EP1859088B1 - Brandschutzstoff - Google Patents

Brandschutzstoff Download PDF

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Publication number
EP1859088B1
EP1859088B1 EP20060726086 EP06726086A EP1859088B1 EP 1859088 B1 EP1859088 B1 EP 1859088B1 EP 20060726086 EP20060726086 EP 20060726086 EP 06726086 A EP06726086 A EP 06726086A EP 1859088 B1 EP1859088 B1 EP 1859088B1
Authority
EP
European Patent Office
Prior art keywords
type
threads
warp
thread
para
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP20060726086
Other languages
English (en)
French (fr)
Other versions
EP1859088A1 (de
Inventor
Laurent Thiriot
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kermel SNC
Original Assignee
Kermel SNC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kermel SNC filed Critical Kermel SNC
Publication of EP1859088A1 publication Critical patent/EP1859088A1/de
Application granted granted Critical
Publication of EP1859088B1 publication Critical patent/EP1859088B1/de
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/08—Heat resistant; Fire retardant
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3976—Including strand which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous composition, water solubility, heat shrinkability, etc.]
    • Y10T442/3984—Strand is other than glass and is heat or fire resistant

Definitions

  • the present invention relates to the field of fire protection. It relates more particularly to a protective fabric for forming the outer layer of a fire protection garment, for example a firefighter's clothing.
  • thermostable or thermoreactive fibers fabrics made from said fibers and clothing made from these fabrics.
  • fibers commonly used in the manufacture of protective clothing against fire known fibers known aramids, whether para-aramids or meta-aramids, for example, the Kermel fiber which belongs to the chemical family of imide polyamides, for example Nomex® fiber which is a polymetaphenilene isophthalamide.
  • Kevlar® The fibers sold under the names Kevlar®, Twaron® and Technora® are also known.
  • a firefighter's clothing must, in addition to its fire properties, meet the same aesthetic requirements as any other garment, in particular having an acceptable or at least reproducible external visual appearance of a garment. to the other.
  • a protective fabric intended to form the outer layer of a fire protection garment use is made of para-aramid type yarns that do not have such a defect, for example the yarns marketed under the names Kevlar®, Twaron® and Technora®.
  • Such a protective fabric is known to WO 00/66823 A .
  • these wires have another disadvantage which lies in the fact that they are sensitive to ultraviolet, and that, when dyed, they have poor color fastness to light. This is why these para-aramid yarns are more and more often used in fabrics of the double fabric type, so that said yarns are arranged on the inner face of the outer layer of the garment. that is, the face that is not directly exposed to light and ultraviolet light.
  • This implementation has a major drawback which consists in having to increase the surface density of the fabric if a relatively high proportion of para-aramid-type yarns is chosen, for example fabrics making at least 300 g / m 2 if the we want on the order of 50% of son of para-aramid type.
  • a relatively high proportion of para-aramid-type yarns for example fabrics making at least 300 g / m 2 if the we want on the order of 50% of son of para-aramid type.
  • the proportion of para-aramid-type yarns for example 10% of para-aramid yarns, must be significantly reduced.
  • the object of the present invention is to provide a protective fabric capable of forming the outer layer of a protective clothing against fire, which overcomes the disadvantages mentioned above.
  • the same garment may have variations in appearance if the cut panels for the confection are taken in remote areas of the same room or two clothes will have different visual aspects depending on whether the panels used for their manufacture come from the beginning or from the end of the room.
  • the contrast of colors concerns only the width of the fabric, generally between 1.50 m and 1.60 m since it is the same weft thread that crosses the warp threads all the way across.
  • a weft mixer it is also possible, with a weft mixer, to use several coils in turn to form the picks and thus reduce the effect of the color variation of the weft son by a statistical mixture.
  • para-aramid yarns which do not exhibit hue variations but are more sensitive to ultraviolet, they are only used in a chain and the fact that they are almost completely masked avoids the problem of degradation due to the action of light and ultraviolet light.
  • the son of the second and possibly the third type represent from 30 to 50% of the warp son and the son of the second type from 30 to 50% of the weft son.
  • the son of the first and second type are of the order of 12 to 16 tex X 2.
  • the subject fabric has a basic armor having in chain the following arrangement: a wire of the first type, a wire of the second type and two son of the first type and in weft an alternation of son of the first and of the second type.
  • the meta-aramid fibers are generally mixed with a small percentage of anti-static fibers, in particular Belltron® fibers or other fibers, charge dissipators or conductive fibers.
  • the yarns of the first type are 14.3 tex X 2 meta-aramid meta-aramid threads (more commonly called Nm 70/2) composed of 99% meta-aramid fibers known under the name Kermel®. and 1% of anti-static fibers.
  • the son of the second type are para-aramid type son 14.3 tex X 2, high modulus, with color variations along their length. This is for example son known as Rusar ®. It may also be son known under the name Armos ®, SVM ® or AuTx-HT ®. These are continuous filament yarns.
  • the warping pattern is 3 son of meta-aramid type (K for KERMEL ®) for a para-aramid type wire (P for para-aramid).
  • the screening pattern it is of a meta-aramid yarn (K) for a para-aramid yarn (P).
  • the texture of the fabric is 52 X 22 threads / cm.
  • Its surface mass is of the order of 220 gr / m 2 , with a final proportion of 66.3% of meta-aramid fibers, 33% of para-aramid fibers and 0.7% of anti-static fibers.
  • each unitary pattern (4 ⁇ 4) having the armor illustrated the high modulus para-aramid type warp yarns are alternately visible in front and back in a ratio of 1 to 3.
  • the meta-aramid (K) warp yarn that is the furthest left of the weave pattern will tend to go over the para-aramid chain (P) so that said warp is actually almost completely masked on the face of the fabric.
  • the second example differs from the first by the basic armor, of the double-sided warp armor type, which is illustrated in the figure 2 , in which the warping pattern is also of three meta-aramid type yarns for a para-aramid type yarn and the screening pattern is also of a meta-aramid type yarn for a para-aramid type yarn .
  • all the para-aramid warp and weft threads can be of the second type, but all the para-aramid warp threads of the third type can also be used.
  • the present invention is not limited to the embodiments described and illustrated as non-exhaustive examples.
  • other armor for example an armor in which the warping pattern is four son of the first type for a wire of the second type and the dithering pattern of a wire of the first type for a wire of the second type, for better density and better masking son of the second type chain, while remaining in the desired surface masses and with a proportion of the order of 30% of the son of the second type.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Woven Fabrics (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Fireproofing Substances (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Laminated Bodies (AREA)

Claims (8)

  1. Schutzgewebe mit einer Oberflächenmasse kleiner als 300 g/m2, weiches vorgesehen ist, eine Außenschicht einer Schutzkleidung gegen Feuer auszubilden, zum Beispiel einer Bekleidung für einen Feuerwehrmann, dadurch gekennzeichnet, daß es aus Kett- und Schußfäden besteht, die zu wenigstens zwei Typen von feuerbeständigen Fäden gehören, nämlich einem ersten Typ von Fäden vom Meta-Aramid-Typ, einem zweiten Typ von Fäden vom Para-Aramid-Typ mit hohem Modul, welche über ihre Länge Tönungsvariationen aufweisen, und gegebenenfalls, in der Kette, einem dritten Typ von Fäden vom Para-Aramid-Typ, der keine Tönungsvariationen aufweist, aber UV-empfindlich ist, und dadurch, daß es 15 - 50% von Fäden des zweiten und gegebenenfalls des dritten Typs aufweist und daß die Bindungsart des Gewebes vom Typ beidseitige Kette und derart festgelegt ist, daß auf der Außenseite des Gewebes die Kettfäden des zweiten und gegebenenfalls dritten Typs fast vollständig maskiert vorliegen.
  2. Gewebe nach Anspruch 1, dadurch gekennzeichnet, daß alle Kett- und Schußfäden aus Para-Aramid vom zweiten Typ sind.
  3. Gewebe nach Anspruch 1, dadurch gekennzeichnet, daß alle Kett- und Schußfäden aus Para-Aramid vom dritten Typ sind.
  4. Gewebe nach Anspruch 1 bis 3, dadurch gekennzeichnet, daß die Fäden vom zweiten Typ und gegebenenfalls vom dritten Typ 30 - 50% der Kettfäden darstellen und die Fäden des zweiten Typs 30 - 50% der Schußfäden.
  5. Gewebe nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß die Fäden des ersten und zweiten Typs in der Größenordnung von 24 bis 32 tex an einem oder zwei Enden liegen.
  6. Gewebe nach einem der Ansprüche 1 bis 5, gekennzeichnet durch eine Grundbindungsart, die ein Kettbaummuster mit drei Fäden des ersten Typs für einen Faden des zweiten Typs aufweist und ein Schußmuster mit einem Faden des ersten Typs für einen Faden des zweiten Typs aufweist.
  7. Gewebe nach Anspruch 6, das in der Größenordnung von 220 g/m2 liegt und einen endgültigen Anteil von 66,3 % Meta-Aramid, 33 % Para-Aramid und 0,7 % antistatischer Fasern hat.
  8. Gewebe nach einem der Ansprüche 1 bis 5, gekennzeichnet durch eine Grundbindungsart, die ein Kettbaummuster mit vier Fäden des ersten Typs für einen Faden des zweiten Typs und ein Schußmuster mit einem Faden des ersten Typs für einen Faden des zweiten Typs aufweist.
EP20060726086 2005-03-16 2006-03-14 Brandschutzstoff Not-in-force EP1859088B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0502600A FR2883134B1 (fr) 2005-03-16 2005-03-16 Tissu de protection contre le feu
PCT/FR2006/000559 WO2006097620A1 (fr) 2005-03-16 2006-03-14 Tissu de protection contre le feu

Publications (2)

Publication Number Publication Date
EP1859088A1 EP1859088A1 (de) 2007-11-28
EP1859088B1 true EP1859088B1 (de) 2010-06-02

Family

ID=35355938

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20060726086 Not-in-force EP1859088B1 (de) 2005-03-16 2006-03-14 Brandschutzstoff

Country Status (11)

Country Link
US (1) US20080153374A1 (de)
EP (1) EP1859088B1 (de)
JP (1) JP4885941B2 (de)
AT (1) ATE469999T1 (de)
AU (1) AU2006224461B2 (de)
CA (1) CA2600255C (de)
DE (1) DE602006014662D1 (de)
ES (1) ES2346688T3 (de)
FR (1) FR2883134B1 (de)
NZ (1) NZ560449A (de)
WO (1) WO2006097620A1 (de)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103221597B (zh) * 2010-07-29 2015-04-15 德里菲尔有限责任公司 阻燃织物和服装
DE202010011193U1 (de) * 2010-08-09 2010-11-04 Ibena Textilwerke Gmbh Gewebe für eine Schutzbekleidung und Schutzbekleidung
US11160320B2 (en) 2016-04-05 2021-11-02 Teijin Limited Fabric, multilayer structured fabric, and fiber product
ES2928336T3 (es) 2016-08-19 2022-11-17 Strauss Levi & Co Acabado de confección con láser
WO2018084040A1 (ja) * 2016-11-01 2018-05-11 帝人株式会社 布帛およびその製造方法および繊維製品
CN111527493A (zh) 2017-10-31 2020-08-11 利惠商业有限公司 在创建服饰设计时使用神经网络
US10712922B2 (en) 2017-10-31 2020-07-14 Levi Strauss & Co. Laser finishing design tool with damage assets
US10618133B1 (en) 2018-02-27 2020-04-14 Levis Strauss & Co. Apparel design system with intelligent asset placement
WO2019168879A1 (en) 2018-02-27 2019-09-06 Levi Strauss & Co. On-demand manufacturing of laser-finished apparel
US10883223B2 (en) 2018-08-07 2021-01-05 Levi Strauss & Co. Laser finishing design tool
WO2020113236A1 (en) 2018-11-30 2020-06-04 Levi Strauss & Co. Shadow neutral 3-d garment rendering
CN114423896A (zh) 2019-07-23 2022-04-29 利惠商业有限公司 对激光精加工服装的三维渲染预览

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9909850D0 (en) * 1999-04-28 1999-06-23 Hainsworth A W & Sons Ltd Fire resistant textile material
WO2002020887A2 (en) * 2000-09-07 2002-03-14 A W Hainsworth & Sons Ltd Fire resistant textile material
US20030228812A1 (en) * 2002-06-07 2003-12-11 Southern Mills, Inc. Flame resistant fabrics comprising filament yarns
JP2004161850A (ja) * 2002-11-12 2004-06-10 Mitsubishi Rayon Co Ltd 難燃性シート状物
ITVI20030037A1 (it) * 2003-02-25 2004-08-26 Q2 Roma Srl Tessuto ad elevate proprieta' ignifughe.
DE202004005008U1 (de) * 2004-03-30 2004-06-24 E.I. Du Pont De Nemours And Company, Wilmington Textiles Flächengebilde für Schutzbekleidung

Also Published As

Publication number Publication date
ATE469999T1 (de) 2010-06-15
FR2883134B1 (fr) 2007-06-22
EP1859088A1 (de) 2007-11-28
WO2006097620A1 (fr) 2006-09-21
AU2006224461B2 (en) 2011-12-22
ES2346688T3 (es) 2010-10-19
FR2883134A1 (fr) 2006-09-22
JP4885941B2 (ja) 2012-02-29
AU2006224461A1 (en) 2006-09-21
NZ560449A (en) 2011-03-31
JP2008533321A (ja) 2008-08-21
CA2600255A1 (fr) 2006-09-21
US20080153374A1 (en) 2008-06-26
DE602006014662D1 (de) 2010-07-15
CA2600255C (fr) 2012-04-03

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