EP2167617A1 - Process to produce a methane rich gas mixture from gasification derived sulphur containing synthesis gases - Google Patents
Process to produce a methane rich gas mixture from gasification derived sulphur containing synthesis gasesInfo
- Publication number
- EP2167617A1 EP2167617A1 EP08773866A EP08773866A EP2167617A1 EP 2167617 A1 EP2167617 A1 EP 2167617A1 EP 08773866 A EP08773866 A EP 08773866A EP 08773866 A EP08773866 A EP 08773866A EP 2167617 A1 EP2167617 A1 EP 2167617A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- gas
- hydrogen
- product gas
- methane
- bringing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
- C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including a sorption process as the refining step in the absence of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/14—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including at least two different refining steps in the absence of hydrogen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/08—Production of synthetic natural gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
- C10L3/102—Removal of contaminants of acid contaminants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1656—Conversion of synthesis gas to chemicals
- C10J2300/1665—Conversion of synthesis gas to chemicals to alcohols, e.g. methanol or ethanol
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
Definitions
- the present invention relates to a method for converting coal or biomass to at least almost sulfur-free substitute natural gas. Further, the invention relates to a process to produce a methane rich gas mixture from gasification derived sulphur containing synthesis gases.
- the present invention relates to a continuous production process of synthetic natural gas (SNG) from biomass, coal or naphta. More specifically, the present invention relates to the production of clean gaseous heating fuels from these less valuable sulphur containing hydrocarbonaceous materials.
- SNG synthetic natural gas
- SNG chemical vapor deposition
- the production of SNG from biomass is the conversion of a "dirty/difficult" fuel into a clean burning well known commodity.
- the costumer has the freedom to use the SNG for power generation, heating or mobility.
- a big plus is the already existing infrastructure such as pipelines and compressed natural gas (NG) cars.
- NG natural gas
- the conversion of biomass to SNG is a complex process, which can be structured roughly into four main units; gasification, raw gas cleaning, fuel synthesis and gas sweetening.
- a solid feed is thermally converted to a raw gas and subsequently cleaned of particles, tars and sulphur.
- the raw gas is converted into raw SNG (a CH4/CO2 mixture) that is cleaned from CO 2 and optionally H 2 (gas sweetening) before injection into the natural gas grid.
- H 2 S, COS or organic sulphur species depending on the temperature of the gasification.
- Low temperature (LT) gasification promotes the formation of organic sulphur species such like thiophenes, mercaptanes and thio-ethers
- HT high temperature
- LT-gasification is advantageous (higher overall cold-gas efficiency) , as the raw gas contains already substantial amounts of CH 4 .
- Drawbacks of this kind of raw gas are the high amount of poisonous components, such as alkenes, alkynes, H 2 S, COS, organic S-species, HCN, NH 3 , organic N-species.
- FIG. 1a An example of a state of the art to produce synthesis gas for applications such as Fischer-Tropsch-Synthesis or production of Methanol, DME, and SNG is shown in figure Ia.
- a scrubber at low temperatures is used to remove the tars and the organic S-species and N-species.
- H 2 S, COS are absorbed on solid absorbers available for this duty (active carbon, ZnO or other metal oxides...) .
- the gas cleaning is followed by a Water-Gas-Shift reactor, C0 2 -seperation and multiple methanation units. To increase the calorific value of the gas to the quality limits of the gas grid, CO 2 and H 2 is removed. The order of units 4-9 can be different.
- the energetic effort in the gasification unit is higher for the production of pure H 2 , CO, CO 2 -mixtures;
- the pure H 2 , CO, CO 2 -mixtures result in higher thermal losses in the synthesis due to the exothermic enthalpy of the methanation reaction.
- a methane-rich stream can be produced from sulphur containing feedstocks containing 10 to 95 mol% of methane.
- the first step following the Low-Temperature-gasification is a multifunctional process unit featuring hydrodesulphurization/denitrogenation, methanation, WGS, tar reforming and cracking and the hydrogenation/reforming of alkenes and alkynes simultaneously.
- the H 2 S produced from the organic sulphur species by hydrolysis and the COS are removed by absorption on common absorber materials such like ZnO, CuO.
- CO 2 can be removed before or after the 2 nd methanation step. For the adjustment of the calorific value excess H 2 is separated and may be recycled to unit 2.
- the hydrodesulphurization unit is a common process step for the desulphurisation of feedstocks in the petrochemical industry or of natural gas before steam reforming.
- the applied catalysts for these units tend to catalyse both methanation and watergas shift reaction which is unwanted as these exothermic reactions may lead to a thermal runaway of the reactor. In the subject process, however, the methanation and WGS-reactions are desired.
- a fluidised bed reactor equipped with means for heat removal can be applied.
- the catalyst fluidisation offers additionally the potential for internal regeneration of the catalyst from carbon deposits caused by compounds like ethylene or tars in the LT-gasifier producer gas.
- Such an internal regeneration can be found for fluidised bed methanation and can be enhanced by staged addition of recycle H 2 and /or steam in the upper part of the fluidised bed.
- the raw gas stream leaving the unit can be tailored to the requirements of a 2 nd methanation unit to minimise the total number of process units by the addition of steam, H 2 from the recycle and the proper choice of temperature and pressure. alkenes and alkynes simultaneously.
- H 2 S produced from the organic sulphur species by hydrolysis and the COS are removed by absorption on common absorber materials such like ZnO, CuO.
- CO 2 can be removed before or after the 2 nd methanation step. For the adjustment of the calorific value excess H 2 is separated and may be recycled to unit 2.
- the hydrodesulphurization unit is a common process step for the desulphurisation of feedstocks in the petrochemical industry or of natural gas before steam reforming.
- the applied catalysts for these units tend to catalyse both methanation and watergas shift reaction which is unwanted as these exothermic reactions may lead to a thermal runaway of the reactor. In the subject process, however, the methanation and WGS-reactions are desired.
- a fluidised bed reactor equipped with means for heat removal can be applied.
- the catalyst fluidisation offers additionally the potential for internal regeneration of the catalyst from carbon deposits caused by compounds like ethylene or tars in the LT-gasifier producer gas. Such an internal regeneration can be found for fluidised bed methanation and can be enhanced by staged addition of recycle H 2 and /or steam in the upper part of the fluidised bed.
- the raw gas stream leaving the unit can be tailored to the requirements of a 2 nd methanation unit to minimise the total number of process units by the addition of steam, H 2 from the recycle and the proper choice of temperature and pressure.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Industrial Gases (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08773866A EP2167617A1 (en) | 2007-07-10 | 2008-07-03 | Process to produce a methane rich gas mixture from gasification derived sulphur containing synthesis gases |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07013482 | 2007-07-10 | ||
EP08773866A EP2167617A1 (en) | 2007-07-10 | 2008-07-03 | Process to produce a methane rich gas mixture from gasification derived sulphur containing synthesis gases |
PCT/EP2008/005464 WO2009007061A1 (en) | 2007-07-10 | 2008-07-03 | Process to produce a methane rich gas mixture from gasification derived sulphur containing synthesis gases |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2167617A1 true EP2167617A1 (en) | 2010-03-31 |
Family
ID=39745214
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08773866A Ceased EP2167617A1 (en) | 2007-07-10 | 2008-07-03 | Process to produce a methane rich gas mixture from gasification derived sulphur containing synthesis gases |
Country Status (5)
Country | Link |
---|---|
US (1) | US20100205863A1 (en) |
EP (1) | EP2167617A1 (en) |
CN (1) | CN101802146A (en) |
CA (1) | CA2693459A1 (en) |
WO (1) | WO2009007061A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2684856A1 (en) | 2012-07-09 | 2014-01-15 | Paul Scherrer Institut | A method for methanation of gasification derived producer gas on metal catalysts in the presence of sulfur |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL2002756C2 (en) | 2009-04-16 | 2010-10-19 | Stichting Energie | METHOD AND SYSTEM FOR MANUFACTURING A FLAMMABLE GAS FROM A FUEL |
WO2011060539A1 (en) * | 2009-11-18 | 2011-05-26 | G4 Insights Inc. | Method and system for biomass hydrogasification |
CA2781204C (en) | 2009-11-18 | 2018-05-01 | G4 Insights Inc. | Sorption enhanced methanation of biomass |
DE102009059310A1 (en) * | 2009-12-23 | 2011-06-30 | Solar Fuel GmbH, 70565 | Highly efficient process for the catalytic methanation of gas mixtures containing carbon dioxide and hydrogen |
CN102250658A (en) * | 2010-05-19 | 2011-11-23 | 上海标氢气体技术有限公司 | Method for preparing liquefied natural gas by converting raw materials of coke oven gas and blast furnace gas |
US8735515B2 (en) | 2010-08-19 | 2014-05-27 | Fina Technology, Inc. | “Green” plastic materials and methods of manufacturing the same |
JP5873496B2 (en) * | 2010-09-13 | 2016-03-01 | ルーマス・テクノロジー・インコーポレーテツド | Low temperature sulfur tolerant tar removal associated with syngas conditioning |
KR20130099100A (en) | 2010-09-13 | 2013-09-05 | 필립스 66 컴퍼니 | Low temperature sulfur tolerant tar and sulfur removal with contomitant synthesis gas conditioning |
US8715616B2 (en) | 2011-02-11 | 2014-05-06 | Phillips 66 Company | Soak and coke |
WO2012142084A1 (en) | 2011-04-11 | 2012-10-18 | ADA-ES, Inc. | Fluidized bed method and system for gas component capture |
FR2982857B1 (en) | 2011-11-21 | 2014-02-14 | Gdf Suez | PROCESS FOR PRODUCING BIOMETHANE |
US8945373B2 (en) | 2011-12-22 | 2015-02-03 | Iogen Corporation | Method for producing renewable fuels |
US8658026B2 (en) | 2011-12-22 | 2014-02-25 | Iogen Corporation | Method for producing fuel with renewable content having reduced lifecycle greenhouse gas emissions |
DE102012013000A1 (en) | 2012-06-28 | 2014-01-02 | Linde Aktiengesellschaft | Producing hydrogen from biomass, comprises e.g. compacting biomass mash, preheating it, hydrolyzing mash, gasifying hydrolyzed mash in supercritical water using catalyst, preferably monolith catalyst, and cooling obtained product gas stream |
IN2015DN02082A (en) | 2012-09-20 | 2015-08-14 | Ada Es Inc | |
DE102012218526A1 (en) * | 2012-10-11 | 2014-04-17 | Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg | Method and device for producing a methane-containing natural gas substitute and associated energy supply system |
CN104232194B (en) * | 2013-06-07 | 2017-06-06 | 中国海洋石油总公司 | A kind of method that methane coproduction liquid fuel is produced by carbonaceous material |
GB201313402D0 (en) * | 2013-07-26 | 2013-09-11 | Advanced Plasma Power Ltd | Process for producing a substitute natural gas |
CN104152199B (en) * | 2014-08-19 | 2017-01-25 | 赛鼎工程有限公司 | Technology for preparing natural gas through sulfur resistant methanation by coal-prepared synthesis gases |
WO2016200719A1 (en) * | 2015-06-08 | 2016-12-15 | Shell Oil Company | Palladium coated metals as hydrogen acceptors for the aromatization of a methane containing gas stream |
FR3050206B1 (en) | 2016-04-15 | 2018-05-11 | Engie | HYDROGENATION DEVICE AND METHOD FOR PRODUCING METHANOL AND DEVICE AND METHOD FOR COGENERATION OF METHANOL AND SYNTHETIC METHANE |
CN106281519B (en) * | 2016-10-21 | 2021-09-14 | 山西高碳能源低碳化利用研究设计院有限公司 | Coke oven gas methanation device with membrane separator and method |
FR3112537B1 (en) | 2020-07-14 | 2023-03-31 | Engie | DEVICE AND METHOD FOR THE HYBRID PRODUCTION OF SYNTHETIC DIHYDROGEN AND/OR SYNTHETIC METHANE |
CA3214940A1 (en) | 2021-04-15 | 2022-10-20 | Iogen Corporation | Process and system for producing low carbon intensity renewable hydrogen |
EP4326671A1 (en) | 2021-04-22 | 2024-02-28 | Iogen Corporation | Process and system for producing fuel |
US11807530B2 (en) | 2022-04-11 | 2023-11-07 | Iogen Corporation | Method for making low carbon intensity hydrogen |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3771261A (en) * | 1971-08-16 | 1973-11-13 | Pullman Inc | Process for making fuel gas |
US4046523A (en) * | 1974-10-07 | 1977-09-06 | Exxon Research And Engineering Company | Synthesis gas production |
US4177202A (en) * | 1977-03-07 | 1979-12-04 | Mobil Oil Corporation | Methanation of synthesis gas |
DE2816035C2 (en) * | 1978-04-13 | 1982-08-12 | Süd-Chemie AG, 8000 München | Fluidized bed catalyst for the production of synthetic natural gas by CO methanation |
US4208191A (en) * | 1978-05-30 | 1980-06-17 | The Lummus Company | Production of pipeline gas from coal |
US4540681A (en) * | 1980-08-18 | 1985-09-10 | United Catalysts, Inc. | Catalyst for the methanation of carbon monoxide in sour gas |
GB2154600A (en) * | 1984-02-23 | 1985-09-11 | British Gas Corp | Producing and purifying methane |
CN1960954B (en) * | 2004-02-12 | 2011-03-23 | 保罗·谢勒学院 | A process for the synthetic generation of methane |
FR2866871B1 (en) * | 2004-02-26 | 2007-01-19 | Rhodia Chimie Sa | COMPOSITION BASED ON ZIRCONIUM, PRASEODYM, LANTHAN OR NEODYME OXIDES, PREPARATION METHOD AND USE IN A CATALYTIC SYSTEM |
US7714547B2 (en) * | 2008-08-08 | 2010-05-11 | Semtech Corporation | Method and apparatus for constant on-time switch mode converters |
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2008
- 2008-07-03 EP EP08773866A patent/EP2167617A1/en not_active Ceased
- 2008-07-03 CA CA2693459A patent/CA2693459A1/en not_active Abandoned
- 2008-07-03 WO PCT/EP2008/005464 patent/WO2009007061A1/en active Application Filing
- 2008-07-03 CN CN200880106240.2A patent/CN101802146A/en active Pending
- 2008-07-03 US US12/668,577 patent/US20100205863A1/en not_active Abandoned
Non-Patent Citations (1)
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2684856A1 (en) | 2012-07-09 | 2014-01-15 | Paul Scherrer Institut | A method for methanation of gasification derived producer gas on metal catalysts in the presence of sulfur |
WO2014009146A1 (en) | 2012-07-09 | 2014-01-16 | Paul Scherrer Institut | A method for methanation of gasification derived producer gas on metal catalysts in the presence of sulfur |
Also Published As
Publication number | Publication date |
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CN101802146A (en) | 2010-08-11 |
WO2009007061A1 (en) | 2009-01-15 |
US20100205863A1 (en) | 2010-08-19 |
CA2693459A1 (en) | 2009-01-15 |
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