EP1787751B1 - Use of a system for for everyday maintenance of a hard floor surface of stone or stone-like material - Google Patents

Use of a system for for everyday maintenance of a hard floor surface of stone or stone-like material Download PDF

Info

Publication number
EP1787751B1
EP1787751B1 EP07101889A EP07101889A EP1787751B1 EP 1787751 B1 EP1787751 B1 EP 1787751B1 EP 07101889 A EP07101889 A EP 07101889A EP 07101889 A EP07101889 A EP 07101889A EP 1787751 B1 EP1787751 B1 EP 1787751B1
Authority
EP
European Patent Office
Prior art keywords
pad
abrasive particles
stone
tool
floor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP07101889A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1787751A2 (en
EP1787751A3 (en
Inventor
Håkan THYSELL
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HTC Sweden AB
Original Assignee
HTC Sweden AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34934264&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1787751(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by HTC Sweden AB filed Critical HTC Sweden AB
Priority to DK07101889.9T priority Critical patent/DK1787751T3/da
Priority to PL07101889T priority patent/PL1787751T3/pl
Priority to SI200531364T priority patent/SI1787751T1/sl
Publication of EP1787751A2 publication Critical patent/EP1787751A2/en
Publication of EP1787751A3 publication Critical patent/EP1787751A3/en
Application granted granted Critical
Publication of EP1787751B1 publication Critical patent/EP1787751B1/en
Priority to CY20111100931T priority patent/CY1111862T1/el
Revoked legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B24—GRINDING; POLISHING
    • B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B7/00—Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor
    • B24B7/10—Single-purpose machines or devices
    • B24B7/18—Single-purpose machines or devices for grinding floorings, walls, ceilings or the like
    • B24B7/186—Single-purpose machines or devices for grinding floorings, walls, ceilings or the like with disc-type tools
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B24—GRINDING; POLISHING
    • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D11/00—Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
    • B24D11/001—Manufacture of flexible abrasive materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B24—GRINDING; POLISHING
    • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D13/00—Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor
    • B24D13/14—Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor acting by the front face
    • B24D13/147—Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor acting by the front face comprising assemblies of felted or spongy material; comprising pads surrounded by a flexible material

Definitions

  • the invention relates to use of a system for maintenance of hard surfaces, primarily concrete (cement), terrazzo and granite floor surfaces, but also marble or limestone surfaces.
  • the invention particularly relates to use of a tool for maintenance which is suitable for use on a daily basis to maintain a polished hard floor surface.
  • the pad is usually provided as a circular, disc-shaped body, which is to be disconnectably mounted on a circular carrier plate, which in use is caused to rotate in a plane parallel with the floor surface, such that the pad, when brought into contact with the floor surface, is slightly compressed by the pressure arising between the floor surface and the carrier plate.
  • the carrier plate is usually driven by a motor and may be mounted on a carrier frame, which may be arranged to be pushed or pulled by a walking operator or which may be arranged as a ridable vehicle.
  • Such pads are formed from fibers of an organic material, e.g. polyamide and/or polyester, particularly polyethylene terephtalate.
  • the fibers also include natural fibers, such as walnut fibers or coconut fibers.
  • the fibers of the pad is interconnected at their mutual points of contact by so-called melt bonding, whereby the fibers are subjected to heat that cause the outer part of the fibers to slightly melt and thereby to bond to each other.
  • the fibers may be interconnected at their mutual points of contact by the pad being impregnated with a polymer resin, hereinafter referred to as a "primary binder".
  • US-A-3,537,121 discloses pads for polishing surfaces of aluminum, plastic, wax and similar surfaces. US-A-3,537,121 also discloses production of such pads.
  • a binder mixed with abrasive particles is applied to the pad by passing the pad between a pair of squeeze rolls, one of which is partially immersed in a container for a mixture of binder resin and abrasive particles, after which the pad is allowed to cure or dry.
  • a pad is provided, which is entirely impregnated by the binder and abrasive particles.
  • US-A-4,893,439 discloses a pad for polishing floor surfaces or aluminum.
  • the pad consists of fibers of organic material and constitutes a lofty open non-woven structure, and contains a binder binding abrasive particles to the fibers.
  • the pad shown in US-A-4,893,493 has larger voids than that shown in US-A-3,537,121 , and thereby has an improved ability to absorb dirt, so that it can be used for a longer period. Also the pad disclosed in US-A-4,893,493 is entirely impregnated by binder and abrasive particles.
  • EP-A-0 397 374 discloses a pad for floor polishing machines, which also is entirely impregnated by binder and abrasive particles.
  • Pads of the above type are frequently used for so-called “burnishing”, i.e. dry polishing (often on a daily basis) of very lightly worn surfaces at high speed (1500-3000 rpm) and relatively low pressure, with a view to restoring a polished surface.
  • This type of treatment is commonly used for both vinyl and marble floorings.
  • Pads suitable for this purpose are available from 3M® under the designation “3MTM Floor Pads", and provide no or little effect on very hard floor surfaces, such as terrazzo or concrete, which have been subject to wear for a longer period of time.
  • EP-B-0 562 919 discloses a non-woven pad of polymer fiber, which is entirely impregnated by a binder comprising a mixture of curable plastic resin and abrasive particles having a particle size of 0,1-30 ⁇ m.
  • curable resins are mentioned phenol resin, acrylic resins, melamine resin and urea resin.
  • Diamond is mentioned as one among several other examples of plausible abrasive particles.
  • the pad disclosed therein is suitable for treatment of marble floor surfaces, and only in combination with crystallization chemicals, which means that treatment must be made in the presence of liquid containing a salt-forming acid.
  • the pad in EP-B-0 562 919 is also provided by passing a non-woven pad through a nip between two squeeze rolls, one of which being partially immersed in a binder/abrasive particles mixture, such that the binder and abrasive particles, via the surface of the cylinder is distributed in the pad.
  • the method described in EP-B-0 562 919 actually constitutes a vitrification method, used with a view to improving the stain resistance and durability of a marble floor.
  • This method is not suitable for daily maintenance purposes, since it involves use of special crystallization chemicals, including acids, which are to react with calcium present in the floor surface to form insoluble calcium salts.
  • Such a method is typically used once in connection with the initial preparation of the polished marble floor, and thereafter at intervals of 6-12 months.
  • the method described in EP-B-0 562 919 is thus too complicated for being used on a daily basis.
  • Pads of the type referred to in EP-B-0 562 919 are sold by 3M® under the designations "3MTM 5200 Brown Stone Renew Pad” and “3MTM 4000 Grey Stone Polish Pad", and are used for treating marble in the presence of crystallization chemicals and at relatively low speeds (below 250 rpm) .
  • WO03/075734 discloses a disc-shaped device for cleaning purposes, comprising a nylon scouring material, which is arranged on a rigid disc, whereby grinding elements containing industrial diamonds are placed in recesses in the active scouring surface.
  • a disadvantage with the device disclosed in WO03/07534 is that it does not eliminate the risk of debris getting stuck in or near the grinding elements.
  • Yet another disadvantage is that this tool is complex and therefore more prone to breaking and more difficult and expensive to manufacture.
  • the method should be simple to use, e.g. by persons who do not have specialist training in floor surface preparation, and the method should be usable with conventional floor surfacing equipment, e.g. burnishing machines, etc.
  • the tools should be easy to manufacture, not too expensive and durable.
  • the invention is based on the idea that abrasive particles in the form of diamond particles provide a polishing effect which is vastly superior to that achievable with those abrasive particles used in the examples shown in e.g. EP-B-0 562 919 , and that this polishing effect is so superior as to eliminate the need for crystallization chemicals.
  • diamond is understood to include natural diamond as well as synthetic diamond, and diamond particles being coated with any suitable coating, e.g. silver.
  • the term "effective amount" is understood as an amount that is sufficient to achieve a measurable gloss improvement as compared to the same treatment using a liquid containing no crystallization agent at all.
  • Amounts known to be effective are about 1-2 liters of crystallization agent (comprising 2-30 % by weight of e.g. magnesium hexafluorosilicate) per 50 m 2 of floor surface for a single treatment operation.
  • amounts known to be effective on an ad-hoc basis range from about 0,4 g of magnesium hexafluorosilicate per m 2 floor surface.
  • diluted crystallization agent e.g. at a ratio of 1:100 is also known to be effective when used repeatedly, e.g.
  • amounts known to be effective for maintenance on a regular basis range from about 0,004 g of magnesium hexafluorosilicate per m 2 floor surface. It is understood that there are other types of crystallization agents, e.g. zinc hexafluorosilicate, hydrofluoric acid and oxalic acid. The values given above may thus need to be adjusted to apply to the respective type of crystallization agent chosen.
  • the combination of a flexible pad and diamond particles provides compensation for unevenness in the surface, and distributes the pressure applied to the pad evenly. Also, this combination, through the flexibility of the pad, considerably reduces the risk of the diamonds scratching the surface.
  • diamond particles as abrasive particles when polishing hard stone surfaces provides an effect equal to or better than use of conventional abrasive particles, both in wet and dry conditions.
  • the use of diamonds enables the crystallization agent to be abolished, thereby eliminating its handling.
  • the abrasive particles have an average diameter of 0.1 to 30 ⁇ m, preferably between 0.1 and 15 ⁇ m and most preferably between 10 and 15 ⁇ m.
  • the second portion is substantially free from diamond particles.
  • pads according to the invention can be manufactured at a lower cost.
  • the tool may be used for and is particularly effective for hard stone or stone-like surfaces, such as granite, concrete, terrazzo, etc.
  • the pad consists of a disc-shaped body having a thickness and a first surface, wherein said abrasive particles are present on said first surface and down to a depth from said first surface, which depth is less than said thickness, such that said first portion is at said first surface and said second portion is at a second surface, opposite said first surface.
  • the pad consists of a disc-shaped body having a thickness and a first surface, wherein said abrasive particles are present over less than the entire first surface, such that said first and second portions are situated adjacent each other at said first surface.
  • This second embodiment facilitates migration of dust and debris into the pad.
  • the pad comprises an open, lofty, three dimensional non-woven web, including a plurality of fibers, which are adhered to each other at their points of mutual contact.
  • the abrasive particles may be bonded to the fibers of the pad by a secondary binder. Hence, the bonding of the fibers of the pad does not in any way need to be negatively affected by the fact that the abrasive particles are only present at the contact surface.
  • the secondary binder may be selected from a group consisting of phenol resin, melamine resin, urea resin and epoxy resin.
  • the secondary binder forms a plurality of distinct droplets having a maximum diameter which is smaller than an average length between two points of mutual contact of a fiber.
  • the fibers are not entirely coated by the binder resin, facilitating further the migration of dust and debris into the pad.
  • the pad may further comprise second abrasive particles selected from a group consisting of graphite, tin oxide, silicon carbide and aluminum oxide.
  • the pad is preferably provided in the shape of a circular disc having a diameter between 30 and 100 cm and an uncompressed thickness between 1 and 5 cm.
  • the description will first focus on a tool suitable for use in maintenance of hard surfaces, subsequently on the method for manufacturing the tool, and finally on the use of the tool for maintenance of a hard surface.
  • a pad 1 made up from an open, lofty three dimensional non-woven web of fibers 2.
  • a first surface of the pad 1 has a portion P1 presenting abrasive particles bonded to the web by means of a secondary binder, i.e. a binder having as a main purpose to bond fibers to the web.
  • the pad 1 is circular in shape.
  • FIG. 1b a cross section along the line S1-S2 in Fig. 1a is shown.
  • the portion P1 presenting the abrasive particles is present at the first surface A and to a depth D, which is less than the thickness T of the pad 1.
  • the second surface B there is a portion P2, which is substantially free from the abrasive particles and the secondary binder.
  • portions it is to be understood as a portions of the macrostructure of the pad 1 and not portions of the individual fibers.
  • a similar pad 1 there is shown a similar pad 1, the difference being that there is a portion P2' also at the first surface A, which portion P2' is substantially free from the abrasive particles and the secondary binder.
  • the abrasive particles are present throughout the secondary binder, and the fibers are bonded to each other by a primary binder and/or by being melt-bonded.
  • Fig. 3a is a microscope photograph showing the pad prior to application of the polymer resin/abrasive particles. From Fig. 3a , it can be seen that the fibers constituting the pad are held together at their points 10 of mutual contact by a primary polymer resin.
  • the pad is flexible and resilient and comprises polyester and nylon fibers.
  • a homogenous polymer resin mixture was prepared, consisting of 200 g PA resin 52-68 phenol resin (available from Perstorp AB, Perstorp, Sweden), 100 g of T-R ⁇ D® ethanol (available from Alfort & Cronholm AB, Bromma, Sweden) and 20 g of LANDS LS600F 4-8 ⁇ m diamond particles (available from Lands Superabrasives, Co., New York, NY, USA).
  • PTS 65% p-toluene sulfonic acid
  • the resin mixture was sprayed onto a first one A of the surfaces of the polishing pad, using a standard-type compressed air spray gun (normally used for spraying paint).
  • the pad with the uncured resin thereafter weighed 173 grams. Subsequently, the pad was placed in a hot air oven at approximately 120°C for approximately 20 minutes.
  • Fig. 3b is a microscope photograph.
  • Globules or droplets 11 of the resin/particle mixture are formed along each fiber, also between the fibers' points of mutual contact. The droplets are so distributed that the fibers to which they are adhered are not entirely covered.
  • Figs 4a-4b show a pad as described above with reference to Figs 1a-1b , and an enlargement of a portion of that pad ( Fig. 4b ), wherein droplets 11 of binder/particle mixture are attached to the fibers.
  • each surface portion was first treated with the brown pad and subsequently with the gray pad.
  • Table 1 Tests performed with water as lubricant on Kolm ⁇ rden marble Pad Brown Gray Green Initial gloss 17 17 10 Liquid Water Water Water Final gloss 17 35 30
  • Table 2 Tests performed without lubricant on Kolm ⁇ rden marble Pad Brown Gray Green Initial gloss 20 25 28 Liquid No No Final gloss 25 30 50
  • the pad according to the invention provides a noticeable improvement as compared with the prior art.
  • the improvement is particularly noticeable during dry conditions and on concrete.
  • Fig. 5 is a sectional view of a floor surfacing machine 20 on which a pad 1 according to the invention is mounted so as to define a contact surface 9 with the hard surface 8, which in this example is a floor surface.
  • the pad 1 is mounted on a driven, rotatable carrier plate 4, which is typically journalled in bearings and thus rotatable relative to a machine body 5, on which a motor unit 6 is arranged.
  • the machine has a handle 7, and is thus adapted for being held/pushed/pulled by a walking operator.
  • the floor surfacing machine 20 may be e.g. a ridable vehicle fitted with a carrier plate 4 that is adapted for receiving the pad 1.
  • the pad 1 and method described above can be used for everyday cleaning/maintenance of polished hard surfaces, such as stone, concrete or terrazzo floor surfaces using a floor surfacing machine such as a scrubber/dryer combination machine, e.g. the Nilfisk CR1300; a single disc floor maintenance machines (low speed or high speed), e.g. the Nilfisk 510B or 545; a burnisher, e.g. the Nilfisk SDH5120, BHS5120 or BHS7014, all of which are available from Nilfisk-Advance, Sweden.
  • a scrubber/dryer combination machine e.g. the Nilfisk CR1300
  • a single disc floor maintenance machines low speed or high speed
  • a burnisher e.g. the Nilfisk SDH5120, BHS5120 or BHS7014, all of which are available from Nilfisk-Advance, Sweden.
  • the treatment of the floor surface is typically performed by causing the pad, when in contact with the floor surface, to rotate in a plane parallel with the floor surface.
  • Typical rotational speeds are from 50 rpm to 3000 rpm. However, lower or higher rotational speeds are not excluded.
  • a first embodiment of the pad according to the invention comprises an open, lofty, three dimensional non-woven web, including a plurality of fibers, which are adhered to each other at their points of mutual contact by means of a primary binder, and in which abrasive particles are mixed with a secondary binder and applied only to a first surface of the pad, such that the pad is only partially impregnated by the binder/particle mixture.
  • the fibers may be melt-bonded to each other.
  • binder/particle mixture is only applied to parts of said first surface. This can be achieved by masking those parts of the surface to which the binder/particle mixture should not be applied.
  • the pad is entirely impregnated with the binder/particle mixture, e.g. by using such squeeze rollers as are described in EP-B-0 562 919 .
  • the abrasive particles are present in the material of the pad.
  • the invention is not limited to the use of phenol resin.
  • suitable resins are melamine, urea, epoxy and polyester resins.
  • the hardener may be selected from any hardener suitable for the type of resin selected. Also it is possible not to include the hardener, e.g. by allowing the pad to cure at a higher temperature and/or for a longer period of time.
  • the solvent (ethanol was used in the example) is provided merely to reduce the viscosity of the mixture and thereby to facilitate spraying thereof. Any suitable solvent may be used, and the solvent may also be excluded, provided that the method of application so allows.
  • the pad 1 having secondary binder and abrasive particles as described above may be attached to a disc or plate having an arbitrary connector for being connected to a carrier plate of the surfacing machine, or that the pad may be directly connectable to the surfacing machine by means of a Velcro-type hook arrangement provided on the carrier plate, the hooks of which engage the fibers of the pad 1.
  • the maintenance tool may be composed of the pad with the primary binder, the secondary binder and the abrasive particles, possibly with the addition of dyes or printed areas providing information on the type of pad, manufacturer, trademark etc.
  • the pad may be provided with a backing layer.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Mechanical Treatment Of Semiconductor (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Manufacturing Cores, Coils, And Magnets (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Floor Finish (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Hooks, Suction Cups, And Attachment By Adhesive Means (AREA)
  • Laminated Bodies (AREA)
  • Turning (AREA)
  • Mounting, Exchange, And Manufacturing Of Dies (AREA)
EP07101889A 2005-03-15 2005-03-15 Use of a system for for everyday maintenance of a hard floor surface of stone or stone-like material Revoked EP1787751B1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DK07101889.9T DK1787751T3 (da) 2005-03-15 2005-03-15 Anvendelse af et system til daglig vedligeholdelse af en hård gulvoverflade bestående af sten eller stenlignende materiale
PL07101889T PL1787751T3 (pl) 2005-03-15 2005-03-15 Zastosowanie układu do codziennej konserwacji twardej powierzchni podłogi z kamienia lub materiału podobnego do kamienia
SI200531364T SI1787751T1 (sl) 2005-03-15 2005-03-15 Uporaba sistema za vsakodnevno vzdrĺ˝evanje trde talne povrĺ ine iz kamna ali kamnu podobnega materiala
CY20111100931T CY1111862T1 (el) 2005-03-15 2011-09-27 Χρηση συστηματος για την καθημερινη συντηρηση σκληρων πετρινων επιφανειων δαπεδου ή υλικου σαν πετρα

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP05005570A EP1702714B1 (en) 2005-03-15 2005-03-15 Method for maintenance of hard surfaces

Related Parent Applications (2)

Application Number Title Priority Date Filing Date
EP05005570A Division EP1702714B1 (en) 2005-03-15 2005-03-15 Method for maintenance of hard surfaces
EP05005570.6 Division 2005-03-15

Publications (3)

Publication Number Publication Date
EP1787751A2 EP1787751A2 (en) 2007-05-23
EP1787751A3 EP1787751A3 (en) 2007-08-01
EP1787751B1 true EP1787751B1 (en) 2011-07-13

Family

ID=34934264

Family Applications (2)

Application Number Title Priority Date Filing Date
EP07101889A Revoked EP1787751B1 (en) 2005-03-15 2005-03-15 Use of a system for for everyday maintenance of a hard floor surface of stone or stone-like material
EP05005570A Revoked EP1702714B1 (en) 2005-03-15 2005-03-15 Method for maintenance of hard surfaces

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP05005570A Revoked EP1702714B1 (en) 2005-03-15 2005-03-15 Method for maintenance of hard surfaces

Country Status (13)

Country Link
EP (2) EP1787751B1 (ru)
CN (3) CN101219526B (ru)
AT (2) ATE516109T1 (ru)
CY (2) CY1108028T1 (ru)
DE (2) DE602005001110T2 (ru)
DK (2) DK1702714T3 (ru)
ES (2) ES2370913T3 (ru)
PL (2) PL1702714T3 (ru)
PT (2) PT1702714E (ru)
SI (1) SI1702714T1 (ru)
TW (1) TWI385052B (ru)
UA (3) UA94911C2 (ru)
ZA (3) ZA200708741B (ru)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8206511B2 (en) 2009-10-06 2012-06-26 Ecolab Usa Inc. Daily cleaner with slip-resistant and gloss-enhancing properties
US9920281B2 (en) 2009-11-12 2018-03-20 Ecolab Usa Inc. Soil resistant surface treatment
DE102010001769A1 (de) * 2010-02-10 2011-08-11 JÖST GmbH, 69483 Schleif- und Reinigungskörper
DE102010002539A1 (de) * 2010-03-03 2011-09-08 Jöst Gmbh Schleifkörper mit Staubspeicherschicht
US8585829B2 (en) 2010-12-13 2013-11-19 Ecolab Usa Inc. Soil resistant floor cleaner
US20130005221A1 (en) * 2011-06-30 2013-01-03 Saint-Gobain Ceramics & Plastics, Inc. Method of polishing a workpiece with an abrasive segment comprising abrasive aggregates having silicon carbide particles
WO2015119826A1 (en) 2014-02-04 2015-08-13 3M Innovative Properties Company Double-sided buffing pads with intertwined seams
CN104400586B (zh) * 2014-10-17 2017-03-15 东莞市热线家具有限公司 一种木材打透毛刺的方法
CN105690240B (zh) * 2016-04-01 2018-09-11 东莞市中微纳米科技有限公司 一种柔性抛光垫
EP3661697A1 (en) * 2017-07-31 2020-06-10 3M Innovative Properties Company Floor pad with variable abrasive distribution
CN110157337A (zh) * 2019-06-26 2019-08-23 河南广度超硬材料有限公司 凹凸不平曲面花岗岩的翻新抛光粉及其翻新抛光的方法
CN111644990B (zh) * 2020-05-29 2021-04-30 杭州电子科技大学 利用木纤维润湿粉末压制的模压棒来抛光硬质材料的方法
CN113400206B (zh) * 2021-06-24 2022-07-19 郑州磨料磨具磨削研究所有限公司 碳化硅衬底抛光用砂轮及其制备方法
CN114161230B (zh) * 2021-11-29 2024-04-12 凯吉斯金刚石(广州)有限公司 一种大理石台面的翻新工艺

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2598593A (en) * 1948-09-30 1952-05-27 Ibm Polycentric articulated finger for artificial hands
DE1694594C3 (de) * 1960-01-11 1975-05-28 Minnesota Mining And Manufacturing Co., Saint Paul, Minn. (V.St.A.) Reinigungs- und Polierkörper
US3324609A (en) * 1964-08-11 1967-06-13 Norton Co Non-woven webs
US4078340A (en) * 1973-12-07 1978-03-14 Minnesota Mining And Manufacturing Company Low density abrasive pad having different abrasive surfaces
EP0449509B1 (en) * 1990-03-30 1995-02-22 Ronald Carlysle Wiand Marble, granite and stone finishing method and abrasive pads therefor
US5054245A (en) * 1990-07-25 1991-10-08 The Butcher Company Combination of cleaning pads, cleaning pad mounting members and a base member for a rotary cleaning machine
US5282900A (en) * 1992-03-19 1994-02-01 Minnesota Mining And Manufacturing Company Nonwoven surface treating articles, system including same, and method of treating calcium carbonate-containing surfaces with said system
US5573844A (en) * 1995-01-06 1996-11-12 Minnesota Mining And Manufacturing Company Conformable surface finishing article and method for manufacture of same
AU1986697A (en) * 1996-11-06 1998-05-29 Minnesota Mining And Manufacturing Company Multiple abrasive assembly and method
US20040098923A1 (en) * 2002-11-25 2004-05-27 3M Innovative Properties Company Nonwoven abrasive articles and methods for making and using the same

Also Published As

Publication number Publication date
PL1787751T3 (pl) 2011-12-30
CY1111862T1 (el) 2015-11-04
CN101175602B (zh) 2013-11-06
EP1702714A1 (en) 2006-09-20
PT1787751E (pt) 2011-10-18
TWI385052B (zh) 2013-02-11
CN101219526A (zh) 2008-07-16
CN101219526B (zh) 2012-05-30
PL1702714T3 (pl) 2007-09-28
DE602005001110T2 (de) 2008-01-10
EP1702714B1 (en) 2007-05-09
EP1787751A2 (en) 2007-05-23
PT1702714E (pt) 2007-07-26
UA88803C2 (ru) 2009-11-25
ZA200708741B (en) 2009-03-25
CY1108028T1 (el) 2013-09-04
ES2370913T3 (es) 2011-12-23
DE202005021478U1 (de) 2008-04-17
ES2286730T3 (es) 2007-12-01
UA94911C2 (ru) 2011-06-25
ZA200805901B (en) 2010-04-28
EP1787751A3 (en) 2007-08-01
SI1702714T1 (sl) 2007-10-31
CN101219527A (zh) 2008-07-16
TW200714412A (en) 2007-04-16
DK1702714T3 (da) 2007-09-10
UA88099C2 (ru) 2009-09-10
ZA200805902B (en) 2010-04-28
ATE516109T1 (de) 2011-07-15
DK1787751T3 (da) 2011-10-31
CN101175602A (zh) 2008-05-07
ATE361815T1 (de) 2007-06-15
CN100571981C (zh) 2009-12-23
DE602005001110D1 (de) 2007-06-21

Similar Documents

Publication Publication Date Title
EP2311604B1 (en) A method for increasing gloss on a polished, hard floor surface of stone or stone-like material
EP1787751B1 (en) Use of a system for for everyday maintenance of a hard floor surface of stone or stone-like material
US10065283B2 (en) Method and tool for maintenance of hard surfaces, and a method for manufacturing such a tool
AU2007216871C1 (en) Methods and Tool for Maintenance of Hard Surfaces, and a Method for Manufacturing Such a Tool

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AC Divisional application: reference to earlier application

Ref document number: 1702714

Country of ref document: EP

Kind code of ref document: P

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

17P Request for examination filed

Effective date: 20080110

17Q First examination report despatched

Effective date: 20080214

AKX Designation fees paid

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

AXX Extension fees paid

Extension state: HR

Payment date: 20080110

Extension state: YU

Payment date: 20080110

Extension state: BA

Payment date: 20080110

Extension state: MK

Payment date: 20080110

RAX Requested extension states of the european patent have changed

Extension state: RS

Payment date: 20080110

Extension state: MK

Payment date: 20080110

Extension state: HR

Payment date: 20080110

Extension state: BA

Payment date: 20080110

DAX Request for extension of the european patent (deleted)
GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RTI1 Title (correction)

Free format text: USE OF A SYSTEM FOR FOR EVERYDAY MAINTENANCE OF A HARD FLOOR SURFACE OF STONE OR STONE-LIKE MATERIAL

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AC Divisional application: reference to earlier application

Ref document number: 1702714

Country of ref document: EP

Kind code of ref document: P

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: NL

Ref legal event code: T3

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602005029038

Country of ref document: DE

Effective date: 20110908

REG Reference to a national code

Ref country code: RO

Ref legal event code: EPE

REG Reference to a national code

Ref country code: PT

Ref legal event code: SC4A

Free format text: AVAILABILITY OF NATIONAL TRANSLATION

Effective date: 20111011

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: FIAMMENGHI-FIAMMENGHI

Ref country code: DK

Ref legal event code: T3

REG Reference to a national code

Ref country code: SK

Ref legal event code: T3

Ref document number: E 10244

Country of ref document: SK

REG Reference to a national code

Ref country code: EE

Ref legal event code: FG4A

Ref document number: E005856

Country of ref document: EE

Effective date: 20111007

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2370913

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20111223

REG Reference to a national code

Ref country code: PL

Ref legal event code: T3

REG Reference to a national code

Ref country code: GR

Ref legal event code: EP

Ref document number: 20110402342

Country of ref document: GR

Effective date: 20111117

REG Reference to a national code

Ref country code: HU

Ref legal event code: AG4A

Ref document number: E012151

Country of ref document: HU

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

26 Opposition filed

Opponent name: 3M INNOVATIVE PROPERTIES CO.

Effective date: 20120412

REG Reference to a national code

Ref country code: DE

Ref legal event code: R026

Ref document number: 602005029038

Country of ref document: DE

Effective date: 20120412

PLAF Information modified related to communication of a notice of opposition and request to file observations + time limit

Free format text: ORIGINAL CODE: EPIDOSCOBS2

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

R26 Opposition filed (corrected)

Opponent name: 3M INNOVATIVE PROPERTIES CO.

Effective date: 20120412

R26 Opposition filed (corrected)

Opponent name: 3M INNOVATIVE PROPERTIES CO.

Effective date: 20120412

REG Reference to a national code

Ref country code: DE

Ref legal event code: R103

Ref document number: 602005029038

Country of ref document: DE

Ref country code: DE

Ref legal event code: R064

Ref document number: 602005029038

Country of ref document: DE

RDAF Communication despatched that patent is revoked

Free format text: ORIGINAL CODE: EPIDOSNREV1

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BG

Payment date: 20140211

Year of fee payment: 10

Ref country code: LU

Payment date: 20140313

Year of fee payment: 10

Ref country code: RO

Payment date: 20140213

Year of fee payment: 10

Ref country code: MC

Payment date: 20140212

Year of fee payment: 10

Ref country code: SK

Payment date: 20140207

Year of fee payment: 10

Ref country code: NL

Payment date: 20140308

Year of fee payment: 10

Ref country code: CZ

Payment date: 20140228

Year of fee payment: 10

Ref country code: FI

Payment date: 20140311

Year of fee payment: 10

Ref country code: LT

Payment date: 20140220

Year of fee payment: 10

Ref country code: IS

Payment date: 20140207

Year of fee payment: 10

Ref country code: EE

Payment date: 20140213

Year of fee payment: 10

Ref country code: CH

Payment date: 20140312

Year of fee payment: 10

Ref country code: SE

Payment date: 20140311

Year of fee payment: 10

Ref country code: DK

Payment date: 20140311

Year of fee payment: 10

Ref country code: IE

Payment date: 20140311

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20140310

Year of fee payment: 10

Ref country code: HU

Payment date: 20140225

Year of fee payment: 10

Ref country code: AT

Payment date: 20140226

Year of fee payment: 10

Ref country code: PL

Payment date: 20140218

Year of fee payment: 10

Ref country code: TR

Payment date: 20140226

Year of fee payment: 10

Ref country code: SI

Payment date: 20140211

Year of fee payment: 10

Ref country code: ES

Payment date: 20140211

Year of fee payment: 10

Ref country code: GR

Payment date: 20140214

Year of fee payment: 10

Ref country code: FR

Payment date: 20140311

Year of fee payment: 10

RDAG Patent revoked

Free format text: ORIGINAL CODE: 0009271

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT REVOKED

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20140312

Year of fee payment: 10

Ref country code: PT

Payment date: 20140228

Year of fee payment: 10

REG Reference to a national code

Ref country code: CH

Ref legal event code: PLX

27W Patent revoked

Effective date: 20140122

GBPR Gb: patent revoked under art. 102 of the ep convention designating the uk as contracting state

Effective date: 20140122

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20140312

Year of fee payment: 10

REG Reference to a national code

Ref country code: PT

Ref legal event code: MP4A

Effective date: 20140730

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20140417

Year of fee payment: 10

Ref country code: CY

Payment date: 20140206

Year of fee payment: 10

REG Reference to a national code

Ref country code: SK

Ref legal event code: MC4A

Ref document number: E 10244

Country of ref document: SK

Effective date: 20140122

Ref country code: DE

Ref legal event code: R107

Ref document number: 602005029038

Country of ref document: DE

Effective date: 20140904

REG Reference to a national code

Ref country code: EE

Ref legal event code: MF4A

Ref document number: E005856

Country of ref document: EE

Effective date: 20140729

Ref country code: AT

Ref legal event code: MA03

Ref document number: 516109

Country of ref document: AT

Kind code of ref document: T

Effective date: 20140122

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF THE APPLICANT RENOUNCES

Effective date: 20110713

Ref country code: LI

Free format text: LAPSE BECAUSE OF THE APPLICANT RENOUNCES

Effective date: 20110713

REG Reference to a national code

Ref country code: SE

Ref legal event code: ECNC

REG Reference to a national code

Ref country code: SE

Ref legal event code: ECNC

REG Reference to a national code

Ref country code: SI

Ref legal event code: KO00

Effective date: 20151116