EP2098611B1 - Layered coated cutting tool - Google Patents
Layered coated cutting tool Download PDFInfo
- Publication number
- EP2098611B1 EP2098611B1 EP09003006A EP09003006A EP2098611B1 EP 2098611 B1 EP2098611 B1 EP 2098611B1 EP 09003006 A EP09003006 A EP 09003006A EP 09003006 A EP09003006 A EP 09003006A EP 2098611 B1 EP2098611 B1 EP 2098611B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- cutting tool
- layers
- tool insert
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/0641—Nitrides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T407/00—Cutters, for shaping
- Y10T407/23—Cutters, for shaping including tool having plural alternatively usable cutting edges
- Y10T407/235—Cutters, for shaping including tool having plural alternatively usable cutting edges with integral chip breaker, guide or deflector
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T407/00—Cutters, for shaping
- Y10T407/27—Cutters, for shaping comprising tool of specific chemical composition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T409/00—Gear cutting, milling, or planing
- Y10T409/30—Milling
- Y10T409/303752—Process
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T409/00—Gear cutting, milling, or planing
- Y10T409/30—Milling
- Y10T409/303752—Process
- Y10T409/303808—Process including infeeding
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
- Y10T428/24975—No layer or component greater than 5 mils thick
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
Definitions
- the present invention relates to a tool for machining by chip removal comprising a body of a hard alloy of cemented carbide, cermet, ceramics, cubic boron nitride based material or high speed steel and a coating comprising laminar, cubic structured MeN where Me is one or more of the metal elements Ti, Nb, Hf, V, Ta, Zr, Cr, Al, stabilizing the cubic phases of (Ti,Al)N and (Ti,Si)N.
- the coating is particularly useful in metal cutting applications generating high temperatures, such as machining of super alloys and stainless steel.
- the coating is grown by physical vapour deposition (PVD) and preferably by cathodic arc evaporation.
- TiN has been widely used as hard layer on cutting tools, but the poor oxidation resistance at temperatures above 500 °C has created an interest in ternary or quaternary compounds, e.g. Ti-Al-N and Ti-Cr-Al-N. More complex quaternaries, e.g., Ti-Al-Si-N have been reported and described as super hard H>45 GPa due to a two phase structure consisting of crystalline phase of NaCl-type in combination with amorphous Si 3 N 4 or SiN x . These coating materials show an improved oxidation re-, sistance and improved performance in machining of hardened steels.
- EP 1736565 , WO 2006/118513 and EP 0588350 disclose hard coatings comprising (Ti,Si)N layers.
- Coating optimization has also been obtained by applying different concepts of multilayer as; alternating Ti and Al containing layers ( US 6,309,738 ), oxygen and non-oxygen containing layers ( US 6,254,984 ), one of the layers stacked in the multilayer consists itself of a multilayer ( US 6,077,596 ), alternating nitrogen content ( US 5,330,853 ) or using one metastable compound ( US 5,503,912 ) or as aperiodic multilayer ( US 6,103,357 ).
- a cutting tool for machining by chip removal comprising a body of a hard alloy of cemented carbide, cermet, ceramics, cubic boron nitride based material or high speed steel onto which a wear resistant coating is deposited comprising alternating layers of cubic structured MeN where Me is one or more of the metal elements Ti, Nb, Hf, V, Ta, Zr, Cr, Al preferably Ti, Nb, Ta or Al, a cubic structured (Ti,Al)N layer and a cubic structured homogeneous (Ti,Si)N layer.
- the average composition of the coating is 46 at% ⁇ Zr + Hf + V + Cr + Nb + Ta + Ti + Al + Si ⁇ 54 at% preferably 48 at% ⁇ Zr + Hf+ V + Cr + Nb + Ta + Ti + Al + Si ⁇ 52 at% and balanced N as determined by, e.g., EDS or WDS techniques.
- the average thickness of layer A (d A ) is 2 ⁇ d A ⁇ 100nm, preferably 2 ⁇ d A ⁇ 25 nm, of layer B (d B ) 4 ⁇ d B ⁇ 150, preferably 4 ⁇ d B ⁇ 50 and layer C (d C ) 4 ⁇ d C ⁇ 150, preferably 4 ⁇ d C ⁇ 50 and essentially constant throughout the coating (some variation may occur for a three-fold rotation of the fixture).
- Said body may be coated with an inner single- and/or multilayer coating of, e.g., TiN, TiC, Ti(C,N) or (Ti,Al)N, preferably (Ti,Al)N and/or an outer single- and/or multilayer coating of, e.g., TiN, TiC, Ti(C,N) or (Ti,Al)N, preferably (Ti,AI)N, to a total coating thickness of 0.5 to 20 ⁇ m, preferably 1 to 10 ⁇ m and most preferably 2 to 7 ⁇ m according to prior art.
- TiN, TiC, Ti(C,N) or (Ti,Al)N preferably (Ti,AI)N
- the deposition method for the coatings of the present invention is based on cathodic arc evaporation of a pure or alloyed cathode under the following conditions; (Ti,Si)N layers are grown using Ti+Si-cathodes with a composition between (95 at% Ti + 5 at% Si) and (75 at% Ti + 25 at% Si), preferably between (95 at% Ti + 5 at% Si) and (85 at% Ti + 15 at% Si), (Ti,Al)N layers using Ti+Al-cathodes with a composition between (70 at% Ti + 30 at% Al) and (5 at% Ti + 95 at% Al), preferably between (40 at% Ti + 60 at% Al) and (30 at% Ti + 70 at% Al) and MeN layers using pure or alloyed Me-cathodes, where Me is one or more of the metal elements Ti, Nb, Hf, V, Ta, Zr, Cr, Al preferably one or more ofTi, Nb, Ta or Al.
- the evaporation current is between 50 A and 200 A depending on the cathode size and preferably between 50 A and 80 A using cathodes of 63 mm in diameter.
- the layers are grown in an Ar + N 2 atmosphere, preferably in a pure N 2 atmosphere at a total pressure of 0.5 Pa to 7.0 Pa, preferably 1.5 Pa to 5.0 Pa.
- the bias is -10 V to -80 V, preferably -30 V to -60V.
- the deposition temperature is between 350 °C and 700 °C, preferably between 400 and 650 °C.
- the invention also relates to the use of cutting tool inserts according to the above for cutting applications generating high temperatures, e.g., machining of stainless steel and super alloys at cutting speeds of 50-400 m/min, preferably 75-300 m/min, with an average feed, per tooth in the case of milling, of 0.08-0.5 mm, preferably 0.1-0.4 mm depending on cutting speed and insert geometry.
- high temperatures e.g., machining of stainless steel and super alloys at cutting speeds of 50-400 m/min, preferably 75-300 m/min, with an average feed, per tooth in the case of milling, of 0.08-0.5 mm, preferably 0.1-0.4 mm depending on cutting speed and insert geometry.
- Cemented carbide inserts with composition 94 wt% WC - 6 wt% Co (WC grain size of 0.8 ⁇ m) were used.
- the inserts were cleaned in ultrasonic baths of an alkali solution and alcohol.
- the system was evacuated to a pressure of less than 2.0x10 -3 Pa, after which the inserts were sputter cleaned with Ar ions. Alternating TiN/(Ti 0.34 Al 0.66 )N/TiN/(Ti 0.91 Si 0.09 )N/TiN...
- the average composition of the coatings was estimated by energy dispersive spectroscopy (EDS) analysis area using a LEO Ultra 55 scanning electron microscope with a Thermo Noran EDS detector operating at 10 kV.
- the data were evaluated using a Noran System Six (NSS ver 2) software (see tab 1).
- Experiment 1 was repeated replacing the Ti cathode for layer A ( Fig 1 ) with a pure Ta cathode.
- Experiment 1 was repeated replacing the Ti cathode for layer A ( Fig 1 ) with a pure Zr cathode.
- the average composition of the coatings was estimated by energy dispersive spectroscopy (EDS) analysis (see example 1) and summarized in tab 3.
- EDS energy dispersive spectroscopy
- Experiment 1 was repeated replacing the Ti cathode for layer A ( Fig 1 ) with a Ti + Nb (95at%Ti + 5at% Nb) cathode.
- Experiment 1 was repeated replacing the Ti cathode for layer A ( Fig 1 ) with a Ti + Zr (70at%Ti + 30at% Zr) cathode.
- Inserts from example 1 were tested in stainless steel according to: Geometry: CNMG120408-MF1 Application: Continuous turning Work piece material: AISI 316L Cutting speed: 230 m/min Feed: 0,15 mm/rev Depth of cut: 1 mm Tool life criteria, flank wear (vb) >0,3 mm
- Inserts from example 1 were tested in super alloy according to: Geometry: CNMG120412-MR3 Application: Continuous turning Work piece material: Inconel 718 Cutting speed: 90 m/min Feed: 0,2 mm/rev Depth of cut: 0,5 mm Tool life criteria, flank wear (vb) >0,2 mm
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Physical Vapour Deposition (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE0800537 | 2008-03-07 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2098611A2 EP2098611A2 (en) | 2009-09-09 |
EP2098611A3 EP2098611A3 (en) | 2011-07-06 |
EP2098611B1 true EP2098611B1 (en) | 2013-02-13 |
Family
ID=40720047
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09003006A Not-in-force EP2098611B1 (en) | 2008-03-07 | 2009-03-03 | Layered coated cutting tool |
Country Status (3)
Country | Link |
---|---|
US (2) | US8003232B2 (zh) |
EP (1) | EP2098611B1 (zh) |
CN (1) | CN101524904B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016169935A1 (en) * | 2015-04-20 | 2016-10-27 | Seco Tools Ab | A coated cutting tool and a method for coating the cutting tool |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7435448B2 (en) * | 2004-02-06 | 2008-10-14 | Hewlett-Packard Development Company, L.P. | Sulfur-containing inorganic media coatings for ink-jet applications |
KR100876366B1 (ko) * | 2008-04-24 | 2008-12-31 | 한국야금 주식회사 | 절삭공구용 다층경질 박막 |
JP5156971B2 (ja) * | 2009-03-17 | 2013-03-06 | Smc株式会社 | 溶損防止用被覆部材 |
SE533883C2 (sv) * | 2009-06-01 | 2011-02-22 | Seco Tools Ab | Nanolaminerat belagt skärverktyg |
SE533884C2 (sv) * | 2009-06-01 | 2011-02-22 | Seco Tools Ab | Nanolaminerat belagt skärverktyg |
US8409695B2 (en) | 2010-05-28 | 2013-04-02 | Kennametal Inc. | Multilayer nitride hard coatings |
DE102010039035A1 (de) * | 2010-08-06 | 2012-02-09 | Walter Ag | Schneidwerkzeug mit mehrlagiger Beschichtung |
CN102234758B (zh) * | 2011-04-20 | 2013-04-17 | 浙江省平湖市工具厂 | 涂钛丝锥的加工工艺 |
JP5960803B2 (ja) * | 2011-05-27 | 2016-08-02 | ナノメック、インコーポレイテッド | 厚膜立方晶窒化ホウ素(cBN)層及びその作製方法 |
CN102586734B (zh) * | 2012-01-13 | 2014-03-12 | 清华大学 | TiAlN/Ta多层膜刀具涂层及其制备方法 |
EP2628826A1 (en) * | 2012-02-14 | 2013-08-21 | Sandvik Intellectual Property AB | Coated cutting tool and method for making the same |
US9662712B2 (en) * | 2012-02-20 | 2017-05-30 | Nanomech, Inc. | Adherent coating on carbide and ceramic substrates |
EP2636764B1 (en) * | 2012-03-07 | 2014-07-09 | Seco Tools Ab | Nanolaminated coated cutting tool |
CN103084600B (zh) * | 2013-02-27 | 2014-12-31 | 武汉大学 | 超硬TiN-TiSiN-CN多层交替复合梯度涂层硬质合金刀片及制备方法 |
CO6700142A1 (es) * | 2013-06-07 | 2013-06-28 | Univ Del Valle | Recubrimiento biocompatible tipo multicapa-pelicula delgada como tratamiento superficial de sustratos biomédicos y proceso de fabricación del mismo |
JP5663815B2 (ja) * | 2013-07-03 | 2015-02-04 | 住友電工ハードメタル株式会社 | 表面被覆窒化硼素焼結体工具 |
CN103586520B (zh) * | 2013-10-17 | 2016-01-27 | 厦门金鹭特种合金有限公司 | 一种涂层切削刀具及其制作方法 |
EP3394312B1 (en) * | 2015-12-22 | 2020-06-17 | Sandvik Intellectual Property AB | A coated cutting tool and method |
RU2637861C1 (ru) * | 2016-10-11 | 2017-12-07 | федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный технический университет" | Способ получения многослойного покрытия для режущего инструмента |
US10570501B2 (en) * | 2017-05-31 | 2020-02-25 | Kennametal Inc. | Multilayer nitride hard coatings |
WO2019239654A1 (ja) * | 2018-06-15 | 2019-12-19 | 住友電工ハードメタル株式会社 | 表面被覆切削工具、及びその製造方法 |
CN114173972B (zh) * | 2019-10-10 | 2024-05-14 | 住友电工硬质合金株式会社 | 切削工具 |
CN114173970A (zh) * | 2019-10-10 | 2022-03-11 | 住友电工硬质合金株式会社 | 切削工具 |
EP3991890B1 (en) | 2019-10-10 | 2023-05-10 | Sumitomo Electric Hardmetal Corp. | Cutting tool |
CN114173974B (zh) | 2019-10-10 | 2024-03-15 | 住友电工硬质合金株式会社 | 切削工具 |
EP3991889B1 (en) | 2019-10-10 | 2023-09-20 | Sumitomo Electric Hardmetal Corp. | Cutting tool |
WO2021106440A1 (ja) * | 2019-11-27 | 2021-06-03 | 株式会社Moldino | 被覆切削工具 |
KR102172454B1 (ko) * | 2020-08-24 | 2020-10-30 | 주식회사 와이지-원 | 다층 피복 절삭 소재, 그 제조 방법 및 이를 포함하는 기계가공용 절삭 공구 인서트 |
EP4151769A1 (en) * | 2021-09-17 | 2023-03-22 | AB Sandvik Coromant | A coated cutting tool |
CN116555725B (zh) * | 2023-07-10 | 2023-09-12 | 赣州澳克泰工具技术有限公司 | 一种cvd涂层切削刀具及其制备方法 |
CN116604057B (zh) * | 2023-07-17 | 2023-10-20 | 赣州澳克泰工具技术有限公司 | 一种复合涂层刀具及其制备方法和应用 |
Family Cites Families (12)
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US5330853A (en) | 1991-03-16 | 1994-07-19 | Leybold Ag | Multilayer Ti-Al-N coating for tools |
JP2892231B2 (ja) * | 1992-09-16 | 1999-05-17 | 健 増本 | Ti−Si−N系複合硬質膜及びその製造方法 |
EP0592986B1 (en) | 1992-10-12 | 1998-07-08 | Sumitomo Electric Industries, Limited | Ultra-thin film laminate |
SE518145C2 (sv) | 1997-04-18 | 2002-09-03 | Sandvik Ab | Multiskiktbelagt skärverktyg |
JP4185172B2 (ja) | 1997-06-19 | 2008-11-26 | 住友電工ハードメタル株式会社 | 被覆硬質工具 |
WO1999040233A1 (en) * | 1998-02-04 | 1999-08-12 | Osg Corporation | Multilayer coated tool |
JP3031907B2 (ja) | 1998-03-16 | 2000-04-10 | 日立ツール株式会社 | 多層膜被覆部材 |
SE526338C2 (sv) | 2002-09-04 | 2005-08-23 | Seco Tools Ab | Skär med utskiljningshärdad slitstark refraktär beläggning |
SE526339C2 (sv) | 2002-09-04 | 2005-08-23 | Seco Tools Ab | Skär med slitstark refraktär beläggning med kompositstruktur |
JP4072155B2 (ja) * | 2004-12-28 | 2008-04-09 | 住友電工ハードメタル株式会社 | 表面被覆切削工具およびその製造方法 |
SE0500994L (sv) * | 2005-04-29 | 2006-10-30 | Seco Tools Ab | Tunt slitstarkt skikt |
SE529161C2 (sv) | 2005-06-22 | 2007-05-22 | Seco Tools Ab | Skärverktyg med kompositbeläggning för finbearbetning av härdade stål |
-
2009
- 2009-03-03 EP EP09003006A patent/EP2098611B1/en not_active Not-in-force
- 2009-03-06 US US12/399,597 patent/US8003232B2/en not_active Expired - Fee Related
- 2009-03-09 CN CN2009101346966A patent/CN101524904B/zh not_active Expired - Fee Related
-
2011
- 2011-07-18 US US13/184,992 patent/US8075744B1/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016169935A1 (en) * | 2015-04-20 | 2016-10-27 | Seco Tools Ab | A coated cutting tool and a method for coating the cutting tool |
US10669622B2 (en) | 2015-04-20 | 2020-06-02 | Seco Tools Ab | Coated cutting tool and a method for coating the cutting tool |
Also Published As
Publication number | Publication date |
---|---|
US8003232B2 (en) | 2011-08-23 |
EP2098611A2 (en) | 2009-09-09 |
CN101524904A (zh) | 2009-09-09 |
EP2098611A3 (en) | 2011-07-06 |
US20110293384A1 (en) | 2011-12-01 |
US20090226273A1 (en) | 2009-09-10 |
US8075744B1 (en) | 2011-12-13 |
CN101524904B (zh) | 2012-06-27 |
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