EP2203062A2 - Active ingredient combinations having insecticidal and acaricidal properties - Google Patents

Active ingredient combinations having insecticidal and acaricidal properties

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Publication number
EP2203062A2
EP2203062A2 EP08785847A EP08785847A EP2203062A2 EP 2203062 A2 EP2203062 A2 EP 2203062A2 EP 08785847 A EP08785847 A EP 08785847A EP 08785847 A EP08785847 A EP 08785847A EP 2203062 A2 EP2203062 A2 EP 2203062A2
Authority
EP
European Patent Office
Prior art keywords
alkyl
spp
alkoxy
inhibitors
optionally substituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP08785847A
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German (de)
French (fr)
Inventor
Reiner Fischer
Wolfram Andersch
Heike Hungenberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer CropScience AG
Original Assignee
Bayer CropScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer CropScience AG filed Critical Bayer CropScience AG
Priority to EP08785847A priority Critical patent/EP2203062A2/en
Publication of EP2203062A2 publication Critical patent/EP2203062A2/en
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

Definitions

  • the present invention relates to novel drug combinations consisting of known spiroketalsubstitu convinced tetramic acid on the one hand and other insecticidal active ingredients on the other hand and are very suitable for controlling animal pests such as insects and / or unwanted acarids.
  • EP-A-0 262 399 and GB-A-2 266 888 disclose similarly structured compounds (3-arylpyrrolidine-2,4-diones), of which, however, no herbicidal, insecticidal or acaricidal action has become known. Unsubstituted, bicyclic 3-arylpyrrolidine-2,4-dione derivatives are known (EP-A-355 599, EP-A-415 21 1 and JP-A-12-053.) With herbicidal, insecticidal or acaricidal activity 670) as well as substituted monocyclic 3-aryl-pyrrolidine-2,4-dione derivatives (EP-A-377 893 and EP-A-442 077).
  • EP-A-442 073 polycyclic 3-arylpyrrolidine-2,4-dione derivatives
  • EP-A-456 063 EP-A-521 334, EP-A- 596 298, EP-A-613 884, EP-A-613 885, WO 94/01 997, WO 95/26 954, WO 95/20 572, EP-A-0 668 267, WO 96/25 395, WO 96 / 35,664, WO 97/01 535, WO 97/02 243, WO 97/36868, WO 97/43275, WO 98/05638, WO 98/06721, WO 98/25928, WO 99/24437, WO 99/43649 , WO 99/48869 and WO 99/55673, WO 01/17972, WO 01/23354, WO 01/74770, WO 03/013249, WO 03
  • ketal-substituted 1-H-arylpyrrolidine-2,4-diones from WO 99/16748 and (spiro) ketal-substituted N-alkoxy-alkoxy-substituted aryl-pyrrolidinediones are disclosed in JP-A-14 205 984 and Ito M. et. al Bioscience, Biotechnology and Biochemistry 67, 1230-1238, (2003).
  • the addition of safeners to ketoenols is also known in principle from WO 03/013249.
  • WO 06/02441 1 discloses herbicidal compositions containing ketoenols.
  • acaricidal and / or insecticidal activity and / or range of action and / or the plant tolerance of the known compounds, in particular to crops, is but not always enough.
  • W is hydrogen, alkyl, alkenyl, alkynyl, halogen, alkoxy, haloalkyl, haloalkoxy or cyano,
  • X is halogen, alkyl, alkenyl, alkynyl, alkoxy, haloalkyl, haloalkoxy, nitro or cyano,
  • Y and Z independently of one another represent hydrogen, alkyl, alkenyl, alkynyl, alkoxy, halogen, haloalkyl, haloalkoxy, cyano or nitro,
  • a and B and the carbon atom to which they are attached are each optionally substituted by alkyl, haloalkyl, alkoxy, alkoxyalkyl or optionally substituted phenyl five- to seven-membered ketal, thioketal or dithioketal, which may optionally be interrupted by another heteroatom,
  • G is hydrogen (a) or one of the groups
  • E is a metal ion or an ammonium ion
  • L is oxygen or sulfur
  • M is oxygen or sulfur
  • R.1 is in each case optionally substituted by halogen or cyano-substituted alkyl, alkenyl,
  • R represents in each case optionally halogen or cyano-substituted alkyl, alkenyl, alkoxyalkyl or polyalkoxyalkyl or in each case optionally substituted cycloalkyl, phenyl or benzyl,
  • R 1, R 4 and R 1 independently of one another are each optionally halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio or cycloalkylthio or in each case optionally substituted phenyl, benzyl, phenoxy or phenylthio,
  • R6 and R4 independently of one another represent hydrogen, in each case optionally halogen or cyano-substituted alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, in each case optionally substituted phenyl or benzyl, or together with the N-atom to which they are attached, form an optionally oxygen or sulfur containing and optionally substituted cycle
  • insecticides and / or acaricides of the formula (II) are very good are suitable for controlling animal pests such as insects and / or acarids.
  • the active substances of the formula (II) are assigned according to the IRAC classification (Version 5.3 July 2007) into different classes (1-30) and groups according to their mechanism of action:
  • Acetylcholinesterase (AChE) inhibitors II-l are Acetylcholinesterase (AChE) inhibitors II-l
  • a carbamates for example alanycarb (II-l.Al), aldicarb (II-lA-2), aldoxycarb (II-lA-3), allyxycarb (II-l .A-4), aminocarb (II -l .A-5), bendiocarb (II-l .A-6), benfuracarb (II-l .A-7), bufencarb (II-lA-8), butacarb (II-lA-9), butocarboxime ( II-l.A-10), butoxycarboxime (II-l.A-II),
  • Carbaryl (II-IA-12), Carbofuran (II-IA-13), Carbosulfan (II-IA-14), Cloethocarb (II-IA-15), Dimetilane (II-IIA-16), Ethiofencarb (II A-17), fenobucarb (II-l.
  • Fosmethilane (II-lB-40), fosthiazate ( ⁇ -lB-41), heptenophos ( ⁇ -lB-42), iodofenofen (II-lB-43), Iprobenfos (II-lB-44), isazofos ( ⁇ -lB -45), isofenphos (II-lB-46), isopropyl (II-lB-47), o-salicylates ( ⁇ -lB-48), isoxathione ( ⁇ -lB-49), malathion (II-lB-50) , Mecarbam ( ⁇ -1 .B-51), methacrifos ( ⁇ -1 .B-52), methamidophos (--1 .B-53), methidathione (II-1 .B-54), mevinphos ( ⁇ -1 .B -55), monocrotophos ( ⁇ -1 .B-56), naled ( ⁇
  • Triazophos ( ⁇ -1 .B-86), triclorfone (--1 .B-87), vamidothion ( ⁇ -1 .B-88)
  • Organochlorines for example, camphechloro (II-2A-1), chlordane (II-2A-2), endosulfan (II-2A-3), gamma-HCH (II-2A-4), HCH (II-2A -5), heptachlor (II-2A-6), lindane (II-2A-7), methoxychlor
  • II-2B Fiproles phenylpyrazoles
  • acetoproles II-2B-1
  • ethiproles II-2B-2
  • fipronil II-2B-3
  • pyrafluproles II-2B-4
  • pyriproles ⁇ - 2B-5
  • vaniliprole II-2B-6
  • II-3 pyrethroids for example, acrinathrin (II-3-1), allethrin (d-cis-trans, d-trans) (II-3-2), beta-cyfluthrin (II-3-3), bifenthrin (II -3-4), bioallethrin (II-3-5), bioallethrin S-cyclopentyl isomer (II-3-6), bioethanomethrin (II-3-7), biopermethrin (II-3-8), bioresmethrin ( II-3-9), chlovaporthrin (II-3-10), cis-cypermethrin ( ⁇ -3-1 1), cis-resmethrin (II-3-12), cis-cypermethrin
  • II-4A-1 acetamiprid
  • II-4A-2 clothianidin
  • II-4A-3 dinotefuran
  • imidacloprid II-4A-4
  • imidaclothiz II-4A-5
  • nitenpyram II -4A-6
  • nithiazines II-4A-7
  • thiacloprid II-4A-8
  • thiamethoxam II-4A-9
  • spinosyns for example spinosad (II-5-1), spinetoram (II-5-2)
  • II-6 Mectins / Macrolides for example, Abamectin (II-6-1), Emamectin (II-6-2), Emamectin benzoate (II-6-3), Ivermectin (11-6-4), Lepimectin (II -6-5), milbemectin (II-6-6)
  • II-7A juvenile hormone analogs for example, hydroprene (II-7A-1), kinoprenes (II-7A-2), methoprene (II-7A-3), epofenonans (II-7A-4), triprene (II-7A-3) 5), fenoxycarb (II-7B-1), Pyriproxifen (II-7C-1), Diofenolane (II-7C-2)
  • ⁇ -8 fumigants for example methyl bromides (II-8A-1), chloropicrin (II-8B-1), sulfuryl fluorides (II-8C-1)
  • II-10 mite growth inhibitors for example clofentezine (II-1 OA-I), hexythiazox (II-10A-2), etoxazoles (II-1 OB-I)
  • II-12B organotin compounds for example azocyclotin (II-12B-1), cyhexatin (II-12B-2), fenbutatin oxides (II-12B-3)
  • II-12C propargite (II-12C-1), tetradifon (II-12C-2)
  • Chlorfenapyr ( ⁇ -13-1)
  • Binapacyrl (II-13-2), dinobutone ( ⁇ -13-3), dinocap (II-13-4), DNOC (II-13-5)
  • 11-15 benzoyl ureas for example bis-trifluron (H-15-1), chlorofluorazuron (ü-15-2), diflubenzuron (II-15-3), fluazuron (II-15-4), flucycloxuron (II-15-5 ), Flufenoxuron (II-15-6), hexaflumuron (FI-15-7), lufenuron (II-15-8), novaluron ( ⁇ -15-9), noviflumuron (11-15-10), penfluron (11 -15- 1 1), teflubenzuron ( ⁇ -15-12), triflumuron (11-15-13)
  • Diacylhydrazines for example Chromafenozide (U-18A-1), Halofenozide (II-18A-2), Methoxyfenozide (II-18A-3), Tebufenozide (II-l 8A-4), JS-1 18 (II -18A-5)
  • Octopaminergic agonists for example Amitraz (II-19-1)
  • Cyflumetofen (II-20D-1), Cyenopyrafen (Ü-20D-2)
  • fenazaquin II-21-1
  • fenpyroximate 11-21 -2
  • pyrimidifen 11-21 -3
  • Metaflumizone (BAS 3201) (II-22B-1)
  • tetronic acid derivatives for example spirodiclofen (11-23 A-I), spiromesifen (11-23 A-2)
  • the compounds of the formula (I) can also be present in different compositions as optical isomers or mixtures of isomers, which can optionally be separated in a customary manner. Both the pure isomers and the mixtures of isomers, their preparation and use and agents containing them are the subject of the present invention. In the following, however, for the sake of simplicity, reference is always made to compounds of the formula (I), although both the pure compounds and, if appropriate, mixtures with different proportions of isomeric compounds are meant.
  • A, B, E, L, M, W, X, Y, Z, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 7 have the meanings given above.
  • W is particularly preferably hydrogen, chlorine, bromine, C j -C ⁇ alkyl, Ci-C4-alkoxy, Ci - C 2 -haloalkyl or Ci-C 2 haloalkoxy,
  • X particularly preferably represents chlorine, bromine, Cj-C ⁇ alkyl, Ci-C4-alkoxy, C] -C4 halo alkyl, Cj-C4-haloalkoxy or cyano,
  • Y and Z are preferably each independently represent hydrogen, fluorine, chlorine, bromine, C] -C4 alkyl, Cj-Cg alkoxy, C] -C4-haloalkyl, Ci-C4-haloalkoxy or cyano,
  • a and B and the carbon atom to which they are attached particularly preferably represent an optionally mono- to trisubstituted by Ci-C 4 alkyl, C
  • E is a metal ion or an ammonium ion
  • M is oxygen or sulfur
  • RI more preferably represents in each case optionally mono- to trisubstituted by fluorine or chlorine, C] -C 6-alkyl, Ci-C2 6 alkenyl, C 1 -CG-alkoxy-C i-C4-alkyl, alkylthio CJ -C ⁇ - Ci-C4-alkyl or poly-C j -CG-alkoxy-Cj-C4-alkyl or represents optionally mono- to disubstituted by fluorine, chlorine, C1-C5 AHCVI or Ci-C5 alkoxy, C3-C7-cycloalkyl, in which optionally one or two are not directly adjacent
  • Methylene groups are replaced by oxygen and / or sulfur
  • R 1 particularly preferably represents in each case optionally monosubstituted to trisubstituted by fluorine or chlorine C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 1 -C 6 -alkoxy-C 2 -C 6 -alkyl or poly-C 1 -C 4 -alkyl -C 6 alkoxy-C 2 -C 6 -alkyl,
  • R 1 particularly preferably represents C 1 -C 5 -alkyl which is optionally monosubstituted to trisubstituted by fluorine or chlorine, or in each case optionally monosubstituted to fluorine,
  • R ⁇ and R ⁇ independently of one another particularly preferably in each case optionally mono- to trisubstituted by fluorine or chlorine, C] -C6 alkyl, Cj-C 6 -alkoxy, C j -C 6 - alkylamino, di- (C 1 - C 6 alkyl) amino, C 1 -C 6 alkylthio or C 3 -C 4 alkenylthio, or in each case optionally mono- or disubstituted by fluorine, chlorine, bromine, nitro, cyano, C 1 -C 3 -alkoxy, C 1 -C 4 -haloalkoxy, C j ⁇ alkylthio, C j ⁇ haloalkylthio, C1 -C3- alkyl, or Cj-C3-halogenoalkyl-substituted phenyl, phenoxy or phenylthio,
  • R 1 and R 2 independently of one another particularly preferably represent hydrogen, in each case optionally mono- to trisubstituted by fluorine or chlorine, C 1 -C 6 -alkyl,
  • halogen is fluorine, chlorine and bromine, in particular fluorine and chlorine.
  • W is very particularly preferably hydrogen, chlorine, bromine, methyl, ethyl, methoxy, ethoxy or trifluoromethyl,
  • X very particularly preferably represents chlorine, bromine, methyl, ethyl, methoxy, ethoxy, trifluoromethyl, difluoromethoxy, trifluoromethoxy or cyano
  • Y and Z very particularly preferably independently of one another represent hydrogen, fluorine, chlorine, bromine, methyl, ethyl, methoxy, trifluoromethyl, trifluoromethoxy or cyano
  • a and B and the carbon atom to which they are attached very particularly preferably represent a five- or six-membered ketal which is optionally mono- to disubstituted by methyl, ethyl, propyl, trifluoromethyl, monochloromethyl, methoxy, ethoxy, methoxymethyl or ethoxymethyl.
  • E is a metal ion or an ammonium ion
  • M is oxygen or sulfur
  • R.1 very particularly preferably represents in each case optionally mono- to trisubstituted by fluorine or chlorine, Ci -Cjo-alkyl, C2-C j o-alkenyl, Ci-C4-alkoxy-Ci-C2-alkyl, Ci-C4-alkylthio C 1 -C 2 -alkyl or, if appropriate, simply by fluorine, chlorine, methyl,
  • phenyl substituted once to twice by fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, n-propyl, i-propyl, methoxy, ethoxy, trifluoromethyl or trifluoromethoxy,
  • R.2 very particularly preferably represents in each case optionally mono- to trisubstituted by fluorine or chlorine, Cj-Cio-alkyl, C2-C ⁇ ) alkenyl, or C ⁇ -C4-alkoxy-C2-C4 alkyl,
  • R.3 very particularly preferably represents in each case optionally mono- to trisubstituted by fluorine or chlorine, methyl, ethyl, propyl or iso-propyl, or optionally simply by fluorine, chlorine, bromine, methyl, ethyl, iso-propyl, tert-butyl , Methoxy, ethoxy, isopropoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro substituted phenyl,
  • R.4 and R.5 independently of one another very particularly preferably represent C 1 -C 4 -alkoxy or C 1 -C 4 -alkylthio or in each case optionally simply by fluorine, chlorine, bromine, nitro, cyano, methyl, methoxy, trifluoromethyl or trifluoromethoxy substituted phenyl, phenoxy or phenylthio,
  • R east and R ⁇ are, independently of one another very particularly preferably represents hydrogen, Ci-C 4 - alkyl, CSS-Cg cycloalkyl, C 1 -C 4 -alkoxy, C3-C4 alkenyl, or Cj-C 4 -AIkOXy- C 2 -C 4 - alkyl, optionally mono- to disubstituted by fluorine, chlorine, bromine, methyl, methoxy or trifluoromethyl substituted phenyl, or together represent a C5-Cg-alkylene radical in which optionally a methylene group is replaced by oxygen or sulfur.
  • W is particularly preferably hydrogen, chlorine, bromine, methyl, ethyl or methoxy
  • X is particularly preferably chlorine, bromine, methyl, ethyl or methoxy
  • Y and Z are more preferably independently of one another hydrogen, chlorine, bromine or methyl
  • a and B and the carbon atom to which they are bonded are particularly preferably a five- or six-membered ketal which is optionally mono- to disubstituted by methyl, ethyl, propyl, monochloromethyl or methoxymethyl.
  • G is particularly preferably hydrogen (a) or one of the groups
  • R.2 especially preferably represents Cj-C j o-alkyl, C2-C jo-alkenyl, or benzyl.
  • the phenyl ring is highlighted substituted 3-fold, resulting in the following substitution patterns: 2,4,6-; 2,4,5- or 2,5,6-substitution.
  • the phenyl ring is highlighted substituted 4-fold, giving the following substitution pattern: 2,4,5,6-Substitution.
  • the phenyl ring is also pronouncedly substituted twice (2,4-; 2,5-position).
  • the phenyl ring is also pronouncedly substituted once (ortho position).
  • the remaining substituents W, X, Y, Z, G, A and B have the definitions given in the text.
  • Saturated or unsaturated hydrocarbon radicals such as alkyl, alkanediyl or alkenyl may also be used in conjunction with heteroatoms, e.g. in alkoxy, as far as possible, in each case straight-chain or branched.
  • optionally substituted radicals may be monosubstituted or polysubstituted, with multiple substituents being the same or different substituents could be.
  • insecticidal and / or acaricidal activity of the active compound combinations according to the invention is substantially higher than the sum of the effects of the individual active compounds. There is an unpredictable true synergistic effect and not just an effect supplement.
  • active compound combinations comprising at least one compound of the formulas (I-1) to (1-6) and at least one active compound of the formula (II).
  • R -CH 3 or -CO 2 CH 3
  • Teflubenzuron (11-15-12) known from EP-A-052 833 and / or
  • Buprofezin (II-16-l) known from DE-A-2 824 126 and / or
  • Tebufenozides (II-18A-4) known from EP-A-339 854 and / or
  • Chromafenocides ( ⁇ -18A-1)
  • Chlorantraniliprole (Rynaxapyr) (II-28-3)
  • Abamectin (II-o-l) is known from DE-A-2717040 and / or 61.
  • Ivermectin (II-6-4) is known from EP-A-001 689 and / or
  • Milbemectin (II-6-6) known from The Pesticide Manual, 1st edition, 1997, p. 846 and or
  • Chlorpyrifos (II-lB-12) known from US 3,244,586 and / or
  • Bacillus thuringiensis strains (11-30-1) and / or
  • the active ingredient combinations may also contain other fungicidal, acaricidal or insecticidal Zumischkomponenten beyond.
  • the combinations according to the invention contain active compounds of the formulas (I-1) to (1-6) and the mixing partner of the formula (II) in the preferred and particularly preferred mixing ratios indicated in the table below: the mixing ratios are based on weight ratios.
  • the ratio is to be understood as active substance of the formula (II): Mixture partner to formula (1-6): Mischpartner
  • the active compound combinations according to the invention are suitable for controlling animal pests, preferably arthropods and nematodes, in particular insects and arachnids, which occur in viticulture, fruit growing, in agriculture, animal health, in forests, in the protection of stored products and in the hygiene sector. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • animal pests preferably arthropods and nematodes, in particular insects and arachnids, which occur in viticulture, fruit growing, in agriculture, animal health, in forests, in the protection of stored products and in the hygiene sector. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • the above mentioned pests include:
  • Orthoptera e.g. Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.
  • Phthiraptera e.g. Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp.
  • Thysanoptera e.g. Herculothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.
  • Heteroptera e.g. Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.
  • Lepidoptera e.g. Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis Spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria me
  • Hymenoptera e.g. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
  • Diptera e.g. Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp.
  • Oestrus spp. Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hylemyia spp., Liriomyza spp.
  • siphonaptera e.g. Xenopsylla cheopis, Ceratophyllus spp.
  • arachnids e.g. Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoroptes spp.
  • Chorioptes spp. Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.
  • the plant parasitic nematodes include e.g. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.
  • the active compound combinations can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension-emulsion concentrates, active substance-impregnated natural and synthetic substances and very fine encapsulations in polymeric substances.
  • formulations are prepared in a known manner, for example by mixing the active compounds with extenders, ie liquid solvents and / or solid carriers, optionally with the use of surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents.
  • extenders ie liquid solvents and / or solid carriers
  • surface-active agents ie emulsifiers and / or dispersants and / or foam-forming agents.
  • organic solvents can also be used as auxiliary solvents.
  • Suitable liquid solvents are essentially: aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • aromatics such as xylene, toluene, or alkylnaphthalenes
  • chlorinated aromatics and chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride
  • Suitable solid carriers are:
  • Ammonium salts and ground natural minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as fumed silica, alumina and silicates, as solid carriers for granules are suitable: e.g. crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, coconut shells, corn cobs and tobacco stalks; suitable emulsifiers and / or foam formers are: e.g.
  • nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates; suitable dispersants are: e.g. Lignin-sulphite liquors and methylcellulose.
  • Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids may be used in the formulations.
  • Other additives may be mineral and vegetable oils.
  • Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • the formulations generally contain between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%.
  • the active compound combinations according to the invention can be used in commercial formulations as well as in the formulations prepared from these formulations in admixture with others Active ingredients, such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth regulators or herbicides.
  • Active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth regulators or herbicides.
  • the insecticides include, for example, phosphoric esters, carbamates, carboxylic esters, chlorinated hydrocarbons, phenylureas, substances produced by microorganisms, among others
  • the active compound combinations according to the invention may also be present when used as insecticides in their commercial formulations as well as in the formulations prepared from these formulations in admixture with synergists.
  • Synergists are compounds which increase the effect of the active ingredients without the added synergist itself having to be active.
  • the active substance content of the application forms prepared from the commercial formulations can vary within wide ranges.
  • the active ingredient concentration of the use forms may be from 0.0000001 to 95% by weight of active ingredient, preferably between 0.0001 and 1% by weight.
  • the application is done in a custom forms adapted to the application.
  • plants and parts of plants can be treated.
  • plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
  • Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights.
  • Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, by way of example, leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and roots, tubers and rhizomes .
  • the plant parts also include crops and vegetative and generative propagation material, such as cuttings, tubers, rhizomes, offshoots and seeds.
  • the treatment according to the invention of the plants and plant parts with the active substance combinations takes place directly or by acting on their environment, habitat or storage space according to the customary treatment methods, for example by dipping, spraying, evaporating, atomizing, spreading, spreading and in the case of propagation material, in particular in the case of seeds, furthermore by single or multi-layer wrapping.
  • all plants and their parts can be treated.
  • wild-type or plant species obtained by conventional biological breeding methods, such as crossing or protoplast fusion, and plant cultivars and their parts are treated.
  • transgenic plants and plant cultivars which have been obtained by genetic engineering methods, if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated.
  • the term “parts” or “parts of plants” or “plant parts” has been explained above.
  • the treatment according to the invention may also give rise to superadditive ("synergistic") effects.
  • superadditive for example, reduced application rates and / or extensions of the spectrum of action and / or an increase in the effect of the substances and agents usable in the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering power facilitated harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or machinability of the harvested products, which exceed the actual expected effects.
  • the preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits").
  • traits are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products.
  • Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active substances.
  • transgenic plants include the important crops, such as cereals (wheat, rice), maize, soya, potato, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), corn, soy, potato , Cotton and oilseed rape become.
  • genes which confer the desired properties can also occur in combinations with one another in the transgenic plants.
  • “Bt plants” are maize varieties, cotton varieties, soybean varieties and potato varieties which are sold under the trade names YIELD GARD® (eg corn, cotton, soya), KnockOut® (eg maize), StarLink® (eg maize), Bollgard® ( Cotton), Nucotn® (cotton) and NewLeaf® (potato).
  • herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties, which are sold under the trade names Roundup Ready® (tolerance to glyphosate eg corn, cotton, soy), Liberty Link® (tolerance to phosphinotricin, eg rapeseed), IMI® (tolerance to Imidazolinone) and STS® (tolerance to sulfonylureas eg corn).
  • Herbicide-resistant (conventionally grown on herbicide tolerance) plants are also mentioned under the name Clearf ⁇ eld® varieties (eg corn). Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits.
  • the listed plants can be treated particularly advantageously according to the invention with the active compound mixture according to the invention.
  • the preferred ranges given above for the mixtures also apply to the treatment of these plants.
  • Particularly emphasized is the plant treatment with the mixtures specifically mentioned in the present text.
  • a synergistic effect is always present in insecticides and acaricides whenever the effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
  • X means the degree of killing, expressed in% of the untreated control, when using the active substance A at a rate of m g / ha or in a concentration of m ppm,
  • Y means the degree of killing, expressed in% of the untreated control, when using the active ingredient B in an application rate of n g / ha or in a concentration of n ppm
  • E means the degree of killing, expressed in% of the untreated control, when using the active compounds A and B at application rates of m and n g / ha or in a concentration of m and n ppm,
  • the combination is over-additive in its kill, ie there is a synergistic effect.
  • the actually observed kill rate must be greater than the expected kill rate (E) value calculated from the above formula.
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cotton leaves (Gossypium herbaceum), which are heavily attacked by the cotton aphid ⁇ Aphis gossypii), are sprayed with the active compound preparation in the desired concentration.
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • the kill is determined in%. 100% means that all white flies have been killed; 0% means that no white flies have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves (Brassica olerace ⁇ ) that are heavily infested with the green peach aphid ⁇ Myzus persicae) are treated by spraying with the preparation of active compound in the desired concentration.
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Rice plants (Oryza sativ ⁇ ) are treated by spraying with the preparation of active compound in the desired concentration and filled with rice cicadas (Nilaparvata lugens) while the leaves are still moist.
  • the kill is determined in%. 100% means that all rice cicadas have been killed; 0% means that no rice cicadas have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves ⁇ Brassica oleraceä) are treated by spraying with the preparation of active compound in the desired concentration and are populated with larvae of the horseradish leaf beetle ⁇ Phaedon cochleariae) while the leaves are still moist.
  • the kill is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves ⁇ Brassica oleraceä) are treated by spraying with the preparation of active compound in the desired concentration and are populated with larvae of the armyworm ⁇ Spodoptera frugiperda) while the leaves are still moist.
  • the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Tetranychus urticae - test surgical-resistant / spray treatment
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Bean leaf discs Phaseolus vulgaris infected by all stages of the common spider mite (Tetranychus urticae) are sprayed with an active compound preparation of the desired concentration.
  • the effect is determined in%. 100% means that all spider mites have been killed; 0% means that no spider mites have been killed.

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Abstract

The invention relates to novel active ingredient combinations containing compounds of formulae (I) and (II), said combinations having very good insecticidal properties and good acaricidal properties.

Description

Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften Drug combinations with insecticidal and acaricidal properties
Die vorliegende Erfindung betrifft neue Wirkstoffkombinationen, die aus bekannten spiroketalsubstituierten Tetramsäurederivaten einerseits und weiteren insektiziden Wirkstoffen andererseits bestehen und sehr gut zur Bekämpfung von tierischen Schädlingen wie Insekten und / oder unerwünschten Akariden geeignet sind.The present invention relates to novel drug combinations consisting of known spiroketalsubstituierten tetramic acid on the one hand and other insecticidal active ingredients on the other hand and are very suitable for controlling animal pests such as insects and / or unwanted acarids.
Von 3-Acyl-pyrrolidin-2,4-dionen sind pharmazeutische Eigenschaften vorbeschrieben (S. Suzuki et al. Chem. Pharm. Bull. 15 1 120 (1967)). Weiterhin wurden N-Phenylpyrrolidin-2,4-dione von R. Schmierer und H. Mildenberger (Liebigs Ann. Chem. 1985, 1095) synthetisiert. Eine biologische Wirksamkeit dieser Verbindungen wurde nicht beschrieben.Pharmaceutical properties of 3-acyl-pyrrolidine-2,4-diones are described above (S. Suzuki et al., Chem. Pharm. Bull. 15 1 120 (1967)). Furthermore, N-phenylpyrrolidine-2,4-diones were synthesized by R. Schmierer and H. Mildenberger (Liebigs Ann. Chem. 1985, 1095). Biological activity of these compounds has not been described.
In EP-A-O 262 399 und GB-A-2 266 888 werden ähnlich strukturierte Verbindungen (3-Aryl-pyr- rolidin-2,4-dione) offenbart, von denen jedoch keine herbizide, insektizide oder akarizide Wirkung bekannt geworden ist. Bekannt mit herbizider, insektizider oder akarizider Wirkung sind unsub- stituierte, bicyclische 3-Aryl-pyrrolidin-2,4-dion-Derivate (EP-A-355 599, EP-A-415 21 1 und JP-A-12-053 670) sowie substituierte monocyclische 3-Aryl-pyrrolidin-2,4-dion-Derivate (EP-A- 377 893 und EP-A-442 077).EP-A-0 262 399 and GB-A-2 266 888 disclose similarly structured compounds (3-arylpyrrolidine-2,4-diones), of which, however, no herbicidal, insecticidal or acaricidal action has become known. Unsubstituted, bicyclic 3-arylpyrrolidine-2,4-dione derivatives are known (EP-A-355 599, EP-A-415 21 1 and JP-A-12-053.) With herbicidal, insecticidal or acaricidal activity 670) as well as substituted monocyclic 3-aryl-pyrrolidine-2,4-dione derivatives (EP-A-377 893 and EP-A-442 077).
Weiterhin bekannt sind polycyclische 3-Arylpyrrolidin-2,4-dion-Derivate (EP-A-442 073) sowie lH-Arylpyrrolidin-dion-Derivate (EP-A-456 063, EP-A-521 334, EP-A-596 298, EP-A-613 884, EP-A-613 885, WO 94/01 997, WO 95/26 954, WO 95/20 572, EP-A-O 668 267, WO 96/25 395, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/36 868, WO 97/43275, WO 98/05638, WO 98/06721 , WO 98/25928, WO 99/24437, WO 99/43649, WO 99/48869 und WO 99/55673, WO 01/17972, WO 01/23354, WO 01/74770, WO 03/013249, WO 03/062244, WO 2004/007448, WO 2004/024 688, WO 04/065366, WO 04/080962, WO 04/1 1 1042, WO 05/044791 , WO 05/044796, WO 05/048710, WO 05/049596, WO 05/066125, WO 05/092897, WO 06/000355, WO 06/029799, WO 06/056281, WO 06/056282, WO 06/089633, WO 07/048545, WO 07/073856, WO 07/096058, WO 07/121868, WO 07/140881 , DE-A-102006050148, DE-A- 102006057036, DE-A-102006057037, DE-A-10205059892). Außerdem sind ketalsubstituierte 1- H-Arylpyrrolidin-2,4-dione aus WO 99/16748 und (spiro)-ketalsubstituierte N-Alkoxy-alkoxy- substituierte Aryl-pyrrolidindione aus JP-A-14 205 984 und Ito M. et. al Bioscience, Biotechnology and Biochemistry 67, 1230-1238, (2003) bekannt. Der Zusatz von Safenern zu Ketoenolen ist ebenfalls prinzipiell aus der WO 03/013249 bekannt. Außerdem sind aus WO 06/02441 1 herbizide Mittel enthaltend Ketoenole bekannt.Also known are polycyclic 3-arylpyrrolidine-2,4-dione derivatives (EP-A-442 073) and 1H-arylpyrrolidine-dione derivatives (EP-A-456 063, EP-A-521 334, EP-A- 596 298, EP-A-613 884, EP-A-613 885, WO 94/01 997, WO 95/26 954, WO 95/20 572, EP-A-0 668 267, WO 96/25 395, WO 96 / 35,664, WO 97/01 535, WO 97/02 243, WO 97/36868, WO 97/43275, WO 98/05638, WO 98/06721, WO 98/25928, WO 99/24437, WO 99/43649 , WO 99/48869 and WO 99/55673, WO 01/17972, WO 01/23354, WO 01/74770, WO 03/013249, WO 03/062244, WO 2004/007448, WO 2004/024 688, WO 04 / 065366, WO 04/080962, WO 04/1 1 1042, WO 05/044791, WO 05/044796, WO 05/048710, WO 05/049596, WO 05/066125, WO 05/092897, WO 06/000355, WO 06/029799, WO 06/056281, WO 06/056282, WO 06/089633, WO 07/048545, WO 07/073856, WO 07/096058, WO 07/121868, WO 07/140881, DE-A-102006050148, DE-A-102006057036, DE-A-102006057037, DE-A-10205059892). Also, ketal-substituted 1-H-arylpyrrolidine-2,4-diones from WO 99/16748 and (spiro) ketal-substituted N-alkoxy-alkoxy-substituted aryl-pyrrolidinediones are disclosed in JP-A-14 205 984 and Ito M. et. al Bioscience, Biotechnology and Biochemistry 67, 1230-1238, (2003). The addition of safeners to ketoenols is also known in principle from WO 03/013249. Furthermore, WO 06/02441 1 discloses herbicidal compositions containing ketoenols.
Die akarizide und / oder insektizide Wirksamkeit und / oder Wirkungsbreite und / oder die Pflanzenverträglichkeit der bekannten Verbindungen, insbesondere gegenüber Kulturpflanzen, ist jedoch nicht immer ausreichend.The acaricidal and / or insecticidal activity and / or range of action and / or the plant tolerance of the known compounds, in particular to crops, is but not always enough.
Weiterhin bekannt sind Mischungen von Verbindungen aus der WO 98/05638 und der WO 04/007448 mit anderen Insektiziden und / oder Akariziden: WO 01/89300, WO 02/00025, WO 02/05648, WO 02/17715, WO 02/19824, WO 02/30199, WO 02/37963, WO 05/004603, WO 05/053405, WO 06/089665, WO 08/006514, WO 08/006516, WO 08/006512, WO 08/006515, WO 08/006513, WO 08/009379, DE-A-10342673. Allerdings ist die Wirkung dieser Mischungen nicht immer befriedigend.Also known are mixtures of compounds from WO 98/05638 and WO 04/007448 with other insecticides and / or acaricides: WO 01/89300, WO 02/00025, WO 02/05648, WO 02/17715, WO 02/19824 , WO 02/30199, WO 02/37963, WO 05/004603, WO 05/053405, WO 06/089665, WO 08/006514, WO 08/006516, WO 08/006512, WO 08/006515, WO 08/006513 WO 08/009379, DE-A-10342673. However, the effect of these mixtures is not always satisfactory.
Es wurde nun gefunden, dass Wirkstoffkombinationen enthaltend mindestens eine Verbindung der Formel (I)It has now been found that active substance combinations comprising at least one compound of the formula (I)
in welcherin which
W für Wasserstoff, Alkyl, Alkenyl, Alkinyl, Halogen, Alkoxy, Halogenalkyl, Halogenalkoxy oder Cyano steht,W is hydrogen, alkyl, alkenyl, alkynyl, halogen, alkoxy, haloalkyl, haloalkoxy or cyano,
X für Halogen, Alkyl, Alkenyl, Alkinyl, Alkoxy, Halogenalkyl, Halogenalkoxy, Nitro oder Cyano steht,X is halogen, alkyl, alkenyl, alkynyl, alkoxy, haloalkyl, haloalkoxy, nitro or cyano,
Y und Z unabhängig voneinander für Wasserstoff, Alkyl, Alkenyl, Alkinyl, Alkoxy, Halogen, Halogenalkyl, Halogenalkoxy, Cyano oder Nitro steht,Y and Z independently of one another represent hydrogen, alkyl, alkenyl, alkynyl, alkoxy, halogen, haloalkyl, haloalkoxy, cyano or nitro,
A und B und das Kohlenstoffatom, an das sie gebunden sind, für jeweils gegebenenfalls durch Alkyl, Halogenalkyl, Alkoxy, Alkoxyalkyl oder gegebenenfalls substituiertes Phenyl substituiertes fünf- bis siebengliedriges Ketal, Thioketal oder Dithioketal steht, welches gegebenenfalls durch ein weiteres Heteroatom unterbrochen sein kann,A and B and the carbon atom to which they are attached are each optionally substituted by alkyl, haloalkyl, alkoxy, alkoxyalkyl or optionally substituted phenyl five- to seven-membered ketal, thioketal or dithioketal, which may optionally be interrupted by another heteroatom,
G für Wasserstoff (a) oder für eine der Gruppen G is hydrogen (a) or one of the groups
steht,stands,
worinwherein
E für ein Metallion oder ein Ammoniumion steht,E is a metal ion or an ammonium ion,
L für Sauerstoff oder Schwefel steht,L is oxygen or sulfur,
M für Sauerstoff oder Schwefel steht,M is oxygen or sulfur,
R.1 für jeweils gegebenenfalls durch Halogen oder Cyano substituiertes Alkyl, Alkenyl,R.1 is in each case optionally substituted by halogen or cyano-substituted alkyl, alkenyl,
Alkoxyalkyl, Alkylthioalkyl oder Polyalkoxyalkyl oder für jeweils gegebenenfalls durchAlkoxyalkyl, alkylthioalkyl or polyalkoxyalkyl or each optionally optionally
Halogen, Alkyl oder Alkoxy substituiertes Cycloalkyl oder Heterocyclyl oder für jeweils gegebenenfalls substituiertes Phenyl, Phenylalkyl, Hetaryl, Phenoxyalkyl oder Hetaryloxy- alkyl steht,Is halogen, alkyl or alkoxy-substituted cycloalkyl or heterocyclyl or represents in each case optionally substituted phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl,
R- für jeweils gegebenenfalls durch Halogen oder Cyano substituiertes Alkyl, Alkenyl, Alkoxyalkyl oder Polyalkoxyalkyl oder für jeweils gegebenenfalls substituiertes Cycloalkyl, Phenyl oder Benzyl steht,R represents in each case optionally halogen or cyano-substituted alkyl, alkenyl, alkoxyalkyl or polyalkoxyalkyl or in each case optionally substituted cycloalkyl, phenyl or benzyl,
R^, R4 und R^ unabhängig voneinander für jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Alkoxy, Alkylamino, Dialkylamino, Alkylthio, Alkenylthio oder Cycloalkylthio oder für jeweils gegebenenfalls substituiertes Phenyl, Benzyl, Phenoxy oder Phenylthio stehen,R 1, R 4 and R 1 independently of one another are each optionally halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio or cycloalkylthio or in each case optionally substituted phenyl, benzyl, phenoxy or phenylthio,
R6 und R^ unabhängig voneinander für Wasserstoff, für jeweils gegebenenfalls durch Halogen oder Cyano substituiertes Alkyl, Cycloalkyl, Alkenyl, Alkoxy, Alkoxyalkyl, für jeweils gegebenenfalls substituiertes Phenyl oder Benzyl stehen, oder gemeinsam mit dem N-Atom, an das sie gebunden sind, einen gegebenenfalls Sauerstoff oder Schwefel enthaltenden und gegebenenfalls substituierten Cyclus bildenR6 and R4 independently of one another represent hydrogen, in each case optionally halogen or cyano-substituted alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, in each case optionally substituted phenyl or benzyl, or together with the N-atom to which they are attached, form an optionally oxygen or sulfur containing and optionally substituted cycle
und ein oder mehrere weitere Insektizide und / oder Akarizide der Formel (II) sich sehr gut zur Bekämpfung von tierischen Schädlingen wie Insekten und / oder Akariden eignen.and one or more further insecticides and / or acaricides of the formula (II) are very good are suitable for controlling animal pests such as insects and / or acarids.
Die Wirkstoffe der Formel (II) sind gemäß der IRAC-Klassifizierung (Version 5.3 Juli 2007) in verschiedene Klassen (1-30) und Gruppen gemäß ihres Wirkmechanismus zugeordnet:The active substances of the formula (II) are assigned according to the IRAC classification (Version 5.3 July 2007) into different classes (1-30) and groups according to their mechanism of action:
Insektizide / Akarizide / Nematizide:Insecticides / acaricides / nematicides:
Acetylcholinesterase (AChE) Inhibitoren II-lAcetylcholinesterase (AChE) inhibitors II-l
II- 1. A Carbamate, zum Beispiel Alanycarb (II-l. A-I), Aldicarb (II-l.A-2), Aldoxycarb (II-l.A-3), Allyxycarb (II-l .A-4), Aminocarb (II-l .A-5), Bendiocarb (II-l .A-6), Benfuracarb (II-l .A-7), Bufencarb (II-l.A-8), Butacarb (II-l.A-9), Butocarboxim (II-l. A-10), Butoxycarboxim (II-l. A-Il),II- 1. A carbamates, for example alanycarb (II-l.Al), aldicarb (II-lA-2), aldoxycarb (II-lA-3), allyxycarb (II-l .A-4), aminocarb (II -l .A-5), bendiocarb (II-l .A-6), benfuracarb (II-l .A-7), bufencarb (II-lA-8), butacarb (II-lA-9), butocarboxime ( II-l.A-10), butoxycarboxime (II-l.A-II),
Carbaryl (II-l.A-12), Carbofuran (II-l.A-13), Carbosulfan (II-l.A-14), Cloethocarb (II- l.A-15), Dimetilan (II-l. A-16), Ethiofencarb (II-l. A-17), Fenobucarb (II-l. A-18), Feno- thiocarb (II-l.A-19), Formetanate (II-l.A-20), Furathiocarb (ü-l.A-21), Isoprocarb (II-l .A- 22), Metam-sodium (II-l.A-23), Methiocarb (II-l.A-24), Methomyl (II-l.A-25), Metolcarb (π-l.A-26), Oxamyl (II-l.A-27), Pirimicarb (H-I .A-28), Promecarb (π-l.A-29), PropoxurCarbaryl (II-IA-12), Carbofuran (II-IA-13), Carbosulfan (II-IA-14), Cloethocarb (II-IA-15), Dimetilane (II-IIA-16), Ethiofencarb (II A-17), fenobucarb (II-l. A-18), fenothiocarb (II-lA-19), formetanates (II-lA-20), furathiocarb (μ-IA-21), isoprocarb ( II-l .A-22), metam-sodium (II-lA-23), methiocarb (II-lA-24), methomyl (II-lA-25), metolcarb (π-lA-26), oxamyl (II -lA-27), pirimicarb (HI .A-28), promecarb (π-lA-29), propoxur
(II-l.A-30), Thiodicarb (ü-l.A-31), Thiofanox (II-l.A-32), Trimethacarb (H-l.A-33), XMC (II-l .A-34), Xylylcarb (II-l .A-35)(II-I-30), thiodicarb (I-A-31), thiofanox (II-IA-32), trimethacarb (HI.A-33), XMC (II-I. A-34), xylylcarb (II- l .A-35)
II- 1. B Organophosphate, zum Beispiel Acephate (II-l. B-I), Azamethiphos (II-l.B-2), Azinphos (-methyl, -ethyl) (II- l.B-3), Bromophos-ethyl (II-l.B-4), Bromfenvinfos (-methyl) (II-l.B-5), Butathiofos (II- l.B-6), Cadusafos (II-l.B-7), Carbophenothion (II-l.B-8), Chlorethoxyfos (ü-l.B-9), Chlorfenvinphos (II-l.B-10), Chlormephos (II-l. B-Il), Chlorpyrifos (-methyl/-ethyl) (II- l.B-12), Coumaphos (II-l.B-13), Cyanofenphos (II-l.B-14), Cyanophos (II-l.B-15), Chlorfenvinphos (II-l.B-16), Demeton-S-methyl (II-l. B-17), Demeton-S-methylsulphon (II-l. B- 18), Dialifos (II-l.B-19), Diazinon (II-l.B-20), Dichlofenthion (ü-l.B-21),II- 1. B Organophosphates, for example Acephate (II-1 BI), Azamethiphos (II-1B-2), Azinphos (-methyl, -ethyl) (II-1B-3), Bromophos-ethyl (II-1B -4), bromoffenvinfos (-methyl) (II-lB-5), butathiofos (II-lB-6), cadusafos (II-lB-7), carbophenothione (II-lB-8), chloroethoxyfos (l-lB) 9), chlorfenvinphos (II-lB-10), chlormephos (II-l.B-1), chlorpyrifos (-methyl / -ethyl) (II-lB-12), coumaphos (II-lB-13), cyanofenphos ( II-lB-14), cyanophos (II-lB-15), chlorfenvinphos (II-lB-16), demeton-S-methyl (II-l. B-17), demeton S-methylsulphone (II-l. B-18), dialifos (II-lB-19), diazinone (II-lB-20), dichlorofenthion (u-lB-21),
Dichlorvos/DDVP (π-l.B-22), Dicrotophos (π-l.B-23), Dimethoate (II-l.B-24), Di- methylvinphos (π-l.B-25), Dioxabenzofos (π-l.B-26), Disulfoton (π-l.B-27), EPN (II- l.B-28), Ethion (II-l.B-29), Ethoprophos (II-l.B-30), Etrimfos (II-l.B-31), Famphur (II- l.B-32), Fenamiphos (II-l.B-33), Fenitrothion (II-l.B-34), Fensulfothion (ü-l.B-35), Fen- thion (II-l.B-36), Flupyrazofos (π-l.B-37), Fonofos (II-l.B-38), Formothion (π-l.B-39),Dichlorvos / DDVP (π-IB-22), dicrotophos (π-IB-23), dimethoates (II-IB-24), dimethylvinphos (π-IB-25), dioxabenzofos (π-IB-26), disulfone (π-lB-27), EPN (II-lB-28), ethione (II-lB-29), ethoprophos (II-lB-30), etrimfos (II-lB-31), famphur (II-lB- 32), fenamiphos (II-lB-33), fenitrothion (II-lB-34), fensulfothion (μ-lB-35), fenethione (II-lB-36), flupyrazofos (π-lB-37), Fonofos (II-lB-38), formothione (π-lB-39),
Fosmethilan (II-l.B-40), Fosthiazate (ü-l.B-41), Heptenophos (ü-l.B-42), Iodofenphos (II- l.B-43), Iprobenfos (II-l.B-44), Isazofos (π-l.B-45), Isofenphos (II-l.B-46), Isopropyl (II- l.B-47), O-salicylate (π-l.B-48), Isoxathion (π-l.B-49), Malathion (II-l.B-50), Mecarbam (π-l .B-51), Methacrifos (π-l .B-52), Methamidophos (ü-l .B-53), Methidathion (II-l .B- 54), Mevinphos (π-l .B-55), Monocrotophos (π-l .B-56), Naled (π-l .B-57), Omethoate (II- l .B-58), Oxydemeton-methyl (π-l .B-59), Parathion (-methyl/-ethyl) (ü-l .B-60), Phentho- ate (II-l .B-61), Phorate (II-l .B-62), Phosalone (π-l .B-63), Phosmet (ü-l .B-64), Phosphamidon (ü-l .B-65), Phosphocarb (ü-l .B-66), Phoxim (ü-l .B-67), Pirimiphos (- methyl/-ethyl) (II-l .B-68), Profenofos (II-l .B-69), Propaphos (II-l .B-70), Propetamphos (II-l .B-71 ), Prothiofos (II-l .B-72), Prothoate (II-l .B-73), Pyraclofos (II-l .B-74), Pyridaphenthion (π-l .B-75), Pyridathion (II-l .B-76), Quinalphos (II-l .B-77), Sebufos (II- l .B-78), Sulfotep (π-l .B-79), Sulprofos (II-l .B-80), Tebupirimfos (π-l .B-81 ), Temephos (II-l .B-82), Terbufos (π-l .B-83), Tetrachlorvinphos (π-l .B-84), Thiometon (II-l .B-85),Fosmethilane (II-lB-40), fosthiazate (μ-lB-41), heptenophos (μ-lB-42), iodofenofen (II-lB-43), Iprobenfos (II-lB-44), isazofos (π-lB -45), isofenphos (II-lB-46), isopropyl (II-lB-47), o-salicylates (π-lB-48), isoxathione (π-lB-49), malathion (II-lB-50) , Mecarbam (π-1 .B-51), methacrifos (π-1 .B-52), methamidophos (--1 .B-53), methidathione (II-1 .B-54), mevinphos (π-1 .B -55), monocrotophos (π-1 .B-56), naled (π-1 .B-57), omethoate (II-1 .B-58), oxydemeton-methyl (π-1 .B-59), Parathion (-methyl / -ethyl) (μL-B-60), phenthocyte (II-l .B-61), phorate (II-l .B-62), phosalone (π-l .B-) 63), phosmet (sup.1-B-64), phosphamidone (sup.1-B-65), phosphocarb (sup.1-B-66), phoxime (sup.1-B-67), pirimiphos (- methyl / ethyl) (II-l .B-68), profenofos (II-l .B-69), propaphos (II-l .B-70), propetamphos (II-l .B-71), prothiofos ( II-l .B-72), prothoates (II-l .B-73), pyraclofos (II-l .B-74), pyridapenthione (π-l .B-75), pyridathione (II-l .B- 76), quinalphos (II-1 .B-77), sebufos (II-1 .B-78), sulfotep (π-1 .B-79), sulforos (II-1 .B-80), tebupirimfos (π -l .B-81), temephos (II-l .B-82), terbufos (π-l .B-83), tetrachlorovinphos (π-l .B-84), thiometone (II-l .B-85 )
Triazophos (π-l .B-86), Triclorfon (ü-l .B-87), Vamidothion (π-l .B-88)Triazophos (π-1 .B-86), triclorfone (--1 .B-87), vamidothion (π-1 .B-88)
GABA-gesteuerte Chlorid-Kanal-Antagonisten II-2GABA-controlled chloride channel antagonists II-2
II-2A Organochlorine, zum Beispiel Camphechlor (II-2A-1 ), Chlordane (II-2A-2), Endosulfan (II-2A-3), Gamma- HCH (II-2A-4), HCH (II-2A-5), Heptachlor (II-2A-6), Lindane (II-2A-7), MethoxychlorII-2A Organochlorines, for example, camphechloro (II-2A-1), chlordane (II-2A-2), endosulfan (II-2A-3), gamma-HCH (II-2A-4), HCH (II-2A -5), heptachlor (II-2A-6), lindane (II-2A-7), methoxychlor
(II-2A-8)(II-2A-8)
II-2B Fiprole (Phenylpyrazole), zum Beispiel Acetoprole (II-2B-1), Ethiprole (II-2B-2), Fipronil (II-2B-3), Pyrafluprole (II- 2B-4), Pyriprole (π-2B-5), Vaniliprole (II-2B-6)II-2B Fiproles (phenylpyrazoles), for example acetoproles (II-2B-1), ethiproles (II-2B-2), fipronil (II-2B-3), pyrafluproles (II-2B-4), pyriproles (π- 2B-5), vaniliprole (II-2B-6)
Natrium-Kanal-Modulatoren / Spannungsabhängige Natrium-Kanal-Blocker II-3Sodium Channel Modulators / Voltage-Dependent Sodium Channel Blocker II-3
II-3 Pyrethroide, zum Beispiel Acrinathrin (II-3-1), Allethrin (d-cis-trans, d-trans) (II-3-2), Beta-Cyfluthrin (II-3-3), Bifenthrin (II-3-4), Bioallethrin (II-3-5), Bioallethrin-S-cyclopentyl-isomer (II-3- 6), Bioethanomethrin (II-3-7), Biopermethrin (II-3-8), Bioresmethrin (II-3-9), Chlovaporthrin (II-3-10), Cis-Cypermethrin (π-3-1 1), Cis-Resmethrin (II-3-12), Cis-II-3 pyrethroids, for example, acrinathrin (II-3-1), allethrin (d-cis-trans, d-trans) (II-3-2), beta-cyfluthrin (II-3-3), bifenthrin (II -3-4), bioallethrin (II-3-5), bioallethrin S-cyclopentyl isomer (II-3-6), bioethanomethrin (II-3-7), biopermethrin (II-3-8), bioresmethrin ( II-3-9), chlovaporthrin (II-3-10), cis-cypermethrin (π-3-1 1), cis-resmethrin (II-3-12), cis-cypermethrin
Permethrin (II-3-13), Clocythrin (II-3-14), Cycloprothrin (II-3-15), Cyfluthrin (π-3-16), Cyhalothrin (II-3-17), Cypermethrin (alpha-, beta-, theta-, zeta-)(II-3-18), Cyphenothrin (II- 3-19), Deltamethrin (II-3-20), Empenthrin (lR-isomer) (II-3-21), Esfenvalerate (π-3-22), Etofenprox (II-3-23), Fenfluthrin (II-3-24), Fenpropathrin (ü-3-25), Fenpyrithrin (II-3-26), Fenvalerate (II-3-27), Flubrocythrinate (II-3-28), Flucythrinate (II-3-29), Flufenprox (II-3-Permethrin (II-3-13), clocthrin (II-3-14), cycloprothrin (II-3-15), cyfluthrin (π-3-16), cyhalothrin (II-3-17), cypermethrin (alpha, beta, theta, zeta) (II-3-18), cyphenothrin (II-3-19), deltamethrin (II-3-20), empenthrin (IR-isomer) (II-3-21), esfenvalerate (π-3-22), etofenprox (II-3-23), fenfluthrin (II-3-24), fenpropathrin (ü-3-25), fenpyrithrin (II-3-26), fenvalerate (II-3) 27), flubrocythrinates (II-3-28), flucythrinates (II-3-29), flufenprox (II-3)
30), Flumethrin (II-3-31), Fluvalinate (II-3-32), Fubfenprox (II-3-33), Gamma-Cyhalothrin (II-3-34), Imiprothrin (II-3-35), Kadethrin (π-3-36), Lambda-Cyhalothrin (π-3-37), Metofluthrin (II-3-38), Permethrin (eis-, trans-) (II-3-39), Phenothrin (lR-trans isomer) (II- 3-40), Prallethrin (ü-3-41), Profluthrin (ü-3-42), Protrifenbute (ü-3-43), Pyresmethrin (U- 3-44), Resmethrin (II-3-45), RU 15525 (II-3-46), Silafluofen (II-3-47), Tau-Fluvalinate (E- 3-48), Tefluthrin (II-3-49), Terallethrin (π-3-50), Tetramethrin (-1R- isomer) (II-3-51), Tralomethrin (II-3-52), Transfluthrin (II-3-53), ZXI 8901 (ü-3-54), Pyrethrin (pyrethrum) (π-3-55), Eflusilanat (II-3-56), DDT (ü-3-57), Methoxychlor (π-3-58),30), flumethrin (II-3-31), fluvalinates (II-3-32), fubfenprox (II-3-33), gamma-cyhalothrin (II-3-34), imiprothrin (II-3-35), Kadethrin (π-3-36), lambda-cyhalothrin (π-3-37), metofluthrin (II-3-38), permethrin (cis-, trans-) (II-3-39), phenothrin (IR-trans isomer) (II- 3-40), prallethrin (U-3-41), profuthrin (U-3-42), protrifenebutene (U-3-43), pyresmethrin (U-3-44), resmethrin (II-3-45), RU 15525 (II-3-46), silafluofen (II-3-47), tau-fluvalinate (E-3-48), tefluthrin (II-3-49), terallethrin (π-3-50), tetramethrin ( -1R- isomer) (II-3-51), tralomethrin (II-3-52), transfluthrin (II-3-53), ZXI 8901 (ü-3-54), pyrethrin (pyrethrum) (π-3) 55), eflusilanate (II-3-56), DDT (ü-3-57), methoxychlor (π-3-58),
Nikotinerge Acetylcholin-Rezeptor-Agonisten/-Antagonisten II-4Nicotinergic acetylcholine receptor agonist / antagonist II-4
II-4A Chloronicotinyle,II-4A chloronicotinyls,
zum Beispiel Acetamiprid (II-4A-1), Clothianidin (II-4A-2), Dinotefuran (II-4A-3), Imidacloprid (II-4A-4), Imidaclothiz (II-4A-5), Nitenpyram (II-4A-6), Nithiazine (II-4A-7), Thiacloprid (II-4A-8), Thiamethoxam (II-4A-9),for example, acetamiprid (II-4A-1), clothianidin (II-4A-2), dinotefuran (II-4A-3), imidacloprid (II-4A-4), imidaclothiz (II-4A-5), nitenpyram (II -4A-6), nithiazines (II-4A-7), thiacloprid (II-4A-8), thiamethoxam (II-4A-9),
II-4A-10 II-4A-1 1II-4A-10 II-4A-1 1
II-4B Nicotine (II-4B-1), Bensultap (II-4B-2), Cartap (II-4B-3), Thiosulfap-Natrium (II-4B-4), Thiocylam (II-4C-4)II-4B Nicotine (II-4B-1), Bensultap (II-4B-2), Cartap (II-4B-3), Thiosulfap Sodium (II-4B-4), Thiocylam (II-4C-4)
Allosterische Acetylcholin-Rezeptor-Modulatoren (Agonisten)Allosteric acetylcholine receptor modulators (agonists)
II-5 Spinosyne, zum Beispiel Spinosad (II-5-1), Spinetoram (II-5-2)II-5 spinosyns, for example spinosad (II-5-1), spinetoram (II-5-2)
Chlorid-Kanal-AktivatorenChloride channel activators
II-6 Mectine / Macrolide, zum Beispiel Abamectin (II-6-1), Emamectin (II-6-2), Emamectin-benzoate (II-6-3), Ivermectin (11-6-4), Lepimectin (II-6-5), Milbemectin (II-6-6)II-6 Mectins / Macrolides, for example, Abamectin (II-6-1), Emamectin (II-6-2), Emamectin benzoate (II-6-3), Ivermectin (11-6-4), Lepimectin (II -6-5), milbemectin (II-6-6)
II-7A Juvenilhormon Analoge, zum Beispiel Hydroprene (II-7A-1), Kinoprene (II-7A-2), Methoprene (II-7A-3), Epofenonane (II-7A-4), Triprene (II-7A-5), Fenoxycarb (II-7B-1), Pyriproxifen (II-7C-1), Diofenolan (II-7C-2)II-7A juvenile hormone analogs, for example, hydroprene (II-7A-1), kinoprenes (II-7A-2), methoprene (II-7A-3), epofenonans (II-7A-4), triprene (II-7A-3) 5), fenoxycarb (II-7B-1), Pyriproxifen (II-7C-1), Diofenolane (II-7C-2)
Wirkstoffe mit unbekannten oder nicht spezifischen WirkmechanismenActive substances with unknown or non-specific mechanisms of action
π-8 Begasungsmittel, zum Beispiel Methyl bromide (II-8A-1 ), Chloropicrin (II-8B-1 ), Sulfuryl fluoride (II-8C-1)π-8 fumigants, for example methyl bromides (II-8A-1), chloropicrin (II-8B-1), sulfuryl fluorides (II-8C-1)
II-9 Selektive Fraßhemmer, zum Beispiel Cryolite (II-9A-1), Pymetrozine (II-9B-1), NNIOl Ol (II-9B-2) , Flonicamid (II-9C-1)II-9 Selective Antifeedants, for example Cryolites (II-9A-1), Pymetrozines (II-9B-1), NN101 Ol (II-9B-2), Flonicamide (II-9C-1)
II- 10 Milbenwachstumsinhibitoren, zum Beispiel Clofentezine (II- 1 OA-I), Hexythiazox (II-10A-2), Etoxazole (II- 1 OB-I)II-10 mite growth inhibitors, for example clofentezine (II-1 OA-I), hexythiazox (II-10A-2), etoxazoles (II-1 OB-I)
Inhibitoren der oxidativen Phosphorylierung, ATP-Di sruptoren 11-12Inhibitors of oxidative phosphorylation, ATP disruptors 11-12
II-12A Diafenthiuron (II-12A-l)II-12A Diafenthiuron (II-12A-I)
II- 12B Organozinnverbindungen, zum Beispiel Azocyclotin (II-12B-1), Cyhexatin (II-12B-2), Fenbutatin-oxide (II-12B-3)II-12B organotin compounds, for example azocyclotin (II-12B-1), cyhexatin (II-12B-2), fenbutatin oxides (II-12B-3)
II-12C Propargite (II-12C-1), Tetradifon (II-12C-2)II-12C propargite (II-12C-1), tetradifon (II-12C-2)
Entkoppler der oxidativen Phoshorylierung durch Unterbrechung des H-Protongradienten II- 13Decoupling of the oxidative phosphorylation by interruption of the H proton gradient II-13
Chlorfenapyr (π-13-1)Chlorfenapyr (π-13-1)
Binapacyrl (II-13-2), Dinobuton (π-13-3), Dinocap (II-13-4), DNOC (II-13-5)Binapacyrl (II-13-2), dinobutone (π-13-3), dinocap (II-13-4), DNOC (II-13-5)
Mikrobielle Disruptoren der InsektendarmmembranMicrobial disruptors of insect intestinal membrane
Bacillus thuringiensis-Stämme (II-13-6)Bacillus thuringiensis strains (II-13-6)
Inhibitoren der ChitinbiosyntheseInhibitors of chitin biosynthesis
11-15 Benzoylharnstoffe, zum Beispiel Bistrifluron (H-15-1 ), Chlorfluazuron (ü-15-2), Diflubenzuron (II-15-3), Fluazuron (II-15-4), Flucycloxuron (II-15-5), Flufenoxuron (II-15-6), Hexaflumuron (FI-15- 7), Lufenuron (II-15-8), Novaluron (π-15-9), Noviflumuron (11-15-10), Penfluron (11-15- 1 1), Teflubenzuron (π-15-12), Triflumuron (11-15-13)11-15 benzoyl ureas, for example bis-trifluron (H-15-1), chlorofluorazuron (ü-15-2), diflubenzuron (II-15-3), fluazuron (II-15-4), flucycloxuron (II-15-5 ), Flufenoxuron (II-15-6), hexaflumuron (FI-15-7), lufenuron (II-15-8), novaluron (π-15-9), noviflumuron (11-15-10), penfluron (11 -15- 1 1), teflubenzuron (π-15-12), triflumuron (11-15-13)
11-16 Buprofezin (π-lό-l) Häutungsstörende Wirkstoffe Cyromazine (II- 17-1)11-16 buprofezin (π-lό-l) Moulting Agents Cyromazines (II-17-1)
Ecdysonagonisten/disruptoren (II- 18)Ecdysonagonists / disruptors (II-18)
II-18A Diacylhydrazine, zum Beispiel Chromafenozide (Ü-18A-1), Halofenozide (II-18A-2), Methoxyfenozide (II- 18A-3), Tebufenozide (II-l 8A-4), JS-1 18 (II-18A-5)II-18A Diacylhydrazines, for example Chromafenozide (U-18A-1), Halofenozide (II-18A-2), Methoxyfenozide (II-18A-3), Tebufenozide (II-l 8A-4), JS-1 18 (II -18A-5)
Azadirachtin (π-18B-1 )Azadirachtin (π-18B-1)
Oktopaminerge Agonisten zum Beispiel Amitraz (II- 19-1)Octopaminergic agonists for example Amitraz (II-19-1)
11-20 Seite-III-Elektronentransportinhibitoren/Seite-II-Elektronentransportinhibitoren11-20 Page III Electron Transport Inhibitors / Page II Electron Transport Inhibitors
Hydramethylnon (11-20 A- 1 )Hydramethylnone (11-20 A-1)
Acequinocyl (II-20B-1)Acequinocyl (II-20B-1)
Fluacrypyrim (II-20C-1)Fluacrypyrim (II-20C-1)
Cyflumetofen (II-20D-1), Cyenopyrafen (Ü-20D-2)Cyflumetofen (II-20D-1), Cyenopyrafen (Ü-20D-2)
ElektronentransportinhibitorenElectron transport inhibitors
11-21 Seite-I-Elektronentransportinhibitoren11-21 Page-I Electron Transport Inhibitors
aus der Gruppe der METI-Akarizide, zum Beispiel Fenazaquin (II-21-1), Fenpyroximate (11-21 -2), Pyrimidifen (11-21 -3),from the group of the METI acaricides, for example fenazaquin (II-21-1), fenpyroximate (11-21 -2), pyrimidifen (11-21 -3),
Pyridaben (11-21 -4), Tebufenpyrad (11-21 -5), Tolfenpyrad (11-21 -6), Rotenone (11-21 -7)Pyridaben (11-21 -4), Tebufenpyrad (11-21 -5), Tolfenpyrad (11-21 -6), Rotenone (11-21 -7)
11-22 Spannungsabhängige Natriumkanal-Blocker11-22 Voltage-Dependent Sodium Channel Blockers
zum Beispiel Indoxacarb (II-22A-1)for example indoxacarb (II-22A-1)
zum Beispiel Metaflumizone (BAS 3201) (II-22B-1)for example Metaflumizone (BAS 3201) (II-22B-1)
11-23 Inhibitoren der Fettsäurebiosynthese11-23 Inhibitors of fatty acid biosynthesis
11-23 A Tetronsäure-Derivate zum Beispiel Spirodiclofen (11-23 A-I), Spiromesifen (11-23 A-2)11-23 A tetronic acid derivatives for example spirodiclofen (11-23 A-I), spiromesifen (11-23 A-2)
II-23B Tetramsäure-Derivate, zum Beispiel Spirotetramat (Ü-23B-1)II-23B tetramic acid derivatives, for example spirotetramat (Ü-23B-1)
11-25 Neuronale Inhibitoren mit unbekannten Wirkmechanismus11-25 Neuronal inhibitors with unknown mechanism of action
Bifenazate (11-25- 1)Bifenazate (11-25-1)
Ryanodinrezeptor-EffektorenRyanodine receptor effectors
11-28 Diamide, zum Beispiel Flubendiamide (11-28- 1),11-28 Diamide, for example Flubendiamide (11-28- 1),
(II-28-2)(II-28-2)
Chlorantraniliprole (Rynaxapyr) (II-28-3), CyazypyrChlorantraniliprole (Rynaxapyr) (II-28-3), Cyazypyr
(II-28-4)(II-28-4)
11-29 Wirkstoffe mit unbekanntem Wirkmechanismus11-29 drugs with unknown mechanism of action
Amidoflumet (11-29- 1), Benclothiaz (II-29-2), Benzoximate (II-29-3), Bromopropylate (II- 29-4), Buprofezin (II-29-5), Chinomethionat (II-29-6), Chlordimeform (π-29-7), Chloro- benzilate (II-29-8), Clothiazoben (II-29-9), Cycloprene (11-29-10), Dicofol (11-29-1 1), Di- cyclanil (11-29-12), Fenoxacrim (11-29-13), Fentrifanil (11-29-14), Flubenzimine (ü-29-15), Flufenerim (ü-29-16), Flutenzin (11-29-17), Gossyplure (11-29-18), Japonilure (π-29-19), Metoxadiazone (ü-29-20), Petroleum (ü-29-21), Potassium oleate (ü-29-22), Pyridalyl (II- 29-23), Sulfluramid (ü-29-24), Tetrasul (π-29-25), Triarathene (π-29-26),Verbutin (11-29- 27),Amidoflumet (11-29-1), benclothiazole (II-29-2), benzoximate (II-29-3), bromopropylate (II-29-4), buprofezin (II-29-5), quinomethionate (II-29 -6), chlorodimeform (π-29-7), chlorobenzilates (II-29-8), clothiazoben (II-29-9), cycloprene (11-29-10), dicofol (11-29-1 1 ), Di-cyclanil (11-29-12), fenoxacrim (11-29-13), fentrifanil (11-29-14), flubenzimines (ü-29-15), flufenerim (ü-29-16), flutenzin (11-29-17), Gossyplure (11-29-18), Japonilure (π-29-19), Metoxadiazone (U-29-20), Petroleum (U-29-21), Potassium Oolate (U-29-22), Pyralidyl (II-29-23), Sulfluramid (U-29-24), Tetrasul (π- 29-25), triarathene (π-29-26), verbutin (11-29-27),
(π-29-28) (π-29-29)(π-29-28) (π-29-29)
(11-29-30) (11-29-31)(11-29-30) (11-29-31)
11-30 Mikrobielle Disruptoren der Insektendarmmembran11-30 Insect intestinal membrane microbial disruptors
II-30-1 Bacillus thuringiensis-Stämme. II-30-1 Bacillus thuringiensis strains.
Die in dieser Beschreibung mit ihrem „common name" genannten Wirkstoffe sind beispielsweise aus „The Pesticide Manual" 13th Ed., British Crop Protection Council 2003, und der Webseite http://www.alanwood.net/pesticides/ bekannt.The active ingredients mentioned in this specification with their "common name" are known, for example, from "The Pesticide Manual" 13th Ed., British Crop Protection Council 2003, and the website http://www.alanwood.net/pesticides/.
Wenn im Rahmen dieser Beschreibung die Kurzform des „common name" eines Wirkstoffes verwendet wird, so sind damit jeweils alle gängigen Derivate, wie die Ester und Salze, undIf the short form of the "common name" of an active ingredient is used in the context of this description, then all common derivatives, such as the esters and salts, and
Isomere, insbesondere optische Isomere umfasst, insbesondere die handelsübliche Form bzw.Isomers, in particular optical isomers, in particular the commercial form or
Formen. Wird mit dem „common name" ein Ester oder Salz bezeichnet, so sind damit auch jeweils alle anderen gängigen Derivate wie andere Ester und Salze, die freien Säuren undTo shape. If the term "common name" refers to an ester or salt, all other common derivatives, such as other esters and salts, the free acids, and all other conventional derivatives are also used
Neutralverbindungen, und Isomere, insbesondere optische Isomere umfasst, insbesondere die handelsübliche Form bzw. Formen. Die angegebenen chemischen Verbindungsnamen bezeichnen zumindest ein der von dem „common name" umfassten Verbindungen, häufig eine bevorzugteNeutral compounds, and isomers, in particular optical isomers, in particular the commercial form or forms. The chemical link names given refer to at least one of the "common name" compounds, often a preferred one
Verbindung.Connection.
Die Verbindungen der Formel (I) können, auch in Abhängigkeit von der Art der Substituenten, als optische Isomere oder Isomerengemische, in unterschiedlicher Zusammensetzung vorliegen, die gegebenenfalls in üblicher Art und Weise getrennt werden können. Sowohl die reinen Isomeren als auch die Isomerengemische, deren Herstellung und Verwendung sowie diese enthaltende Mittel sind Gegenstand der vorliegenden Erfindung. Im folgenden wird der Einfachheit halber jedoch stets von Verbindungen der Formel (I) gesprochen, obwohl sowohl die reinen Verbindungen als gegebenenfalls auch Gemische mit unterschiedlichen Anteilen an isomeren Verbindungen gemeint sind.Depending on the nature of the substituents, the compounds of the formula (I) can also be present in different compositions as optical isomers or mixtures of isomers, which can optionally be separated in a customary manner. Both the pure isomers and the mixtures of isomers, their preparation and use and agents containing them are the subject of the present invention. In the following, however, for the sake of simplicity, reference is always made to compounds of the formula (I), although both the pure compounds and, if appropriate, mixtures with different proportions of isomeric compounds are meant.
Unter Einbeziehung der verschiedenen Bedeutungen (a), (b), (c), (d), (e), (f) und (g) der Gruppe G ergeben sich folgende hauptsächliche Strukturen (I-a) bis (I-g),Including the different meanings (a), (b), (c), (d), (e), (f) and (g) of the group G, the following main structures (I-a) to (I-g) result,
(I-a) (I-e) (Ia) (Ie)
worinwherein
A, B, E, L, M, W, X, Y, Z, R1 , R2, R3, R4, R5, R6 und R7 die oben angegebenen Bedeutungen besitzen.A, B, E, L, M, W, X, Y, Z, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 7 have the meanings given above.
W steht besonders bevorzugt für Wasserstoff, Chlor, Brom, Cj-C^Alkyl, Ci -C4-Alkoxy, Ci - C2-Halogenalkyl oder Ci-C2-Halogenalkoxy,W is particularly preferably hydrogen, chlorine, bromine, C j -C ^ alkyl, Ci-C4-alkoxy, Ci - C 2 -haloalkyl or Ci-C 2 haloalkoxy,
X steht besonders bevorzugt für Chlor, Brom, Cj-C^Alkyl, Ci -C4-Alkoxy, C] -C4-Halogen- alkyl, Cj-C4-Halogenalkoxy oder Cyano,X particularly preferably represents chlorine, bromine, Cj-C ^ alkyl, Ci-C4-alkoxy, C] -C4 halo alkyl, Cj-C4-haloalkoxy or cyano,
Y und Z stehen besonders bevorzugt unabhängig voneinander für Wasserstoff, Fluor, Chlor, Brom, C] -C4-Alkyl, Cj-Cg-Alkoxy, C]-C4-Halogenalkyl, Ci -C4-Halogenalkoxy oder Cyano,Y and Z are preferably each independently represent hydrogen, fluorine, chlorine, bromine, C] -C4 alkyl, Cj-Cg alkoxy, C] -C4-haloalkyl, Ci-C4-haloalkoxy or cyano,
A und B und das Kohlenstoffatom, an dass sie gebunden sind, stehen besonders bevorzugt für ein gegebenenfalls einfach bis dreifach durch Ci-C4-Alkyl, C|-C3-Halogenalkyl, CrC4-Alkoxy oder Ci -C4-Alkoxy-C i-C2-alkyl substituiertes fünf-, sechs- oder siebengliedriges Ketal, welches gegebenenfalls durch ein weiteres Sauerstoffatom unterbrochen sein kann,A and B and the carbon atom to which they are attached particularly preferably represent an optionally mono- to trisubstituted by Ci-C 4 alkyl, C | -C 3 haloalkyl, C r C 4 alkoxy or Ci-C4 - Alkoxy-C 1 -C 2 -alkyl-substituted five-, six- or seven-membered ketal, which may optionally be interrupted by another oxygen atom,
steht besonders bevorzugt für Wasserstoff (a) oder für eine der Gruppen is particularly preferably hydrogen (a) or one of the groups
in welchenin which
E für ein Metallion oder ein Ammoniumion steht,E is a metal ion or an ammonium ion,
L für Sauerstoff oder Schwefel steht undL stands for oxygen or sulfur and
M für Sauerstoff oder Schwefel steht,M is oxygen or sulfur,
R I steht besonders bevorzugt für jeweils gegebenenfalls einfach bis dreifach durch Fluor oder Chlor substituiertes C]-Ci 6-Alkyl, C2-Ci 6-Alkenyl, C 1 -Cg-Alkoxy-C i -C4-alkyl, C J -CÖ- Alkylthio-Ci-C4-alkyl oder PoIy-C j -Cg-alkoxy-C j -C4-alkyl oder für gegebenenfalls einfach bis zweifach durch Fluor, Chlor, C1 -C5-AHCVI oder Ci -C5-Alkoxy substituiertes C3-C7-Cycloalkyl, in welchem gegebenenfalls eine oder zwei nicht direkt benachbarteRI more preferably represents in each case optionally mono- to trisubstituted by fluorine or chlorine, C] -C 6-alkyl, Ci-C2 6 alkenyl, C 1 -CG-alkoxy-C i-C4-alkyl, alkylthio CJ -CÖ- Ci-C4-alkyl or poly-C j -CG-alkoxy-Cj-C4-alkyl or represents optionally mono- to disubstituted by fluorine, chlorine, C1-C5 AHCVI or Ci-C5 alkoxy, C3-C7-cycloalkyl, in which optionally one or two are not directly adjacent
Methylengruppen durch Sauerstoff und / oder Schwefel ersetzt sind,Methylene groups are replaced by oxygen and / or sulfur,
für gegebenenfalls einfach bis dreifach durch Fluor, Chlor, Brom, Cyano, Nitro, C1 -C4- Alkyl, Ci -C4-Alkoxy, Ci-C3-Halogenalkyl, Ci -C3-Halogenalkoxy, Cj^-Alkylthio oder Cj -C4-Alkylsulfonyl substituiertes Phenyl,optionally mono- to trisubstituted by fluorine, chlorine, bromine, cyano, nitro, C1 -C4- alkyl, Ci-C4-alkoxy, Ci-C3-haloalkyl, Ci-C3 haloalkoxy, Cj ^ alkylthio, or C j -C 4 Alkylsulfonyl-substituted phenyl,
für gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Brom, Ci-C4-Alkyl, C1 -C4-optionally once or twice by fluorine, chlorine, bromine, C 1 -C 4 -alkyl, C 1 -C 4 -alkyl,
Alkoxy, Ci -Cß-Halogenalkyl oder Ci -Cß-Halogenalkoxy substituiertes Phenyl-Ci -C4- alkyl,Alkoxy, C 1 -C 6 -haloalkyl or C 1 -C 6 -haloalkoxy-substituted phenyl-C 1 -C 4 -alkyl,
für jeweils gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Brom oder C1 -C4- Alkyl substituiertes Pyrazolyl, Thiazolyl, Pyridyl, Pyrimidyl, Furanyl oder Thienyl,in each case optionally mono- to disubstituted by fluorine, chlorine, bromine or C 1 -C 4 -alkyl-substituted pyrazolyl, thiazolyl, pyridyl, pyrimidyl, furanyl or thienyl,
für gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Brom oder Ci -C4-Alkyl substituiertes Phenoxy-C]-C5-alkyl oderfor optionally mono- to disubstituted by fluorine, chlorine, bromine or Ci-C4-alkyl-substituted phenoxy-C ] -C5-alkyl or
für jeweils gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Brom, Amino oder Ci - C4-Alkyl substituiertes Pyridyloxy-Ci-C5-alkyl, Pyrimidyloxy-Ci -C5-alkyl oder Thi- azolyloxy-Cj -C5-alkyl, R^ steht besonders bevorzugt für jeweils gegebenenfalls einfach bis dreifach durch Fluor oder Chlor substituiertes C \ -C \ 6-Alkyl, C2-C] 6-Alkenyl, Ci-C6-Alkoxy-C2-C6-alkyl oder PoIy-Ci -C6-alkoxy-C2-C6-alkyl,in each case optionally mono- to disubstituted by fluorine, chlorine, bromine, amino or C 1 -C 4 -alkyl-substituted pyridyloxy-C 1 -C 5 -alkyl, pyrimidyloxy-C 1 -C 5 -alkyl or thiazolyloxyC 1 -C 5 -alkyl, R 1 particularly preferably represents in each case optionally monosubstituted to trisubstituted by fluorine or chlorine C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 1 -C 6 -alkoxy-C 2 -C 6 -alkyl or poly-C 1 -C 4 -alkyl -C 6 alkoxy-C 2 -C 6 -alkyl,
für gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Ci-C,4-Alkyl oder C1-C4- Alkoxy substituiertes Cß-Cγ-Cycloalkyl oderfor optionally mono- to disubstituted by fluorine, chlorine, Ci-C, 4-alkyl or C1-C4 alkoxy substituted Cβ-Cγ-cycloalkyl or
für jeweils gegebenenfalls einfach bis dreifach durch Fluor, Chlor, Brom, Cyano, Nitro, Ci -C4-Alkyl, Cj ^-Alkoxy, Ci -C3-Halogenalkyl oder Cj -Cß-Halogenalkoxy substituiertes Phenyl oder Benzyl,in each case optionally monosubstituted to trisubstituted by fluorine, chlorine, bromine, cyano, nitro, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 3 -haloalkyl or C 1 -C 6 -haloalkoxy, phenyl or benzyl,
R^ steht besonders bevorzugt für gegebenenfalls einfach bis dreifach durch Fluor oder Chlor substituiertes C] -C5-Alkyl oder jeweils gegebenenfalls einfach bis zweifach durch Fluor,R 1 particularly preferably represents C 1 -C 5 -alkyl which is optionally monosubstituted to trisubstituted by fluorine or chlorine, or in each case optionally monosubstituted to fluorine,
Chlor, Brom, Ci -C4-Alkyl, Cj-C4-Alkoxy, Ci-C2-Halogenalkoxy, Ci-C2-Halogenalkyl, Cyano oder Nitro substituiertes Phenyl oder Benzyl,Chlorine, bromine, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 2 -haloalkoxy, C 1 -C 2 -haloalkyl, cyano- or nitro-substituted phenyl or benzyl,
R^ und R^ stehen unabhängig voneinander besonders bevorzugt für jeweils gegebenenfalls einfach bis dreifach durch Fluor oder Chlor substituiertes C]-C6-Alkyl, Cj-C6-AIkOXy, Cj-C6- Alkylamino, Di-(C 1 -C6-alkyl)amino, C \ -Cg-Alkylthio oder C3-C4-Alkenylthio oder für jeweils gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Brom, Nitro, Cyano, C\- C3-Alkoxy, Cj^-Halogenalkoxy, Cj^-Alkylthio, Cj^-Halogenalkylthio, C1 -C3- Alkyl oder Cj-C3-Halogenalkyl substituiertes Phenyl, Phenoxy oder Phenylthio,R ^ and R ^ independently of one another particularly preferably in each case optionally mono- to trisubstituted by fluorine or chlorine, C] -C6 alkyl, Cj-C 6 -alkoxy, C j -C 6 - alkylamino, di- (C 1 - C 6 alkyl) amino, C 1 -C 6 alkylthio or C 3 -C 4 alkenylthio, or in each case optionally mono- or disubstituted by fluorine, chlorine, bromine, nitro, cyano, C 1 -C 3 -alkoxy, C 1 -C 4 -haloalkoxy, C j ^ alkylthio, C j ^ haloalkylthio, C1 -C3- alkyl, or Cj-C3-halogenoalkyl-substituted phenyl, phenoxy or phenylthio,
R^ und R^ stehen unabhängig voneinander besonders bevorzugt für Wasserstoff, für jeweils gegebenenfalls einfach bis dreifach durch Fluor oder Chlor substituiertes Ci -Cö-Alkyl,R 1 and R 2 independently of one another particularly preferably represent hydrogen, in each case optionally mono- to trisubstituted by fluorine or chlorine, C 1 -C 6 -alkyl,
C3-C6-Cycloalkyl, C 1 -Cg-Alkoxy, C3-C6-Alkenyl oder für jeweils gegebenenfalls einfach bis dreifach durch Fluor, Chlor, Brom, Cj -C5-Halo- genalkyl, Cj -C5-Alkyl oder C] -C5-Alkoxy substituiertes Phenyl oder Benzyl, oder zusammen für einen gegebenenfalls durch Cj-C4-Alkyl substituierten C3-C6-Alkylenrest, in welchem gegebenenfalls eine Methylengruppe durch Sauerstoff oder Schwefel ersetzt ist.C 3 -C 6 -cycloalkyl, C 1 -Cg -alkoxy, C 3 -C 6 -alkenyl or in each case optionally mono- to trisubstituted j by fluorine, chlorine, bromine, C-C5 halo- genalkyl, Cj-C5-alkyl or C] -C5-alkoxy-substituted phenyl or benzyl, or together represent an optionally substituted by C j -C4- Alkyl-substituted C 3 -C 6 -alkylene radical in which optionally a methylene group is replaced by oxygen or sulfur.
In den als besonders bevorzugt genannten Restedefinitionen steht Halogen für Fluor, Chlor und Brom, insbesondere für Fluor und Chlor.In the radical definitions mentioned as being particularly preferred, halogen is fluorine, chlorine and bromine, in particular fluorine and chlorine.
W steht ganz besonders bevorzugt für Wasserstoff, Chlor, Brom, Methyl, Ethyl, Methoxy, Ethoxy oder Trifluormethyl,W is very particularly preferably hydrogen, chlorine, bromine, methyl, ethyl, methoxy, ethoxy or trifluoromethyl,
X steht ganz besonders bevorzugt für Chlor, Brom, Methyl, Ethyl, Methoxy, Ethoxy, Trifluormethyl, Difluormethoxy, Trifluormethoxy oder Cyano, Y und Z stehen ganz besonders bevorzugt unabhängig voneinander für Wasserstoff, Fluor, Chlor, Brom, Methyl, Ethyl, Methoxy, Trifluormethyl, Trifluormethoxy oder Cyano,X very particularly preferably represents chlorine, bromine, methyl, ethyl, methoxy, ethoxy, trifluoromethyl, difluoromethoxy, trifluoromethoxy or cyano, Y and Z very particularly preferably independently of one another represent hydrogen, fluorine, chlorine, bromine, methyl, ethyl, methoxy, trifluoromethyl, trifluoromethoxy or cyano,
A und B und das Kohlenstoffatom, an dass sie gebunden sind, stehen ganz besonders bevorzugt für ein gegebenenfalls einfach bis zweifach durch Methyl, Ethyl, Propyl, Trifluormethyl, Monochlormethyl, Methoxy, Ethoxy, Methoxymethyl oder Ethoxymethyl substituiertes fünf- oder sechsgliedriges Ketal,A and B and the carbon atom to which they are attached very particularly preferably represent a five- or six-membered ketal which is optionally mono- to disubstituted by methyl, ethyl, propyl, trifluoromethyl, monochloromethyl, methoxy, ethoxy, methoxymethyl or ethoxymethyl.
steht ganz besonders bevorzugt für Wasserstoff (a) oder für eine der Gruppenis very particularly preferably hydrogen (a) or one of the groups
A I R2 /SO^3 AIR 2 / SO ^ 3
^R1 ^> ^V (O, (d),^ R 1 ^ > ^ V (O, (d),
? (g), ? (g) ,
in welchenin which
E für ein Metallion oder ein Ammoniumion steht,E is a metal ion or an ammonium ion,
L für Sauerstoff oder Schwefel steht undL stands for oxygen or sulfur and
M für Sauerstoff oder Schwefel steht,M is oxygen or sulfur,
R.1 steht ganz besonders bevorzugt für jeweils gegebenenfalls einfach bis dreifach durch Fluor oder Chlor substituiertes Ci -Cjo-Alkyl, C2-Cjo-Alkenyl, Ci-C4-Alkoxy-Ci-C2-alkyl, Ci -C4-Alkylthio-C|-C2-alkyl oder für gegebenenfalls einfach durch Fluor, Chlor, Methyl,R.1 very particularly preferably represents in each case optionally mono- to trisubstituted by fluorine or chlorine, Ci -Cjo-alkyl, C2-C j o-alkenyl, Ci-C4-alkoxy-Ci-C2-alkyl, Ci-C4-alkylthio C 1 -C 2 -alkyl or, if appropriate, simply by fluorine, chlorine, methyl,
Ethyl oder Methoxy substituiertes C3-C6-Cycloalkyl,Ethyl or methoxy substituted C3-C6-cycloalkyl,
für gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Brom, Cyano, Nitro, Methyl, Ethyl, n-Propyl, i-Propyl, Methoxy, Ethoxy, Trifluormethyl oder Trifluormethoxy substituiertes Phenyl,optionally phenyl substituted once to twice by fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, n-propyl, i-propyl, methoxy, ethoxy, trifluoromethyl or trifluoromethoxy,
für jeweils gegebenenfalls einfach durch Chlor, Brom oder Methyl substituiertes Furanyl,each optionally optionally substituted by chlorine, bromine or methyl furanyl,
Thienyl oder Pyridyl,Thienyl or pyridyl,
R.2 steht ganz besonders bevorzugt für jeweils gegebenenfalls einfach bis dreifach durch Fluor oder Chlor substituiertes Cj-Cio-Alkyl, C2-Cκ)-Alkenyl oder C \ -C4-Alkoxy-C2-C4- alkyl,R.2 very particularly preferably represents in each case optionally mono- to trisubstituted by fluorine or chlorine, Cj-Cio-alkyl, C2-Cκ) alkenyl, or C \ -C4-alkoxy-C2-C4 alkyl,
für Cyclopentyl oder Cyclohexylfor cyclopentyl or cyclohexyl
oder für jeweils gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Cyano, Nitro, Methyl, Ethyl, Methoxy, Trifluormethyl oder Trifluormethoxy substituiertes Phenyl oder Benzyl,or phenyl or benzyl which is optionally mono- to disubstituted by fluorine, chlorine, cyano, nitro, methyl, ethyl, methoxy, trifluoromethyl or trifluoromethoxy,
R.3 steht ganz besonders bevorzugt für jeweils gegebenenfalls einfach bis dreifach durch Fluor oder Chlor substituiertes Methyl, Ethyl, Propyl oder iso-Propyl, oder gegebenenfalls einfach durch Fluor, Chlor, Brom, Methyl, Ethyl, iso-Propyl, tert.-Butyl, Methoxy, Ethoxy, iso-Propoxy, Trifluormethyl, Trifluormethoxy, Cyano oder Nitro substituiertes Phenyl,R.3 very particularly preferably represents in each case optionally mono- to trisubstituted by fluorine or chlorine, methyl, ethyl, propyl or iso-propyl, or optionally simply by fluorine, chlorine, bromine, methyl, ethyl, iso-propyl, tert-butyl , Methoxy, ethoxy, isopropoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro substituted phenyl,
R.4 und R.5 stehen unabhängig voneinander ganz besonders bevorzugt für Ci -C4-Alkoxy oder C\- C4-Alkylthio oder für jeweils gegebenenfalls einfach durch Fluor, Chlor, Brom, Nitro, Cyano, Methyl, Methoxy, Trifluormethyl oder Trifluormethoxy substituiertes Phenyl, Phenoxy oder Phenylthio,R.4 and R.5 independently of one another very particularly preferably represent C 1 -C 4 -alkoxy or C 1 -C 4 -alkylthio or in each case optionally simply by fluorine, chlorine, bromine, nitro, cyano, methyl, methoxy, trifluoromethyl or trifluoromethoxy substituted phenyl, phenoxy or phenylthio,
RÖ und R^ stehen unabhängig voneinander ganz besonders bevorzugt für Wasserstoff, für Ci-C4- Alkyl, Cß-Cg-Cycloalkyl, C1-C4-AIkOXy, C3-C4-Alkenyl oder Cj-C4-AIkOXy-C2-C4- alkyl, für gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Brom, Methyl, Methoxy oder Trifluormethyl substituiertes Phenyl, oder zusammen für einen C5-Cg-Alkylenrest, in welchem gegebenenfalls eine Methylengruppe durch Sauerstoff oder Schwefel ersetzt ist.R east and R ^ are, independently of one another very particularly preferably represents hydrogen, Ci-C 4 - alkyl, CSS-Cg cycloalkyl, C 1 -C 4 -alkoxy, C3-C4 alkenyl, or Cj-C 4 -AIkOXy- C 2 -C 4 - alkyl, optionally mono- to disubstituted by fluorine, chlorine, bromine, methyl, methoxy or trifluoromethyl substituted phenyl, or together represent a C5-Cg-alkylene radical in which optionally a methylene group is replaced by oxygen or sulfur.
W steht insbesondere bevorzugt für Wasserstoff, Chlor, Brom, Methyl, Ethyl oder Methoxy,W is particularly preferably hydrogen, chlorine, bromine, methyl, ethyl or methoxy,
X steht insbesondere bevorzugt für Chlor, Brom, Methyl, Ethyl oder Methoxy,X is particularly preferably chlorine, bromine, methyl, ethyl or methoxy,
Y und Z stehen insbesondere bevorzugt unabhängig voneinander für Wasserstoff, Chlor, Brom oder Methyl,Y and Z are more preferably independently of one another hydrogen, chlorine, bromine or methyl,
A und B und das Kohlenstoffatom, an dass sie gebunden sind, stehen insbesondere bevorzugt für ein gegebenenfalls einfach bis zweifach durch Methyl, Ethyl, Propyl, Monochlormethyl oder Methoxymethyl substituiertes fünf- oder sechsgliedriges Ketal,A and B and the carbon atom to which they are bonded are particularly preferably a five- or six-membered ketal which is optionally mono- to disubstituted by methyl, ethyl, propyl, monochloromethyl or methoxymethyl.
G steht insbesondere bevorzugt für Wasserstoff (a) oder für eine der GruppenG is particularly preferably hydrogen (a) or one of the groups
O OO O
^^ R1 (b) ^^ o ' (c) oder E (O R I steht insbesondere bevorzugt für Ci-Cjg-Alkyl, Ci-C4-Alkoxy-C]-C2-alkyl, Cß-Cg- Cycloalkyl,^^ R 1 (b) ^^ o '(c) or E (O RI is particularly preferred for Ci-Cjg alkyl, Ci-C4-alkoxy-C] -C2-alkyl, CSS-Cg cycloalkyl,
für gegebenenfalls einfach durch Chlor substituiertes Phenyl, oder für Thienyl,for optionally monosubstituted by chlorine phenyl, or for thienyl,
R.2 steht insbesondere bevorzugt für Cj-Cjo-Alkyl, C2-Cjo-Alkenyl, oder für Benzyl.R.2 especially preferably represents Cj-C j o-alkyl, C2-C jo-alkenyl, or benzyl.
Die oben aufgeführten allgemeinen oder in Vorzugsbereichen aufgeführten Restedefinitionen bzw. Erläuterungen können untereinander, also auch zwischen den jeweiligen Bereichen und Vorzugsbereichen beliebig kombiniert werden.The general or preferred radical definitions or explanations given above can be combined as desired with one another, ie also between the respective ranges and preferred ranges.
Erfindungsgemäß bevorzugt werden die Verbindungen der Formel (I), in welchen eine Kombination der vorstehend als bevorzugt (vorzugsweise) aufgeführten Bedeutungen vorliegt.Preference according to the invention is given to the compounds of the formula (I) which contain a combination of the meanings listed above as being preferred (preferred).
Erfindungsgemäß besonders bevorzugt werden die Verbindungen der Formel (I), in welchen eine Kombination der vorstehend als besonders bevorzugt aufgeführten Bedeutungen vorliegt.Particular preference according to the invention is given to the compounds of the formula (I) in which a combination of the meanings listed above as being particularly preferred is present.
Erfindungsgemäß ganz besonders bevorzugt werden die Verbindungen der Formel (I), in welchen eine Kombination der vorstehend als ganz besonders bevorzugt aufgeführten Bedeutungen vorliegt.Very particular preference according to the invention is given to the compounds of the formula (I) which contain a combination of the meanings given above as being very particularly preferred.
Erfindungsgemäß insbesondere bevorzugt werden die Verbindungen der Formel (I), in welchen eine Kombination der vorstehend als insbesondere bevorzugt aufgeführten Bedeutungen vorliegt.Especially preferred according to the invention are the compounds of the formula (I) which contain a combination of the meanings given above as being particularly preferred.
Hervorgehoben sind Verbindungen der Formel (I) in welchen G für Wasserstoff steht.Emphasis is given to compounds of the formula (I) in which G is hydrogen.
Im Fall der Verbindungen der Formel (I) ist der Phenylring hervorgehoben 3-fach substituiert, wobei sich folgende Substitutionsmuster ergeben: 2,4,6-; 2,4,5- oder 2,5,6-Substitution. Außerdem ist im der Fall der Verbindungen der Formel (I) der Phenylring hervorgehoben 4-fach substituiert, wobei sich folgendes Substitutionsmuster ergibt: 2,4,5,6-Substitution. Im Falle der Verbindungen der Formel (I) ist der Phenylring hervorgehoben auch 2-fach (2,4-; 2,5-Position) substituiert. Im Falle der Verbindungen der Formel (I) ist der Phenylring hervorgehoben auch 1-fach (ortho Position) substituiert. Die übrigen Substituenten W, X, Y, Z, G, A und B haben die im Text genannten Definitionen.In the case of the compounds of the formula (I), the phenyl ring is highlighted substituted 3-fold, resulting in the following substitution patterns: 2,4,6-; 2,4,5- or 2,5,6-substitution. In addition, in the case of the compounds of formula (I), the phenyl ring is highlighted substituted 4-fold, giving the following substitution pattern: 2,4,5,6-Substitution. In the case of the compounds of the formula (I), the phenyl ring is also pronouncedly substituted twice (2,4-; 2,5-position). In the case of the compounds of the formula (I), the phenyl ring is also pronouncedly substituted once (ortho position). The remaining substituents W, X, Y, Z, G, A and B have the definitions given in the text.
Gesättigte oder ungesättigte Kohlenwasserstoffreste wie Alkyl, Alkandiyl oder Alkenyl können, auch in Verbindung mit Heteroatomen, wie z.B. in Alkoxy, soweit möglich, jeweils geradkettig oder verzweigt sein.Saturated or unsaturated hydrocarbon radicals such as alkyl, alkanediyl or alkenyl may also be used in conjunction with heteroatoms, e.g. in alkoxy, as far as possible, in each case straight-chain or branched.
Gegebenenfalls substituierte Reste können, sofern nicht anderes angegeben ist, einfach oder mehr- fach substituiert sein, wobei bei Mehrfachsubstitutionen die Substituenten gleich oder verschieden sein können.Unless otherwise specified, optionally substituted radicals may be monosubstituted or polysubstituted, with multiple substituents being the same or different substituents could be.
Hervorgehoben bevorzugt sind die Verbindungen der Formel (I) mit G = WasserstoffParticularly preferred are the compounds of the formula (I) where G = hydrogen
Überraschenderweise ist die insektizide und / oder akarizide Wirkung der erfindungsgemäßen Wirkstoffkombinationen wesentlich höher als die Summe der Wirkungen der einzelnen Wirkstoffe. Es liegt ein nicht vorhersehbarer echter synergistischer Effekt vor und nicht nur eine Wirkungsergänzung.Surprisingly, the insecticidal and / or acaricidal activity of the active compound combinations according to the invention is substantially higher than the sum of the effects of the individual active compounds. There is an unpredictable true synergistic effect and not just an effect supplement.
Bevorzugt sind Wirkstoffkombinationen enthaltend mindestens eine Verbindung der Formeln (I- 1) bis (1-6) und mindestens einen Wirkstoff der Formel (II).Preference is given to active compound combinations comprising at least one compound of the formulas (I-1) to (1-6) and at least one active compound of the formula (II).
Von besonderem Interesse sind folgende Kombinationen: -1 + II-1A-1 1-1 + 11-1 B-2 1-1 + 11-1 B-38-1 + II-1A-2 1-1 + II-1 B-3 1-1 + II-1 B-39-1 + II-1A-3 1-1 + 11-1 B-4 1-1 + 11-1 B-40-1 + II-1A-4 1-1 + II-1 B-5 1-1 + 11-1 B-41-1 + II-1A-5 1-1 + 11-1 B-6 1-1 + 11-1 B-42-1 + II-1A-6 1-1 + II-1 B-7 1-1 + 11-1 B-43-1 + II-1A-7 1-1 + II-1 B-8 1-1 + 11-1 B-44-1 + II-1A-8 1-1 + II-1 B-9 1-1 + 11-1 B-45-1 + II-1A-9 1-1 + II-1 B-10 1-1 + 11-1 B-46-1 + II-1A-10 1-1 + 11-1 B-11 1-1 + 11-1 B-47-1 + II-1A-1 1 1-1 + II-1 B-12 1-1 + 11-1 B-48-1 + II-1A-12 1-1 + II-1 B-13 1-1 + 11-1 B-49-1 + II-1A-13 1-1 + II-1 B-14 1-1 + 11-1 B-50-1 + II-1A-14 1-1 + II-1 B-15 1-1 + 11-1 B-51-1 + II-1A-15 1-1 + II-1 B-16 1-1 + 11-1 B-52-1 + II-1A-16 1-1 + II-1 B-17 1-1 + 11-1 B-53-1 + II-1A-17 1-1 + II-1 B-18 1-1 + 11-1 B-54-1 + II-1A-18 1-1 + II-1 B-19 1-1 + 11-1 B-55-1 + II-1A-19 1-1 + II-1 B-20 1-1 + 11-1 B-56-1 + II-1A-20 1-1 + 11-1 B-21 1-1 + 11-1 B-57-1 + II-1A-21 1-1 + 11-1 B-22 1-1 + 11-1 B-58-1 + II-1A-22 1-1 + 11-1 B-23 1-1 + 11-1 B-59-1 + II-1A-23 1-1 + 11-1 B-24 1-1 + 11-1 B-60-1 + II-1A-24 1-1 + 11-1 B-25 1-1 + 11-1 B-61-1 + II-1A-25 1-1 + 11-1 B-26 1-1 + 11-1 B-62-1 + II-1A-26 1-1 + 11-1 B-27 1-1 + 11-1 B-63-1 + II-1A-27 1-1 + 11-1 B-28 1-1 + 11-1 B-64-1 + II-1A-28 1-1 + 11-1 B-29 1-1 + 11-1 B-65-1 + II-1A-29 1-1 + 11-1 B-30 1-1 + 11-1 B-66-1 + II-1A-30 1-1 + II-1 B-31 1-1 + 11-1 B-67-1 + II-1A-31 1-1 + 11-1 B-32 1-1 + 11-1 B-68-1 + II-1A-32 1-1 + II-1 B-33 1-1 + 11-1 B-69-1 + II-1A-33 1-1 + 11-1 B-34 1-1 + II-1 B-70-1 + II-1A-34 1-1 + 11-1 B-35 1-1 + II-1 B-71-1 + II-1A-35 1-1 + 11-1 B-36 1-1 + 11-1 B-72-1 + 11-1 B-1 1-1 + 11-1 B-37 1-1 + 11-1 B-73 -1 + 11-1 B-74 1-1 + II-3-9 1-1 + II-3-46-1 + 11-1 B-75 1-1 + 11-3-10 1-1 + II-3-47-1 + 11-1 B-76 1-1 + 11-3-1 1 1-1 + II-3-48-1 + II-1 B-77 1-1 + 11-3-12 1-1 + II-3-49-1 + II-1 B-78 1-1 + 11-3-13 1-1 + II-3-50-1 + 11-1 B-79 1-1 + 11-3-14 1-1 + 11-3-51-1 + II-1 B-80 1-1 + 11-3-15 1-1 + II-3-52-1 + 11-1 B-81 1-1 + 11-3-16 1-1 + II-3-53-1 + 11-1 B-82 1-1 + 11-3-17 1-1 + II-3-54-1 + 11-1 B-83 1-1 + 11-3-18 1-1 + II-3-55-1 + 11-1 B-84 1-1 + 11-3-19 1-1 + II-3-56-1 + 11-1 B-85 1-1 + II-3-20 1-1 + II-3-57-1 + 11-1 B-86 1-1 + 11-3-21 1-1 + II-3-58-1 + 11-1 B-87 1-1 + II-3-22 1-1 + II-4A-1-1 + 11-1 B-88 1-1 + II-3-23 1-1 + II-4A-2-1 + II-2A-1 1-1 + II-3-24 1-1 + II-4A-3-1 + II-2A-2 1-1 + II-3-25 1-1 + II-4A-4-1 + II-2A-3 1-1 + II-3-26 1-1 + II-4A-5-1 + II-2A-4 1-1 + II-3-27 1-1 + II-4A-6-1 + II-2A-5 1-1 + II-3-28 1-1 + II-4A-7-1 + II-2A-6 1-1 + II-3-29 1-1 + II-4A-8-1 + II-2A-7 1-1 + II-3-30 1-1 + II-4A-9-1 + II-2A-8 1-1 + 11-3-31 1-1 + II-4A-10-1 + II-2B-1 1-1 + II-3-32 1-1 + II-4A-1 1-1 + II-2B-2 1-1 + II-3-33 1-1 + II-4B-1-1 + II-2B-3 1-1 + II-3-34 1-1 + II-4B-2-1 + II-2B-4 1-1 + II-3-35 1-1 + II-4B-3-1 + II-2B-5 1-1 + II-3-36 1-1 + II-4B-4-1 + II-2B-6 1-1 + II-3-37 1-1 + II-4C-4-1 + 11-3-1 1-1 + II-3-38 1-1 + 11-5-1-1 + II-3-2 1-1 + II-3-39 1-1 + II-5-2-1 + II-3-3 1-1 + II-3-40 1-1 + 11-6-1-1 + II-3-4 1-1 + 11-3-41 1-1 + II-6-2-1 + II-3-5 1-1 + II-3-42 1-1 + II-6-3-1 + II-3-6 1-1 + II-3-43 1-1 + II-6-4-1 + II-3-7 1-1 + II-3-44 1-1 + II-6-5-1 + II-3-8 1-1 + II-3-45 1-1 + II-6-6 -1 + II-7A-1 1-1 + 11-15-8 1-1 + 11-29-1-1 + II-7A-2 1-1 + 11-15-9 1-1 + II-29-2-1 + II-7A-3 1-1 + 11-15-10 1-1 + II-29-3-1 + II-7A-4 1-1 + 11-15-11 1-1 + II-29-4-1 + II-7A-5 1-1 + 11-15-12 1-1 + II-29-5-1 + II-7B-1 1-1 + 11-15-13 1-1 + II-29-6-1 + II-7C-1 1-1 + 11-16-1 1-1 + II-29-7-1 + II-7C-2 1-1 + 11-17-1 1-1 + II-29-8-1 + II-8A-1 1-1 + II-18A-1 1-1 + II-29-9-1 + II-8B-1 1-1 + 11-18A-2 1-1 + 11-29-10-1 + II-8C-1 1-1 + II-18A-3 1-1 + 11-29-1 1-1 + II-9A-1 1-1 + II-18A-4 1-1 + 11-29-12-1 + II-9B-1 1-1 + II-18A-5 1-1 + 11-29-13-1 + II-9B-2 1-1 + II-18B-1 1-1 + 11-29-14-1 + II-9C-1 1-1 + 11-19-1 1-1 + 11-29-15-1 + 11-1 OA- 1 1-1 + II-20A-1 1-1 + 11-29-16-1 + II-10A-2 1-1 + II-20B-1 1-1 + 11-29-17-1 + II-10B-1 1-1 + II-20C-1 1-1 + 11-29-18-1 + II-12A-1 1-1 + II-20D-1 1-1 + 11-29-19-1 + II-12B-1 1-1 + II-20D-2 1-1 + II-29-20-1 + II-12B-2 1-1 + 11-21-1 1-1 + 11-29-21-1 + II-12B-3 1-1 + 11-21-2 1-1 + M-29-22-1 + II-12C-1 1-1 + 11-21-3 1-1 + II-29-23-1 + II-12C-2 1-1 + 11-21-4 1-1 + N-29-24-1 + 11-13-1 1-1 + 11-21-5 1-1 + II-29-25-1 + 11-13-2 1-1 + 11-21-6 1-1 + M-29-26-1 + 11-13-3 1-1 + 11-21-7 1-1 + II-29-27-1 + 11-13-4 1-1 + II-22A-1 1-1 + II-29-28-1 + 11-13-5 1-1 + II-22B-1 1-1 + II-29-29-1 + 11-13-6 1-1 + II-23A-1 1-1 + M-29-30-1 + 11-15-1 1-1 + II-23A-2 1-1 + 11-29-31-1 + 11-15-2 1-1 + II-23B-1 1-1 + 11-30-1-1 + 11-15-3 1-1 + 11-25-1 I-2 + II-1A-1-1 + 11-15-4 1-1 + 11-28-1 I-2 + II-1A-2-1 + 11-15-5 1-1 + II-28-2 I-2 + II-1A-3-1 + 11-15-6 1-1 + II-28-3 I-2 + II-1A-4-1 + 11-15-7 1-1 + II-28-4 I-2 + II-1A-5 1-2 + U-1A-6 I-2 + II-1 B-8 I-2 + 11-1 B-45Of particular interest are the following combinations: -1 + II-1A-1 1-1 + 11-1 B-2 1-1 + 11-1 B-38-1 + II-1A-2 1-1 + II-1 B-3 1-1 + II-1 B-39-1 + II-1A-3 1-1 + 11-1 B-4 1-1 + 11-1 B-40-1 + II-1A-4 1-1 + II-1 B -5 1-1 + 11-1 B-41-1 + II-1A-5 1-1 + 11-1 B-6 1-1 + 11-1 B-42-1 + II-1A-6 1- 1 + II-1 B-7 1-1 + 11-1 B-43-1 + II-1A-7 1-1 + II-1 B-8 1-1 + 11-1 B-44-1 + II -1A-8 1-1 + II-1 B-9 1-1 + 11-1B-45-1 + II-1A-9 1-1 + II-1 B-10 1-1 + 11-1B -46-1 + II-1A-10 1-1 + 11-1 B-11 1-1 + 11-1 B-47-1 + II-1A-1 1 1-1 + II-1 B-12 1 -1 + 11-1 B-48-1 + II-1A-12 1-1 + II-1 B-13 1-1 + 11-1 B-49-1 + II-1A-13 1-1 + II -1 B-14 1-1 + 11-1 B-50-1 + II-1A-14 1-1 + II-1 B-15 1-1 + 11-1 B-51-1 + II-1A- 15 1-1 + II-1 B-16 1-1 + 11-1 B-52-1 + II-1A-16 1-1 + II-1 B-17 1-1 + 11-1 B-53- 1 + II-1A-17 1-1 + II-1 B-18 1-1 + 11-1 B-54-1 + II-1A-18 1-1 + II-1 B-19 1-1 + 11 -1 B-55-1 + II-1A-19 1-1 + II-1 B-20 1-1 + 11-1 B-56-1 + II-1A-20 1-1 + 11-1 B- 21 1-1 + 11-1 B-57-1 + II-1A-21 1-1 + 11-1 B-22 1-1 + 11-1 B-58-1 + II-1A-22 1-1 + 11-1 B-23 1-1 + 11-1 B-59-1 + II-1A-23 1-1 + 11-1 B -24 1-1 + 11-1 B-60-1 + II-1A-24 1-1 + 11-1 B-25 1-1 + 11-1 B-61-1 + II-1A-25 1- 1 + 11-1 B-26 1-1 + 11-1 B-62-1 + II-1A-26 1-1 + 11-1 B-27 1-1 + 11-1 B-63-1 + II -1A-27 1-1 + 11-1 B-28 1-1 + 11-1 B-64-1 + II-1A-28 1-1 + 11-1 B-29 1-1 + 11-1 B -65-1 + II-1A-29 1-1 + 11-1 B-30 1-1 + 11-1 B-66-1 + II-1A-30 1-1 + II-1 B-31 1- 1 + 11-1 B-67-1 + II-1A-31 1-1 + 11-1 B-32 1-1 + 11-1 B-68-1 + II-1A-32 1-1 + II- 1 B-33 1-1 + 11-1 B-69-1 + II-1A-33 1-1 + 11-1 B-34 1-1 + II-1 B-70-1 + II-1A-34 1-1 + 11-1 B-35 1-1 + II-1 B-71-1 + II-1A-35 1-1 + 11-1 B-36 1-1 + 11-1 B-72-1 + 11-1 B-1 1-1 + 11-1 B-37 1-1 + 11-1 B-73 -1 + 11-1 B-74 1-1 + II-3-9 1-1 + II-3-46-1 + 11-1 B-75 1-1 + 11-3-10 1-1 + II -3-47-1 + 11-1 B-76 1-1 + 11-3-1 1 1-1 + II-3-48-1 + II-1 B-77 1-1 + 11-3-12 1-1 + II-3-49-1 + II-1 B-78 1-1 + 11-3-13 1-1 + II-3-50-1 + 11-1 B-79 1-1 + 11 -3-14 1-1 + 11-3-51-1 + II-1 B-80 1-1 + 11-3-15 1-1 + II-3-52-1 + 11-1 B-81 1 -1 + 11-3-16 1-1 + II-3-53-1 + 11-1 B-82 1-1 + 11-3-17 1-1 + II-3-54-1 + 11-1 B-83 1-1 + 11-3-18 1-1 + II-3-55-1 + 11-1 B-84 1-1 + 11-3-19 1-1 + II-3-56-1 + 11-1 B-85 1-1 + II-3-20 1-1 + II-3-57-1 + 11-1 B-86 1-1 + 11-3-21 1-1 + II-3 -58-1 + 11-1 B-87 1-1 + II-3-22 1-1 + II-4A-1-1 + 11-1 B-88 1-1 + II-3-23 1-1 + II-4A-2-1 + II-2A-1 1-1 + II-3-24 1-1 + II-4A-3-1 + II-2A-2 1-1 + II-3-25 1 -1 + II-4A-4-1 + II-2A-3 1-1 + II-3-26 1-1 + II-4A-5-1 + II-2A-4 1-1 + II-3 27 1-1 + II-4A-6-1 + II-2A-5 1-1 + II-3-28 1-1 + II-4A-7-1 + II-2A-6 1-1 + II- 3-29 1-1 + II-4A-8-1 + II-2A-7 1-1 + II-3-30 1-1 + II-4A-9-1 + II-2A-8 1-1 + 11-3-31 1-1 + II-4A-10-1 + II-2B-1 1-1 + II-3-32 1-1 + II-4A-1 1-1 + II -2B-2 1-1 + II-3-33 1-1 + II-4B-1-1 + II-2B-3 1-1 + II-3-34 1-1 + II-4B-2-1 + II-2B-4 1-1 + II-3-35 1-1 + II-4B-3-1 + II-2B-5 1-1 + II-3-36 1-1 + II-4B-4 -1 + II-2B-6 1-1 + II-3-37 1-1 + II-4C-4-1 + 11-3-1 1-1 + II-3-38 1-1 + 11-5 -1-1 + II-3-2 1-1 + II-3-39 1-1 + II-5-2-1 + II-3-3 1-1 + II-3-40 1-1 + 11 -6-1-1 + II-3-4 1-1 + 11-3-41 1-1 + II-6-2-1 + II-3-5 1-1 + II-3-42 1-1 + II-6-3-1 + II-3-6 1-1 + II-3-43 1-1 + II-6-4-1 + II-3-7 1-1 + II-3-44 1 -1 + II-6-5-1 + II-3-8 1-1 + II-3-45 1-1 + II-6-6 -1 + II-7A-1 1-1 + 11-15-8 1-1 + 11-29-1-1 + II-7A-2 1-1 + 11-15-9 1-1 + II-29 -2-1 + II-7A-3 1-1 + 11-15-10 1-1 + II-29-3-1 + II-7A-4 1-1 + 11-15-11 1-1 + II -29-4-1 + II-7A-5 1-1 + 11-15-12 1-1 + II-29-5-1 + II-7B-1 1-1 + 11-15-13 1-1 + II-29-6-1 + II-7C-1 1-1 + 11-16-1 1-1 + II-29-7-1 + II-7C-2 1-1 + 11-17-1 1 -1 + II-29-8-1 + II-8A-1 1-1 + II-18A-1 1-1 + II-29-9-1 + II-8B-1 1-1 + 11-18A- 2 1-1 + 11-29-10-1 + II-8C-1 1-1 + II-18A-3 1-1 + 11-29-1 1-1 + II-9A-1 1-1 + II -18A-4 1-1 + 11-29-12-1 + II-9B-1 1-1 + II-18A-5 1-1 + 11-29-13-1 + II-9B-2 1-1 + II-18B-1 1-1 + 11-29-14-1 + II-9C-1 1-1 + 11-19-1 1-1 + 11-29-15-1 + 11-1 OA-1 1-1 + II-20A-1 1-1 + 11-29-16-1 + II-10A-2 1-1 + II-20B-1 1-1 + 11-29-17-1 + II-10B -1 1-1 + II-20C-1 1-1 + 11-29-18-1 + II-12A-1 1-1 + II-20D-1 1-1 + 11-29-19-1 + II -12B-1 1-1 + II-20D-2 1-1 + II-29-20-1 + II-12B-2 1-1 + 11-21-1 1-1 + 11-29-21-1 + II-12B-3 1-1 + 11-21-2 1-1 + M-29-22-1 + II-12C-1 1-1 + 11-21-3 1-1 + II-29-23 -1 + II-12C-2 1-1 + 11-21-4 1-1 + N-29-24 -1 + 11-13-1 1-1 + 11-21-5 1-1 + II-29-25-1 + 11-13-2 1-1 + 11-21-6 1-1 + M-29 -26-1 + 11-13-3 1-1 + 11-21-7 1-1 + II-29-27-1 + 11-13-4 1-1 + II-22A-1 1-1 + II -29-28-1 + 11-13-5 1-1 + II-22B-1 1-1 + II-29-29-1 + 11-13-6 1-1 + II-23A-1 1-1 + M-29-30-1 + 11-15-1 1-1 + II-23A-2 1-1 + 11-29-31-1 + 11-15-2 1-1 + II-23B-1 1 -1 + 11-30-1-1 + 11-15-3 1-1 + 11-25-1 I-2 + II-1A-1-1 + 11-15-4 1-1 + 11-28- 1 I-2 + II-1A-2-1 + 11-15-5 1-1 + II-28-2 I-2 + II-1A-3-1 + 11-15-6 1-1 + II- 28-3 I-2 + II-1A-4-1 + 11-15-7 1-1 + II-28-4 I-2 + II-1A-5 1-2 + U-1A-6 I-2 + II-1 B-8 I-2 + 11-1 B-45
I-2 + 11-1 A-7 I-2 + 11-1 B-9 I-2 + 11-1 B-46I-2 + 11-1 A-7 I-2 + 11-1 B-9 I-2 + 11-1 B-46
I-2 + II-1A-8 I-2 + II-1B-10 I-2 + II-1 B-47I-2 + II-1A-8 I-2 + II-1B-10 I-2 + II-1 B-47
I-2 + 11-1 A-9 I-2 + 11-1 B-11 I-2 + 11-1 B-48I-2 + 11-1 A-9 I-2 + 11-1 B-11 I-2 + 11-1 B-48
I-2 + II-1A-10 I-2 + II-1 B-12 I-2 + II-1 B-49I-2 + II-1A-10 I-2 + II-1 B-12 I-2 + II-1 B-49
I-2 + 11-1 A-11 I-2 + 11-1 B-13 I-2 + II-1 B-50I-2 + 11-1 A-11 I-2 + 11-1 B-13 I-2 + II-1 B-50
I-2 + 11-1 A-12 I-2 + 11-1 B-14 I-2 + 11-1 B-51I-2 + 11-1 A-12 I-2 + 11-1 B-14 I-2 + 11-1 B-51
I-2 + II-1A-13 I-2 + 11-1 B-15 I-2 + II-1 B-52I-2 + II-1A-13 I-2 + 11-1 B-15 I-2 + II-1 B-52
I-2 11-1 A-14 I-2 + 11-1 B-16 I-2 + 11-1 B-53I-2 11-1 A-14 I-2 + 11-1 B-16 I-2 + 11-1 B-53
I-2 + II-1A-15 I-2 + II-1 B-17 I-2 + II-1 B-54I-2 + II-1A-15 I-2 + II-1 B-17 I-2 + II-1 B-54
I-2 + II-1A-16 I-2 + II-1 B-18 I-2 + II-1 B-55I-2 + II-1A-16 I-2 + II-1 B-18 I-2 + II-1 B-55
I-2 + II-1A-17 I-2 + II-1 B-19 I-2 + II-1 B-56I-2 + II-1A-17 I-2 + II-1 B-19 I-2 + II-1 B-56
I-2 + II-1A-18 I-2 + II-1 B-20 I-2 + II-1 B-57I-2 + II-1A-18 I-2 + II-1 B-20 I-2 + II-1 B-57
I-2 + II-1A-19 I-2 + II-1 B-21 I-2 + II-1 B-58I-2 + II-1A-19 I-2 + II-1 B-21 I-2 + II-1 B-58
I-2 + 11-1 A-20 I-2 + 11-1 B-22 I-2 + 11-1 B-59I-2 + 11-1 A-20 I-2 + 11-1 B-22 I-2 + 11-1 B-59
I-2 + 11-1 A-21 I-2 + 11-1 B-23 I-2 + 11-1 B-60I-2 + 11-1 A-21 I-2 + 11-1 B-23 I-2 + 11-1 B-60
I-2 + II-1A-22 I-2 + 11-1 B-24 I-2 + 11-1 B-61I-2 + II-1A-22 I-2 + 11-1 B-24 I-2 + 11-1 B-61
I-2 + 11-1 A-23 I-2 + 11-1 B-25 I-2 + 11-1 B-62I-2 + 11-1 A-23 I-2 + 11-1 B-25 I-2 + 11-1 B-62
I-2 + 11-1 A-24 I-2 + 11-1 B-26 I-2 + 11-1 B-63I-2 + 11-1 A-24 I-2 + 11-1 B-26 I-2 + 11-1 B-63
I-2 + 11-1 A-25 I-2 + II-1 B-27 I-2 + 11-1 B-64I-2 + 11-1 A-25 I-2 + II-1 B-27 I-2 + 11-1 B-64
I-2 + II-1A-26 I-2 + 11-1 B-28 I-2 + 11-1 B-65I-2 + II-1A-26 I-2 + 11-1 B-28 I-2 + 11-1 B-65
I-2 + 11-1 A-27 I-2 + 11-1 B-29 I-2 + II-1 B-66I-2 + 11-1 A-27 I-2 + 11-1 B-29 I-2 + II-1 B-66
I-2 + 11-1 A-28 I-2 + II-1 B-30 I-2 + 11-1 B-67I-2 + 11-1 A-28 I-2 + II-1 B-30 I-2 + 11-1 B-67
I-2 + 11-1 A-29 I-2 + 11-1 B-31 I-2 + 11-1 B-68I-2 + 11-1 A-29 I-2 + 11-1 B-31 I-2 + 11-1 B-68
I-2 + 11-1 A-30 I-2 + 11-1 B-32 I-2 + 11-1 B-69I-2 + 11-1 A-30 I-2 + 11-1 B-32 I-2 + 11-1 B-69
I-2 + II-1A-31 I-2 + 11-1 B-33 I-2 + 11-1 B-70I-2 + II-1A-31 I-2 + 11-1 B-33 I-2 + 11-1 B-70
I-2 + 11-1 A-32 I-2 + II-1 B-34 I-2 + 11-1 B-71I-2 + 11-1 A-32 I-2 + II-1 B-34 I-2 + 11-1 B-71
I-2 + 11-1 A-33 I-2 + 11-1 B-35 I-2 + 11-1 B-72I-2 + 11-1 A-33 I-2 + 11-1 B-35 I-2 + 11-1 B-72
I-2 + 11-1 A-34 I-2 + 11-1 B-36 I-2 + 11-1 B-73I-2 + 11-1 A-34 I-2 + 11-1 B-36 I-2 + 11-1 B-73
I-2 + 11-1 A-35 I-2 + II-1 B-37 I-2 + 11-1 B-74I-2 + 11-1 A-35 I-2 + II-1 B-37 I-2 + 11-1 B-74
I-2 + 11-1 B-1 I-2 + 11-1 B-38 I-2 + 11-1 B-75I-2 + 11-1 B-1 I-2 + 11-1 B-38 I-2 + 11-1 B-75
I-2 + II-1 B-2 I-2 + 11-1 B-39 I-2 + 11-1 B-76I-2 + II-1 B-2 I-2 + 11-1 B-39 I-2 + 11-1 B-76
I-2 + II-1 B-3 I-2 + 11-1 B-40 I-2 + 11-1 B-77I-2 + II-1 B-3 I-2 + 11-1 B-40 I-2 + 11-1 B-77
I-2 + 11-1 B-4 I-2 + 11-1 B-41 I-2 + 11-1 B-78I-2 + 11-1 B-4 I-2 + 11-1 B-41 I-2 + 11-1 B-78
I-2 + 11-1 B-5 I-2 + 11-1 B-42 I-2 + 11-1 B-79I-2 + 11-1 B-5 I-2 + 11-1 B-42 I-2 + 11-1 B-79
I-2 + 11-1 B-6 I-2 + 11-1 B-43 I-2 + 11-1 B-80I-2 + 11-1 B-6 I-2 + 11-1 B-43 I-2 + 11-1 B-80
I-2 + 11-1 B-7 I-2 + 11-1 B-44 I-2 + 11-1 B-81 1-2 + 11-1 B-82 I-2 + 11-3-17 I-2 + II-3-54I-2 + 11-1 B-7 I-2 + 11-1 B-44 I-2 + 11-1 B-81 1-2 + 11-1 B-82 I-2 + 11-3-17 I-2 + II-3-54
I-2 + 11-1 B-83 I-2 + 11-3-18 I-2 + II-3-55I-2 + 11-1 B-83 I-2 + 11-3-18 I-2 + II-3-55
I-2 + 11-1 B-84 I-2 + 11-3-19 I-2 + II-3-56I-2 + 11-1 B-84 I-2 + 11-3-19 I-2 + II-3-56
I-2 + 11-1 B-85 I-2 + II-3-20 I-2 + II-3-57I-2 + 11-1 B-85 I-2 + II-3-20 I-2 + II-3-57
I-2 + II-1 B-86 I-2 + 11-3-21 I-2 + II-3-58I-2 + II-1 B-86 I-2 + 11-3-21 I-2 + II-3-58
I-2 + 11-1 B-87 I-2 + II-3-22 I-2 + II-4A-1I-2 + 11-1 B-87 I-2 + II-3-22 I-2 + II-4A-1
I-2 + 11-1 B-88 I-2 + II-3-23 I-2 + II-4A-2I-2 + 11-1 B-88 I-2 + II-3-23 I-2 + II-4A-2
I-2 + II-2A-1 I-2 + II-3-24 I-2 + II-4A-3I-2 + II-2A-1 I-2 + II-3-24 I-2 + II-4A-3
I-2 + II-2A-2 I-2 + II-3-25 I-2 + II-4A-4I-2 + II-2A-2 I-2 + II-3-25 I-2 + II-4A-4
I-2 + II-2A-3 I-2 + II-3-26 I-2 + II-4A-5I-2 + II-2A-3I-2 + II-3-26I-2 + II-4A-5
I-2 + II-2A-4 I-2 + II-3-27 I-2 + II-4A-6I-2 + II-2A-4 I-2 + II-3-27 I-2 + II-4A-6
I-2 + II-2A-5 I-2 + II-3-28 I-2 + II-4A-7I-2 + II-2A-5 I-2 + II-3-28 I-2 + II-4A-7
I-2 + II-2A-6 I-2 + II-3-29 I-2 + II-4A-8I-2 + II-2A-6 I-2 + II-3-29 I-2 + II-4A-8
I-2 + II-2A-7 I-2 + II-3-30 I-2 + II-4A-9I-2 + II-2A-7 I-2 + II-3-30 I-2 + II-4A-9
I-2 + II-2A-8 I-2 + 11-3-31 I-2 + II-4A-10I-2 + II-2A-8 I-2 + 11-3-31 I-2 + II-4A-10
I-2 + II-2B-1 I-2 + II-3-32 I-2 + II-4A-11I-2 + II-2B-1 I-2 + II-3-32 I-2 + II-4A-11
I-2 + II-2B-2 I-2 + II-3-33 I-2 + II-4B-1I-2 + II-2B-2 I-2 + II-3-33 I-2 + II-4B-1
I-2 + II-2B-3 I-2 + II-3-34 I-2 + II-4B-2I-2 + II-2B-3 I-2 + II-3-34 I-2 + II-4B-2
I-2 + II-2B-4 I-2 + II-3-35 I-2 + II-4B-3I-2 + II-2B-4 I-2 + II-3-35 I-2 + II-4B-3
I-2 + II-2B-5 I-2 + II-3-36 I-2 + II-4B-4I-2 + II-2B-5 I-2 + II-3-36 I-2 + II-4B-4
I-2 + II-2B-6 I-2 + II-3-37 I-2 + II-4C-4I-2 + II-2B-6 I-2 + II-3-37 I-2 + II-4C-4
I-2 + 11-3-1 I-2 + II-3-38 I-2 + 11-5-1I-2 + 11-3-1 I-2 + II-3-38 I-2 + 11-5-1
I-2 + II-3-2 I-2 + II-3-39 I-2 + II-5-2I-2 + II-3-2 I-2 + II-3-39 I-2 + II-5-2
I-2 + II-3-3 I-2 + II-3-40 I-2 + 11-6-1I-2 + II-3-3 I-2 + II-3-40 I-2 + 11-6-1
I-2 + II-3-4 I-2 + 11-3-41 I-2 + II-6-2I-2 + II-3-4 I-2 + 11-3-41 I-2 + II-6-2
I-2 + II-3-5 I-2 + II-3-42 I-2 + II-6-3I-2 + II-3-5 I-2 + II-3-42 I-2 + II-6-3
I-2 + II-3-6 I-2 + II-3-43 I-2 + II-6-4I-2 + II-3-6 I-2 + II-3-43 I-2 + II-6-4
I-2 + II-3-7 I-2 + II-3-44 I-2 + II-6-5I-2 + II-3-7 I-2 + II-3-44 I-2 + II-6-5
I-2 + II-3-8 I-2 + II-3-45 I-2 + II-6-6I-2 + II-3-8 I-2 + II-3-45 I-2 + II-6-6
I-2 + II-3-9 I-2 + II-3-46 I-2 + II-7A-1I-2 + II-3-9 I-2 + II-3-46 I-2 + II-7A-1
I-2 + 11-3-10 I-2 + II-3-47 I-2 + II-7A-2I-2 + 11-3-10 I-2 + II-3-47 I-2 + II-7A-2
I-2 + 11-3-11 I-2 + II-3-48 I-2 + II-7A-3I-2 + 11-3-11 I-2 + II-3-48 I-2 + II-7A-3
I-2 + 11-3-12 I-2 + II-3-49 I-2 + II-7A-4I-2 + 11-3-12 I-2 + II-3-49 I-2 + II-7A-4
I-2 + 11-3-13 I-2 + II-3-50 I-2 + II-7A-5I-2 + 11-3-13 I-2 + II-3-50 I-2 + II-7A-5
I-2 + 11-3-14 I-2 + 11-3-51 I-2 + II-7B-1I-2 + 11-3-14 I-2 + 11-3-51 I-2 + II-7B-1
I-2 + 11-3-15 I-2 + II-3-52 I-2 + II-7C-1I-2 + 11-3-15 I-2 + II-3-52 I-2 + II-7C-1
I-2 + 11-3-16 I-2 + II-3-53 I-2 + II-7C-2 -2 + I I-8A-1 I-2 + 11-18A-1 I-2 + II-29-9-2 + I I-8B-1 I-2 + 11-18A-2 I-2 + 11-29-10-2 + I I-8C-1 I-2 + 11-18A-3 I-2 + 11-29-1 1-2 + I I-9A-1 I-2 + 11-18A-4 I-2 + 11-29-12-2 + I I-9B-1 I-2 + 11-18A-5 I-2 + 11-29-13-2 + I I-9B-2 I-2 + II-18B-1 I-2 + 11-29-14-2 + I I-9C-1 I-2 + 11-19-1 I-2 + 11-29-15-2 + I I-10A-1 I-2 + II-20A-1 I-2 + 11-29-16-2 + I I-10A-2 I-2 + II-20B-1 I-2 + 11-29-17-2 + I I-10B-1 I-2 + II-20C-1 I-2 + 11-29-18-2 + I I-12A-1 I-2 + II-20D-1 I-2 + 11-29-19-2 + I I-12B-1 I-2 + II-20D-2 I-2 + II-29-20-2 + I I-12B-2 I-2 + 11-21-1 I-2 + 11-29-21-2 + I I-12B-3 I-2 + 11-21-2 I-2 + M-29-22-2 + I I-12C-1 I-2 + 11-21 -3 I-2 + M-29-23-2 + I I-12C-2 I-2 + 11-21 -4 I-2 + M-29-24-2 + I 1-13-1 I-2 + 11-21 -5 I-2 + II-29-25-2 + I 1-13-2 I-2 + 11-21 -6 I-2 + M-29-26-2 + I 1-13-3 I-2 + 11-21 -7 I-2 + II-29-27-2 + I 1-13-4 I-2 + II-22A-1 I-2 + II-29-28-2 + I 1-13-5 I-2 + II-22B-1 I-2 + M-29-29-2 + I 1-13-6 I-2 + II-23A-1 I-2 + M-29-30-2 + I 1-15-1 I-2 + II-23A-2 I-2 + 11-29-31-2 + I 1-15-2 I-2 + II-23B-1 I-2 + 11-30-1-2 + I 1-15-3 I-2 + 11-25-1 I-3 + II-1 A-1-2 + I 1-15-4 I-2 + 11-28-1 I-3 + II-1A-2-2 + I 1-15-5 I-2 + II-28-2 I-3 + II-1A-3-2 + I 1-15-6 I-2 + II-28-3 I-3 + II-1A-4-2 + I 1-15-7 I-2 + II-28-4 I-3 + II-1A-5-2 + I 1-15-8 I-2 + 11-29-1 I-3 + II-1A-6-2 + I 1-15-9 I-2 + II-29-2 I-3 + II-1A-7-2 + I 1-15-10 I-2 + II-29-3 I-3 + II-1A-8-2 + I 1-15-11 I-2 + II-29-4 I-3 + II-1A-9-2 + I 1-15-12 I-2 + II-29-5 I-3 + II-1A-10-2 + I 1-15-13 I-2 + II-29-6 I-3 + 11-1 A-1 1-2 + I 1-16-1 I-2 + II-29-7 I-3 + II-1A-12-2 + I 1-17-1 I-2 + II-29-8 I-3 + II-1A-13 1-3 + II-1A-14 I-3 + 11-1 B-16 I-3 + 11-1 B-53I-2 + 11-3-16 I-2 + II-3-53 I-2 + II-7C-2 -2 + I I-8A-1 I-2 + 11-18A-1 I-2 + II-29-9-2 + I I-8B-1 I-2 + 11-18A-2 I-2 + 11 -29-10-2 + I I-8C-1 I-2 + 11-18A-3 I-2 + 11-29-1 1-2 + I I-9A-1 I-2 + 11-18A-4 I-2 + 11-29-12-2 + I I-9B-1 I-2 + 11-18A-5 I-2 + 11-29-13-2 + I I-9B-2 I-2 + II -18B-1 I-2 + 11-29-14-2 + I I-9C-1 I-2 + 11-19-1 I-2 + 11-29-15-2 + I I-10A-1 I -2 + II-20A-1 I-2 + 11-29-16-2 + I I-10A-2 I-2 + II-20B-1 I-2 + 11-29-17-2 + I- 10B-1I-2 + II-20C-1I-2 + 11-29-18-2 + II-12A-1I-2 + II-20D-1I-2 + 11-29-19-2 + I I-12B-1 I-2 + II-20D-2 I-2 + II-29-20-2 + I I-12B-2 I-2 + 11-21-1 I-2 + 11-29 -21-2 + I I-12B-3 I-2 + 11-21-2 I-2 + M-29-22-2 + I I-12C-1 I-2 + 11-21-3 I-2 + M-29-23-2 + I I-12C-2 I-2 + 11-21 -4 I-2 + M-29-24-2 + I 1-13-1 I-2 + 11-21 - 5 I-2 + II-29-25-2 + I 1-13-2 I-2 + 11-21 -6 I-2 + M-29-26-2 + I 1-13-3 I-2 + 11-21 -7 I-2 + II-29-27-2 + I 1-13-4 I-2 + II-22A-1 I-2 + II-29-28-2 + I 1-13-5 I-2 + II-22B-1 I-2 + M-29-29-2 + I 1-13-6 I-2 + II-23A-1 I-2 + M-29-30-2 + I 1 -15-1 I-2 + II-23A-2 I-2 + 11-29-31-2 + I 1-15 -2 I-2 + II-23B-1 I-2 + 11-30-1-2 + I 1-15-3 I-2 + 11-25-1 I-3 + II-1 A-1-2 + I 1-15-4 I-2 + 11-28-1 I-3 + II-1A-2-2 + I 1-15-5 I-2 + II-28-2 I-3 + II-1A -3-2 + I 1-15-6 I-2 + II-28-3 I-3 + II-1A-4-2 + I 1-15-7 I-2 + II-28-4 I-3 + II-1A-5-2 + I 1-15-8 I-2 + 11-29-1 I-3 + II-1A-6-2 + I 1-15-9 I-2 + II-29- 2 I-3 + II-1A-7-2 + I 1-15-10 I-2 + II-29-3 I-3 + II-1A-8-2 + I 1-15-11 I-2 + II-29-4 I-3 + II-1A-9-2 + I 1-15-12 I-2 + II-29-5 I-3 + II-1A-10-2 + I 1-15-13 I-2 + II-29-6 I-3 + 11-1 A-1 1-2 + I 1-16-1 I-2 + II-29-7 I-3 + II-1A-12-2 + I 1-17-1 I-2 + II-29-8 I-3 + II-1A-13 1-3 + II-1A-14 I-3 + 11-1 B-16 I-3 + 11-1 B-53
I-3 + II-1A-15 I-3 + II-1 B-17 I-3 + 11-1 B-54I-3 + II-1A-15 I-3 + II-1 B-17 I-3 + 11-1 B-54
I-3 + II-1A-16 I-3 + II-1 B-18 I-3 + II-1 B-55I-3 + II-1A-16 I-3 + II-1 B-18 I-3 + II-1 B-55
I-3 + II-1A-17 I-3 + II-1 B-19 I-3 + 11-1 B-56I-3 + II-1A-17 I-3 + II-1 B-19 I-3 + 11-1 B-56
I-3 + II-1A-18 I-3 + II-1 B-20 I-3 + II-1 B-57I-3 + II-1A-18 I-3 + II-1 B-20 I-3 + II-1 B-57
I-3 + II-1A-19 I-3 + II-1 B-21 I-3 + II-1B-58I-3 + II-1A-19 I-3 + II-1 B-21 I-3 + II-1B-58
I-3 + 11-1 A-20 I-3 + 11-1 B-22 I-3 + 11-1 B-59I-3 + 11-1 A-20 I-3 + 11-1 B-22 I-3 + 11-1 B-59
I-3 + 11-1 A-21 I-3 + 11-1 B-23 I-3 + 11-1 B-60I-3 + 11-1 A-21 I-3 + 11-1 B-23 I-3 + 11-1 B-60
I-3 + 11-1 A-22 I-3 + 11-1 B-24 I-3 + 11-1 B-61I-3 + 11-1 A-22 I-3 + 11-1 B-24 I-3 + 11-1 B-61
I-3 + 11-1 A-23 I-3 + 11-1 B-25 I-3 + 11-1 B-62I-3 + 11-1 A-23 I-3 + 11-1 B-25 I-3 + 11-1 B-62
I-3 + II-1A-24 I-3 + 11-1 B-26 I-3 + 11-1 B-63I-3 + II-1A-24 I-3 + 11-1 B-26 I-3 + 11-1 B-63
I-3 + 11-1 A-25 I-3 + 11-1 B-27 I-3 + 11-1 B-64I-3 + 11-1 A-25 I-3 + 11-1 B-27 I-3 + 11-1 B-64
I-3 + 11-1 A-26 I-3 + 11-1 B-28 I-3 + II-1 B-65I-3 + 11-1 A-26 I-3 + 11-1 B-28 I-3 + II-1 B-65
I-3 + 11-1 A-27 I-3 + 11-1 B-29 I-3 + 11-1 B-66I-3 + 11-1 A-27 I-3 + 11-1 B-29 I-3 + 11-1 B-66
I-3 + 11-1 A-28 I-3 + 11-1 B-30 I-3 + II-1 B-67I-3 + 11-1 A-28 I-3 + 11-1 B-30 I-3 + II-1 B-67
I-3 + 11-1 A-29 I-3 + 11-1 B-31 I-3 + 11-1 B-68I-3 + 11-1 A-29 I-3 + 11-1 B-31 I-3 + 11-1 B-68
I-3 + 11-1 A-30 I-3 + 11-1 B-32 I-3 + 11-1 B-69I-3 + 11-1 A-30 I-3 + 11-1 B-32 I-3 + 11-1 B-69
I-3 + 11-1 A-31 I-3 + 11-1 B-33 I-3 + 11-1 B-70I-3 + 11-1 A-31 I-3 + 11-1 B-33 I-3 + 11-1 B-70
I-3 + 11-1 A-32 I-3 + 11-1 B-34 I-3 + II-1 B-71I-3 + 11-1 A-32 I-3 + 11-1 B-34 I-3 + II-1 B-71
I-3 + II-1A-33 I-3 + 11-1 B-35 I-3 + 11-1 B-72I-3 + II-1A-33 I-3 + 11-1 B-35 I-3 + 11-1 B-72
I-3 + 11-1 A-34 I-3 + 11-1 B-36 I-3 + 11-1 B-73I-3 + 11-1 A-34 I-3 + 11-1 B-36 I-3 + 11-1 B-73
I-3 + 11-1 A-35 I-3 + 11-1 B-37 I-3 + 11-1 B-74I-3 + 11-1 A-35 I-3 + 11-1 B-37 I-3 + 11-1 B-74
I-3 + 11-1 B- 1 I-3 + 11-1 B-38 I-3 + 11-1 B-75I-3 + 11-1 B-1 I-3 + 11-1 B-38 I-3 + 11-1 B-75
I-3 + II-1 B-2 I-3 + 11-1 B-39 I-3 + 11-1 B-76I-3 + II-1 B-2 I-3 + 11-1 B-39 I-3 + 11-1 B-76
I-3 + 11-1 B-3 I-3 + 11-1 B-40 I-3 + II-1 B-77I-3 + 11-1 B-3 I-3 + 11-1 B-40 I-3 + II-1 B-77
I-3 + 11-1 B-4 I-3 + 11-1 B-41 I-3 + 11-1 B-78I-3 + 11-1 B-4 I-3 + 11-1 B-41 I-3 + 11-1 B-78
I-3 + 11-1 B-5 I-3 + 11-1 B-42 I-3 + 11-1 B-79I-3 + 11-1 B-5 I-3 + 11-1 B-42 I-3 + 11-1 B-79
I-3 + 11-1 B-6 I-3 + 11-1 B-43 I-3 + 11-1 B-80I-3 + 11-1 B-6 I-3 + 11-1 B-43 I-3 + 11-1 B-80
I-3 + 11-1 B-7 I-3 + 11-1 B-44 I-3 + 11-1 B-81I-3 + 11-1 B-7 I-3 + 11-1 B-44 I-3 + 11-1 B-81
I-3 + II-1 B-8 I-3 + 11-1 B-45 I-3 + 11-1 B-82I-3 + II-1 B-8 I-3 + 11-1 B-45 I-3 + 11-1 B-82
I-3 + 11-1 B-9 I-3 + 11-1 B-46 I-3 + 11-1 B-83I-3 + 11-1 B-9 I-3 + 11-1 B-46 I-3 + 11-1 B-83
I-3 + 11-1 B-10 I-3 + 11-1 B-47 I-3 + 11-1 B-84I-3 + 11-1 B-10 I-3 + 11-1 B-47 I-3 + 11-1 B-84
I-3 + 11-1 B-1 1 I-3 + 11-1 B-48 I-3 + 11-1 B-85I-3 + 11-1 B-1 1 I-3 + 11-1 B-48 I-3 + 11-1 B-85
I-3 + 11-1 B-12 I-3 + 11-1 B-49 I-3 + II-1 B-86I-3 + 11-1 B-12 I-3 + 11-1 B-49 I-3 + II-1 B-86
I-3 + II-1 B-13 I-3 + II-1 B-50 I-3 + 11-1 B-87I-3 + II-1 B-13 I-3 + II-1 B-50 I-3 + 11-1 B-87
I-3 + II-1 B-14 I-3 + II-1 B-51 I-3 + II-1 B-88I-3 + II-1 B-14 I-3 + II-1 B-51 I-3 + II-1 B-88
I-3 + 11-1 B-15 I-3 + 11-1 B-52 I-3 + II-2A-1 1-3 + II-2A-2 1-3 + 11-3-25 1-3 + II-4A-4I-3 + 11-1 B-15 I-3 + 11-1 B-52 I-3 + II-2A-1 1-3 + II-2A-2 1-3 + 11-3-25 1-3 + II-4A-4
1-3 + II-2A-3 1-3 + 11-3-26 1-3 + II-4A-51-3 + II-2A-3 1-3 + 11-3-26 1-3 + II-4A-5
1-3 + II-2A-4 1-3 + 11-3-27 1-3 + II-4A-61-3 + II-2A-4 1-3 + 11-3-27 1-3 + II-4A-6
1-3 + II-2A-5 1-3 + 11-3-28 1-3 + II-4A-71-3 + II-2A-5 1-3 + 11-3-28 1-3 + II-4A-7
1-3 + II-2A-6 1-3 + 11-3-29 1-3 + II-4A-81-3 + II-2A-6 1-3 + 11-3-29 1-3 + II-4A-8
1-3 + II-2A-7 1-3 + 11-3-30 1-3 + II-4A-91-3 + II-2A-7 1-3 + 11-3-30 1-3 + II-4A-9
1-3 + II-2A-8 1-3 + 11-3-31 I-3 + II-4A-101-3 + II-2A-8 1-3 + 11-3-31 I-3 + II-4A-10
I-3 + II-2B-1 I-3 + II-3-32 I-3 + II-4A-11I-3 + II-2B-1 I-3 + II-3-32 I-3 + II-4A-11
I-3 + II-2B-2 I-3 + II-3-33 I-3 + II-4B-1I-3 + II-2B-2 I-3 + II-3-33 I-3 + II-4B-1
I-3 + II-2B-3 I-3 + II-3-34 I-3 + II-4B-2I-3 + II-2B-3 I-3 + II-3-34 I-3 + II-4B-2
I-3 + II-2B-4 I-3 + II-3-35 I-3 + II-4B-3I-3 + II-2B-4 I-3 + II-3-35 I-3 + II-4B-3
I-3 + II-2B-5 I-3 + II-3-36 I-3 + II-4B-4I-3 + II-2B-5 I-3 + II-3-36 I-3 + II-4B-4
I-3 + II-2B-6 I-3 + II-3-37 I-3 + II-4C-4I-3 + II-2B-6 I-3 + II-3-37 I-3 + II-4C-4
I-3 + 11-3-1 I-3 + II-3-38 I-3 + 11-5-1I-3 + 11-3-1 I-3 + II-3-38 I-3 + 11-5-1
I-3 + II-3-2 I-3 + II-3-39 I-3 + II-5-2I-3 + II-3-2 I-3 + II-3-39 I-3 + II-5-2
I-3 + II-3-3 I-3 + II-3-40 I-3 + 11-6-1I-3 + II-3-3 I-3 + II-3-40 I-3 + 11-6-1
I-3 + II-3-4 I-3 + 11-3-41 I-3 + II-6-2I-3 + II-3-4 I-3 + 11-3-41 I-3 + II-6-2
I-3 + II-3-5 I-3 + II-3-42 I-3 + II-6-3I-3 + II-3-5 I-3 + II-3-42 I-3 + II-6-3
I-3 + II-3-6 I-3 + II-3-43 I-3 + II-6-4I-3 + II-3-6 I-3 + II-3-43 I-3 + II-6-4
I-3 + II-3-7 I-3 + II-3-44 I-3 + II-6-5I-3 + II-3-7 I-3 + II-3-44 I-3 + II-6-5
I-3 + II-3-8 I-3 + II-3-45 I-3 + II-6-6I-3 + II-3-8 I-3 + II-3-45 I-3 + II-6-6
I-3 + II-3-9 I-3 + II-3-46 I-3 + II-7A-1I-3 + II-3-9 I-3 + II-3-46 I-3 + II-7A-1
I-3 + 11-3-10 I-3 + II-3-47 I-3 + II-7A-2I-3 + 11-3-10 I-3 + II-3-47 I-3 + II-7A-2
I-3 + 11-3-11 I-3 + II-3-48 I-3 + II-7A-3I-3 + 11-3-11 I-3 + II-3-48 I-3 + II-7A-3
I-3 + 11-3-12 I-3 + II-3-49 I-3 + II-7A-4I-3 + 11-3-12 I-3 + II-3-49 I-3 + II-7A-4
I-3 + 11-3-13 I-3 + II-3-50 I-3 + II-7A-5I-3 + 11-3-13 I-3 + II-3-50 I-3 + II-7A-5
I-3 + 11-3-14 I-3 + 11-3-51 I-3 + II-7B-1I-3 + 11-3-14 I-3 + 11-3-51 I-3 + II-7B-1
I-3 + 11-3-15 I-3 + II-3-52 I-3 + II-7C-1I-3 + 11-3-15 I-3 + II-3-52 I-3 + II-7C-1
I-3 + 11-3-16 I-3 + II-3-53 I-3 + II-7C-2I-3 + 11-3-16 I-3 + II-3-53 I-3 + II-7C-2
I-3 + 11-3-17 I-3 + II-3-54 I-3 + II-8A-1I-3 + 11-3-17 I-3 + II-3-54 I-3 + II-8A-1
I-3 + 11-3-18 I-3 + II-3-55 I-3 + II-8B-1I-3 + 11-3-18 I-3 + II-3-55 I-3 + II-8B-1
I-3 + 11-3-19 I-3 + II-3-56 I-3 + II-8C-1I-3 + 11-3-19 I-3 + II-3-56 I-3 + II-8C-1
I-3 + II-3-20 I-3 + II-3-57 I-3 + II-9A-1I-3 + II-3-20 I-3 + II-3-57 I-3 + II-9A-1
I-3 + 11-3-21 I-3 + II-3-58 I-3 + II-9B-1I-3 + 11-3-21 I-3 + II-3-58 I-3 + II-9B-1
I-3 + II-3-22 I-3 + II-4A-1 I-3 + II-9B-2I-3 + II-3-22 I-3 + II-4A-1 I-3 + II-9B-2
I-3 + II-3-23 I-3 + II-4A-2 I-3 + II-9C-1I-3 + II-3-23 I-3 + II-4A-2 I-3 + II-9C-1
I-3 + II-3-24 I-3 + II-4A-3 I-3 + II-10A-1 1-3 + M-10A-2 I-3 + II-20B-1 I-3 + 11-29-17I-3 + II-3-24 I-3 + II-4A-3I-3 + II-10A-1 1-3 + M-10A-2 I-3 + II-20B-1 I-3 + 11-29-17
I-3 + M-10B-1 I-3 + II-20C-1 I-3 + 11-29-18I-3 + M-10B-1 I-3 + II-20C-1 I-3 + 11-29-18
I-3 + 11-12A- 1 I-3 + II-20D-1 I-3 + 11-29-19I-3 + 11-12A-1 I-3 + II-20D-1 I-3 + 11-29-19
I-3 + 11-12B-1 I-3 + II-20D-2 I-3 + II-29-20I-3 + 11-12B-1 I-3 + II-20D-2 I-3 + II-29-20
I-3 + II-12B-2 I-3 + 11-21 -1 I-3 + 11-29-21I-3 + II-12B-2 I-3 + 11-21-1 I-3 + 11-29-21
I-3 + II-12B-3 I-3 + 11-21-2 I-3 + M-29-22I-3 + II-12B-3 I-3 + 11-21-2 I-3 + M-29-22
I-3 + II-12C-1 I-3 + 11-21-3 I-3 + M-29-23I-3 + II-12C-1 I-3 + 11-21-3 I-3 + M-29-23
I-3 + II-12C-2 I-3 + 11-21-4 I-3 + II-29-24I-3 + II-12C-2 I-3 + 11-21-4 I-3 + II-29-24
I-3 + 11-13-1 I-3 + 11-21-5 I-3 + II-29-25I-3 + 11-13-1 I-3 + 11-21-5 I-3 + II-29-25
I-3 + 11-13-2 I-3 + 11-21-6 I-3 + II-29-26I-3 + 11-13-2 I-3 + 11-21-6 I-3 + II-29-26
I-3 + 11-13-3 I-3 + 11-21 -7 I-3 + M-29-27I-3 + 11-13-3 I-3 + 11-21 -7 I-3 + M-29-27
I-3 + 11-13-4 I-3 + II-22A-1 I-3 + II-29-28I-3 + 11-13-4 I-3 + II-22A-1 I-3 + II-29-28
I-3 + 11-13-5 I-3 + II-22B-1 I-3 + II-29-29I-3 + 11-13-5 I-3 + II-22B-1 I-3 + II-29-29
I-3 + 11-13-6 I-3 + II-23A-1 I-3 + II-29-30I-3 + 11-13-6 I-3 + II-23A-1 I-3 + II-29-30
I-3 + 11-15-1 I-3 + II-23A-2 I-3 + 11-29-31I-3 + 11-15-1 I-3 + II-23A-2 I-3 + 11-29-31
I-3 + 11-15-2 I-3 + II-23B-1 I-3 + 11-30-1I-3 + 11-15-2 I-3 + II-23B-1 I-3 + 11-30-1
I-3 + 11-15-3 I-3 + 11-25-1 I-4 + II-1A-1I-3 + 11-15-3 I-3 + 11-25-1 I-4 + II-1A-1
I-3 + 11-15-4 I-3 + 11-28-1 I-4 + 11-1 A-2I-3 + 11-15-4 I-3 + 11-28-1 I-4 + 11-1 A-2
I-3 + 11-15-5 I-3 + II-28-2 I-4 + II-1A-3I-3 + 11-15-5 I-3 + II-28-2 I-4 + II-1A-3
I-3 + 11-15-6 I-3 + II-28-3 I-4 + II-1A-4I-3 + 11-15-6 I-3 + II-28-3 I-4 + II-1A-4
I-3 + 11-15-7 I-3 + II-28-4 I-4 + II-1A-5I-3 + 11-15-7 I-3 + II-28-4 I-4 + II-1A-5
I-3 + 11-15-8 I-3 + 11-29-1 I-4 + 11-1 A-6I-3 + 11-15-8 I-3 + 11-29-1 I-4 + 11-1 A-6
I-3 + 11-15-9 I-3 + II-29-2 I-4 + II-1A-7I-3 + 11-15-9 I-3 + II-29-2 I-4 + II-1A-7
I-3 + 11-15-10 I-3 + II-29-3 I-4 + II-1A-8I-3 + 11-15-10 I-3 + II-29-3 I-4 + II-1A-8
I-3 + 11-15-1 1 I-3 + II-29-4 I-4 + II-1A-9I-3 + 11-15-1 1 I-3 + II-29-4 I-4 + II-1A-9
I-3 + 11-15-12 I-3 + II-29-5 I-4 + II-1A-10I-3 + 11-15-12 I-3 + II-29-5 I-4 + II-1A-10
I-3 + 11-15-13 I-3 + II-29-6 I-4 + 11-1 A-1 1I-3 + 11-15-13 I-3 + II-29-6 I-4 + 11-1 A-1 1
I-3 + 11-16-1 I-3 + II-29-7 I-4 + II-1A-12I-3 + 11-16-1 I-3 + II-29-7 I-4 + II-1A-12
I-3 + 11-17-1 I-3 + II-29-8 I-4 + II-1A-13I-3 + 11-17-1 I-3 + II-29-8 I-4 + II-1A-13
I-3 + II-18A-1 I-3 + II-29-9 I-4 + II-1A-14I-3 + II-18A-1 I-3 + II-29-9 I-4 + II-1A-14
I-3 + II-18A-2 I-3 + 11-29-10 I-4 + II-1A-15I-3 + II-18A-2 I-3 + 11-29-10 I-4 + II-1A-15
I-3 + II-18A-3 I-3 + 11-29-1 1 I-4 + II-1A-16I-3 + II-18A-3 I-3 + 11-29-1 1 I-4 + II-1A-16
I-3 + 11-18A-4 I-3 + 11-29-12 I-4 + II-1A-17I-3 + 11-18A-4 I-3 + 11-29-12 I-4 + II-1A-17
I-3 + 11-18A-5 I-3 + 11-29-13 I-4 + 11-1 A-18I-3 + 11-18A-5 I-3 + 11-29-13 I-4 + 11-1 A-18
I-3 + II-18B-1 I-3 + 11-29-14 I-4 + II-1A-19I-3 + II-18B-1 I-3 + 11-29-14 I-4 + II-1A-19
I-3 + 11-19-1 I-3 + 11-29-15 I-4 + II-1A-20I-3 + 11-19-1 I-3 + 11-29-15 I-4 + II-1A-20
I-3 + II-20A-1 I-3 + 11-29-16 I-4 + II-1A-21 1-4 + II-1A-22 I-4 + 11-1 B-24 I-4 + 11-1 B-61I-3 + II-20A-1 I-3 + 11-29-16 I-4 + II-1A-21 1-4 + II-1A-22 I-4 + 11-1 B-24 I-4 + 11-1 B-61
I-4 + M-1A-23 I-4 + 11-1 B-25 I-4 + 11-1 B-62I-4 + M-1A-23 I-4 + 11-1 B-25 I-4 + 11-1 B-62
I-4 + II-1A-24 I-4 + 11-1 B-26 I-4 + II-1 B-63I-4 + II-1A-24 I-4 + 11-1 B-26 I-4 + II-1 B-63
I-4 + 11-1 A-25 I-4 + 11-1 B-27 I-4 + 11-1 B-64I-4 + 11-1 A-25 I-4 + 11-1 B-27 I-4 + 11-1 B-64
I-4 + II-1A-26 I-4 + 11-1 B-28 I-4 + 11-1 B-65I-4 + II-1A-26 I-4 + 11-1 B-28 I-4 + 11-1 B-65
I-4 + II-1A-27 I-4 + 11-1 B-29 I-4 + II-1 B-66I-4 + II-1A-27 I-4 + 11-1 B-29 I-4 + II-1 B-66
I-4 + II-1A-28 I-4 + 11-1 B-30 I-4 + II-1 B-67I-4 + II-1A-28 I-4 + 11-1 B-30 I-4 + II-1 B-67
I-4 + 11-1 A-29 I-4 + 11-1 B-31 I-4 + II-1 B-68I-4 + 11-1 A-29 I-4 + 11-1 B-31 I-4 + II-1 B-68
I-4 + 11-1 A-30 I-4 + II-1 B-32 I-4 + 11-1 B-69I-4 + 11-1 A-30 I-4 + II-1 B-32 I-4 + 11-1 B-69
I-4 + 11-1 A-31 I-4 + 11-1 B-33 I-4 + 11-1 B-70I-4 + 11-1 A-31 I-4 + 11-1 B-33 I-4 + 11-1 B-70
I-4 + 11-1 A-32 I-4 + 11-1 B-34 I-4 + 11-1 B-71I-4 + 11-1 A-32 I-4 + 11-1 B-34 I-4 + 11-1 B-71
I-4 + II-1A-33 I-4 + 11-1 B-35 I-4 + 11-1 B-72I-4 + II-1A-33 I-4 + 11-1 B-35 I-4 + 11-1 B-72
I-4 + II-1A-34 I-4 + 11-1 B-36 I-4 + 11-1 B-73I-4 + II-1A-34 I-4 + 11-1 B-36 I-4 + 11-1 B-73
I-4 + II-1A-35 I-4 + 11-1 B-37 I-4 + 11-1 B-74I-4 + II-1A-35 I-4 + 11-1 B-37 I-4 + 11-1 B-74
I-4 + 11-1 B- 1 I-4 + 11-1 B-38 I-4 + 11-1 B-75I-4 + 11-1 B-1 I-4 + 11-1 B-38 I-4 + 11-1 B-75
I-4 + 11-1 B-2 I-4 + 11-1 B-39 I-4 + 11-1 B-76I-4 + 11-1 B-2 I-4 + 11-1 B-39 I-4 + 11-1 B-76
I-4 + 11-1 B-3 I-4 + 11-1 B-40 I-4 + 11-1 B-77I-4 + 11-1 B-3 I-4 + 11-1 B-40 I-4 + 11-1 B-77
|-4 + ||-1 B-4 I-4 + 11-1 B-41 I-4 + 11-1 B-78| -4 + || -1 B-4 I-4 + 11-1 B-41 I-4 + 11-1 B-78
I-4 + 11-1 B-5 I-4 + 11-1 B-42 I-4 + 11-1 B-79I-4 + 11-1 B-5 I-4 + 11-1 B-42 I-4 + 11-1 B-79
I-4 + 11-1 B-6 I-4 + 11-1 B-43 I-4 + 11-1 B-80I-4 + 11-1 B-6 I-4 + 11-1 B-43 I-4 + 11-1 B-80
I-4 + 11-1 B-7 I-4 + 11-1 B-44 I-4 + 11-1 B-81I-4 + 11-1 B-7 I-4 + 11-1 B-44 I-4 + 11-1 B-81
I-4 + 11-1 B-8 I-4 + 11-1 B-45 I-4 + II-1 B-82I-4 + 11-1 B-8 I-4 + 11-1 B-45 I-4 + II-1 B-82
I-4 + 11-1 B-9 I-4 + 11-1 B-46 I-4 + 11-1 B-83I-4 + 11-1 B-9 I-4 + 11-1 B-46 I-4 + 11-1 B-83
I-4 + 11-1 B-10 I-4 + 11-1 B-47 I-4 + 11-1 B-84I-4 + 11-1 B-10 I-4 + 11-1 B-47 I-4 + 11-1 B-84
I-4 + 11-1 B-11 I-4 + 11-1 B-48 I-4 + 11-1 B-85I-4 + 11-1 B-11 I-4 + 11-1 B-48 I-4 + 11-1 B-85
I-4 + 11-1 B-12 I-4 + 11-1 B-49 I-4 + 11-1 B-86I-4 + 11-1 B-12 I-4 + 11-1 B-49 I-4 + 11-1 B-86
I-4 + 11-1 B-13 I-4 + 11-1 B-50 I-4 + II-1 B-87I-4 + 11-1 B-13 I-4 + 11-1 B-50 I-4 + II-1 B-87
I-4 + 11-1 B-14 I-4 + 11-1 B-51 I-4 + 11-1 B-88I-4 + 11-1 B-14 I-4 + 11-1 B-51 I-4 + 11-1 B-88
I-4 + 11-1 B-15 I-4 + 11-1 B-52 I-4 + II-2A-1I-4 + 11-1 B-15 I-4 + 11-1 B-52 I-4 + II-2A-1
I-4 + 11-1 B-16 I-4 + 11-1 B-53 I-4 + II-2A-2I-4 + 11-1 B-16 I-4 + 11-1 B-53 I-4 + II-2A-2
I-4 + 11-1 B-17 I-4 + 11-1 B-54 I-4 + II-2A-3I-4 + 11-1 B-17 I-4 + 11-1 B-54 I-4 + II-2A-3
I-4 + 11-1 B-18 I-4 + 11-1 B-55 I-4 + II-2A-4I-4 + 11-1 B-18 I-4 + 11-1 B-55 I-4 + II-2A-4
I-4 + 11-1 B-19 I-4 + 11-1 B-56 I-4 + II-2A-5I-4 + 11-1 B-19 I-4 + 11-1 B-56 I-4 + II-2A-5
I-4 + 11-1 B-20 I-4 + 11-1 B-57 I-4 + II-2A-6I-4 + 11-1 B-20 I-4 + 11-1 B-57 I-4 + II-2A-6
I-4 + 11-1 B-21 I-4 + 11-1 B-58 I-4 + II-2A-7I-4 + 11-1 B-21 I-4 + 11-1 B-58 I-4 + II-2A-7
I-4 + 11-1 B-22 I-4 + 11-1 B-59 I-4 + II-2A-8I-4 + 11-1 B-22 I-4 + 11-1 B-59 I-4 + II-2A-8
I-4 + 11-1 B-23 I-4 + 11-1 B-60 I-4 + II-2B-1 1-4 + II-2B-2 1-4 + 11-3-33 1-4 + II-4B-1I-4 + 11-1 B-23 I-4 + 11-1 B-60 I-4 + II-2B-1 1-4 + II-2B-2 1-4 + 11-3-33 1-4 + II-4B-1
I-4 + II-2B-3 I-4 + II-3-34 I-4 + II-4B-2I-4 + II-2B-3 I-4 + II-3-34 I-4 + II-4B-2
I-4 + II-2B-4 I-4 + II-3-35 I-4 + II-4B-3I-4 + II-2B-4 I-4 + II-3-35 I-4 + II-4B-3
I-4 + II-2B-5 I-4 + II-3-36 I-4 + II-4B-4I-4 + II-2B-5 I-4 + II-3-36 I-4 + II-4B-4
I-4 + II-2B-6 I-4 + II-3-37 I-4 + II-4C-4I-4 + II-2B-6 I-4 + II-3-37 I-4 + II-4C-4
I-4 + 11-3-1 I-4 + II-3-38 I-4 + 11-5-1I-4 + 11-3-1 I-4 + II-3-38 I-4 + 11-5-1
I-4 + II-3-2 I-4 + II-3-39 I-4 + II-5-2I-4 + II-3-2 I-4 + II-3-39 I-4 + II-5-2
I-4 + II-3-3 I-4 + II-3-40 I-4 + 11-6-1I-4 + II-3-3 I-4 + II-3-40 I-4 + 11-6-1
I-4 + II-3-4 I-4 + 11-3-41 I-4 + II-6-2I-4 + II-3-4 I-4 + 11-3-41 I-4 + II-6-2
I-4 + II-3-5 I-4 + II-3-42 I-4 + II-6-3I-4 + II-3-5 I-4 + II-3-42 I-4 + II-6-3
I-4 + II-3-6 I-4 + II-3-43 I-4 + II-6-4I-4 + II-3-6 I-4 + II-3-43 I-4 + II-6-4
I-4 + II-3-7 I-4 + II-3-44 I-4 + II-6-5I-4 + II-3-7 I-4 + II-3-44 I-4 + II-6-5
I-4 + II-3-8 I-4 + II-3-45 I-4 + II-6-6I-4 + II-3-8 I-4 + II-3-45 I-4 + II-6-6
I-4 + II-3-9 I-4 + II-3-46 I-4 + II-7A-1I-4 + II-3-9 I-4 + II-3-46 I-4 + II-7A-1
I-4 + 11-3-10 I-4 + II-3-47 I-4 + II-7A-2I-4 + 11-3-10 I-4 + II-3-47 I-4 + II-7A-2
I-4 + 11-3-11 I-4 + II-3-48 I-4 + II-7A-3I-4 + 11-3-11 I-4 + II-3-48 I-4 + II-7A-3
I-4 + 11-3-12 I-4 + II-3-49 I-4 + II-7A-4I-4 + 11-3-12 I-4 + II-3-49 I-4 + II-7A-4
I-4 + 11-3-13 I-4 + II-3-50 I-4 + II-7A-5I-4 + 11-3-13 I-4 + II-3-50 I-4 + II-7A-5
I-4 + H-3-14 |-4 + H-3-51 |-4 + II-7B-1I-4 + H-3-14 | -4 + H-3-51 | -4 + II-7B-1
I-4 + 11-3-15 I-4 + II-3-52 I-4 + II-7C-1I-4 + 11-3-15 I-4 + II-3-52 I-4 + II-7C-1
I-4 + 11-3-16 I-4 + II-3-53 I-4 + II-7C-2I-4 + 11-3-16 I-4 + II-3-53 I-4 + II-7C-2
I-4 + 11-3-17 I-4 + II-3-54 I-4 + II-8A-1I-4 + 11-3-17 I-4 + II-3-54 I-4 + II-8A-1
I-4 + 11-3-18 I-4 + II-3-55 I-4 + II-8B-1I-4 + 11-3-18 I-4 + II-3-55 I-4 + II-8B-1
I-4 + 11-3-19 I-4 + II-3-56 I-4 + II-8C-1I-4 + 11-3-19 I-4 + II-3-56 I-4 + II-8C-1
I-4 + II-3-20 I-4 + II-3-57 I-4 + II-9A-1I-4 + II-3-20 I-4 + II-3-57 I-4 + II-9A-1
I-4 + 11-3-21 I-4 + II-3-58 I-4 + II-9B-1I-4 + 11-3-21 I-4 + II-3-58 I-4 + II-9B-1
I-4 + II-3-22 I-4 + II-4A-1 I-4 + II-9B-2I-4 + II-3-22 I-4 + II-4A-1 I-4 + II-9B-2
I-4 + II-3-23 I-4 + II-4A-2 I-4 + II-9C-1I-4 + II-3-23 I-4 + II-4A-2 I-4 + II-9C-1
I-4 + II-3-24 I-4 + II-4A-3 I-4 + II-10A-1I-4 + II-3-24 I-4 + II-4A-3 I-4 + II-10A-1
I-4 + II-3-25 I-4 + II-4A-4 I-4 + II-10A-2I-4 + II-3-25 I-4 + II-4A-4 I-4 + II-10A-2
I-4 + II-3-26 I-4 + II-4A-5 I-4 + II-10B-1I-4 + II-3-26 I-4 + II-4A-5 I-4 + II-10B-1
I-4 + II-3-27 I-4 + II-4A-6 I-4 + II-12A-1I-4 + II-3-27 I-4 + II-4A-6 I-4 + II-12A-1
I-4 + II-3-28 I-4 + II-4A-7 I-4 + II-12B-1I-4 + II-3-28 I-4 + II-4A-7 I-4 + II-12B-1
I-4 + II-3-29 I-4 + II-4A-8 I-4 + II-12B-2I-4 + II-3-29 I-4 + II-4A-8 I-4 + II-12B-2
I-4 + II-3-30 I-4 + II-4A-9 I-4 + II-12B-3I-4 + II-3-30 I-4 + II-4A-9 I-4 + II-12B-3
I-4 + 11-3-31 I-4 + II-4A-10 I-4 + II-12C-1I-4 + 11-3-31 I-4 + II-4A-10 I-4 + II-12C-1
I-4 + II-3-32 I-4 + II-4A-11 I-4 + 11-12C-2 -4 + I 1-13-1 I-4 + 11-21-5 I-4 + II-29-25-4 + I 1-13-2 I-4 + 11-21-6 I-4 + M-29-26-4 + I 1-13-3 I-4 + 11-21-7 I-4 + II-29-27-4 + I 1-13-4 I-4 + II-22A-1 I-4 + II-29-28-4 + I 1-13-5 I-4 + II-22B-1 I-4 + H-29-29-4 + I 1-13-6 I-4 + II-23A-1 I-4 + II-29-30-4 + I 1-15-1 I-4 + II-23A-2 I-4 + 11-29-31-4 + I 1-15-2 I-4 + II-23B-1 I-4 + 11-30-1-4 + I 1-15-3 I-4 + 11-25-1 I-5 + II-1A-1-4 + I 1-15-4 I-4 + 11-28-1 I-5 + II-1A-2-4 + I 1-15-5 I-4 + II-28-2 I-5 + II-1A-3-4 + I 1-15-6 I-4 + II-28-3 I-5 + II-1A-4-4 + I 1-15-7 I-4 + II-28-4 I-5 + II-1A-5-4 + I 1-15-8 I-4 + 11-29-1 I-5 + II-1A-6-4 + I 1-15-9 I-4 + II-29-2 I-5 + II-1A-7-4 + I 1-15-10 I-4 + II-29-3 I-5 + II-1A-8-4 + I 1-15-1 1 I-4 + II-29-4 I-5 + II-1A-9-4 + I 1-15-12 I-4 + II-29-5 I-5 + II-1A-10-4 + I 1-15-13 I-4 + II-29-6 I-5 + 11-1 A-11-4 + I 1-16-1 I-4 + II-29-7 I-5 + II-1A-12-4 + I 1-17-1 I-4 + II-29-8 I-5 + II-1A-13-4 + I 1-18A- 1 I-4 + II-29-9 I-5 + II-1A-14-4 + I I-18A-2 I-4 + 11-29-10 I-5 + II-1A-15-4 + I I-18A-3 I-4 + 11-29-1 1 I-5 + II-1A-16-4 + I I-18A-4 I-4 + 11-29-12 I-5 + II-1A-17-4 + I I-18A-5 I-4 + 11-29-13 I-5 + II-1A-18-4 + I I-18B-1 I-4 + 11-29-14 I-5 + II-1A-19-4 + I 1-19-1 I-4 + 11-29-15 I-5 + II-1A-20-4 + I I-20A-1 I-4 + 11-29-16 I-5 + II-1A-21-4 + I I-20B-1 I-4 + 11-29-17 I-5 + M-1A-22-4 + I I-20C-1 I-4 + 11-29-18 I-5 + II-1A-23-4 + I I-20D-1 I-4 + 11-29-19 I-5 + M-1A-24-4 + I I-20D-2 I-4 + II-29-20 I-5 + II-1A-25-4 + I 1-21 -1 I-4 + 11-29-21 I-5 + II-1A-26-4 + I 1-21 -2 I-4 + M-29-22 I-5 + II-1A-27-4 + I 1-21 -3 I-4 + II-29-23 I-5 + II-1A-28-4 + I 1-21 -4 I-4 + II-29-24 I-5 + II-1A-29 1-5 + II-1A-30 I-5 + 11-1 B-32 I-5 + 11-1 B-69I-4 + II-3-32 I-4 + II-4A-11 I-4 + 11-12C-2 -4 + I 1-13-1 I-4 + 11-21-5 I-4 + II-29-25-4 + I 1-13-2 I-4 + 11-21-6 I-4 + M -29-26-4 + I 1-13-3 I-4 + 11-21-7 I-4 + II-29-27-4 + I 1-13-4 I-4 + II-22A-1 I -4 + II-29-28-4 + I 1-13-5 I-4 + II-22B-1 I-4 + H-29-29-4 + I 1-13-6 I-4 + II- 23A-1I-4 + II-29-30-4 + I 1-15-1I-4 + II-23A-2I-4 + 11-29-31-4 + I 1-15-2I- 4 + II-23B-1 I-4 + 11-30-1-4 + I 1-15-3 I-4 + 11-25-1 I-5 + II-1A-1-4 + I 1-15 -4 I-4 + 11-28-1 I-5 + II-1A-2-4 + I 1-15-5 I-4 + II-28-2 I-5 + II-1A-3-4 + I 1-15-6 I-4 + II-28-3 I-5 + II-1A-4-4 + I 1-15-7 I-4 + II-28-4 I-5 + II-1A- 5-4 + I 1-15-8 I-4 + 11-29-1 I-5 + II-1A-6-4 + I 1-15-9 I-4 + II-29-2 I-5 + II-1A-7-4 + I 1-15-10 I-4 + II-29-3 I-5 + II-1A-8-4 + I 1-15-1 1 I-4 + II-29- 4 I-5 + II-1A-9-4 + I 1-15-12 I-4 + II-29-5 I-5 + II-1A-10-4 + I 1-15-13 I-4 + II-29-6 I-5 + 11-1 A-11-4 + I 1-16-1 I-4 + II-29-7 I-5 + II-1A-12-4 + I 1-17- 1 I-4 + II-29-8 I-5 + II-1A-13-4 + I 1-18A- 1 I-4 + II-29-9 I-5 + II-1A-14-4 + I I-18A-2 I-4 + 11-29-10 I-5 + II-1A-15-4 + I I-18A-3 I-4 + 11-29-1 1 I-5 + II-1A-16-4 + I I-18A-4 I-4 + 11-29-12 I-5 + II-1A-17-4 + I I-18A-5 I-4 + 11 -29-13 I-5 + II-1A-18-4 + I I-18B-1 I-4 + 11-29-14 I-5 + II-1A-19-4 + I 1-19-1 I -4 + 11-29-15 I-5 + II-1A-20-4 + I I-20A-1 I-4 + 11-29-16 I-5 + II-1A-21-4 + I- 20B-1 I-4 + 11-29-17 I-5 + M-1A-22-4 + I I-20C-1 I-4 + 11-29-18 I-5 + II-1A-23-4 I-20D-1 I-4 + 11-29-19 I-5 + M-1A-24-4 + I I-20D-2 I-4 + II-29-20 I-5 + II-1A -25-4 + I 1-21 -1 I-4 + 11-29-21 I-5 + II-1A-26-4 + I 1-21 -2 I-4 + M-29-22 I-5 + II-1A-27-4 + I 1-21-3 I-4 + II-29-23 I-5 + II-1A-28-4 + I 1-21 -4 I-4 + II-29- 24 I-5 + II-1A-29 1-5 + II-1A-30 I-5 + 11-1 B-32 I-5 + 11-1 B-69
I-5 + 11-1 A-31 I-5 + II-1 B-33 I-5 + 11-1 B-70I-5 + 11-1 A-31 I-5 + II-1 B-33 I-5 + 11-1 B-70
I-5 + II-1A-32 I-5 + 11-1 B-34 I-5 + 11-1 B-71I-5 + II-1A-32 I-5 + 11-1 B-34 I-5 + 11-1 B-71
I-5 + 11-1 A-33 I-5 + 11-1 B-35 I-5 + 11-1 B-72I-5 + 11-1 A-33 I-5 + 11-1 B-35 I-5 + 11-1 B-72
I-5 + 11-1 A-34 I-5 + 11-1 B-36 I-5 + II-1 B-73I-5 + 11-1 A-34 I-5 + 11-1 B-36 I-5 + II-1 B-73
I-5 + 11-1 A-35 I-5 + 11-1 B-37 I-5 + 11-1 B-74I-5 + 11-1 A-35 I-5 + 11-1 B-37 I-5 + 11-1 B-74
I-5 + 11-1 B- 1 I-5 + 11-1 B-38 I-5 + 11-1 B-75I-5 + 11-1 B-1 I-5 + 11-1 B-38 I-5 + 11-1 B-75
I-5 + 11-1 B-2 I-5 + 11-1 B-39 I-5 + 11-1 B-76I-5 + 11-1 B-2 I-5 + 11-1 B-39 I-5 + 11-1 B-76
I-5 + 11-1 B-3 I-5 + 11-1 B-40 I-5 + 11-1 B-77I-5 + 11-1 B-3 I-5 + 11-1 B-40 I-5 + 11-1 B-77
I-5 + 11-1 B-4 I-5 + 11-1 B-41 I-5 + II-1 B-78I-5 + 11-1 B-4 I-5 + 11-1 B-41 I-5 + II-1 B-78
I-5 + 11-1 B-5 I-5 + 11-1 B-42 I-5 + 11-1 B-79I-5 + 11-1 B-5 I-5 + 11-1 B-42 I-5 + 11-1 B-79
I-5 + 11-1 B-6 I-5 + 11-1 B-43 I-5 + 11-1 B-80I-5 + 11-1 B-6 I-5 + 11-1 B-43 I-5 + 11-1 B-80
I-5 + 11-1 B-7 I-5 + 11-1 B-44 I-5 + 11-1 B-81I-5 + 11-1 B-7 I-5 + 11-1 B-44 I-5 + 11-1 B-81
I-5 + II-1 B-8 I-5 + 11-1 B-45 I-5 + 11-1 B-82I-5 + II-1 B-8 I-5 + 11-1 B-45 I-5 + 11-1 B-82
I-5 + 11-1 B-9 I-5 + 11-1 B-46 I-5 + 11-1 B-83I-5 + 11-1 B-9 I-5 + 11-1 B-46 I-5 + 11-1 B-83
I-5 + 11-1 B-10 I-5 + II-1 B-47 I-5 + 11-1 B-84I-5 + 11-1 B-10 I-5 + II-1 B-47 I-5 + 11-1 B-84
I-5 + 11-1 B-11 I-5 + 11-1 B-48 I-5 + 11-1 B-85I-5 + 11-1 B-11 I-5 + 11-1 B-48 I-5 + 11-1 B-85
I-5 + 11-1 B-12 I-5 + II-1 B-49 I-5 + 11-1 B-86I-5 + 11-1 B-12 I-5 + II-1 B-49 I-5 + 11-1 B-86
I-5 + 11-1 B-13 I-5 + 11-1 B-50 I-5 + 11-1 B-87I-5 + 11-1 B-13 I-5 + 11-1 B-50 I-5 + 11-1 B-87
I-5 + II-1 B-14 I-5 + II-1 B-51 I-5 + II-1 B-88I-5 + II-1 B-14 I-5 + II-1 B-51 I-5 + II-1 B-88
I-5 + 11-1 B-15 I-5 + 11-1 B-52 I-5 + II-2A-1I-5 + 11-1 B-15 I-5 + 11-1 B-52 I-5 + II-2A-1
I-5 + 11-1 B-16 I-5 + 11-1 B-53 I-5 + II-2A-2I-5 + 11-1 B-16 I-5 + 11-1 B-53 I-5 + II-2A-2
I-5 + II-1 B-17 I-5 + II-1 B-54 I-5 + II-2A-3I-5 + II-1 B-17 I-5 + II-1 B-54 I-5 + II-2A-3
I-5 + 11-1 B-18 I-5 + 11-1 B-55 I-5 + II-2A-4I-5 + 11-1 B-18 I-5 + 11-1 B-55 I-5 + II-2A-4
I-5 + 11-1 B-19 I-5 + 11-1 B-56 I-5 + II-2A-5I-5 + 11-1 B-19 I-5 + 11-1 B-56 I-5 + II-2A-5
I-5 + 11-1 B-20 I-5 + II-1 B-57 I-5 + II-2A-6I-5 + 11-1 B-20 I-5 + II-1 B-57 I-5 + II-2A-6
I-5 + 11-1 B-21 I-5 + 11-1 B-58 I-5 + II-2A-7I-5 + 11-1 B-21 I-5 + 11-1 B-58 I-5 + II-2A-7
I-5 + II-1 B-22 I-5 + 11-1 B-59 I-5 + II-2A-8I-5 + II-1 B-22 I-5 + 11-1 B-59 I-5 + II-2A-8
I-5 + 11-1 B-23 I-5 + 11-1 B-60 I-5 + II-2B-1I-5 + 11-1 B-23 I-5 + 11-1 B-60 I-5 + II-2B-1
I-5 + 11-1 B-24 I-5 + 11-1 B-61 I-5 + II-2B-2I-5 + 11-1 B-24 I-5 + 11-1 B-61 I-5 + II-2B-2
I-5 + 11-1 B-25 I-5 + 11-1 B-62 I-5 + II-2B-3I-5 + 11-1 B-25 I-5 + 11-1 B-62 I-5 + II-2B-3
I-5 + 11-1 B-26 I-5 + II-1 B-63 I-5 + II-2B-4I-5 + 11-1 B-26 I-5 + II-1 B-63 I-5 + II-2B-4
I-5 + 11-1 B-27 I-5 + 11-1 B-64 I-5 + II-2B-5I-5 + 11-1 B-27 I-5 + 11-1 B-64 I-5 + II-2B-5
I-5 + 11-1 B-28 I-5 + II-1 B-65 I-5 + II-2B-6I-5 + 11-1 B-28 I-5 + II-1 B-65 I-5 + II-2B-6
I-5 + 11-1 B-29 I-5 + 11-1 B-66 I-5 + 11-3-1I-5 + 11-1 B-29 I-5 + 11-1 B-66 I-5 + 11-3-1
I-5 + 11-1 B-30 I-5 + 11-1 B-67 I-5 + II-3-2I-5 + 11-1 B-30 I-5 + 11-1 B-67 I-5 + II-3-2
I-5 + 11-1 B-31 I-5 + II-1 B-68 I-5 + II-3-3 1-5 + 11-3-4 1-5 + 11-3-41 I-5 + II-6-2I-5 + 11-1 B-31 I-5 + II-1 B-68 I-5 + II-3-3 1-5 + 11-3-4 1-5 + 11-3-41 I-5 + II-6-2
I-5 + II-3-5 I-5 + II-3-42 I-5 + II-6-3I-5 + II-3-5 I-5 + II-3-42 I-5 + II-6-3
I-5 + II-3-6 I-5 + II-3-43 I-5 + II-6-4I-5 + II-3-6 I-5 + II-3-43 I-5 + II-6-4
I-5 + II-3-7 I-5 + II-3-44 I-5 + II-6-5I-5 + II-3-7 I-5 + II-3-44 I-5 + II-6-5
I-5 + II-3-8 I-5 + II-3-45 I-5 + II-6-6I-5 + II-3-8 I-5 + II-3-45 I-5 + II-6-6
I-5 + II-3-9 I-5 + II-3-46 I-5 + II-7A-1I-5 + II-3-9 I-5 + II-3-46 I-5 + II-7A-1
I-5 + 11-3-10 I-5 + II-3-47 I-5 + II-7A-2I-5 + 11-3-10 I-5 + II-3-47 I-5 + II-7A-2
I-5 + 11-3-11 I-5 + II-3-48 I-5 + II-7A-3I-5 + 11-3-11 I-5 + II-3-48 I-5 + II-7A-3
I-5 + 11-3-12 I-5 + II-3-49 I-5 + II-7A-4I-5 + 11-3-12 I-5 + II-3-49 I-5 + II-7A-4
I-5 + 11-3-13 I-5 + II-3-50 I-5 + II-7A-5I-5 + 11-3-13 I-5 + II-3-50 I-5 + II-7A-5
I-5 + 11-3-14 I-5 + 11-3-51 I-5 + II-7B-1I-5 + 11-3-14 I-5 + 11-3-51 I-5 + II-7B-1
I-5 + 11-3-15 I-5 + II-3-52 I-5 + II-7C-1I-5 + 11-3-15 I-5 + II-3-52 I-5 + II-7C-1
I-5 + 11-3-16 I-5 + II-3-53 I-5 + II-7C-2I-5 + 11-3-16 I-5 + II-3-53 I-5 + II-7C-2
I-5 + 11-3-17 I-5 + II-3-54 I-5 + II-8A-1I-5 + 11-3-17 I-5 + II-3-54 I-5 + II-8A-1
I-5 + 11-3-18 I-5 + II-3-55 I-5 + II-8B-1I-5 + 11-3-18 I-5 + II-3-55 I-5 + II-8B-1
I-5 + 11-3-19 I-5 + II-3-56 I-5 + II-8C-1I-5 + 11-3-19 I-5 + II-3-56 I-5 + II-8C-1
I-5 + II-3-20 I-5 + II-3-57 I-5 + II-9A-1I-5 + II-3-20 I-5 + II-3-57 I-5 + II-9A-1
I-5 + 11-3-21 I-5 + II-3-58 I-5 + II-9B-1I-5 + 11-3-21 I-5 + II-3-58 I-5 + II-9B-1
I-5 + II-3-22 I-5 + II-4A-1 I-5 + II-9B-2I-5 + II-3-22 I-5 + II-4A-1 I-5 + II-9B-2
I-5 + II-3-23 I-5 + II-4A-2 I-5 + II-9C-1I-5 + II-3-23 I-5 + II-4A-2 I-5 + II-9C-1
I-5 + II-3-24 I-5 + II-4A-3 I-5 + II-10A-1I-5 + II-3-24 I-5 + II-4A-3 I-5 + II-10A-1
I-5 + II-3-25 I-5 + II-4A-4 I-5 + 11-1 OA-2I-5 + II-3-25 I-5 + II-4A-4 I-5 + 11-1 OA-2
I-5 + II-3-26 I-5 + II-4A-5 I-5 + 11-10B-1I-5 + II-3-26 I-5 + II-4A-5 I-5 + 11-10B-1
I-5 + II-3-27 I-5 + II-4A-6 I-5 + 11-12A- 1I-5 + II-3-27 I-5 + II-4A-6 I-5 + 11-12A-1
I-5 + II-3-28 I-5 + II-4A-7 I-5 + 11-12B- 1I-5 + II-3-28 I-5 + II-4A-7 I-5 + 11-12B-1
I-5 + II-3-29 I-5 + II-4A-8 I-5 + 11-12B-2I-5 + II-3-29 I-5 + II-4A-8 I-5 + 11-12B-2
I-5 + II-3-30 I-5 + II-4A-9 I-5 + 11-12B-3I-5 + II-3-30 I-5 + II-4A-9 I-5 + 11-12B-3
I-5 + 11-3-31 I-5 + II-4A-10 I-5 + 11-12C- 1I-5 + 11-3-31 I-5 + II-4A-10 I-5 + 11-12C-1
I-5 + II-3-32 I-5 + II-4A-11 I-5 + 11-12C-2I-5 + II-3-32 I-5 + II-4A-11 I-5 + 11-12C-2
I-5 + II-3-33 I-5 + II-4B-1 I-5 + 11-13-1I-5 + II-3-33 I-5 + II-4B-1 I-5 + 11-13-1
I-5 + II-3-34 I-5 + II-4B-2 I-5 + 11-13-2I-5 + II-3-34 I-5 + II-4B-2 I-5 + 11-13-2
I-5 + II-3-35 I-5 + II-4B-3 I-5 + 11-13-3I-5 + II-3-35 I-5 + II-4B-3 I-5 + 11-13-3
I-5 + II-3-36 I-5 + II-4B-4 I-5 + 11-13-4I-5 + II-3-36 I-5 + II-4B-4 I-5 + 11-13-4
I-5 + 11-3-37 1-5 + II-4C-4 1-5 + 11-13-5I-5 + 11-3-37 1-5 + II-4C-4 1-5 + 11-13-5
I-5 + II-3-38 I-5 + 11-5-1 I-5 + 11-13-6I-5 + II-3-38 I-5 + 11-5-1 I-5 + 11-13-6
I-5 + II-3-39 I-5 + II-5-2 I-5 + 11-15-1I-5 + II-3-39 I-5 + II-5-2 I-5 + 11-15-1
I-5 + II-3-40 I-5 + 11-6-1 I-5 + 11-15-2 1-5 + 11-15-3 I-5 + 11-25-1 I-6 + II-1A-1I-5 + II-3-40 I-5 + 11-6-1 I-5 + 11-15-2 1-5 + 11-15-3 I-5 + 11-25-1 I-6 + II-1A-1
I-5 + 11-15-4 I-5 + 11-28-1 I-6 + II-1A-2I-5 + 11-15-4 I-5 + 11-28-1 I-6 + II-1A-2
I-5 + 11-15-5 I-5 + II-28-2 I-6 + II-1A-3I-5 + 11-15-5 I-5 + II-28-2 I-6 + II-1A-3
I-5 + 11-15-6 I-5 + II-28-3 I-6 + 11-1 A-4I-5 + 11-15-6 I-5 + II-28-3 I-6 + 11-1 A-4
I-5 + 11-15-7 I-5 + II-28-4 I-6 + II-1A-5I-5 + 11-15-7 I-5 + II-28-4 I-6 + II-1A-5
I-5 + 11-15-8 I-5 + 11-29-1 I-6 + 11-1 A-6I-5 + 11-15-8 I-5 + 11-29-1 I-6 + 11-1 A-6
I-5 + 11-15-9 I-5 + II-29-2 I-6 + II-1A-7I-5 + 11-15-9 I-5 + II-29-2 I-6 + II-1A-7
I-5 + 11-15-10 I-5 + II-29-3 I-6 + II-1A-8I-5 + 11-15-10 I-5 + II-29-3 I-6 + II-1A-8
I-5 + 11-15-1 1 I-5 + II-29-4 I-6 + II-1A-9I-5 + 11-15-1 1 I-5 + II-29-4 I-6 + II-1A-9
I-5 + 11-15-12 I-5 + II-29-5 I-6 + II-1A-10I-5 + 11-15-12 I-5 + II-29-5 I-6 + II-1A-10
I-5 + 11-15-13 I-5 + II-29-6 I-6 + 11-1 A-11I-5 + 11-15-13 I-5 + II-29-6 I-6 + 11-1 A-11
I-5 + 11-16-1 I-5 + II-29-7 I-6 + II-1A-12I-5 + 11-16-1 I-5 + II-29-7 I-6 + II-1A-12
I-5 + 11-17-1 I-5 + II-29-8 I-6 + II-1A-13I-5 + 11-17-1 I-5 + II-29-8 I-6 + II-1A-13
I-5 + II-18A-1 I-5 + II-29-9 I-6 + II-1A-14I-5 + II-18A-1 I-5 + II-29-9 I-6 + II-1A-14
I-5 + II-18A-2 I-5 + 11-29-10 I-6 + II-1A-15I-5 + II-18A-2 I-5 + 11-29-10 I-6 + II-1A-15
I-5 + II-18A-3 I-5 + 11-29-11 I-6 + 11-1 A-16I-5 + II-18A-3 I-5 + 11-29-11 I-6 + 11-1 A-16
I-5 + II-18A-4 I-5 + 11-29-12 I-6 + II-1A-17I-5 + II-18A-4 I-5 + 11-29-12 I-6 + II-1A-17
I-5 + II-18A-5 I-5 + 11-29-13 I-6 + II-1A-18I-5 + II-18A-5 I-5 + 11-29-13 I-6 + II-1A-18
I-5 + II-18B-1 I-5 + 11-29-14 I-6 + II-1A-19I-5 + II-18B-1 I-5 + 11-29-14 I-6 + II-1A-19
I-5 + 11-19-1 I-5 + 11-29-15 I-6 + II-1A-20I-5 + 11-19-1 I-5 + 11-29-15 I-6 + II-1A-20
I-5 + II-20A-1 I-5 + 11-29-16 I-6 + II-1A-21I-5 + II-20A-1 I-5 + 11-29-16 I-6 + II-1A-21
I-5 + II-20B-1 I-5 + 11-29-17 I-6 + 11-1 A-22I-5 + II-20B-1 I-5 + 11-29-17 I-6 + 11-1 A-22
I-5 + II-20C-1 I-5 + 11-29-18 I-6 + 11-1 A-23I-5 + II-20C-1 I-5 + 11-29-18 I-6 + 11-1 A-23
I-5 + II-20D-1 I-5 + 11-29-19 I-6 + 11-1 A-24I-5 + II-20D-1 I-5 + 11-29-19 I-6 + 11-1 A-24
I-5 + II-20D-2 I-5 + II-29-20 I-6 + II-1A-25I-5 + II-20D-2 I-5 + II-29-20 I-6 + II-1A-25
I-5 + 11-21-1 I-5 + 11-29-21 I-6 + II-1A-26I-5 + 11-21-1 I-5 + 11-29-21 I-6 + II-1A-26
I-5 + 11-21-2 I-5 + M-29-22 I-6 + II-1A-27I-5 + 11-21-2 I-5 + M-29-22 I-6 + II-1A-27
I-5 + 11-21-3 I-5 + II-29-23 I-6 + 11-1 A-28I-5 + 11-21-3 I-5 + II-29-23 I-6 + 11-1 A-28
I-5 + 11-21-4 I-5 + II-29-24 I-6 + II-1A-29I-5 + 11-21-4 I-5 + II-29-24 I-6 + II-1A-29
I-5 + 11-21-5 I-5 + H-29-25 I-6 + II-1A-30I-5 + 11-21-5 I-5 + H-29-25 I-6 + II-1A-30
I-5 + 11-21-6 I-5 + II-29-26 I-6 + II-1A-31I-5 + 11-21-6 I-5 + II-29-26 I-6 + II-1A-31
I-5 + 11-21-7 I-5 + II-29-27 I-6 + II-1A-32I-5 + 11-21-7 I-5 + II-29-27 I-6 + II-1A-32
I-5 + II-22A-1 I-5 + II-29-28 I-6 + II-1A-33I-5 + II-22A-1 I-5 + II-29-28 I-6 + II-1A-33
I-5 + II-22B-1 I-5 + M-29-29 I-6 + II-1A-34I-5 + II-22B-1 I-5 + M-29-29 I-6 + II-1A-34
I-5 + II-23A-1 I-5 + II-29-30 I-6 + II-1A-35I-5 + II-23A-1 I-5 + II-29-30 I-6 + II-1A-35
I-5 + II-23A-2 I-5 + 11-29-31 I-6 + 11-1 B- 1I-5 + II-23A-2 I-5 + 11-29-31 I-6 + 11-1 B-1
I-5 + II-23B-1 I-5 + 11-30-1 I-6 + 11-1 B-2 1-6 + 11-1 B-3 I-6 + 11-1 B-40 I-6 + 11-1 B-77I-5 + II-23B-1 I-5 + 11-30-1 I-6 + 11-1 B-2 1-6 + 11-1 B-3 I-6 + 11-1 B-40 I-6 + 11-1 B-77
I-6 + 11-1 B-4 I-6 + 11-1 B-41 I-6 + II-1 B-78I-6 + 11-1 B-4 I-6 + 11-1 B-41 I-6 + II-1 B-78
I-6 + 11-1 B-5 I-6 + 11-1 B-42 I-6 + II-1 B-79I-6 + 11-1 B-5 I-6 + 11-1 B-42 I-6 + II-1 B-79
I-6 + 11-1 B-6 I-6 + 11-1 B-43 I-6 + 11-1 B-80I-6 + 11-1 B-6 I-6 + 11-1 B-43 I-6 + 11-1 B-80
I-6 + 11-1 B-7 I-6 + 11-1 B-44 I-6 + 11-1 B-81I-6 + 11-1 B-7 I-6 + 11-1 B-44 I-6 + 11-1 B-81
I-6 + 11-1 B-8 I-6 + 11-1 B-45 I-6 + 11-1 B-82I-6 + 11-1 B-8 I-6 + 11-1 B-45 I-6 + 11-1 B-82
I-6 + II-1 B-9 I-6 + 11-1 B-46 I-6 + II-1 B-83I-6 + II-1 B-9 I-6 + 11-1 B-46 I-6 + II-1 B-83
I-6 + 11-1 B-10 I-6 + 11-1 B-47 I-6 + 11-1 B-84I-6 + 11-1 B-10 I-6 + 11-1 B-47 I-6 + 11-1 B-84
I-6 + 11-1 B-11 I-6 + 11-1 B-48 I-6 + 11-1 B-85I-6 + 11-1 B-11 I-6 + 11-1 B-48 I-6 + 11-1 B-85
I-6 + 11-1 B-12 I-6 + II-1 B-49 I-6 + II-1 B-86I-6 + 11-1 B-12 I-6 + II-1 B-49 I-6 + II-1 B-86
I-6 + 11-1 B-13 I-6 + 11-1 B-50 I-6 + 11-1 B-87I-6 + 11-1 B-13 I-6 + 11-1 B-50 I-6 + 11-1 B-87
I-6 + 11-1 B-14 I-6 + 11-1 B-51 I-6 + 11-1 B-88I-6 + 11-1 B-14 I-6 + 11-1 B-51 I-6 + 11-1 B-88
I-6 + 11-1 B-15 I-6 + 11-1 B-52 I-6 + II-2A-1I-6 + 11-1 B-15 I-6 + 11-1 B-52 I-6 + II-2A-1
I-6 + 11-1 B-16 I-6 + 11-1 B-53 I-6 + II-2A-2I-6 + 11-1 B-16 I-6 + 11-1 B-53 I-6 + II-2A-2
I-6 + 11-1 B-17 I-6 + 11-1 B-54 I-6 + II-2A-3I-6 + 11-1 B-17 I-6 + 11-1 B-54 I-6 + II-2A-3
I-6 + II-1 B-18 I-6 + II-1 B-55 I-6 + II-2A-4I-6 + II-1 B-18 I-6 + II-1 B-55 I-6 + II-2A-4
I-6 + II-1 B-19 I-6 + II-1 B-56 I-6 + II-2A-5I-6 + II-1 B-19 I-6 + II-1 B-56 I-6 + II-2A-5
I-6 + 11-1 B-20 I-6 + 11-1 B-57 I-6 + II-2A-6I-6 + 11-1 B-20 I-6 + 11-1 B-57 I-6 + II-2A-6
I-6 + 11-1 B-21 I-6 + II-1 B-58 I-6 + II-2A-7I-6 + 11-1 B-21 I-6 + II-1 B-58 I-6 + II-2A-7
I-6 + 11-1 B-22 I-6 + 11-1 B-59 I-6 + II-2A-8I-6 + 11-1 B-22 I-6 + 11-1 B-59 I-6 + II-2A-8
I-6 + 11-1 B-23 I-6 + 11-1 B-60 I-6 + II-2B-1I-6 + 11-1 B-23 I-6 + 11-1 B-60 I-6 + II-2B-1
I-6 + 11-1 B-24 I-6 + 11-1 B-61 I-6 + II-2B-2I-6 + 11-1 B-24 I-6 + 11-1 B-61 I-6 + II-2B-2
I-6 + 11-1 B-25 I-6 + 11-1 B-62 I-6 + II-2B-3I-6 + 11-1 B-25 I-6 + 11-1 B-62 I-6 + II-2B-3
I-6 + 11-1 B-26 I-6 + 11-1 B-63 I-6 + II-2B-4I-6 + 11-1 B-26 I-6 + 11-1 B-63 I-6 + II-2B-4
I-6 + 11-1 B-27 I-6 + 11-1 B-64 I-6 + II-2B-5I-6 + 11-1 B-27 I-6 + 11-1 B-64 I-6 + II-2B-5
I-6 + 11-1 B-28 I-6 + 11-1 B-65 I-6 + II-2B-6I-6 + 11-1 B-28 I-6 + 11-1 B-65 I-6 + II-2B-6
I-6 + 11-1 B-29 I-6 + 11-1 B-66 I-6 + 11-3-1I-6 + 11-1 B-29 I-6 + 11-1 B-66 I-6 + 11-3-1
I-6 + 11-1 B-30 I-6 + 11-1 B-67 I-6 + II-3-2I-6 + 11-1 B-30 I-6 + 11-1 B-67 I-6 + II-3-2
I-6 + 11-1 B-31 I-6 + 11-1 B-68 I-6 + II-3-3I-6 + 11-1 B-31 I-6 + 11-1 B-68 I-6 + II-3-3
I-6 + 11-1 B-32 I-6 + 11-1 B-69 I-6 + II-3-4I-6 + 11-1 B-32 I-6 + 11-1 B-69 I-6 + II-3-4
I-6 + 11-1 B-33 I-6 + 11-1 B-70 I-6 + II-3-5I-6 + 11-1 B-33 I-6 + 11-1 B-70 I-6 + II-3-5
I-6 + 11-1 B-34 I-6 + 11-1 B-71 I-6 + II-3-6I-6 + 11-1 B-34 I-6 + 11-1 B-71 I-6 + II-3-6
I-6 + II-1 B-35 I-6 + 11-1 B-72 I-6 + II-3-7I-6 + II-1 B-35 I-6 + 11-1 B-72 I-6 + II-3-7
I-6 + 11-1 B-36 I-6 + 11-1 B-73 I-6 + II-3-8I-6 + 11-1 B-36 I-6 + 11-1 B-73 I-6 + II-3-8
I-6 + 11-1 B-37 I-6 + 11-1 B-74 I-6 + II-3-9I-6 + 11-1 B-37 I-6 + 11-1 B-74 I-6 + II-3-9
I-6 + 11-1 B-38 I-6 + 11-1 B-75 I-6 + 11-3-10I-6 + 11-1 B-38 I-6 + 11-1 B-75 I-6 + 11-3-10
I-6 + 11-1 B-39 I-6 + 11-1 B-76 I-6 + 11-3-11 1-6 + 11-3-12 I-6 + II-3-49 I-6 + II-7A-4I-6 + 11-1 B-39 I-6 + 11-1 B-76 I-6 + 11-3-11 1-6 + 11-3-12 I-6 + II-3-49 I-6 + II-7A-4
I-6 + 11-3-13 I-6 + II-3-50 I-6 + II-7A-5I-6 + 11-3-13 I-6 + II-3-50 I-6 + II-7A-5
I-6 + 11-3-14 I-6 + 11-3-51 I-6 + II-7B-1I-6 + 11-3-14 I-6 + 11-3-51 I-6 + II-7B-1
I-6 + 11-3-15 I-6 + II-3-52 I-6 + II-7C-1I-6 + 11-3-15 I-6 + II-3-52 I-6 + II-7C-1
I-6 + 11-3-16 I-6 + II-3-53 I-6 + II-7C-2I-6 + 11-3-16 I-6 + II-3-53 I-6 + II-7C-2
I-6 + 11-3-17 I-6 + II-3-54 I-6 + II-8A-1I-6 + 11-3-17 I-6 + II-3-54 I-6 + II-8A-1
I-6 + 11-3-18 I-6 + II-3-55 I-6 + II-8B-1I-6 + 11-3-18 I-6 + II-3-55 I-6 + II-8B-1
I-6 + 11-3-19 I-6 + II-3-56 I-6 + II-8C-1I-6 + 11-3-19 I-6 + II-3-56 I-6 + II-8C-1
I-6 + II-3-20 I-6 + II-3-57 I-6 + II-9A-1I-6 + II-3-20 I-6 + II-3-57 I-6 + II-9A-1
I-6 + 11-3-21 I-6 + II-3-58 I-6 + II-9B-1I-6 + 11-3-21 I-6 + II-3-58 I-6 + II-9B-1
I-6 + II-3-22 I-6 + II-4A-1 I-6 + II-9B-2I-6 + II-3-22 I-6 + II-4A-1 I-6 + II-9B-2
I-6 + II-3-23 I-6 + II-4A-2 I-6 + II-9C-1I-6 + II-3-23 I-6 + II-4A-2 I-6 + II-9C-1
I-6 + II-3-24 I-6 + II-4A-3 I-6 + 11-1 OA- 1I-6 + II-3-24 I-6 + II-4A-3 I-6 + 11-1 OA-1
I-6 + II-3-25 I-6 + II-4A-4 I-6 + II-10A-2I-6 + II-3-25 I-6 + II-4A-4I-6 + II-10A-2
I-6 + II-3-26 I-6 + II-4A-5 I-6 + II-10B-1I-6 + II-3-26 I-6 + II-4A-5 I-6 + II-10B-1
I-6 + II-3-27 I-6 + II-4A-6 I-6 + 11-12A- 1I-6 + II-3-27 I-6 + II-4A-6 I-6 + 11-12A-1
I-6 + II-3-28 I-6 + II-4A-7 I-6 + 11-12B- 1I-6 + II-3-28 I-6 + II-4A-7 I-6 + 11-12B-1
I-6 + II-3-29 I-6 + II-4A-8 I-6 + 11-12B-2I-6 + II-3-29 I-6 + II-4A-8 I-6 + 11-12B-2
I-6 + II-3-30 I-6 + II-4A-9 I-6 + 11-12B-3I-6 + II-3-30 I-6 + II-4A-9 I-6 + 11-12B-3
I-6 + 11-3-31 I-6 + II-4A-10 I-6 + 11-12C- 1I-6 + 11-3-31 I-6 + II-4A-10 I-6 + 11-12C-1
I-6 + II-3-32 I-6 + II-4A-1 1 I-6 + II-12C-2I-6 + II-3-32 I-6 + II-4A-1 1 I-6 + II-12C-2
I-6 + II-3-33 I-6 + II-4B-1 I-6 + 11-13-1I-6 + II-3-33 I-6 + II-4B-1 I-6 + 11-13-1
I-6 + II-3-34 I-6 + II-4B-2 I-6 + 11-13-2I-6 + II-3-34 I-6 + II-4B-2 I-6 + 11-13-2
I-6 + II-3-35 I-6 + II-4B-3 I-6 + 11-13-3I-6 + II-3-35 I-6 + II-4B-3 I-6 + 11-13-3
I-6 + II-3-36 I-6 + II-4B-4 I-6 + 11-13-4I-6 + II-3-36 I-6 + II-4B-4 I-6 + 11-13-4
I-6 + II-3-37 I-6 + II-4C-4 I-6 + 11-13-5I-6 + II-3-37 I-6 + II-4C-4 I-6 + 11-13-5
I-6 + II-3-38 I-6 + 11-5-1 I-6 + 11-13-6I-6 + II-3-38 I-6 + 11-5-1 I-6 + 11-13-6
I-6 + II-3-39 I-6 + II-5-2 I-6 + 11-15-1I-6 + II-3-39 I-6 + II-5-2 I-6 + 11-15-1
I-6 + II-3-40 I-6 + 11-6-1 I-6 + 11-15-2I-6 + II-3-40 I-6 + 11-6-1 I-6 + 11-15-2
I-6 + 11-3-41 I-6 + II-6-2 I-6 + 11-15-3I-6 + 11-3-41 I-6 + II-6-2 I-6 + 11-15-3
I-6 + II-3-42 I-6 + II-6-3 I-6 + 11-15-4I-6 + II-3-42 I-6 + II-6-3 I-6 + 11-15-4
I-6 + II-3-43 I-6 + II-6-4 I-6 + 11-15-5I-6 + II-3-43 I-6 + II-6-4 I-6 + 11-15-5
I-6 + II-3-44 I-6 + II-6-5 I-6 + 11-15-6I-6 + II-3-44 I-6 + II-6-5 I-6 + 11-15-6
I-6 + II-3-45 I-6 + II-6-6 I-6 + 11-15-7I-6 + II-3-45 I-6 + II-6-6 I-6 + 11-15-7
I-6 + II-3-46 I-6 + II-7A-1 I-6 + 11-15-8I-6 + II-3-46 I-6 + II-7A-1 I-6 + 11-15-8
I-6 + M-3-47 I-6 + II-7A-2 I-6 + 11-15-9I-6 + M-3-47 I-6 + II-7A-2 I-6 + 11-15-9
I-6 + II-3-48 I-6 + II-7A-3 I-6 + 11-15-10 1-6 + 11-15-1 1 I-6 + 11-21 -6 I-6 + 11-29-1 1I-6 + II-3-48 I-6 + II-7A-3 I-6 + 11-15-10 1-6 + 11-15-1 1 I-6 + 11-21 -6 I-6 + 11-29-1 1
I-6 + 11-15-12 I-6 + 11-21 -7 I-6 + 11-29-12I-6 + 11-15-12 I-6 + 11-21 -7 I-6 + 11-29-12
I-6 + 11-15-13 I-6 + II-22A-1 I-6 + 11-29-13I-6 + 11-15-13 I-6 + II-22A-1 I-6 + 11-29-13
I-6 + 11-16-1 I-6 + II-22B-1 I-6 + 11-29-14I-6 + 11-16-1 I-6 + II-22B-1 I-6 + 11-29-14
I-6 + 11-17-1 I-6 + II-23A-1 I-6 + 11-29-15I-6 + 11-17-1 I-6 + II-23A-1 I-6 + 11-29-15
I-6 + 11-18A- 1 I-6 + M-23A-2 I-6 + 11-29-16I-6 + 11-18A-1 I-6 + M-23A-2 I-6 + 11-29-16
I-6 + 11-18A-2 I-6 + II-23B-1 I-6 + 11-29-17I-6 + 11-18A-2 I-6 + II-23B-1 I-6 + 11-29-17
I-6 + II-18A-3 I-6 + 11-25-1 I-6 + 11-29-18I-6 + II-18A-3 I-6 + 11-25-1 I-6 + 11-29-18
I-6 + II-18A-4 I-6 + 11-28-1 I-6 + 11-29-19I-6 + II-18A-4 I-6 + 11-28-1 I-6 + 11-29-19
I-6 + II-18A-5 I-6 + II-28-2 I-6 + II-29-20I-6 + II-18A-5 I-6 + II-28-2 I-6 + II-29-20
I-6 + 11-18B- 1 I-6 + II-28-3 I-6 + 11-29-21I-6 + 11-18B-1 I-6 + II-28-3 I-6 + 11-29-21
I-6 + 11-19-1 I-6 + II-28-4 I-6 + II-29-22I-6 + 11-19-1 I-6 + II-28-4 I-6 + II-29-22
I-6 + II-20A-1 I-6 + 11-29-1 I-6 + II-29-23I-6 + II-20A-1 I-6 + 11-29-1 I-6 + II-29-23
I-6 + II-20B-1 I-6 + II-29-2 I-6 + II-29-24I-6 + II-20B-1 I-6 + II-29-2 I-6 + II-29-24
I-6 + II-20C-1 I-6 + II-29-3 I-6 + II-29-25I-6 + II-20C-1 I-6 + II-29-3 I-6 + II-29-25
I-6 + II-20D-1 I-6 + II-29-4 I-6 + M-29-26I-6 + II-20D-1 I-6 + II-29-4 I-6 + M-29-26
I-6 + II-20D-2 I-6 + II-29-5 I-6 + II-29-27I-6 + II-20D-2 I-6 + II-29-5 I-6 + II-29-27
I-6 + 11-21 -1 I-6 + II-29-6 I-6 + M-29-28I-6 + 11-21 -1 I-6 + II-29-6 I-6 + M-29-28
I-6 + 11-21-2 I-6 + II-29-7 I-6 + M-29-29I-6 + 11-21-2 I-6 + II-29-7 I-6 + M-29-29
I-6 + 11-21-3 I-6 + II-29-8 I-6 + II-29-30I-6 + 11-21-3 I-6 + II-29-8 I-6 + II-29-30
I-6 + 11-21 -4 I-6 + II-29-9 I-6 + 11-29-31I-6 + 11-21 -4 I-6 + II-29-9 I-6 + 11-29-31
I-6 + 11-21 -5 I-6 + 11-29-10 I-6 + 11-30-1 I-6 + 11-21 -5 I-6 + 11-29-10 I-6 + 11-30-1
Ganz besonders bevorzugt sind folgende Wirkstoffe:Very particular preference is given to the following active substances:
1. Acrinathrin (H-3-l)1. Acrinathrin (H-3-l)
bekannt aus EP-A-048 186 und / oder known from EP-A-048186 and / or
2. Alpha-cypermethrin (II-3-18)2. Alpha-cypermethrin (II-3-18)
bekannt aus EP-A-067 461 und / oder 3. Betacyfluthrin (II-3-3) known from EP-A-067 461 and / or 3. Betacyfluthrin (II-3-3)
bekannt aus EP-A-206 149 und / oder known from EP-A-206 149 and / or
4. Cyhalothrin (II-3-17)4. Cyhalothrin (II-3-17)
bekannt aus DE-A-2 802 962 und / oder known from DE-A-2 802 962 and / or
5. Cypermethrin (II-3-18)5. Cypermethrin (II-3-18)
bekannt aus DE-A-2326077 und / oder 6. Deltamethrin (II-3-20) known from DE-A-2326077 and / or 6. Deltamethrin (II-3-20)
bekannt aus DE-A-2326077 und / oder known from DE-A-2326077 and / or
7. Esfenvalerat (II-3-22)7. Esfenvalerat (II-3-22)
bekannt aus DE-A-2 737 297 und / oder known from DE-A-2 737 297 and / or
Etofenprox (II-3-23)Etofenprox (II-3-23)
bekannt aus DE-A-3117510 und / oder 9. Fenpropathrin (II-3-25) known from DE-A-3117510 and / or 9. Fenpropathrin (II-3-25)
bekannt aus DE-A-2231312 und / oder 10. Fenvalerat (π-3-27) known from DE-A-2231312 and / or 10. fenvalerate (π-3-27)
bekannt aus DE-A-2335347 und / oder known from DE-A-2335347 and / or
1 1. Flucythrinat (II-3-29)1 1. Flucythrinate (II-3-29)
bekannt aus DE-A-2757066 und / oder 12 a. Lambda-cyhalothrin (II-3-37) known from DE-A-2757066 and / or 12 a. Lambda-cyhalothrin (II-3-37)
bekannt aus EP-A-106469 und / oder 12 b. gamma-Cyhalothrin (II-3-34) known from EP-A-106469 and / or 12 b. gamma-cyhalothrin (II-3-34)
bekannt aus GB-A-02143823 und / oder known from GB-A-02143823 and / or
13. Permethrin (II-3-39) bekannt aus DE-A-2326077 und / oder13. Permethrin (II-3-39) known from DE-A-2326077 and / or
14. Taufluvalinat (II-3-48)14. Baptistry Luvalinate (II-3-48)
bekannt aus EP-A-038 617 und / oder known from EP-A-038 617 and / or
15. Tralomethrin (II-3-52)15. Tralomethrin (II-3-52)
bekannt aus DE-A-2 742 546 und / oder known from DE-A-2 742 546 and / or
16. Zeta-cypermethrin(II-3-18) 16. Zeta-cypermethrin (II-3-18)
bekannt aus EP-A-026542 und / oder known from EP-A-026542 and / or
17. Cyfluthrin(II-3-16)17. Cyfluthrin (II-3-16)
bekannt aus DE-A-2709264 und / oder known from DE-A-2709264 and / or
18. Bifenthrin (π-3-4)18. Bifenthrin (π-3-4)
bekannt aus EP-A-049 977 und / oder known from EP-A-049 977 and / or
19. Cycloprothrin (II-3-15) bekannt aus DE-A-2653189 und / oder19. Cycloprotein (II-3-15) known from DE-A-2653189 and / or
20. Eflusilanat (II-3-56)20. Eflusilanate (II-3-56)
bekannt aus DE-A-36 04 781 und / oder known from DE-A-36 04 781 and / or
21. Fubfenprox (II-3-33)21. Fubfenprox (II-3-33)
bekannt aus DE-A-37 08 231 und / oder known from DE-A-37 08 231 and / or
22. Pyrethrin (II-3-55) 22. Pyrethrin (II-3-55)
R = -CH3 oder -CO2CH3 R = -CH 3 or -CO 2 CH 3
R1 = -CH=CH2 oder -CH3 oder -CH2CH3 bekannt aus The Pesticide manual, 1997, 1 1. Ausgabe, S.1056 und / oderR 1 = -CH = CH 2 or -CH 3 or -CH 2 CH 3 known from The Pesticide manual, 1997, 1st edition, p.1056 and / or
23. Resmethrin (II-3-45)23. Resmethrin (II-3-45)
bekannt aus GB-A-I 168 797 und / oder 24. Imidacloprid (II-4A-4) known from GB-AI 168 797 and / or 24. Imidacloprid (II-4A-4)
bekannt aus EP-A-OO 192060 und / oder known from EP-A-OO 192060 and / or
25. Acetamiprid (II-4A-1) 25. Acetaminopride (II-4A-1)
bekannt aus WO 91/04965known from WO 91/04965
und / oderand or
26. Thiamethoxam (II-4A-9)26. Thiamethoxam (II-4A-9)
bekannt aus EP-A-00580553known from EP-A-00580553
und / oderand or
27. Nitenpyram (II-4A-6)27. Nitenpyram (II-4A-6)
C2H5 C 2 H 5
Cl - / (/f % x>— CH.- N ' - C- NHCH,Cl - / (/ f% x > - CH.-N '- C - NHCH,
N : N :
CH \CH \
NO0 NO 0
bekannt aus EP-A-00302389known from EP-A-00302389
und / oderand or
28. Thiacloprid (II-4A-8)28. Thiacloprid (II-4A-8)
bekannt aus EP-A-00235725known from EP-A-00235725
und / oder 29. Dinotefuran (π-4A-3)and or 29. Dinotefuran (π-4A-3)
bekannt aus EP-A-00649845 und / oder 30. Clothianidin (II-4A-2) known from EP-A-00649845 and / or 30. Clothianidin (II-4A-2)
bekannt aus EP-A-00376279 und / oder 31. Imidaclothiz (II-4A-5) known from EP-A-00376279 and / or 31. Imidaclothiz (II-4A-5)
bekannt aus EP-A-OO 192060 und / oder 32. Chlorfluazuron (II-15-2) bekannt aus DE-A-2818830 und / oder known from EP-A-OO 192060 and / or 32. Chlorofluorazuron (II-15-2) known from DE-A-2818830 and / or
33. Diflubenzuron (II-15-3)33. Diflubenzuron (II-15-3)
bekannt aus DE-A 2 123 236 und / oder known from DE-A 2 123 236 and / or
34. Lufenuron (II-15-8)34. Lufenuron (II-15-8)
bekannt aus EP-A-179022 und / oder known from EP-A-179022 and / or
35. Teflubenzuron (11-15-12) bekannt aus EP-A-052 833 und / oder35. Teflubenzuron (11-15-12) known from EP-A-052 833 and / or
36. Triflumuron (11-15-13)36. Triflumuron (11-15-13)
bekannt aus DE-A-2 601 780 und / oder known from DE-A-2 601 780 and / or
37. Novaluron (II-15-9)37. Novaluron (II-15-9)
bekannt aus US 4,980,376 und / oder known from US 4,980,376 and / or
38. Flufenoxuron (II-15-6)38. Flufenoxuron (II-15-6)
bekannt aus EP-A 161 019 und / oder known from EP-A 161 019 and / or
39. Hexaflumuron (II-15-7)39. Hexaflumuron (II-15-7)
bekannt aus EP-A 71279 und / oder known from EP-A 71279 and / or
40. Bistrifluron (II-15-l)40th Bistrifluron (II-15-l)
bekannt aus WO 98/00394 und / oder known from WO 98/00394 and / or
41. Noviflumuron (11-15-10)41. Noviflumuron (11-15-10)
bekannt aus WO 98/19542 und / oder 42. Buprofezin (II-16-l) bekannt aus DE-A-2 824 126 und / oder known from WO 98/19542 and / or 42. Buprofezin (II-16-l) known from DE-A-2 824 126 and / or
43. Cyromazine (II-17-l)43. Cyromazine (II-17-l)
bekannt aus DE-A-2736876 und / oder known from DE-A-2736876 and / or
44. Methoxyfenozide (II-18A-3)44. Methoxyfenocides (II-18A-3)
bekannt aus EP-A-639 559 und / oder known from EP-A-639 559 and / or
45. Tebufenozide (II-18A-4) bekannt aus EP-A-339 854 und / oder45. Tebufenozides (II-18A-4) known from EP-A-339 854 and / or
46. Halofenozide (II- 18 A-2)46. Halofenocides (II- 18 A-2)
bekannt aus EP-A 228 564 und / oder known from EP-A 228 564 and / or
47. JS-1 18 (II-18A-5)47. JS-1 18 (II-18A-5)
bekannt aus ZL 01 108161.9, Handelsname Fu-Shen, known from ZL 01 108161.9, trade name Fu-Shen,
Modern Agrochemicals, Vol. 4, No. 3, 2005, 1-7 und / oder 48. Chromafenozide (π-18A-1)Modern Agrochemicals, Vol. 4, no. 3, 2005, 1-7 and / or 48. Chromafenocides (π-18A-1)
bekannt aus EP-A-496342 und / oder 49. Endosulfan (II-2A-3) known from EP-A-496342 and / or 49. Endosulfan (II-2A-3)
und / oder and or
50. Fipronil (II-2B-3)50. Fipronil (II-2B-3)
bekannt aus EP-A-295 1 17 und / oder 51. Ethiprole (π-2B-2) known from EP-A-295 1 17 and / or 51. Ethiproles (π-2B-2)
bekannt aus WO 97/22593 und / oder 52. Pyrafluprole (II-2B-4) known from WO 97/22593 and / or 52. Pyrafluprole (II-2B-4)
bekannt aus WO 01/00614 und / oder known from WO 01/00614 and / or
53. Pyriprole (II-2B-5)53. Pyriprole (II-2B-5)
bekannt aus WO 02/10153 und / oder 54. Flubendiamide (π-28-l) known from WO 02/10153 and / or 54. Flubendiamide (π-28-l)
bekannt aus EP-A-01006107 und / oder 55. die Verbindung (II-28-2) known from EP-A-01006107 and / or 55. the compound (II-28-2)
bekannt aus WO 06/022225 und / oder known from WO 06/022225 and / or
56. Chlorantraniliprole (Rynaxapyr) (II-28-3)56. Chlorantraniliprole (Rynaxapyr) (II-28-3)
bekannt aus WO 03/015519 und / oder known from WO 03/015519 and or
57. Cyazypyr (II-28-4)57. Cyazypyr (II-28-4)
bekannt aus WO 04/067528 und / oder known from WO 04/067528 and / or
58. Emamectin (II-6-2) bekannt aus EP-A-089 202 und / oder58. emamectin (II-6-2) known from EP-A-089 202 and / or
59. Emamectin benzoate (II-6-3) bekannt aus EP-A-089202 und / oder59. emamectin benzoate (II-6-3) known from EP-A-089202 and / or
60. Abamectin (II-o-l) bekannt aus DE-A-2717040 und / oder 61. Ivermectin (II-6-4) bekannt aus EP-A-001 689 und / oder60. Abamectin (II-o-l) is known from DE-A-2717040 and / or 61. Ivermectin (II-6-4) is known from EP-A-001 689 and / or
62. Milbemectin (II-6-6) bekannt aus The Pesticide Manual, 1 1. Ausgabe, 1997, S. 846 und / oder62. Milbemectin (II-6-6) known from The Pesticide Manual, 1st edition, 1997, p. 846 and or
63. Lepimectin (II-6-5) bekannt aus EP-A-675 133 und / oder 64. Tebufenpyrad (π-21-5)63. Lepimectin (II-6-5) known from EP-A-675 133 and / or 64. Tebufenpyrad (π-21-5)
bekannt aus EP-A-289 879 und / oder known from EP-A-289 879 and / or
65. Fenpyroximate (II-21 -2)65. Fenpyroximate (II-21-2)
bekannt aus EP-A-234 045 und / oder known from EP-A-234 045 and / or
66. Pyridaben(II-21-4)66. Pyridaben (II-21-4)
bekant aus EP-A-134439 und / oder 67. Fenazaquin (π-21-1) bekant from EP-A-134439 and / or 67. Fenazaquin (π-21-1)
bekannt aus EP-A-326 329 und / oder 68. Pyrimidifen (II-21-3) known from EP-A-326 329 and / or 68. Pyrimidifen (II-21-3)
bekannt aus EP-A-196524 und / oder known from EP-A-196524 and / or
69. Tolfenpyrad (II-21-6)69. Tolfenpyrad (II-21-6)
bekannt aus EP-A-365 925 und / oder 70. Dicofol (π-29-l l) known from EP-A-365 925 and / or 70. Dicofol (π-29-II)
bekannt aus US 2,812,280known from US 2,812,280
und / oderand or
71. Cyenopyrafen (Ü-20D-2)71. Cyenopyrafen (Ü-20D-2)
(lE)-2-Cyano-2-[4-(l,l-dimethylethyl)phenyl]-l-(l,3,4-trimethyl-lH-pyrazol-5-yl)ethenyl- 2,2-dimethylpropanoate(IE) -2-cyano-2- [4- (1,1-dimethylethyl) phenyl] -1- (1,3,4-trimethyl-1H-pyrazol-5-yl) ethenyl-2,2-dimethylpropanoate
bekannt aus JP-A-2003 201 280known from JP-A-2003 201 280
und / oderand or
72. Cyflumetofen (II-20D- 1 )72. Cyflumetofen (II-20D-1)
2-Methoxyethyl-alpha-cyano-alpha- [4-(l , 1 -dimethylethyl)phenyl]-beta-oxo-2- (trifluoromethyl)benzenepropanoate 2-Methoxyethyl-alpha-cyano-alpha- [4- (l, 1-dimethyl-ethyl) phenyl] -beta-oxo-2- (trifluoromethyl) benzenepropanoate
bekannt aus WO 2002/014263 und / oder known from WO 2002/014263 and / or
73. Acequinocyl (II-20B-l)73. Acequinocyl (II-20B-1)
bekannt aus DE-A-2641343 und / oder known from DE-A-2641343 and / or
74. Fluacrypyrim (II-20C- 1 )74. Fluacrypyrim (II-20C-1)
bekannt aus WO 96/16047 und / oder known from WO 96/16047 and or
75. Bifenazate (π-25-l)75. Bifenazate (π-25-l)
bekannt aus WO 93/10 083 und / oder known from WO 93/10 083 and / or
76. Diafenthiuron (II-12A-l)76. Diafenthiuron (II-12A-I)
bekannt aus EP-A-210 487 und / oder 77. Etoxazole (II- 1 OB-I) known from EP-A-210 487 and / or 77. Etoxazole (II-1 OB-I)
bekannt aus WO 93/22 297 und / oder known from WO 93/22 297 and / or
78. Clofentezine (π-1 OA-I) bekannt aus EP-A-005 912 und / oder78. Clofentezine (π-1 OA-I) known from EP-A-005 912 and / or
79. dem Makrolid der Formel79. the macrolide of the formula
Spinosad (II-5-1) ein Gemisch aus bevorzugtSpinosad (II-5-1) a mixture of preferred
85 % Spinosyn A R=H85% spinosyn A R = H
15 % Spinosyn B R = CH3 bekannt aus EP-A-375 316 und / oder15% spinosyn BR = CH 3 known from EP-A-375 316 and / or
80. Triarathen (11-29-26)80. Triarathen (11-29-26)
bekannt aus DE-A-2 724 494 und / oder known from DE-A-2 724 494 and or
81. Tetradifon (π-12C-2)81. Tetradifon (π-12C-2)
bekannt aus US 2,812,281 und / oder 82. Propargite (H-12C-l) known from US 2,812,281 and / or 82. propargite (H-12C-1)
bekannt aus US 3,272,854 und / oder 83. Hexythiazox (II-10A-2) known from US 3,272,854 and / or 83. Hexythiazox (II-10A-2)
bekannt aus DE-A-3 037 105 und / oder 84. Bromopropylat (II-29-4) known from DE-A-3 037 105 and / or 84. Bromopropylate (II-29-4)
bekannt aus US 3,784,696 und / oder 85. Chinomethionat (II-29-6) known from US 3,784,696 and / or 85. quinomethionate (II-29-6)
bekannt aus DE-A-I 100 372 und / oder known from DE-A1 100 372 and / or
86. Amitraz (II-19-l)86. Amitraz (II-19-l)
bekannt aus DE-A-2 061 132 und / oder known from DE-A-2 061 132 and / or
87. NNI OlOl (II-9B-2)87. NNI OlOl (II-9B-2)
1 -Acetyl-3,4-dihydro-3-[(3-pyridinylmethyl)amino]-6-[ 1 ,2,2,2-tetrafluoro- 1 ■ (trifluoromethyl)ethyl-2( 1 H)-quinazolinone1-Acetyl-3,4-dihydro-3 - [(3-pyridinylmethyl) amino] -6- [1,2,2,2-tetrafluoro-1 (trifluoromethyl) ethyl-2 (1H) -quinazolinone
bekannt aus EP-A-01097932known from EP-A-01097932
und / oderand or
88. Pymetrozine (π-9B-1)88. Pymetrozine (π-9B-1)
bekannt aus EP-A-314615 und / oder known from EP-A-314615 and / or
89. Flonicamid(π-9C-1)89. Flonicamide (π-9C-1)
bekannt aus EP-A-00580374known from EP-A-00580374
und / oderand or
90. Pyriproxyfen (II-7C- 1 ) bekannt aus EP-A-128648 und / oder90. Pyriproxyfen (II-7C-1) known from EP-A-128648 and / or
91. Diofenolan (II-7C-2)91. Diofenolane (II-7C-2)
bekannt aus DE-A 2 655 910 und / oder known from DE-A 2 655 910 and / or
92. Chlorfenapyr (II-13-l)92. Chlorfenapyr (II-13-l)
bekannt aus EP-A-347 488 und / oder known from EP-A-347 488 and / or
93. Metaflumizone (II-22B-l) 93. Metaflumizone (II-22B-1)
bekannt aus EP-A-00462456known from EP-A-00462456
und / oderand or
94. Indoxacarb (11-22 A-I)94. Indoxacarb (11-22 A-I)
bekannt aus WO 92/1 1249 sowie das +-Enantiomer DPX-KN 128 bekannt aus ACS Symposium Series 800, S.178known from WO 92/1 1249 and the + enantiomer DPX-KN 128 known from ACS Symposium Series 800, p.178
und / oderand or
95. Chlorpyrifos (II-lB-12) bekannt aus US 3,244,586 und / oder95. Chlorpyrifos (II-lB-12) known from US 3,244,586 and / or
96. Spirodiclofen (π-23A-1)96. spirodiclofen (π-23A-1)
bekannt aus EP-A-528 156 und / oder known from EP-A-528 156 and / or
97. Spiromesifen (II-23A-2)97. Spiromesifen (II-23A-2)
bekannt aus EP-A-528 156 und / oder known from EP-A-528 156 and / or
98. Spirotetramat (II-23B-l) bekannt aus WO 04/007 448 und / oder98. Spirotetramat (II-23B-1) known from WO 04/007 448 and / or
99. Pyridalyl (ü-29-23)99. Pyridyl (ü-29-23)
bekannt aus WO 96/1 1909 und / oder known from WO 96/1 1909 and / or
100. die Verbindung (II-4A- 10)100. the compound (II-4A-10)
bekannt aus EP-A-0539588 und / oder known from EP-A-0539588 and / or
101. die Verbindung (II-4A- 1 1 ) 101. the compound (II-4A-1 1)
bekannt aus WO 2007/115644known from WO 2007/115644
und / oderand or
102. Spinetoram (π-5-2)102. Spinetoram (π-5-2)
bekannt aus WO 97/00265, Crouse GD et. al. Pest. Management Science 57, 177-185, (2001)known from WO 97/00265, Crouse GD et. al. Pest. Management Science 57, 177-185, (2001)
und / oderand or
103. die Verbindung (11-29-28)103. the connection (11-29-28)
bekannt aus WO 2007/149134 und seine Diastereomerenknown from WO 2007/149134 and its diastereomers
und / oderand or
104. die Verbindung (11-29-29)104. the connection (11-29-29)
bekannt aus WO 2007/149134 und seine Diastereomeren und / oder 105. die Verbindung (11-29-30) known from WO 2007/149134 and its diastereomers and / or 105. the compound (11-29-30)
bekannt aus WO 2007/095229 und seine Enantiomeren und / oder known from WO 2007/095229 and its enantiomers and / or
106. die Verbindung (11-29-31)106. the compound (11-29-31)
bekannt aus WO 99/55668 und / oder known from WO 99/55668 and / or
107. Bacillus thuringiensis-Stämme (11-30- 1 ) und / oder107. Bacillus thuringiensis strains (11-30-1) and / or
108. Aldicarb (II-l .A-2)108. Aldicarb (II-1 .A-2)
bekannt aus US 3,217,037 und / oder known from US 3,217,037 and / or
109. Carbosulfan (II-l .A-14) bekannt aus DE-A-02433680 und / oder109. Carbosulfan (II-1 .A-14) known from DE-A-02433680 and / or
bekannt aus DE-A 1162352 und / oder known from DE-A 1162352 and / or
111. Thiodicarb (π-l.A-31)111. thiodicarb (π-l.A-31)
bekannt aus DE-A 2530439 und / oder known from DE-A 2530439 and / or
112. Acephate(π-l.B-l)112. Acephates (π-1 B-1)
bekannt aus DE-A 2014027 und / oder 113. Methamidophos (π-l.B-53) known from DE-A 2014027 and / or 113. Methamidophos (π-lB-53)
bekannt aus US 3,309,266known from US 3,309,266
und / oderand or
1 14. Profenophos (II- 1.B-69)1 14. Profenophos (II- 1.B-69)
bekannt aus DE-A 22 49 462known from DE-A 22 49 462
und / oderand or
1 15. Triazophos (II-l .B-86)1 15. Triazophos (II-l .B-86)
bekannt aus DE-A 12 99 924.known from DE-A 12 99 924.
Die Wirkstoffkombinationen können darüber hinaus auch weitere fungizid, akarizid oder insektizid wirksame Zumischkomponenten enthalten.The active ingredient combinations may also contain other fungicidal, acaricidal or insecticidal Zumischkomponenten beyond.
Wenn die Wirkstoffe in den erfindungsgemäßen Wirkstoffkombinationen in bestimmten Gewichtsverhältnissen vorhanden sind, zeigt sich die verbesserte Wirkung. Jedoch können die Gewichtsverhältnisse der Wirkstoffe in den Wirkstoffkombinationen in einem relativ großen Bereich variiert werden. Im allgemeinen enthalten die erfindungsgemäßen Kombinationen Wirkstoffe der Formeln (I- 1) bis (1-6) und den Mischpartner der Formel (II) in den in der nachfolgenden Tabelle angegeben bevorzugten und besonders bevorzugten Mischungsverhältnissen: die Mischungsverhältnisse basieren auf Gewichtsverhältnissen. Das Verhältnis ist zu verstehen als Wirkstoff der Formel (I-l):Mischpartner bis Formel (1-6): Mischpartner If the active ingredients in the active compound combinations according to the invention are present in certain weight ratios, the improved effect is shown. However, the weight ratios of the active ingredients in the drug combinations can be varied within a relatively wide range. In general, the combinations according to the invention contain active compounds of the formulas (I-1) to (1-6) and the mixing partner of the formula (II) in the preferred and particularly preferred mixing ratios indicated in the table below: the mixing ratios are based on weight ratios. The ratio is to be understood as active substance of the formula (II): Mixture partner to formula (1-6): Mischpartner
Die erfindungsgemäßen Wirkstoffkombinationen eignen sich zur Bekämpfung von tierischen Schädlingen, vorzugsweise Arthropoden und Nematoden, insbesondere Insekten und Spinnentieren, die im Weinanbau, Obstanbau, in der Landwirtschaft, der Tiergesundheit, in Forsten, im Vorrats- und Materialschutz sowie auf dem Hygienesektor vorkommen. Sie sind gegen normal sensible und resistente Arten sowie gegen alle oder einzelne Entwicklungsstadien wirksam. Zu den oben erwähnten Schädlingen gehören:The active compound combinations according to the invention are suitable for controlling animal pests, preferably arthropods and nematodes, in particular insects and arachnids, which occur in viticulture, fruit growing, in agriculture, animal health, in forests, in the protection of stored products and in the hygiene sector. They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The above mentioned pests include:
Aus der Ordnung der Isopoda z.B. Oniscus asellus, Armadillidium vulgäre, Porcellio scaber.From the order of isopods e.g. Oniscus asellus, Armadillidium vulgaris, Porcellio scaber.
Aus der Ordnung der Diplopoda z.B. Blaniulus guttulatus.From the order of diplopoda e.g. Blaniulus guttulatus.
Aus der Ordnung der Chilopoda z.B. Geophilus carpophagus, Scutigera spp..From the order of Chilopoda e.g. Geophilus carpophagus, Scutigera spp ..
Aus der Ordnung der Symphyla z.B. Scutigerella immaculata. Aus der Ordnung der Thysanura z.B. Lepisma saccharina.From the order of Symphyla eg Scutigerella immaculata. From the order of Thysanura eg Lepisma saccharina.
Aus der Ordnung der Collembola z.B. Onychiurus armatus.From the order of Collembola e.g. Onychiurus armatus.
Aus der Ordnung der Orthoptera z.B. Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.From the order of Orthoptera e.g. Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.
Aus der Ordnung der Blattaria z.B. Blatta orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica.From the order of the Blattaria e.g. Blatta orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica.
Aus der Ordnung der Dermaptera z.B. Forficula auricularia.From the order of the Dermaptera e.g. Forficula auricularia.
Aus der Ordnung der Isoptera z.B. Reticulitermes spp..From the order of Isoptera e.g. Reticulitermes spp ..
Aus der Ordnung der Phthiraptera z.B. Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp..From the order of Phthiraptera e.g. Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp.
Aus der Ordnung der Thysanoptera z.B. Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.From the order of Thysanoptera e.g. Herculothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.
Aus der Ordnung der Heteroptera z.B. Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.From the order of Heteroptera, e.g. Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.
Aus der Ordnung der Homoptera z.B. Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigus spp., Macro- siphum avenae, Myzus spp., Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp.From the order of Homoptera e.g. Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp., Phorodon humuli, Rhopalosiphum Padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp.
Aus der Ordnung der Lepidoptera z.B. Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella, Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.From the order of Lepidoptera e.g. Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis Spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella, Cacoecia podana, Capua reticulana Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.
Aus der Ordnung der Coleoptera z.B. Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varive- stis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp., Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Cono- derus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.From the order of Coleoptera eg Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varvestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp., Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp , Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.
Aus der Ordnung der Hymenoptera z.B. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.From the order of Hymenoptera e.g. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
Aus der Ordnung der Diptera z.B. Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hylemyia spp., Liriomyza spp..From the order of Diptera e.g. Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp. Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hylemyia spp., Liriomyza spp.
Aus der Ordnung der Siphonaptera z.B. Xenopsylla cheopis, Ceratophyllus spp..From the order of siphonaptera e.g. Xenopsylla cheopis, Ceratophyllus spp.
Aus der Klasse der Arachnida z.B. Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp..From the class of arachnids, e.g. Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoroptes spp. Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.
Zu den pflanzenparasitären Nematoden gehören z.B. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp..The plant parasitic nematodes include e.g. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.
Die Wirkstoffkombinationen können in die üblichen Formulierungen überführt werden, wie Lösungen, Emulsionen, Spritzpulver, Suspensionen, Pulver, Stäubemittel, Pasten, lösliche Pulver, Granulate, Suspensions-Emulsions-Konzentrate, Wirkstoff-imprägnierte Natur- und synthetische Stoffe sowie Feinstverkapselungen in polymeren Stoffen.The active compound combinations can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension-emulsion concentrates, active substance-impregnated natural and synthetic substances and very fine encapsulations in polymeric substances.
Diese Formulierungen werden in bekannter Weise hergestellt, z.B. durch Vermischen der Wirkstoffe mit Streckmitteln, also flüssigen Lösungsmitteln und/oder festen Trägerstoffen, gegebenenfalls unter Verwendung von oberflächenaktiven Mitteln, also Emulgiermitteln und/oder Dispergiermitteln und/oder schaumerzeugenden Mitteln. Im Falle der Benutzung von Wasser als Streckmittel können z.B. auch organische Lösungsmittel als Hilfslösungsmittel verwendet werden. Als flüssige Lösungsmittel kommen im wesentlichen in Frage: Aromaten, wie Xylol, Toluol, oder Alkylnaphthaline, chlorierte Aromaten und chlorierte aliphatische Kohlenwasserstoffe, wie Chlorbenzole, Chlorethylene oder Methylenchlorid, aliphatische Kohlenwasserstoffe, wie Cyclohexan oder Paraffine, z.B. Erdölfraktionen, mineralische und pflanzliche Öle, Alkohole, wie Butanol oder Glykol sowie deren Ether und Ester, Ketone wie Aceton, Methylethylketon, Methylisobutylketon oder Cyclohexanon, stark polare Lösungsmittel, wie Dimethylformamid und Dimethylsulfoxid, sowie Wasser.These formulations are prepared in a known manner, for example by mixing the active compounds with extenders, ie liquid solvents and / or solid carriers, optionally with the use of surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents. In the case of using water as extender, for example, organic solvents can also be used as auxiliary solvents. Suitable liquid solvents are essentially: aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
Als feste Trägerstoffe kommen in Frage:Suitable solid carriers are:
z.B. Ammoniumsalze und natürliche Gesteinsmehle, wie Kaoline, Tonerden, Talkum, Kreide, Quarz, Attapulgit, Montmorillonit oder Diatomeenerde und synthetische Gesteinsmehle, wie hochdisperse Kieselsäure, Aluminiumoxid und Silikate, als feste Trägerstoffe für Granulate kommen in Frage: z.B. gebrochene und fraktionierte natürliche Gesteine wie Calcit, Marmor, Bims, Sepiolith, Dolomit sowie synthetische Granulate aus anorganischen und organischen Mehlen sowie Granulate aus organischem Material wie Sägemehl, Kokosnußschalen, Maiskolben und Tabakstengeln; als Emulgier- und/oder schaumerzeugende Mittel kommen in Frage: z.B. nichtionogene und anionische Emulgatoren, wie Polyoxyethylen-Fettsäure-Ester, Polyoxyethylen- Fettalkohol-Ether, z.B. Alkylaryl-polyglykolether, Alkylsulfonate, Alkylsulfate, Arylsulfonate sowie Einweißhydrolysate; als Dispergiermittel kommen in Frage: z.B. Lignin-Sulfitablaugen und Methylcellulose.e.g. Ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as fumed silica, alumina and silicates, as solid carriers for granules are suitable: e.g. crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, coconut shells, corn cobs and tobacco stalks; suitable emulsifiers and / or foam formers are: e.g. nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates; suitable dispersants are: e.g. Lignin-sulphite liquors and methylcellulose.
Es können in den Formulierungen Haftmittel wie Carboxymethylcellulose, natürliche und synthetische pulvrige, körnige oder latexförmige Polymere verwendet werden, wie Gummiarabicum, Polyvinylalkohol, Polyvinylacetat, sowie natürliche Phospholipide, wie Kephaline und Lecithine und synthetische Phospholipide. Weitere Additive können mineralische und vegetabile Öle sein.Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids may be used in the formulations. Other additives may be mineral and vegetable oils.
Es können Farbstoffe wie anorganische Pigmente, z.B. Eisenoxid, Titanoxid, Ferrocyanblau und organische Farbstoffe, wie Alizarin-, Azo- und Metallphthalocyaninfarbstoffe und Spurennährstoffe wie Salze von Eisen, Mangan, Bor, Kupfer, Kobalt, Molybdän und Zink verwendet werden.Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
Die Formulierungen enthalten im allgemeinen zwischen 0,1 und 95 Gew.-% Wirkstoff, vorzugsweise zwischen 0,5 und 90 %.The formulations generally contain between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%.
Die erfindungsgemäßen Wirkstoffkombinationen können in handelsüblichen Formulierungen sowie in den aus diesen Formulierungen bereiteten Anwendungsformen in Mischung mit anderen Wirkstoffen, wie Insektiziden, Lockstoffen, Sterilantien, Bakteriziden, Akariziden, Nematiziden, Fungiziden, wachstumsregulierenden Stoffen oder Herbiziden vorliegen. Zu den Insektiziden zählen beispielsweise Phosphorsäureester, Carbamate, Carbonsäureester, chlorierte Kohlenwasserstoffe, Phenylharnstoffe, durch Mikroorganismen hergestellte Stoffe u.a.The active compound combinations according to the invention can be used in commercial formulations as well as in the formulations prepared from these formulations in admixture with others Active ingredients, such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth regulators or herbicides. The insecticides include, for example, phosphoric esters, carbamates, carboxylic esters, chlorinated hydrocarbons, phenylureas, substances produced by microorganisms, among others
Auch eine Mischung mit anderen bekannten Wirkstoffen, wie Herbiziden oder mit Düngemitteln und Wachstumsregulatoren ist möglich.A mixture with other known active substances, such as herbicides or with fertilizers and growth regulators is possible.
Die erfindungsgemäßen Wirkstoffkombinationen können ferner beim Einsatz als Insektizide in ihren handelsüblichen Formulierungen sowie in den aus diesen Formulierungen bereiteten Anwendungsformen in Mischung mit Synergisten vorliegen. Synergisten sind Verbindungen, durch die die Wirkung der Wirkstoffe gesteigert wird, ohne daß der zugesetzte Synergist selbst aktiv wirksam sein muß.The active compound combinations according to the invention may also be present when used as insecticides in their commercial formulations as well as in the formulations prepared from these formulations in admixture with synergists. Synergists are compounds which increase the effect of the active ingredients without the added synergist itself having to be active.
Der Wirkstoffgehalt der aus den handelsüblichen Formulierungen bereiteten Anwendungsformen kann in weiten Bereichen variieren. Die Wirkstoffkonzentration der Anwendungsformen kann von 0,0000001 bis zu 95 Gew.-% Wirkstoff, vorzugsweise zwischen 0,0001 und 1 Gew.-% liegen.The active substance content of the application forms prepared from the commercial formulations can vary within wide ranges. The active ingredient concentration of the use forms may be from 0.0000001 to 95% by weight of active ingredient, preferably between 0.0001 and 1% by weight.
Die Anwendung geschieht in einer den Anwendungsformen angepaßten üblichen Weise.The application is done in a custom forms adapted to the application.
Erfindungsgemäß können alle Planzen und Pflanzenteile behandelt werden. Unter Pflanzen werden hierbei alle Pflanzen und Pflanzenpopulationen verstanden, wie erwünschte und unerwünschte Wildpflanzen oder Kulturpflanzen (einschließlich natürlich vorkommender Kulturpflanzen). Kulturpflanzen können Pflanzen sein, die durch konventionelle Züchtungs- und Optimierungsmethoden oder durch biotechnologische und gentechnologische Methoden oder Kombinationen dieser Methoden erhalten werden können, einschließlich der transgenen Pflanzen und einschließlich der durch Sortenschutzrechte schützbaren oder nicht schützbaren Pflanzensorten. Unter Pflanzenteilen sollen alle oberirdischen und unterirdischen Teile und Organe der Pflanzen, wie Spross, Blatt, Blüte und Wurzel verstanden werden, wobei beispielhaft, Blätter, Nadeln, Stängel, Stämme, Blüten, Fruchtkörper, Früchte und Samen sowie Wurzeln, Knollen und Rhizome aufgeführt werden. Zu den Pflanzenteilen gehört auch Erntegut sowie vegetatives und generatives Vermehrungsmaterial, beispielsweise Stecklinge, Knollen, Rhizome, Ableger und Samen.According to the invention, all plants and parts of plants can be treated. In this context, plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights. Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, by way of example, leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and roots, tubers and rhizomes , The plant parts also include crops and vegetative and generative propagation material, such as cuttings, tubers, rhizomes, offshoots and seeds.
Die erfindungsgemäße Behandlung der Pflanzen und Pflanzenteile mit den Wirk- Stoffkombinationen erfolgt direkt oder durch Einwirkung auf deren Umgebung, Lebensraum oder Lagerraum nach den üblichen Behandlungsmethoden, z.B. durch Tauchen, Sprühen, Verdampfen, Vernebeln, Streuen, Aufstreichen und bei Vermehrungsmaterial, insbesondere bei Samen, weiterhin durch ein- oder mehrschichtiges Umhüllen. Wie bereits oben erwähnt, können erfindungsgemäß alle Pflanzen und deren Teile behandelt werden. In einer bevorzugten Ausführungsform werden wild vorkommende oder durch konventionelle biologische Zuchtmethoden, wie Kreuzung oder Protoplastenfusion erhaltenen Pflanzenarten und Pflanzensorten sowie deren Teile behandelt. In einer weiteren bevorzugten Ausführungsform werden transgene Pflanzen und Pflanzensorten, die durch gentechnologische Methoden gegebenenfalls in Kombination mit konventionellen Methoden erhalten wurden (Genetic Modified Organisms) und deren Teile behandelt. Der Begriff "Teile" bzw. "Teile von Pflanzen" oder "Pflanzenteile" wurde oben erläutert.The treatment according to the invention of the plants and plant parts with the active substance combinations takes place directly or by acting on their environment, habitat or storage space according to the customary treatment methods, for example by dipping, spraying, evaporating, atomizing, spreading, spreading and in the case of propagation material, in particular in the case of seeds, furthermore by single or multi-layer wrapping. As already mentioned above, according to the invention all plants and their parts can be treated. In a preferred embodiment, wild-type or plant species obtained by conventional biological breeding methods, such as crossing or protoplast fusion, and plant cultivars and their parts are treated. In a further preferred embodiment, transgenic plants and plant cultivars which have been obtained by genetic engineering methods, if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated. The term "parts" or "parts of plants" or "plant parts" has been explained above.
Besonders bevorzugt werden erfindungsgemäß Pflanzen der jeweils handelsüblichen oder in Gebrauch befindlichen Pflanzensorten behandelt.It is particularly preferred according to the invention to treat plants of the respective commercially available or in use plant cultivars.
Je nach Pflanzenarten bzw. Pflanzensorten, deren Standort und Wachstumsbedingungen (Böden, Klima, Vegetationsperiode, Ernährung) können durch die erfindungsgemäße Behandlung auch überadditive ("synergistische") Effekte auftreten. So sind beispielsweise erniedrigte Aufwandmengen und/oder Erweiterungen des Wirkungsspektrums und/oder eine Verstärkung der Wirkung der erfindungsgemäß verwendbaren Stoffe und Mittel, besseres Pflanzenwachstum, erhöhte Toleranz gegenüber hohen oder niedrigen Temperaturen, erhöhte Toleranz gegen Trockenheit oder gegen Wasser- bzw. Bodensalzgehalt, erhöhte Blühleistung, erleichterte Ernte, Beschleunigung der Reife, höhere Ernteerträge, höhere Qualität und/oder höherer Ernährungswert der Ernteprodukte, höhere Lagerfähigkeit und/oder Bearbeitbarkeit der Ernteprodukte möglich, die über die eigentlich zu erwartenden Effekte hinausgehen.Depending on the plant species or plant cultivars, their location and growth conditions (soils, climate, vegetation period, diet), the treatment according to the invention may also give rise to superadditive ("synergistic") effects. Thus, for example, reduced application rates and / or extensions of the spectrum of action and / or an increase in the effect of the substances and agents usable in the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering power facilitated harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or machinability of the harvested products, which exceed the actual expected effects.
Zu den bevorzugten erfindungsgemäß zu behandelnden transgenen (gentechnologisch erhaltenen) Pflanzen bzw. Pflanzensorten gehören alle Pflanzen, die durch die gentechnologische Modifikation genetisches Material erhielten, welches diesen Pflanzen besondere vorteilhafte wertvolle Eigenschaften ("Traits") verleiht. Beispiele für solche Eigenschaften sind besseres Pflanzenwachstum, erhöhte Toleranz gegenüber hohen oder niedrigen Temperaturen, erhöhte Toleranz gegen Trockenheit oder gegen Wasser- bzw. Bodensalzgehalt, erhöhte Blühleistung, erleichterte Ernte, Beschleunigung der Reife, höhere Ernteerträge, höhere Qualität und/oder höherer Ernährungswert der Ernteprodukte, höhere Lagerfähigkeit und/oder Bearbeitbarkeit der Ernteprodukte. Weitere und besonders hervorgehobene Beispiele für solche Eigenschaften sind eine erhöhte Abwehr der Pflanzen gegen tierische und mikrobielle Schädlinge, wie gegenüber Insekten, Milben, pflanzenpathogenen Pilzen, Bakterien und/oder Viren sowie eine erhöhte Toleranz der Pflanzen gegen bestimmte herbizide Wirkstoffe. Als Beispiele transgener Pflanzen werden die wichtigen Kulturpflanzen, wie Getreide (Weizen, Reis), Mais, Soja, Kartoffel, Baumwolle, Raps sowie Obstpflanzen (mit den Früchten Äpfel, Birnen, Zitrusfrüchten und Wein- trauben) erwähnt, wobei Mais, Soja, Kartoffel, Baumwolle und Raps besonders hervorgehoben werden. Als Eigenschaften ("Traits") werden besonders hervorgehoben die erhöhte Abwehr der Pflanzen gegen Insekten durch in den Pflanzen entstehende Toxine, insbesondere solche, die durch das genetische Material aus Bacillus Thuringiensis (z.B. durch die Gene CryΙA(a), CryΙA(b), CryΙA(c), CryllA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb und CrylF sowie deren Kombinationen) in den Pflanzen erzeugt werden (im folgenden "Bt Pflanzen"). Als Eigenschaften ("Traits") werden weiterhin besonders hervorgehoben die erhöhte Toleranz der Pflanzen gegenüber bestimmten herbiziden Wirkstoffen, beispielsweise Imidazolinonen, Sulfonylharnstoffen, Glyphosate oder Phosphinotricin (z.B. "PAT"-Gen). Die jeweils die gewünschten Eigenschaften ("Traits") verleihenden Gene können auch in Kombinationen miteinander in den transgenen Pflanzen vorkommen. Als Beispiele für "Bt Pflanzen" seien Maissorten, Baumwollsorten, Sojasorten und Kartoffelsorten genannt, die unter den Handelsbezeichnungen YIELD GARD® (z.B. Mais, Baumwolle, Soja), KnockOut® (z.B. Mais), StarLink® (z.B. Mais), Bollgard® (Baumwolle), Nucotn® (Baumwolle) und NewLeaf® (Kartoffel) vertrieben werden. Als Beispiele für Herbizid tolerante Pflanzen seien Maissorten, Baumwollsorten und Sojasorten genannt, die unter den Handelsbezeichnungen Roundup Ready® (Toleranz gegen Glyphosate z.B. Mais, Baumwolle, Soja), Liberty Link® (Toleranz gegen Phosphinotricin, z.B. Raps), IMI® (Toleranz gegen Imidazolinone) und STS® (Toleranz gegen Sulfonylharnstoffe z.B. Mais) vertrieben werden. Als Herbizid resistente (konventionell auf Herbizid-Toleranz gezüchtete) Pflanzen seien auch die unter der Bezeichnung Clearfϊeld® vertriebenen Sorten (z.B. Mais) erwähnt. Selbstverständlich gelten diese Aussagen auch für in der Zukunft entwickelte bzw. zukünftig auf den Markt kommende Pflanzensorten mit diesen oder zukünftig entwickelten genetischen Eigenschaften ("Traits").The preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits"). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products. Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active substances. Examples of transgenic plants include the important crops, such as cereals (wheat, rice), maize, soya, potato, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), corn, soy, potato , Cotton and oilseed rape become. Traits that are particularly emphasized are the increased defense of the plants against insects by toxins produced in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (eg by the genes CryΙA (a), CryΙA (b), CryΙA (c), CryllA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF and combinations thereof) are produced in the plants (hereinafter "Bt plants"). Traits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene). The genes which confer the desired properties ("traits") can also occur in combinations with one another in the transgenic plants. Examples of "Bt plants" are maize varieties, cotton varieties, soybean varieties and potato varieties which are sold under the trade names YIELD GARD® (eg corn, cotton, soya), KnockOut® (eg maize), StarLink® (eg maize), Bollgard® ( Cotton), Nucotn® (cotton) and NewLeaf® (potato). Examples of herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties, which are sold under the trade names Roundup Ready® (tolerance to glyphosate eg corn, cotton, soy), Liberty Link® (tolerance to phosphinotricin, eg rapeseed), IMI® (tolerance to Imidazolinone) and STS® (tolerance to sulfonylureas eg corn). Herbicide-resistant (conventionally grown on herbicide tolerance) plants are also mentioned under the name Clearfϊeld® varieties (eg corn). Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits.
Die aufgeführten Pflanzen können besonders vorteilhaft erfindungsgemäß mit der erfindungsgemäßen Wirkstoffmischung behandelt werden. Die bei den Mischungen oben angegebenen Vorzugsbereiche gelten auch für die Behandlung dieser Pflanzen. Besonders hervorgehoben sei die Pflanzenbehandlung mit den im vorliegenden Text speziell aufgeführten Mischungen.The listed plants can be treated particularly advantageously according to the invention with the active compound mixture according to the invention. The preferred ranges given above for the mixtures also apply to the treatment of these plants. Particularly emphasized is the plant treatment with the mixtures specifically mentioned in the present text.
Die gute insektizide und akarizide Wirkung der erfindungsgemäßen Wirkstoffkombinationen geht aus den nachfolgenden Beispielen hervor. Während die einzelnen Wirkstoffe in der Wirkung Schwächen aufweisen, zeigen die Kombinationen eine Wirkung, die über eine einfache Wirkungssummierung hinausgeht.The good insecticidal and acaricidal action of the active compound combinations according to the invention is evident from the examples below. While the individual active ingredients have weaknesses in effect, the combinations show an effect that goes beyond a simple action summation.
Ein synergistischer Effekt liegt bei Insektiziden und Akariziden immer dann vor, wenn die Wirkung der Wirkstoffkombinationen größer ist als die Summe der Wirkungen der einzeln applizierten Wirkstoffe.A synergistic effect is always present in insecticides and acaricides whenever the effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
Die zu erwartende Wirkung für eine gegebene Kombination zweier Wirkstoffe kann nach S. R. Colby, Weeds 15 (1967), 20-22 wie folgt berechnet werden:The expected effect for a given combination of two drugs may be according to SR Colby, Weeds 15 (1967), 20-22 are calculated as follows:
WennIf
X den Abtötungsgrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes A in einer Aufwandmenge von m g/ha oder in einer Konzentration von m ppm bedeutet,X means the degree of killing, expressed in% of the untreated control, when using the active substance A at a rate of m g / ha or in a concentration of m ppm,
Y den Abtötungsgrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes B in einer Aufwandmenge von n g/ha oder in einer Konzentration von n ppm bedeutet undY means the degree of killing, expressed in% of the untreated control, when using the active ingredient B in an application rate of n g / ha or in a concentration of n ppm, and
E den Abtötungsgrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz der Wirkstoffe A und B in Aufwandmengen von m und n g/ha oder in einer Konzentration von m und n ppm bedeutet,E means the degree of killing, expressed in% of the untreated control, when using the active compounds A and B at application rates of m and n g / ha or in a concentration of m and n ppm,
dann istthen
X YXY
E=X + Y- 100E = X + Y-100
Ist der tatsächliche Abtötungsgrad größer als berechnet, so ist die Kombination in ihrer Abtötung überadditiv, d.h. es liegt ein synergistischer Effekt vor. In diesem Fall muss der tatsächlich beobachtete Abtötungsgrad größer sein als der aus der oben angeführten Formel errechnete Wert für den erwarteten Abtötungsgrad (E). If the actual kill rate is greater than calculated, the combination is over-additive in its kill, ie there is a synergistic effect. In this case, the actually observed kill rate must be greater than the expected kill rate (E) value calculated from the above formula.
Beispiel AExample A
Aphis gossypii -TestAphis gossypii test
Lösungsmittel: 7 Gewichtsteile Dimethylformamid Emulgator: 2 Gewichtsteile AlkylarylpolyglykoletherSolvent: 7 parts by weight of dimethylformamide Emulsifier: 2 parts by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit den angegebenen Mengen Lösungsmittel und Emulgator und verdünnt das Konzentrat mit emulgatorhaltigem Wasser auf die gewünschte Konzentration.To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
Baumwollblätter (Gossypium herbaceum), die stark von der Baumwollblattlaus {Aphis gossypii) befallen sind, werden mit der Wirkstoffzubereitung in der gewünschten Konzentration besprüht.Cotton leaves (Gossypium herbaceum), which are heavily attacked by the cotton aphid {Aphis gossypii), are sprayed with the active compound preparation in the desired concentration.
Nach der gewünschten Zeit wird die Abtötung in % bestimmt. Dabei bedeutet 100 %, dass alle Blattläuse abgetötet wurden; 0 % bedeutet, dass keine Blattläuse abgetötet wurden. Die ermittelten Abtötungswerte verrechnet man nach der Colby-Formel.After the desired time the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed. The determined kill values are calculated according to the Colby formula.
Bei diesem Test zeigen z. B. die folgenden Wirkstoffkombinationen gemäß vorliegender Anmeldung eine synergistisch verstärkte Wirksamkeit im Vergleich zu den einzeln angewendeten Wirkstoffen:In this test, z. B. the following drug combinations according to the present application a synergistically enhanced efficacy compared to the individually applied drugs:
Tabelle A - 1 : Apbis gossypii - TestTable A - 1: Apbis gossypii test
* gef. = gefundene Wirkung* gef. = found effect
** ber. = nach der Colby-Formel berechnete Wirkung Beispiel B** calc. = calculated according to the Colby formula Example B
Bemisia tabaci -TestBemisia tabaci test
Lösungsmittel: 7 Gewichtsteile DimethylformamidSolvent: 7 parts by weight of dimethylformamide
Emulgator: 2 Gewichtsteile AlkylarylpolyglykoletherEmulsifier: 2 parts by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit den angegebenen Mengen Lösungsmittel und Emulgator und verdünnt das Konzentrat mit emulgatorhaltigem Wasser auf die gewünschte Konzentration.To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
Baumwollblätter {Gossypium herbaceum), die stark mit Larvenstadien der Weißen Fliegen {Bemisia tabaci) befallen sind, werden mit der Wirkstoffzubereitung in der gewünschten Konzentration besprüht.Cotton leaves {Gossypium herbaceum), which are heavily infested with larval stages of the white flies {Bemisia tabaci), are sprayed with the preparation of active compound in the desired concentration.
Nach der gewünschten Zeit wird die Abtötung in % bestimmt. Dabei bedeutet 100 %, dass alle Weißen Fliegen abgetötet wurden; 0 % bedeutet, dass keine Weißen Fliegen abgetötet wurden. Die ermittelten Abtötungswerte verrechnet man nach der Colby-Formel.After the desired time the kill is determined in%. 100% means that all white flies have been killed; 0% means that no white flies have been killed. The determined kill values are calculated according to the Colby formula.
Bei diesem Test zeigen z. B. die folgenden Wirkstoffkombinationen gemäß vorliegender Anmeldung eine synergistisch verstärkte Wirksamkeit im Vergleich zu den einzeln angewendeten Wirkstoffen:In this test, z. B. the following drug combinations according to the present application a synergistically enhanced efficacy compared to the individually applied drugs:
Tabelle B - 1 : Bemisia tabaci - TestTable B - 1: Bemisia tabaci test
* gef. = gefundene Wirkung* gef. = found effect
** ber. = nach der Colby-Formel berechnete Wirkung Beispiel C** calc. = calculated according to the Colby formula Example C
Myzus persicae -TestMyzus persicae test
Lösungsmittel: 78 Gewichtsteile AcetonSolvent: 78 parts by weight of acetone
1 ,5 Gewichtsteile Dimethylformamid1.5 parts by weight of dimethylformamide
Emulgator: 0,5 Gewichtsteile AlkylarylpolyglykoletherEmulsifier: 0.5 part by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit den angegebenen Mengen Lösungsmittel und Emulgator und verdünnt das Konzentrat mit emulgatorhaltigem Wasser auf die gewünschte Konzentration.To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
Kohlblätter (Brassica oleraceά), die stark von der Grünen Pfirsichblattlaus {Myzus persicae) befallen sind, werden durch Spritzen mit der Wirkstoffzubereitung in der gewünschten Konzentration behandelt.Cabbage leaves (Brassica oleraceά) that are heavily infested with the green peach aphid {Myzus persicae) are treated by spraying with the preparation of active compound in the desired concentration.
Nach der gewünschten Zeit wird die Abtötung in % bestimmt. Dabei bedeutet 100 %, dass alle Blattläuse abgetötet wurden; 0 % bedeutet, dass keine Blattläuse abgetötet wurden. Die ermittelten Abtötungswerte verrechnet man nach der Colby-Formel.After the desired time the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed. The determined kill values are calculated according to the Colby formula.
Bei diesem Test zeigen z. B. die folgenden Wirkstoffkombinationen gemäß vorliegender Anmeldung eine synergistisch verstärkte Wirksamkeit im Vergleich zu den einzeln angewendeten Wirkstoffen: In this test, z. B. the following drug combinations according to the present application a synergistically enhanced efficacy compared to the individually applied drugs:
Tabelle C - 1 : Myzus persicae - TestTable C - 1: Myzus persicae test
* gef. = gefundene Wirkung* gef. = found effect
** ber. = nach der Colby-Formel berechnete Wirkung** calc. = calculated according to the Colby formula
Tabelle C - 2Table C - 2
* gef. = gefundene Wirkung* gef. = found effect
** ber. = nach der Colby-Formel berechnete Wirkung ** calc. = calculated according to the Colby formula
Beispiel DExample D
Nilaparvata lugens -TestNilaparvata lugens test
Lösungsmittel: 7 Gewichtsteile DimethylformamidSolvent: 7 parts by weight of dimethylformamide
Emulgator: 2 Gewichtsteile AlkylarylpolyglykoletherEmulsifier: 2 parts by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit den angegebenen Mengen Lösungsmittel und Emulgator und verdünnt das Konzentrat mit emulgatorhaltigem Wasser auf die gewünschte Konzentration.To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
Reispflanzen (Oryza sativά) werden durch Spritzen mit der Wirkstoffzubereitung in der gewünschten Konzentration behandelt und mit Reiszikaden (Nilaparvata lugens) besetzt, solange die Blätter noch feucht sind.Rice plants (Oryza sativά) are treated by spraying with the preparation of active compound in the desired concentration and filled with rice cicadas (Nilaparvata lugens) while the leaves are still moist.
Nach der gewünschten Zeit wird die Abtötung in % bestimmt. Dabei bedeutet 100 %, dass alle Reiszikaden abgetötet wurden; 0 % bedeutet, dass keine Reiszikaden abgetötet wurden. Die ermittelten Abtötungswerte verrechnet man nach der Colby-Formel.After the desired time the kill is determined in%. 100% means that all rice cicadas have been killed; 0% means that no rice cicadas have been killed. The determined kill values are calculated according to the Colby formula.
Bei diesem Test zeigen z. B. die folgenden Wirkstoffkombinationen gemäß vorliegender Anmeldung eine synergistisch verstärkte Wirksamkeit im Vergleich zu den einzeln angewendeten Wirkstoffen:In this test, z. B. the following drug combinations according to the present application a synergistically enhanced efficacy compared to the individually applied drugs:
Tabelle D - 1 : Nilaparvata lugens - TestTable D-1: Nilaparvata lugens test
* gef. = gefundene Wirkung* gef. = found effect
** ber. = nach der Colby-Formel berechnete Wirkung Beispiel E** calc. = calculated according to the Colby formula Example E
Phaedon cochleariae - Larven -TestPhaedon cochleariae - larval test
Lösungsmittel: 78 Gewichtsteile AcetonSolvent: 78 parts by weight of acetone
1,5 Gewichtsteile Dimethylformamid1.5 parts by weight of dimethylformamide
Emulgator: 0,5 Gewichtsteile AlkylarylpolyglykoletherEmulsifier: 0.5 part by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit den angegebenen Mengen Lösungsmittel und Emulgator und verdünnt das Konzentrat mit emulgatorhaltigem Wasser auf die gewünschte Konzentration.To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
Kohlblätter {Brassica oleraceä) werden durch Spritzen mit der Wirkstoffzubereitung in der gewünschten Konzentration behandelt und mit Larven des Meerrettichblattkäfers {Phaedon cochleariae) besetzt, solange die Blätter noch feucht sind.Cabbage leaves {Brassica oleraceä) are treated by spraying with the preparation of active compound in the desired concentration and are populated with larvae of the horseradish leaf beetle {Phaedon cochleariae) while the leaves are still moist.
Nach der gewünschten Zeit wird die Abtötung in % bestimmt. Dabei bedeutet 100 %, dass alle Käferlarven abgetötet wurden; 0 % bedeutet, dass keine Käferlarven abgetötet wurden. Die ermittelten Abtötungswerte verrechnet man nach der Colby-Formel.After the desired time the kill is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed. The determined kill values are calculated according to the Colby formula.
Bei diesem Test zeigen die folgenden Wirkstoffkombinationen gemäß vorliegender Anmeldung eine synergistisch verstärkte Wirksamkeit im Vergleich zu den einzeln angewendeten Wirkstoffen: In this test, the following active ingredient combinations according to the present application show a synergistically enhanced effectiveness compared to the individually applied active ingredients:
Tabelle E - 1 : Phaedon cochleariae Larven - Test Table E - 1: Phaedon cochleariae larval test
Tabelle E - 2 Table E - 2
* gef. = gefundene Wirkung* gef. = found effect
** ber. = nach der Colby-Formel berechnete Wirkung ** calc. = calculated according to the Colby formula
Beispiel FExample F
Spodoptera frugiperda - Larven -TestSpodoptera frugiperda - larval test
Lösungsmittel: 78 Gewichtsteile AcetonSolvent: 78 parts by weight of acetone
1 ,5 Gewichtsteile Dimethylformamid1.5 parts by weight of dimethylformamide
Emulgator: 0,5 Gewichtsteile AlkylarylpolyglykoletherEmulsifier: 0.5 part by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit den angegebenen Mengen Lösungsmittel und Emulgator und verdünnt das Konzentrat mit emulgatorhaltigem Wasser auf die gewünschte Konzentration.To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
Kohlblätter {Brassica oleraceä) werden durch Spritzen mit der Wirkstoffzubereitung in der gewünschten Konzentration behandelt und mit Larven des Heerwurms {Spodoptera frugiperda) besetzt, solange die Blätter noch feucht sind.Cabbage leaves {Brassica oleraceä) are treated by spraying with the preparation of active compound in the desired concentration and are populated with larvae of the armyworm {Spodoptera frugiperda) while the leaves are still moist.
Nach der gewünschten Zeit wird die Abtötung in % bestimmt. Dabei bedeutet 100 %, dass alle Raupen abgetötet wurden; 0 % bedeutet, dass keine Raupen abgetötet wurden. Die ermittelten Abtötungswerte verrechnet man nach der Colby- Formel.After the desired time the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed. The determined kill values are calculated according to the Colby formula.
Bei diesem Test zeigen die folgenden Wirkstoffkombinationen gemäß vorliegender Anmeldung eine synergistisch verstärkte Wirksamkeit im Vergleich zu den einzeln angewendeten Wirkstoffen: In this test, the following active ingredient combinations according to the present application show a synergistically enhanced effectiveness compared to the individually applied active ingredients:
Tabelle F - 1 : Spodoptera frugiperda Larven - TestTable F - 1: Spodoptera frugiperda larvae test
Tabelle F - 2:Table F - 2:
* gef. = gefundene Wirkung* gef. = found effect
** ber. = nach der Colby-Formel berechnete Wirkung Beispiel G** calc. = calculated according to the Colby formula Example G
Tetranychus urticae - Test (OP-resistent/Spritzbehandlung)Tetranychus urticae - test (surgical-resistant / spray treatment)
Lösungsmittel: 78 Gewichtsteile AcetonSolvent: 78 parts by weight of acetone
1,5 Gewichtsteile Dimethylformamid1.5 parts by weight of dimethylformamide
Emulgator: 0,5 Gewichtsteile AlkylarylpolyglykoletherEmulsifier: 0.5 part by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit den angegebenen Mengen Lösungsmittel und Emulgator und verdünnt das Konzentrat mit emulgatorhaltigem Wasser auf die gewünschte Konzentration.To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
Bohnenblattscheiben (Phaseolus vulgaris), die von allen Stadien der Gemeinen Spinnmilbe (Tetranychus urticae) befallen sind, werden mit einer Wirkstoffzubereitung der gewünschten Konzentration gespritzt.Bean leaf discs (Phaseolus vulgaris) infected by all stages of the common spider mite (Tetranychus urticae) are sprayed with an active compound preparation of the desired concentration.
Nach der gewünschten Zeit wird die Wirkung in % bestimmt. Dabei bedeutet 100 %, dass alle Spinnmilben abgetötet wurden; 0 % bedeutet, dass keine Spinnmilben abgetötet wurden.After the desired time, the effect is determined in%. 100% means that all spider mites have been killed; 0% means that no spider mites have been killed.
Bei diesem Test zeigte die folgende Wirkstoffkombination gemäß vorliegender Anmeldung eine synergistisch verstärkte Wirksamkeit im Vergleich zu den einzeln angewendeten Wirkstoffen: In this test, the following active ingredient combination according to the present application showed a synergistically enhanced effectiveness in comparison to the individually applied active ingredients:
Tabelle G - 1 : Tetranychus urticae - TestTable G - 1: Tetranychus urticae test
Tabelle G - 2Table G - 2
* gef. = gefundene Wirkung* gef. = found effect
** ber. = nach der Colby-Formel berechnete Wirkung Beispiel H** calc. = calculated according to the Colby formula Example H
Grenzkonzentrations-Test / Bodeninsekten - Behandlung transgener PflanzenBoundary Concentration Test / Soil Insects - Treatment of transgenic plants
Testinsekt: Diabrotica balteata - Larven im BodenTest insect: Diabrotica balteata - larvae in soil
Lösungsmittel: 7 Gewichtsteile AcetonSolvent: 7 parts by weight of acetone
Emulgator: 2 Gewichtsteil AlkylarylpolyglykoletherEmulsifier: 2 parts by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit der angegebenen Menge Lösungsmittel, gibt die angegebene Menge Emulgator zu und verdünnt das Konzentrat mit Wasser auf die gewünschte Konzentration.To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent, the indicated amount of emulsifier is added and the concentrate is diluted with water to the desired concentration.
Die Wirkstoffzubereitung wird auf den Boden gegossen. Dabei spielt die Konzentration des Wirkstoffs in der Zubereitung praktisch keine Rolle, entscheidend ist allein die Wirkstoffgewichtsmenge pro Volumeneinheit Boden, welche in ppm (mg/1) angegeben wird. Man füllt den Boden in 0,25 1 Töpfe und läßt diese bei 200C stehen.The preparation of active compound is poured onto the ground. In this case, the concentration of the active substance in the preparation plays virtually no role, the only decisive factor is the amount of active ingredient per unit volume of soil, which is stated in ppm (mg / l). The soil is poured into 0.25 1 pots and allowed to stand at 20 0 C.
Sofort nach dem Ansatz werden je Topf 5 vorgekeimte Maiskörner der Sorte YIELD GUARD (Warenzeichen von Monsanto Comp., USA) gelegt. Nach 2 Tagen werden die entsprechenden Testinsekten in den behandelten Boden gesetzt. Nach weiteren 7 Tagen wird der Wirkungsgrad des Wirkstoffs durch Auszählen der aufgelaufenen Maispflanzen bestimmt (Auflauf aller Pflanzen = 100 % Wirkung). Immediately after the batch, 5 pre-germinated corn kernels of the YIELD GUARD variety (trademark of Monsanto Comp., USA) are placed per pot. After 2 days the appropriate test insects are placed in the treated soil. After another 7 days, the efficiency of the active ingredient is determined by counting the accumulated maize plants (casserole of all plants = 100% effect).
Beispiel IExample I
Heliotbis virescens - Test - Behandlung transgener PflanzenHeliotbis virescens - test - treatment of transgenic plants
Lösungsmittel: 7 Gewichtsteile DimethylformamidSolvent: 7 parts by weight of dimethylformamide
Emulgator : 2 Gewichtsteil AlkylarylpolyglykoletherEmulsifier: 2 parts by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit der angegebenen Menge Lösungsmittel und der angegebenen Menge Emulgator und verdünnt das Konzentrat mit Wasser auf die gewünschte Konzentration.To prepare a suitable preparation of active compound, 1 part by weight of active compound with the stated amount of solvent and the stated amount of emulsifier and the concentrate is diluted with water to the desired concentration.
Sojatriebe (Glycine max) der Sorte Roundup Ready (Warenzeichen der Monsanto Comp. USA) werden durch Spritzen mit der Wirkstoffzubereitung in der gewünschten Konzentration behandelt und mit der Tabakknospenraupe Heliothis virescens besetzt, solange die Blätter noch feucht sind.Soybean shoots (Glycine max) of the variety Roundup Ready (trademark of Monsanto Comp. USA) are treated by spraying with the preparation of active compound in the desired concentration and populated with the tobacco budworm Heliothis virescens while the leaves are still moist.
Nach der gewünschten Zeit wird die Abtötung der Insekten bestimmt.After the desired time, the kill of the insects is determined.
Beispiel JExample J
Myzus persicae - Test - Behandlung transgener PflanzenMyzus persicae - test - treatment of transgenic plants
Lösungsmittel: 7 Gewichtsteile AcetonSolvent: 7 parts by weight of acetone
Emulgator : 2 Gewichtsteil AlkylarylpolyglykoletherEmulsifier: 2 parts by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit der angegebenen Menge Lösungsmittel und der angegebenen Menge Emulgator und verdünnt das Konzentrat mit Wasser auf die gewünschte Konzentration.To prepare a suitable preparation of active compound, 1 part by weight of active compound with the stated amount of solvent and the stated amount of emulsifier and the concentrate is diluted with water to the desired concentration.
Transgene Kohlpflanzen (Brassica oleracea), die stark von der Grünen Pfirsichblattlaus Myzus persicae befallen sind, werden durch Spritzen mit der Wirkstoffzubereitung in der gewünschten Konzentration behandelt.Transgenic cabbage plants (Brassica oleracea) which are heavily infested with the green peach aphid Myzus persicae are treated by spraying with the preparation of active compound in the desired concentration.
Nach der gewünschten Zeit wird die Abtötung der Insekten bestimmt. After the desired time, the kill of the insects is determined.

Claims

PatentansprücheWirkstoffkombinationen enthaltend mindestens eine Verbindung der Formel (I)in welcherW für Wasserstoff, Alkyl, Alkenyl, Alkinyl, Halogen, Alkoxy, Halogenalkyl, Halogenalkoxy oder Cyano steht,X für Halogen, Alkyl, Alkenyl, Alkinyl, Alkoxy, Halogenalkyl, Halogenalkoxy, Nitro oder Cyano steht,Y und Z unabhängig voneinander für Wasserstoff, Alkyl, Alkenyl, Alkinyl, Alkoxy, Halogen, Halogenalkyl, Halogenalkoxy, Cyano oder Nitro steht,A und B und das Kohlenstoffatom, an das sie gebunden sind, für jeweils gegebenenfalls durch Alkyl, Halogenalkyl, Alkoxy, Alkoxyalkyl oder gegebenenfalls substituiertes Phenyl substituiertes fünf- bis siebengliedriges Ketal, Thioketal oder Dithioketal steht, welches gegebenenfalls durch ein weiteres Heteroatom unterbrochen sein kann,G für Wasserstoff (a) oder für eine der GruppenO (g). steht,worinE für ein Metallion oder ein Ammoniumion steht,L für Sauerstoff oder Schwefel steht,M für Sauerstoff oder Schwefel steht,R.1 für jeweils gegebenenfalls durch Halogen oder Cyano substituiertes Alkyl, Alke- nyl, Alkoxyalkyl, Alkylthioalkyl oder Polyalkoxyalkyl oder für jeweils gegebenenfalls durch Halogen, Alkyl oder Alkoxy substituiertes Cycloalkyl oder Heterocyclyl oder für jeweils gegebenenfalls substituiertes Phenyl, Phenylalkyl, Hetaryl, Phenoxyalkyl oder Hetaryloxyalkyl steht,R.2 für jeweils gegebenenfalls durch Halogen oder Cyano substituiertes Alkyl, Alke- nyl, Alkoxyalkyl oder Polyalkoxyalkyl oder für jeweils gegebenenfalls substituiertes Cycloalkyl, Phenyl oder Benzyl steht,R.3, R^ und RS unabhängig voneinander für jeweils gegebenenfalls durch Halogen substi- tuiertes Alkyl, Alkoxy, Alkylamino, Dialkylamino, Alkylthio, Alkenylthio oderCycloalkylthio oder für jeweils gegebenenfalls substituiertes Phenyl, Benzyl, Phenoxy oder Phenylthio stehen,RÖ und R^ unabhängig voneinander für Wasserstoff, für jeweils gegebenenfalls durch Halogen oder Cyano substituiertes Alkyl, Cycloalkyl, Alkenyl, Alkoxy, Alkoxy- alkyl, für jeweils gegebenenfalls substituiertes Phenyl oder Benzyl stehen, oder gemeinsam mit dem N-Atom, an das sie gebunden sind, einen gegebenenfalls Sauerstoff oder Schwefel enthaltenden und gegebenenfalls substituierten Cyclus bildenund ein oder mehrere weitere Insektizide und / oder Akarizide der Formel (II):Acetylcholinesterase (AChE) Inhibitoren II- 1II-l .A Carbamate,Alanycarb (II-l .A-1), Aldicarb (II-l .A-2), Aldoxycarb (II-l .A-3), Allyxycarb (II- l .A-4), Aminocarb (II-l .A-5), Bendiocarb (II-l .A-6), Benfuracarb (II-l .A-7),Bufencarb (π-l .A-8), Butacarb (II-l .A-9), Butocarboxim (II- 1.A- 10), Butoxycarb- oxim (II-l .A-1 1), Carbaryl (π-l .A-12), Carbofuran (II-l .A-13), Carbosulfan (II- An active substance combination comprising at least one compound of the formula (I) in which W is hydrogen, alkyl, alkenyl, alkynyl, halogen, alkoxy, haloalkyl, haloalkoxy or cyano, X is halogen, alkyl, alkenyl, alkynyl, alkoxy, haloalkyl, haloalkoxy, nitro or Cyano, Y and Z are independently hydrogen, alkyl, alkenyl, alkynyl, alkoxy, halogen, haloalkyl, haloalkoxy, cyano or nitro, A and B and the carbon atom to which they are attached, each optionally substituted by alkyl, haloalkyl , Alkoxy, alkoxyalkyl or optionally substituted phenyl substituted five- to seven-membered ketal, thioketal or dithioketal, which may optionally be interrupted by another heteroatom, G is hydrogen (a) or one of the groups O (g). wherein E is a metal ion or an ammonium ion, L is oxygen or sulfur, M is oxygen or sulfur, R.1 is in each case optionally halogen- or cyano-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl or polyalkoxyalkyl or in each case optionally substituted by halogen, alkyl or alkoxy-substituted cycloalkyl or heterocyclyl or each optionally substituted phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl, R.2 is in each case optionally substituted by halogen or cyano alkyl, alkenyl, alkoxyalkyl or polyalkoxyalkyl or for each optionally substituted cycloalkyl, phenyl or benzyl, R.3, R ^ and RS independently of one another in each case halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio or cycloalkylthio or in each case optionally substituted phenyl, benzyl, phenoxy or Phenylthio, RÖ and R ^ una independently of one another represent hydrogen, in each case optionally halogen or cyano-substituted alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, in each case optionally substituted phenyl or benzyl, or together with the N-atom to which they are attached, optionally Oxygen-containing or sulfur-containing and optionally substituted cycle and one or more further insecticides and / or acaricides of formula (II): acetylcholinesterase (AChE) inhibitors II-1II-l .A carbamate, alanycarb (II-l .A-1), aldicarb (II-l .A-2), aldoxycarb (II-l .A-3), allyxycarb (II-l .A-4), aminocarb (II-l .A-5), bendiocarb (II-l .A -6), benfuracarb (II-l .A-7), bufencarb (π-l .A-8), butacarb (II-l .A-9), butocarboxime (II-1.A-10), butoxycarbone oxime (II-l .A-1 l), carbaryl (π-l .A-12), carbofuran (II-l .A-13), carbosulfan (II.
1.A- 14), Cloethocarb (D- 1.A- 15), Dimetilan (II- 1.A- 16), Ethiofencarb (II- 1.A- 17), Fenobucarb (II-l.A-18), Fenothiocarb (ü-l.A-19), Formetanate (II-l.A-20), Furathiocarb (II-l.A-21), Isoprocarb (D-l.A-22), Metam-sodium (ü-l.A-23), Me- thiocarb (II-l.A-24), Methomyl (π-l.A-25), Metolcarb (II-l.A-26), Oxamyl (D- l.A-27), Pirimicarb (U-I. A-28), Promecarb (π-l.A-29), Propoxur (II-l.A-30),1.A-14), cloethocarb (D-1.A-15), dimetilane (II-1.A-16), ethiofenecarb (II-1.A-17), fenobucarb (II-IA-18), fenothiocarb (ü-lA-19), formetanate (II-lA-20), furathiocarb (II-lA-21), isoprocarb (Dl.A-22), metam-sodium (ü-lA-23), methylthiocarb ( II-lA-24), methomyl (π-lA-25), metolcarb (II-lA-26), oxamyl (D-lA-27), pirimicarb (UI.A-28), promecarb (π-lA-29 ), Propoxur (II-IA-30),
Thiodicarb (π-l.A-31), Thiofanox (π-l.A-32), Trimethacarb (II-l.A-33), XMC (II- l.A-34), Xylylcarb (II-l.A-35)Thiodicarb (π-l.A-31), thiofanox (π-l.A-32), trimethacarb (II-l.A-33), XMC (II-l.A-34), xylylcarb (II-l.A-35)
Organophosphate,organophosphates,
Acephate (II-l.B-1), Azamethiphos (ü-l.B-2), Azinphos (-methyl, -ethyl) (II-l.B- 3), Bromophos-ethyl (ü-l.B-4), Bromfenvinfos (-methyl) (ü-l.B-5), ButathiofosAcephates (II-lB-1), azamethiphos (μ-lB-2), azinphos (-methyl, -ethyl) (II-lB-3), bromophospheth-ethyl (μ-lB-4), bromfenfenvinfos (-methyl) (ü-lB-5), butathiofos
(II-l.B-6), Cadusafos (ü-l.B-7), Carbophenothion (π-l.B-8), Chlorethoxyfos (II- l.B-9), Chlorfenvinphos (H-I. B-IO), Chlormephos (ü-1. B-Il), Chloφyrifos (- methylΛethyl) (π-l.B-12), Coumaphos (II- 1.B- 13), Cyanofenphos (II- 1.B- 14), Cyanophos (II-l.B-15), Chlorfenvinphos (II-l.B-16), Demeton-S-methyl (II-l.B- 17), Demeton-S-methylsulphon (II- 1.B- 18), Dialifos (II- 1.B- 19), Diazinon (II- 1.B-(II-lB-6), cadusafos (μ-lB-7), carbophenothione (π-lB-8), chloroethoxyfos (II-lB-9), chlorfenvinphos (HI.B-IO), chlormephos (ü-1. B-II), chloφyrifos (- methylethyl) (π-IB-12), coumaphos (II-1.B-13), cyanofenphos (II-1.B-14), cyanophos (II-IB-15), chlorfenvinphos (II-lB-16), demeton S -methyl (II-lB-17), demeton S-methylsulphone (II-1.B-18), dialifos (II-1.B-19), diazinon (II - 1.B-
20), Dichlofenthion (ü-l.B-21), Dichlorvos/DDVP (II-l.B-22), Dicrotophos (II- l.B-23), Dimethoate (ü-l.B-24), Dimethylvinphos (II-l.B-25), Dioxabenzofos (II- l.B-26), Disulfoton (II-l.B-27), EPN (II-l.B-28), Ethion (II-l.B-29), Ethoprophos (II-l.B-30), Etrimfos (II-l.B-31), Famphur (II-l.B-32), Fenamiphos (II-l.B-33), Fenitrothion (II-l.B-34), Fensulfothion (π-l.B-35), Fenthion (II-l.B-36),20), dichlorofenthione (μ-lB-21), dichlorvos / DDVP (II-lB-22), dicrotophos (II-lB-23), dimethoates (μ-lB-24), dimethylvinphos (II-lB-25), Dioxabenzofos (II-lB-26), disulfonone (II-lB-27), EPN (II-lB-28), ethione (II-lB-29), ethoprophos (II-lB-30), etrimfos (II-lB -31), Famphur (II-lB-32), Fenamiphos (II-lB-33), Fenitrothion (II-lB-34), Fensulfothion (π-lB-35), Fenthion (II-lB-36),
Flupyrazofos (II-l.B-37), Fonofos (II-l.B-38), Formothion (II-l.B-39), Fos- methilan (ü-l.B-40), Fosthiazate (π-l.B-41), Heptenophos (II-l.B-42), Iodofenphos (II-l.B-43), Iprobenfos (II-l.B-44), Isazofos (II-l.B-45), Isofenphos (II-l.B-46), Isopropyl (II-l.B-47), O-salicylate (II-l.B-48), Isoxathion (π-l.B-49), Malathion (IM.B-50), Mecarbam (π-l.B-51), Methacrifos (II-l.B-52),Flupyrazofos (II-lB-37), fonofos (II-lB-38), formothione (II-lB-39), fos-methilane (μ-lB-40), fosthiazate (π-lB-41), heptenophos (II -lB-42), iodofenofen (II-lB-43), Iprobenfos (II-lB-44), isazofos (II-lB-45), isofenphos (II-lB-46), isopropyl (II-lB-47) , O-salicylates (II-lB-48), isoxathione (π-lB-49), malathion (IM.B-50), mecarbam (π-lB-51), methacrifos (II-lB-52),
Methamidophos (π-l.B-53), Methidathion (π-l.B-54), Mevinphos (II-l.B-55), Monocrotophos (II-l.B-56), Naled (II-l.B-57), Omethoate (II-l.B-58), Oxydemeton-methyl (π-l.B-59), Parathion (-methylΛethyl) (π-l.B-60), Phenthoate (II-l.B-61), Phorate (ü-l.B-62), Phosalone (π-l.B-63), Phosmet (II-l.B-64), Phosphamidon (II-l.B-65), Phosphocarb (ü-l.B-66), Phoxim (II-l.B-67),Methamidophos (π-lB-53), Methidathione (π-lB-54), Mevinphos (II-lB-55), Monocrotophos (II-lB-56), Naled (II-lB-57), Omethoate (II-lB -58), oxydemeton-methyl (π-lB-59), parathion (-methylethyl) (π-lB-60), phenthoates (II-lB-61), phorates (μ-lB-62), phosalones (π- lB-63), phosmet (II-lB-64), phosphamidone (II-lB-65), phosphocarb (μ-lB-66), phoxim (II-lB-67),
Pirimiphos (-methyl/-ethyl) (ü-l.B-68), Profenofos (II-l.B-69), Propaphos (II-l.B- 70), Propetamphos (II-l.B-71), Prothiofos (π-l.B-72), Prothoate (II-l.B-73), Pyraclofos (II-l.B-74), Pyridaphenthion (ü-l.B-75), Pyridathion (π-l.B-76), Quin- alphos (II-l.B-77), Sebufos (π-l.B-78), Sulfotep (π-l.B-79), Sulprofos (ü-l.B-80), Tebupirimfos (ü-l.B-81), Temephos (ü-l.B-82), Terbufos (ü-l.B-83), Tetra- chlorvinphos (π-l.B-84), Thiometon (π-l.B-85), Triazophos (II-l.B-86), Triclorfon (II-l .B-87), Vamidothion (D-I . B-88)Pirimiphos (-methyl / -ethyl) (μ-lB-68), profenofos (II-lB-69), propaphos (II-lB-70), propetamphos (II-lB-71), prothiofos (π-lB-72 ), Prothoates (II-lB-73), pyraclofos (II-lB-74), pyridapenthione (μ-lB-75), pyridathione (π-lB-76), quin-alphos (II-lB-77), sebufos (π-lB-78), sulfotep (π-lB-79), sulprofos (--lB-80), tebupirimfos (--lB-81), temephos (--lB-82), terbufos (--lB-) 83), tetrachlorine- phosphine (π-lB-84), thiometone (π-lB-85), triazophos (II-lB-86), Triclophon (II-l .B-87), vamidothione (DI. B-88)
GABA-gesteuerte Chlorid-Kanal-Antagonisten II-2GABA-controlled chloride channel antagonists II-2
II-2A Organochlorine,II-2A organochlorines,
Camphechlor (II-2A-1), Chlordane (II-2A-2), Endosulfan (π-2A-3), Gamma-HCH (II-2A-4), HCH (II-2A-5), Heptachlor (II-2A-6), Lindane (π-2A-7), MethoxychlorCamphechlor (II-2A-1), chlordane (II-2A-2), endosulfan (π-2A-3), gamma-HCH (II-2A-4), HCH (II-2A-5), heptachlor (II -2A-6), lindane (π-2A-7), methoxychlor
(π-2A-8)(Π-2A-8)
II-2B Fiprole (Phenylpyrazole),II-2B fiproles (phenylpyrazoles),
Acetoprole (II-2B-1), Ethiprole (II-2B-2), Fipronil (II-2B-3), Pyrafluprole (II-2B- 4), Pyriprole (II-2B-5), Vaniliprole (II-2B-6)Acetoprole (II-2B-1), ethiprole (II-2B-2), fipronil (II-2B-3), pyrafluprole (II-2B-4), pyriprole (II-2B-5), vaniliprole (II-2B -6)
Natrium-Kanal-Modulatoren / Spannungsabhängige Natrium-Kanal-Blocker II-3Sodium Channel Modulators / Voltage-Dependent Sodium Channel Blocker II-3
II-3 Pyrethroide,II-3 pyrethroids,
Acrinathrin (II-3-1), Allethrin (d-cis-trans, d-trans) (II-3-2), Beta-Cyfluthrin (II-3- 3), Bifenthrin (II-3-4), Bioallethrin (ü-3-5), Bioallethrin-S-cyclopentyl-isomer (II- 3-6), Bioethanomethrin (II-3-7), Biopermethrin (II-3-8), Bioresmethrin (II-3-9), Chlovaporthrin (II-3-10), Cis-Cypermethrin (II-3-1 1), Cis-Resmethrin (II-3-12),Acrinathrin (II-3-1), Allethrin (d-cis-trans, d-trans) (II-3-2), Beta-Cyfluthrin (II-3-3), Bifenthrin (II-3-4), Bioallethrin (ü-3-5), bioallethrin S-cyclopentyl isomer (II-3-6), bioethanomethrin (II-3-7), biopermethrin (II-3-8), bioresmethrin (II-3-9), Chlovaporthrin (II-3-10), cis-cypermethrin (II-3-1 1), cis-resmethrin (II-3-12),
Cis-Permethrin (II-3-13), Clocythrin (II-3-14), Cycloprothrin (ü-3-15), Cyfluthrin (II-3-16), Cyhalothrin (II-3-17), Cypermethrin (alpha-, beta-, theta-, zeta-)(II-3-18), Cyphenothrin (II-3-19), Deltamethrin (II-3-20), Empenthrin (lR-isomer) (II-3-21), Esfenvalerate (II-3-22), Etofenprox (II-3-23), Fenfluthrin (II-3-24), Fenpropathrin (II-3-25), Fenpyrithrin (II-3-26), Fenvalerate (II-3-27), Flubrocythrinate (II-3-28),Cis-permethrin (II-3-13), clocthrin (II-3-14), cycloprothrin (ü-3-15), cyfluthrin (II-3-16), cyhalothrin (II-3-17), cypermethrin (alpha , beta-, theta-, zeta-) (II-3-18), cyphenothrin (II-3-19), deltamethrin (II-3-20), empenthrin (IR-isomer) (II-3-21) , Esfenvalerate (II-3-22), etofenprox (II-3-23), fenfluthrin (II-3-24), fenpropathrin (II-3-25), fenpyrithrin (II-3-26), fenvalerate (II- 3-27), flubrocythrinates (II-3-28),
Flucythrinate (π-3-29), Flufenprox (D-3-30), Flumethrin (II-3-31), Fluvalinate (II- 3-32), Fubfenprox (II-3-33), Gamma-Cyhalothrin (II-3-34), Imiprothrin (D-3-35), Kadethrin (II-3-36), Lambda-Cyhalothrin (II-3-37), Metofluthrin (II-3-38), Permethrin (eis-, trans-) (II-3-39), Phenothrin (lR-trans isomer) (II-3-40), Prallethrin (II-3-41), Profluthrin (II-3-42), Protrifenbute (ü-3-43), Pyresmethrin (II-Flucythrinates (π-3-29), Flufenprox (D-3-30), Flumethrin (II-3-31), Fluvalinates (II-3-32), Fubfenprox (II-3-33), Gamma-Cyhalothrin (II -3-34), imiprothrin (D-3-35), kadethrin (II-3-36), lambda-cyhalothrin (II-3-37), metofluthrin (II-3-38), permethrin (cis-, trans -) (II-3-39), phenothrin (IR trans isomer) (II-3-40), prallethrin (II-3-41), profuthrin (II-3-42), protrifenbute (ü-3-43 ), Pyresmethrin (II-
3-44), Resmethrin (II-3-45), RU 15525 (π-3-46), Silafluofen (II-3-47), Tau- Fluvalinate (II-3-48), Tefluthrin (II-3-49), Terallethrin (π-3-50), Tetramethrin (- IR- isomer) (II-3-51), Tralomethrin (II-3-52), Transfluthrin (II-3-53), ZXI 8901 (II- 3-54), Pyrethrin (pyrethrum) (π-3-55), Eflusilanat (II-3-56), DDT (II-3-57), Methoxychlor (II-3-58),3-44), resmethrin (II-3-45), RU 15525 (π-3-46), silafluofen (II-3-47), tau-fluvalinate (II-3-48), tefluthrin (II-3-47). 49), terallethrin (π-3-50), tetramethrin (- IR isomer) (II-3-51), tralomethrin (II-3-52), transfluthrin (II-3-53), ZXI 8901 (II- 3-54), pyrethrin (pyrethrum) (π-3-55), eflusilanate (II-3-56), DDT (II-3-57), methoxychlor (II-3-58),
Nikotinerge Acetylcholin-Rezeptor-Agonisten/-Antagonisten II-4Nicotinergic acetylcholine receptor agonist / antagonist II-4
II-4A Chloronicotinyle, Acetamiprid (II-4A-1), Clothianidin (II-4A-2), Dinotefuran (II-4A-3), Imidacloprid (II-4A-4), Imidaclothiz (II-4A-5), Nitenpyram (II-4A-6), Nithiazine (π-4A-7), Thiacloprid (II-4A-8), Thiamethoxam (II-4A-9),II-4A chloronicotinyls, Acetamiprid (II-4A-1), clothianidin (II-4A-2), dinotefuran (II-4A-3), imidacloprid (II-4A-4), imidactylizide (II-4A-5), nitenpyram (II-4A -6), nithiazines (π-4A-7), thiacloprid (II-4A-8), thiamethoxam (II-4A-9),
II-4A-10 π-4A-l lII-4A-10 π-4A-1
II-4B Nicotine (II-4B-1), Bensultap (II-4B-2), Cartap (π-4B-3), Thiosulfap-Natrium (II-II-4B Nicotine (II-4B-1), Bensultap (II-4B-2), Cartap (π-4B-3), Thiosulfap Sodium (II-
4B-4), Thiocylam (II-4C-4)4B-4), thiocylam (II-4C-4)
Allosterische Acetylcholin-Rezeptor-Modulatoren (Agonisten)Allosteric acetylcholine receptor modulators (agonists)
II-5 Spinosyne,II-5 Spinosyns,
Spinosad (II-5-1), Spinetoram (II-5-2)Spinosad (II-5-1), Spinetoram (II-5-2)
Chlorid-Kanal-AktivatorenChloride channel activators
II-6 Mectine / Macrolide,II-6 Mectins / Macrolides,
Abamectin (II-6-1), Emamectin (II-6-2), Emamectin-benzoate (II-6-3), Ivermectin (II-6-4), Lepimectin (II-6-5), Milbemectin (II-6-6)Abamectin (II-6-1), Emamectin (II-6-2), Emamectin benzoate (II-6-3), Ivermectin (II-6-4), Lepimectin (II-6-5), Milbemectin (II -6-6)
II-7A Juvenilhormon Analoge, Hydroprene (II-7A-1), Kinoprene (II-7A-2), Methoprene (II-7A-3), EpofenonaneII-7A juvenile hormone analogs, hydroprene (II-7A-1), kinoprenes (II-7A-2), methoprene (II-7A-3), epofenonans
(II-7A-4), Triprene (II-7A-5), Fenoxycarb (II-7B-1),(II-7A-4), triprene (II-7A-5), fenoxycarb (II-7B-1),
Pyriproxifen (II-7C-1), Diofenolan (II-7C-2)Pyriproxifen (II-7C-1), Diofenolane (II-7C-2)
Wirkstoffe mit unbekannten oder nicht spezifischen WirkmechanismenActive substances with unknown or non-specific mechanisms of action
II-8 Begasungsmittel, Methyl bromide (II-8 A- 1 ), Chloropicrin (II-8B- 1 ), Sulfuryl fluoride (II-8C- 1 )II-8 fumigants, methyl bromides (II-8A-1), chloropicrin (II-8B-1), sulfuryl fluorides (II-8C-1)
II-9 Selektive Fraßhemmer,II-9 selective feeding inhibitors,
Cryolite (II-9A-1), Pymetrozine (II-9B-1), NNIOlOl (II-9B-2) , Flonicamid (D-9C- 1) II- 10 Milbenwachstumsinhibitoren,Cryolites (II-9A-1), pymetrozines (II-9B-1), NN10110 (II-9B-2), flonicamide (D-9C-1) II- 10 mite growth inhibitors,
Clofentezine (II- 1 OA-I), Hexythiazox (Ü-10A-2), Etoxazole (II- 1 OB-I)Clofentezine (II-1 OA-I), hexythiazoxy (T-10A-2), etoxazole (II-1 OB-I)
Inhibitoren der oxidativen Phosphorylierung, ATP-Disruptoren 11-12Inhibitors of oxidative phosphorylation, ATP disruptors 11-12
II- 12 A Diafenthiuron (II- 12 A- 1 )II- 12 A Diafenthiuron (II-12 A-1)
II-12B Organozinnverbindungen,II-12B organotin compounds,
Azocyclotin (II-12B-1), Cyhexatin (Ü-12B-2), Fenbutatin-oxide (II-12B-3)Azocyclotine (II-12B-1), cyhexatin (U-12B-2), fenbutatin oxide (II-12B-3)
II-12C Propargite (II-12C-1), Tetradifon (Ü-12C-2)II-12C propargite (II-12C-1), tetradifon (Ü-12C-2)
Entkoppler der oxidativen Phoshorylierung durch Unterbrechung des H-Protongradienten II- 13Decoupling of the oxidative phosphorylation by interruption of the H proton gradient II-13
Chlorfenapyr (π-13-1)Chlorfenapyr (π-13-1)
Binapacyrl (II-13-2), Dinobuton (H-13-3), Dinocap (H-13-4), DNOC (II-13-5)Binapacyrl (II-13-2), dinobutone (H-13-3), dinocap (H-13-4), DNOC (II-13-5)
Mikrobielle Disruptoren der InsektendarmmembranMicrobial disruptors of insect intestinal membrane
Bacillus thuringiensis-Stämme (H-13-6)Bacillus thuringiensis strains (H-13-6)
Inhibitoren der ChitinbiosyntheseInhibitors of chitin biosynthesis
11-15 Benzoylharnstoffe,11-15 benzoylureas,
Bistrifluron (II-15-1), Chlorfluazuron (U-15-2), Diflubenzuron (11-15-3), Fluazuron (II- 15-4), Flucycloxuron (II- 15-5), Flufenoxuron (II- 15-6), Hexaflumuron (II- 15-7), Lufenuron (II- 15-8), Novaluron (II- 15-9), Noviflumuron (11-15-10), Penfluron (II- 15-1 1), Teflubenzuron (π-15-12), Triflumuron (11-15-13)Bistrifluron (II-15-1), chlorofluorazuron (U-15-2), diflubenzuron (11-15-3), fluazuron (II-15-4), flucycloxuron (II-15-5), flufenoxuron (II-15 -6), hexaflumuron (II-15-7), lufenuron (II-15-8), novaluron (II-15-9), noviflumuron (11-15-10), penfluron (II-15-1 1), Teflubenzuron (π-15-12), triflumuron (11-15-13)
II- 16 Buprofezin (II- 16-1)II- 16 Buprofezin (II-16-1)
Häutungsstörende Wirkstoffe Cyromazine (II- 17-1)Moulting Agents Cyromazines (II-17-1)
Ecdysonagonisten/disruptoren (II- 18)Ecdysonagonists / disruptors (II-18)
II-18A Diacylhydrazine,II-18A diacylhydrazines,
Chromafenozide (II-18A-1), Halofenozide (Ü-18A-2), Methoxyfenozide (II- 18 A- 3), Tebufenozide (Ü-18A-4), JS-1 18 (II-18A-5)Chromafenozide (II-18A-1), Halofenozide (Ü-18A-2), Methoxyfenozide (II-18A-3), Tebufenozide (Ü-18A-4), JS-1 18 (II-18A-5)
Azadirachtin (II-18B-l) Oktopaminerge Agonisten Amitraz (II-19-l)Azadirachtin (II-18B-l) Octopaminergic agonist Amitraz (II-19-l)
11-20 Seite-III-Elektronentransportinhibitoren/Seite-II-Elektronentransportinhibitoren11-20 Page III Electron Transport Inhibitors / Page II Electron Transport Inhibitors
Hydramethylnon (Ü-20A-1)Hydramethylnone (T-20A-1)
Acequinocyl (II-20B-l)Acequinocyl (II-20B-1)
Fluacrypyrim (Ü-20C-1)Fluacrypyrim (T-20C-1)
Cyflumetofen (II-20D-1), Cyenopyrafen (II-20D-2)Cyflumetofen (II-20D-1), Cyenopyrafen (II-20D-2)
ElektronentransportinhibitorenElectron transport inhibitors
II-21 Seite-I-ElektronentransportinhibitorenII-21 Side-I Electron Transport Inhibitors
aus der Gruppe der METI-Akarizide,from the group of METI acaricides,
Fenazaquin (II-21-1), Fenpyroximate (11-21 -2), Pyrimidifen (11-21 -3), Pyridaben (π-21-4), Tebufenpyrad (π-21-5), Tolfenpyrad (11-21 -6), Rotenone (11-21 -7)Fenazaquin (II-21-1), fenpyroximate (11-21-2), pyrimidifen (11-21-3), pyridaben (π-21-4), tebufenpyrade (π-21-5), tolfenpyrade (11-21 -6), Rotenone (11-21 -7)
11-22 Spannungsabhängige Natriumkanal-Blocker11-22 Voltage-Dependent Sodium Channel Blockers
Indoxacarb (Ü-22A-1)Indoxacarb (U-22A-1)
Metaflumizone (BAS 3201 ) (II-22B- 1 )Metaflumizone (BAS 3201) (II-22B-1)
11-23 Inhibitoren der Fettsäurebiosynthese11-23 Inhibitors of fatty acid biosynthesis
II-23A Tetronsäure-DerivateII-23A tetronic acid derivatives
Spirodiclofen (Ü-23A-1), Spiromesifen (11-23 A-2)Spirodiclofen (U-23A-1), spiromesifen (11-23 A-2)
II-23B Tetramsäure-Derivate, Spirotetramat (π-23B-1)II-23B tetramic acid derivatives, spirotetramat (π-23B-1)
II-25 Neuronale Inhibitoren mit unbekannten WirkmechanismusII-25 Neuronal inhibitors with unknown mechanism of action
Bifenazate (π-25-l)Bifenazate (π-25-l)
Ryanodinrezeptor-EffektorenRyanodine receptor effectors
11-28 Diamide, Flubendiamide (π-28-l), 11-28 Diamide, Flubendiamide (π-28-l),
(II-28-2)(II-28-2)
Chlorantraniliprole (Rynaxapyr) (II-28-3), CyazypyrChlorantraniliprole (Rynaxapyr) (II-28-3), Cyazypyr
(II-28-4)(II-28-4)
11-29 Wirkstoffe mit unbekanntem Wirkmechanismus11-29 drugs with unknown mechanism of action
Amidoflumet (11-29- 1), Benclothiaz (II-29-2), Benzoximate (II-29-3), Bromopro- pylate (II-29-4), Buprofezin (π-29-5), Chinomethionat (II-29-6), Chlordimeform (II-29-7), Chlorobenzilate (11-29-8), Clothiazoben (II-29-9), Cycloprene (11-29-10), Dicofol (11-29- 1 1), Dicyclanil (11-29-12), Fenoxacrim (11-29-13), Fentrifanil (11-29- 14), Flubenzimine (11-29-15), Flufenerim (11-29-16), Flutenzin (11-29-17), Gossyplure (11-29-18), Japonilure (11-29-19), Metoxadiazone (11-29-20), Petroleum (11-29-21), Potassium oleate (ü-29-22), Pyridalyl (11-29-23), Sulfluramid (11-29- 24), Tetrasul (11-29-25), Triarathene (II-29-26),Verbutin (11-29-27).Amidoflumet (11-29-1), benclothiaz (II-29-2), benzoximate (II-29-3), bromoproparates (II-29-4), buprofezin (π-29-5), quinomethionate (II -29-6), chlorodimeformate (II-29-7), chlorobenzilate (11-29-8), clothiazoben (II-29-9), cycloprene (11-29-10), dicofol (11-29-1 ), Dicyclanil (11-29-12), fenoxacrim (11-29-13), fentrifanil (11-29-14), flubenzimines (11-29-15), flufenerim (11-29-16), flutenzin (11 -29-17), Gossyplure (11-29-18), Japonilure (11-29-19), Metoxadiazone (11-29-20), Petroleum (11-29-21), Potassium oleate (ü-29-22 ), Pyralidyl (11-29-23), sulfluramide (11-29-24), tetrasul (11-29-25), triarathene (II-29-26), verbutin (11-29-27).
(11-29-28) (π-29-29) (11-29-28) (π-29-29)
(π-29-30) (π-29-31)(π-29-30) (π-29-31)
11-30 Mikrobielle Disruptoren der Insektendarmmembran11-30 Insect intestinal membrane microbial disruptors
11-30- 1 Bacillυs thuringiensis-Stämme.11-30- 1 Bacillus thuringiensis strains.
2. Wirkstoffkombinationen gemäß Anspruch 1, enthaltend mindestens eine Verbindung der2. active compound combinations according to claim 1, containing at least one compound of
Formeln (I- 1), (1-2), (1-3), (1-4), (1-5), (1-6).Formulas (I-1), (1-2), (1-3), (1-4), (1-5), (1-6).
3. Verwendung von Wirkstoffkombinationen wie in Anspruch 1 definiert, zur Bekämpfung tierischer Schädlinge.3. Use of active compound combinations as defined in claim 1, for controlling animal pests.
4. Verfahren zur Bekämpfung tierischer Schädlinge, dadurch gekennzeichnet, dass man Wirkstoffkombinationen wie in Anspruch 1 definiert, auf tierische Schädlinge und/oder deren Lebensraum einwirken lässt.4. A method for controlling animal pests, characterized in that one allows drug combinations as defined in claim 1, to act on animal pests and / or their habitat.
5. Verfahren zur Herstellung insektizider und/oder akarizider Mittel, dadurch gekennzeichnet, dass man Wirkstoffkombinationen wie in Anspruch 1 definiert, mit Streckmitteln und/oder oberflächenaktiven Stoffen vermischt.5. A process for the preparation of insecticidal and / or acaricidal agents, characterized in that one mixes active compound combinations as defined in claim 1, with extenders and / or surface-active substances.
6. Mittel enthaltend Wirkstoffkombinationen wie in Anspruch 1 definiert, zur Bekämpfung tierischer Schädlinge. 6. agents containing active compound combinations as defined in claim 1, for controlling animal pests.
EP08785847A 2007-09-21 2008-09-09 Active ingredient combinations having insecticidal and acaricidal properties Withdrawn EP2203062A2 (en)

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