EP1957705B8 - Verfahren zur ausrüstung von textilien - Google Patents
Verfahren zur ausrüstung von textilienInfo
- Publication number
- EP1957705B8 EP1957705B8 EP06793689A EP06793689A EP1957705B8 EP 1957705 B8 EP1957705 B8 EP 1957705B8 EP 06793689 A EP06793689 A EP 06793689A EP 06793689 A EP06793689 A EP 06793689A EP 1957705 B8 EP1957705 B8 EP 1957705B8
- Authority
- EP
- European Patent Office
- Prior art keywords
- process according
- done
- fabric
- linear
- branched
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 28
- 239000004753 textile Substances 0.000 title claims abstract description 11
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 54
- 238000001035 drying Methods 0.000 claims abstract description 12
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 9
- 239000004744 fabric Substances 0.000 claims description 40
- 239000001913 cellulose Substances 0.000 claims description 15
- 229920002678 cellulose Polymers 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- -1 amino, carboxyl Chemical group 0.000 claims description 7
- 238000005470 impregnation Methods 0.000 claims description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
- 239000000080 wetting agent Substances 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 125000000524 functional group Chemical group 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 239000000314 lubricant Substances 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- 235000011167 hydrochloric acid Nutrition 0.000 claims description 3
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 235000011007 phosphoric acid Nutrition 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000001117 sulphuric acid Substances 0.000 claims description 2
- 235000011149 sulphuric acid Nutrition 0.000 claims description 2
- 239000004902 Softening Agent Substances 0.000 claims 1
- 150000001412 amines Chemical class 0.000 abstract description 5
- 238000004383 yellowing Methods 0.000 abstract description 4
- 150000008625 2-imidazolidinones Chemical class 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000004971 Cross linker Substances 0.000 description 7
- 238000001723 curing Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000013036 cure process Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 230000001046 anti-mould Effects 0.000 description 2
- 239000002546 antimould Substances 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 230000002939 deleterious effect Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000006266 etherification reaction Methods 0.000 description 2
- 238000007730 finishing process Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000000077 insect repellent Substances 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 238000010409 ironing Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- JTNCEQNHURODLX-UHFFFAOYSA-N 2-phenylethanimidamide Chemical compound NC(=N)CC1=CC=CC=C1 JTNCEQNHURODLX-UHFFFAOYSA-N 0.000 description 1
- ZEYUSQVGRCPBPG-UHFFFAOYSA-N 4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one Chemical compound OCN1C(O)C(O)N(CO)C1=O ZEYUSQVGRCPBPG-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 238000013035 low temperature curing Methods 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Chemical class 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 150000002913 oxalic acids Chemical class 0.000 description 1
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229910000343 potassium bisulfate Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Definitions
- the present invention relates to a process for finishing a cellulose-based textile as well as a cellulose-based textile finished according to this process.
- Cross-linking textile finishes are currently used for conferring on cellulose fabrics properties of durable press and resistance to creasing or crease recovery, a dimensional stability to domestic washes as well as easy care (easy ironing or no ironing), among other properties.
- finished fabrics according to this prior art have low resistance to tearing, show a great tendency to yellowing, and may generate an unpleasant amine smell.
- non formaldehyde crosslinkers can be applied under extreme acidic conditions to a cellulose based fabric in a moist cure process (a combination of impregnation, padding, gentle drying, low temperature curing and washing) to give good easy-care properties.
- the finished fabrics according to this invention have an excellent whiteness level, a very high tear strength, and no unpleasant amine smell.
- This invention provides a formaldehyde free cross-linking finishing process of cellulose fabrics or cellulose containing fabrics.
- X is O or S, preferably O
- R 1 , R 2 are the same or different and are linear or branched Ci-C 2 o-alkyl, preferably Ci-Cs-alkyl, most preferably methyl, or linear or branched C 2 -C 2 o-alkyl, preferably C 2 -Cs-alkyl, substituted by one or more functional groups like hydroxyl, amino, carboxyl, amide, ester, ether, and halogen (fluorine, chlorine, bromine and iodine),
- R 3 , R 4 are the same or different (R 3 and R 4 may be part of the same ring structure) : and are H or linear or branched Ci-C 2 o-alkyl, preferably Ci-Cs-alkyl, eventually substituted by one or more functional groups like hydroxyl, amino, carboxyl, amide, ester, ether, and halogen (fluorine, chlorine, bromine and iodine), or groups like
- n is 1-20, preferably 1-6, most preferably 2, and R 5 is H or linear or branched chain alkyl C 1 -C 4 , preferably H.
- R 1 and R 2 are methyl and R 3 and R 4 are H or methyl or -(CH 2 ) 2 OH
- Preferred compounds of the invention are l,3-Dimethyl-4,5-dihydroxy-2-imidazolidinone (also called DMeDHEU, DiMethylDiHydroxyEthylenUrea) and its etherified derivatives.
- DMeDHEU DiMethylDiHydroxyEthylenUrea
- the preferred alcohols are methanol or DEG (diethylenglycol) or mixtures thereof.
- Arkofix NZF New (Clariant) or can be prepared by different techniques known to the man skilled in the art as described among other possible processes in US 3 304 312, US 4 295 846, EP 0 141 755, or US 5 707 404.
- the process is generally a condensation of glyoxal and a di-substituted urea followed or not by an etherification step with one or more alcohol or polyol.
- Process of this invention is characterised by the following steps : a) Impregnation of a cellulose containing fabric with a bath containing a non formaldehyde cross-linking agent of formula (I) and a catalyst or a mixture of catalysts under acidic conditions,
- an additional top-finishing step may complete the instant process.
- a cellulose containing fabric is impregnated with a bath containing a non formaldehyde cross- linking agent of formula (I) and a catalyst or a mixture of catalysts.
- the concentration of the finishing agent of formula (I) in the bath calculated as solid is generally governed by the desired effect. As a rule it is between 30 and 500 g/1, preferably between 100 and 300 g/1, most preferably between 120 and 240 g/1.
- Catalysts suitable for this process are one single acid or combinations of organic and inorganic acids or acid donors.
- the cross-linking of the cellulose is acid-catalysed; the bath pH is adjusted to 3 or below, preferably to 2 or below, and most preferably to 0.8-1.5.
- Typical catalysts include acids such as hydrochloric, sulphuric, fluoroboric, phosphoric, nitric, acetic, glycolic, maleic, lactic, citric, tartaric, muriatic and oxalic acids; metal salts such as magnesium chloride, nitrate, fluoroborate, or fiuorosilicate; zinc chloride, nitrate, fluoroborate, or fiuorosilicate; ammonium chloride; zirconium oxychloride; sodium or potassium bisulfate; amine hydrochlorides such as the hydrochloride of 2-amino-2-methyl-l- propanol; and the like and mixtures thereof.
- Preferred are hydrochloric acid, sulphuric acid, phosphoric acid or ammonium chloride.
- additives may be added to the bath.
- Conventional additives such as wetting agents, lubricants, softeners, bodying agents, water repellents, flame retardants, soil shedding agents, mildew inhibitors, anti-wet soiling agents, fluorescent brighteners, biocides (antimicrobial, anti-bacterial, anti-algae, anti- fungi, insect repellent, anti-dust mite, anti-mould) and the like may be used in the treating bath in conventional amounts as long as the stability of the bath is compatible with the very low pH range of the invention.
- auxiliaries must not, however, interfere with the proper functioning of the finishing resin, must not themselves have a deleterious effect on the fabric, and desirably are free of formaldehyde.
- the impregnated fabric is dried at low temperature below 130 0 C, preferably below 10O 0 C and most preferably between 60 and 90 0 C to a residual moisture of from 3 to 30% , preferably from 5 to 15% and most preferably of from 6 to 10%.
- the fabric being kept at this humidity either by being wrapped with a plastic film or by any other means, is cured at low temperature, below 50 0 C, preferentially below 40 0 C, to avoid fibre damage for 5 to 30 h , preferentially for 15 to 25 h.
- the fabric is preferentially kept under rotation to avoid migration and local over-concentration of the catalyst that could damage the fabric.
- the fabric is washed and neutralised with any conventional method generally used by the man skilled in the art. Neutralisation may be achieved for example with a base like caustic soda or just by rinsing.
- the fabric is dried.
- the fabric is top-finished with a bath containing additives. This step can be subsequent to the drying or the fabric can be padded after the washing in a wet-in- wet process and then dried.
- additives such as wetting agents, lubricants, softeners, bodying agents, water repellents, flame retardants, soil shedding agents, mildew inhibitors, anti-wet soiling agents, fluorescent brighteners, biocides (anti-microbial, anti-bacterial, anti-algae, anti-fungi, insect repellent, anti-dust mite, anti-mould) and the like may be used in the top-finish bath in conventional amounts as long as the bath is stable.
- auxiliaries must not, however, interfere with the proper functioning of the finishing resin, must not themselves have a deleterious effect on the fabric, and desirably are free of formaldehyde.
- non- formaldehyde finished fabrics according to the disclosed process have easy-care properties and furthermore have a better tear strength, a high whiteness level (no yellowing) and do not generate any unpleasant amine smell.
- the following examples shall explain the instant invention in more detail.
- degree of fixation is obtained by the nitrogen determination (N%) of the fabric before and after washing by elementary analysis.
- a bleached white 100% cotton toile 1/1 (116 g/m 2 , 40x27.5 treads/cm) was impregnated in a bath according to recipe #1.
- the material was squeezed to a wet pick-up of 65%, and then it was dried with hot air having 70 0 C to a residual moisture of 7-8 %.
- the material was wrapped in a plastic bag and was allowed to stand at 35°C for 24 hours (curing). Thereupon it was promptly washed, neutralised, rinsed with water at 30 0 C for 5 minutes then squeezed and dried at 120 0 C. After the drying, the material was impregnated and squeezed with recipe A to a wet pick up of 60%, and dried at 130 0 C (top-finish).
- the fabric of example 1 is impregnated in a bath according to recipe #2.
- the material was squeezed to a wet pick-up of 65% then it was dried and cured at 150 0 C (effective time at 150 0 C: 60 seconds).
- a bleached white 100% cotton poplin 120 g/m 2 was impregnated in a bath according to recipe #3.
- the material was squeezed to a wet pick-up of 75%, then it was dried with hot air having 90 0 C to a residual moisture of 9 %.
- the material was wrapped in a plastic bag and was allowed to stand at 20 0 C for 22 hours. Thereupon it was promptly rinsed, neutralised with caustic soda, rinsed with water for 10 minutes , acidified with acetic acid, rinsed again then squeezed and dried at 120 0 C. After the drying, the material was impregnated and squeezed with recipe B to a wet pick up of 75%, and dried at 120 0 C.
- the fabric of example 2 is impregnated in a bath according to recipe #4.
- the material was squeezed to a wet pick-up of 75% then it was dried for 45 seconds at 120 0 C and cured for 30 seconds at 160 0 C.
- the finished material of comparative example 2 was washed with 1 g/1 of a detergent/wetting and dispersing agent for 15 minutes at 45°C then was rinsed with water, squeezed and dried for 45" at 120 0 C.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06793689A EP1957705B8 (de) | 2005-10-12 | 2006-09-21 | Verfahren zur ausrüstung von textilien |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP05292137 | 2005-10-12 | ||
| EP06793689A EP1957705B8 (de) | 2005-10-12 | 2006-09-21 | Verfahren zur ausrüstung von textilien |
| PCT/EP2006/066563 WO2007042380A1 (en) | 2005-10-12 | 2006-09-21 | Process for finishing textiles |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP1957705A1 EP1957705A1 (de) | 2008-08-20 |
| EP1957705B1 EP1957705B1 (de) | 2011-12-14 |
| EP1957705B8 true EP1957705B8 (de) | 2012-03-14 |
Family
ID=36677238
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP06793689A Active EP1957705B8 (de) | 2005-10-12 | 2006-09-21 | Verfahren zur ausrüstung von textilien |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20090044347A1 (de) |
| EP (1) | EP1957705B8 (de) |
| JP (1) | JP2009511763A (de) |
| CN (1) | CN101305125A (de) |
| BR (1) | BRPI0617298B1 (de) |
| ES (1) | ES2379007T3 (de) |
| PE (1) | PE20070735A1 (de) |
| PT (1) | PT1957705E (de) |
| WO (1) | WO2007042380A1 (de) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011078068A1 (ja) * | 2009-12-24 | 2011-06-30 | コニカミノルタＩｊ株式会社 | インクジェット捺染用布帛前処理剤、布帛の前処理方法及びテキスタイルプリント方法 |
| CN102220694B (zh) * | 2010-04-16 | 2012-11-07 | 香港纺织及成衣研发中心 | 用于织物多功能整理的组合物及使用其的织物多功能整理方法 |
| JP6496012B2 (ja) | 2014-08-27 | 2019-04-03 | ダブリュ．エル．ゴア アンド アソシエーツ，ゲゼルシャフト ミット ベシュレンクテル ハフツングＷ．Ｌ． Ｇｏｒｅ ＆ Ａｓｓｏｃｉａｔｅｓ， Ｇｅｓｅｌｌｓｃｈａｆｔ Ｍｉｔ Ｂｅｓｃｈｒａｎｋｔｅｒ Ｈａｆｔｕｎｇ | 防水性かつ水蒸気透過性のラミネート |
| CN105177819B (zh) * | 2015-10-26 | 2017-01-11 | 南通金仕达超微阻燃材料有限公司 | 一种高品质寛幅竹纤维机织物及其生产方法 |
| MX2020002778A (es) | 2017-09-12 | 2020-11-06 | Cotton Inc | Mejora del equilibrio de las propiedades de planchado permanente de telas de algodon usando tecnologia sin formaldehido. |
| CN107747219B (zh) * | 2017-11-10 | 2020-09-08 | 浙江乔治白服饰股份有限公司 | 一种零甲醛泡沫整理液整理免烫衬衫的方法 |
| GB201720140D0 (en) * | 2017-12-04 | 2018-01-17 | Novolab Ltd | Improvements relating to crease recovery in textiles |
| JP2021122484A (ja) * | 2020-02-05 | 2021-08-30 | Ykk株式会社 | 撥水製品、撥水製品の製造方法 |
| WO2022114931A1 (ko) * | 2020-11-30 | 2022-06-02 | 주식회사 엘지생활건강 | 섬유 케어 조성물 |
| CN112981961A (zh) * | 2021-03-05 | 2021-06-18 | 鲁泰纺织股份有限公司 | 光能自消毒无甲醛免烫面料的制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH353566D (de) * | 1965-03-20 | |||
| US3853604A (en) * | 1966-07-09 | 1974-12-10 | Vepa Ag | Method for the continuous high-grade finishing of textile materials |
| DE1594918A1 (de) * | 1966-10-20 | 1970-06-25 | Basf Ag | Verfahren zum Knitterfestausruesten von Leinen oder leinenhaltigem Textilgut |
| CH1548868D (de) * | 1967-10-18 | |||
| US3827994A (en) * | 1971-11-04 | 1974-08-06 | Grace W R & Co | Composition for producing wrinkle-free permanently pressed cellulosic textile materials |
| US3979178A (en) * | 1974-10-09 | 1976-09-07 | The United States Of America As Represented By The Secretary Of Agriculture | Finishing of cellulose fabrics with N-methylol amide crosslinking agents, magnesium sulfate and sulfuric acid |
| US4295846A (en) * | 1980-03-18 | 1981-10-20 | Basf Aktiengesellschaft | Process for the production of formaldehyde-free finishing agents for cellulosic textiles and the use of such agents |
| GB8314180D0 (en) * | 1983-05-23 | 1983-06-29 | Sandoz Products Ltd | Organic compounds |
| US6184271B1 (en) * | 1994-03-25 | 2001-02-06 | Weyerhaeuser Company | Absorbent composite containing polymaleic acid crosslinked cellulosic fibers |
| CA2305673A1 (en) * | 1997-10-03 | 1999-04-15 | Clariant Finance (Bvi) Limited | Finishing for jeans material |
| JP4264767B2 (ja) * | 1998-07-03 | 2009-05-20 | 東洋紡績株式会社 | 形態安定加工用セルロース系繊維含有繊維構造物及び形態安定性セルロース系繊維含有繊維構造物の製造方法 |
| JP2000096442A (ja) * | 1998-09-14 | 2000-04-04 | Toyobo Co Ltd | セルロース系繊維布帛の加工方法 |
| BR0013837A (pt) * | 1999-09-08 | 2002-05-21 | Clariant Finance Bvi Ltd | Acabamento da superfìcie de papel ou papelão, e agente para este propósito |
-
2006
- 2006-09-21 JP JP2008534968A patent/JP2009511763A/ja active Pending
- 2006-09-21 US US12/083,262 patent/US20090044347A1/en not_active Abandoned
- 2006-09-21 BR BRPI0617298A patent/BRPI0617298B1/pt active IP Right Grant
- 2006-09-21 EP EP06793689A patent/EP1957705B8/de active Active
- 2006-09-21 ES ES06793689T patent/ES2379007T3/es active Active
- 2006-09-21 CN CNA2006800372192A patent/CN101305125A/zh active Pending
- 2006-09-21 PT PT06793689T patent/PT1957705E/pt unknown
- 2006-09-21 WO PCT/EP2006/066563 patent/WO2007042380A1/en active Application Filing
- 2006-10-11 PE PE2006001236A patent/PE20070735A1/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CN101305125A (zh) | 2008-11-12 |
| PT1957705E (pt) | 2012-02-22 |
| PE20070735A1 (es) | 2007-08-24 |
| BRPI0617298B1 (pt) | 2016-12-20 |
| ES2379007T3 (es) | 2012-04-19 |
| WO2007042380A1 (en) | 2007-04-19 |
| JP2009511763A (ja) | 2009-03-19 |
| US20090044347A1 (en) | 2009-02-19 |
| BRPI0617298A2 (pt) | 2011-07-19 |
| EP1957705B1 (de) | 2011-12-14 |
| EP1957705A1 (de) | 2008-08-20 |
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