EP2025660A2 - Processes for producing ethylene and carbon monoxide mixtures from ethane - Google Patents

Processes for producing ethylene and carbon monoxide mixtures from ethane Download PDF

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Publication number
EP2025660A2
EP2025660A2 EP08161461A EP08161461A EP2025660A2 EP 2025660 A2 EP2025660 A2 EP 2025660A2 EP 08161461 A EP08161461 A EP 08161461A EP 08161461 A EP08161461 A EP 08161461A EP 2025660 A2 EP2025660 A2 EP 2025660A2
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Prior art keywords
ethylene
carbon monoxide
ethane
produce
alkyl
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German (de)
French (fr)
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EP2025660A3 (en
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Abraham Benderly
Scott Han
Mark Anthony Silvano
Donald Lee Zolotorofe
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Rohm and Haas Co
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Rohm and Haas Co
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethylene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/75—Reactions with formaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tatalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Definitions

  • the present invention relates to a process for producing ethylene and carbon monoxide mixtures from ethane and carbon dioxide, and further to various integrated processes for producing alkyl propionates or methacrylic acid esters from ethane and carbon dioxide.
  • Ethylene and carbon monoxide mixtures are used as a feedstock for homologation of ethylene to propionic acid derivatives.
  • carbonylation of ethylene to produce methyl propionate, followed by condensation with formaldehyde is an important commercial route to methyl methacrylate.
  • U.S. Pat. No. 6,284,919 discloses a process for carbonylation of ethylene to methyl propionate.
  • ethylene, CO, and methanol feed is converted to methyl propionate.
  • the ethylene and CO feeds used would generally be from conventional sources such as steam cracking and methane steam reforming.
  • ethylene is a relatively expensive starting material.
  • a process that uses ethane, which is a component of natural gas, as a starting material would be economically desirable due to the large price difference between ethane and ethylene.
  • An integrated process which provides for the production of esters such as methyl propionate and methyl methacrylate using cheap and abundantly available feeds would be of high value.
  • the problem addressed by this invention is to provide an alternative process for producing mixtures of ethylene and carbon monoxide suitable as a feedstock for other processes.
  • the present invention provides a method for producing a mixture of ethylene and carbon monoxide by contacting ethane and carbon dioxide at a temperature of at least 500°C to produce ethylene and carbon monoxide.
  • the present invention further comprises steps of: (a) contacting an alcohol, and the ethylene and carbon monoxide with an ethylene carbonylation catalyst to produce an alkyl propionate; and (b) separating the alkyl propionate from byproducts and starting materials, thus providing an integrated process for producing an alkyl propionate.
  • the invention further comprises condensing the alkyl propionate with formaldehyde, thus providing an integrated process for producing methacrylic acid esters.
  • the invention further comprises converting the ethylene and carbon monoxide to copolymers.
  • the invention further comprises combining the ethylene and carbon monoxide with hydrogen to produce propionaldehyde, and optionally, condensing propionaldehyde with formaldehyde to produce methacrolein.
  • An alkyl group is a saturated hydrocarbyl group having from one to twenty carbon atoms, and may be linear or branched. Preferably, alkyl groups have from one to eight carbon atoms, alternatively from one to four carbon atoms, alternatively one or two carbon atoms, alternatively one carbon atom.
  • the alcohol used in the ethylene carbonylation reaction corresponds to an alkyl group, as defined above, substituted with a hydroxyl group.
  • the catalyst used in the reaction of ethane and carbon dioxide is selected from: (a) a catalyst comprising one or more metals selected from Pt, Pd, Rh, Ir and Ru; and (b) a catalyst comprising at least one oxide of a metal selected from Li, Mo, W, V, Nb, Sb, Sn, Ga, Zr, Mg, Mn, Ni, Co, Ce and rare earth metals.
  • a mixed-metal oxide (“MMO”) catalyst is used as the catalyst in the reaction of ethane and carbon dioxide.
  • e i.e. the amount of oxygen present, is dependent on the oxidation state of the other elements in the catalyst.
  • e is typically in the range of from 3 to 4.7.
  • A is Mo.
  • D is V.
  • E is Te.
  • X is Nb or Ta; and most preferably, X is Nb.
  • the catalyst is Mo a V b Te c Nb d O e .
  • MMO catalysts and their preparation have been reported, for example, in U.S. Pat. Nos. 6,982,343 and 7,049,466 .
  • the ethane and carbon dioxide are contacted at a temperature from 500°C to 1000°C.
  • the temperature is from 550°C to 800°C, alternatively from 600°C to 700°C.
  • the flow rate is from 100 to 5000 hr -1 total gas hourly space velocity (GHSV), alternatively from 500 to 2500 hr -1 GHSV, alternatively from 1000 to 2000 hr -1 GHSV.
  • GHSV gas hourly space velocity
  • inert carrier gasses may be present, e.g., nitrogen. Inert carriers do not participate in, and are unaffected by, the reactions of concern.
  • Catalysts may include support materials, e.g. alumina, silica, silicon carbide, magnesia, zirconia, titania, and combinations thereof; as well as a carrier, such as a monolithic carrier comprising, e.g., cordierite, metal or ceramic. Supports may be modified, stabilized or pretreated to achieve structural stability under the operating conditions.
  • support materials e.g. alumina, silica, silicon carbide, magnesia, zirconia, titania, and combinations thereof
  • a carrier such as a monolithic carrier comprising, e.g., cordierite, metal or ceramic.
  • Supports may be modified, stabilized or pretreated to achieve structural stability under the operating conditions.
  • Ethylene carbonylation catalysts and conditions are well known, and are described, e.g., in U.S. Pat. No. 6,284,919 .
  • Typical catalysts include, e.g., those having a Group VIII metal, e.g. palladium, and a phosphine ligand, e.g. an alkyl phosphine, cycloalkyl phosphine, aryl phosphine, pyridyl phosphine or bidentate phosphine.
  • the products of reaction of ethane and carbon dioxide which comprise ethylene and carbon monoxide
  • the ethylene and carbon monoxide stream may be passed into a different reactor for carbonylation, or alternatively, into another portion of the same reactor.
  • the alkyl propionate product can be converted to an alkyl acrylate in an oxidative dehydrogenation process.
  • Unreacted ethane and carbon dioxide may be present in the product stream from reaction of ethane and carbon dioxide, as well as in the product stream from carbonylation. After separation of the carbonylation product stream, ethane and carbon oxides may be recycled to the input of the reaction of ethane and carbon dioxide. Trace amounts of ethylene and alcohol may also be present. Unreacted ethylene and alcohol from the carbonylation reaction may be recycled to the input of the carbonylation reaction.
  • the alcohol is methanol
  • the alkyl propionate is methyl propionate
  • the alkyl methacrylate is methyl methacrylate.
  • the method represents an integrated process for producing methyl methacrylate starting from ethane and carbon dioxide.
  • the ethylene and carbon monoxide products from the reaction of ethane and carbon dioxide are subjected to a hydroformylation reaction to produce propionaldehyde, as described, e.g., in U.S. Pat. No. 4,408,079 .
  • the propionaldehyde product can be oxidized to propionic acid or condensed with formaldehyde to produce methacrolein, which in turn can be used to produce methacrylic acid.
  • the method further comprises polymerization of the methyl methacrylate product to provide an integrated process for producing methyl methacrylate polymers or copolymers starting from ethane and carbon dioxide.
  • methanol is used to produce methyl methacrylate as described herein, and the methyl methacrylate then is transesterified with other alcohols to produce other alkyl methacrylates.
  • the ethylene and carbon monoxide are copolymerized.
  • a palladium compound is used as a catalyst, e.g., palladium cyanide, aryl phosphine complexes of palladium or palladium halides, or tetrakis triarylphosphine platinum complex.
  • Polymerization processes are described, e.g., in U.S. Pat. Nos. 3,530,109 and 3,694,412 .
  • the ethylene-carbon monoxide polymer can be converted to a thermosetting compound by heating.
  • ethane, carbon dioxide and oxygen are reacted under millisecond contact times resulting in an autothermal reaction.
  • Millisecond contact times are times less than one second, alternatively less than 900 milliseconds, alternatively less than 500 milliseconds, alternatively less than 100 milliseconds, alternatively less than 50 milliseconds, alternatively less than 10 milliseconds.
  • ethane and carbon dioxide react either in a single reactor or in staged reactors to provide improved heat balance.
  • Catalytic experiments were carried out using 4 mL of catalyst diluted with 4 mL of silicon carbide chips charged to a 1 ⁇ 2" (12.7 mm) O.D. stainless steel reactor tube.
  • the reactor was heated to 675°C in flowing N 2 .
  • a feed comprising C 2 H 6 :CO 2 :N 2 in a 1:3:1 molar ratio was introduced into the reactor.
  • the gases were fed at 100 mL/min total (ethane: 20 mL/min, CO 2 : 60 mL/min, and N 2 : 20 mL/min).
  • Analysis of the products was by GC and N 2 was employed as an internal standard. Feed conversions and product yields were calculated on a molar basis.

Abstract

A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source at a temperature of at least 500°C to produce ethylene and carbon monoxide. A method for producing an alkyl propionate by steps of: (a) contacting ethane and an oxygen source at a temperature of at least 500°C to produce ethylene; (b) contacting an alcohol, ethylene and carbon monoxide with an ethylene carbonylation catalyst to produce the alkyl propionate; and (c) separating the alkyl propionate from byproducts and starting materials. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.

Description

  • The present invention relates to a process for producing ethylene and carbon monoxide mixtures from ethane and carbon dioxide, and further to various integrated processes for producing alkyl propionates or methacrylic acid esters from ethane and carbon dioxide.
  • Ethylene and carbon monoxide mixtures are used as a feedstock for homologation of ethylene to propionic acid derivatives. For example, carbonylation of ethylene to produce methyl propionate, followed by condensation with formaldehyde, is an important commercial route to methyl methacrylate. For example, U.S. Pat. No. 6,284,919 discloses a process for carbonylation of ethylene to methyl propionate. In the first step of this process, ethylene, CO, and methanol feed is converted to methyl propionate. The ethylene and CO feeds used would generally be from conventional sources such as steam cracking and methane steam reforming. However, due to the high cost associated with these ethylene-producing processes, ethylene is a relatively expensive starting material. A process that uses ethane, which is a component of natural gas, as a starting material would be economically desirable due to the large price difference between ethane and ethylene. An integrated process which provides for the production of esters such as methyl propionate and methyl methacrylate using cheap and abundantly available feeds would be of high value.
  • The problem addressed by this invention is to provide an alternative process for producing mixtures of ethylene and carbon monoxide suitable as a feedstock for other processes.
    • STATEMENT OF THE INVENTION
  • The present invention provides a method for producing a mixture of ethylene and carbon monoxide by contacting ethane and carbon dioxide at a temperature of at least 500°C to produce ethylene and carbon monoxide.
  • The present invention further comprises steps of: (a) contacting an alcohol, and the ethylene and carbon monoxide with an ethylene carbonylation catalyst to produce an alkyl propionate; and (b) separating the alkyl propionate from byproducts and starting materials, thus providing an integrated process for producing an alkyl propionate. The invention further comprises condensing the alkyl propionate with formaldehyde, thus providing an integrated process for producing methacrylic acid esters. The invention further comprises converting the ethylene and carbon monoxide to copolymers. The invention further comprises combining the ethylene and carbon monoxide with hydrogen to produce propionaldehyde, and optionally, condensing propionaldehyde with formaldehyde to produce methacrolein.
    • DETAILED DESCRIPTION OF THE INVENTION
  • Percentages are weight percentages, and temperatures are in °C, unless specified otherwise. An alkyl group is a saturated hydrocarbyl group having from one to twenty carbon atoms, and may be linear or branched. Preferably, alkyl groups have from one to eight carbon atoms, alternatively from one to four carbon atoms, alternatively one or two carbon atoms, alternatively one carbon atom. The alcohol used in the ethylene carbonylation reaction corresponds to an alkyl group, as defined above, substituted with a hydroxyl group.
  • In some embodiments of the invention, the catalyst used in the reaction of ethane and carbon dioxide is selected from: (a) a catalyst comprising one or more metals selected from Pt, Pd, Rh, Ir and Ru; and (b) a catalyst comprising at least one oxide of a metal selected from Li, Mo, W, V, Nb, Sb, Sn, Ga, Zr, Mg, Mn, Ni, Co, Ce and rare earth metals.
  • In some embodiments of this invention, a mixed-metal oxide ("MMO") catalyst is used as the catalyst in the reaction of ethane and carbon dioxide. The general empirical formula for the MMO catalysts is AaDbEcXdOe, wherein A is at least one element selected from the group consisting of Mo and W, D is at least one element selected from the group consisting of V and Ce, E is at least one element selected from the group consisting of Te, Sb and Se, and X is at least one element selected from the group consisting of Nb, Ta, Ti, Al, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ni, Pt, Sb, Bi, B, In, As, Ge, Sn, Li, Na, K, Rb, Cs, Fr, Be, Mg, Ca, Sr, Ba, Ra, Hf, Ag, Pb, P, Pm, Eu, Gd, Dy, Ho, Er, Tm, Yb and Lu; and a = 1, b = 0.01 to 1.0, c = 0.01 to 1.0, d = 0.01 to 1.0, and e is dependent on the oxidation state of elements other than oxygen.
  • Preferably, when a = 1, b = 0.1 to 0.5, c = 0.05 to 0.5 and d = 0.01 to 0.5. More preferably, when a = 1, b = 0.15 to 0.45, c = 0.05 to 0.45 and d = 0.05 to 0.2. The value of e, i.e. the amount of oxygen present, is dependent on the oxidation state of the other elements in the catalyst. However, e is typically in the range of from 3 to 4.7. Preferably, A is Mo. Preferably, D is V. Preferably, E is Te. Preferably, X is Nb or Ta; and most preferably, X is Nb. In one preferred embodiment of the invention, the catalyst is MoaVbTecNbdOe.
  • MMO catalysts and their preparation have been reported, for example, in U.S. Pat. Nos. 6,982,343 and 7,049,466 .
  • Preferably, the ethane and carbon dioxide are contacted at a temperature from 500°C to 1000°C. In embodiments where a catalyst is used, preferably the temperature is from 550°C to 800°C, alternatively from 600°C to 700°C. Preferably, the flow rate is from 100 to 5000 hr-1 total gas hourly space velocity (GHSV), alternatively from 500 to 2500 hr-1 GHSV, alternatively from 1000 to 2000 hr-1 GHSV.
  • In embodiments where no catalyst is used in the ethane-carbon dioxide reaction, preferably the ethane and carbon dioxide are contacted at a temperature from 600°C to 750°C. Preferably, the flow rate is from 0.1 to 10 L/min, alternatively from 1 to 3 L/min.
  • In addition to ethane and carbon dioxide, inert carrier gasses may be present, e.g., nitrogen. Inert carriers do not participate in, and are unaffected by, the reactions of concern.
  • Catalysts may include support materials, e.g. alumina, silica, silicon carbide, magnesia, zirconia, titania, and combinations thereof; as well as a carrier, such as a monolithic carrier comprising, e.g., cordierite, metal or ceramic. Supports may be modified, stabilized or pretreated to achieve structural stability under the operating conditions.
  • Ethylene carbonylation catalysts and conditions are well known, and are described, e.g., in U.S. Pat. No. 6,284,919 . Typical catalysts include, e.g., those having a Group VIII metal, e.g. palladium, and a phosphine ligand, e.g. an alkyl phosphine, cycloalkyl phosphine, aryl phosphine, pyridyl phosphine or bidentate phosphine.
  • In some embodiments of the invention, the products of reaction of ethane and carbon dioxide, which comprise ethylene and carbon monoxide, are contacted with an ethylene carbonylation catalyst, along with an alcohol. The ethylene and carbon monoxide stream may be passed into a different reactor for carbonylation, or alternatively, into another portion of the same reactor. The alkyl propionate product can be converted to an alkyl acrylate in an oxidative dehydrogenation process.
  • Unreacted ethane and carbon dioxide may be present in the product stream from reaction of ethane and carbon dioxide, as well as in the product stream from carbonylation. After separation of the carbonylation product stream, ethane and carbon oxides may be recycled to the input of the reaction of ethane and carbon dioxide. Trace amounts of ethylene and alcohol may also be present. Unreacted ethylene and alcohol from the carbonylation reaction may be recycled to the input of the carbonylation reaction.
  • In some embodiments of the invention, the alcohol is methanol, the alkyl propionate is methyl propionate and the alkyl methacrylate is methyl methacrylate. In these embodiments, the method represents an integrated process for producing methyl methacrylate starting from ethane and carbon dioxide.
  • In some embodiments of the invention, the ethylene and carbon monoxide products from the reaction of ethane and carbon dioxide are subjected to a hydroformylation reaction to produce propionaldehyde, as described, e.g., in U.S. Pat. No. 4,408,079 . The propionaldehyde product can be oxidized to propionic acid or condensed with formaldehyde to produce methacrolein, which in turn can be used to produce methacrylic acid.
  • In some embodiments of the invention, the method further comprises polymerization of the methyl methacrylate product to provide an integrated process for producing methyl methacrylate polymers or copolymers starting from ethane and carbon dioxide.
  • In some embodiments of the invention, methanol is used to produce methyl methacrylate as described herein, and the methyl methacrylate then is transesterified with other alcohols to produce other alkyl methacrylates.
  • In some embodiments of the invention, the ethylene and carbon monoxide are copolymerized. Preferably, a palladium compound is used as a catalyst, e.g., palladium cyanide, aryl phosphine complexes of palladium or palladium halides, or tetrakis triarylphosphine platinum complex. Polymerization processes are described, e.g., in U.S. Pat. Nos. 3,530,109 and 3,694,412 . The ethylene-carbon monoxide polymer can be converted to a thermosetting compound by heating.
  • In some embodiments of the invention, ethane, carbon dioxide and oxygen are reacted under millisecond contact times resulting in an autothermal reaction. Millisecond contact times are times less than one second, alternatively less than 900 milliseconds, alternatively less than 500 milliseconds, alternatively less than 100 milliseconds, alternatively less than 50 milliseconds, alternatively less than 10 milliseconds. In some embodiments of the invention, ethane and carbon dioxide react either in a single reactor or in staged reactors to provide improved heat balance.
    • EXAMPLES Example 1: Ethane conversion with catalyst
  • The catalyst used was a Mo/V/Te/Nb mixed metal oxide prepared as previously reported in U.S. Pat. No. 6,982,343 .
  • Catalytic experiments were carried out using 4 mL of catalyst diluted with 4 mL of silicon carbide chips charged to a ½" (12.7 mm) O.D. stainless steel reactor tube. The reactor was heated to 675°C in flowing N2. Once at 675°C, a feed comprising C2H6:CO2:N2 in a 1:3:1 molar ratio was introduced into the reactor. The gases were fed at 100 mL/min total (ethane: 20 mL/min, CO2: 60 mL/min, and N2: 20 mL/min). Analysis of the products was by GC and N2 was employed as an internal standard. Feed conversions and product yields were calculated on a molar basis. Data obtained from the experiment described above are given below.
    Time on stream, hrs C2H6 conversion, % C2H4 yield, % CO yield, %
    0.5 38.0 13.5 4.3
    1.0 20.5 15.5 5.2
    1.5 19.8 15.2 4.9
    2.0 18.4 14.5 4.5
    2.5 16.5 13.6 4.0
    3.0 14.5 12.3 3.4
    3.5 9.5 10.9 2.8
    4.0 7.3 9.3 2.2
    4.5 5.7 7.5 1.7
    The data clearly show that desired ethylene and CO products from the process are formed in quantities suitable for further processing to methyl propionate.

Claims (10)

  1. A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and carbon dioxide at a temperature of at least 500°C to produce ethylene and carbon monoxide.
  2. The method of claim 1 in which the ethane and carbon dioxide are contacted with a MMO catalyst having empirical formula AaDbEcXdOe, wherein A is at least one element selected from the group consisting of Mo and W, D is at least one element selected from the group consisting of V and Ce, E is at least one element selected from the group consisting of Te, Sb and Se, and X is at least one element selected from the group consisting of Nb, Ta, Ti, Al, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ni, Pt, Sb, Bi, B, In, As, Ge, Sn, Li, Na, K, Rb, Cs, Fr, Be, Mg, Ca, Sr, Ba, Ra, Hf, Ag, Pb, P, Pm, Eu, Gd, Dy, Ho, Er, Tm, Yb and Lu; and a = 1, b = 0.01 to 1.0, c = 0.01 to 1.0, d = 0.01 to 1.0, and e is dependent on the oxidation state of elements other than oxygen.
  3. The method of claim 2 in which the MMO catalyst is MoaVbTecNbdOe and the temperature is from 600°C to 700°C.
  4. The method of claim 1, further comprising steps of:
    (a) contacting an alcohol, and said ethylene and carbon monoxide with an ethylene carbonylation catalyst to produce an alkyl propionate; and
    (b) separating the alkyl propionate from byproducts and starting materials.
  5. The method of claim 4, further comprising reacting the alkyl propionate with formaldehyde to produce an alkyl methacrylate.
  6. The method of claim 5 in which the alcohol is methanol, the alkyl propionate is methyl propionate and the alkyl methacrylate is methyl methacrylate.
  7. The method of claim 6, further comprising polymerizing the methyl methacrylate.
  8. The method of claim 1, further comprising co-polymerizing the ethylene and carbon monoxide.
  9. The method of claim 1, further comprising combining said ethylene and carbon monoxide with hydrogen to produce propionaldehyde.
  10. The method of claim 9, further comprising condensing the propionaldehyde with formaldehyde to produce methacrolein.
EP08161461A 2007-08-14 2008-07-30 Processes for producing ethylene and carbon monoxide mixtures from ethane Withdrawn EP2025660A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US96473307P 2007-08-14 2007-08-14

Publications (2)

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CN101367698B (en) 2012-05-23
US7906699B2 (en) 2011-03-15
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