EP1881083A1 - Pièce en acier à haute résistance mécanique et sa utilisation - Google Patents
Pièce en acier à haute résistance mécanique et sa utilisation Download PDFInfo
- Publication number
- EP1881083A1 EP1881083A1 EP07014185A EP07014185A EP1881083A1 EP 1881083 A1 EP1881083 A1 EP 1881083A1 EP 07014185 A EP07014185 A EP 07014185A EP 07014185 A EP07014185 A EP 07014185A EP 1881083 A1 EP1881083 A1 EP 1881083A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- workpiece
- mpa
- elongation
- followed
- break
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/25—Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
Definitions
- the invention relates to a workpiece made of a high-strength steel alloy and its manufacture and use.
- Air hardening steel alloys have the advantage that they already have a high strength in the normalized state. They are only slightly influenced by the strength of joining processes such as welding and soldering and at the same time have a high tempering resistance in the hot dip galvanizing, z. B. in the high-temperature galvanizing.
- Classic air-hardening steel materials are based on the CrMoV concept with Mo contents between 0.4% and 0.6% and V contents between 0.1% and 0.2%. Due to the sharp increase in raw material costs, classic CrMoV steels are in the range of mass applications, such as e.g. in the automotive industry, generally no longer economically viable.
- An alternative alloying concept is the MnTiB concept, which is known from water-hardening steels.
- MnTiB concept By adding molybdenum and tungsten to the MnTiB concept, as in the DE 10 2004 053 620 A1 proposed, air-hardening properties are achieved at low C-hooks at high elongation at break.
- the raw material costs for the alloying elements are very high.
- air-hardening materials with C contents of between 0.09% and 0.12% achieve considerable strengths of up to 1200 MPa and a comparatively high breaking elongation or toughness due to the low C contents during rapid cooling,
- continuous casting tend to above-average failure rates due to poor surfaces. The reason is to be seen in the peritectic solidification with the result that a reworking of the material is necessary.
- the invention is based on the object to show a workpiece using a high-strength, air-hardening steel alloy with a cost-effective alloy concept and its production, which is particularly suitable for use in motor vehicle construction.
- the setting of the hardenability in the alloy type is carried out primarily by adding manganese and chromium in cooperation with titanium and niobium.
- Essential for achieving a high elongation at break with high tensile strengths is the addition of niobium and the adjustment of a controlled N content together with titanium, niobium and boron and a suitable thermomechanical treatment of the material. In this procedure can be dispensed with the costly alloying elements molybdenum and vanadium.
- the microalloying concept allows the A5 elongation at break to be increased from 10% to 16% through targeted thermomechanical treatment during hot strip production and also during the production of seamless tubes.
- the thermomechanical treatment provides for control of rolling temperatures, picking and cooling control after rolling. This allows a bainitic structure with bainite contents greater than 80% with particle sizes below 10 microns and especially below 5 microns can be adjusted so that there are high elongation at break values.
- the high strength can be adjusted not only by the thermomechanical treatment, but also by an additional heat treatment, in particular by hardening and tempering.
- a semifinished product of the alloy of sheet metal or tube according to the invention can first be used in the soft, ferritic-pearlitic state.
- This condition can be achieved by an annealing treatment or by setting suitable reel temperatures during belt production.
- the soft ferritic-pearlitic state is characterized by a yield strength Rp 0.2 of 500 MPa and a high elongation at break A5 of more than 25% and allows a very good cold working of the semi-finished products.
- a subsequent heat treatment by austenitizing above Ac3 and cooling in air high strengths are achieved.
- strengths Rm in the range from 1100 MPa to 1400 MPa are achieved at yield strengths in the range from 850 MPa to 1050 MPa and strains A5 in the range from 10% to 16%.
- a subsequent tempering treatment each desired strength / expansion ratios can be adjusted. For example, a subsequent tempering treatment at 600 ° C reduces the strength to 880 MPa at an elongation A5 of 16%.
- the increased process reliability during thermoforming or hardening in the forming tool is a significant advantage in the production of the workpieces from the steel alloy according to the invention.
- the problem may arise that arise between the cold tool and the abhorred structural component geometry-dependent air gaps, which inevitably adversely affect the homogeneity of the desired high cooling rate in the forming tool.
- an inventive workpiece made of the air-hardening steel material can be produced by thermoforming with increased process reliability getting produced.
- Workpieces made of conventional water-quenched materials sometimes show local tensile strengths Rm of less than 850 MPa in areas which, due to errors in the tool geometry, led to uneven cooling conditions.
- the material according to the invention exhibits a homogeneous tensile strength of more than 1,300 MPa in the tool-tempered state, even in the case of significant irregularities in the process.
- workpieces according to the invention have advantages in terms of weldability and in terms of tempering behavior.
- Usual steels for tooling e.g. a 25MnB5 steel show disadvantageously in the region of the weld hard toes and in the heat affected zone a hardness drop, so that the component properties are significantly deteriorated in welded areas, So is e.g. For workpieces from a 25MnB5, a drop in hardness to well below 300 HV can be observed.
- Welding tests on workpieces according to the invention have shown that in the area of the welding zone and the heat-affected zone of the air-hardened or tool-tempered components, no appreciable hardening and no appreciable hardness drop are to be observed.
- Thermoformed or air hardened workpieces of the present invention may also provide corrosion protection benefits, although it is generally difficult to achieve the highest corrosion protection requirements for thermoformed components.
- Highest corrosion protection requirements can be achieved with zinc coatings.
- a conventional electrochemical galvanizing of high-strength thermoformed workpieces is not possible, since there is an embrittlement or cracking due to the influence of hydrogen.
- a downstream thermal galvanizing in a molten zinc leads in the hitherto customary workpieces made of water-resistant steels adversely to a high decrease in strength, which almost completely abolishes the tempering effect of the hot forming.
- the use of hot-dip aluminized sheets disadvantageously has the significantly poorer corrosion protection of aluminum compared to zinc, Difficulties in processing, for example, by the formation of adhesions on the forming tools, as well as high costs.
- the workpieces according to the invention made from the steel alloy according to the invention advantageously permit thermal galvanization without substantial loss of strength. It could even be shown that after hot-dip galvanizing in a zinc-aluminum melt at a process temperature of 400-450 ° C, the yield strength of the thermoformed components increased from 1,000 MPa to over 1,100 MPa. This can be produced at the same time advantageously high-strength and highly corrosion-resistant workpieces.
- Workpieces according to the invention also show the advantage of low-heat-treatment.
- air hardening the surface can be better protected against scaling, which has an advantageous effect on subsequent processing and coating processes.
- Workpieces produced according to the invention are preferably suitable for seamless or welded steel pipes.
- workpieces can be used as thick-walled, torque-transmitting components in the form of drive shafts, transmission shafts or camshafts for motor vehicles.
- workpieces according to the invention can be used for the construction of welded or brazed assemblies, in particular for the production of materially bonded frame structures for motor vehicles, such as e.g. Grid frame, where high strength requirements also exist in the region of the joining zone, are used.
- the workpieces can be used advantageously as Achsbau former for motor vehicles.
- Workpieces according to the invention may preferably be used in a forming tool for use as motor vehicle construction parts be hardened, since it is precisely in this area that essential process steps can be optimized.
- the automotive components in the cured state may have tensile strengths Rm in a range of from 1,200 MPa to 1,500 MPa at a yield point Rp 0.2> 900 MPa and at an elongation at break A5 in a range of 8% -16%.
- tensile strengths Rm in a range of from 1,200 MPa to 1,500 MPa at a yield point Rp 0.2> 900 MPa and at an elongation at break A5 in a range of 8% -16%.
- tensile strengths Rm of> 1,000 MPa with a yield strength Rp 0.2> 750 MPa and with an elongation at break A5> 14% result in the air-hard state.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Articles (AREA)
- Forging (AREA)
- Heat Treatment Of Steel (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006033813 | 2006-07-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1881083A1 true EP1881083A1 (fr) | 2008-01-23 |
EP1881083B1 EP1881083B1 (fr) | 2009-12-30 |
Family
ID=38577445
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07014185A Not-in-force EP1881083B1 (fr) | 2006-07-19 | 2007-07-19 | Pièce en acier à haute résistance mécanique et sa utilisation |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP1881083B1 (fr) |
AT (1) | ATE453733T1 (fr) |
DE (2) | DE102007033950A1 (fr) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CZ305430B6 (cs) * | 2010-01-06 | 2015-09-16 | Benteler Automobiltechnik Gmbh | Způsob k tváření za tepla a kalení výstřižku |
WO2017006159A1 (fr) | 2015-07-09 | 2017-01-12 | Arcelormittal | Acier pour une trempe à la presse et pièce trempée à la presse fabriquée à partir d'un tel acier |
WO2017085135A1 (fr) * | 2015-11-16 | 2017-05-26 | Benteler Steel/Tube Gmbh | Alliage d'acier présentant une grande capacité d'absorption d'énergie et produit en forme de tube à base d'acier |
DE102011012428B4 (de) | 2011-02-23 | 2018-03-29 | Adient Luxembourg Holding S.à.r.l. | Beschlag für einen Fahrzeugsitz |
WO2018220430A1 (fr) | 2017-06-02 | 2018-12-06 | Arcelormittal | Tôle d'acier destinée à la fabrication de pièces trempées à la presse, pièce trempée à la presse présentant une association de résistance élevée et de ductilité d'impact, et procédés de fabrication de cette dernière |
CN114174542A (zh) * | 2019-05-27 | 2022-03-11 | 德国沙士基达板材有限公司 | 用于由成形的高强度钢制造焊接构件的方法和用于此目的的构件 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008051992B4 (de) | 2008-10-16 | 2011-03-24 | Benteler Automobiltechnik Gmbh | Verfahren zur Herstellung eines Werkstücks, Werkstück und Verwendung eines Werkstückes |
DE102019123334A1 (de) | 2019-08-30 | 2021-03-04 | Mannesmann Precision Tubes Gmbh | Stahlwerkstoff für eine Antriebswelle, Verfahren zur Herstellung einer Antriebswelle aus diesem Stahlwerkstoff und Antriebswelle hieraus |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05302119A (ja) * | 1992-03-27 | 1993-11-16 | Sumitomo Metal Ind Ltd | 高強度自動車部品の製造方法 |
EP0576107A1 (fr) * | 1992-06-10 | 1993-12-29 | MANNESMANN Aktiengesellschaft | Utilisation d'un acier pour la fabrication de tubes |
JPH07331381A (ja) * | 1994-06-06 | 1995-12-19 | Nippon Steel Corp | 高強度高靭性継目無鋼管およびその製造法 |
EP1565588B1 (fr) * | 2002-11-27 | 2006-03-22 | Benteler Stahl/Rohr Gmbh | Utilisation d'un alliage d'acier comme matiere premiere pour la production de composants tubulaires a paroi epaisse destines a des vehicules automobiles |
DE102004053620A1 (de) * | 2004-11-03 | 2006-05-04 | Salzgitter Flachstahl Gmbh | Hochfester, lufthärtender Stahl mit ausgezeichneten Umformeigenschaften |
-
2007
- 2007-07-19 DE DE102007033950A patent/DE102007033950A1/de not_active Ceased
- 2007-07-19 AT AT07014185T patent/ATE453733T1/de active
- 2007-07-19 EP EP07014185A patent/EP1881083B1/fr not_active Not-in-force
- 2007-07-19 DE DE502007002467T patent/DE502007002467D1/de active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05302119A (ja) * | 1992-03-27 | 1993-11-16 | Sumitomo Metal Ind Ltd | 高強度自動車部品の製造方法 |
EP0576107A1 (fr) * | 1992-06-10 | 1993-12-29 | MANNESMANN Aktiengesellschaft | Utilisation d'un acier pour la fabrication de tubes |
JPH07331381A (ja) * | 1994-06-06 | 1995-12-19 | Nippon Steel Corp | 高強度高靭性継目無鋼管およびその製造法 |
EP1565588B1 (fr) * | 2002-11-27 | 2006-03-22 | Benteler Stahl/Rohr Gmbh | Utilisation d'un alliage d'acier comme matiere premiere pour la production de composants tubulaires a paroi epaisse destines a des vehicules automobiles |
DE102004053620A1 (de) * | 2004-11-03 | 2006-05-04 | Salzgitter Flachstahl Gmbh | Hochfester, lufthärtender Stahl mit ausgezeichneten Umformeigenschaften |
Non-Patent Citations (1)
Title |
---|
KATSUMATA M ET AL: "DEVELOPMENT OF HIGH STRENGTH AND HIGH TOUGHNESS LOW CARBON - LOW ALLOY STEEL FOR HOT FORGED PARTS", KOBELCO TECHNOLOGY REVIEW, KOBE STEEL, KOBE, JP, no. 11, June 1991 (1991-06-01), pages 29 - 32, XP001038795, ISSN: 0913-4794 * |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CZ305430B6 (cs) * | 2010-01-06 | 2015-09-16 | Benteler Automobiltechnik Gmbh | Způsob k tváření za tepla a kalení výstřižku |
DE102011012428B4 (de) | 2011-02-23 | 2018-03-29 | Adient Luxembourg Holding S.à.r.l. | Beschlag für einen Fahrzeugsitz |
EP3591079A1 (fr) | 2015-07-09 | 2020-01-08 | ArcelorMittal | Acier pour le durcissement à la presse et pièce durcie à la presse fabriquée à partir d'un tel en acier |
EP3604564A1 (fr) | 2015-07-09 | 2020-02-05 | ArcelorMittal | Acier pour une trempe à la presse et pièce trempée à la presse fabriquée à partir d'un tel acier |
WO2017006144A1 (fr) | 2015-07-09 | 2017-01-12 | Arcelormittal | Acier pour trempe à la presse et pièce trempée à la presse fabriquée à partir d'un tel acier |
US11814696B2 (en) | 2015-07-09 | 2023-11-14 | Arcelormittal | Steel for press hardening and press hardened part manufactured from such steel |
EP4234746A2 (fr) | 2015-07-09 | 2023-08-30 | ArcelorMittal | Acier pour une trempe à la presse et pièce trempée à la presse fabriquée à partir d'un tel acier |
US11319610B2 (en) | 2015-07-09 | 2022-05-03 | Arcelormittal | Steel for press hardening and press hardened part manufactured from such steel |
WO2017006159A1 (fr) | 2015-07-09 | 2017-01-12 | Arcelormittal | Acier pour une trempe à la presse et pièce trempée à la presse fabriquée à partir d'un tel acier |
US11384415B2 (en) | 2015-11-16 | 2022-07-12 | Benteler Steel/Tube Gmbh | Steel alloy with high energy absorption capacity and tubular steel product |
WO2017085135A1 (fr) * | 2015-11-16 | 2017-05-26 | Benteler Steel/Tube Gmbh | Alliage d'acier présentant une grande capacité d'absorption d'énergie et produit en forme de tube à base d'acier |
CN108474080A (zh) * | 2015-11-16 | 2018-08-31 | 本特勒尔钢管有限公司 | 具有高能量吸收能力的钢合金和钢管产品 |
WO2018220598A1 (fr) | 2017-06-02 | 2018-12-06 | Arcelormittal | Tôle d'acier pour la production de pièces trempées sous presse, pièce trempée sous presse présentant une combinaison de résistance élevée et de ductilité élevée après collision, et procédés de production associés |
US11629388B2 (en) | 2017-06-02 | 2023-04-18 | Arcelormittal | Steel sheet for manufacturing press hardened parts, press hardened part having a combination of high strength and crash ductility, and manufacturing methods thereof |
WO2018220430A1 (fr) | 2017-06-02 | 2018-12-06 | Arcelormittal | Tôle d'acier destinée à la fabrication de pièces trempées à la presse, pièce trempée à la presse présentant une association de résistance élevée et de ductilité d'impact, et procédés de fabrication de cette dernière |
CN114174542A (zh) * | 2019-05-27 | 2022-03-11 | 德国沙士基达板材有限公司 | 用于由成形的高强度钢制造焊接构件的方法和用于此目的的构件 |
Also Published As
Publication number | Publication date |
---|---|
ATE453733T1 (de) | 2010-01-15 |
EP1881083B1 (fr) | 2009-12-30 |
DE502007002467D1 (de) | 2010-02-11 |
DE102007033950A1 (de) | 2008-01-31 |
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