EP1825943B1 - Coated cutting tool - Google Patents
Coated cutting tool Download PDFInfo
- Publication number
- EP1825943B1 EP1825943B1 EP05814749.7A EP05814749A EP1825943B1 EP 1825943 B1 EP1825943 B1 EP 1825943B1 EP 05814749 A EP05814749 A EP 05814749A EP 1825943 B1 EP1825943 B1 EP 1825943B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- coating
- mpa
- cutting tool
- stress
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000005520 cutting process Methods 0.000 title claims description 93
- 238000000576 coating method Methods 0.000 claims description 133
- 239000011248 coating agent Substances 0.000 claims description 132
- 239000000758 substrate Substances 0.000 claims description 43
- 239000013078 crystal Substances 0.000 claims description 21
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
- 229910052760 oxygen Inorganic materials 0.000 claims description 14
- 239000001301 oxygen Substances 0.000 claims description 14
- 229910052594 sapphire Inorganic materials 0.000 claims description 12
- 229910052796 boron Inorganic materials 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 230000000737 periodic effect Effects 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- 229910052727 yttrium Inorganic materials 0.000 claims description 7
- 238000000034 method Methods 0.000 description 29
- 239000011247 coating layer Substances 0.000 description 16
- 238000005259 measurement Methods 0.000 description 12
- 238000009826 distribution Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 239000010410 layer Substances 0.000 description 10
- 238000005229 chemical vapour deposition Methods 0.000 description 9
- 238000005422 blasting Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 230000007423 decrease Effects 0.000 description 7
- 150000001247 metal acetylides Chemical class 0.000 description 7
- 230000003746 surface roughness Effects 0.000 description 7
- 238000005240 physical vapour deposition Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 4
- 239000011195 cermet Substances 0.000 description 4
- 229910003460 diamond Inorganic materials 0.000 description 4
- 239000010432 diamond Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000010955 niobium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 229910052581 Si3N4 Inorganic materials 0.000 description 3
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 3
- 239000006061 abrasive grain Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 230000000593 degrading effect Effects 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000009499 grossing Methods 0.000 description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 2
- HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
- LDXJRKWFNNFDSA-UHFFFAOYSA-N 2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]ethanone Chemical compound C1CN(CC2=NNN=C21)CC(=O)N3CCN(CC3)C4=CN=C(N=C4)NCC5=CC(=CC=C5)OC(F)(F)F LDXJRKWFNNFDSA-UHFFFAOYSA-N 0.000 description 1
- 229910017083 AlN Inorganic materials 0.000 description 1
- 229910017109 AlON Inorganic materials 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 229910000997 High-speed steel Inorganic materials 0.000 description 1
- 229910010037 TiAlN Inorganic materials 0.000 description 1
- 229910010060 TiBN Inorganic materials 0.000 description 1
- 229910009043 WC-Co Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 238000005480 shot peening Methods 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 238000002230 thermal chemical vapour deposition Methods 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B27/00—Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
- B23B27/14—Cutting tools of which the bits or tips or cutting inserts are of special material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B51/00—Tools for drilling machines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23C—MILLING
- B23C5/00—Milling-cutters
- B23C5/16—Milling-cutters characterised by physical features other than shape
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/36—Carbonitrides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/40—Oxides
- C23C16/403—Oxides of aluminium, magnesium or beryllium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/56—After-treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
- Y10T428/24975—No layer or component greater than 5 mils thick
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
Definitions
- the present invention relates to a cutting tool for a drill, an end mill, an indexable insert for a drill, an indexable insert for an end mill, an indexable insert for milling, an indexable insert for turning, a metal saw, a gear cutting tool, a reamer, and a tap, and particularly to a coated cutting tool with a coated for improving characteristics such as toughness and wear resistance.
- cemented carbides (WC-Co alloys or WC-CO alloys further containing carbonitride of Ti (titanium), Ta (tantalum), or Nb (niobium) have been used.
- hard alloy tools each including a substrate composed of a cemented carbide, cermet, a sintered cubic boron nitride compact, or an alumina or silicon_nitride ceramic, and at least one coating formed on the surface of the substrate by a CVD (Chemical Vapor Deposition) method of a PVD (Physical Vapor Deposition) method using a compound of at least one first element selected from the group IVa elements, Va elements, VIa elements in the periodic table, Al (aluminum), Si, and B and at least one second element selected from B, C, N, and O (when the first element is B alone, the second element is other than B), the thickness of the coating being 3 to 20 ⁇ m.
- CVD Chemical Vapor Deposition
- PVD Physical Vapor Deposition
- Such cutting tools have a rake face in contact with cutting chips of a work piece in a cutting work and a flank face in contact with the work piece, and a portion (and the vicinity thereof) corresponding to the edge at the crossing of the rake face and the flank face is referred to as an "edge line".
- the cutting speed has recently increased for further improving the cutting efficiency, and accordingly, such cutting tools have been required to have higher wear resistance.
- toughness is decreased by the requirement for higher wear resistance, and thus it has been required to satisfy both high wear resistance and high toughness.
- the measure uses a method of improving toughness (resistance to fracture) while maintaining high wear resistance, in which a first coating layer having such tensile stress is first formed on the substrate, and a second coating layer having compressive stress is formed on the first coating layer after a predetermined crack is formed in the first coating layer.
- Patent Document 2 uses an approach different from the above-described measure with attention to tensile stress of the coating layer as described above, and proposes a method in which an inner coating layer having tensile stress is formed on a hard ceramic substrate, and an outer coating layer having compressive stress is formed on the inner coating layer. Further, Japanese Unexamined Patent Application Publication No. 5-177413 (Patent Document 3) proposes a cutting tool having the same constitution as in Patent Document 2 including a cermet substrate.
- Patent Publication No. 3087465 Japanese Unexamined Patent Application Publication No. 6-079502 , Patent Document 5 proposes a cutting tool including a titanium carbonitride-based cermet substrate and a hard coating layer formed on the surface thereof and having a compressive stress distribution substantially the same over the entirety of a cutting edge, wherein the hard coating layer is subjected to shot blasting so that the compressive stress possessed by a rake portion is 49 MPa or more higher than that possessed by a flank portion.
- both the toughness and the wear resistance can be improved to some extent, but a cutting tool is required to have higher performance under current circumstances surrounding cutting tools. Therefore, the development of a cutting tool satisfying such performance is demanded.
- Document EP-A-0965404 relates to a coated cemented carbide cutting tool comprising a substrate consisting of a matrix of WC and a binder phase of an iron group metal and a plurality of coated layers provided on a surface or the substrate.
- An innermost layer, adjacent to the substrate, of the coated layers consists essentially of titanium nitride.
- an average crack interval in the coated film on a ridge of a cutting edge and/or rake face is smaller than an average crack interval in the coated layer on a flank face.
- At least 50 % of the cracks in the coated film on the ridge of the cutting edge and/or rake face have ends of the cracks in the innermost titanium nitride layer, in a layer above the titanium nitride layer or in an interface between these layers. Furthermore, an average crack length in the coated film on the ridge of the cutting edge and/or rake face is shorter than an average film thickness on the flank face.
- the present invention has been achieved in consideration of the above-mentioned present conditions, and an object of the present invention is to provide a coated cutting tool satisfying high degrees of both toughness and wear resistance.
- the ratio of surface area increase of a portion concerned in cutting may be 0.0005 to 0.07.
- the first coating may have a columnar structure with an aspect ratio of 3 or more and a crystal structure with an average grain diameter of 0.05 ⁇ m to 1.5 ⁇ m. Also, the first coating may have s thickness of 2 to 20 ⁇ m, and the second coating may have a thickness of 0.5 to 20 ⁇ m.
- the first coating may further contain oxygen and contain at least one element selected from the group consisting of the group IVa elements, group Va elements, and group VIa elements in the periodic table, Si, Y, B, and S.
- the second coating may further contain at least one element selected from the group consisting of the group IVa elements, group Va elements, and group VIa elements in the periodic table, Si, Y, B, and S.
- the coated cutting tool of the present invention has the above-described constitution and thus satisfies high degrees of both toughness and wear resistance.
- a coated cutting tool of the present invention includes a substrate and a coating formed on the substrate.
- a coated cutting tool 1 has a rake face 2 in contact with a cutting chip 6 of a work piece 5 in a cutting work and a flank face 3 in contact with the work piece.
- a portion corresponding to the edge at the crossing between the rake face 2 and the flank face 3 is referred to as an "edge line 4" functioning as a central point of action in cutting of the workpiece 5.
- a through hole 7 can be provided at the center as shown in Fig. 2 so that the cutting tool can be attached to a tool body.
- another fixing means may be provided according to demand.
- a commonly known substrate known as a substrate for such a cutting tool can be used without any limitation.
- the substrate include cemented carbides (e.g., WC-based cemented carbides and cemented carbides containing WC and Co or further containing a carbonitride of Ti, Ta, or Nb), cermet (containing TiC, TiN, or TiCN as a main component), high-speed steel, ceramics (titanium carbide, silicon carbide, silicon nitride, aluminum nitride, and aluminum oxide), sintered cubic boron nitride compacts, sintered diamond compacts, sintered silicon nitride compacts, and mixtures of aluminum oxide and titanium carbide.
- cemented carbides e.g., WC-based cemented carbides and cemented carbides containing WC and Co or further containing a carbonitride of Ti, Ta, or Nb
- cermet containing TiC, TiN, or TiCN as a main component
- high-speed steel ceramics
- cemented carbides are particularly preferably used among these various substrates. This is because the cemented carbides contain high-hardness tungsten carbide as a main component and an iron group metal such as cobalt, and are thus well-balanced alloys as substrates for cutting tools having both high hardness and high strength.
- a coating 9 is formed on the substrate 8, mainly for the purpose of further improving toughness and further improving wear resistance.
- the coating 9 includes a first coating 10 composed of TiCN and a second coating 11 composed of ⁇ -Al 2 O 3 .
- Such a coating may further include a third coating other than the first and second coatings, for the purpose of further improving the adhesion between the coating and the substrate, further improving the adhesion between the first coating and the second coating, or improving the surface state of the coating.
- Examples of the third coating include TiN, TiC, TiCO, TiBN, ZrCN, TiZrCN, AlN, AlON, and TiAlN.
- the third coating can be formed in one layer or two or more layers, and the multilayer form thereof is not particularly limited.
- the third coating can be formed at at least one desired multilayer point, e.g., between the substrate and the first coating, between the first coating and the second coating, or on the surface of the second coating.
- the first coating may be composed of TiCN alone but may further contain oxygen.
- the containing form of oxygen is not particularly limited.
- oxygen may be contained as a substitutional element at a normal position in a TiCN crystal lattice, contained as an interstitial element between the crystal lattices, or present as an amorphous substance.
- the first coating may further contain at least one element selected from the group consisting of the group IVa elements (Ti, Zr, and Hf), group Va elements (V, Nb, and Ta), group VIa elements (Cr, Mo, and W), Si, Y, B, and S. These elements can be contained together with oxygen or contained alone without oxygen, and like the oxygen, any desired containing form may be used.
- group IVa elements Ti, Zr, and Hf
- group Va elements V, Nb, and Ta
- group VIa elements Cr, Mo, and W
- Si Y, B, and S.
- the first coating may be composed of TiCN alone or may include TiCN as a main component and the above-described elements such as oxygen.
- the element may be present with any desired concentration distribution, such as a distribution in which the concentration of the element is uniform in the coating, a distribution in which the element is distributed at a high or low concentration at crystal grain boundaries, or a distribution in which the element is distributed at a high or low concentration on the surface of the coating.
- the content of the element such as oxygen is preferably 0.1 to 40 atomic % relative to the total of C and N of TiCN, and the upper limit and the lower limit thereof are preferably 30 atomic % and 1 atomic % and more preferably 20 atomic % and 5 atomic %, respectively.
- the effect caused by adding the element such as oxygen may not be exhibited, while at the content over 40 atomic %, the crystal lattice of the film may be distorted to decrease hardness and strength.
- the first coating is preferably formed to a thickness of 2 to 20 ⁇ m, and the upper and lower limits thereof are preferably 15 ⁇ m and 2.5 ⁇ m and more preferably 10 ⁇ m and 3 ⁇ m, respectively. With the thickness less than 2 ⁇ m, wearing may proceed and more significantly proceeds due to the exposure of the substrate. With the thickness of over 20 ⁇ m, the strength of the film is degraded to cause peeling and chipping of the film, finally leading to fracture.
- the first coating preferably has a columnar structure with an aspect ratio of 3 or more and has a crystal structure with an average grain diameter of 0.05 ⁇ m to 1.5 ⁇ m.
- the aspect ratio is a value obtained by dividing the thickness of the first coating by the average grain diameter of crystals contained in the first coating, the average grain diameter being measured by the following method: A section of the first coating is mirror-processed, and crystal grain boundaries are etched. Then, the width (width of each crystal in a direction perpendicular to the thickness direction) of each crystal at a point of a 1/2 thickness of the first coating is measured. The average value of the widths is determined as the average grain diameter.
- the resistance to abrasive wear cannot be improved in some cases. Since the resistance to abrasive wear is improved as the aspect ratio increase, the upper limit thereof need not be specified. However, when the aspect ratio exceeds 300, crystals may be made excessively fine, thereby embrittling the structure and degrading the resistance to fracture.
- the aspect ratio is more preferably 7 to 200, and the upper limit and lower limit thereof are further more preferably 100 and 15 and particularly preferably 50 and 20, respectively.
- the average grain diameter is preferably 0.1 ⁇ m to 1.0 ⁇ m, and the upper and lower limits thereof are preferably 0.6 ⁇ m and 0.15 ⁇ m and more preferably 0.4 ⁇ m and 0.2 ⁇ m, respectively.
- the stress of the first coating is tensile stress
- a high degree of adhesion can be achieved between the substrate and the first coating, and particularly excellent wear resistance can be realized.
- the substrate is a cemented carbide
- the tensile stress is preferably 5 MPa to 300 MPa.
- the first coating can be formed by a known CVD method. Therefore, tensile stress can be imparted to the first coating at the same time as the formation of the first coating.
- the first coating can also be formed by a known PVD method. In this case, the coating generally has compressive stress. Therefore, in order to change compressive stress to tensile stress, it is necessary to treat the first coating by any one of various methods such as heat treatment, laser processing, and radio-frequency processing.
- the stress of the first coating can be measured by a sin 2 ⁇ method using an X-ray stress measurement device and a TiCN (422) plane selected as a measurement diffracting plane in the same manner as for the second coating described below. Even when the first coating of the present invention further contains an element such as oxygen, stress can be measured by the same method because the (422) plane is present at substantially the same 2 ⁇ position.
- the second coating of the present invention is composed of ⁇ -Al 2 O 3 and has compressive stress S2.
- the second coating is composed of such a material and is formed on the top surface or near the top surface of the substrate, it is possible to effectively prevent oxidation of the substrate and effectively prevent diffusion of the constituent elements of a work piece to the substrate side in a cutting work. Such oxidation and diffusion are accelerated by heat generation in the cutting work.
- ⁇ -Al 2 O 3 is excellent in high-temperature stability, and thus a very excellent effect can be exhibited by synergism of these effects.
- the element may be present with any desired concentration distribution, such as a distribution in which the concentration of the element is uniform in the coating, a distribution in which the element is distributed at a high or low concentration at crystal grain boundaries, or a distribution in which the element is distributed at a high or low concentration on the surface of the coating.
- the content of the element is preferably 0.01 to 30 atomic % relative to the amount of Al of ⁇ -Al 2 O 3 , and the upper limit and the lower limit thereof are preferably 20 atomic % and 0.05 atomic % and more preferably 10 atomic % and 0.1 atomic %, respectively.
- the second coating is preferably formed to a thickness of 0.5 to 20 ⁇ m, and the upper and lower limits thereof are preferably 10 ⁇ m and 1 ⁇ m and more preferably 5 ⁇ m and 1.5 ⁇ m, respectively.
- the thickness less than 0.5 ⁇ m the chemical stability of the second coating may be impaired, and thus wearing such as adhesion wear and diffusion wear may be accelerated.
- the thickness of over 20 ⁇ m the strength of the film is degraded to cause peeling and chipping of the film, finally leading to fracturing.
- the second coating has compressive stress S2, and the compressive stress S2 and the tensile stress S1 of the first coating are defined by the following equation (1): 400 MPa ⁇ S 2 ⁇ S 1 ⁇ 3500 MPa
- the compressive stress is a type of internal stress (inherent distortion) present in the coating and represents stress expressed by a "-" minus value (unit: MPa). Therefore, the concept of high compressive stress means that the value increases, while the concept of low compressive stress means that the value decreases.
- the phrase "having tensile stress” includes the state in which the tensile stress is released to cause substantially no stress.
- the second coating of the present invention contains at least one element selected from the group consisting of the group IVa elements, Va elements, and VIa elements in the periodic table, Si, Y, B, and S, the stress can be measured by the same method as described above because a (116) plane is present at substantially the same 2 ⁇ position.
- the coated cutting tool of the present invention preferably has such surface roughness that the ratio of surface area increase in a portion concerned in cutting is 0.0005 to 0.07.
- the upper and lower limits of the ratio of surface area increase are more preferably 0.05 and 0.001 and further preferably 0.02 and 0.005, respectively.
- the ratio of surface area increase defines the surface roughness of a coating from a three-dimensional viewpoint, thus has a concept completely different from usual surface roughness Ra and Rmax which define two-dimensional surface roughness only in the height direction.
- the ratio of surface area increase is represented by (a1/s2) - 1, i.e., a value obtained by subtracting 1 from the ratio (a1/a2) of the total surface area a1 including irregularities in all directions including the vertical direction and the horizontal direction in a predetermined measurement field of view to a two-dimensional area a2 in the same measurement field of view.
- the ratio indicates that smoothness is improved as the ratio of surface area increase decreases.
- the ratio of surface area increase can be determined from the values measured with an electron-ray three-dimensional roughness analyzer (ERA-8000) manufactured by Elionix Co., Ltd.
- the magnification is set to 5000 times in order to exclude macroscopic unevenness in a coating surface and permit the measurement of fine unevenness, and the surface of the coating is observed.
- the sampling numbers in the horizontal and vertical directions in a measurement field of view in a portion concerned in cutting are 280 and 210, respectively.
- the ratio can be measured using any measurement device as long as it is capable of measurement according to the same principle.
- the ratio of surface area increase in a portion concerned in cutting is preferably specified to 0.0005 to 0.07.
- the coating surface has particularly high smoothness in a portion concerned in cutting, thereby improving the removal of chips in cutting and exhibiting the effect of suppressing a temperature rise of the rake face. This is possibly because in a cutting work, chips at a high temperature are sufficiently removed, and, accordingly, a temperature rise of the rake face is suppressed.
- the coated cutting tool of the present invention has surface roughness defined by the above-described ratio of surface area increase
- the surface, particularly a portion concerned in cutting is preferably processed by known polishing or smoothing. Examples of such processing include buffing, brushing, barreling, diamond lapping, and blast polishing.
- the width in the flank face direction is little influenced by the cutting depth because the flank face does not contact a cutting chip, and thus a maximum value of 1.5 mm or less is usually sufficient. Therefore, the width of the region is particularly preferably 0.5 mm to 1.5 mm.
- the edge line not only means a portion (sharp edge) corresponding to the edge at the intersection of the rake face and the flank face but also includes a portion (so-called edge processed portion) in which the sharp edge is edge-processed to have radius (R) and a chamfered portion (so-called negative land portion) and a portion subjected to a combination of edge processing and chamfering.
- Each of the stress values (particularly, compressive stress S2 of each second coating, and the absolute value of the difference
- Table I indicates that the coated cutting tools in each of which the absolute value of the difference (
- Example 3 smoothing was carried out in a region (i.e., a portion concerned in cutting) extending with a width of 0.5 mm from the edge line in each of the rake face direction and the flank face direction using diamond abrasive grains with different grain sizes (#1000 to #3000) and different lapping times as shown in Table II (Examples 3-1 to 3-6).
- the surface roughness of the portion concerned in cutting was measured using an electron-ray three-dimensional roughness analyzer (ERA-8000 manufactured by Elionix Co., Ltd.). As a result, the ratio of surface area increase was as shown in Table II.
- Table II indicates that in a coated cutting tool, as the ratio of surface area increase in a portion concerned in cutting decreases, the tool life is improved, and high degrees of both toughness and wear resistance are satisfied.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Chemical Vapour Deposition (AREA)
- Drilling Tools (AREA)
- Milling Processes (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004361652 | 2004-12-14 | ||
PCT/JP2005/022636 WO2006064724A1 (ja) | 2004-12-14 | 2005-12-09 | 表面被覆切削工具 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1825943A1 EP1825943A1 (en) | 2007-08-29 |
EP1825943A4 EP1825943A4 (en) | 2009-09-16 |
EP1825943B1 true EP1825943B1 (en) | 2017-01-25 |
Family
ID=36587780
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05814749.7A Active EP1825943B1 (en) | 2004-12-14 | 2005-12-09 | Coated cutting tool |
Country Status (7)
Country | Link |
---|---|
US (1) | US7972714B2 (ko) |
EP (1) | EP1825943B1 (ko) |
JP (1) | JP4739235B2 (ko) |
KR (1) | KR101168464B1 (ko) |
CN (1) | CN101080295B (ko) |
IL (1) | IL183812A (ko) |
WO (1) | WO2006064724A1 (ko) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006046498A1 (ja) * | 2004-10-29 | 2006-05-04 | Sumitomo Electric Hardmetal Corp. | 表面被覆切削工具 |
SE529023C2 (sv) | 2005-06-17 | 2007-04-10 | Sandvik Intellectual Property | Belagt skär av hårdmetall |
DE102008009487B4 (de) * | 2008-02-15 | 2022-09-22 | Walter Ag | Strahlbehandelter Schneideinsatz und Verfahren |
DE102008013966A1 (de) * | 2008-03-12 | 2009-09-17 | Kennametal Inc. | Hartstoffbeschichteter Körper |
DE102008013965A1 (de) * | 2008-03-12 | 2009-09-17 | Kennametal Inc. | Hartstoffbeschichteter Körper |
WO2009133814A1 (ja) * | 2008-04-30 | 2009-11-05 | 住友電気工業株式会社 | 表面被覆切削工具 |
EP2287359B1 (en) * | 2009-07-03 | 2012-05-23 | Sandvik Intellectual Property AB | Coated cutting tool insert |
CN102398051B (zh) * | 2010-09-16 | 2015-10-14 | 三菱综合材料株式会社 | 硬质包覆层发挥优异的耐崩刀性的表面包覆切削工具 |
JP5682500B2 (ja) * | 2010-09-27 | 2015-03-11 | 三菱マテリアル株式会社 | 硬質被覆層がすぐれた耐チッピング性と耐摩耗性を発揮する表面被覆切削工具 |
JP5682501B2 (ja) * | 2010-09-29 | 2015-03-11 | 三菱マテリアル株式会社 | 硬質被覆層がすぐれた耐摩耗性を発揮する表面被覆切削工具 |
US8715838B2 (en) | 2010-11-10 | 2014-05-06 | Sumitomo Electric Hardmetal Corp. | Surface-coated cutting tool |
JP5742572B2 (ja) * | 2011-02-09 | 2015-07-01 | 三菱マテリアル株式会社 | 硬質被覆層がすぐれた耐摩耗性を発揮する表面被覆切削工具 |
DE102011053705A1 (de) | 2011-09-16 | 2013-03-21 | Walter Ag | Schneideinsatz und Verfahren zu dessen Herstellung |
JP5757232B2 (ja) | 2011-12-26 | 2015-07-29 | 三菱マテリアル株式会社 | 硬質被覆層がすぐれた耐チッピング性と耐摩耗性を発揮する表面被覆切削工具 |
US9103036B2 (en) | 2013-03-15 | 2015-08-11 | Kennametal Inc. | Hard coatings comprising cubic phase forming compositions |
US9371580B2 (en) | 2013-03-21 | 2016-06-21 | Kennametal Inc. | Coated body wherein the coating scheme includes a coating layer of TiAl2O3 and method of making the same |
CN105051248B (zh) | 2013-03-21 | 2018-03-20 | 钴碳化钨硬质合金公司 | 用于切削工具的涂层 |
DE112014001520B4 (de) | 2013-03-21 | 2023-06-15 | Kennametal Inc. | Beschichtungen für Schneidwerkzeuge |
US9168664B2 (en) | 2013-08-16 | 2015-10-27 | Kennametal Inc. | Low stress hard coatings and applications thereof |
US9896767B2 (en) | 2013-08-16 | 2018-02-20 | Kennametal Inc | Low stress hard coatings and applications thereof |
US9427808B2 (en) | 2013-08-30 | 2016-08-30 | Kennametal Inc. | Refractory coatings for cutting tools |
RU2643754C2 (ru) | 2013-11-08 | 2018-02-05 | Тунгалой Корпорейшн | Режущий инструмент с износостойким покрытием |
KR101528790B1 (ko) * | 2013-12-27 | 2015-06-15 | 한국야금 주식회사 | 경질피막이 코팅된 절삭공구 |
KR20150083621A (ko) * | 2014-01-10 | 2015-07-20 | 한국야금 주식회사 | 절삭공구용 경질 피막 |
US9719175B2 (en) | 2014-09-30 | 2017-08-01 | Kennametal Inc. | Multilayer structured coatings for cutting tools |
US9650712B2 (en) | 2014-12-08 | 2017-05-16 | Kennametal Inc. | Inter-anchored multilayer refractory coatings |
US9650714B2 (en) | 2014-12-08 | 2017-05-16 | Kennametal Inc. | Nanocomposite refractory coatings and applications thereof |
KR101675649B1 (ko) | 2014-12-24 | 2016-11-11 | 한국야금 주식회사 | 절삭공구 |
CN106660138B (zh) * | 2015-08-28 | 2019-12-13 | 住友电工硬质合金株式会社 | 表面被覆切削工具 |
RU2637860C1 (ru) * | 2016-10-11 | 2017-12-07 | федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный технический университет" | Способ получения износостойкого покрытия для режущего инструмента |
WO2018125676A1 (en) | 2016-12-30 | 2018-07-05 | Corning Incorporated | Coated articles with optical coatings having residual compressive stress |
JP6521127B2 (ja) | 2017-04-21 | 2019-05-29 | 株式会社タンガロイ | 被覆切削工具 |
JP6521130B2 (ja) | 2017-04-21 | 2019-05-29 | 株式会社タンガロイ | 被覆切削工具 |
CN109112500B (zh) | 2017-06-22 | 2022-01-28 | 肯纳金属公司 | Cvd复合材料耐火涂层及其应用 |
EP3769873A4 (en) * | 2018-03-20 | 2021-12-01 | Kyocera Corporation | INSERT AND ITS CUTTING TOOLS |
CN111867758B (zh) * | 2018-03-20 | 2023-03-21 | 京瓷株式会社 | 涂层刀具和具备它的切削刀具 |
WO2020002664A1 (en) * | 2018-06-29 | 2020-01-02 | Ab Sandvik Coromant | Method of treating a cutting tool, and a cutting tool |
JP7470963B2 (ja) * | 2020-01-27 | 2024-04-19 | 株式会社不二機販 | 焼結体のバインダ金属相強化方法 |
CN115916437A (zh) | 2020-06-30 | 2023-04-04 | 京瓷株式会社 | 涂层刀具以及切削刀具 |
WO2022004522A1 (ja) | 2020-06-30 | 2022-01-06 | 京セラ株式会社 | 被覆工具および切削工具 |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0594875A1 (en) | 1992-10-22 | 1994-05-04 | Mitsubishi Materials Corporation | Multilayer coated hard alloy cutting tool |
WO1995019457A1 (en) | 1994-01-14 | 1995-07-20 | Sandvik Ab | Oxide coated cutting tool |
EP0732423A1 (en) | 1994-10-04 | 1996-09-18 | Sumitomo Electric Industries, Ltd | Coated hard alloy |
WO1998010119A1 (en) | 1996-09-06 | 1998-03-12 | Sandvik Aktiebolag | Coated cutting insert |
WO1998051839A1 (de) | 1997-05-09 | 1998-11-19 | Widia Gmbh | Schneideinsatz zum zerspanen und verfahren zur herstellung dieses schneideinsatzes |
EP0965404A1 (en) | 1997-11-06 | 1999-12-22 | Sumitomo Electric Industries, Ltd. | Coated tool of cemented carbide |
JP2001341007A (ja) | 2000-06-01 | 2001-12-11 | Sumitomo Electric Ind Ltd | 被覆切削工具 |
US20020039521A1 (en) | 2000-10-02 | 2002-04-04 | Wolfgang Votsch | Cutting insert with wear detection |
DE10123554A1 (de) | 2001-03-27 | 2002-10-02 | Widia Gmbh | Verfahren zur Erhöhung der Druckspannung oder zur Erniedrigung der Zugeigenspannung einer CVD-, PCVD- oder PVD-Schicht und Schneideinsatz zum Zerspanen |
EP1471166A2 (en) | 2003-04-24 | 2004-10-27 | Seco Tools Ab | Layer with controlled grain size and morphology for enhanced wear resistance |
EP1806193A1 (en) * | 2004-10-29 | 2007-07-11 | Sumitomo Electric Hardmetal Corp. | Surface-coated cutting tool |
US9238267B2 (en) | 2011-09-16 | 2016-01-19 | Walter Ag | Cutting insert and method for production thereof |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2854335B2 (ja) | 1989-08-31 | 1999-02-03 | 株式会社アイジー技術研究所 | 出隅構造 |
US5250367A (en) * | 1990-09-17 | 1993-10-05 | Kennametal Inc. | Binder enriched CVD and PVD coated cutting tool |
JPH05177413A (ja) | 1991-12-26 | 1993-07-20 | Sumitomo Electric Ind Ltd | 被覆サーメット切削工具及びその製造方法 |
JPH05177412A (ja) | 1991-12-26 | 1993-07-20 | Sumitomo Electric Ind Ltd | 被覆セラミックス切削工具及びその製造方法 |
JPH05177411A (ja) * | 1991-12-26 | 1993-07-20 | Sumitomo Electric Ind Ltd | 被覆切削工具及びその製造方法 |
JP3236899B2 (ja) | 1992-08-11 | 2001-12-10 | 三菱マテリアル株式会社 | 耐摩耗性および耐欠損性のすぐれた表面被覆炭化タングステン基超硬合金製切削工具の製造法 |
JP3087465B2 (ja) | 1992-08-27 | 2000-09-11 | 三菱マテリアル株式会社 | 耐摩耗性および耐欠損性のすぐれた表面被覆炭窒化チタン基サーメット製切削工具の製造法 |
BR9611781A (pt) * | 1995-11-30 | 1999-02-23 | Sandvik Ab | Inserção revestida para torneamento e método de fabricação da mesma |
JPH09309007A (ja) * | 1996-05-22 | 1997-12-02 | Sumitomo Electric Ind Ltd | 被覆硬質工具 |
JP3252711B2 (ja) | 1996-07-02 | 2002-02-04 | 住友電気工業株式会社 | 被覆窒化珪素系工具 |
SE511211C2 (sv) * | 1996-12-20 | 1999-08-23 | Sandvik Ab | Ett multiskiktbelagt skärverktyg av polykristallin kubisk bornitrid |
US6015614A (en) | 1997-11-03 | 2000-01-18 | Seco Tools Ab | Cemented carbide body with high wear resistance and extra tough behavior |
JP3061041B2 (ja) * | 1998-01-22 | 2000-07-10 | 住友電気工業株式会社 | 被覆超硬合金工具 |
EP1306150B1 (en) * | 2000-07-12 | 2012-03-21 | Sumitomo Electric Industries, Ltd. | Coated cutting tool |
EP1311712A2 (de) * | 2001-03-27 | 2003-05-21 | Widia GmbH | Verfahren zur erhöhung der druckspannung oder zur erniedrigung der zugeigenspannung einer schicht |
SE526603C3 (sv) * | 2003-01-24 | 2005-11-16 | Sandvik Intellectual Property | Belagt hårdmetallskär |
US7172807B2 (en) * | 2003-02-17 | 2007-02-06 | Kyocera Corporation | Surface-coated member |
SE526526C3 (sv) * | 2003-04-01 | 2005-10-26 | Sandvik Intellectual Property | Sätt att belägga skär med A1203 samt ett med A1203 belagt skärverktyg |
-
2005
- 2005-12-09 EP EP05814749.7A patent/EP1825943B1/en active Active
- 2005-12-09 US US11/721,520 patent/US7972714B2/en active Active
- 2005-12-09 WO PCT/JP2005/022636 patent/WO2006064724A1/ja active Application Filing
- 2005-12-09 CN CN2005800429213A patent/CN101080295B/zh active Active
- 2005-12-09 KR KR1020077012102A patent/KR101168464B1/ko active IP Right Grant
- 2005-12-09 JP JP2006548799A patent/JP4739235B2/ja active Active
-
2007
- 2007-06-10 IL IL183812A patent/IL183812A/en active IP Right Grant
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0594875A1 (en) | 1992-10-22 | 1994-05-04 | Mitsubishi Materials Corporation | Multilayer coated hard alloy cutting tool |
WO1995019457A1 (en) | 1994-01-14 | 1995-07-20 | Sandvik Ab | Oxide coated cutting tool |
EP0732423A1 (en) | 1994-10-04 | 1996-09-18 | Sumitomo Electric Industries, Ltd | Coated hard alloy |
WO1998010119A1 (en) | 1996-09-06 | 1998-03-12 | Sandvik Aktiebolag | Coated cutting insert |
US6350510B1 (en) | 1997-05-09 | 2002-02-26 | Widia Gmbh | Processing insert, and production of same |
WO1998051839A1 (de) | 1997-05-09 | 1998-11-19 | Widia Gmbh | Schneideinsatz zum zerspanen und verfahren zur herstellung dieses schneideinsatzes |
EP0965404A1 (en) | 1997-11-06 | 1999-12-22 | Sumitomo Electric Industries, Ltd. | Coated tool of cemented carbide |
JP2001341007A (ja) | 2000-06-01 | 2001-12-11 | Sumitomo Electric Ind Ltd | 被覆切削工具 |
US20020039521A1 (en) | 2000-10-02 | 2002-04-04 | Wolfgang Votsch | Cutting insert with wear detection |
DE10123554A1 (de) | 2001-03-27 | 2002-10-02 | Widia Gmbh | Verfahren zur Erhöhung der Druckspannung oder zur Erniedrigung der Zugeigenspannung einer CVD-, PCVD- oder PVD-Schicht und Schneideinsatz zum Zerspanen |
EP1471166A2 (en) | 2003-04-24 | 2004-10-27 | Seco Tools Ab | Layer with controlled grain size and morphology for enhanced wear resistance |
EP1806193A1 (en) * | 2004-10-29 | 2007-07-11 | Sumitomo Electric Hardmetal Corp. | Surface-coated cutting tool |
US9238267B2 (en) | 2011-09-16 | 2016-01-19 | Walter Ag | Cutting insert and method for production thereof |
Non-Patent Citations (16)
Title |
---|
"Highly efficient milling of cast iron", PRODUCT INFORMATION. OSG-WALTER. FC(FCD) WAK25. FOR FC(FCD) MACHINING TIGER TEC, pages 1 - 4 |
"Inserts achieve 75% more components per edge in CI", 23 July 2001 (2001-07-23), XP055437625, Retrieved from the Internet <URL:Manufacturingtalk.com> |
"Microstructure of coating layer - WAK 10", SEM MEASUREMENT REPORT, 2 June 2004 (2004-06-02), XP055437754 |
"Microstructure of coating layer - WAK 15", SEM MEASUREMENT REPORT, 2 June 2004 (2004-06-02), XP055437757 |
"Microstructure of coating layer - WAK 25", SEM MEASUREMENT REPORT, 2 June 2004 (2004-06-02), XP055437759 |
"WAK 10", SEM MEASUREMENT REPORT, 9 September 2003 (2003-09-09), XP055437761 |
"X-Ray stress measuring method", THE SOCIETY OF MATERIALS SCIENCE, 1996, pages 84 - 105, XP055437652 |
CH. GENZEL ET AL: "Application of energy-dispersive diffraction to the analysis of multiaxial residual stress fields in the intermediate zone between surface and volume", MATERIAL SCIENCE AND ENGINEERING A, vol. 372, 2004, pages 28 - 43, XP055437658 |
GENZEL CH.: "X-ray stress analysis in presence of gradients and texture", ADV. IN X-RAY ANALYSIS, vol. 44, 2001, pages 247 - 256, XP055437647 |
KRAAS: "Schneidwerkzeug mit Biss", WERKZEUG & FORMENBAU, vol. 4, September 2001 (2001-09-01), XP055437621 |
M.E. FITZPATRICK ET AL., MEASUREMENT GOOD PRACTICE GUIDE NO 52, DETERMINATION OF RESIDUAL STRESSES BY X-RAY DIFFRACTION - ISSUE 2, September 2005 (2005-09-01), pages 1 - 68, XP055437739, ISSN: 1744-3911 |
MARQUES M.J. ET AL: "A methodology development for the study of near surface stress gradients", MATERIALS SCIENCE AND ENGINEERING A, vol. 287, 2000, pages 78 - 86, XP055437662 |
MITTEMEIJER ET AL.: "Diffraction Analysis of the Microstructure of Materials", 2004, ISBN: 978-3-642-07352-6, article C. GENZEL: "Chapter 18 - Problems Related to X-Ray Stress Analysis in Thin Films in the Presence of Gradients and Texture", pages: 473 - 503, XP055437604 |
REPORT FOR EDS ANALYSIS [USING HORIBA EDAX SYS], 2 June 2004 (2004-06-02), XP055437632 |
T. PRADELL ET AL.: "Physical Science - The measurement of residual stress in engineeringceramics", COMMISSION OF THE EUROPEAN COMMUNITIES CATALOGUE CD-NA-12635-EN-C, 1990, pages 1 - 84, XP055437736 |
WALTER AG, TIGER TEC BROCHURE, 2001, pages 1 - 4, XP055437618 |
Also Published As
Publication number | Publication date |
---|---|
JP4739235B2 (ja) | 2011-08-03 |
KR101168464B1 (ko) | 2012-07-26 |
US7972714B2 (en) | 2011-07-05 |
EP1825943A4 (en) | 2009-09-16 |
EP1825943A1 (en) | 2007-08-29 |
CN101080295B (zh) | 2010-08-18 |
US20090297835A1 (en) | 2009-12-03 |
IL183812A0 (en) | 2007-09-20 |
CN101080295A (zh) | 2007-11-28 |
IL183812A (en) | 2010-11-30 |
KR20070085526A (ko) | 2007-08-27 |
JPWO2006064724A1 (ja) | 2008-06-12 |
WO2006064724A1 (ja) | 2006-06-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1825943B1 (en) | Coated cutting tool | |
EP1806193B1 (en) | Surface-coated cutting tool | |
EP1832364B1 (en) | Surface-coated cutting tool | |
JP5866650B2 (ja) | 表面被覆切削工具 | |
US7985471B2 (en) | Coated cutting tool | |
EP2594352B1 (en) | Surface coating cutting tool | |
JP2007136631A (ja) | 刃先交換型切削チップ | |
EP3326741A1 (en) | Surface-coated cutting tool and method for producing same | |
EP2379778A1 (en) | Improved coated cutting insert for rough turning | |
EP3199277A1 (en) | Coated tool | |
JP7137149B2 (ja) | 硬質被覆層が優れた耐チッピング性を発揮する表面被覆切削工具 | |
EP3195960B1 (en) | Coated tool | |
JP2021146478A (ja) | 耐欠損性にすぐれた表面被覆切削工具 | |
JP2012030359A (ja) | 刃先交換型切削チップ |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20070606 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): DE SE |
|
DAX | Request for extension of the european patent (deleted) | ||
RBV | Designated contracting states (corrected) |
Designated state(s): DE SE |
|
A4 | Supplementary search report drawn up and despatched |
Effective date: 20090818 |
|
17Q | First examination report despatched |
Effective date: 20121031 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
INTG | Intention to grant announced |
Effective date: 20160823 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: TAKANASHI, NORIHIRO SUMITOMO ELECTRIC HARDMETAL CO Inventor name: OKADA, YOSHIO SUMITOMO ELECTRIC HARDMETAL CORP. Inventor name: ITOH, MINORU SUMITOMO ELECTRIC HARDMETAL CORP. Inventor name: IMAMURA, SHINYA SUMITOMO ELECTRIC HARDMETAL CORP. Inventor name: OKUNO, SUSUMU SUMITOMO ELECTRIC HARDMETAL CORP. Inventor name: OMORI, NAOYA SUMITOMO ELECTRIC HARDMETAL CORP.. |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: OKADA, YOSHIO Inventor name: OMORI, NAOYA Inventor name: OKUNO, SUSUMU Inventor name: TAKANASHI, NORIHIRO Inventor name: IMAMURA, SHINYA Inventor name: ITOH, MINORU |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): DE SE |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602005051240 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R026 Ref document number: 602005051240 Country of ref document: DE |
|
PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
PLAX | Notice of opposition and request to file observation + time limit sent |
Free format text: ORIGINAL CODE: EPIDOSNOBS2 |
|
26 | Opposition filed |
Opponent name: ISCAR LTD. Effective date: 20171025 |
|
PLBB | Reply of patent proprietor to notice(s) of opposition received |
Free format text: ORIGINAL CODE: EPIDOSNOBS3 |
|
APBM | Appeal reference recorded |
Free format text: ORIGINAL CODE: EPIDOSNREFNO |
|
APBP | Date of receipt of notice of appeal recorded |
Free format text: ORIGINAL CODE: EPIDOSNNOA2O |
|
APAH | Appeal reference modified |
Free format text: ORIGINAL CODE: EPIDOSCREFNO |
|
APBM | Appeal reference recorded |
Free format text: ORIGINAL CODE: EPIDOSNREFNO |
|
APBP | Date of receipt of notice of appeal recorded |
Free format text: ORIGINAL CODE: EPIDOSNNOA2O |
|
APAH | Appeal reference modified |
Free format text: ORIGINAL CODE: EPIDOSCREFNO |
|
APBQ | Date of receipt of statement of grounds of appeal recorded |
Free format text: ORIGINAL CODE: EPIDOSNNOA3O |
|
APBQ | Date of receipt of statement of grounds of appeal recorded |
Free format text: ORIGINAL CODE: EPIDOSNNOA3O |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230515 |
|
APBU | Appeal procedure closed |
Free format text: ORIGINAL CODE: EPIDOSNNOA9O |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20231110 Year of fee payment: 19 Ref country code: DE Payment date: 20231031 Year of fee payment: 19 |
|
PLAY | Examination report in opposition despatched + time limit |
Free format text: ORIGINAL CODE: EPIDOSNORE2 |
|
PLBC | Reply to examination report in opposition received |
Free format text: ORIGINAL CODE: EPIDOSNORE3 |