EP2176610B1 - Processus de séparation d'air par distillation cryogénique - Google Patents
Processus de séparation d'air par distillation cryogénique Download PDFInfo
- Publication number
- EP2176610B1 EP2176610B1 EP07785309.1A EP07785309A EP2176610B1 EP 2176610 B1 EP2176610 B1 EP 2176610B1 EP 07785309 A EP07785309 A EP 07785309A EP 2176610 B1 EP2176610 B1 EP 2176610B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- air
- sent
- mode
- compressor
- heat exchange
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
- 238000000034 method Methods 0.000 title claims description 14
- 238000004821 distillation Methods 0.000 title claims description 3
- 238000000926 separation method Methods 0.000 title description 8
- 239000007788 liquid Substances 0.000 claims description 25
- 239000000047 product Substances 0.000 claims description 7
- 239000012467 final product Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 239000012263 liquid product Substances 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
- 239000007789 gas Substances 0.000 description 15
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 238000000746 purification Methods 0.000 description 5
- 230000005611 electricity Effects 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
- F25J3/04163—Hot end purification of the feed air
- F25J3/04169—Hot end purification of the feed air by adsorption of the impurities
- F25J3/04175—Hot end purification of the feed air by adsorption of the impurities at a pressure of substantially more than the highest pressure column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04048—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of cold gaseous streams, e.g. intermediate or oxygen enriched (waste) streams
- F25J3/04054—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of cold gaseous streams, e.g. intermediate or oxygen enriched (waste) streams of air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04078—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
- F25J3/0409—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
- F25J3/04187—Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
- F25J3/04296—Claude expansion, i.e. expanded into the main or high pressure column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04375—Details relating to the work expansion, e.g. process parameter etc.
- F25J3/04393—Details relating to the work expansion, e.g. process parameter etc. using multiple or multistage gas work expansion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04406—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
- F25J3/04412—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04763—Start-up or control of the process; Details of the apparatus used
- F25J3/04769—Operation, control and regulation of the process; Instrumentation within the process
- F25J3/04812—Different modes, i.e. "runs" of operation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/40—Air or oxygen enriched air, i.e. generally less than 30mol% of O2
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/40—Processes or apparatus involving steps for recycling of process streams the recycled stream being air
Definitions
- the present invention relates to a process for the separation of air by cryogenic distillation.
- the present invention allows the apparatus to function with optimal power consumption during both modes of operation.
- the air separation unit includes an air separation column system which may be of any known type, but may particularly be a double column system including a high pressure column and a low pressure column, thermally coupled via a reboiler condenser at the bottom of the low pressure column wherein nitrogen from the top of the high pressure column is condensed.
- an air separation column system which may be of any known type, but may particularly be a double column system including a high pressure column and a low pressure column, thermally coupled via a reboiler condenser at the bottom of the low pressure column wherein nitrogen from the top of the high pressure column is condensed.
- US 2006/010912 A1 describes an air separation process in which in all modes of operation, compressed and purified gaseous air is cooled in a heat exchange line and sent to at least one column of a column system, a liquid stream enriched in a component of air is removed from a column of the column system and vaporised in the heat exchange line, air at an elevated pressure is sent to the heat exchange line, condensed and sent to the column system.
- Part of the feed air can be sent to one of at least two expanders and thence to a column of the column system.
- a first mode, called peak period no air is sent to a second compressor but air is sent to a cold compressor and then liquefied. No refrigeration is produced using the air expanders.
- a second mode called off-peak period
- only a part of the air is sent to the second compressor to be compressed to a pressure higher than the highest column pressure of the column system and no air is sent to the cold compressor, whilst refrigeration is produced using two air expanders.
- the process can produce more liquid as final product than during the first mode. It is not clear how the production of liquid for consumption outside the air separation unit varies during the two modes and the second compressor outlet pressure is not given.
- Figures 1 , 2 and 3 show air flow diagrams for an air separation unit according to the invention.
- the dashed lines indicate couplings between a compressor and a turbine.
- FIG. 1 uses a double column system in which a high pressure column 65 is placed underneath a low pressure column 67 and thermally coupled thereto via a reboiler condenser 69.
- cooled, purified and compressed gaseous air is fed to the high pressure column 65.
- Reflux streams (not shown) are sent from the high pressure column to the low pressure column 67 as is well known in the art.
- gaseous nitrogen 61 is removed from the top of the low pressure column 67 and warmed in exchanger 19 whilst waste nitrogen 59 is removed from lower down the low pressure column 67 and warmed in exchanger 19 before being used to regenerate the purification unit 8.
- liquid oxygen is removed from the bottom of the low pressure column 57 and pressurised as stream 55 in pump 57 before being vaporised in the heat exchanger 19 to form product high pressure gaseous oxygen (HP GOX).
- liquid oxygen LOX 53 and liquid nitrogen LIN 71 are removed from the low pressure.
- liquid oxygen is removed from the bottom of the low pressure column 67 and pressurised as stream 55 in pump 57 before being vaporised in the heat exchanger 19 to form product high pressure gaseous oxygen (HP GOX).
- the cooling section 43 receives air at 47 bars which is then cooled by passing through the whole heat exchange line during the liquid mode and receives air at 26 bars coming from the cold compressor 37 during the gas mode.
- section 23 sees a reversal of flow between the two modes, air flowing in one direction from the heat exchange line 19 to the turbine 29 in liquid mode and in the other direction from the cold compressor 37 to the heat exchange line 19 in gas mode.
- the nitrogen 61 is compressed to a higher pressure in compressor 63.
- liquid oxygen is removed from the bottom of the low pressure column 57 and pressurised as stream 55 in pump 57 before being vaporised in the heat exchanger 19 to form product high pressure gaseous oxygen (HP GOX).
- liquid oxygen LOX 53 and liquid nitrogen LIN 71 are removed from the low pressure.
- liquid oxygen is removed from the bottom of the low pressure column 67 and pressurised as stream 55 in pump 57 before being vaporised in the heat exchanger 19 to form product high pressure gaseous oxygen (HP GOX).
- the cooling section 43 receives air which is then cooled by passing through the whole heat exchange line during the liquid mode and receives air at 26 bars coming from the cold compressor 37 during the gas mode.
- section 23 sees a reversal of flow between the two modes, air flowing in one direction from the heat exchange line 19 to the turbine 29 in liquid mode and in the other direction from the cold compressor 37 to the heat exchange line 19 in gas mode.
- the nitrogen 61 is compressed to a higher pressure in compressor 63.
- FIG. 3 may use a double column system as shown and described for Figure 1 , in which a high pressure column 65 is placed underneath a low pressure column 67 and thermally coupled thereto via a reboiler condenser 69.
- liquid oxygen is removed from the bottom of the low pressure column 57 and pressurised as stream 55 in pump 57 before being vaporised in the heat exchanger 19 to form product high pressure gaseous oxygen (HP GOX).
- the cooling section 43 receives air at 47 bars which is then cooled by passing through the whole heat exchange line during the liquid mode and receives air at 26 bars coming from the cold compressor 37 during the gas mode.
- section 23 sees a reversal of flow between the two modes, air flowing in one direction from the heat exchange line 19 to the turbine 29 in liquid mode and in the other direction from the cold compressor 37 to the heat exchange line 19 in gas mode.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Separation By Low-Temperature Treatments (AREA)
Claims (7)
- Procédé de production d'au moins un produit liquide (53) et d'au moins un produit gazeux (55, 61) par distillation cryogénique d'air dans un premier mode opératoire et dans un second mode opératoire, le procédé produisant plus de liquide comme produit final au cours du second mode qu'au cours du premier mode, dans lequel, dans tous les modes opératoires, de l'air gazeux comprimé et purifié est refroidi dans une ligne d'échange thermique (19) et envoyé à au moins une colonne d'un système colonnaire (65, 67), un courant de liquide (55) enrichi en un composant de l'air est retiré d'une colonne du système colonnaire et vaporisé dans la ligne d'échange thermique, de l'air (3) sous pression élevée est envoyé à la ligne d'échange thermique, condensé et envoyé au système colonnaire et une partie de l'air comprimé et purifié est envoyée à l'un d'au moins deux dispositifs expanseurs (29, 39) et, de là, à une colonne du système colonnaire, dans lequel :a) selon le premier mode, au moins une partie (7) de l'air comprimé et purifié est retirée d'un point intermédiaire de la ligne d'échange thermique, comprimée à une température cryogénique dans un compresseur froid (37) et envoyée à la ligne d'échange thermique pour être encore refroidie et envoyée au système colonnaire et une partie de l'air d'alimentation est envoyée au premier dispositif expanseur (39), aucun air n'étant envoyé à un second compresseur (11, 12, 17) etb) selon le second mode, la totalité de l'air comprimé et purifié (5) est comprimée à une pression élevée d'au moins 20 bars supérieure à la pression colonnaire la plus élevée du système colonnaire dans le second compresseur (11, 12, 17), refroidie dans la ligne d'échange thermique et envoyée en partie à un système colonnaire, une autre partie de l'air sous pression élevée étant envoyée au second dispositif expanseur (29), aucun air n'étant envoyé au compresseur froid.
- Procédé selon la revendication 1, dans lequel, selon le premier mode, une partie de l'air à la pression de sortie du compresseur froid est refroidie et envoyée au premier dispositif expanseur (39).
- Procédé selon la revendication 1 ou 2, dans lequel le compresseur froid (37) est couplé au premier dispositif expanseur (39).
- Procédé selon la revendication 1, 2 ou 3, dans lequel le second compresseur (11, 12, 17) est couplé au second expanseur (29).
- Procédé selon l'une quelconque des revendications précédentes, dans lequel l'air traité dans le second compresseur (11, 12, 17) dans le second mode et dans le compresseur froid (37) dans le premier mode est ensuite envoyé à un moyen de transfert commun (23) en amont du système colonnaire.
- Procédé selon la revendication 5, dans lequel, dans le premier mode, l'air est envoyé du compresseur froid (37) à la ligne d'échange thermique (19) via un conduit (23) et, dans le second mode, l'air est envoyé du second compresseur (11, 12, 17) au second dispositif expanseur (29) via le même conduit.
- Procédé selon la revendication 5, dans lequel, dans le premier mode, l'air est envoyé du compresseur froid (37) via un passage de la ligne d'échange thermique (19) à son extrémité froide et, dans le second mode, l'air est envoyé du second compresseur (11, 12, 17) à l'extrémité froide de la ligne d'échange thermique via le même passage.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CN2007/002404 WO2009021350A1 (fr) | 2007-08-10 | 2007-08-10 | Processus et appareil de séparation d'air par distillation cryogénique |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2176610A1 EP2176610A1 (fr) | 2010-04-21 |
EP2176610A4 EP2176610A4 (fr) | 2018-03-21 |
EP2176610B1 true EP2176610B1 (fr) | 2019-04-24 |
Family
ID=40350332
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07785309.1A Not-in-force EP2176610B1 (fr) | 2007-08-10 | 2007-08-10 | Processus de séparation d'air par distillation cryogénique |
Country Status (7)
Country | Link |
---|---|
US (1) | US20110197630A1 (fr) |
EP (1) | EP2176610B1 (fr) |
JP (1) | JP4908634B2 (fr) |
CN (1) | CN101779092A (fr) |
BR (1) | BRPI0721931A2 (fr) |
CA (1) | CA2695817A1 (fr) |
WO (1) | WO2009021350A1 (fr) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2948184B1 (fr) | 2009-07-20 | 2016-04-15 | Air Liquide | Procede et appareil de separation d'air par distillation cryogenique |
FR2973487B1 (fr) * | 2011-03-31 | 2018-01-26 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede et appareil de production d'un gaz de l'air sous pression par distillation cryogenique |
FR2973486B1 (fr) * | 2011-03-31 | 2013-05-03 | Air Liquide | Procede de separation d'air par distillation cryogenique |
FR2983287B1 (fr) * | 2011-11-25 | 2018-03-02 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede et installation de separation d'air par distillation cryogenique |
TR201808162T4 (tr) * | 2014-07-05 | 2018-07-23 | Linde Ag | Havanın düşük sıcaklıkta ayrıştırılması vasıtasıyla bir basınçlı gaz ürününün kazanılmasına yönelik yöntem ve cihaz. |
PL2963370T3 (pl) * | 2014-07-05 | 2018-11-30 | Linde Aktiengesellschaft | Sposób i urządzenie do kriogenicznego rozdziału powietrza |
US11384288B2 (en) | 2019-03-20 | 2022-07-12 | Carbon Holdings Intellectual Properties, Llc | Using stimulus to convert coal to mesophase pitch and carbon fibers |
WO2020191407A1 (fr) | 2019-03-21 | 2020-09-24 | Carbon Holdings Intellectual Properties, Llc | Processus à co2 supercritique solvaté pour convertir du charbon en fibres de carbone |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2736543B2 (ja) * | 1989-04-17 | 1998-04-02 | 日本酸素株式会社 | 空気液化分離方法 |
FR2700205B1 (fr) * | 1993-01-05 | 1995-02-10 | Air Liquide | Procédé et installation de production d'au moins un produit gazeux sous pression et d'au moins un liquide par distillation d'air. |
FR2703140B1 (fr) * | 1993-03-23 | 1995-05-19 | Air Liquide | Procédé et installation de production d'oxygène gazeux et/ou d'azote gazeux sous pression par distillation de l'air. |
US5355681A (en) * | 1993-09-23 | 1994-10-18 | Air Products And Chemicals, Inc. | Air separation schemes for oxygen and nitrogen coproduction as gas and/or liquid products |
US5475980A (en) * | 1993-12-30 | 1995-12-19 | L'air Liquide, Societe Anonyme Pour L'etude L'exploitation Des Procedes Georges Claude | Process and installation for production of high pressure gaseous fluid |
FR2721383B1 (fr) * | 1994-06-20 | 1996-07-19 | Maurice Grenier | Procédé et installation de production d'oxygène gazeux sous pression. |
GB9515907D0 (en) * | 1995-08-03 | 1995-10-04 | Boc Group Plc | Air separation |
US5907959A (en) * | 1998-01-22 | 1999-06-01 | Air Products And Chemicals, Inc. | Air separation process using warm and cold expanders |
FR2851330B1 (fr) * | 2003-02-13 | 2006-01-06 | Air Liquide | Procede et installation de production sous forme gazeuse et sous haute pression d'au moins un fluide choisi parmi l'oxygene, l'argon et l'azote par distillation cryogenique de l'air |
FR2854682B1 (fr) * | 2003-05-05 | 2005-06-17 | Air Liquide | Procede et installation de separation d'air par distillation cryogenique |
FR2854683B1 (fr) * | 2003-05-05 | 2006-09-29 | Air Liquide | Procede et installation de production de gaz de l'air sous pression par distillation cryogenique d'air |
US6962062B2 (en) * | 2003-12-10 | 2005-11-08 | L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Proédés Georges Claude | Process and apparatus for the separation of air by cryogenic distillation |
FR2864214B1 (fr) * | 2003-12-22 | 2017-04-21 | Air Liquide | Appareil de separation d'air, appareil integre de separation d'air et de production d'un metal et procede de demarrage d'un tel appareil de separation d'air |
US7272954B2 (en) * | 2004-07-14 | 2007-09-25 | L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Proceded Georges Claude | Low temperature air separation process for producing pressurized gaseous product |
FR2913759B1 (fr) * | 2007-03-13 | 2013-08-16 | Air Liquide | Procede et appareil de production de gaz de l'air sous forme gazeuse et liquide a haute flexibilite par distillation cryogenique. |
-
2007
- 2007-08-10 EP EP07785309.1A patent/EP2176610B1/fr not_active Not-in-force
- 2007-08-10 WO PCT/CN2007/002404 patent/WO2009021350A1/fr active Application Filing
- 2007-08-10 US US12/671,927 patent/US20110197630A1/en not_active Abandoned
- 2007-08-10 CA CA2695817A patent/CA2695817A1/fr not_active Abandoned
- 2007-08-10 CN CN200780100211A patent/CN101779092A/zh active Pending
- 2007-08-10 JP JP2010519320A patent/JP4908634B2/ja not_active Expired - Fee Related
- 2007-08-10 BR BRPI0721931-8A patent/BRPI0721931A2/pt not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
None * |
Also Published As
Publication number | Publication date |
---|---|
US20110197630A1 (en) | 2011-08-18 |
BRPI0721931A2 (pt) | 2014-03-18 |
EP2176610A4 (fr) | 2018-03-21 |
JP2010536003A (ja) | 2010-11-25 |
JP4908634B2 (ja) | 2012-04-04 |
WO2009021350A1 (fr) | 2009-02-19 |
CA2695817A1 (fr) | 2009-02-19 |
CN101779092A (zh) | 2010-07-14 |
EP2176610A1 (fr) | 2010-04-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2176610B1 (fr) | Processus de séparation d'air par distillation cryogénique | |
KR100192874B1 (ko) | 공기 분리 | |
CN102652247B (zh) | 用于通过低温蒸馏分离空气的方法和单元 | |
EP2634517B1 (fr) | Procédé et appareil pour la séparation d'air par distillation cryogénique | |
EP3374713B1 (fr) | Procédé et système d'apport de réfrigération supplémentaire à une installation de séparation d'air | |
JP2009516149A (ja) | 深冷蒸留によって空気を分離する方法および装置 | |
EP1999422B1 (fr) | Système de séparation cryogénique d'air | |
CN102901322B (zh) | 通过低温空气分离获得压力氮和压力氧的方法和装置 | |
AU782163B2 (en) | Process and apparatus for separating a gas mixture with emergency operation | |
CN105378411A (zh) | 生产至少一种空气产品的方法、空分设备、产生电能的方法和装置 | |
EP1726900A1 (fr) | Procédé et installation pour la séparation cryogénique d'air | |
US7114352B2 (en) | Cryogenic air separation system for producing elevated pressure nitrogen | |
CN105765329A (zh) | 通过低温蒸馏分离空气的方法和装置 | |
CN216115003U (zh) | 一种制取低压低纯氧和中压氮的小型空分装置 | |
US5901577A (en) | Process and plant for air separation by cryogenic distillation | |
CN104620067A (zh) | 用于通过低温蒸馏分离空气的方法和设备 | |
EP3405726A1 (fr) | Procédé et système d'apport de réfrigération auxiliaire à une installation de séparation d'air | |
JP2005505740A (ja) | 極低温蒸留による空気の分離方法及びそのための装置 | |
CN114017990B (zh) | 一种制取低压低纯氧和中压氮的小型空分装置 | |
EP4163576A1 (fr) | Appareil et procédé de séparation d'air par distillation cryogénique | |
WO2012155318A1 (fr) | Procédé et appareil de production d'oxygène à haute pression par distillation cryogénique | |
CN109642771B (zh) | 操作空气分离装置的方法和设备 | |
WO2021016756A1 (fr) | Procédé et appareil de séparation de l'air par distillation cryogénique | |
RU2428641C1 (ru) | Способ и установка для разделения воздуха путем криогенной дистилляции | |
CN116538763A (zh) | 空分设备及空分方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20100310 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL BA HR MK RS |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: GUILLARD, ALAIN Inventor name: JAOUANI, LASAD Inventor name: PONTONE, XAVIER |
|
DAX | Request for extension of the european patent (deleted) | ||
RA4 | Supplementary search report drawn up and despatched (corrected) |
Effective date: 20180215 |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: F25J 3/04 20060101AFI20180210BHEP |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20181127 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1124631 Country of ref document: AT Kind code of ref document: T Effective date: 20190515 Ref country code: IE Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602007058190 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20190424 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190824 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20190822 Year of fee payment: 13 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190725 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190724 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 1124631 Country of ref document: AT Kind code of ref document: T Effective date: 20190424 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190824 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602007058190 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 |
|
26N | No opposition filed |
Effective date: 20200127 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190831 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190831 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190810 Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20190831 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190831 Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190810 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190831 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 602007058190 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210302 Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20070810 Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190424 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20220822 Year of fee payment: 16 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20230810 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230810 |