlan Smith).
  • the solid textile care composition comprises a water-soluble carrier, a water-soluble polymer, a fabric-care compound, a polysaccharide and a perfume, wherein the water-soluble carrier is in particulate form and at least partially an enclosure of the water-soluble polymer and the perfume, and wherein the sheath is incorporated with a mixture of the fabric care compound and the polysaccharide.
  • the water-soluble polymer is first melted and mixed with the perfume in the molten state.
  • the resulting melt is added to the particulate carrier in such a way that it is at least partially enveloped, and then a mixture of the textile-care compound and the polysaccharide is incorporated into the still-melted coating.
  • the mixture is preferably incorporated completely into the casing.
  • the solid, fabric care composition comprises a water-soluble carrier, a water-soluble polymer, a fabric-care compound, a polysaccharide and a perfume, wherein the water-soluble carrier is in particulate form and at least partially an enclosure of the water-soluble polymer and the perfume and wherein the wrapper or wrapper and the non-enveloped portions of the water-soluble carrier are / are at least partially coated with a blend of the fabric care composition and the polysaccharide.
  • the water-soluble polymer is first melted and mixed with the perfume in the molten state.
  • the resulting melt is placed on the particulate carrier so that it is at least partially enveloped, and then the wrapper or sheath and non-enveloped portions of the water-soluble carrier become at least partially coated with a mixture of the fabric care compound and the polysaccharide coated.
  • the particulate carrier is completely enveloped.
  • the textile-care compound is a bentonite and the polysaccharide is a cellulose derivative.
  • the cellulose derivative is an N, N, N-trialkylaminohydroxyalkyl quaternized hydroxyethylcellulose, an N, N, N-trialkylaminohydroxyalkyl quaternized hydroxypropylcellulose, a carboxymethylcellulose, a methylhydroxypropylcellulose, a hydroxyethylcellulose, an N, N-dialkylaminoalkyl substituted cellulose derivative, or a methylcellulose , It is also preferred that both compounds be used in powder form.
  • the textile-care composition is suitable in particular for conditioning textile fabrics and is brought into contact with the textile fabrics together with a conventional washing or cleaning agent in the (main) wash cycle of a conventional washing and cleaning process.
  • the fabric care composition can be incorporated into a detergent or cleanser.
  • a solid detergent or cleaning agent with 1 to 20 wt .-%, preferably 5 to 15 wt .-%, of the textile-care composition according to the invention is mixed.
  • the textile-care washing or cleaning compositions according to the invention contain, in addition to the textile-care composition, surfactant (s), it being possible to use anionic, nonionic, zwitterionic and / or amphoteric surfactants. From an application point of view, preference is given to mixtures of anionic and nonionic surfactants.
  • the total surfactant content of a detergent is preferably below 40% by weight, and more preferably below 35% by weight, based on the total liquid detergent.
  • the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten.
  • alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for example of coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred.
  • nonionic surfactants which can also be used are alkyl glycosides, polyhydroxy fatty acid amides, alkoxylated fatty acid alkyl esters, fatty acid alkanolamides and / or amine oxides.
  • the content of nonionic surfactants in the detergents or cleaners is preferably 5 to 30 wt .-%, preferably 7 to 20 wt .-% and in particular 9 to 15 wt .-%, each based on the total detergent or cleaning agent.
  • anionic surfactants for example, those of the sulfonate type and sulfates are used.
  • Suitable surfactants of the sulfonate type are preferably C 9-13 -alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates.
  • alkanesulfonates are also suitable.
  • esters of ⁇ -sulfo fatty acids esters of ⁇ -sulfo fatty acids (ester sulfonates), for example the ⁇ -sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids.
  • Suitable anionic surfactants are sulfated fatty acid glycerol esters.
  • alk (en) ylsulfate the alkali metal and in particular the sodium salts of sulfuric acid half esters of C 12 -C 18 fatty alcohols are preferred.
  • the sulfuric acid monoesters of straight-chain or branched with 1 to 6 moles of ethylene oxide ethoxylated C 7-21 alcohols, such as 2-methyl-branched C 9-11 alcohols containing on average 3.5 moles of ethylene oxide (EO) or C 12-18 fatty alcohols containing 1 to 4 EO are suitable.
  • anionic surfactants are also the salts of alkylsulfosuccinic acid and the monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols.
  • Particularly preferred anionic surfactants are soaps.
  • Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and, in particular, soap mixtures derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids.
  • the anionic surfactants may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine.
  • the anionic surfactants are preferably present in the form of their sodium or potassium salts, in particular in the form of the sodium salts.
  • the content of preferred detergents or cleaning agents to anionic surfactants is 2 to 30 wt .-%, preferably 4 to 25 wt .-% and in particular 5 to 22 wt .-%, each based on the total washing or cleaning agent.
  • the textile-care composition contains a cationic polymer, that the washing or cleaning agent contains only nonionic surfactants.
  • the detergents or cleaners may contain further ingredients which further improve the performance and / or aesthetic properties of the washing or cleaning agent.
  • preferred washing or cleaning agents additionally contain one or more substances from the group of builders, bleaches, bleach activators, enzymes, perfumes, perfume carriers, fluorescers, dyes, foam inhibitors, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents , Color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, antistatic agents, bittering agents, ironing aids, repellents and impregnating agents, swelling and anti-slip agents, neutral filler salts and UV absorbers.
  • Suitable builders which may be present in the detergents or cleaners are in particular silicates, aluminum silicates (in particular zeolites), carbonates, salts of organic di- and polycarboxylic acids and mixtures of these substances.
  • phosphates as builders are possible, unless such use should not be avoided for environmental reasons.
  • Organic builders that may be present in the detergent or cleaning agent include polycarboxylate polymers such as polyacrylates and acrylic acid / maleic acid copolymers, polyaspartates and monomeric polycarboxylates such as citrates, gluconates, succinates or malonates, which are preferably used as the sodium salts.
  • sodium perborate tetrahydrate and sodium perborate monohydrate are of particular importance.
  • Other useful bleaching agents are, for example, sodium percarbonate, peroxypyrophosphates, citrate perhydrates and H 2 O 2 -producing peracidic salts or peracids, such as perbenzoates, peroxophthalates, diperazelaic acid, phthaloiminoperacid or diperdodecanedioic acid.
  • bleach activators can be incorporated into the detergents or cleaners.
  • bleach activators it is possible to use compounds which, under perhydrolysis conditions, give aliphatic peroxycarboxylic acids having preferably 1 to 10 C atoms, in particular 2 to 4 C atoms, and / or optionally substituted perbenzoic acid.
  • Suitable substances are those which carry O- and / or N-acyl groups of the stated C atom number and / or optionally substituted benzoyl groups.
  • polyacylated alkylenediamines in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular tetraacetylglycoluril (TAGU), N- Acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic anhydrides, in particular phthalic anhydride, acylated polyhydric alcohols, in particular triacetin, ethylene glycol diacetate and 2,5-diacetoxy- 2,5-dihydrofuran.
  • TAED tetraacet
  • bleach catalysts can also be incorporated into the detergents or cleaners.
  • These substances are bleach-enhancing transition metal salts or transition metal complexes such as Mn, Fe, Co, Ru or Mo saline complexes or carbonyl complexes.
  • Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with nitrogen-containing tripod ligands and Co, Fe, Cu and Ru ammine complexes can also be used as bleach catalysts.
  • the washing or cleaning agent may contain enzymes in encapsulated form and / or directly in the washing or cleaning agent.
  • Suitable enzymes include in particular those from the classes of hydrolases such as proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases, hemicellulases, cutinases, ⁇ -glucanases, oxidases, peroxidases, mannanases, perhydrolases and / or laccases and mixtures of said enzymes in question.
  • hydrolases such as proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases, hemicellulases, cutinases, ⁇ -glucanases, oxidases, peroxidases, mannanases, perhydrolases and / or laccases and mixtures of said enzymes in question.
  • Enzyme mixtures for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic acting Enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes are of particular interest.
  • lipolytic enzymes examples include the known cutinases. Peroxidases or oxidases have also proved suitable in some cases. Suitable amylases include in particular ⁇ -amylases, iso-amylases, pullulanases and pectinases. As cellulases are preferably cellobiohydrolases, endoglucanases and ⁇ -glucosidases, which are also called cellobiases, or mixtures thereof used. Since different cellulase types differ by their CMCase and avicelase activities, the desired activities can be set by targeted mixtures of the cellulases.
  • the enzymes may be adsorbed to carriers to protect against premature degradation.
  • the proportion of enzymes or enzyme granules directly in the washing or cleaning agent may be, for example, about 0.01 to 5 wt .-%, preferably 0.12 to about 2.5 wt .-%.
  • washing or cleaning agent contains no enzymes.
  • the washing or cleaning agent optionally contains one or more perfumes in an amount of usually up to 10 wt .-%, preferably 0.5 to 7 wt .-%, in particular 1 to 3 wt .-%.
  • the amount of perfume used is also dependent on the type of detergent or cleaning agent. However, it is particularly preferred that the perfume is introduced into the washing or cleaning agent via the textile care composition. However, it is also possible for the washing or cleaning agent to contain perfume which is not introduced into the washing or cleaning agent via the textile care composition.
  • the detergents or cleaners may (optionally only partially) be colored with suitable dyes.
  • Preferred dyes the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
  • Suitable foam inhibitors which can be used in the detergents or cleaners are, for example, soaps, paraffins or silicone oils, which may optionally be applied to support materials.
  • Suitable soil release polymers also referred to as "anti-redeposition agents” include, for example, nonionic cellulose ethers such as methyl cellulose and methyl hydroxypropyl cellulose having a methoxy group content of 15 to 30 wt% and hydroxypropyl groups of 1 to 15 wt%, respectively based on the nonionic cellulose ether and the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular polymers of ethylene terephthalates and / or polyethylene and / or polypropylene glycol terephthalates or anionic and / or nonionic modified derivatives thereof.
  • nonionic cellulose ethers such as methyl cellulose and methyl hydroxypropyl cellulose having a methoxy group content of 15 to 30 wt% and hydroxypropyl groups of 1 to 15 wt%, respectively based on the nonionic cellulose ether and the known from the prior art polymers of phthalic acid and
  • Suitable derivatives include the sulfonated derivatives of the phthalic and terephthalic acid polymers.
  • Another class of suitable soil-release polymers, in particular for cotton-containing textiles, are modified, for example alkoxylated and / or quaternized and / or oxidized, polyamines.
  • the polyamines are, for example, polyalkyleneamines, such as polyethyleneamines, or polyalkylenimines, such as polyethylenimines.
  • Preferred examples of this class of soil release polymers are ethoxylated polyethylenimines and ethoxylated polyethyleneamines.
  • Optical brighteners can be added to the detergents or cleaners to eliminate graying and yellowing of the treated fabrics. These fabrics impinge on the fiber and cause whitening and bleaching by transforming invisible ultraviolet radiation into visible longer wavelength light, emitting the ultraviolet light absorbed from the sunlight as faint bluish fluorescence, and pure with the yellowness of the grayed or yellowed wash White results.
  • Suitable compounds are derived, for example, from the substance classes of 4,4'-diamino-2,2'-stilbenedisulfonic acids (flavonic acids), 4,4'-distyrylbiphenyls, methylumbelliferones, coumarins, dihydroquinolinones, 1,3-diarylpyrazolines, naphthalimides, benzoxazole , Benzisoxazole and benzimidazole systems as well as heterocyclic substituted pyrene derivatives.
  • the optical brighteners are usually used in amounts of between 0% and 0.3% by weight, based on the finished washing or cleaning agent.
  • Grayness inhibitors have the task of keeping the dirt detached from the fiber suspended in the liquor and thus preventing the dirt from being rebuilt.
  • Water-soluble colloids of mostly organic nature are suitable for this purpose, for example glue, gelatine, salts of ether sulfonic acids or cellulose or salts of acidic sulfuric acid esters of cellulose or starch.
  • water-soluble polyamides containing acidic groups are suitable for this purpose. It is also possible to use soluble starch preparations and starch products other than those mentioned above, for example degraded starch, aldehyde starches, etc. Polyvinylpyrrolidone is also useful.
  • cellulose ethers such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof in amounts of from 0.1 to 5% by weight, based on the washing or cleaning agents.
  • the washing or cleaning agent may contain a dye transfer inhibitor.
  • the Color transfer inhibitor is a polymer or copolymer of cyclic amines.
  • Suitable color transfer inhibiting polymers include polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI), copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI), polyvinylpyridine-N-oxide, poly-N-carboxymethyl-4-vinylpyridium chloride, and mixtures thereof.
  • the amount of dye transfer inhibitor based on the total amount of the detergent or cleaning agent is preferably from 0.01 to 2% by weight, preferably from 0.05 to 1% by weight, and more preferably from 0.1 to 0.5% by weight. -%.
  • enzymatic systems comprising a peroxidase and hydrogen peroxide or a substance which produces hydrogen peroxide in water as a color transfer inhibitor.
  • a mediator compound for the peroxidase for example an acetosyringone, a phenol derivative or a phenotiazine or phenoxazine, is preferred in this case, wherein additionally the above-mentioned polymeric dye transfer inhibitors can be used.
  • the detergents or cleaning agents may contain synthetic crease inhibitors. These include, for example, synthetic products based on fatty acids, fatty acid esters, fatty acid amides, alkylol esters, -alkylolamides or fatty alcohols, which are usually reacted with ethylene oxide, or products based on lecithin or modified phosphoric acid ester.
  • washing or cleaning agents may contain antimicrobial agents.
  • antimicrobial agents Depending on the antimicrobial spectrum and mechanism of action, a distinction is made between bacteriostatic agents and bactericides, fungistats and fungicides, etc.
  • Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenolmercuric acetate, and the compounds according to the invention can be completely dispensed with in these detergents or cleaners ,
  • the detergents or cleaners according to the invention may contain preservatives, it being preferred to use only those which have no or only a low skin-sensitizing potential.
  • preservatives examples are sorbic acid and its salts, benzoic acid and its salts, salicylic acid and its salts, phenoxyethanol, 3-iodo-2-propynyl butylcarbamate, sodium N- (hydroxymethyl) glycinate, biphenyl-2-ol and mixtures thereof.
  • a suitable preservative is the solvent-free, aqueous combination of diazolidinyl urea, sodium benzoate and potassium sorbate (available as Euxyl® K 500 ex Schuelke & Mayr), which can be used in a pH range up to 7.
  • the detergents or cleaners may contain antioxidants.
  • This class of compounds includes, for example, substituted phenols, hydroquinones, catechols and aromatic amines, as well as organic sulfides, polysulfides, dithiocarbamates, phosphites, phosphonates and vitamin E.
  • the most surface-active antistatic agents can be subdivided into nitrogen-containing (amines, amides, quaternary ammonium compounds), phosphorus-containing (phosphoric acid esters) and sulfur-containing (alkyl sulfonates, alkyl sulfates) antistatic agents.
  • silicone derivatives can be used in the detergents or cleaners. These additionally improve the rinsing behavior of the washing or cleaning agents by their foam-inhibiting properties.
  • the detergents or cleaning agents may also contain UV absorbers.
  • Suitable compounds include benzophenone having substituents in the 2- and / or 4-position or substituted benzotriazoles.
  • Suitable heavy metal complexing agents are, for example, the alkali metal salts of ethylenediaminetetraacetic acid (EDTA) or nitrilotriacetic acid (NTA) and alkali metal salts of anionic polyelectrolytes such as polymaleates and polysulfonates.
  • EDTA ethylenediaminetetraacetic acid
  • NTA nitrilotriacetic acid
  • a preferred class of complexing agents are the phosphonates.
  • organophosphonates such as 1-hydroxyethane-1,1-diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriamine penta (methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane-1,2 , 4-tricarboxylic acid (PBS-AM), which are used mostly in the form of their ammonium or alkali metal salts.
  • organophosphonates such as 1-hydroxyethane-1,1-diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriamine penta (methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane-1,2 , 4-tricarboxylic acid (PBS-AM), which are used mostly in the form of their ammonium or alkali metal salts.
  • neutral fillers such as sodium sulfate or sodium carbonate may be included in the solid detergents or cleaners.
  • washing or cleaning agents according to the invention can be used in particular for cleaning and conditioning textile fabrics.
  • the washing or cleaning agent without the textile-care compound is first prepared by known processes, which include, for example, drying steps, mixing steps, densification steps, shaping steps and / or the subsequent addition of heat-sensitive ingredients ("post-addition") may be prepared. Subsequently, the resulting product is mixed with a solid textile-care composition.
  • the mixing step may be followed by further compaction and / or shaping steps.
  • Table 1 shows textile-care compositions E1 to E4 according to the invention and a composition V1 not according to the invention.
  • Table 1 V1 E1 E2 E3 E4 Sucrose crystals (1 - 4 mm) 69.99 69.99 69.99 69.99 69.99 69.99 69.99 69.99 Bentonite (powder) 10 9 9 9 9 9 methylhydroxypropylcellulose * - 1 - - - hydroxyethyl * - - 1 - - Methylcellulose * - - - 1 - Cationic hydroxyethylcellulose * - - - - 1 Perfume 5 5 5 5 5 5 5 5 PEG 8000 15 15 15 15 15 Dye (blue) 0.01 0.01 0.01 0.01 0.01 * The cellulose derivatives were all used in powder form.
  • the polyethylene glycol having an average molecular weight of 8,000 (PEG 8,000) was melted and the perfume and the dye were introduced into the melt. Subsequently, the colored melt was added to the sucrose crystals and the coated sucrose crystals were powdered with stirring with a mixture of bentonite powder and cellulose derivative powder while the melt of PEG 8000, perfume and dye was not completely solidified.
  • compositions E1 to E4 showed a better flow behavior in the freshly prepared state than the comparative composition V1.
  • all of the compositions E1 to E4 and V1 had a clear, crystalline appearance when fresh.
  • methylhydroxypropylcellulose, methylcellulose and hydroxyethylcellulose-containing textile-care compositions E1 to E3 after 8 weeks storage at room temperature had a clear appearance and no color changes.
  • the methylcellulose and hydroxyethylcellulose-containing textile-care compositions E2 and E3 still showed a clear, crystalline appearance after 12 weeks of storage and showed no color changes.
  • the crystals E3 showed no color changes even after 24 weeks.
  • the textile-care composition E4 showed a clear appearance even after 8 weeks storage at room temperature, but also a slight tendency to form smaller aggregates could be observed.
  • the textile care compositions E1 to E4 showed a very good dissolution behavior when in contact with water and, compared with water, a softening effect with respect to fabrics treated therewith.
  • the textile care compositions E1 to E4 on wet, freshly laundered laundry exhibited a significantly higher scent intensity compared to laundry treated with a conventional liquid esterquat-containing softener.
  • Table 2 shows further textile care compositions E5 to E7 according to the invention and a composition V2 not according to the invention.
  • Table 2 V2 ' E5 E6 E7 Sucrose crystals (1 - 4 mm) 69.99 69.99 69.99 69.99 69.99 Bentonite (powder) 10 9.5 9 8th Carboxymethyl cellulose, Na salt * - 0.5 1 2 Perfume 5 5 5 5 PEG 8000 15 15 15 15 Dye (blue) 0.01 0.01 0.01 0.01 * The cellulose derivative was used in powder form.
  • the polyethylene glycol having an average molecular weight of 8000 (PEG 8000) was melted and the perfume and the dye were added to the melt. Subsequently, the colored melt was added to the sucrose crystals and the coated sucrose crystals were powdered with a mixture of bentonite powder and the cellulose derivative powder while the melt of PEG 8000, perfume and dye was not completely solidified.
  • compositions E5 to E7 and V2 had a clear, crystalline appearance in the freshly prepared state. After 4 weeks of storage at room temperature, the textile-care composition V2 began to lose its clarity. Already after 8 weeks of storage at room temperature, the crystals V2 had completely lost their clear appearance and showed a clear color change.
  • the textile care composition E5 according to the invention also showed a loss in clarity after 4 weeks of storage. However, this loss of clarity was lower than in the non-inventive textile-care composition V2.
  • the two textile care compositions E6 and E7 according to the invention were clear and color-stable even after 8 weeks of storage, while the textile care composition V2 not according to the invention completely changed its color and lost its clarity.
  • the textile care composition E5 according to the invention showed, after 8 weeks of storage, a further slight loss in clarity and a slight change in color.
  • a particularly color-stable textile care composition E8 with beautiful, crystalline appearance was obtained when using diethylaminoethyl-hydroxyethylcellulose as a polysaccharide.
  • E8 Sucrose crystals (1 - 4 mm) 69.99 Bentonite (powder) 9.5 Amine-substituted cellulose derivative * 0.5 Perfume 5 PEG 8000 15 Dye (blue) 0.01 * The cellulose derivative was used in powder form.
  • the polyethylene glycol having an average molecular weight of 8,000 (PEG 8,000) was melted, and the perfume and the dye were added to the melt. Subsequently, the colored melt was added to the sucrose crystals and the coated sucrose crystals were powdered with a mixture of bentonite powder and the cellulose derivative powder while the melt of PEG 8000, perfume and dye was not completely solidified.
  • the textile-care composition E8 according to the invention was still crystal clear after 20 weeks of storage and showed no change in color.
  • the textile-care compositions E1 to E8 according to the invention could be filled at significantly higher product end temperatures compared with the textile-care compositions V1 and V2 .
  • the textile-care compositions E1 to E3 according to the invention and E5 to E8 showed no tendencies to agglomerate or agglomerate neither during production nor during storage.
  • the agglomeration tendency during storage of the textile-care composition E4 was only slight and did not adversely affect the handling and in particular the metering behavior of the textile-care composition E4 .
  • a solid, unscented washing or cleaning agent was mixed with 15% by weight (based on the total amount of finished washing or cleaning agent) of the textile-care composition E3 .
  • the washing or cleaning agent according to the invention showed good cleaning and conditioning properties.

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Description

Die Erfindung betrifft eine feste, Textil-pflegende Zusammensetzung sowie deren Verwendung und Herstellung. Des Weiteren betrifft die Erfindung ein Wasch- oder Reinigungsmittel, das die feste, Textilpflegende Zusammensetzung enthält.The invention relates to a solid, textile-care composition and its use and preparation. Furthermore, the invention relates to a washing or cleaning agent containing the solid, textile care composition.

Durch wiederholtes Waschen werden Textilien oft hart und verlieren ihre Weichheit. Um Textilien ihre Weichheit/Flexibilität wiederzugeben, um ihnen einen angenehmen Duft zu verleihen und/oder um ihre antistatischen Eigenschaften zu verbessern, werden die Textilien nach dem eigentlichen Wasch- und Reinigungsprozess in einem anschließenden Spülprozess mit einem Weichspüler behandelt.Repeated washing often causes textiles to harden and lose their softness. To give textiles their softness / flexibility to give them a pleasant fragrance and / or to improve their antistatic properties, the textiles are treated after the actual washing and cleaning process in a subsequent rinsing process with a fabric softener.

Die meisten, im Markt befindlichen Weichspüler sind wässrige Formulierungen, die als Hauptwirkungsbestandteil eine kationische Textil-weichmachende Verbindung, die eine oder zwei langkettige Alkylgruppen in einem Molekül aufweisen, enthalten. Weit verbreitete kationische Textil-weichmachende Verbindungen umfassen beispielsweise Methyl-N-(2-hydroxyethyl)-N,N-di(talgacyloxyethyl)ammonium-Verbindungen oder N,N-Dimethyl-N,N-di(talgacyloxyethyl)ammonium-Verbindungen.Most fabric softeners on the market are aqueous formulations containing as the main active ingredient a cationic fabric softening compound having one or two long-chain alkyl groups in one molecule. Commonly used cationic fabric softening compounds include, for example, methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium compounds or N, N-dimethyl-N, N-di (tallowacyloxyethyl) ammonium compounds.

Diese herkömmlichen Weichspülerformulierungen können wegen der kationischen, Textil-weichmachenden Verbindungen nicht gleichzeitig mit dem Wasch- oder Reinigungsmittel im eigentlichen Wasch- oder Reinigungsprozess verwendet werden, da die kationischen Textil-weichmachenden Verbindungen mit den anionischen Tensiden der Wasch- oder Reinigungsmittel unerwünscht wechselwirken. Deshalb ist ein zusätzlicher Spülvorgang notwendig, der aber zeit- und energieintensiv ist.These conventional softener formulations can not be used concurrently with the detergent or cleaning agent in the actual washing or cleaning process because of the cationic fabric softening compounds because the cationic fabric softening compounds undesirably interact with the anionic surfactants of the detergents or cleaners. Therefore, an additional flushing process is necessary, but which is time and energy intensive.

Ein weiterer Nachteil ist, dass herkömmliche Weichspüler nicht die Ablagerung von Kalkrückständen während des Spülvorgangs auf der Wäsche verhindern. Zusätzlich hinterlassen die herkömmlichen Weichspüler oft unschöne Ablagerung in der Einspülkammer der Waschmaschine.Another disadvantage is that conventional softeners do not prevent the deposition of limescale during the rinse on the laundry. In addition, the conventional softener often leave unsightly deposit in the Einspülkammer the washing machine.

Auch bei anderen Textil-pflegenden Verbindungen können Probleme auftreten, die beispielsweise eine separate Dosierung und/oder einen separaten Spülgang erforderlich machen.Even with other textile-care compounds, problems may arise that require, for example, a separate dosage and / or a separate rinse.

Aus der WO 2007/115872 A1 sind deshalb feste Textilbehandlungsmittel mit einem wasserlöslichen Träger, der eine Umhüllung aus einem wasserlöslichen Polymer und Parfüm aufweist, wobei die Umhüllung zumindest teilweise mit einer textil-pflegenden Verbindung beschichtet ist, bekannt.From the WO 2007/115872 A1 are therefore solid textile treatment agents with a water-soluble carrier which comprises a coating of a water-soluble polymer and perfume, the coating being at least partially coated with a textile-care compound.

Die WO 2007/113326 A1 offenbart ein festes Textilbehandlungsmittel, welches einen wasserlöslichen Träger aus einer Alkalimetall-, Erdalkalimetall- und/oder Ammoniumverbindung, ein wasserlösliches Polymer, eine Textil-pflegende Verbindung und ein Parfüm enthält.The WO 2007/113326 A1 discloses a solid fabric treatment composition containing a water-soluble carrier of an alkali metal, alkaline earth metal and / or ammonium compound, a water-soluble polymer, a fabric-care compound and a perfume.

Bei der Herstellung und Lagerung kann es allerdings passieren, dass die einzelnen Textilbehandlungsmittelpartikel aufgrund einer hohen Klebrigkeit aneinander kleben und nicht problemlos weiter verarbeitet oder vom Verbraucher dosiert werden können.In the production and storage, it may happen, however, that the individual textile treatment agent particles stick together due to high tackiness and can not be further processed without difficulty or metered by the consumer.

Es ist deshalb eine Aufgabe der vorliegenden Erfindung, ein festes Textilbehandlungsmittel mit einem wasserlöslichen Träger, der eine Umhüllung aus einem wasserlöslichen Polymer, einem Parfüm und einer Textil-pflegenden Verbindung aufweist, bereitzustellen, welches bei der Herstellung und/oder Lagerung keine oder deutlich weniger Aggregate bzw. Verklumpungen bildet.It is therefore an object of the present invention to provide a solid textile treatment agent comprising a water-soluble carrier having a coating of a water-soluble polymer, a perfume and a fabric-care compound, which does not or significantly less aggregates in the production and / or storage or clumps forms.

Diese Aufgabe wird gelöst durch eine feste, Textil-pflegende Zusammensetzung, umfassend einen wasserlöslichen Träger, ein wasserlösliches Polymer, eine Textil-pflegende Verbindung, ein Polysaccharid und ein Parfüm, wobei der wasserlösliche Träger in partikulärer Form vorliegt und zumindest teilweise eine Umhüllung aus dem wasserlöslichen Polymer und dem Parfüm aufweist und eine Mischung aus der Textil-pflegenden Verbindung und dem Polysaccharid zumindest teilweise in und/oder zumindest teilweise auf der Umhüllung vorhanden ist.This object is achieved by a solid, textile-care composition comprising a water-soluble carrier, a water-soluble polymer, a fabric-care compound, a polysaccharide and a perfume, wherein the water-soluble carrier is in particulate form and at least partially an enclosure of the water-soluble Polymer and the perfume and a mixture of the fabric-care compound and the polysaccharide is at least partially present in and / or at least partially on the enclosure.

Überraschenderweise hat sich gezeigt, dass ein Verkleben der Textilbehandlungsmittelpartikel verhindert werden kann, wenn die Umhüllung eine Mischung aus dem Textil-pflegenden Mittel und einem Polysaccharid aufweist. Weder bei der Herstellung noch bei der Lagerung zeigten derart umhüllte textilpflegende Zusammensetzungen Tendenzen zu verklumpen bzw. zu agglomerieren. Zusätzlich sind derart umhülltee Textilbehandlungsmittelpartikel fließfähiger. Ferner hat sich gezeigt, dass die frisch hergestellten Textilbehandlungsmittelpartikel bei höheren Produktendtemperaturen abgefüllt werden können, was zu kürzeren Herstellungszeiten führt.Surprisingly, it has been found that sticking of the textile treatment agent particles can be prevented if the coating comprises a mixture of the textile care agent and a polysaccharide. Neither in production nor during storage did such coated textile-care compositions show tendencies to clump or agglomerate. In addition, such wrapped textile treatment agent particles are more flowable. Furthermore, it has been shown that the freshly prepared textile treatment agent particles can be filled at higher final product temperatures, resulting in shorter production times.

Ebenso hat sich gezeigt, dass Textilbehandlungsmittelpartikel deren Umhüllung eine Mischung aus der Textil-pflegenden Verbindung und einem Polysaccharid aufweist, länger ihre kristalline Optik behalten.It has also been found that textile treatment agent particles whose coating comprises a mixture of the textile-care compound and a polysaccharide retain their crystalline appearance for a longer time.

Weiterhin ist vorteilhaft, dass die feste, Textil-pflegende Zusammensetzung im Waschgang eines Wäschereinigungsverfahrens eingesetzt werden kann und so die Textil-pflegende Verbindung und das Parfüm bereits direkt zu Beginn des Waschverfahrens zur Wäsche transportiert werden und so ihr volles Potential entfalten können. Weiterhin ist diese feste Zusammensetzung einfacher und besser zu handhaben als flüssige Zusammensetzungen, da keine Tropfen am Flaschenrand zurückbleiben, die bei der anschließenden Lagerung der Flasche zu Rändern auf dem Untergrund oder zu unschönen Ablagerungen im Bereich des Verschlusses führen. Dasselbe gilt für den Fall, dass bei der Dosierung etwas von der Zusammensetzung versehentlich verschüttet wird. Die verschüttete Zusammensetzung kann auch einfacher und sauberer entfernt werden.Furthermore, it is advantageous that the solid, textile-care composition can be used in the wash cycle of a laundry cleaning process and so the textile-care compound and the perfume are already transported directly to the laundry at the beginning of the washing process and so can develop their full potential. Furthermore, this solid composition is easier and better to handle than liquid compositions, since no drops remain on the edge of the bottle, which lead to subsequent storage of the bottle to edges on the ground or to unsightly deposits in the region of the closure. The same applies in the event that some of the composition is accidentally spilled during dosing. The spilled composition can also be removed easier and cleaner.

Es ist bevorzugt, dass der wasserlösliche Träger ausgewählt ist aus der Gruppe bestehend aus anorganischen Alkalimetallsalzen, organischen Alkalimetallsalzen, anorganischen Erdalkalimetallsalzen, organischen Erdalkalimetallsalzen, organischen Säuren, Kohlenhydraten, Silikaten, Harnstoff und Mischungen daraus.It is preferable that the water-soluble carrier is selected from the group consisting of inorganic alkali metal salts, organic alkali metal salts, inorganic alkaline earth metal salts, organic alkaline earth metal salts, organic acids, carbohydrates, silicates, urea and mixtures thereof.

Diese Materialien sind nicht nur preiswert, sondern lösen sich sehr gut in Wasser. Außerdem sind diese Materialien geruchsneutral oder geruchsarm.These materials are not only inexpensive, but dissolve very well in water. In addition, these materials are odorless or odorless.

Es ist vorteilhaft, dass die feste, Textil-pflegende Zusammensetzung 50 bis 99 Gew.-%, bevorzugt 75 bis 95 Gew.%, an dem wasserlöslichen Träger enthält.It is preferable that the solid textile care composition contains 50 to 99% by weight, preferably 75 to 95% by weight, of the water-soluble carrier.

Weiterhin ist es bevorzugt, dass die Textil-pflegende Verbindung aus Textil-weichmachenden Verbindungen, Bleichmitteln, Bleichaktivatoren, Enzymen, Silikonölen, Antiredepositionsmittel, optischen Aufheller, Vergrauungsinhibitoren, Einlaufverhinderer, Knitterschutzmittel, Farbübertragungsinhibitoren, antimikrobiellen Wirkstoffen, Germiziden, Fungiziden, Antioxidantien, Antistatika, Bügelhilfsmitteln, Phobier- und Imprägniermitteln, Quell- und Schiebefestmitteln, UV-Absorber sowie Mischungen daraus ausgewählt ist.Further, it is preferred that the fabric care composition is composed of fabric softening compounds, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, crease inhibitors, color transfer inhibitors, antimicrobials, germicides, fungicides, antioxidants, antistatic agents, ironing aids , Phobic and impregnating agents, swelling and anti-slip agents, UV absorbers and mixtures thereof.

Es ist insbesondere bevorzugt, dass die Textil-pflegende Verbindung eine Textil-weichmachende Verbindung ist. Dabei ist ganz besonders bevorzugt, dass die Textil-weichmachende Verbindung aus Polysiloxanen, Textil-weichmachenden Tonen, kationischen Polymeren und Mischungen daraus ausgewählt ist.It is particularly preferred that the fabric care compound is a fabric softening compound. It is most preferred that the fabric softening compound is selected from polysiloxanes, fabric softening clays, cationic polymers and mixtures thereof.

Ein solcher Weichspüler kann im Hauptwaschgang eines automatischen Wasch- oder Reinigungsverfahrens eingesetzt werden. Die Textil-pflegende Zusammensetzung kann beispielsweise zusammen mit dem Wasch- oder Reinigungsmittel in die Trommel oder die Einspülkammer einer Waschmaschine gegeben werden. Dies hat den Vorteil, dass kein zusätzlicher Spülgang notwendig ist und keine unschönen Ablagerungen in der Einspülkammer auftretenSuch a fabric conditioner can be used in the main wash of an automatic washing or cleaning process. The textile-care composition can be added, for example, together with the detergent or cleaning agent in the drum or the dispenser of a washing machine. This has the advantage that no additional rinse is necessary and no unsightly deposits occur in the dispenser

Die Verwendung von Polysiloxanen und/oder kationischen Polymeren als Textil-pflegende Verbindung in der Textil-pflegenden Zusammensetzung ist vorteilhaft, da diese nicht nur einen weichmachenden Effekt zeigen, sondern auch den Parfümeindruck auf der Wäsche verstärken. Die Verwendung von weichmachenden Tonen als Textil-pflegende Verbindung in der Textil-pflegenden Zusammensetzung ist vorteilhaft, da diese zusätzlich einen Wasser-enthärtenden Effekt aufweisen und so Kalkablagerungen auf der Wäsche verhindert werden. Um eine optimale Leistung zu erzielen, kann es bevorzugt sein, dass eine Textil-pflegende Zusammensetzung eine Kombination von wenigstens zwei Textil-pflegenden Verbindungen enthält.The use of polysiloxanes and / or cationic polymers as a fabric care compound in the fabric care composition is advantageous because they not only have a softening effect but also enhance the perfume impression on the laundry. The use of softening clays as textile-care compound in the textile-care composition is advantageous because they additionally have a water-softening effect and thus lime deposits are prevented on the laundry. For optimum performance, it may be preferred for a fabric care composition to contain a combination of at least two fabric care compounds.

Es ist bevorzugt, dass das wasserlösliche Polymer ausgewählt ist aus Polyalkylenglykolen, Polyvinylalkoholen und Mischungen daraus. Diese wasserlöslichen Polymere fungieren als Bindemittel.It is preferred that the water-soluble polymer is selected from polyalkylene glycols, polyvinyl alcohols and mixtures thereof. These water-soluble polymers function as binders.

Auch ist es bevorzugt, dass der wasserlösliche Träger Partikelgrößen im Bereich von 0,6 bis 30 mm, insbesondere 0,8 bis 7 mm und besonders bevorzugt 1 bis 3 mm, aufweist.It is also preferable for the water-soluble carrier to have particle sizes in the range from 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm.

Textil-pflegende Zusammensetzungen mit Partikelgrößen im Bereich von 0,8 bis 7 mm und besonders bevorzugt im Bereich 1 bis 3 mm lassen sich besonders gut und gezielt dosieren.Textile-care compositions with particle sizes in the range from 0.8 to 7 mm and particularly preferably in the range from 1 to 3 mm can be metered particularly well and in a targeted manner.

Es ist weiterhin bevorzugt, dass das Polysaccharid ausgewählt ist aus der Gruppe umfassend Glycogen, Stärke, Chitin, Callose, Cellulose, Dextran, Tunicin, Inulin, Alginsäure, Xanthan, Gellan, Guar, Johannisbrotkernmehl, Carrageenan, Derivate dieser Verbindungen oder Mischungen dieser Verbindungen sowie deren Derivate.It is further preferred that the polysaccharide is selected from the group comprising glycogen, starch, chitin, callose, cellulose, dextran, tunicin, inulin, alginic acid, xanthan, gellan, guar, locust bean gum, carrageenan, derivatives of these compounds or mixtures of these compounds and their derivatives.

Es ist insbesondere bevorzugt, dass die Mischung als Polysaccharid Cellulose oder ein Cellulosederivat ausgewählt aus der Gruppe umfassend Methylcellulose, Ethylcellulose, Propylcellulose, Methylethylcellulose, Carboxymethylcellulose, Ethylcarboxymethylcellulose, Hydroxyethylcellulose, Hydroxypropylcellulose, Carboxymethylhydroxyethylcellulose, Methylhydroxyethylcellulose Hydroxypropylmethylcellulose, Ethylhydroxyethylcellulose, Methylethylhydroxyethylcellulose, quaternisierte Cellulose, quaternisierte Cellulosederivate, Amin-modifizierte Cellulose, Amin-modifizierte Cellulosederivate oder Mischungen dieser Verbindungen umfasst.It is particularly preferred that the mixture as polysaccharide is cellulose or a cellulose derivative selected from the group comprising methylcellulose, ethylcellulose, propylcellulose, methylethylcellulose, carboxymethylcellulose, ethylcarboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylhydroxyethylcellulose, methylhydroxyethylcellulose hydroxypropylmethylcellulose, ethylhydroxyethylcellulose, methylethylhydroxyethylcellulose, quaternized cellulose, quaternized cellulose derivatives, Amine-modified cellulose, amine-modified cellulose derivatives or mixtures of these compounds.

Cellulose und deren Derivate verhindern besonders effektiv ein Verkleben der Partikel des Textilbehandlungsmittels. Es hat sich auch gezeigt, dass insbesondere Cellulose oder deren Derivate die Farbstabilität gefärbter, fester Textil-pflegender Zusammensetzungen erhöhen.Cellulose and its derivatives are particularly effective in preventing sticking of the particles of the textile treatment agent. It has also been found that in particular cellulose or its derivatives increase the color stability of colored, solid textile-care compositions.

Um die anwendungstechnischen und/oder ästhetischen Eigenschaften der Textil-pflegenden Zusammensetzung zu verbessern, kann diese zusätzliche Inhaltsstoffe enthalten, vorzugsweise ausgewählt aus der Gruppe bestehend aus Farbstoffen, Füllstoffen, Perlglanzmitteln, Haut-pflegenden Verbindungen, Bitterstoffe und Mischungen daraus.In order to improve the performance and / or aesthetics of the fabric care composition, it may contain additional ingredients, preferably selected from the group consisting of dyes, fillers, pearlescers, skin care compounds, bittering agents, and mixtures thereof.

In einer bevorzugten Ausführungsform enthält die Textil-pflegende Zusammensetzung 0,1 bis 15 Gew.-%, bevorzugt 1 bis 10 Gew.-% und insbesondere bevorzugt 2 bis 7 Gew.-% Parfüm.In a preferred embodiment, the fabric care composition contains from 0.1% to 15%, preferably from 1% to 10%, and most preferably from 2% to 7%, by weight of perfume.

Bei herkömmlichen flüssigen Weichspülerzusammensetzungen mit quaternären Ammoniumverbindungen als Textil-pflegende Verbindungen tritt bei höheren Parfümkonzentration (> 0,4 Gew.-% Parfüm bei regulären Weichspülerzusammensetzungen und ≥ 1 Gew.-% bei konzentrierten Weichspülerzusammensetzungen) ein Problem mit der Stabilität der Zusammensetzung auf. Bei den erfindungsgemäßen Textil-pflegenden Zusammensetzungen können problemlos größere Mengen (≥ 1 Gew.-%) an Parfüm eingearbeitet werden.In conventional liquid fabric softener compositions containing quaternary ammonium compounds as fabric care compounds, at higher perfume concentration (> 0.4% by weight of perfume in regular fabric softener compositions and ≥1% by weight in concentrated fabric softener compositions) a problem arises with the stability of the composition. In the case of the textile-care compositions according to the invention, relatively large amounts (≥1% by weight) of perfume can readily be incorporated.

In einer besonders bevorzugten Ausführungsform der Erfindung ist die Mischung aus der Textil-pflegenden Verbindung und dem Polysaccharid zumindest teilweise in die Umhüllung eingearbeitet. In dieser Ausführungsform sind die zuvor beschriebenen Vorteile (reduzierte bis nicht vorhandene Neigung zur Verklumpung bzw. Agglomerisation, Farbstabilität, Erhalt der kristalline Optik, verbessertes Fliessverhalten, etc.) besonders stark ausgeprägt.In a particularly preferred embodiment of the invention, the mixture of the textile-care compound and the polysaccharide is at least partially incorporated into the sheath. In this embodiment, the advantages described above (reduced to nonexistent tendency to clumping or agglomeration, color stability, retention of the crystalline appearance, improved flow behavior, etc.) are particularly pronounced.

In einer alternativen Ausführungsform ist die Umhüllung oder sind die Umhüllung und die nicht-umhüllten Bereiche des wasserlöslichen Trägers zumindest teilweise mit einer Mischung aus der Textil-pflegenden Verbindung und dem Polysaccharid beschichtet.In an alternative embodiment, the sheath or sheath and non-coated portions of the water-soluble carrier are at least partially coated with a mixture of the fabric care compound and the polysaccharide.

Die Erfindung betrifft auch die Verwendung einer erfindungsgemäßen festen, Textil-pflegenden Zusammensetzung zum Konditionieren von textilen Flächengebilden.The invention also relates to the use of a solid textile-care composition according to the invention for conditioning textile fabrics.

Außerdem betrifft die Erfindung ein Verfahren zur Herstellung einer festen, Textil-pflegende Zusammensetzung, umfassend einen partikulären wasserlöslichen Träger, ein wasserlösliches Polymer, eine Textil-pflegende Verbindung, ein Polysaccharid und ein Parfüm, bei dem das wasserlösliche Polymer geschmolzen wird, im geschmolzenen Zustand mit dem Parfüm gemischt wird, die erhaltene Schmelze derart auf den partikulären Träger gegeben wird, dass dieser zumindest teilweise umhüllt ist und anschließend in die noch geschmolzene Umhüllung eine Mischung aus der Textil-pflegenden Verbindung und dem Polysaccharid eingearbeitet wird.Furthermore, the invention relates to a process for producing a solid textile-care composition comprising a particulate water-soluble carrier, a water-soluble polymer, a fabric-care compound, a polysaccharide and a perfume in which the water-soluble polymer is melted in the molten state is mixed with the perfume, the resulting melt is added to the particulate carrier in such a way that it is at least partially enveloped and then incorporated into the still molten envelope a mixture of the fabric-care compound and the polysaccharide.

Die Erfindung betrifft auch ein Verfahren zur Herstellung einer festen, Textil-pflegende Zusammensetzung, umfassend einen partikulären wasserlöslichen Träger, ein wasserlösliches Polymer, eine Textil-pflegende Verbindung, ein Polysaccharid und ein Parfüm, bei dem das wasserlösliche Polymer geschmolzen wird, im geschmolzenen Zustand mit dem Parfüm gemischt wird, die erhaltene Schmelze derart auf den partikulären Träger gegeben wird, dass dieser zumindest teilweise umhüllt ist und der zumindest teilweise umhüllte partikuläre Träger mit einer Mischung aus der Textil-pflegenden Verbindung und dem Polysaccharid beschichtet wird.The invention also relates to a process for producing a solid textile-care composition comprising a particulate water-soluble carrier, a water-soluble polymer, a fabric-care compound, a polysaccharide and a perfume in which the water-soluble polymer is melted in the molten state the perfume is added, the resulting melt is added to the particulate carrier in such a way that it is at least partially enveloped and the at least partially coated particulate carrier is coated with a mixture of the fabric-care compound and the polysaccharide.

Ferner betrifft die Erfindung ein Wasch- oder Reinigungsmittel, umfassend eine erfindungsgemäße feste, Textil-pflegende Zusammensetzung.Furthermore, the invention relates to a washing or cleaning agent comprising a solid, textile-care composition according to the invention.

Durch das Einbringen der erfindungsgemäßen Textil-pflegenden Zusammensetzung in ein Wasch- oder Reinigungsmittel steht dem Verbraucher ein Textil-pflegendes Wasch- oder Reinigungsmittel ("2in1"-Wasch- oder Reinigungsmittel) zur Verfügung und er braucht nicht zwei Mittel zu dosieren. So steht beim Einbringen einer Textil-weichmachenden Zusammensetzung in ein Wasch- oder Reinigungsmittel dem Verbraucher dann ein Textil-weichmachendes Wasch- oder Reinigungsmittel ("2in1"-Wasch- oder Reinigungsmittel) zur Verfügung und er braucht nicht zwei Mittel (Wasch- oder Reinigungsmittel und Weichspüler) zu dosieren sowie keinen separaten Spülgang.By introducing the textile-care composition according to the invention into a washing or cleaning agent, the consumer is provided with a textile-care washing or cleaning agent ("2in1" washing or cleaning agent) and does not need to dose two agents. Thus, when a textile-softening composition is introduced into a washing or cleaning agent, the consumer is then provided with a fabric-softening washing or cleaning agent ("2in1" washing or cleaning agent) and does not need two detergents or cleaners Fabric softener) and no separate rinse.

Weiterhin müssen nicht das Wasch- oder Reinigungsmittel und die Textil-pflegende Zusammensetzung parfümiert werden, sondern nur noch eines der beiden Mittel, vorzugsweise die Textil-pflegende Zusammensetzung. Dies führt nicht nur zu geringeren Kosten, sondern ist auch für Verbraucher mit empfindlicher Haut und/oder Allergien vorteilhaft.Furthermore, it is not necessary to perfume the washing or cleaning agent and the textile-care composition, but only one of the two agents, preferably the textile-care composition. Not only does this result in lower costs, it is also beneficial for consumers with sensitive skin and / or allergies.

Im Folgenden soll die Erfindung unter anderem anhand von Beispielen eingehender beschrieben werden.In the following, the invention will be described in more detail, inter alia, by way of examples.

Die feste Textil-pflegende Zusammensetzung enthält als essentielle Bestandteile einen wasserlöslichen Träger, ein wasserlösliches Polymer, eine Textil-pflegende Verbindung, ein Polysaccharid und ein Parfüm.The solid textile care composition contains as essential ingredients a water-soluble carrier, a water-soluble polymer, a fabric-care compound, a polysaccharide and a perfume.

Ein essentieller Bestandteil der Textil-pflegenden Zusammensetzung ist der wasserlösliche Träger. Dieser umfasst bevorzugt anorganische Alkalimetallsalze wie beispielsweise Natriumchlorid, Kaliumchlorid, Natriumsulfat, Natriumcarbonat, Kaliumsulfat, Kaliumcarbonat, Natriumhydrogencarbonat, Kaliumhydrogencarbonat oder deren Mischungen, organische Alkalimetallsalze wie beispielsweise Natriumacetat, Kaliumacetat, Natriumcitrat, Natriumtartrat oder Kaliumnatriumtartrat, anorganische Erdalkalimetallsalze wie beispielsweise Calciumchlorid, Magnesiumsulfat oder Magnesiumchlorid, organische Erdalkalimetallsalze wie beispielsweise wie Calciumlactat, Kohlenhydrate, organische Säuren wie beispielsweise Citronensäure oder Weinsäure, Silikate wie beispielsweise Wasserglas, Natriumsilikat oder Kaliumsilikat, Harnstoff sowie Mischungen daraus. Der wasserlösliche Träger kann insbesondere ein Kohlenhydrat umfassen, welches beispielsweise ausgewählt ist aus der Gruppe bestehend aus Dextrose, Fructose, Galactose, Isoglucose, Glucose, Saccharose, Raffinose, Isomalt, Xylitol und Mischungen daraus. Das eingesetzte Kohlenhydrat kann beispielsweise Kandiszucker oder Hagelzucker sein.An essential component of the fabric care composition is the water-soluble carrier. This preferably includes inorganic alkali metal salts such as sodium chloride, potassium chloride, sodium sulfate, sodium carbonate, potassium sulfate, potassium carbonate, sodium bicarbonate, potassium bicarbonate or mixtures thereof, organic alkali metal salts such as sodium acetate, potassium acetate, sodium citrate, sodium tartrate or potassium sodium tartrate, inorganic alkaline earth metal salts such as calcium chloride, magnesium sulfate or magnesium chloride, organic alkaline earth metal salts such as calcium lactate, carbohydrates, organic acids such as citric acid or tartaric acid, silicates such as water glass, sodium silicate or potassium silicate, urea and mixtures thereof. In particular, the water-soluble carrier may comprise a carbohydrate selected, for example, from the group consisting of dextrose, fructose, galactose, isoglucose, glucose, sucrose, raffinose, isomalt, xylitol, and mixtures thereof. The carbohydrate used may be, for example, candy or hail sugar.

Kohlenhydrate als Träger haben den Vorteil, dass sie die Korrosion von metallischen Bauteilen in automatischen Waschmaschinen nicht begünstigen. Citronensäure als Träger hat den Vorteil, dass die Textil-pflegende Zusammensetzung gleichzeitig einen Gerüststoff zur Senkung der Wasserhärte aufweist.Carbohydrates as carriers have the advantage that they do not favor the corrosion of metallic components in automatic washing machines. Citric acid as a carrier has the advantage that the textile-care composition at the same time has a builder for lowering the water hardness.

Der wasserlösliche Träger kann auch Mischungen aus den genannten Materialien enthalten.The water-soluble carrier may also contain mixtures of said materials.

Es ist bevorzugt, dass der wasserlösliche Träger partikulär ist und Partikelgrößen im Bereich von 0,6 bis 30 mm, insbesondere 0,8 bis 7 mm und besonders bevorzugt 1 bis 3 mm, aufweist.It is preferred that the water-soluble carrier is particulate and has particle sizes in the range of 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm.

Unter einer Textil-pflegenden Verbindung wird in diesem Zusammenhang jede Verbindung verstanden, die damit behandelten textilen Flächengebilden einen vorteilhaften Effekt vermittelt, wie beispielsweise einen Textil-weichmachenden Effekt, Knitterfestigkeit bzw. die schädliche oder negative Effekte, die beim Reinigen und/oder Konditionieren und/oder Tragen auftreten können, wie beispielsweise Verblassen, Vergrauung, usw., reduziert.In this context, a textile care compound is understood to mean any compound which gives textile fabrics treated therewith a beneficial effect, such as, for example, a textile softening effect, crease resistance or the harmful or negative effects which result during cleaning and / or conditioning and / or or wearing, such as fading, graying, etc., reduced.

Die Textil-pflegende Verbindung kann beispielsweise eine Textil-weichmachende Verbindung, Bleichmittel, Bleichaktivatoren, Enzyme, Silikonöle, Antiredepositionsmittel, optische Aufheller, Vergrauungsinhibitoren, Einlaufverhinderer, Knitterschutzmittel, Farbübertragungsinhibitoren, antimikrobiellen Wirkstoffe, Germizide, Fungizide, Antioxidantien, Antistatika, Bügelhilfsmittel, Phobier- und Imprägniermittel, Quell- und Schiebefestmitteln, UV-Absorber sowie Mischungen daraus umfassen. Konkrete Beispiele für diese Textil-pflegenden Verbindungen finden sich bei der Beschreibung des erfindungsgemäßen Wasch- oder Reinigungsmittels und können auch in der festen, Textil-pflegenden Zusammensetzung verwendet werden.The fabric care composition may include, for example, a fabric softening compound, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, wrinkle inhibitors, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, antistatic agents, ironing aids, phobizers and the like Impregnating, swelling and slipping agents, UV absorbers and mixtures thereof. Concrete examples of these fabric-care compounds can be found in the description of the washing or cleaning agent of the invention and can also be used in the solid, textile-care composition.

Die Textil-pflegende Verbindung ist vorzugsweise eine Textil-weichmachende Verbindung und ist beispielsweise ein Polysiloxan, ein Textil-weichmachender Ton, ein kationisches Polymer oder eine Mischung aus wenigstens zwei dieser Textil-pflegenden Verbindungen. Dementsprechend ist die Textilpflegende Zusammensetzung vorzugsweise eine Textil-weichmachende Zusammensetzung.The fabric conditioning compound is preferably a fabric softening compound and is, for example, a polysiloxane, a fabric softening clay, a cationic polymer, or a blend of at least two of these fabric care compounds. Accordingly, the fabric care composition is preferably a fabric softening composition.

Ein bevorzugt einsetzbares Polysiloxan weist zumindest folgende Struktureinheit auf

Figure imgb0001
mit
R1= unabhängig von einander C1-C30-Alkyl, vorzugsweise C1-C4-Alkyl, insbesondere Methyl oder Ethyl,
n = 1 bis 5000, vorzugsweise 10 bis 2500, insbesondere 100 bis 1500.A preferably usable polysiloxane has at least the following structural unit
Figure imgb0001
 With
R 1 = independently of one another C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,
n = 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.

Es kann bevorzugt sein, dass das Polysiloxan zusätzlich auch folgende Struktureinheit aufweist:

Figure imgb0002
mit
R'= C1-C30-Alkyl, vorzugsweise C1-C4-Alkyl, insbesondere Methyl oder Ethyl,
Y = ggf. substituiertes, lineares oder verzweigtes C1-C20-Alkylen, vorzugsweise -(CH2)m- mit m= 1 bis 16, vorzugsweise 1 bis 8, insbesondere 2 bis 4, im speziellen 3,
R2, R3 = unabhängig voneinander H oder gegebenenfalls substituiertes, lineares oder verzweigtes C1-C30-Alkyl, vorzugsweise mit Aminogruppen substituiertes C1-C30-Alkyl, besonders bevorzugt -(CH2)b-NH2 mit b = 1 bis 10, äußerst bevorzugt b = 2,
x = 1 bis 5000, vorzugsweise 10 bis 2500, insbesondere 100 bis 1500.It may be preferred that the polysiloxane additionally has the following structural unit:
Figure imgb0002
 With
R '= C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,
Y = optionally substituted, linear or branched C 1 -C 20 -alkylene, preferably - (CH 2 ) m - where m = 1 to 16, preferably 1 to 8, in particular 2 to 4, in particular 3,
R 2 , R 3 = independently of one another are H or optionally substituted, linear or branched C 1 -C 30 -alkyl, preferably C 1 -C 30 -alkyl substituted by amino groups, more preferably - (CH 2 ) b -NH 2 where b = 1 to 10, most preferably b = 2,
x = 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.

Weist das Polysiloxan nur die Struktureinheit a) mit R1 = Methyl auf, handelt es sich um ein Polydimethylsiloxan. Polydimethylpolysiloxane sind als effiziente Textil-pflegende Verbindungen bekannt.If the polysiloxane has only the structural unit a) with R 1 = methyl, it is a polydimethylsiloxane. Polydimethylpolysiloxanes are known as efficient fabric care compounds.

Geeignete Polydimethysiloxane umfassen DC-200 (ex Dow Corning), Baysilone® M 50, Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 oder Baysilone® M 5000 (alle ex GE Bayer Silicones).Suitable polydimethysiloxanes include DC-200 (ex Dow Corning), Baysilone® M 50, Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 or Baysilone® M 5000 (all ex GE Bayer Silicones).

Es kann allerdings auch bevorzugt sein, dass das Polysiloxan die Struktureinheiten a) und b) enthält. Ein besonders bevorzugtes Polysiloxan weist die folgende Struktur auf:

        (CH3)3Si-[O-Si(CH3)2]n-[O-Si(CH3){(CH2)3-NH-(CH2)2-NH2}]x-OSi(CH3)3

wobei die Summe n + x eine Zahl zwischen 2 und 10.000 ist.However, it may also be preferred that the polysiloxane contains the structural units a) and b). A particularly preferred polysiloxane has the following structure:

(CH 3 ) 3 Si [O-Si (CH 3 ) 2 ] n - [O-Si (CH 3 ) {(CH 2 ) 3 -NH- (CH 2 ) 2 -NH 2 }] x -OSi ( CH 3 ) 3

where the sum n + x is a number between 2 and 10,000.

Geeignete Polysiloxane mit den Struktureinheiten a) und b) sind beispielsweise kommerziell unter den Markennamen DC2-8663, DC2-8035, DC2-8203, DC05-7022 oder DC2-8566 (alle ex Dow Corning) erhältlich. Erfindungsgemäß ebenfalls geeignet sind beispielsweise die im Handel erhältlichen Produkte Dow Corning® 7224, Dow Corning® 929 Cationic Emulsion oder Formasil 410 (GE Silicones).Suitable polysiloxanes having the structural units a) and b) are for example commercially available under the trade names DC2-8663, DC2-8035, DC2-8203, DC05-7022 or DC2-8566 (all ex Dow Corning). According to the invention are also suitable for example the products commercially available Dow Corning ® 7224, Dow Corning ® 929 Cationic Emulsion or Formasil 410 (GE Silicones).

Ein geeigneter Textil-weichmachender Ton ist beispielsweise ein Smectit-Ton. Bevorzugte Smectit-Tone sind Beidellit-Tone, Hectorit-Tone, Laponit-Tone, Montmorillonit-Tone, Nontronit-Tone, Saponit-Tone, Sauconit-Tone und Mischungen daraus. Montmorillonit-Tone sind die bevorzugten weichmachenden Tone. Bentonite enthalten hauptsächlich Montmorillonite und können als bevorzugte Quelle für den Textil-weichmachenden Ton dienen. Die Bentonite können als Pulver oder Kristalle eingesetzt werden.A suitable fabric softening clay is, for example, a smectite clay. Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontronite clays, saponite clays, sauconite clays, and mixtures thereof. Montmorillonite clays are the preferred softening clays. Bentonites contain mainly montmorillonites and can serve as a preferred source of fabric softening clay. The bentonites can be used as powder or crystals.

Geeignete Bentonite werden beispielsweise unter den Bezeichnungen Laundrosil® von der Firma Süd-Chemie oder unter der Bezeichnung Detercal von der Firma Laviosa vertrieben. Es ist bevorzugt, dass die Textil-pflegende Zusammensetzung einen pulverförmigen Bentonit als Textil-pflegende Verbindung enthält.Suitable bentonites are sold, for example, under the names Laundrosil® by Süd-Chemie or under the name Detercal by Laviosa. It is preferable that the textile-care composition contains a powdery bentonite as a fabric-care compound.

Geeignete kationische Polymere umfassen insbesondere solche, die in " CTFA International Cosmetic Ingredient Dictionary", Fourth Edition, J. M. Nikitakis, et al, Editors, veröffentlicht durch die Cosmetic, Toiletry, and Fragrance Association, 1991 beschrieben sind und unter der Sammelbezeichnung "Polyquaternium" zusammengefasst sind. Im Folgenden sind einige geeignete Polyquaternium-Verbindungen genauer aufgeführt.

  • POLYQUATERNIUM-1 (CAS-Nummer: 68518-54-7)
    Definition: {(HOCH2CH2)3N+-CH2CH=CHCH2-[N+(CH3)2-CH2CH=CHCH2]x-N+(CH2CH2OH)3}[Cl-]x+2
  • POLYQUATERNIUM-2 (CAS-Nummer: 63451-27-4)
    Definition: [-N(CH3)2-CH2CH2CH2-NH-C(O)-NH-CH2CH2CH2-N(CH3)2-CH2CH2OCH2CH2-]2+(Cl-)2
  • POLYQUATERNIUM-3
    Definition: Copolymer von Acrylamid und Trimethylammoniumethylmethacrylatmethosulfat
  • POLYQUATERNIUM-4 (CAS-Nummer: 92183-41-0)
    Definition: Copolymer von Hydroxyethylcellulose und Diallyldimethylammoniumchlorid
    Beispielsweise erhältlich als Celquat® H 100 oder Celquat® L200 (ex National Starch)
  • POLYQUATERNIUM-5 (CAS-Nummer: 26006-22-4)
    Definition: Copolymer von Acrylamid und β-Methacrylyloxyethyltrimethylammoniummethosulfat.
  • POLYQUATERNIUM-6 (CAS-Nummer: 26062-79-3)
    Definition: Polymer von Dimethyldiallylammoniumchlorid
  • POLYOUATERNIUM-7 (CAS-Nummer: 26590-05-6)
    Definition: Polymeres quaternäres Ammoniumsalz bestehend aus Acrylamid- und Dimethyldiallylammoniumchlorid-Monomeren.
  • POLYQUATERNIUM-8
    Definition: Polymeres quaternäres Ammoniumsalz von Methyl- und Stearyldimethylaminoethylmethacrylat, welches mit Dimethylsulfat quaternierte wurde
  • POLYQUATERNIUM-9
    Definition: Polymeres quaternäres Ammoniumsalz von Polydimethylaminoethylmethacrylat, welches mit Methylbromid quaternierte wurde
  • POLYQUATERNIUM-11 (CAS-Nummer: 53633-54-8)
    Definition: Quaternäres Ammoniumpolymer, welches durch Umsetzung von Diethylsulfat mit dem Copolymer von Vinylpyrrolidon und Dimethylaminoethylmethacrylat gebildet wird.
  • POLYQUATERNIUM-12 (CAS-Nummer: 68877-50-9)
    Definition: Quaternäres Ammoniumpolymersalz, welches durch Umsetzung des Ethylmethacrylat/Abietylmethacrylat/Diethylaminoethylmethacrylat-Copolymers mit Dimethylsulfat erhältlich ist
  • POLYQUATERNIUM-13 (CAS Nummer: 68877-47-4)
    Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung des Ethylmethacrylat/- Oleylmethacrylat/Diethylaminoethylmethacrylat-Copolymers mit Dimethylsulfat erhältlich ist
  • POLYQUATERNIUM-14 (CAS-Nummer: 27103-90-8)
    Definition: Polymeres quaternäres Ammoniumsalz der Formel -{-CH2-C-(CH3)-[C(O)O-CH2CH2-N(CH3)3 -]}x +[CH3SO4]- x
  • POLYQUATERNIUM-15 (CAS-Nummer: 35429-19-7)
    Definition: Copolymer von Acrylamid und β-Methacrylyloxyethyltrimethylammoniumchlorid
  • POLYQUATERNIUM-16 (CAS-Nummer: 95144-24-4)
    Definition: Polymeres quaternäres Ammoniumsalz, gebildet aus Methylvinylimidazoliumchlorid und Vinylpyrrolidon
  • POLYQUATERNIUM-17 (CAS-Nummer: 90624-75-2)
    Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung von Adipinsäure und Dimethylaminopropylamin mit Dichlorethylether erhältlich ist.
  • POLYQUATERNIUM-18
    Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung von Azelainsäure und Dimethylaminopropylamin mit Dichlorethylether erhältlich ist.
  • POLYQUATERNIUM-19
    Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung von Polyvinylalkohol mit 2,3-Epoxypropylamin erhältlich ist.
  • POLYQUATERNIUM-20
    Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung von Polyvinyloctadecylether mit 2,3-Epoxypropylamin erhältlich ist.
  • POLYQUATERNIUM-21 (CAS-Nummer: 102523-94-4)
    Definition: Polysiloxan/Polydimethyldialkylammoniumacetat-Copolymer
  • POLYQUATERNIUM-22 (CAS-Nummer: 53694-17-0)
    Definition: Dimethyldiallylammoniumchlorid/Acrylsäure-Copolymer
  • POLYQUATERNIUM-24 (CAS-Nummer: 107987-23-5)
    Definition: Polymeres quaternäres Ammoniumsalz aus der Umsetzung von Hydroxyethylcellulose mit einem mit Lauryldimethylammonium substituierten-Epoxid
  • POLYQUATERNIUM-27
    Definition: Blockcopolymer aus der Umsetzung von Polyquaternium-2 mit Polyquaternium-17.
  • POLYQUATERNIUM-28 (CAS-Nummer: 131954-48-8)
    Definition: Vinylpyrrolidon/Methacrylamidopropyltrimethylammoniumchlorid-Copolymer
  • POLYQUATERNIUM-29
    Definition: Chitosan, welches mit Propylenoxid umgesetzt und mit Epichlorhydrin quaternisiert wurde
  • POLYQUATERNIUM-30
    Definition: Polymeres quaternäres Ammoniumsalz der Formel: -[CH2C(CH3)(C(O)OCH3)]x-[CH2C(CH3)(C(O) OCH2CH2N+(CH3)2CH2COO-)]y-
  • POLYQUATERNIUM-31 (CAS-Nummer. 136505-02-7)
  • POLYQUATERNIUM-32 (CAS-Nummer: 35429-19-7)
    Definition: Polymer von N,N,N-Trimethyl-2-[(2-methyl-1-oxo-2-propenyl)oxy]-ethanaminiumchlorid mit 2-Propenamid
  • POLYQUATERNIUM-37 (CAS-Nummer: 26161-33-1)
    Definition: Homopolymer von Methacryloyltrimethylchlorid
    Beispielsweise erhältlich als Synthalen® CR (ex 3V Sigma)
  • POLYQUATERNIUM-44 (CAS-Nummer: 150595-70-5)
    Definition: Quaternäres Ammoniumsalz des Copolymers von Vinylpyrrolidon und quaternisiertem Imidazolin
  • POLYQUATERNIUM-68 (CAS-Nummer: 827346-45-2)
    Definition: Quaternisiertes Copolymer von Vinylpyrrolidon, Methacrylamid, Vinylimidazol und quatemisiertem Vinylimidazol
Suitable cationic polymers include in particular those described in " CTFA International Cosmetic Ingredient Dictionary, Fourth Edition, JM Nikitakis, et al, Editors, published by the Cosmetic, Toiletry, and Fragrance Association, 1991 are described and summarized under the collective name "Polyquaternium". In the following, some suitable polyquaternium compounds are listed in more detail.
  • POLYQUATERNIUM-1 (CAS number: 68518-54-7)
    Definition: {(HOCH 2 CH 2 ) 3 N + -CH 2 CH = CHCH 2 - [N + (CH 3 ) 2 -CH 2 CH = CHCH 2 ] x -N + (CH 2 CH 2 OH) 3 } [ Cl - ] x + 2
  • POLYQUATERNIUM-2 (CAS number: 63451-27-4)
    Definition: [-N (CH 3 ) 2 -CH 2 CH 2 CH 2 -NH-C (O) -NH-CH 2 CH 2 CH 2 -N (CH 3 ) 2 -CH 2 CH 2 OCH 2 CH 2 - ] 2+ (Cl - ) 2
  • Polyquaternium-3
    Definition: copolymer of acrylamide and trimethylammoniumethyl methacrylate methosulfate
  • POLYQUATERNIUM-4 (CAS number: 92183-41-0)
    Definition: Copolymer of hydroxyethylcellulose and diallyldimethylammonium chloride
    For example, available as Celquat® H 100 or Celquat® L200 (ex National Starch)
  • POLYQUATERNIUM-5 (CAS number: 26006-22-4)
    Definition: Copolymer of acrylamide and β-methacrylyloxyethyltrimethylammonium methosulfate.
  • POLYQUATERNIUM-6 (CAS number: 26062-79-3)
    Definition: Polymer of dimethyldiallylammonium chloride
  • POLYOUATERNIUM-7 (CAS number: 26590-05-6)
    Definition: Polymeric quaternary ammonium salt consisting of acrylamide and dimethyldiallylammonium chloride monomers.
  • Polyquaternium-8
    Definition: Polymeric quaternary ammonium salt of methyl and stearyldimethylaminoethyl methacrylate quaternized with dimethyl sulfate
  • Polyquaternium-9
    Definition: Polymeric quaternary ammonium salt of polydimethylaminoethyl methacrylate quaternized with methyl bromide
  • POLYQUATERNIUM-11 (CAS number: 53633-54-8)
    Definition: Quaternary ammonium polymer formed by reaction of diethyl sulfate with the copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate.
  • POLYQUATERNIUM-12 (CAS number: 68877-50-9)
    Definition: Quaternary ammonium polymer salt obtainable by reacting the ethyl methacrylate / abietyl methacrylate / diethylaminoethyl methacrylate copolymer with dimethyl sulfate
  • POLYQUATERNIUM-13 (CAS number: 68877-47-4)
    Definition: Polymeric quaternary ammonium salt obtainable by reaction of the ethyl methacrylate / oleyl methacrylate / diethylaminoethyl methacrylate copolymer with dimethyl sulfate
  • POLYQUATERNIUM-14 (CAS number: 27103-90-8)
    Definition: Polymeric quaternary ammonium salt of the formula - {- CH 2 -C- (CH 3 ) - [C (O) O-CH 2 CH 2 -N (CH 3 ) 3 - ]} x + [CH 3 SO 4 ] - x
  • POLYQUATERNIUM-15 (CAS number: 35429-19-7)
    Definition: copolymer of acrylamide and β-methacrylyloxyethyltrimethylammonium chloride
  • POLYQUATERNIUM-16 (CAS number: 95144-24-4)
    Definition: Polymeric quaternary ammonium salt formed from methylvinylimidazolium chloride and vinylpyrrolidone
  • POLYQUATERNIUM-17 (CAS number: 90624-75-2)
    Definition: Polymeric quaternary ammonium salt obtainable by reaction of adipic acid and dimethylaminopropylamine with dichloroethyl ether.
  • Polyquaternium-18
    Definition: Polymeric quaternary ammonium salt, which is obtainable by reaction of azelaic acid and dimethylaminopropylamine with dichloroethyl ether.
  • Polyquaternium-19
    Definition: Polymeric quaternary ammonium salt, which is obtainable by reaction of polyvinyl alcohol with 2,3-epoxypropylamine.
  • Polyquaternium-20
    Definition: Polymeric quaternary ammonium salt, obtainable by reaction of polyvinyloctadecyl ether with 2,3-epoxypropylamine.
  • POLYQUATERNIUM-21 (CAS number: 102523-94-4)
    Definition: polysiloxane / polydimethyldialkylammonium acetate copolymer
  • POLYQUATERNIUM-22 (CAS number: 53694-17-0)
    Definition: dimethyldiallylammonium chloride / acrylic acid copolymer
  • POLYQUATERNIUM-24 (CAS number: 107987-23-5)
    Definition: Polymeric quaternary ammonium salt from the reaction of hydroxyethylcellulose with a lauryldimethylammonium substituted epoxide
  • Polyquaternium-27
    Definition: Block copolymer from the reaction of Polyquaternium-2 with Polyquaternium-17.
  • POLYQUATERNIUM-28 (CAS number: 131954-48-8)
    Definition: Vinylpyrrolidone / methacrylamidopropyltrimethylammonium chloride copolymer
  • Polyquaternium-29
    Definition: Chitosan, which was reacted with propylene oxide and quaternized with epichlorohydrin
  • Polyquaternium-30
    Definition: Polymeric quaternary ammonium salt of the formula: - [CH 2 C (CH 3 ) (C (O) OCH 3 )] x - [CH 2 C (CH 3 ) (C (O) OCH 2 CH 2 N + (CH 3 ) 2 CH 2 COO - )] y -
  • POLYQUATERNIUM-31 (CAS number: 136505-02-7)
  • POLYQUATERNIUM-32 (CAS number: 35429-19-7)
    Definition: Polymer of N, N, N-trimethyl-2 - [(2-methyl-1-oxo-2-propenyl) oxy] -ethanaminium chloride with 2-propenamide
  • POLYQUATERNIUM-37 (CAS number: 26161-33-1)
    Definition: homopolymer of methacryloyltrimethyl chloride
    For example, available as Synthalen® CR (ex 3V Sigma)
  • POLYQUATERNIUM-44 (CAS number: 150595-70-5)
    Definition: Quaternary ammonium salt of the copolymer of vinylpyrrolidone and quaternized imidazoline
  • POLYQUATERNIUM-68 (CAS-Number: 827346-45-2)
    Definition: Quaternized copolymer of vinylpyrrolidone, methacrylamide, vinylimidazole and quaternized vinylimidazole

Es kann bevorzugt sein, dass die Textil-pflegende Zusammensetzung eine Textil-weichmachende Verbindung und eine oder mehr weitere Textil-pflegende Verbindung(en) enthält.It may be preferred that the fabric care composition contains a fabric softening compound and one or more other fabric care compounds.

Die Menge an Textil-pflegender Verbindung in der Textil-pflegenden Zusammensetzung beträgt 0,1 bis 15 Gew.% und bevorzugt zwischen 2 und 12 Gew.%.The amount of fabric care compound in the fabric care composition is 0.1 to 15 weight percent and preferably between 2 and 12 weight percent.

Ein weiterer Bestandteil der Textil-pflegenden Zusammensetzung ist das wasserlösliche Polymer. Geeignete wasserlösliche Polymere weisen vorzugsweise einen Schmelz- oder Erweichungspunkt im Bereich von 48°C bis 300°C auf und können Polyalkylenglykole, insbesondere Polyethylenglykole, und/oder Polyvinylalkohole umfassen. Insbesondere bevorzugt weisen die wasserlöslichen Polymere ein Schmelz- oder Erweichungspunkt im Bereich von 48°C bis 120°C auf.Another ingredient of the fabric care composition is the water-soluble polymer. Suitable water-soluble polymers preferably have a melting or softening point in the range of 48 ° C to 300 ° C and may include polyalkylene glycols, especially polyethylene glycols, and / or polyvinyl alcohols. Most preferably, the water-soluble polymers have a melting or softening point in the range of 48 ° C to 120 ° C.

Mit Schmelzpunkt ist der Übergang von einem festen Zustand in einen flüssigen (frei fließenden) Zustand gemeint. Die Erweichungstemperatur beschreibt den Übergang von einem festen Zustand in eine gummiartige bis zähflüssige Schmelze. Der Schmelz- und die Erweichungstemperatur können jeweils entweder eine bestimmte Temperatur oder ein kleinerer Bereich innerhalb des Bereichs von 48°C bis 300°C sein.By melting point is meant the transition from a solid state to a liquid (free flowing) state. The softening temperature describes the transition from a solid state to a rubbery to viscous melt. The melting and softening temperatures may each be either a certain temperature or a smaller range within the range of 48 ° C to 300 ° C.

Geeignete Polyalkylenglykole umfassen insbesondere Polyethylenglykole, die je nach Kettenlänge flüssige oder feste Polymere sind. Ab einem Molekulargewicht von 3000 sind die Polyethylenglykole feste Substanzen und werden als Schuppen oder Pulver in den Handel gebracht. Härte und Schmelzbereich steigen mit zunehmendem Molekulargewicht an. Bevorzugt für die vorliegende Erfindung sind Polyethylenglykole mit einem mittleren Molekulargewicht zwischen 3.000 und 12.000, mehr bevorzugt mit einem mittleren Molekulargewicht zwischen 4.000 und 10.000 und insbesondere bevorzugt mit einem mittleren Molekulargewicht zwischen 6.000 und 8.000.Suitable polyalkylene glycols include in particular polyethylene glycols, which are liquid or solid polymers depending on the chain length. From a molecular weight of 3000, the polyethylene glycols are solid substances and are sold as flakes or powders. Hardness and melting range increase with increasing molecular weight. Preferred for the present invention are polyethylene glycols having an average molecular weight between 3,000 and 12,000, more preferably having an average molecular weight between 4,000 and 10,000, and most preferably having an average molecular weight between 6,000 and 8,000.

Polyvinylalkohole sind als weiß-gelbliche Pulver oder Granulate mit Polymerisationsgraden im Bereich von ca. 500-2500 (Molmassen von ca. 20.000 - 100.000 g/mol) im Handel erhältlich. Der Hydrolysegrad beträgt von 98-99 bzw. 87-89 Mol-% und somit enthalten die Polyvinylalkohole noch einen Restgehalt an Acetyl-Gruppen. Charakterisiert werden die Polyvinylalkohole von Seiten der Hersteller durch Angabe des Polymerisationsgrades des Ausgangspolymeren, des Hydrolysegrades und/oder der Verseifungszahl. Vollverseifte Polyvinylalkohole haben eine Erweichungstemperatur von 85 °C und einen Schmelzpunkt von 228 °C. Die entsprechenden Werte für teilverseifte (87-89%) Produkte liegen mit ca. 58 °C (Erweichungspunkt) bzw. 186 °C (Schmelzpunkt) deutlich niedriger.Polyvinyl alcohols are commercially available as white-yellowish powders or granules with degrees of polymerization in the range of about 500-2500 (molar masses of about 20,000 - 100,000 g / mol). The degree of hydrolysis is 98-99 or 87-89 mol% and thus the polyvinyl alcohols still contain a residual content of acetyl groups. The polyvinyl alcohols are characterized by the manufacturer by indicating the degree of polymerization of the starting polymer, the degree of hydrolysis and / or the saponification number. Fully saponified polyvinyl alcohols have a softening temperature of 85 ° C and a melting point of 228 ° C. The corresponding values for partially hydrolyzed (87-89%) products are significantly lower at approx. 58 ° C (softening point) or 186 ° C (melting point).

Das wasserlösliche Polymer kann auch eine Mischung aus den genannten Materialien enthalten. Es ist allerdings bevorzugt, dass die Textil-pflegende Zusammensetzung ein Polyalkylenglykol und insbesondere ein Polyethylenglykol als wasserlösliches Polymer umfasst.The water-soluble polymer may also contain a mixture of said materials. However, it is preferred that the textile care composition comprises a polyalkylene glycol and in particular a polyethylene glycol as the water-soluble polymer.

Ein weiterer essentieller Bestandteil der Textil-pflegenden Zusammensetzung ist das Parfüm. Als Parfümöle bzw. Duftstoffe können einzelne Riechstoffverbindungen, z.B. die synthetischen Produkte vom Typ der Ester, Ether, Aldehyde, Ketone, Alkohole und Kohlenwasserstoffe verwendet werden. Bevorzugt werden jedoch Mischungen verschiedener Riechstoffe verwendet, die gemeinsam eine ansprechende Duftnote erzeugen. Solche Parfümöle können auch natürliche Riechstoffgemische enthalten, wie sie aus pflanzlichen Quellen zugänglich sind.Another essential ingredient of the textile-care composition is the perfume. As perfume oils or fragrances, individual fragrance compounds, e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type are used. Preferably, however, mixtures of different fragrances are used, which together produce an attractive fragrance. Such perfume oils may also contain natural fragrance mixtures as are available from plant sources.

Die Menge an Parfüm in der Textil-pflegenden Zusammensetzung beträgt dabei vorzugsweise zwischen 0,1 und 15 Gew.-%, insbesondere bevorzugt zwischen 0,5 und 10 Gew.-% und ganz besonders bevorzugt zwischen 1 und 7 Gew.-%.The amount of perfume in the textile-care composition is preferably between 0.1 and 15 wt .-%, particularly preferably between 0.5 and 10 wt .-% and most preferably between 1 and 7 wt .-%.

In einer alternativen Ausführungsform kann es bevorzugt sein, dass zumindest ein Teil des Parfüms in verkapselter Form, insbesondere in Mikrokapseln, in der Umhüllung eingesetzt wird. Bei den Mikrokapseln kann es sich um wasserlösliche und/oder wasserunlösliche Mikrokapseln handeln. Es können beispielsweise Melamin-Harnstoff-Formaldehyd-Mikrokapseln, Melamin-Formaldehyd-Mikrokapseln, Harnstoff-Formaldehyd-Mikrokapseln oder Stärke-Mikrokapseln eingesetzt werden.In an alternative embodiment, it may be preferred that at least a portion of the perfume is used in encapsulated form, especially in microcapsules, in the wrapper. The microcapsules may be water-soluble and / or water-insoluble microcapsules. For example, melamine-urea-formaldehyde microcapsules, melamine-formaldehyde microcapsules, urea-formaldehyde microcapsules, or starch microcapsules can be used.

Weiterhin enthält die Textil-pflegende Zusammensetzung als essentiellen Inhaltsstoff ein Polysaccharid. Geeignete Polysaccharide umfassen beispielsweise Glycogen, Stärke, Chitin, Callose, Cellulose, Dextran, Tunicin, Inulin, Alginsäure, Xanthan, Gellan, Guar, Johannisbrotkernmehl, Carrageenan, Derivate dieser Verbindungen oder Mischungen dieser Verbindungen sowie deren Derivate.Furthermore, the textile-care composition contains as essential ingredient a polysaccharide. Suitable polysaccharides include, for example, glycogen, starch, chitin, callose, cellulose, dextran, tunicin, inulin, alginic acid, xanthan, gellan, guar, locust bean gum, carrageenan, derivatives of these compounds or mixtures of these compounds and derivatives thereof.

Es ist bevorzugt, dass das Polysaccharid Cellulose oder ein Cellulosederivat umfasst. Es ist insbesondere Bevorzugt, dass das Polysaccharid ein Cellulosederivat umfasst. Geeignete Cellulosederivate umfassen beispielsweise Methylcellulose, Ethylcellulose, Propylcellulose, Methylethylcellulose, Carboxymethylcellulose, Ethylcarboxymethylcellulose, Hydroxyethylcellulose, Hydroxypropylcellulose, Carboxymethylhydroxyethylcellulose, Methylhydroxypropylcellulose, Methylhydroxyethylcellulose Hydroxypropylmethylcellulose, Ethylhydroxyethylcellulose, Methylethylhydroxyethylcellulose, quaternisierte Cellulose, quaternisierte Cellulosederivate, Amin-modifizierte Cellulose, Amin-modifizierte Cellulosederivate oder Mischungen dieser Verbindungen. Geeignete Methylhydroxypropylcellulosen sind beispielsweise unter den Bezeichnungen Methocel© J 40 MS oder Methocel© J 5 S (beide ex Dow Chemical) erhältlich. Hydroxyethylcellulosen, die in der vorliegenden Erfindung eingesetzt werden können, umfassen beispielsweise Cellosize© HEC QP (ex Dow Chemical). Geeignete Methylcellulosen umfassen zum Beispiel Methocel© A (ex Dow Chemical). Geeignete kationische Cellulosederivate sind beispielsweise die Polyquaternium-10-Verbindungen Celquat® SC-240 (ex National Starch) oder UCARE® Polymer JR-125, UCARE® Polymer JR-400, UCARE® Polymer JR-30M, UCARE® Polymer LR 400, UCARE® Polymer LR 30M und Ucare® Polymer SR-10 (alle ex Amerchol). Als Carboxymethylcellulose kann beispielsweise Finnfix BDA (ex Kelco) eingesetzt werden.It is preferred that the polysaccharide comprises cellulose or a cellulose derivative. It is particularly preferred that the polysaccharide comprises a cellulose derivative. Suitable cellulose derivatives include, for example, methylcellulose, ethylcellulose, propylcellulose, Methylethylcellulose, carboxymethylcellulose, ethylcarboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylhydroxyethylcellulose, methylhydroxypropylcellulose, methylhydroxyethylcellulose hydroxypropylmethylcellulose, ethylhydroxyethylcellulose, methylethylhydroxyethylcellulose, quaternized cellulose, quaternized cellulose derivatives, amine-modified cellulose, amine-modified cellulose derivatives or mixtures of these compounds. Suitable methylhydroxypropylcelluloses are available, for example, under the names Methocel® J 40 MS or Methocel® J 5 S (both ex Dow Chemical). Hydroxyethyl celluloses which can be used in the present invention include, for example, Cellosize® HEC QP (ex Dow Chemical). Suitable methylcelluloses include, for example, Methocel® A (ex Dow Chemical). Examples of suitable cationic cellulose derivatives are the Polyquaternium 10 compounds Celquat® SC-240 (ex National Starch) or UCARE® Polymer JR-125, UCARE® Polymer JR-400, UCARE® Polymer JR-30M, UCARE® Polymer LR 400, UCARE ® Polymer LR 30M and Ucare® Polymer SR-10 (all ex Amerchol). For example, Finnfix BDA (ex Kelco) can be used as the carboxymethylcellulose.

Dabei ist es weiterhin bevorzugt, dass die Cellulose und/oder Cellulosederivate in Pulverform eingesetzt werden.It is further preferred that the cellulose and / or cellulose derivatives are used in powder form.

In der Mischung beträgt das Verhältnis Textilpflegende-Verbindung zu Polysaccharid vorzugsweise zwischen 15 : 1 und 1 : 5, mehr bevorzugt zwischen 12 : 1 und 1 : 1 und insbesondere bevorzugt zwischen 9 : 1 und 4 : 1.In the mixture, the ratio of fabric care compound to polysaccharide is preferably between 15: 1 and 1: 5, more preferably between 12: 1 and 1: 1, and most preferably between 9: 1 and 4: 1.

Die Textil-pflegende Zusammensetzung kann optional weitere Inhaltsstoffe enthalten.The fabric care composition may optionally contain other ingredients.

Um den ästhetischen Eindruck der Textil-pflegenden Zusammensetzung zu verbessern, können sie mit geeigneten Farbstoffen eingefärbt werden. Bevorzugte Farbstoffe, deren Auswahl dem Fachmann keinerlei Schwierigkeit bereitet, sollten eine hohe Lagerstabilität und Unempfindlichkeit gegenüber den übrigen Inhaltsstoffen der Wasch- oder Reinigungsmittel und gegen Licht sowie keine ausgeprägte Substantivität gegenüber Textilfasern, um diese nicht anzufärben.In order to improve the aesthetic impression of the textile-care composition, they can be dyed with suitable dyes. Preferred dyestuffs, the selection of which presents no difficulty to a person skilled in the art, should have a high storage stability and insensitivity to the other ingredients of the detergents or to light and no pronounced substantivity to textile fibers in order not to stain them.

Weiterhin kann die Textil-pflegende Zusammensetzung einen Füllstoff, wie Silica, enthalten. Die Menge an Füllstoff kann zwischen 0,1 und 10 Gew.-% betragen und beträgt bevorzugt 1 bis 5 Gew.-%.Further, the fabric care composition may contain a filler such as silica. The amount of filler may be between 0.1 and 10 wt .-% and is preferably 1 to 5 wt .-%.

Die Textil-pflegende Zusammensetzung kann zur Erhöhung des Glanzes auch ein Perlglanzmittel enthalten. Beispiele für geeignete Perlglanzmittel sind Ethylenglykolmono- und -distearat (zum Beispiel Cutina®AGS von Cognis) sowie PEG-3-distearat.The fabric care composition may also contain a pearlescer to increase gloss. Examples of suitable pearlescing agents are ethylene glycol mono- and distearate (for example Cutina®AGS from Cognis) and PEG-3-distearate.

Weiterhin kann die Textil-pflegende Zusammensetzung eine hautpflegende Verbindung umfassen.Furthermore, the fabric care composition may comprise a skin care compound.

Unter einer hautpflegenden Verbindung wird eine Verbindung oder eine Mischung aus Verbindungen verstanden, die bei Kontakt eines Textils mit dem Waschmittel auf das Textil aufziehen und bei Kontakt des Textils mit Haut der Haut einen Vorteil verleihen verglichen mit einem Textil, welches nicht mit dem erfindungemäßen Wasch- und Reinigungsmittel behandelt wurde. Dieser Vorteil kann beispielsweise den Transfer der hautpflegenden Verbindung vom Textil auf die Haut, einen geringeren Wassertransfer von der Haut auf das Textil oder eine geringere Reibung auf der Hautoberfläche durch das Textil umfassen.A skin-care compound is understood as meaning a compound or a mixture of compounds which, upon contact of a textile with the detergent, are applied to the textile and on contact give the textile with skin an advantage on the skin compared to a textile which has not been treated with the detergent and cleaning agent according to the invention. This benefit may include, for example, the transfer of the skin care compound from the textile to the skin, less water transfer from the skin to the textile, or less friction on the skin surface through the textile.

Die hautpflegende Verbindung ist vorzugsweise hydrophob, kann flüssig oder fest sein und muss kompatibel mit den anderen Inhaltsstoffen der festen, Textil-pflegenden Zusammensetzung sein. Die hautpflegende Verbindung kann beispielsweise

  1. a) Wachse wie Carnauba, Spermaceti, Bienenwachs, Lanolin, Derivate davon sowie Mischungen daraus;
  2. b) Pflanzenextrakte, zum Beispiel pflanzliche Öle wie Avokadoöl, Olivenöl, Palmöl, Palmenkernöl, Rapsöl, Leinöl, Sojaöl, Erdnussöl, Korianderöl, Ricinusöl, Mohnöl, Kakaoöl, Kokosnussöl, Kürbiskernöl, Weizenkeimöl, Sesamöl, Sonnenblumenöl, Mandelöl, Macadamianussöl, Aprikosenkernöl, Haselnussöl, Jojobaöl oder Canolaöl, Kamille, Aloe Vera sowie Mischungen daraus;
  3. c) höhere Fettsäuren wie Laurinsäure, Myristinsäure, Palmitinsäure, Stearinsäure, Behensäure, Ölsäure, Linolsäure, Linolensäure, Isostearinsäure oder mehrfach ungesättigte Fettsäuren;
  4. d) höhere Fettalkohole wie Laurylalkohol, Cetylalkohol, Stearylalkohol, Oleylalkohol, Behenylalkohol oder 2-Hexadecanol,
  5. e) Ester wie Cetyloctanoat, Lauryllactat, Myristyllactat, Cetyllactat, Isopropylmyristat, Myristylmyristat, Isopropylpalmitat, Isopropyladipat, Butylstearat, Decyloleat, Cholesterolisostearat, Glycerolmonostearat, Glyceroldistearat, Glyceroltristearat, Alkyllactat, Alkylcitrat oder Alkyltartrat;
  6. f) Kohlenwasserstoffe wie Paraffine, Mineralöle, Squalan oder Squalen;
  7. g) Lipide;
  8. h) Vitamine wie Vitamin A, C oder E oder Vitaminalkylester;
  9. i) Phospholipide;
  10. j) Sonnenschutzmittel wie Octylmethoxylcinnamat und Butylmethoxybenzoylmethan;
  11. k) Silikonöle wie lineare oder cyclische Polydimethylsiloxane, Amino-, Alkyl-, Alkylaryl- oder Arylsubstituierte Silikonöle und
  12. l) Mischungen daraus
umfassen.The skin care composition is preferably hydrophobic, may be liquid or solid, and must be compatible with the other ingredients of the solid, fabric care composition. For example, the skin care compound
  1. a) waxes such as carnauba, spermaceti, beeswax, lanolin, derivatives thereof and mixtures thereof;
  2. b) Plant extracts, for example vegetable oils such as avocado oil, olive oil, palm oil, palm kernel oil, rapeseed oil, linseed oil, soybean oil, peanut oil, coriander oil, castor oil, poppy seed oil, cocoa oil, coconut oil, pumpkin seed oil, wheat germ oil, sesame oil, sunflower oil, almond oil, macadamia nut oil, apricot kernel oil, hazelnut oil , Jojoba oil or canola oil, chamomile, aloe vera and mixtures thereof;
  3. c) higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid or polyunsaturated fatty acids;
  4. d) higher fatty alcohols, such as lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, behenyl alcohol or 2-hexadecanol,
  5. e) esters such as cetyloctanoate, lauryl lactate, myristyl lactate, cetyl lactate, isopropyl myristate, myristyl myristate, isopropyl palmitate, isopropyl adipate, butyl stearate, decyl oleate, cholesterol isostearate, glycerol monostearate, glyceryl distearate, glycerol tristearate, alkyl lactate, alkyl citrate or alkyl tartrate;
  6. f) hydrocarbons such as paraffins, mineral oils, squalane or squalene;
  7. g) lipids;
  8. h) vitamins such as vitamins A, C or E or vitamin alkyl esters;
  9. i) phospholipids;
  10. j) sunscreens such as octyl methoxyl cinnamate and butyl methoxybenzoyl methane;
  11. k) silicone oils such as linear or cyclic polydimethylsiloxanes, amino-, alkyl-, alkylaryl- or aryl-substituted silicone oils and
  12. l) mixtures thereof
include.

Die Menge an hautpflegender Verbindung beträgt vorzugsweise zwischen 0,01 und 10 Gew.-%, vorzugsweise zwischen 0,1 und 5 Gew.-% und ganz besonders bevorzugt zwischen 0,3 und 3 Gew.-% bezogen auf die feste, Textil-pflegende Zusammensetzung. Es kann sein, dass die Haut-pflegende Verbindung zusätzlich auch einen Textil-pflegenden Effekt besitzt.The amount of skin-care compound is preferably between 0.01 and 10% by weight, preferably between 0.1 and 5% by weight and very particularly preferably between 0.3 and 3% by weight, based on the solid, textile nourishing composition. It may be that the skin-nourishing compound additionally has a textile care effect.

Um eine orale Aufnahme der Textil-pflegenden Zusammensetzung durch Menschen, insbesondere Kinder, oder Tiere zu verhindern, kann diese einen Bitterstoff wie Bitrex® (ex Macfarlan Smith) enthalten.To prevent oral ingestion of the fabric care composition by humans, particularly children, or animals, it may contain a bittering agent such as Bitrex® (ex Macfarlan Smith).

Diese weiteren Inhaltsstoffe werden vorzugsweise in die Umhüllung aus dem wasserlöslichen Polymer eingebracht.These further ingredients are preferably introduced into the enclosure of the water-soluble polymer.

In einer besonders bevorzugten Ausführungsform umfasst die feste, Textil-pflegende Zusammensetzung einen wasserlöslichen Träger, ein wasserlösliches Polymer, eine Textil-pflegende Verbindung, ein Polysaccharid und ein Parfüm, wobei der wasserlösliche Träger in partikulärer Form vorliegt und zumindest teilweise eine Umhüllung aus dem wasserlöslichen Polymer und dem Parfüm aufweist und wobei in die Umhüllung eine Mischung aus der Textil-pflegenden Verbindung und dem Polysaccharid eingearbeitet ist.In a particularly preferred embodiment, the solid textile care composition comprises a water-soluble carrier, a water-soluble polymer, a fabric-care compound, a polysaccharide and a perfume, wherein the water-soluble carrier is in particulate form and at least partially an enclosure of the water-soluble polymer and the perfume, and wherein the sheath is incorporated with a mixture of the fabric care compound and the polysaccharide.

Zur Herstellung einer solchen festen, Textil-pflegenden Zusammensetzung wird zunächst das wasserlösliche Polymer geschmolzen und im geschmolzenen Zustand mit dem Parfüm gemischt. Die erhaltene Schmelze wird derart auf den partikulären Träger gegeben, so dass dieser zumindest teilweise umhüllt ist und anschließend wird in die noch geschmolzene Umhüllung eine Mischung aus der Textil-pflegenden Verbindung und dem Polysaccharid eingearbeitet. Die Mischung wird dabei vorzugsweise vollständig in die Umhüllung eingearbeitet. Es ist aber alternativ auch möglich, dass ein großer Teil der Mischung aus der textil-pflegenden Verbindung und dem Polysaccharid an der Oberfläche der Umhüllung ist.To prepare such a solid textile-care composition, the water-soluble polymer is first melted and mixed with the perfume in the molten state. The resulting melt is added to the particulate carrier in such a way that it is at least partially enveloped, and then a mixture of the textile-care compound and the polysaccharide is incorporated into the still-melted coating. The mixture is preferably incorporated completely into the casing. Alternatively, however, it is also possible that a large part of the mixture of the textile-care compound and the polysaccharide is on the surface of the casing.

In einer alternativen Ausführungsform umfasst die feste, Textil-pflegende Zusammensetzung einen wasserlöslichen Träger, ein wasserlösliches Polymer, eine Textil-pflegende Verbindung, ein Polysaccharid und ein Parfüm, wobei der wasserlösliche Träger in partikulärer Form vorliegt und zumindest teilweise eine Umhüllung aus dem wasserlöslichen Polymer und dem Parfüm aufweist und wobei die Umhüllung oder die Umhüllung und die nicht-umhüllten Bereiche des wasserlöslichen Trägers zumindest teilweise mit einer Mischung aus der Textil-pflegenden Verbindung und dem Polysaccharid beschichtet ist/sind.In an alternative embodiment, the solid, fabric care composition comprises a water-soluble carrier, a water-soluble polymer, a fabric-care compound, a polysaccharide and a perfume, wherein the water-soluble carrier is in particulate form and at least partially an enclosure of the water-soluble polymer and the perfume and wherein the wrapper or wrapper and the non-enveloped portions of the water-soluble carrier are / are at least partially coated with a blend of the fabric care composition and the polysaccharide.

Zur Herstellung einer solchen festen, Textil-pflegenden Zusammensetzung wird zunächst das wasserlösliche Polymer geschmolzen und im geschmolzenen Zustand mit dem Parfüm gemischt. Die erhaltene Schmelze wird derart auf den partikulären Träger gegeben, so dass dieser zumindest teilweise umhüllt ist und anschließend wird die Umhüllung oder werden die Umhüllung und die nicht-umhüllten Bereiche des wasserlöslichen Trägers zumindest teilweise mit einer Mischung aus der Textil-pflegenden Verbindung und dem Polysaccharid beschichtet.To prepare such a solid textile-care composition, the water-soluble polymer is first melted and mixed with the perfume in the molten state. The resulting melt is placed on the particulate carrier so that it is at least partially enveloped, and then the wrapper or sheath and non-enveloped portions of the water-soluble carrier become at least partially coated with a mixture of the fabric care compound and the polysaccharide coated.

Es ist bei beiden Ausführungsformen bevorzugt, dass der partikuläre Träger vollständig umhüllt ist.It is preferred in both embodiments that the particulate carrier is completely enveloped.

Es ist insgesamt bevorzugt, dass die Textil-pflegende Verbindung ein Bentonit ist und das Polysaccharid ein Cellulosederivat. Insbesondere bevorzugt ist das Cellulosederivat eine N,N,N-Trialkylaminohydroxyalkyl-quaternisierte Hydroxyethylcellulose, eine N,N,N-Trialkylaminohydroxyalkyl-quaternisierte Hydroxypropylcellulose, eine Carboxymethylcellulose, eine Methylhydroxypropylcellulose, eine Hydroxyethylcellulose, ein N,N-Dialkylaminoalkyl-substituiertes Cellulosederivat oder eine Methylcellulose. Es ist auch bevorzugt, dass beide Verbindungen in Pulverform eingesetzt.It is generally preferred that the textile-care compound is a bentonite and the polysaccharide is a cellulose derivative. Most preferably, the cellulose derivative is an N, N, N-trialkylaminohydroxyalkyl quaternized hydroxyethylcellulose, an N, N, N-trialkylaminohydroxyalkyl quaternized hydroxypropylcellulose, a carboxymethylcellulose, a methylhydroxypropylcellulose, a hydroxyethylcellulose, an N, N-dialkylaminoalkyl substituted cellulose derivative, or a methylcellulose , It is also preferred that both compounds be used in powder form.

Die Textil-pflegende Zusammensetzung eignet sich insbesondere zum Konditionieren von textilen Flächengebilden und wird dazu zusammen mit einem herkömmlichen Wasch- oder Reinigungsmittel im (Haupt)Waschgang eines herkömmlichen Wasch- und Reinigungsprozesses mit den textilen Flächengebilden in Kontakt gebracht.The textile-care composition is suitable in particular for conditioning textile fabrics and is brought into contact with the textile fabrics together with a conventional washing or cleaning agent in the (main) wash cycle of a conventional washing and cleaning process.

Die Textil-pflegende Zusammensetzung kann in ein Wasch- oder Reinigungsmittel eingebracht werden.The fabric care composition can be incorporated into a detergent or cleanser.

Dazu wird ein festes Wasch- oder Reinigungsmittel mit 1 bis 20 Gew.-%, vorzugsweise 5 bis 15 Gew.-%, der erfindungsgemäßen Textil-pflegenden Zusammensetzung gemischt.For this purpose, a solid detergent or cleaning agent with 1 to 20 wt .-%, preferably 5 to 15 wt .-%, of the textile-care composition according to the invention is mixed.

Die erfindungsgemäßen Textil-pflegenden Wasch- oder Reinigungsmittel enthalten neben der Textil-pflegenden Zusammensetzung Tensid(e), wobei anionische, nichtionische, zwitterionische und/oder amphotere Tenside eingesetzt werden können. Bevorzugt sind aus anwendungstechnischer Sicht Mischungen aus anionischen und nichtionischen Tensiden. Der Gesamttensidgehalt eines Waschmittels liegt vorzugsweise unterhalb von 40 Gew.-% und besonders bevorzugt unterhalb von 35 Gew.-%, bezogen auf das gesamte flüssige Waschmittel.The textile-care washing or cleaning compositions according to the invention contain, in addition to the textile-care composition, surfactant (s), it being possible to use anionic, nonionic, zwitterionic and / or amphoteric surfactants. From an application point of view, preference is given to mixtures of anionic and nonionic surfactants. The total surfactant content of a detergent is preferably below 40% by weight, and more preferably below 35% by weight, based on the total liquid detergent.

Als nichtionische Tenside werden vorzugsweise alkoxylierte, vorteilhafterweise ethoxylierte, insbesondere primäre Alkohole mit vorzugsweise 8 bis 18 C-Atomen und durchschnittlich 1 bis 12 Mol Ethylenoxid (EO) pro Mol Alkohol eingesetzt, in denen der Alkoholrest linear oder bevorzugt in 2-Stellung methylverzweigt sein kann bzw. lineare und methylverzweigte Reste im Gemisch enthalten kann, so wie sie üblicherweise in Oxoalkoholresten vorliegen. Insbesondere sind jedoch Alkoholethoxylate mit linearen Resten aus Alkoholen nativen Ursprungs mit 12 bis 18 C-Atomen, zum Beispiel aus Kokos-, Palm-, Talgfett- oder Oleylalkohol, und durchschnittlich 2 bis 8 EO pro Mol Alkohol bevorzugt.The nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten. In particular, however, alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for example of coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred.

Außerdem können als weitere nichtionische Tenside auch Alkylglykoside, Polyhydroxyfettsäureamide, alkoxylierte Fettsäurealkylester Fettsäurealkanolamide und/oder Aminoxide eingesetzt werden.In addition, other nonionic surfactants which can also be used are alkyl glycosides, polyhydroxy fatty acid amides, alkoxylated fatty acid alkyl esters, fatty acid alkanolamides and / or amine oxides.

Der Gehalt an nichtionischen Tensiden beträgt in den Wasch- oder Reinigungsmitteln bevorzugt 5 bis 30 Gew.-%, vorzugsweise 7 bis 20 Gew.-% und insbesondere 9 bis 15 Gew.-%, jeweils bezogen auf das gesamte Wasch- oder Reinigungsmittel.The content of nonionic surfactants in the detergents or cleaners is preferably 5 to 30 wt .-%, preferably 7 to 20 wt .-% and in particular 9 to 15 wt .-%, each based on the total detergent or cleaning agent.

Als anionische Tenside werden beispielsweise solche vom Typ der Sulfonate und Sulfate eingesetzt. Als Tenside vom Sulfonat-Typ kommen dabei vorzugsweise C9-13-Alkylbenzolsulfonate, Olefinsulfonate, d.h. Gemische aus Alken- und Hydroxyalkansulfonaten sowie Disulfonaten in Betracht. Geeignet sind auch Alkansulfonate. Ebenso sind auch die Ester von α-Sulfofettsäuren (Estersulfonate), zum Beispiel die α-sulfonierten Methylester der hydrierten Kokos-, Palmkern- oder Talgfettsäuren geeignet. Weitere geeignete Aniontenside sind sulfierte Fettsäureglycerinester. Als Alk(en)ylsulfate werden die Alkali- und insbesondere die Natriumsalze der Schwefelsäurehalbester der C12-C18-Fettalkohole bevorzugt. Auch die Schwefelsäuremonoester der mit 1 bis 6 Mol Ethylenoxid ethoxylierten geradkettigen oder verzweigten C7-21-Alkohole, wie 2-Methyl-verzweigte C9-11-Alkohole mit im Durchschnitt 3,5 Mol Ethylenoxid (EO) oder C12-18-Fettalkohole mit 1 bis 4 EO, sind geeignet.As anionic surfactants, for example, those of the sulfonate type and sulfates are used. Suitable surfactants of the sulfonate type are preferably C 9-13 -alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates. Also suitable are alkanesulfonates. Likewise suitable are the esters of α-sulfo fatty acids (ester sulfonates), for example the α-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids. Further suitable anionic surfactants are sulfated fatty acid glycerol esters. As alk (en) ylsulfate the alkali metal and in particular the sodium salts of sulfuric acid half esters of C 12 -C 18 fatty alcohols are preferred. Also, the sulfuric acid monoesters of straight-chain or branched with 1 to 6 moles of ethylene oxide ethoxylated C 7-21 alcohols, such as 2-methyl-branched C 9-11 alcohols containing on average 3.5 moles of ethylene oxide (EO) or C 12-18 fatty alcohols containing 1 to 4 EO, are suitable.

Weitere geeignete Aniontenside sind auch die Salze der Alkylsulfobernsteinsäure und die Monoester und/oder Diester der Sulfobernsteinsäure mit Alkoholen, vorzugsweise Fettalkoholen und insbesondere ethoxylierten Fettalkoholen.Further suitable anionic surfactants are also the salts of alkylsulfosuccinic acid and the monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols.

Insbesondere bevorzugte anionische Tenside sind Seifen. Geeignet sind gesättigte und ungesättigte Fettsäureseifen, wie die Salze der Laurinsäure, Myristinsäure, Palmitinsäure, Stearinsäure, (hydrierten) Erucasäure und Behensäure sowie insbesondere aus natürlichen Fettsäuren, zum Beispiel Kokos-, Palmkern-, Olivenöl- oder Talgfettsäuren, abgeleitete Seifengemische.Particularly preferred anionic surfactants are soaps. Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and, in particular, soap mixtures derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids.

Die anionischen Tenside einschließlich der Seifen können in Form ihrer Natrium-, Kalium- oder Ammoniumsalze sowie als lösliche Salze organischer Basen, wie Mono-, Di- oder Triethanolamin, vorliegen. Vorzugsweise liegen die anionischen Tenside in Form ihrer Natrium- oder Kaliumsalze, insbesondere in Form der Natriumsalze vor.The anionic surfactants, including the soaps, may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine. The anionic surfactants are preferably present in the form of their sodium or potassium salts, in particular in the form of the sodium salts.

Der Gehalt bevorzugter Wasch- oder Reinigungsmittel an anionischen Tensiden beträgt 2 bis 30 Gew.-%, vorzugsweise 4 bis 25 Gew.-% und insbesondere 5 bis 22 Gew.-%, jeweils bezogen auf das gesamte Wasch- oder Reinigungsmittel. Es kann allerdings, beispielsweise wenn die Textil-pflegende Zusammensetzung ein kationisches Polymer enthält, vorteilhaft sein, dass das Wasch- oder Reinigungsmittel nur nichtionische Tenside enthält.The content of preferred detergents or cleaning agents to anionic surfactants is 2 to 30 wt .-%, preferably 4 to 25 wt .-% and in particular 5 to 22 wt .-%, each based on the total washing or cleaning agent. However, it may be advantageous, for example if the textile-care composition contains a cationic polymer, that the washing or cleaning agent contains only nonionic surfactants.

Zusätzlich zu der Textil-pflegenden Zusammensetzung und den Tensiden können die Wasch- oder Reinigungsmittel weitere Inhaltsstoffe enthalten, die die anwendungstechnischen und/oder ästhetischen Eigenschaften des Wasch- oder Reinigungsmittels weiter verbessern. Im Rahmen der vorliegenden Erfindung enthalten bevorzugte Wasch- oder Reinigungsmittel zusätzlich einen oder mehrere Stoffe aus der Gruppe der Gerüststoffe, Bleichmittel, Bleichaktivatoren, Enzyme, Parfüme, Parfümträger, Fluoreszenzmittel, Farbstoffe, Schauminhibitoren, Silikonöle, Antiredepositionsmittel, optischen Aufheller, Vergrauungsinhibitoren, Einlaufverhinderer, Knitterschutzmittel, Farbübertragungsinhibitoren, antimikrobiellen Wirkstoffe, Germizide, Fungizide, Antioxidantien, Konservierungsmittel, Korrosionsinhibitoren, Antistatika, Bittermittel, Bügelhilfsmittel, Phobier- und Imprägniermittel, Quell- und Schiebefestmittel, neutrale Füllsalze sowie UV-Absorber.In addition to the textile-care composition and the surfactants, the detergents or cleaners may contain further ingredients which further improve the performance and / or aesthetic properties of the washing or cleaning agent. In the context of the present invention, preferred washing or cleaning agents additionally contain one or more substances from the group of builders, bleaches, bleach activators, enzymes, perfumes, perfume carriers, fluorescers, dyes, foam inhibitors, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents , Color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, antistatic agents, bittering agents, ironing aids, repellents and impregnating agents, swelling and anti-slip agents, neutral filler salts and UV absorbers.

Als Gerüststoffe, die in den Wasch- oder Reinigungsmitteln enthalten sein können, sind insbesondere Silikate, Aluminiumsilikate (insbesondere Zeolithe), Carbonate, Salze organischer Di- und Polycarbonsäuren sowie Mischungen dieser Stoffe zu nennen.Suitable builders which may be present in the detergents or cleaners are in particular silicates, aluminum silicates (in particular zeolites), carbonates, salts of organic di- and polycarboxylic acids and mixtures of these substances.

Selbstverständlich ist auch ein Einsatz der allgemein bekannten Phosphate als Buildersubstanzen möglich, sofern ein derartiger Einsatz nicht aus ökologischen Gründen vermieden werden sollte. Geeignet sind insbesondere die Natriumsalze der Orthophosphate, der Pyrophosphate und insbesondere der Tripolyphosphate.Of course, a use of the well-known phosphates as builders is possible, unless such use should not be avoided for environmental reasons. Particularly suitable are the sodium salts of orthophosphates, pyrophosphates and in particular tripolyphosphates.

Organische Builder, welche in dem Wasch- oder Reinigungsmittel vorhanden sein können, umfassen Polycarboxylatpolymere wie Polyacrylate und Acrylsäure/Maleinsäure-Copolymere, Polyaspartate und monomere Polycarboxylate wie Citrate, Gluconate, Succinate oder Malonate, die bevorzugt als Natriumsalze eingesetzt werden.Organic builders that may be present in the detergent or cleaning agent include polycarboxylate polymers such as polyacrylates and acrylic acid / maleic acid copolymers, polyaspartates and monomeric polycarboxylates such as citrates, gluconates, succinates or malonates, which are preferably used as the sodium salts.

Unter den als Bleichmittel dienenden, in Wasser H2O2 liefernden Verbindungen haben das Natriumperborattetrahydrat und das Natriumperboratmonohydrat besondere Bedeutung. Weitere brauchbare Bleichmittel sind beispielsweise Natriumpercarbonat, Peroxypyrophosphate, Citratperhydrate sowie H2O2 liefernde persaure Salze oder Persäuren, wie Perbenzoate, Peroxophthalate, Diperazelainsäure, Phthaloiminopersäure oder Diperdodecandisäure.Among the compounds serving as bleaches in water H 2 O 2 , sodium perborate tetrahydrate and sodium perborate monohydrate are of particular importance. Other useful bleaching agents are, for example, sodium percarbonate, peroxypyrophosphates, citrate perhydrates and H 2 O 2 -producing peracidic salts or peracids, such as perbenzoates, peroxophthalates, diperazelaic acid, phthaloiminoperacid or diperdodecanedioic acid.

Um beim Waschen bei Temperaturen von 60°C und darunter eine verbesserte Bleichwirkung zu erreichen, können Bleichaktivatoren in die Wasch- oder Reinigungsmittel eingearbeitet werden. Als Bleichaktivatoren können Verbindungen, die unter Perhydrolysebedingungen aliphatische Peroxocarbonsäuren mit vorzugsweise 1 bis 10 C-Atomen, insbesondere 2 bis 4 C-Atomen, und/oder gegebenenfalls substituierte Perbenzoesäure ergeben, eingesetzt werden. Geeignet sind Substanzen, die O- und/oder N-Acylgruppen der genannten C-Atomzahl und/oder gegebenenfalls substituierte Benzoylgruppen tragen. Bevorzugt sind mehrfach acylierte Alkylendiamine, insbesondere Tetraacetylethylendiamin (TAED), acylierte Triazinderivate, insbesondere 1,5-Diacetyl-2,4-dioxohexahydro-1,3,5-triazin (DADHT), acylierte Glykolurile, insbesondere Tetraacetylglykoluril (TAGU), N-Acylimide, insbesondere N-Nonanoylsuccinimid (NOSI), acylierte Phenolsulfonate, insbesondere n-Nonanoyl- oder Isononanoyloxybenzolsulfonat (n- bzw. iso-NOBS), Carbonsäureanhydride, insbesondere Phthalsäureanhydrid, acylierte mehrwertige Alkohole, insbesondere Triacetin, Ethylenglykoldiacetat und 2,5-Diacetoxy-2,5-dihydrofuran.In order to achieve an improved bleaching effect when washing at temperatures of 60 ° C and below, bleach activators can be incorporated into the detergents or cleaners. As bleach activators, it is possible to use compounds which, under perhydrolysis conditions, give aliphatic peroxycarboxylic acids having preferably 1 to 10 C atoms, in particular 2 to 4 C atoms, and / or optionally substituted perbenzoic acid. Suitable substances are those which carry O- and / or N-acyl groups of the stated C atom number and / or optionally substituted benzoyl groups. Preference is given to polyacylated alkylenediamines, in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular tetraacetylglycoluril (TAGU), N- Acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic anhydrides, in particular phthalic anhydride, acylated polyhydric alcohols, in particular triacetin, ethylene glycol diacetate and 2,5-diacetoxy- 2,5-dihydrofuran.

Zusätzlich zu den konventionellen Bleichaktivatoren oder an deren Stelle können auch so genannte Bleichkatalysatoren in die Wasch- oder Reinigungsmittel eingearbeitet werden. Bei diesen Stoffen handelt es sich um bleichverstärkende Übergangsmetallsalze bzw. Übergangsmetallkomplexe wie beispielsweise Mn-, Fe-, Co-, Ru- oder Mo-Salenkomplexe oder -carbonylkomplexe. Auch Mn-, Fe-, Co-, Ru-, Mo-, Ti-, V- und Cu-Komplexe mit stickstoffhaltigen Tripod-Liganden sowie Co-, Fe-, Cu- und Ru-Amminkomplexe sind als Bleichkatalysatoren verwendbar.In addition to or in place of the conventional bleach activators, so-called bleach catalysts can also be incorporated into the detergents or cleaners. These substances are bleach-enhancing transition metal salts or transition metal complexes such as Mn, Fe, Co, Ru or Mo saline complexes or carbonyl complexes. Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with nitrogen-containing tripod ligands and Co, Fe, Cu and Ru ammine complexes can also be used as bleach catalysts.

Das Wasch- oder Reinigungsmittel kann Enzyme in verkapselter Form und/oder direkt in dem Wasch- oder Reinigungsmittel enthalten. Als Enzyme kommen insbesondere solche aus der Klassen der Hydrolasen wie der Proteasen, Esterasen, Lipasen bzw. lipolytisch wirkende Enzyme, Amylasen, Cellulasen bzw. andere Glykosylhydrolasen, Hemicellulase, Cutinasen, β-Glucanasen, Oxidasen, Peroxidasen, Mannanasen, Perhydrolasen und/oder Laccasen und Gemische der genannten Enzyme in Frage. Besonders gut geeignet sind aus Bakterienstämmen oder Pilzen wie Bacillus subtilis, Bacillus licheniformis, Streptomyceus griseus und Humicola insolens gewonnene enzymatische Wirkstoffe. Enzymmischungen, beispielsweise aus Protease und Amylase oder Protease und Lipase bzw. lipolytisch wirkenden Enzymen oder Protease und Cellulase oder aus Cellulase und Lipase bzw. lipolytisch wirkenden Enzymen oder aus Protease, Amylase und Lipase bzw. lipolytisch wirkenden Enzymen oder Protease, Lipase bzw. lipolytisch wirkenden Enzymen und Cellulase, insbesondere jedoch Protease und/oder Lipase-haltige Mischungen bzw. Mischungen mit lipolytisch wirkenden Enzymen sind von besonderem Interesse. Beispiele für derartige lipolytisch wirkende Enzyme sind die bekannten Cutinasen. Auch Peroxidasen oder Oxidasen haben sich in einigen Fällen als geeignet erwiesen. Zu den geeigneten Amylasen zählen insbesondere α-Amylasen, Iso-Amylasen, Pullulanasen und Pektinasen. Als Cellulasen werden vorzugsweise Cellobiohydrolasen, Endoglucanasen und β-Glucosidasen, die auch Cellobiasen genannt werden, bzw. Mischungen aus diesen eingesetzt. Da sich verschiedene Cellulase-Typen durch ihre CMCase- und Avicelase-Aktivitäten unterscheiden, können durch gezielte Mischungen der Cellulasen die gewünschten Aktivitäten eingestellt werden.The washing or cleaning agent may contain enzymes in encapsulated form and / or directly in the washing or cleaning agent. Suitable enzymes include in particular those from the classes of hydrolases such as proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases, hemicellulases, cutinases, β-glucanases, oxidases, peroxidases, mannanases, perhydrolases and / or laccases and mixtures of said enzymes in question. Particularly suitable are from bacterial strains or fungi such as Bacillus subtilis, Bacillus licheniformis, Streptomyceus griseus and Humicola insolens enzymatic agents. Enzyme mixtures, for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic acting Enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes are of particular interest. Examples of such lipolytic enzymes are the known cutinases. Peroxidases or oxidases have also proved suitable in some cases. Suitable amylases include in particular α-amylases, iso-amylases, pullulanases and pectinases. As cellulases are preferably cellobiohydrolases, endoglucanases and β-glucosidases, which are also called cellobiases, or mixtures thereof used. Since different cellulase types differ by their CMCase and avicelase activities, the desired activities can be set by targeted mixtures of the cellulases.

Die Enzyme können an Trägerstoffe adsorbiert sein, um sie gegen vorzeitige Zersetzung zu schützen. Der Anteil der Enzyme oder der Enzymgranulate direkt in dem Wasch- oder Reinigungsmittel kann beispielsweise etwa 0,01 bis 5 Gew.-%, vorzugsweise 0,12 bis etwa 2,5 Gew.-% betragen.The enzymes may be adsorbed to carriers to protect against premature degradation. The proportion of enzymes or enzyme granules directly in the washing or cleaning agent may be, for example, about 0.01 to 5 wt .-%, preferably 0.12 to about 2.5 wt .-%.

Es kann, beispielsweise bei speziellen Wasch- oder Reinigungsmitteln für Konsumenten mit Allergien und/oder sensibler Haut, aber auch bevorzugt sein, dass das Wasch- oder Reinigungsmittel keine Enzyme enthält.However, it may also be preferred, for example in the case of special detergents or cleaners for consumers with allergies and / or sensitive skin, that the washing or cleaning agent contains no enzymes.

In einer Ausführungsform enthält das Wasch- oder Reinigungsmittel gegebenenfalls ein oder mehrere Parfüms in einer Menge von üblicherweise bis 10 Gew.-%, vorzugsweise 0,5 bis 7 Gew.-%, insbesondere 1 bis 3 Gew.-%. Dabei ist die Menge an eingesetztem Parfüm auch von der Art des Wasch- oder Reinigungsmittels abhängig. Es ist aber insbesondere bevorzugt, dass das Parfüm über die Textilpflegende Zusammensetzung in das Wasch- oder Reinigungsmittel eingebracht wird. Es ist allerdings auch möglich, dass das Wasch- oder Reinigungsmittel Parfüm enthält, welches nicht über die Textilpflegende Zusammensetzung in das Wasch- oder Reinigungsmittel eingebracht wird.In one embodiment, the washing or cleaning agent optionally contains one or more perfumes in an amount of usually up to 10 wt .-%, preferably 0.5 to 7 wt .-%, in particular 1 to 3 wt .-%. The amount of perfume used is also dependent on the type of detergent or cleaning agent. However, it is particularly preferred that the perfume is introduced into the washing or cleaning agent via the textile care composition. However, it is also possible for the washing or cleaning agent to contain perfume which is not introduced into the washing or cleaning agent via the textile care composition.

Um den ästhetischen Eindruck der Wasch- oder Reinigungsmittel zu verbessern, können sie (gegebenenfalls auch nur teilweise) mit geeigneten Farbstoffen eingefärbt werden. Bevorzugte Farbstoffe, deren Auswahl dem Fachmann keinerlei Schwierigkeit bereitet, besitzen eine hohe Lagerstabilität und Unempfindlichkeit gegenüber den übrigen Inhaltsstoffen der Wasch- oder Reinigungsmittel und gegen Licht sowie keine ausgeprägte Substantivität gegenüber Textilfasern, um diese nicht anzufärben.In order to improve the aesthetic impression of the detergents or cleaners, they may (optionally only partially) be colored with suitable dyes. Preferred dyes, the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.

Als Schauminhibitoren, die in den Wasch- oder Reinigungsmitteln eingesetzt werden können, kommen beispielsweise Seifen, Paraffine oder Silikonöle in Betracht, die gegebenenfalls auf Trägermaterialien aufgebracht sein können.Suitable foam inhibitors which can be used in the detergents or cleaners are, for example, soaps, paraffins or silicone oils, which may optionally be applied to support materials.

Geeignete Soil-Release-Polymere, die auch als "Antiredepositionsmittel" bezeichnet werden, sind beispielsweise nichtionische Celluloseether wie Methylcellulose und Methylhydroxypropylcellulose mit einem Anteil an Methoxygruppen von 15 bis 30 Gew.-% und an Hydroxypropylgruppen von 1 bis 15 Gew.-%, jeweils bezogen auf den nichtionischen Celluloseether sowie die aus dem Stand der Technik bekannten Polymere der Phthalsäure und/oder Terephthalsäure bzw. von deren Derivaten, insbesondere Polymere aus Ethylenterephthalaten und/oder Polyethylen- und/oder Polypropylenglykolterephthalaten oder anionisch und/oder nichtionisch modifizierten Derivaten von diesen. Geeignete Derivate umfassen die sulfonierten Derivate der Phthalsäure- und Terephthalsäure-Polymere. Eine weitere Klasse an geeigneten Soil-Release-Polymeren, insbesondere für Baumwoll-haltige Textilien, stellen modifizierte, beispielsweise alkoxylierte und/oder quaternierte und/oder oxidierte, Polyamine dar. Die Polyamine sind beispielsweise Polyalkylenamine, wie Polyethylenamine, oder Polyalkylenimine, wie Polyethylenimine. Bevorzugte Beispiele für diese Klasse an Soil-Release-Polymeren sind ethoxylierte Polyethylenimine und ethoxylierte Polyethylenamine.Suitable soil release polymers, also referred to as "anti-redeposition agents", include, for example, nonionic cellulose ethers such as methyl cellulose and methyl hydroxypropyl cellulose having a methoxy group content of 15 to 30 wt% and hydroxypropyl groups of 1 to 15 wt%, respectively based on the nonionic cellulose ether and the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular polymers of ethylene terephthalates and / or polyethylene and / or polypropylene glycol terephthalates or anionic and / or nonionic modified derivatives thereof. Suitable derivatives include the sulfonated derivatives of the phthalic and terephthalic acid polymers. Another class of suitable soil-release polymers, in particular for cotton-containing textiles, are modified, for example alkoxylated and / or quaternized and / or oxidized, polyamines. The polyamines are, for example, polyalkyleneamines, such as polyethyleneamines, or polyalkylenimines, such as polyethylenimines. Preferred examples of this class of soil release polymers are ethoxylated polyethylenimines and ethoxylated polyethyleneamines.

Optische Aufheller (so genannte "Weißtöner") können den Wasch- oder Reinigungsmitteln zugesetzt werden, um Vergrauungen und Vergilbungen der behandelten textilen Flächengebilde zu beseitigen. Diese Stoffe ziehen auf die Faser auf und bewirken eine Aufhellung und vorgetäuschte Bleichwirkung, indem sie unsichtbare Ultraviolettstrahlung in sichtbares längerwelliges Licht umwandeln, wobei das aus dem Sonnenlicht absorbierte ultraviolette Licht als schwach bläuliche Fluoreszenz abgestrahlt wird und mit dem Gelbton der vergrauten bzw. vergilbten Wäsche reines Weiß ergibt. Geeignete Verbindungen stammen beispielsweise aus den Substanzklassen der 4,4'-Diamino-2,2'-stilbendisulfonsäuren (Flavonsäuren), 4,4'-Distyryl-biphenylen, Methylumbelliferone, Cumarine, Dihydrochinolinone, 1,3-Diarylpyrazoline, Naphthalsäureimide, Benzoxazol-, Benzisoxazol- und Benzimidazol-Systeme sowie der durch Heterocyclen substituierten Pyrenderivate. Die optischen Aufheller werden üblicherweise in Mengen zwischen 0% und 0,3 Gew.-%, bezogen auf das fertige Wasch- oder Reinigungsmittel, eingesetzt.Optical brighteners (so-called "whiteners") can be added to the detergents or cleaners to eliminate graying and yellowing of the treated fabrics. These fabrics impinge on the fiber and cause whitening and bleaching by transforming invisible ultraviolet radiation into visible longer wavelength light, emitting the ultraviolet light absorbed from the sunlight as faint bluish fluorescence, and pure with the yellowness of the grayed or yellowed wash White results. Suitable compounds are derived, for example, from the substance classes of 4,4'-diamino-2,2'-stilbenedisulfonic acids (flavonic acids), 4,4'-distyrylbiphenyls, methylumbelliferones, coumarins, dihydroquinolinones, 1,3-diarylpyrazolines, naphthalimides, benzoxazole , Benzisoxazole and benzimidazole systems as well as heterocyclic substituted pyrene derivatives. The optical brighteners are usually used in amounts of between 0% and 0.3% by weight, based on the finished washing or cleaning agent.

Vergrauungsinhibitoren haben die Aufgabe, den von der Faser abgelösten Schmutz in der Flotte suspendiert zu halten und so das Wiederaufziehen des Schmutzes zu verhindern. Hierzu sind wasserlösliche Kolloide meist organischer Natur geeignet, beispielsweise Leim, Gelatine, Salze von Ethersulfonsäuren der Stärke oder der Cellulose oder Salze von sauren Schwefelsäureestern der Cellulose oder der Stärke. Auch wasserlösliche, saure Gruppen enthaltende Polyamide sind für diesen Zweck geeignet. Weiterhin lassen sich lösliche Stärkepräparate und andere als die oben genannten Stärkeprodukte verwenden, zum Beispiel abgebaute Stärke, Aldehydstärken usw. Auch Polyvinylpyrrolidon ist brauchbar. Bevorzugt werden jedoch Celluloseether wie Carboxymethylcellulose (Na-Salz), Methylcellulose, Hydroxyalkylcellulose und Mischether wie Methylhydroxyethylcellulose, Methylhydroxypropylcellulose, Methylcarboxymethylcellulose und deren Gemische in Mengen von 0,1 bis 5 Gew.-%, bezogen auf die Wasch- oder Reinigungsmittel, eingesetzt.Grayness inhibitors have the task of keeping the dirt detached from the fiber suspended in the liquor and thus preventing the dirt from being rebuilt. Water-soluble colloids of mostly organic nature are suitable for this purpose, for example glue, gelatine, salts of ether sulfonic acids or cellulose or salts of acidic sulfuric acid esters of cellulose or starch. Also, water-soluble polyamides containing acidic groups are suitable for this purpose. It is also possible to use soluble starch preparations and starch products other than those mentioned above, for example degraded starch, aldehyde starches, etc. Polyvinylpyrrolidone is also useful. However, preference is given to using cellulose ethers such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof in amounts of from 0.1 to 5% by weight, based on the washing or cleaning agents.

Um während des Waschens und/oder des Reinigens von gefärbten Textilien die Farbstoffablösung und/oder die Farbstoffübertragung auf andere Textilien wirksam zu unterdrücken, kann das Wasch- oder Reinigungsmittel einen Farbübertragungsinhibitor enthalten. Es ist bevorzugt, dass der Farbübertragungsinhibitor ein Polymer oder Copolymer von cyclischen Aminen ist. Als Farbübertragungsinhibitor geeignete Polymere umfassen Polyvinylpyrrolidon (PVP), Polyvinylimidazol (PVI), Copolymere von Vinylpyrrolidon und Vinylimidazol (PVP/PVI), Polyvinylpyridin-N-oxid, Poly-N-carboxymethyl-4-vinylpyridiumchlorid sowie Mischungen daraus.In order to effectively suppress dye release and / or dye transfer to other fabrics during washing and / or cleaning of dyed fabrics, the washing or cleaning agent may contain a dye transfer inhibitor. It is preferable that the Color transfer inhibitor is a polymer or copolymer of cyclic amines. Suitable color transfer inhibiting polymers include polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI), copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI), polyvinylpyridine-N-oxide, poly-N-carboxymethyl-4-vinylpyridium chloride, and mixtures thereof.

Die Menge an Farbübertragungsinhibitor bezogen auf die Gesamtmenge des Wasch- oder Reinigungsmittel liegt bevorzugt von 0,01 bis 2 Gew.-%, vorzugsweise von 0,05 bis 1 Gew.-% und mehr bevorzugt von 0,1 bis 0,5 Gew.-%.The amount of dye transfer inhibitor based on the total amount of the detergent or cleaning agent is preferably from 0.01 to 2% by weight, preferably from 0.05 to 1% by weight, and more preferably from 0.1 to 0.5% by weight. -%.

Alternativ können aber auch enzymatische Systeme, umfassend eine Peroxidase und Wasserstoffperoxid beziehungsweise eine in Wasser Wasserstoffperoxid-liefernde Substanz, als Farbübertragungsinhibitor eingesetzt werden. Der Zusatz einer Mediatorverbindung für die Peroxidase, zum Beispiel eines Acetosyringons, eines Phenolderivats oder eines Phenotiazins oder Phenoxazins, ist in diesem Fall bevorzugt, wobei auch zusätzlich die oben genannten polymeren Farbübertragungsinhibitoren eingesetzt werden können.Alternatively, however, it is also possible to use enzymatic systems comprising a peroxidase and hydrogen peroxide or a substance which produces hydrogen peroxide in water as a color transfer inhibitor. The addition of a mediator compound for the peroxidase, for example an acetosyringone, a phenol derivative or a phenotiazine or phenoxazine, is preferred in this case, wherein additionally the above-mentioned polymeric dye transfer inhibitors can be used.

Da textile Flächengebilde, insbesondere aus Reyon, Zellwolle, Baumwolle und deren Mischungen, zum Knittern neigen können, weil die Einzelfasern gegen Durchbiegen, Knicken, Pressen und Quetschen quer zur Faserrichtung empfindlich sind, können die Wasch- oder Reinigungsmittel synthetische Knitterschutzmittel enthalten. Hierzu zählen beispielsweise synthetische Produkte auf der Basis von Fettsäuren, Fettsäureestern, Fettsäureamiden, -alkylolestern, -alkylolamiden oder Fettalkoholen, die meist mit Ethylenoxid umgesetzt sind, oder Produkte auf der Basis von Lecithin oder modifizierter Phosphorsäureester.Since textile fabrics, in particular of rayon, rayon, cotton and their mixtures, can tend to wrinkle, because the individual fibers are sensitive to bending, buckling, pressing and squeezing transverse to the fiber direction, the detergents or cleaning agents may contain synthetic crease inhibitors. These include, for example, synthetic products based on fatty acids, fatty acid esters, fatty acid amides, alkylol esters, -alkylolamides or fatty alcohols, which are usually reacted with ethylene oxide, or products based on lecithin or modified phosphoric acid ester.

Zur Bekämpfung von Mikroorganismen können die Wasch- oder Reinigungsmittel antimikrobielle Wirkstoffe enthalten. Hierbei unterscheidet man je nach antimikrobiellem Spektrum und Wirkungsmechanismus zwischen Bakteriostatika und Bakteriziden, Fungistatika und Fungiziden usw. Wichtige Stoffe aus diesen Gruppen sind beispielsweise Benzalkoniumchloride, Alkylarylsulfonate, Halogenphenole und Phenolmercuriacetat, wobei bei den erfindungemäßen Wasch- oder Reinigungsmitteln auch gänzlich auf diese Verbindungen verzichtet werden kann.To combat microorganisms washing or cleaning agents may contain antimicrobial agents. Depending on the antimicrobial spectrum and mechanism of action, a distinction is made between bacteriostatic agents and bactericides, fungistats and fungicides, etc. Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenolmercuric acetate, and the compounds according to the invention can be completely dispensed with in these detergents or cleaners ,

Die erfindungsgemäßen Wasch- oder Reinigungsmittel können Konservierungsmittel enthalten, wobei vorzugsweise nur solche eingesetzt werden, die kein oder nur ein geringes hautsensibilisierendes Potential besitzen. Beispiele sind Sorbinsäure und seine Salze, Benzoesäure und seine Salze, Salicylsäure und seine Salze, Phenoxyethanol, 3-lod-2-propynylbutylcarbamat, Natrium N-(hydroxymethyl)glycinat, Biphenyl-2-ol sowie Mischungen davon. Ein geeignetes Konservierungsmittel stellt die lösungsmittelfreie, wässrige Kombination von Diazolidinylharnstoff, Natriumbenzoat und Kaliumsorbat (erhältlich als Euxyl® K 500 ex Schuelke & Mayr) dar, welches in einem pH-Bereich bis 7 eingesetzt werden kann.The detergents or cleaners according to the invention may contain preservatives, it being preferred to use only those which have no or only a low skin-sensitizing potential. Examples are sorbic acid and its salts, benzoic acid and its salts, salicylic acid and its salts, phenoxyethanol, 3-iodo-2-propynyl butylcarbamate, sodium N- (hydroxymethyl) glycinate, biphenyl-2-ol and mixtures thereof. A suitable preservative is the solvent-free, aqueous combination of diazolidinyl urea, sodium benzoate and potassium sorbate (available as Euxyl® K 500 ex Schuelke & Mayr), which can be used in a pH range up to 7.

Um unerwünschte, durch Sauerstoffeinwirkung und andere oxidative Prozesse verursachte Veränderungen an den Wasch- oder Reinigungsmittel und/oder den behandelten textilen Flächengebilden zu verhindern, können die Wasch- oder Reinigungsmittel Antioxidantien enthalten. Zu dieser Verbindungsklasse gehören beispielsweise substituierte Phenole, Hydrochinone, Brenzcatechine und aromatische Amine sowie organische Sulfide, Polysulfide, Dithiocarbamate, Phosphite, Phosphonate und Vitamin E.In order to prevent undesirable changes to the detergents or cleaners and / or the treated fabrics caused by the action of oxygen and other oxidative processes, the detergents or cleaners may contain antioxidants. This class of compounds includes, for example, substituted phenols, hydroquinones, catechols and aromatic amines, as well as organic sulfides, polysulfides, dithiocarbamates, phosphites, phosphonates and vitamin E.

Ein erhöhter Tragekomfort kann aus der zusätzlichen Verwendung von Antistatika resultieren, die den Wasch- oder Reinigungsmitteln beigefügt werden. Die zumeist grenzflächenaktiven Antistatika lassen sich in stickstoffhaltige (Amine, Amide, quartäre Ammoniumverbindungen), phosphorhaltige (Phosphorsäureester) und schwefelhaltige (Alkylsulfonate, Alkylsulfate) Antistatika unterteilen.Increased comfort may result from the additional use of antistatic agents added to the detergents or cleaners. The most surface-active antistatic agents can be subdivided into nitrogen-containing (amines, amides, quaternary ammonium compounds), phosphorus-containing (phosphoric acid esters) and sulfur-containing (alkyl sulfonates, alkyl sulfates) antistatic agents.

Zur Verbesserung des der Wiederbenetzbarkeit der behandelten textilen Flächengebilde und zur Erleichterung des Bügelns der behandelten textilen Flächengebilde können in den Wasch- oder Reinigungsmitteln beispielsweise Silikonderivate eingesetzt werden. Diese verbessern zusätzlich das Ausspülverhalten der Wasch- oder Reinigungsmittel durch ihre schauminhibierenden Eigenschaften.To improve the rewettability of the treated fabrics and to facilitate the ironing of the treated fabrics, for example, silicone derivatives can be used in the detergents or cleaners. These additionally improve the rinsing behavior of the washing or cleaning agents by their foam-inhibiting properties.

Schließlich können die Wasch- oder Reinigungsmittel auch UV-Absorber enthalten. Geeignete Verbindungen umfassen Benzophenon mit Substituenten in 2- und/oder 4-Stellung oder substituierte Benzotriazole.Finally, the detergents or cleaning agents may also contain UV absorbers. Suitable compounds include benzophenone having substituents in the 2- and / or 4-position or substituted benzotriazoles.

Um die durch Schwermetalle katalysierte Zersetzung bestimmter Waschmittel-Inhaltsstoffe zu vermeiden, können Stoffe eingesetzt werden, die Schwermetalle komplexieren. Geeignete Schwermetallkomplexbildner sind beispielsweise die Alkalisalze der Ethylendiamintetraessigsäure (EDTA) oder der Nitrilotriessigsäure (NTA) sowie Alkalimetallsalze von anionischen Polyelektrolyten wie Polymaleaten und Polysulfonaten. Eine bevorzugte Klasse von Komplexbildnern sind die Phosphonate. Zu diesen bevorzugten Verbindungen zählen insbesondere Organophosphonate wie beispielsweise 1-Hydroxyethan-1,1-diphosphonsäure (HEDP), Aminotri(methylenphosphonsäure) (ATMP), Diethylentriamin-penta(methylenphosphonsäure) (DTPMP bzw. DETPMP) sowie 2-Phosphonobutan-1,2,4-tricarbonsäure (PBS-AM), die zumeist in Form ihrer Ammonium- oder Alkalimetallsalze eingesetzt werden.In order to avoid the catalyzed by heavy metals decomposition of certain detergent ingredients, substances that complex heavy metals can be used. Suitable heavy metal complexing agents are, for example, the alkali metal salts of ethylenediaminetetraacetic acid (EDTA) or nitrilotriacetic acid (NTA) and alkali metal salts of anionic polyelectrolytes such as polymaleates and polysulfonates. A preferred class of complexing agents are the phosphonates. These preferred compounds include in particular organophosphonates such as 1-hydroxyethane-1,1-diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriamine penta (methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane-1,2 , 4-tricarboxylic acid (PBS-AM), which are used mostly in the form of their ammonium or alkali metal salts.

Zusätzlich können noch neutrale Füllsalze wie Natriumsulfat oder Natriumcarbonat in den festen Wasch- oder Reinigungsmitteln enthalten sein.In addition, neutral fillers such as sodium sulfate or sodium carbonate may be included in the solid detergents or cleaners.

Die erfindungsgemäßen Wasch- oder Reinigungsmittel können insbesondere zum Reinigen und Konditionieren von textilen Flächengebilden verwendet werden.The washing or cleaning agents according to the invention can be used in particular for cleaning and conditioning textile fabrics.

Zur Herstellung der erfindungsgemäßen Wasch- oder Reinigungsmittel wird zunächst das Wasch- oder Reinigungsmittel ohne die Textil-pflegende Verbindung nach bekannten Verfahren, welche beispielsweise Trocknungsschritte, Mischungsschritte, Verdichtungsschritte, Formgebungsschritte und/oder die nachträgliche Zugabe wärmeempfindlicher Inhaltsstoffe ("Post Addition") umfassen können, hergestellt. Anschließend wird das erhaltene Produkt mit einer festen Textil-pflegenden Zusammensetzung vermischt. Zur Herstellung von Wasch- oder Reinigungsmitteltabletten können sich dem Mischungsschritt weitere Verdichtungs- und/oder Formgebungsschritte anschließen.For the preparation of detergents or cleaning agents according to the invention, the washing or cleaning agent without the textile-care compound is first prepared by known processes, which include, for example, drying steps, mixing steps, densification steps, shaping steps and / or the subsequent addition of heat-sensitive ingredients ("post-addition") may be prepared. Subsequently, the resulting product is mixed with a solid textile-care composition. For the preparation of detergent tablets, the mixing step may be followed by further compaction and / or shaping steps.

In Tabelle 1 sind erfindungsgemäße Textil-pflegende Zusammensetzungen E1 bis E4 sowie eine nicht erfindungsgemäße Zusammensetzung V1 gezeigt. Tabelle 1: V1 E1 E2 E3 E4 Saccharose-Kristalle (1 - 4 mm) 69,99 69,99 69,99 69,99 69,99 Bentonit (Pulver) 10 9 9 9 9 Methylhydroxypropylcellulose* -- 1 -- -- -- Hydroxyethylcellulose* -- -- 1 -- -- Methylcellulose* -- -- -- 1 -- Kationische Hydroxyethylcellulose* -- -- -- -- 1 Parfüm 5 5 5 5 5 PEG 8000 15 15 15 15 15 Farbstoff (blau) 0,01 0,01 0,01 0,01 0,01 * Die Cellulosederivate wurden allesamt in Pulverform eingesetzt. Table 1 shows textile-care compositions E1 to E4 according to the invention and a composition V1 not according to the invention. Table 1: V1 E1 E2 E3 E4 Sucrose crystals (1 - 4 mm) 69.99 69.99 69.99 69.99 69.99 Bentonite (powder) 10 9 9 9 9 methylhydroxypropylcellulose * - 1 - - - hydroxyethyl * - - 1 - - Methylcellulose * - - - 1 - Cationic hydroxyethylcellulose * - - - - 1 Perfume 5 5 5 5 5 PEG 8000 15 15 15 15 15 Dye (blue) 0.01 0.01 0.01 0.01 0.01 * The cellulose derivatives were all used in powder form.

Zur Herstellung der erfindungsgemäßen Textil-pflegenden Zusammensetzungen E1 bis E4 wurde das Polyethylenglykol mit einer mittleren Molmasse von 8.000 (PEG 8.000) geschmolzen und in die Schmelze wurden das Parfüm und der Farbstoff gegeben. Anschließend wurde die gefärbte Schmelze auf die Saccharose-Kristalle gegeben und die umhüllten Saccharose-Kristalle wurden unter Rühren mit einer Mischung aus Bentonit-Pulver und Cellulosederivat-Pulver abgepudert während die Schmelze aus PEG 8000, Parfüm und Farbstoff noch nicht vollständig erstarrt war.To prepare the textile-care compositions E1 to E4 according to the invention, the polyethylene glycol having an average molecular weight of 8,000 (PEG 8,000) was melted and the perfume and the dye were introduced into the melt. Subsequently, the colored melt was added to the sucrose crystals and the coated sucrose crystals were powdered with stirring with a mixture of bentonite powder and cellulose derivative powder while the melt of PEG 8000, perfume and dye was not completely solidified.

Die erfindungsgemäßen Zusammensetzungen E1 bis E4 zeigten im frisch hergestellten Zustand ein besseres Fließverhalten als die Vergleichszusammensetzung V1. Außerdem besaßen alle Zusammensetzungen E1 bis E4 und V1 im frischen Zustand eine klare, kristalline Optik.The inventive compositions E1 to E4 showed a better flow behavior in the freshly prepared state than the comparative composition V1. In addition, all of the compositions E1 to E4 and V1 had a clear, crystalline appearance when fresh.

Nach 4 Wochen Lagerung bei Raumtemperatur begann die textil-pflegende Zusammensetzung V1 an Klarheit zu verlieren. Bereits nach 8 Wochen Lagerung hatten die Kristalle V1 ihre klare Optik vollständig verloren und wiesen sogar eine deutliche Farbveränderung auf.After 4 weeks storage at room temperature, the fabric care composition V1 began to lose clarity. Already after 8 weeks storage the crystals V1 had completely lost their clear optics and even showed a clear color change.

Dagegen wiesen insbesondere die Methylhydroxypropylcellulose-, Methylcellulose- und Hydroxyethylcellulose-enthaltenden textil-pflegenden Zusammensetzungen E1 bis E3 nach 8 Wochen Lagerzeit bei Raumtemperatur eine klare Optik und keinerlei Farbveränderungen auf. Die Methylcellulose- und Hydroxyethylcellulose-enthaltenden textil-pflegenden Zusammensetzungen E2 und E3 zeigten auch nach 12 Wochen Lagerzeit noch ein klares, kristallines Aussehen und wiesen keinerlei Farbveränderungen auf. Als besonders stabil in Bezug auf Klarheit erwiesen sich die Hydroxyethylcellulose-enthaltende textil-pflegende Zusammensetzung E3, welche nach 24 Wochen noch eine klare, kristalline Optik aufwiesen. Außerdem zeigten die Kristalle E3 auch nach 24 Wochen keinerlei Farbveränderungen. Die textil-pflegende Zusammensetzung E4 zeigte auch nach 8 Wochen Lagerzeit bei Raumtemperatur eine klare Optik, jedoch konnte auch eine leichte Neigung zur Bildung kleinerer Aggregate beobachtet werden.In contrast, especially the methylhydroxypropylcellulose, methylcellulose and hydroxyethylcellulose-containing textile-care compositions E1 to E3 after 8 weeks storage at room temperature had a clear appearance and no color changes. The methylcellulose and hydroxyethylcellulose-containing textile-care compositions E2 and E3 still showed a clear, crystalline appearance after 12 weeks of storage and showed no color changes. The hydroxyethyl cellulose-containing textile-care composition E3, which still had a clear, crystalline appearance after 24 weeks, proved to be particularly stable in terms of clarity. In addition, the crystals E3 showed no color changes even after 24 weeks. The textile-care composition E4 showed a clear appearance even after 8 weeks storage at room temperature, but also a slight tendency to form smaller aggregates could be observed.

Die Textil-pflegenden Zusammensetzungen E1 bis E4 zeigten ein sehr gutes Auflösungsverhalten bei Kontakt mit Wasser und im Vergleich mit Wasser einen weichmachenden Effekt bezüglich damit behandelter textiler Flächengebilde. Außerdem zeigten die Textil-pflegenden Zusammensetzungen E1 bis E4 an feuchter, frisch gewaschener Wäsche eine deutlich höhere Duftintensität verglichen mit Wäsche, die mit einem herkömmlichen flüssigen, Esterquat-haltigen Weichspüler behandelt wurde.The textile care compositions E1 to E4 showed a very good dissolution behavior when in contact with water and, compared with water, a softening effect with respect to fabrics treated therewith. In addition, the textile care compositions E1 to E4 on wet, freshly laundered laundry exhibited a significantly higher scent intensity compared to laundry treated with a conventional liquid esterquat-containing softener.

In Tabelle 2 sind weitere erfindungsgemäße Textil-pflegende Zusammensetzungen E5 bis E7 sowie eine nicht erfindungsgemäße Zusammensetzung V2 gezeigt. Tabelle 2: V2' E5 E6 E7 Saccharose-Kristalle (1 - 4 mm) 69,99 69,99 69,99 69,99 Bentonit (Pulver) 10 9,5 9 8 Carboxymethylcellulose, Na-Salz* -- 0,5 1 2 Parfüm 5 5 5 5 PEG 8000 15 15 15 15 Farbstoff (blau) 0,01 0,01 0,01 0,01 * Das Cellulosederivat wurde in Pulverform eingesetzt. Table 2 shows further textile care compositions E5 to E7 according to the invention and a composition V2 not according to the invention. Table 2: V2 ' E5 E6 E7 Sucrose crystals (1 - 4 mm) 69.99 69.99 69.99 69.99 Bentonite (powder) 10 9.5 9 8th Carboxymethyl cellulose, Na salt * - 0.5 1 2 Perfume 5 5 5 5 PEG 8000 15 15 15 15 Dye (blue) 0.01 0.01 0.01 0.01 * The cellulose derivative was used in powder form.

Zur Herstellung der erfindungsgemäßen Textil-pflegenden Zusammensetzungen E5 bis E7 wurde das Polyethylenglykol mit einer mittleren Molmasse von 8000 (PEG 8000) geschmolzen und in die Schmelze wurden das Parfüm und der Farbstoff gegeben. Anschließend wurde die gefärbte Schmelze auf die Saccharose-Kristalle gegeben und die umhüllten Saccharose-Kristalle mit einer Mischung aus Bentonit-Pulver und dem Cellulosederivat-Pulver abgepudert während die Schmelze aus PEG 8000, Parfüm und Farbstoff noch nicht vollständig erstarrt war.For the preparation of the textile-care compositions E5 to E7 according to the invention, the polyethylene glycol having an average molecular weight of 8000 (PEG 8000) was melted and the perfume and the dye were added to the melt. Subsequently, the colored melt was added to the sucrose crystals and the coated sucrose crystals were powdered with a mixture of bentonite powder and the cellulose derivative powder while the melt of PEG 8000, perfume and dye was not completely solidified.

Die Zusammensetzungen E5 bis E7 und V2 besaßen im frisch hergestellten Zustand eine klare, kristalline Optik. Nach 4 Wochen Lagerung bei Raumtemperatur begann die textil-pflegende Zusammensetzung V2 an Klarheit zu verlieren. Bereits nach 8 Wochen Lagerung bei Raumtemperatur hatten die Kristalle V2 ihre klare Optik vollständig verloren und wiesen eine deutliche Farbveränderung auf.The compositions E5 to E7 and V2 had a clear, crystalline appearance in the freshly prepared state. After 4 weeks of storage at room temperature, the textile-care composition V2 began to lose its clarity. Already after 8 weeks of storage at room temperature, the crystals V2 had completely lost their clear appearance and showed a clear color change.

Auch die erfindungsgemäße Textil-pflegende Zusammensetzung E5 zeigte nach 4 Wochen Lagerung einen Verlust in der Klarheit. Dieser Verlust an Klarheit war aber geringer als bei der nicht erfindungsgemäßen Textil-pflegenden Zusammensetzung V2. Die beiden erfindungsgemäßen Textil-pflegenden Zusammensetzung E6 und E7 waren auch nach 8 Wochen Lagerung klar und farbstabil, während die nicht erfindungsgemäße Textil-pflegende Zusammensetzung V2 ihre Farbe vollständig verändert und ihre Klarheit verloren hatte. Die erfindungsgemäße Textil-pflegende Zusammensetzung E5 zeigte nach 8 Wochen Lagerung einen weiteren leichten Verlust in der Klarheit und eine leichte Veränderung der Farbe.The textile care composition E5 according to the invention also showed a loss in clarity after 4 weeks of storage. However, this loss of clarity was lower than in the non-inventive textile-care composition V2. The two textile care compositions E6 and E7 according to the invention were clear and color-stable even after 8 weeks of storage, while the textile care composition V2 not according to the invention completely changed its color and lost its clarity. The textile care composition E5 according to the invention showed, after 8 weeks of storage, a further slight loss in clarity and a slight change in color.

Eine besonders farbstabile Textil-pflegende Zusammensetzung E8 mit schöner, kristalliner Optik wurde bei Einsatz von Diethylaminoethyl-hydroxyethylcellulose als Polysaccharid erhalten. E8 Saccharose-Kristalle (1 - 4 mm) 69,99 Bentonit (Pulver) 9,5 Amin-substituiertes Cellulosederivat* 0,5 Parfüm 5 PEG 8000 15 Farbstoff (blau) 0,01 * Das Cellulosederivat wurde in Pulverform eingesetzt. A particularly color-stable textile care composition E8 with beautiful, crystalline appearance was obtained when using diethylaminoethyl-hydroxyethylcellulose as a polysaccharide. E8 Sucrose crystals (1 - 4 mm) 69.99 Bentonite (powder) 9.5 Amine-substituted cellulose derivative * 0.5 Perfume 5 PEG 8000 15 Dye (blue) 0.01 * The cellulose derivative was used in powder form.

Zur Herstellung der erfindungsgemäßen Textil-pflegenden Zusammensetzung E8 wurde das Polyethylenglykol mit einer mittleren Molmasse von 8000 (PEG 8000) geschmolzen und in die Schmelze wurden das Parfüm und der Farbstoff gegeben. Anschließend wurde die gefärbte Schmelze auf die Saccharose-Kristalle gegeben und die umhüllten Saccharose-Kristalle mit einer Mischung aus Bentonit-Pulver und dem Cellulosederivat-Pulver abgepudert während die Schmelze aus PEG 8000, Parfüm und Farbstoff noch nicht vollständig erstarrt war.To prepare the textile care composition E8 of the present invention, the polyethylene glycol having an average molecular weight of 8,000 (PEG 8,000) was melted, and the perfume and the dye were added to the melt. Subsequently, the colored melt was added to the sucrose crystals and the coated sucrose crystals were powdered with a mixture of bentonite powder and the cellulose derivative powder while the melt of PEG 8000, perfume and dye was not completely solidified.

Die erfindungsgemäßen Textil-pflegenden Zusammensetzung E8 war auch nach 20 Wochen Lagerung immer noch kristallin-klar und zeigte keinerlei Veränderung der Farbe.The textile-care composition E8 according to the invention was still crystal clear after 20 weeks of storage and showed no change in color.

Bei der Herstellung der textil-pflegenden Zusammensetzungen E1 bis E8 sowie V1 und V2 konnten die erfindungsgemäßen textil-pflegenden Zusammensetzungen E1 bis E8 bei deutlich höheren Produktendtemperaturen verglichen mit den textil-pflegenden Zusammensetzungen V1 und V2 abgefüllt werden. Außerdem zeigten insbesondere die erfindungsgemäßen textil-pflegenden Zusammensetzungen E1 bis E3 sowie E5 bis E8 weder bei der Herstellung noch bei der Lagerung keinerlei Tendenzen zu verklumpen bzw. zu agglomerieren. Die Agglomerisationsneigung bei der Lagerung der Textil-pflegenden Zusammensetzung E4 war nur gering und wirkte sich nicht negativ auf die Handhabung und insbesondere auf das Dosierverhalten der Textil-pflegenden Zusammensetzung E4 aus.In the preparation of the textile-care compositions E1 to E8 and V1 and V2 , the textile-care compositions E1 to E8 according to the invention could be filled at significantly higher product end temperatures compared with the textile-care compositions V1 and V2 . In addition, in particular the textile-care compositions E1 to E3 according to the invention and E5 to E8 showed no tendencies to agglomerate or agglomerate neither during production nor during storage. The agglomeration tendency during storage of the textile-care composition E4 was only slight and did not adversely affect the handling and in particular the metering behavior of the textile-care composition E4 .

Zur Herstellung eines erfindungsgemäßen Wasch- oder Reinigungsmittels wurde ein festes, unparfümiertes Wasch- oder Reinigungsmittel mit 15 Gew.-% (bezogen auf die Gesamtmenge an fertigem Wasch- oder Reinigungsmittel) der Textil-pflegenden Zusammensetzung E3 gemischt.To prepare a washing or cleaning agent according to the invention, a solid, unscented washing or cleaning agent was mixed with 15% by weight (based on the total amount of finished washing or cleaning agent) of the textile-care composition E3 .

Das erfindungsgemäßen Wasch- oder Reinigungsmittel zeigte gute reinigende und konditionierende Eigenschaften.The washing or cleaning agent according to the invention showed good cleaning and conditioning properties.

Weder bei separater Verwendung der Textil-pflegenden Verbindung noch eingebracht in einem Wasch- oder Reinigungsmittel wurden Kalkablagerungen auf der Wäsche und/oder Ablagerungen/Rückstände in der Einspülkammer der Waschmaschinen beobachtet. Außerdem behielten die festen Textil-pflegenden Zusammensetzungen ihre Farbe und ihre kristalline Optik.Lime deposits on the laundry and / or deposits / residues in the dispensing compartment of the washing machines were not observed either with separate use of the textile-care compound or incorporated in a washing or cleaning agent. In addition, the solid fabric care compositions retained their color and crystalline appearance.

Claims (15)

  1. A solid, fabric care composition comprising a water-soluble carrier, a water-soluble polymer, a fabric care compound, a polysaccharide and a perfume, wherein the water-soluble carrier is present in particulate form and at least partially possesses a coating of the water-soluble polymer and the perfume, and a mixture of the fabric care compound and the polysaccharide is at least partially present in and/or at least partially on the coating.
  2. The solid, fabric care composition according to claim 1, characterized in that the water-soluble carrier is selected from the group consisting of inorganic alkali metal salts, organic alkali metal salts, inorganic alkaline earth metal salts, organic alkaline earth metal salts, organic acids, carbohydrates, silicates, urea and mixtures thereof.
  3. The solid, fabric care composition according to claim 1 or claim 2, characterized in that the fabric care compound is selected from fabric-softening compounds, bleaching agents, bleach activators, enzymes, silicone oils, anti-redeposition agents, optical brighteners, graying inhibitors, shrink inhibitors, anti-creasing agents, color transfer inhibitors, antimicrobials, germicides, fungicides, antioxidants, antistats, ironing auxiliaries, water proofing and impregnation agents, swelling and anti-slip agents, UV absorbers and mixtures thereof.
  4. The solid, fabric care composition according to one of claims 1 to 3, characterized in that the fabric care compound is a fabric softening compound.
  5. The solid, fabric care composition according to claim 4, characterized in that the fabric softening compound is selected from polysiloxanes, fabric softening clays, cationic polymers and mixtures thereof.
  6. The solid, fabric care composition according to one of claims 1 to 5, characterized in that the water-soluble polymer is selected from polyalkylene glycols, polyvinyl alcohols and mixtures thereof.
  7. The solid, fabric care composition according to one of claims 1 to 6, characterized in that the polysaccharide is selected from the group containing glycogen, starch, chitin, callose, cellulose, dextran, tunicin, inulin, alginic acid, xanthane, gellan, guar, carob flour, carrageenan, derivatives of these compounds or mixtures of these compounds and their derivatives.
  8. The solid, fabric care composition according to claim 7, characterized in that the polysaccharide contained in the mixture is cellulose or a cellulose derivative, selected from the group comprising methyl cellulose, ethyl cellulose, propyl cellulose, methyl ethyl cellulose, carboxymethyl cellulose, ethyl carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl hydroxyethyl cellulose, methyl hydroxyethyl cellulose, hydroxypropyl methyl cellulose, ethyl hydroxyethyl cellulose, methyl ethyl hydroxyethyl cellulose, quaternized cellulose, quaternized cellulose derivatives, amine-modified cellulose, amine-modified cellulose derivatives or mixtures of these compounds.
  9. The solid, fabric care composition according to one of claims 1 to 8, characterized in that the solid, fabric care composition comprises additional ingredients, preferably selected from the group consisting of colorants, fillers, pearlizers, skin care compounds, bitter agents and mixtures thereof.
  10. The solid, fabric care composition according to one of claims 1 to 9, characterized in that the mixture of the fabric care compound and the polysaccharide is at least partially incorporated into the coating.
  11. The solid, fabric care composition according to one of claims 1 to 9, characterized in that the coating or the coating and the non-coated area of the water-soluble carrier is/are at least partially coated with a mixture of the fabric care compound and the polysaccharide.
  12. Use of the solid, fabric care composition according to one of claims 1 to 11 for conditioning textile fabrics.
  13. A process for manufacturing a solid, fabric care composition, containing a particulate water-soluble carrier, a water-soluble polymer, a fabric care compound, a polysaccharide and a perfume, in which process the water-soluble polymer is melted, is mixed in the molten state with the perfume, the resulting melt is added onto the particulate carrier such that said carrier is at least partially coated and then a mixture of the fabric care compound and the polysaccharide is incorporated into the still molten coating.
  14. A process for manufacturing a solid, fabric care composition, containing a particulate water-soluble carrier, a water-soluble polymer, a fabric care compound, a polysaccharide and a perfume, in which process the water-soluble polymer is melted, is mixed in the molten state with the perfume, the resulting melt is added to the particulate carrier such that said carrier is at least partially coated and the at least partially coated particulate carrier is coated with a mixture of the fabric care compound and the polysaccharide.
  15. A washing or cleaning agent comprising a solid, fabric care composition according to one of claims 1 to 11.
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DE200810047233 DE102008047233A1 (en) 2008-09-12 2008-09-12 Solid textile care composition, useful for conditioning textile fabrics and in detergents and cleaning products, comprises water-soluble carrier, water-soluble polymer, textile care compound, polysaccharide and fragrance
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