EP1858329A1 - Melanges fongicides a base d'un derive de triazolopyrimidine - Google Patents
Melanges fongicides a base d'un derive de triazolopyrimidineInfo
- Publication number
- EP1858329A1 EP1858329A1 EP05732318A EP05732318A EP1858329A1 EP 1858329 A1 EP1858329 A1 EP 1858329A1 EP 05732318 A EP05732318 A EP 05732318A EP 05732318 A EP05732318 A EP 05732318A EP 1858329 A1 EP1858329 A1 EP 1858329A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- compound
- mixtures
- compounds
- formula
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Definitions
- the present invention relates to fungicidal mixtures containing as active components
- the invention also relates to a method for controlling harmful fungi with mixtures of the compound I with the compound II and the use of the compound I with the compound II for the production of such mixtures and agents which contain these mixtures.
- the compound I 5-chloro-7- (4-methyl-piperidin-1-yl) -6- (2,4,6-trifluorophenyl) - [1,2,4] tri-azolo [1, 5 -a] pyrimidine, its preparation and its action against harmful fungi is known from the literature (WO 98/46607).
- the compound II, 1- (3,5-dichlorophenyl) -2-pyridin-3-ylethanone-O-methyloxime, its preparation and its action against harmful fungi is also known from the literature (EP-A 49854; common name: pyrifenox).
- the mixtures of the compound I and the compound II or the simultaneous joint or separate use of the compound I and the compound II are distinguished by an outstanding activity against a broad spectrum of phytopathogenic fungi, in particular from the class of the Ascomycetes, Deuteromyces ten, Oomycetes and Basidiomycetes. They can be used in plant protection as leaf, pickling and soil fungicides.
- the compound I and the compound II can be applied simultaneously together or separately or in succession, the sequence in the case of separate application generally not having any effect on the success of the control measures.
- Pests such as insects, arachnids or nematodes, or herbicidal or growth-regulating active ingredients or fertilizers.
- Fungicides selected from the following group are particularly suitable as further active ingredients in the above sense:
- Acylalanines such as benalaxyl, metalaxyl, ofurace, oxadixyl,
- Amine derivatives such as aldimorph, dodine, dodemorph, fenpropimorph, fenpropidine, guazatine, iminoctadine, spiroxamine, tridemorph • anilinopyrimidines such as pyrimethanil, mepanipyrim or cyprodinil, •
- Antibiotics such as cycloheximide, griseofulvin, kasugamycin, natamycin, polyoxin or streptomycin,
- Azoles such as bitertanol, bromoconazole, cyproconazole, difenoconazole, dinitroconazole, enilconazole, epoxiconazole, fenbuconazole, fluquiconazole, flusilazole, flutriafol, hexaconazole, imazalil, ipconazole, metconazol, penocolazolol, myocazolol, myocazolol, myclazol, myclazol, myclazol, myocazolol, myclazol, myclazol, myclazol, myclazol, myclazol, myclazol, myclazol, myclazol, myclazol, myclazol , Tetraconazole, tri-dimefon, triadimenol, triflumizole, triticonazole,
- Dicarboximides such as iprodione, myclozolin, procymidone, vinclozolin,
- Dithiocarbamates such as Ferbam, Nabam, Maneb, Mancozeb, Metam, Metiram, Propineb, Polycarbamat, Thiram. Ziram, Zineb,
- Heterocyclic compounds such as anilazine, benomyl, boscalid, carbendazim, carboxin, oxycarboxin, cyazofamid, dazomet, dithianon, famoxadone, fenamidon, fenarimol, isoprothiolan, pentazolidolid, prozolidolid, prozolid Pyroquilone, quinoxyfen, silthiofam, thiabendazole, thifluzamide, thiophanate-methyl, tiadinil, tricyclazole, tri-forine,
- Copper fungicides such as Bordeaux broth, copper acetate, copper oxychloride, basic copper sulfate,
- Nitrophenyl derivatives such as binapacryl, dinocap, dinobutone, nitrophthal-isopropyl, phenylpyrroles such as fenpiclonil or fludioxonil, • sulfur,
- fungicides such as AcibenzoIar-S-methyl, Benthiavalicarb, Carpropamid, Chlo-rothalonil, Cyflufenamid, Cymoxanil, Diclomezin, Diclocymet, Diethofencarb, Edifenphos, Ethaboxam, Fenhexamid, Fentin-Acetate, Fenoxanyl, namim, Fosinzone, Fluorozone, Fluorozone Fosetyl aluminum, iprovalicarb, hexachlorobenzene, mandipropamide, metrafenone, pencycuron, propamocarb, phosphorous acid, phthalide, toloclofos-methyl, quintozene, zoxamide,
- Strobilurins such as azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, cresoxim-methyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin or trifloxystrobin,
- Sulfenic acid derivatives such as Captafol, Captan, dichlofluanid, Folpet, Tolylfluanid
- Cinnamic acid amides and analogues such as dimethomorph, flumetover or flumorph.
- a further fungicide III or two fungicides III and IV are added to the compounds I and II.
- Mixtures of the compounds I and II with a component IM are preferred. Mixtures of compounds I and II are particularly preferred.
- the compound I and the compound II are usually used in a weight ratio of 100: 1 to 1: 100, preferably 20: 1 to 1:20, in particular 10: 1 to 1:10.
- components III and, if appropriate, IV are mixed in a ratio of 20: 1 to 1:20 to compound I.
- the application rates of the mixtures according to the invention are from 5 g / ha to 1000 g / ha, preferably 50 to 900 g / ha, in particular 50 to 750 g / ha.
- the application rates for the compound I are accordingly generally from 1 to 1000 g / ha, preferably from 10 to 900 g / ha, in particular from 20 to 750 g / ha.
- the application rates for the compound II are generally from 1 to 1000 g / ha, preferably from 10 to 900 g / ha, in particular from 40 to 750 g / ha.
- application rates of mixture of 1 to 1000 g / 100 kg of seed preferably 1 to 750 g / 100 kg, in particular 5 to 500 g / 100 kg, are generally used.
- the method for controlling harmful fungi is carried out by the separate or joint application of the compound I and the compound II or the mixtures of the compound I and the compound II by spraying or dusting the seeds, the plants or the soil before or after the plants are sown or before or after emergence of the plants.
- the mixtures according to the invention, or the compounds I and II, can be converted into the customary formulations, e.g. Solutions, emulsions, suspensions, dusts, powders, pastes and granules.
- the form of application depends on the respective purpose; in any case, it should ensure a fine and uniform distribution of the compound according to the invention.
- the formulations are prepared in a known manner, e.g. by stretching the active ingredient with solvents and / or carriers, if desired using emulsifiers and dispersants.
- solvents / auxiliaries water, aromatic solvents (for example Solvesso products, xylene), paraffins (for example petroleum fractions), alcohols (for example methanol, butanol, pentanol, benzyl alcohol), ketones (for example cyclohexanone, gamma-butryolactone) , Pyrrolidones (NMP, NOP), acetates (glycol diacetate), glycols, dimethyl fatty acid amides, fatty acids and fatty acid esters.
- aromatic solvents for example Solvesso products, xylene
- paraffins for example petroleum fractions
- alcohols for example methanol, butanol, pentanol, benzyl alcohol
- ketones for example cyclohexanone, gamm
- solvent mixtures can also be used, carriers such as natural stone powder (e.g. kaolins, clays, talc, chalk) and synthetic stone powder (e.g. highly disperse silica, silicates); Emulsifiers such as nonionic and anionic emulsifiers (e.g. polyoxyethylene fatty alcohol ethers, alkyl sulfonates and aryl sulfonates) and dispersants such as lignin sulfite liquors and methyl cellulose.
- carriers such as natural stone powder (e.g. kaolins, clays, talc, chalk) and synthetic stone powder (e.g. highly disperse silica, silicates); Emulsifiers such as nonionic and anionic emulsifiers (e.g. polyoxyethylene fatty alcohol ethers, alkyl sulfonates and aryl sulfonates) and dispersants such as lignin sulfite liquors and methyl
- Alkali metal, alkaline earth metal, ammonium salts of lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalenesulfonic acid, alkylarylsulfonates, alkyl sulfates, alkyl sulfonates, fatty alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers of sulfonate derivatives and condensation etherates are also used, as well as condensation ether derivatives with sulfonate derivatives and sulfonating derivatives
- Formaldehyde condensation products of naphthalene or naphthalene sulfonic acid with phenol and formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenol polyglycol ether, tribut
- Mineral oil fractions of medium to high boiling point such as kerosene or diesel oil, also coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, for example toluene, xy-, are used to produce directly sprayable solutions, emulsions, pastes or oil dispersions.
- lol paraffin, tetrahydronaphthalene, alkylated naphthalenes or their derivatives, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, strongly polar solvents, for example dimethyl sulfoxide, N-methylpyrrolidone or water.
- Powders, materials for broadcasting and dusts can be prepared by mixing or grinding the active substances together with a solid carrier.
- Granules e.g. Coating, impregnation and homogeneous granules can be produced by binding the active ingredients to solid carriers.
- Solid carriers are e.g. Mineral earths, such as silica gels, silicates, talc, kaolin, attack clay, limestone, lime, chalk, bolus, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulfate, magnesium oxide, ground plastics, fertilizers, e.g. Ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas and vegetable products such as cereal flour, tree bark, wood and nutshell flour, cellulose powder and other solid carriers.
- Mineral earths such as silica gels, silicates, talc, kaolin, attack clay, limestone, lime, chalk, bolus, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulfate, magnesium oxide, ground plastics,
- the formulations generally contain between 0.01 and 95% by weight, preferably between 0.1 and 90% by weight, of the active ingredients.
- the active ingredients are used in a purity of 90% to 100%, preferably 95% to 100% (according to the NMR spectrum).
- formulations are: 1. Products for dilution in water
- Emulsions EW, EO 40 parts by weight of the active ingredients are dissolved in xylene with the addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (5% each). This mixture is introduced into water using an emulsifying machine (Ultraturax) and brought to a homogeneous emulsion. Dilution in water results in an emulsion.
- EW Emulsions
- the active ingredients are finely ground with the addition of dispersing and wetting agents and produced using technical equipment (e.g. extrusion, spray tower, fluidized bed) as water-dispersible or water-soluble granules. Dilution in water results in a stable dispersion or solution of the active ingredient.
- technical equipment e.g. extrusion, spray tower, fluidized bed
- 75 parts by weight of the active ingredients are ground in a rotor-strator mill with the addition of dispersing and wetting agents and silica gel. Dilution in water results in a stable dispersion or solution of the active ingredient.
- Dusts (DP) 5 parts by weight of the active ingredients are finely ground and intimately mixed with 95% finely divided kaolin. This gives a dust.
- the active ingredients as such, in the form of their formulations or the use forms prepared therefrom, for example in the form of directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dusts, scattering agents, granules by spraying, atomizing, dusting, scattering or Pouring can be applied.
- the application forms depend entirely on the purposes; in any case, they should ensure the finest possible distribution of the active compounds according to the invention.
- Aqueous application forms can be prepared from emulsion concentrates, pastes or wettable powders (wettable powders, oil dispersions) by adding water.
- emulsions, pastes or oil dispersions the substances as such or dissolved in an oil or solvent can be homogenized in water by means of wetting agents, adhesives, dispersants or emulsifiers.
- concentrates composed of an active substance, wetting agents, adhesives, dispersants or emulsifiers and possibly solvents or oil, which are suitable for dilution with water.
- the active ingredient concentrations in the ready-to-use preparations can be varied over a wide range. In general, they are between 0.0001 and 10%, preferably between 0.01 and 1%.
- the active ingredients can also be used with great success in the ultra-low-volume process (ULV), it being possible to apply formulations with more than 95% by weight of active ingredient or even the active ingredient without additives.
- UUV ultra-low-volume process
- Oils of various types, wetting agents, adjuvants, herbicides, fungicides, other pesticides, bactericides can be added to the active compounds, if appropriate also only immediately before use (tank mix). These agents are usually added to the agents according to the invention in a weight ratio of 1:10 to 10: 1.
- the compounds I and II, or the mixtures or the corresponding formulations are used in that the harmful fungi, the plants, seeds, soils, surfaces, materials or spaces to be kept free from them are mixed with a fungicidally effective amount of the mixture or the compounds I and II when applied separately.
- the application can take place before or after the infestation by the harmful fungi.
- the fungicidal activity of the compound and the mixtures can be demonstrated by the following tests:
- the active ingredients were prepared separately or together as a stock solution with 0.25% by weight of active ingredient in acetone or DMSO. 1% by weight of emulsifier Uniperol® EL (wetting agent with emulsifying and dispersing action based on ethoxylated alkylphenols) was added to this solution and diluted with water to the desired concentration.
- emulsifier Uniperol® EL wetting agent with emulsifying and dispersing action based on ethoxylated alkylphenols
- Leaves of potted plants of the "Golden Princess” variety were sprayed to runoff point with an aqueous suspension in the active ingredient concentration given below. The following day, the leaves were infected with an aqueous spore suspension of Alternaria solani in 2% biomalt solution with a density of 0.17 x 10 6 spores / ml. The plants were then placed in a water vapor-saturated chamber at temperatures between 20 and 22 ° C. After 5 days the disease had developed so strongly on the untreated but infected control plants that the infestation could be determined visually in%.
- ⁇ corresponds to the fungal attack of the treated plants in% and ß corresponds to the fungal attack of the untreated (control) plants in%
- the infection of the treated plants corresponds to that of the untreated control plants; with an efficiency of 100, the treated plants show no infection.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Catching Or Destruction (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004020846 | 2004-04-27 | ||
PCT/EP2005/003997 WO2005104849A1 (fr) | 2004-04-27 | 2005-04-15 | Melanges fongicides |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1858329A1 true EP1858329A1 (fr) | 2007-11-28 |
Family
ID=34964634
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05732318A Withdrawn EP1858329A1 (fr) | 2004-04-27 | 2005-04-15 | Melanges fongicides a base d'un derive de triazolopyrimidine |
Country Status (17)
Country | Link |
---|---|
US (1) | US20070232625A1 (fr) |
EP (1) | EP1858329A1 (fr) |
JP (1) | JP2007534712A (fr) |
KR (1) | KR20070007948A (fr) |
CN (1) | CN1949972A (fr) |
AR (1) | AR048714A1 (fr) |
AU (1) | AU2005237221A1 (fr) |
BR (1) | BRPI0509093A (fr) |
CA (1) | CA2559245A1 (fr) |
CR (1) | CR8582A (fr) |
EA (1) | EA200601840A1 (fr) |
EC (1) | ECSP066945A (fr) |
IL (1) | IL177776A0 (fr) |
NO (1) | NO20065056L (fr) |
NZ (1) | NZ549922A (fr) |
TW (1) | TW200605789A (fr) |
WO (1) | WO2005104849A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009143814A (ja) * | 2007-12-11 | 2009-07-02 | Japan Enviro Chemicals Ltd | 防かび組成物 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1225092A (fr) * | 1980-10-10 | 1987-08-04 | Franz Dorn | Derives de pyridine et de pyrazine |
JPH0232003A (ja) * | 1988-07-21 | 1990-02-01 | Nippon Kayaku Co Ltd | 種子消毒剤 |
US5593996A (en) * | 1991-12-30 | 1997-01-14 | American Cyanamid Company | Triazolopyrimidine derivatives |
TWI252231B (en) * | 1997-04-14 | 2006-04-01 | American Cyanamid Co | Fungicidal trifluorophenyl-triazolopyrimidines |
US5994360A (en) * | 1997-07-14 | 1999-11-30 | American Cyanamid Company | Fungicidal 5-alkyl-triazolopyrimidines |
US6268371B1 (en) * | 1998-09-10 | 2001-07-31 | American Cyanamid Co. | Fungicidal mixtures |
SI0988790T1 (en) * | 1998-09-25 | 2003-10-31 | Basf Aktiengesellschaft | Fungicidal mixtures |
US6346535B1 (en) * | 1999-01-29 | 2002-02-12 | American Cyanamid Company | Fungicidal mixtures |
-
2005
- 2005-04-15 CA CA002559245A patent/CA2559245A1/fr not_active Abandoned
- 2005-04-15 JP JP2007509918A patent/JP2007534712A/ja not_active Withdrawn
- 2005-04-15 KR KR1020067024688A patent/KR20070007948A/ko not_active Application Discontinuation
- 2005-04-15 EA EA200601840A patent/EA200601840A1/ru unknown
- 2005-04-15 CN CNA2005800136157A patent/CN1949972A/zh active Pending
- 2005-04-15 US US11/587,939 patent/US20070232625A1/en not_active Abandoned
- 2005-04-15 NZ NZ549922A patent/NZ549922A/en unknown
- 2005-04-15 AU AU2005237221A patent/AU2005237221A1/en not_active Abandoned
- 2005-04-15 BR BRPI0509093-8A patent/BRPI0509093A/pt not_active IP Right Cessation
- 2005-04-15 WO PCT/EP2005/003997 patent/WO2005104849A1/fr active Application Filing
- 2005-04-15 EP EP05732318A patent/EP1858329A1/fr not_active Withdrawn
- 2005-04-27 TW TW094113364A patent/TW200605789A/zh unknown
- 2005-04-27 AR ARP050101658A patent/AR048714A1/es not_active Application Discontinuation
-
2006
- 2006-08-30 CR CR8582A patent/CR8582A/es not_active Application Discontinuation
- 2006-08-30 IL IL177776A patent/IL177776A0/en unknown
- 2006-10-23 EC EC2006006945A patent/ECSP066945A/es unknown
- 2006-11-02 NO NO20065056A patent/NO20065056L/no not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO2005104849A1 * |
Also Published As
Publication number | Publication date |
---|---|
CA2559245A1 (fr) | 2005-11-10 |
NO20065056L (no) | 2006-11-21 |
TW200605789A (en) | 2006-02-16 |
CN1949972A (zh) | 2007-04-18 |
EA200601840A1 (ru) | 2007-04-27 |
KR20070007948A (ko) | 2007-01-16 |
IL177776A0 (en) | 2006-12-31 |
CR8582A (es) | 2007-06-08 |
AR048714A1 (es) | 2006-05-17 |
JP2007534712A (ja) | 2007-11-29 |
BRPI0509093A (pt) | 2007-08-28 |
AU2005237221A1 (en) | 2005-11-10 |
WO2005104849A1 (fr) | 2005-11-10 |
ECSP066945A (es) | 2007-01-26 |
NZ549922A (en) | 2009-05-31 |
US20070232625A1 (en) | 2007-10-04 |
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Legal Events
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Ipc: A01P 3/00 20060101ALI20081010BHEP Ipc: A01N 43/40 20060101ALI20081010BHEP Ipc: A01N 43/90 20060101AFI20081010BHEP |
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